QUANTA CHEMISTRY

An Institute of Chemical Sciences

CSIR-NET | IIT-GATE | IIT-JAM | Other MSc. Entrance

DPP- (2) Name Reaction (JAM)

1. What is the major product –

O

OH 

COOH O
(a) (b) (c) (d)
O OH O O
2. How many of the following give CO2.
COOH
O
O O
(a) HO (b) (c) (d) O OH
O O O O
O COOH COOH
3. What is the major product –
O O
O
OEt 1. NaOEt 1. NaOH
(A) (B)
2. CH3 – Br 2. HCl / 

O OEt
O O
O COOH O CH 3

(a) (b)

COOH O OH
O
O O CH3
O CH3
COOH
(c) COOH (d)

COOEt

Address : 50 Mall Road, Near GTB Nagar Metro Station Gate No 3, Kingsway Camp, Delhi 110009
1
Contact Us : 9990382567, 9717373074, 8285815185 [1]
 DPP- (2) Name Reaction (JAM)
4. What is the major product –
O O

EtO OH
O O O O O
(a) (b) (c) (d)
EtO HO HO OH
5. What is the major product –
O O

HO OH
O O O
(a) OH (b) (c) (d) All of the above
OH
6. What is the major product –
O O

H2N OH
O
O O O
(a) (b) (c) (d) N
H2N OH H2N OH
H
7. What is the major product –
O O

OH 
OH

O
O O
O
O O O

(a) OH (b) O (c) OH (d)

O O
8. What is the major product –
O O O

HO OH 

O O O O
COOH HOOC
(a) (b) (c) (d)

9. What is the major product –

O OH

HO OH  (A) (B)
O O
Address : 50 Mall Road, Near GTB Nagar Metro Station Gate No 3, Kingsway Camp, Delhi 110009
2
Contact Us : 9990382567, 9717373074, 8285815185 [2]
 DPP- (2) Name Reaction (JAM)

O O O O O
(a) (b) (c) (d)
HO OH H3C OH HO C C OH

10. What is the major product –

O O
1. NaOEt 1. NaOEt
EtO OEt (A) (B)
2. CH3 – I 2. HCl / 
O OEt
O O
O O O
(a) (b) (c) (d) EtO COEt
CH 3
HO HO EtO
Numerical Answer Type (NAT)
11. How many moles of CO2 released.
COOH
F O
OH

O
O O COOH
COOH
12. How many enols are possible.
O
H H+
O
13. How many moles of CO2 released as
O OH
O
O
OH 
O
C O
OH
14. How many enol can be posible.
O
H+

ANSWER KEY
1. (c) 2. (a) 3. (b) 4. (a) 5. (b) 6. (a) 7. (c)
8. (a) 9. (b) 10. (b) 11. (2) 12. (2) 13. (3) 14. (1)

Address : 50 Mall Road, Near GTB Nagar Metro Station Gate No 3, Kingsway Camp, Delhi 110009
Contact Us : 9990382567, 9717373074, 8285815185
3 [3]
 DPP- (2) Name Reaction (JAM)

HINTS & SOLUTION

1. OH 

O O
Correct option is (c)

O O

2. HO
O O
O
Correct option is (a)
O O O O
O O
3. OEt OEt NaOH
CH3 – Br CH3

O OEt O OEt
O O O
O O
OH HCl / 
CH3
CH3 – CO2

O OH O OH
Correct option is (b)

O O O
4.  + CO2
EtO OH EtO
Correct option is (a)
O O O O
5. 
HO OH – CO2 HO HO CH3
Correct option is (b)
O O O
6. 
+ CO2
H2N OH H2N
Correct option is (a)

Address : 50 Mall Road, Near GTB Nagar Metro Station Gate No 3, Kingsway Camp, Delhi 110009
4
Contact Us : 9990382567, 9717373074, 8285815185 [4]
 DPP- (2) Name Reaction (JAM)

O O O

7. OH 
OH OH

O O
Correct option is (c)

O O O O O O

8. HO OH  HO
– CO 2 – CO 2
Correct option is (a)

O OH HO O O
9. HO OH 
C
–CO2 HO CH3
O O O
HO
Correct option is (b)

O O O O
10. EtO OEt NaOEt EtO OEt CH3 – I

O OEt O OEt
O O O O O
CH3
EtO OEt NaOH CH3
HO OH HO
CH3 – 2CO2
O OEt O OH
Correct option is (b)
11. 2- keto acid are present so 2 moles of CO2 released.
Correct answer is (2)
O OH
12. H H

OH O

Address : 50 Mall Road, Near GTB Nagar Metro Station Gate No 3, Kingsway Camp, Delhi 110009
Contact Us : 9990382567, 9717373074, 8285815185
5 [5]
 DPP- (2) Name Reaction (JAM)
O O H
H H+ H

O O H

H+ H2 O

H
O O
H H
H
O OH
A Major
H2O OH
H

O
B
Correct answer is (2)

O OH O OH
O C
O O O
OH  – CO2
13.
O O O
C O

OH

Correct answer is (3)

H
O O OH
14. H+ H2O

Enol.
Correct answer is (1)

Address : 50 Mall Road, Near GTB Nagar Metro Station Gate No 3, Kingsway Camp, Delhi 110009
6
Contact Us : 9990382567, 9717373074, 8285815185 [6]