QUANTA CHEMISTRY

An Institute of Chemical Sciences

CSIR-NET | IIT-GATE | IIT-JAM | Other MSc. Entrance

DPP- (8) Name Reaction (JAM)

1. Major product A will be

CO2Me 1. MeOK, THF

+
O O

CO 2Me O COOMe COOMe

(a) (b) (c) (d)

O O O O
2. Major product
COOEt EtO
+
EtOOC EtOH
O

O O O O

(a) (b) (c) (d)

O O O O
COOEt COOEt COOEt COOEt

3. Major product formed

O OEt

O
NaOEt
O

Address : 50 Mall Road, Near GTB Nagar Metro Station Gate No 3, Kingsway Camp, Delhi 110009
1
Contact Us : 9990382567, 7082062392, 9717373074, 8285815185
 DPP- (8) Name Reaction (JAM)
O O
O O O
O OEt O OEt
OEt
(a) (b) (c) (d)
O
O O
O O
4. Major product formed in the given reaction
OEt
O O 1.
O
EtO OEt NaOEt
2. NaOH
3. H3O+/
O
O O HO
(a) (b) OH
HO OH O
O

HO
O
(c) (d) O OH
HO
5. Major product will be
O
O

NaOH
O
O
O O
O O O
O

(a) (b) (c) (d)

O O O
O
6. Major product formed
O
O
OEt
1.

NaOEt
2. NaOH

Address : 50 Mall Road, Near GTB Nagar Metro Station Gate No 3, Kingsway Camp, Delhi 110009
2
Contact Us : 9990382567, 9717373074, 8285815185
 DPP- (8) Name Reaction (JAM)
O O O O

OH OH
(a) (b)

O OH O OH
O O

(c) (d)

7. Major product A will be

O 1. NaOEt
EtO OEt OEt (A)
EtO EtOH
+ 2. NaOH
O O O
3. H 3O+/
OH
O O
O O
(a) (b)
HOOC HO OH
OH
O COOH O O COOH
(c) (d)
HO OH HO
8. Major product formed
O
O CO2Et
H
H3C

O O O
COOEt
(a) (b) (c) (d)
COOEt O
COOEt COOEt

9. Major product formed

O
CHO
KOH

O
O
CHO CHO
O
(a) (b) (c) (d)
O O O
O
10. Major product formed

Address : 50 Mall Road, Near GTB Nagar Metro Station Gate No 3, Kingsway Camp, Delhi 110009
3
Contact Us : 9990382567, 9717373074, 8285815185
 DPP- (8) Name Reaction (JAM)

COOEt O
KOEt

O
O
COOEt COOEt
O (c) O
(a) (b) (d)
O O O O

11. Major product formed –

O
KOC(CH 3)3
CH3
+ H2C CHCO 2CH 3

O O
CH3 CH3
(a) OH (b) OCH3

O O

O O
H3C
(c) OH (d) OEt
O O

12. Major product A will be

O
1. NaOEt
2. NaOH
+
COOEt 3. H 3O /

COOEt

Address : 50 Mall Road, Near GTB Nagar Metro Station Gate No 3, Kingsway Camp, Delhi 110009
4
Contact Us : 9990382567, 9717373074, 8285815185
 DPP- (8) Name Reaction (JAM)

O
O
O
O COOH
(a) (b) (c) (d)
COOH COOH
COOH

13. Major product will be

O
Ph + NaOH
CN
O CN O O
O
Ph CN
(a) NC (b) (c) (d)
Ph CN
Ph Ph
14. Major product A will be
O
O
(A)
NaOH
O
O O O O

(a) (b) (c) (d)

O O O O
15. Major product (A) will be
O
O
NaOH
O O O O

(a) (b) (c) (d)

ANSWER KEY
1. (a) 2. (c) 3. (c) 4. (a) 5. (c) 6. (b) 7. (a)
8. (c) 9. (a) 10. (d) 11. (b) 12. (d) 13. (c) 14. (c)
15. (c)

Address : 50 Mall Road, Near GTB Nagar Metro Station Gate No 3, Kingsway Camp, Delhi 110009
5
Contact Us : 9990382567, 9717373074, 8285815185
 DPP- (8) Name Reaction (JAM)

HINTS & SOLUTION

O
C OMe 1. MeOK, THF
1. + O
O

O O O

C OMe OMe OMe

+ O MeOK/THF
O O O
O O
O O
OMe OEt
–H2O

O O
OH
H
Correct option is (a)
O
O
EtOOC EtOOC EtO EtO C
2. + O O
EtOOC EtOOC EtO C
O
O
EtO C

O O
Correct option is (c)

OEt
O O O
H O OEt
3. + OEt
NaOEt O
O O O O
O
H+

OEt
O
O
Correct option is (c)
Address : 50 Mall Road, Near GTB Nagar Metro Station Gate No 3, Kingsway Camp, Delhi 110009
6
Contact Us : 9990382567, 9717373074, 8285815185
 DPP- (8) Name Reaction (JAM)

O O
O O O O
+ OEt EtO C
EtO OEt EtO OEt OEt
4. H H NaOEt EtO C
O
O
O OH O O
H+ EtO C EtO C NaOH
OEt OEt
EtO C EtO C
O O
O O
NaOH HO C  decarboxylation HO OH
OH
 H3O+/
HO C O O
–CO2
O
Correct option is (a)

O O
O
O O O O O
H
5. H + H+
O NaOH O O O
Correct option is (c)

O O O O O
+
6. OEt 1. NaOEt OEt OEt H
H + +
2. NaOH
O
O O

OEt OH
NaOH
O O
Correct option is (b)

O OEt OEt OEt OEt

O
EtO EtO
OEt O O O H+ O O O
+
7. EtO O EtO EtO
OEt OEt
O
O O

Address : 50 Mall Road, Near GTB Nagar Metro Station Gate No 3, Kingsway Camp, Delhi 110009
7
Contact Us : 9990382567, 9717373074, 8285815185
 DPP- (8) Name Reaction (JAM)

OH OH OH

 H3O +/ 
NaOH O O O O O
HO Decarboxylation HOOC
OH –CO2 OH
O
Correct option is (a)

O O
NaOEt
8. COOEt
+ H EtOH
COOEt OH
O CH3
O O COOEt COOEt
EtO –H2O
COOEt H
H +
O O
O
Correct option is (c)

O CHO CHO
CHO

9.
O O O
OH

Correct option is (a)

O COOEt COOEt
COOEt

10.
O O O
OH

Correct option is (d)

O O
H O O
11. CH3 KOC(CH3) 3 CH3
+ H2C C C OCH3 + H2C C C OCH3
H H

O O
O OH
CH3 CH3
H2C C C OCH3 H+ CH C OCH3
H

Address : 50 Mall Road, Near GTB Nagar Metro Station Gate No 3, Kingsway Camp, Delhi 110009
8
Contact Us : 9990382567, 9717373074, 8285815185
 DPP- (8) Name Reaction (JAM)
O
CH 3
OCH3

O
Correct option is (b)

O O O O
1. NaOEt H+ NaOH
2. NaOH
12. H 3. H 3O+/ COOEt COOEt
COOEt COOEt
COOEt COOEt
COOEt COOEt

O O

O H3O +/
O
 C OH Decarboxylation
(–CO2) C OH
C OH

O

Correct option is (d)

O O Ph
Ph + NaOH Ph + H+
CN C N CN
13
H O

Correct option is (c)

O O O O
3 1
5 4 2
14.. NaOH

O O O O O 1 O O
O O
NaOH

O O
HO H
Correct option is (c)
O O
H
O O O HO

O NaOH –H2O
15.
NaOH
O O

Correct option is (c)

Address : 50 Mall Road, Near GTB Nagar Metro Station Gate No 3, Kingsway Camp, Delhi 110009
9
Contact Us : 9990382567, 9717373074, 8285815185