IITJEE 2021

PRACTICE PAPER – 6
PHYSICAL CHEMISTRY
(TEAS, TOAS, TIAS, TEOS) TIME : 60 MIN
ONE OR MORE THAN ONE CORRECT:

1. Select the correct statement:

(A) Over a boundary surface, value of probability density is constant for an orbital.
(B) Probability of finding an electron is 100% within the boundary surface diagram of that orbital.
(C) Number of angular nodes for an orbital is always less than the number of radial nodes for that
orbital.
(D) For 1s orbital, the probability density is maximum at the nucleus.

2. Liquids ‘P’ and ‘Q’ form a solution resulting minimum boiling azeotrope. Which of the following is/are
correct parameters for the solution?
(A) Hmix = +ve (B) Smix = +ve (C) | Ssurr| < | Smix| (D) Vmix = - ve

3. Which of the following statement(s) is/are incorrect regarding activated adsorption?

(A) Its extent increases with the increase in pressure and it may change to multilayer adsorption at
high pressure.
(B) Its extent decreases with the decrease in temperature and it may change to multilayer adsorption
at low temperature.
(C) Its extent increases with the increase in surface area of adsorbent.
(D) When oxygen is adsorbed at graphite surface, none of the gas leaves the surface on strong heating.

4. 100 ml of 0.2M-H3A (tribasic acid) solution is mixed with 100 ml of 0.1M-Na3A solution. Correct
information(s) related with the final solution is/are (For H3A: K1 = 10-5, K2 = 10-9, K3 = 10-13)
(A) pH = 7.00 (B) [H3A] 1.5 10-3 M
(C) [A3-] 1.5 10-9 M (D) [H2A-] 0.15 M

5. A heat engine absorbs 760 kJ heat from a hot reservoir at 380K and rejects heat to the cold reservoir at
280K. Which of the following value of heat is impossible to be rejected by the engine?
(A) 650 kJ (B) 560 kJ (C) 504 kJ (D) 380 kJ

SUBJECTIVE (DECIMAL TWO DIGIT):

6. 40 gm of a sample of caustic soda containing NaOH, Na2CO3 and inert impurity is dissolved in water
to prepare 1.0 litre solution. A 25 ml portion of this solution required 24 ml 1.0 M-HCl for complete
neutralisation. To another 25 ml solution, excess of BaCl2 is added, and after filtration, the resulting
solution required 22 ml HCl of same strength to reach end point. Calculate the mass percent of Na2CO3
in the original sample.

7. A cloud mass moving across the ocean at an altitude of 2000 m encounters a coastal mountain range.
As it rises to a height of 3500 m to pass over the mountains, it undergoes an adiabatic expansion. The
pressure at 2000 m and 3500 m is 0.80 and 0.60 atm, respectively. If the initial temperature of the cloud
mass is 290K, what is the cloud temperature (in K) as it passes over the mountains? Assume that CP.m
for air is 29.88 JK-1 mol-1 and that air obeys the ideal gas law. (R = 8.3 J K-1 mol-1, log 2 = 0.30, log 3 =
0.48, 30 log 0.92 = −1)

8. Calculate the pH of 5×10-6 M-HCN solution. (Ka = 5 × 10-10, log 2 = 0.30)

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 IITJEE 2021
PRACTICE PAPER – 6
PHYSICAL CHEMISTRY
(TEAS, TOAS, TIAS, TEOS) TIME : 60 MIN

9. What is the partial pressure (in Pa) of HCl(g) above a solution that is 2M in H+ and 2M in Cl-? Given:
35900
f G oHCl ( g ) = - 95.27 kJ/mol, f G oCl− ( aq ) = - 131.17 kJ/mol [ = ln (1.96 106)]
8.314 298

10. How many of the following statements are correct?

(A) Delta at the mouth of river is formed due to coagulation of the colloidal sea water by the
electrolytes present in the river water.
(B) Artificial rain is caused by the coagulation of colloidal water droplets in the cloud by an
electrolyte.
(C) Cottrell precipitator is used in the precipitation of the colloidal waste in the sewage water.
(D) Cheese is an example of solid foam.
(E) A colloid formed by adding small amount of AgNO3 to KI solution is negatively charged.
(F) Micelles are formed only below the Kraft temperature.
(G) Mixing of hydrated ferric oxide sol and arsenious sulphide sol bring mutual coagulation.
(H) An oil in water emulsion can be diluted by addition of water.
(I) Emulsions show Brownian motion and Tyndall effect.

11. At 25oC, the vapour pressure of water increases from 30 mm Hg to 31 mm Hg on increasing the external
pressure up to 10 atm. If the vapour pressure of water is to be maintained at 30 mm Hg at 25 oC and
10 atm external pressure, how many gram NaCl should be added per kg of water?

12. The molecular diameter of a N2 molecule, as deduced from the Vander waals parameter, b, is
3.20 × 10-8 cm. The density of liquid nitrogen is 0.80 gm/cm3. On a hard sphere model, what percent of
the liquid nitrogen appears to be empty space? [ (3.2)3 = 102.94, NA = 6 1023]

PARAGRAPH BASED:

In any nuclear reaction, the total mass of products is found to be less than the total mass of
reactants. The difference in mass is due to the conversion of some mass into energy and hence
energy is produced in the nuclear reactions.

13. The nuclide Sc50, mass 49.9516 amu, is neutron rich. It decays to form Ti50, mass 49.94479 amu. If the
emitted -particle has a kinetic energy of 0.80 MeV, what is the kinetic energy of the antineutrino
emitted simultaneously?
(A) 2.87 MeV (B) 5.54 MeV (C) 9.36 MeV (D) 6.34 MeV

14. The alpha particles emitted by radium have energies of 4.795 MeV and 4.611 MeV. What is the
wavelength of the gamma rays accompanying the decay? The difference in energies of alpha particle
emitted out is equal to the energy of gamma rays.
(A) 6.74 pm (B) 9.87 pm (C) 3.37 pm (D) 4.58 pm

15. Th228 emits an alpha particle to reduce to Ra224. Calculate the kinetic energy of the alpha particle emitted
in the following decay: Th228 → Ra224* + ; Ra224* → Ra224 + (217 KeV) Atomic masses of Th228,
Ra224 and He4 are 228.028726 u, 224.020196 u and 4.00260 u, respectively.
(A) 1.12 MeV (B) 3.24 MeV (C) 4.46 MeV (D) 5.31 MeV

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 IITJEE 2021
PRACTICE PAPER – 6
PHYSICAL CHEMISTRY
(TEAS, TOAS, TIAS, TEOS) TIME : 60 MIN

ANSERKEY

1. A, D 2. A, B, C 3. A, D 4. A, B, C, D
5. C, D 6. 10.60 7. 266.80 8. 6.95
9. 0.20 10. (B, E, G, H, I) 11. 54.16 or 54.17 12. 70.59
13. B 14. A 15. D