11.

True about alkyl halides is/are -

(A) Tertiary alkyl halides undergo SN2 substitutions
(B) Alkyl iodides on exposure to sunlight gradually darken
Model Paper-03 (C) Alkyl chlorides do not give beilstein test
(D)A nucleophilic substitution is most difficult in alkyl iodides
Subject: Chemistry Max. Marks: 70 12. Hydrogen bonding is possible in-
Class: Second PU Time: 3.15 hrs (A) Ethers (B) Hydrocarbons (C) Alkanes (D) Alcohols
13. Which of the following compounds does not have a carboxyl group -
(A) Methanoic acid (B) Ethanoic acid (C) Picric acid (D) Benzoic acid
PART - A 14. Gabriel phthalimide reaction is used to prepare -
I. Answer all of the following questions. 20 X 1 = 10 (A) Primary amine (B) Secondry amine (C) Tertiary amine (D) All of above
15. The main structural feature of protein is–
1. Which is amorphous solid - (A) Ester linkage (B) Ether linkage (C) Peptide linkage (D) All of these
(A) Rubber (B) Plastic (C) Glass (D) All
2. 15 gram of methyl alcohol is dissolved in 35 gram of water. What is the mass percentage of II. Fill in the blanks by using appropriate word from those given in the brackets: 5 X 1 = 05
methyl alcohol in solution?
(A) 30% (B) 50% (C) 70% (D) 75% (Antiseptic, Solute, Antipyretic, diatomic covalent, instantaneous rate)
3. Molarity of a solution relates the- 16. The component of solution which is in lesser amount is_____
(A) Moles of solute and solvent (B) Moles of solute and mass of solution
17. Slope at any point of the curve indicates ________ of reaction.
(C) Volume of solute and volume of solvent (D) Volume of solution and moles of
solute 18. All the halogens exist as _______ molecules
4. The passage of current through a solution of certain electrolyte results in the evolution of 19. Iodoform is extensively used as an _________ for dressing of wounds
H2 at cathode and Cl2 at anode. The electrolytic solution is - 20. ________is a drug which is responsible for lowering the temperature of feverish body.
(A) Water (B) H2SO4 (C) Aq. NaCl (D) Aq. CuCl2
5. When concentration of reactant in reaction A → B is increased by 8 times, the rate increase
only 2 times. The order of the reaction would be- PART - B
(A) 2 (B) 1/3 (C) 4 (D) ½
III. Answer any FOUR of the following questions. 4X2=8
6. In order to coagulate the impurities present in water. Which is the most effective ion
present in the 'alum' - 21. Distinguish between hexagonal and monoclinic unit cells.
(A) K+ (B) SO42– (C) Al3+ (D) None of these 22. What is a salt bridge? Give one function of it.
7. Carnallite is an ore of: 23. What is zero order reaction? Give an example.
(A) Sodium (B) Potassium (C) Mangnese (D) Aluminium 24. Among lantanoid contraction and actionoid contraction which is greater? A justify with
8. The formula of sulphur molecule is – your answer.
(A) S2 (B) S4 (C) S6 (D) S8 25. With a suitable example write equations for Kolbe’s rection.
9. Which of the following statements is correct ? 26. Identify A and B in the following reaction.
(A) Iron belongs to third transition series of the periodic table
CHO
(B) Iron belongs to f-block of the periodic table
(C) Iron belongs to first transition series
(D) Iron belongs to group VIII of the periodic table
10. The solution of the complex [Cu(NH3)4] SO4 in water – 2 + Conc. NaoH A+B.

(A) Will give the tests of Cu2+ ions 27. Explain saponification of oils/fats with equation.
(B) Will give the tests of NH3
28. What are antifertility drugs? Give example.
(C) Will give the tests of SO42– ions
(D) Will not give the tests of any of the above species
 PART - C VI. Answer any THREE of the following questions. 3 X 5 = 15
IV. Answer any FOUR of the following questions. 4 X 3 = 12 42. a) Write S1N
mechanism for the conversion of butyl bromide to ter.butyl alcohol
29. Give three differences between roasting and calcinations. b) Aryl halides are less reactive than alkyl halide. Give two reasons.
30. For the manufacture of ammonia by Haber’s process. Write the equation and optimum 43. Mention the major product in the following reactions.
condition for maximum yield of ammonia. i) (BH3 )2
31. Complete the following equations. a) (i) 3CH3 − CH = CH2 (ii) THF ?
MnO2 (iii)H2 O, 3H2 O2 , OH −
i) 2KClO3 ?
catalyst
ii) SO2 (g) + Cl2 (g) ? (ii)
Zn-dust ?
iii) SO3 + Conc. H2 SO4 ?
32. a) Give two reasons for anamolous behaviour of fluorine.
b) why interhalogens are more reactive than halogens.
(iii)
33. a) Why do transition metals exhibit higher enthalpies of atomisation?
b) Name a transition element which doesnot exhibit variable oxidation state. +HI ?
34. Explain the manufacture of potassium dichromate from chromite ore. (FeCr2 O4 ).
35. Using VBT, account for the hybridisation geometry and magnetic property of [Ni(CN)4 ]2− .
b) What is Lucas reagent? How does it reacts with 30 alcohol?
(Give atomic no of Ni=28).
44. a) Explain clemmenson’s reduction with an example
36. a) What is ionisation isomerism? Give an example.
b) Whar are X and Y in the following reaction.
b) Write the IUPAC name of the complex.[Ag(NH3 )2 ][Ag(CN)2 ]. o
||
PART - D + − 1. Cl2 /Red. P
CH3 − C − NH2 H or OH ×
V. Answer any THREE of the following questions. 3 X 5 = 15 ∆ 2. H2 O
c) Why formic acid is stronger than acetic acid.
37. a) Calculate the packing efficiency in simple cubic crystal.
45. a) Give the equations to synthesize methanamine by Gabrielphalimide synthesis.
b) A cubic solid is made of two elements P and Q. Atoms of P are at the corners of the
b) Between bezenamine and ammonia which is less basic and why?
cube and Q at the edge centre and body centre. What is the formula of the compound?
46. a) What is peptide bond? How many peptide bonds are present in tripeptide.
38. a) 18 g of glucose, is dissolved in 1 kg of water in saucepan. At what temperature will
b) What is reducing sugar? Give an example.
water boil at 1.013 bar ? K b for water is 0.52 k.kg. mol−1 . 47. a) Name the monomers of the following polymers:
b) Describe the process of reverse osmosis. i) Nylon-6
39. a) Calculate the emf of the cell in which the following reaction taking place: ii) Buna- N
Ni(3) + 2Ag + +2 0
(0.002 M) → Ni(0.160M) + 2Ag (s) (E(Cell) = 1.05V). b) What is copolymerisation ? Give an example.
b) Write anodic and cathodic reactions of Ni − Cd cell
40. a) Derive the integrated rate equation for the rate constant of a 1st order reaction. ****************
b) The conversion of molecules X and Y follows second order kinetics. If concentration
of X is increased to three times how will it affect the rate of formation of Y?
41. a) Describe the preparation of gold by Bredig’s are method.
b) Explain homogenous catalysis with a suitable example.
c) Enthalpy of chemisorptions is high. Why?