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19.04.20 Sr.N-SUPERCHAINA Jee Adv 2016 P2 GTA-11 P-2 QP
19.04.20 Sr.N-SUPERCHAINA Jee Adv 2016 P2 GTA-11 P-2 QP
CHEMISTRY:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 19 – 24) Questions with Single Correct Choice 3 -1 6 18
Questions with Multiple Correct
Sec – II(Q.N : 25 – 32) 4 -2 8 32
Choice (Partial Marking +1)
Questions with ComprehensionType
Sec – III(Q.N : 33 – 36) 3 0 4 12
(2 Comprehension-2+2=4Q)
Total 18 62
MATHS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I(Q.N : 37 – 42) Questions with Single Correct Choice 3 -1 6 18
Questions with Multiple Correct
Sec – II(Q.N : 43 – 50) 4 -2 8 32
Choice (Partial Marking +1)
Questions with ComprehensionType
Sec – III(Q.N : 51 – 54) 3 0 4 12
(2 Comprehension-2+2=4Q)
Total 18 62
A)
r q
B)
q
C)
r 1 q D)
r 1 q
4 r22 4 r r22 4 r
2
2
4 r r22
2. A parallel plate capacitor (plate area: A) connected to battery of emf ‘V’ and
negligible internal resistance, so that one of the plate is made to oscillate and distance
between plate varies as d d 0 a cos t , a d 0 . If maximum current observed in
circuit is I 0 then maximum possible amplitude of vibration (a) is
a2 I0 I 0 d0 I 0 d 02 I 0d0
A) B) C) D)
VA 0 V A 0 VA 0 VA 0
3. A slit is cut along the left bottom edge of a rectangular tank. The slit is closed by a
wooden wedge mass ‘M’ and apex angle ‘ ’ as shown in diagram. The vertical plane
surface of the wedge is in the contact with the left vertical wall of the tank. Coefficient
of static friction between these surfaces in contact is ‘ ’. To what maximum height,
can water be filled in tank without any leakage through the silt? The width of tank is
‘b’ and density of water is ‘ ’
2M 4M
A) B)
b tan b tan
2M 2 M cos
C) D)
b sin cos b tan cos
4. A small disc is attached at one end of a light inextensible string that passes through a
hole in a frictionless horizontal tabletop. Initially the disc moves on a circle of radius
R with kinetic energy K 0 . The other end of the string is slowly pulled so that the disc
finally moves on a circle of radius R / . What is the work W done by the pulling
agency?
A) W 0 B) W 2 K 0 C) W 2 1 K 0 D) W 1 K 0
C) Magnitude of force exerted by light beam on mirror depends only on ‘P’ & ‘c’
Qq 1 r r
F
where : positive constant, r is position vector of charge ‘q’ relative
4 0 r 3
to ‘Q’
qenctosed
C) Gauss’s law E.ds 0
holds true
V V V V
A) sin 1 B) sin 1 C) cos 1 D) cos 1
2 R 2 R R R
11. If wedge is moving with acceleration a as shown in the figure then value of net force
on m is
mg 2m 2 g
A) ma B) 2 ma C) 2 D)
2m M 2m M
A) The plot below represents schematically the variation of beat frequency with time
B) The rate of change in beat frequency is maximum where the car passes through Q
C) vP vR 2vQ
D) The plot below represents schematically the variation of beat frequency with time
13. A ball of mass m falls vertically from a height h and collides with a block of equal
mass m moving horizontally with a velocity v on surface. The coefficient of kinetic
friction between the block and the surface is k 0.2, while the coefficient of
restitution (e) between the ball and the block is 0.5. There is no friction acting between
the ball and the block. Then
14. A uniform rod of length ‘ l ’ is pivoted at point ‘A’. it is struck by a horizontal force
which delivers an impulse ‘J’ at a distance ‘x’ from point ‘A’ as shown in figure,
2 3
A) B) C) D)
2 3 3 4
15. What should the minimum width of the belt be so that the disc always remains on the
belt?
A) 0.9 m B) 1.6 m C) 2.0 m D) 2.5 m
16. What is the minimum speed of the disc relative to the ground?
A) 0.0 m / s B) 1.8 m / s C) 2.4 m / s D) 3.0 m / s
Paragraph for Questions 17 and 18
A hollow cylinder made of a thermally insulating material is equipped with a horizontal
piston P of mass m and area A . The piston is also made of a thermally insulating
material. There is no friction between inner surface of the cylinder and the piston.
Above the piston, a liquid of density is filled up to brim of the cylinder. The piston is
supported at the position shown due to pressure of an ideal gas filled in the lower
portion of the cylinder. Number of moles of the gas is n , atmospheric pressure is p0
and initial temperature of the gas is T0 . The heater H is switched on till the liquid
completely spills out (assume Quasi static process)
17. Work done by the gas on the piston in the entire process is
A) gh 2 A mgh B) p0 hA gh 2 A mgh
C) p0 hA 0.5 gh 2 A mgh D) 0.5 p0 hA gh 2 A mgh
18. Final temperature of the gas is
p0 gh p0
A) 2T0 B) 2T0
p0 p0 gh
p0 A ghA mg p A mg
C) 2T0 D) 2T0 0
p0 A mg p0 A ghA mg
CHEMISTRY Max.Marks: 62
SECTION-I
(Single Correct Answer Type)
This section contains 6 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) out of which
ONLY ONE option can be correct.
Marking scheme: +3 for correct answer, 0 if not attempted and -1 in all other cases.
2
19. The overall formation constant of Co NH 3 6 in aqueous solution is 105 at 298 K and
3
the standard potential for reduction of Co3 (aq) and Co NH 3 6 (aq) as follows
Co 2 (aq); E 0 1.90V
Co3 (aq) e
3 2
Co NH 3 6 aq e
Co NH 3 (aq) ; E 0 0.1V
6
3
If the overall formation constant of the Co NH 3 6 ion is 10 x at 298 K. Then the
2.303RT
value of x would be (Given : 0.06 )
F
A) 35.0 B) 31.2 C) 39.6 D) 29.3
C) XeF4 H 2O XeO3 O2 HF
D) XeF2 2 NO Xe 2 NOF
SECTION-II
(Multiple Correct Answer Type)
This section contains 8 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE than ONE option can be correct.
Marking scheme: +4 for all correct options & +1 partial marks, 0 if not attempted and -2 in all wrong cases.
25. Select the incorrect option(s) amongst the following.
A) Gold sol is a positive charged sol.
B) Lyophobic sols can act as protective colloid for Lyophilic sols.
C) When FeCl3 is hydrolysed with hot water, then ferric hydroxide sol (positively
charged) will be obtained.
D) Colour of colloidal solution depends on size & shape of dispersed phase.
26. For a real gas obeying van der waals equation, which of the following is/are true?
A) Internal energy of gas is dependent on temperature only.
B) If Z > 1, then forces of repulsion are dominant.
D) The second virial coefficient (B) depends on the nature of gas and temperature.
Scheme-1
NO 2
1) Fe, HCl
[Q]
2) Ac 2O
major
3) Br 2, CS 2
[P]
4) (aq) NaOH
5) NaNO 2, HCl, 273 K
6) H 2O, Boil
7) Br 2 (excess), H 2O
Scheme-2
Br
1) Mg, THF
2) CO 2
[S]
+
3) H , H 2O major
4) SOCl 2, Pyridine
[R]
5) Br 2, FeBr 3
Scheme-3
1) NaOH
[Q] [T]
2) S
major
A) 5 B) 4 C) 6 D) 7
Scheme-2:
CN 1) DIBAL-H
[S]
2) NaBH 4
O
3) dil HCl
O
[R]
Scheme-3:
NaBH 4
[S] [Q]
Ethanol
OH OH
Q is S is
OH
A) B) CHO
OH
CHO
Q is S is
CO 2H CO 2H
C) D)
30. The reactions leading to the formation of benzene is/are
H3C CH3
-
(i) hot KMnO 4, OH
+
(ii) H 3O
(iii) HI / Red P
Cr 2O 3 or V 2O 5
n - hexane
A) 773 K, 10 - 20 atm B) H3C CH3
C) CH3 CH3
D) (iv) Zn,
32. Among the following pair of compounds, identify the pairs which can be differentiated
by Fehling as well as Tollen’s regent?
O OH O OH
O O
O
O
O
H
H3C H H3C CH3
H3C H
C) D) O
SECTION-III
(Paragraph Type)
This section contains 2 groups of question. Each group has 2 multiple choice questions based on a paragraph.
Each question has 4 choice (A), (B),(C) AND (D) for its answer, out of which ONLY ONE is correct.
Marking scheme: +3 for correct answer, 0 if not attempted and 0 in all other cases.
Paragraph For Questions 33 and 34
In the following reaction sequence, the compound [J] is an intermediate product.
(CH 3CO) 2O 1) NaOH, Cao,
I J K
CH 3COONa 2) Br 2 / CCl 4
Major
3) 2NaNH 2,
4) HgSO 4, H 2SO 4, H 2O
5) Br 2 , FeBr 3
J(C9 H8O 2 ) gives effervescence on treatment with NaHCO3 and a positive Baeyer's
test
SR.IIT_N-SC/ N-C Page. No. 15
OH O CH3 H
O H
A) B) C) D)
34. The compound K is
O CH3
O
O O
CH3
Br
Br
A) Br B) Br C) D)
35. Which of the following complexes are formed when Pt and Au dissolved in aquaregia
?
36. The magnetic nature of the complexes of gold and platinum formed in aquaregia
respectively, is
SECTION-I
(Single Correct Answer Type)
This section contains 6 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) out of which
ONLY ONE option can be correct.
Marking scheme: +3 for correct answer, 0 if not attempted and -1 in all other cases.
37. An ellipse intersects the hyperbola 2 x 2 2 y 2 1 orthogonally at point P. The
eccentricity of the ellipse is reciprocal to that of the hyperbola. If the axes of the
ellipse are along the co – ordinate axes and product of focal distance of P is x then
2x is
A) 1 B) 2 C) 3 D) 5
38. If x1 , x2 and x3 are the positive roots of the equation x3 6 x 2 3 px 2 p 0, p R, then the
1 1 1 1 1 1
value of sin 1 cos 1 tan 1 is equal to
x1 x2 x2 x3 x3 x1
3
A) B) C) D)
4 2 4
x3 x 6 x9 x 4 x 7 x10 x 2 x 5 x8 x11
39. If a 1 ...., b x .... and c .... then the value
3! 6! 9! 4! 7! 10! 2! 5! 8! 11!
of a b c 3abc is equal to (given ‘x’ is a three digit positive number)
3 3 3
A) 0 B) -1 C) 2 D) None
40. Let A iˆ 3 ˆj 4kˆ, B 6iˆ 4 ˆj 8kˆ, C 5iˆ 2 ˆj 5kˆ and a vector R satisfies
B
R B C B, R. A 0 , then the value of is
R C
A) 1 B) 2 C) 3 D) 4
a b 1 ca c b ab ca cb c2
41. If b c 1 2010 and a b a c bc a b a c a 2 P then sum of all digits in the
c a 1 b c b a ca b c b a b2
number P is
A) 7 B) 8 C) 9 D) None
42. If c a b d , then roots of the equation bx 2 1 b c d x bcd a 0
A) Are real and one lies between c and a
B) Are real and distinct in which one lies between a and b
C) Are real and distinct in which one lies between c and d
D) Are not real
SR.IIT_N-SC/ N-C Page. No. 17
44. Let A aij be a third order square matrix and B bij be a matrix of order 3 1, X is an
unknown matrix such that AX B . Then which of the following statements are true?
x2 2x d
45. If f : R a, 6 defined by f x is an onto function, then
x 2 3x d
2
A) a is equal to B) d is equal to 4
7
C) a is equal to 1 D) d – 7a is equal to – 3
10 x x 2
A) If f x log , then f x is odd function
10 x x 2
D) There are exactly two distinct linear functions, which map 1,1 onto 0,3
47. Which of the following are the solutions of equation 2sin11x cos 3x 3 sin 3 x 0?
n n 7
A) x ,nZ B) x ,nZ
7 84 4 48
n n
C) x ,nZ D) x ,nZ
7 63 4 24
x 1
48. If f t dt e x ae 2 x f t e t dt , then
0 0
1
A) a B) f x e x 2e2 x
3 2e
1
C) a D) f x e x e x
e
x 7 y 3
2 2
7
A) The eccentricity of the hyperbola is
5
A) Tr. A 3
B) Volume of parallelepiped formed by r2 , r3 and r2 r3 equals 30
SECTION-III
(Paragraph Type)
This section contains 2 groups of question. Each group has 2 multiple choice questions based on a paragraph.
Each question has 4 choice (A), (B),(C) AND (D) for its answer, out of which ONLY ONE is correct.
Marking scheme: +3 for correct answer, 0 if not attempted and 0 in all other cases.
Paragraph For Questions 51 and 52:
A function f x having the following properties
i) f x is continuous except at x 3
iii) f 0 0, lim
x 3 f x , x f x 3, x f x 0
lim lim
A) 2 B) 1 C) 3 D) 4
52. f x 3 x 0 has five solutions if
A) f 2 6 B) f 0 3 and f 2 6
C) f 0 3 D) f 0 3 and f 2 6