Alcohols phenols

and Ethers
② Ethanol can be prepared by treating HCHO and CH3MgBr.
Justify your answer.
&
· ShT3,
My n 1
By
1-
1) -> -

2 1 +

A
-
-

↓
1,120
CA-CH-0N

MgCON) B.
+
①a) Name the product obtained when phenol is treated with
chloroform in the presence of NaOH.
b) Name the above reaction.
o
Reines tiem any
or
ou

co
I
NaOU

I+ cel
->

↓acidity
CH0
1 01
-

salicylaldehyde 10
①Mixture of Conc. HCl and anhydrous ZnCl2 is oan important
o o
reagent which helps to distinguish between 1 , 2 and 3
alcohols.
a) Give the name of the above reagent.
b) Explain how the above reagent helps to distinguish
above three types of alcohols.

② Lucas Seagent 30723710

R - 21 H20
+

R - 0n Hc/
+

zo Turbidity Immediatly
20 - > Turbidity (5mins

i>
No turbidity
⑦
Identify A and B. explain the reaction.

oZ" cM)
#V # Ct
->
-
I f

07
⑦Convert Phenol to picric acid

oN
01
Couc HNOz NOL 1 402
1 -

-
-

- -
L
D

% Love H2SO
"Oz
2,4,6 To init
phenol
-
-

picoic acid
-
⑨
a Write the correct pair of reactants for the preparation of
t-butyl ether by Williamson synthesis

fo -
- R-0-R
1

R-oNa
CH3
+ +

CH3
Nax

Cty-bonla +
C15I ->
cyko -cs
dny ins
⑦ Write the name of products formed when salicylic acid is
treated with acetic anhydride in acid medium.

200N 2001
I

-0 (atyc0),0I
I -
OCOCH
0
1- 7
1
Aspisin
salicylic -
⑤

acid
+

(HcOcH]
② Predict the products A and B. Hydroboration
oxidatoy
-

(H)
B246
(Ct5 cyz
B
-
-

32H5C7 CM
= -

Toipropyl boxue

1,120/on
-

3(Hz
-
(45CH504
② Explain the commercial preparation of wood spirit.
Give the chemical equation.
Methanol
-
⑨

(6203
2n0
CHOH
-

->
C02H
+ 2
573k -
⑤>

200 atu
QWhat is cumene? Explain the preparation of phenol from
cumene.

CUs-CH-Ctz
Is o p copy)
I benzene
1
1/
o ~
-

Cumene
-
⑤
ooM 01
cHz d ct

10
CH
cm
-

CH
-
- -

1 1 11
-
02
-
1
-
L/
&

1/ Cumene hydro + (HzCOCH

peroxide