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$RUHB1CR
$RUHB1CR
Chemicak ond
3 Bond osdes
of bondg toomec
Num ber
bonded atoms
betweRn two
molecuda Bond N-a
in
i) HybidisatonMixng OF
atove
atoie
atom ait
osbita Sama
Comparble
eaag to foam
Aumbes SFKubnd
eauak
orbtals ort Sama EAay
ii) bond
Head n - ovslap o f
osbital Ton bon!
bon
aatnu
P bord oveslap oF
S r d2
a UaS
orbital
atu
bond
33 AcLodin to s E PR eT
e-p bp-p b-bp
apueion
*| CH bp- bp
NHz bp -p mpaion
p-p apulsion
Ho
bond angle
So -te
So
dffarenb
Sp2 hubsioisabon B3
Gisound stare C o n t g T a t i o n
Boson Is22p
oF
Gound State
2S
Ercated staba
Sp
kuypai d'coation 117
E
2s
1
37 AO
t o Pind
ave
Let ot a o m i e osbrtal
wave tuunctons
A B
moleclas ovbiéays
fos
* V = C o n 3 a u e t i v a
interactio
PA
bo nding
destructive
clestuctiva
A = in terachon
Yanbikonding=
P o l e m o m a n t
A =, x 2d,
i s a n a btveeA
tuwo
dpola
Mament
cherge
CoVala nE bond is
olaty of
dipole mome nt.
Meaused
O
2
M,+(-,
A, tu,
=
M
hale Sama
CO bonds
Magnitude but oPpoSite
section
) i sstauchre ofNo
:0= N -)
2
SO
-2
o S =E
O
4+NO
O:
0 - o -1H
iv 03
:O O.
2. Bgn toSmation
) Bacl
2
Be +2e
22 Ha
[HeJ
c CN
e) 3s3p5 CAx
B t 2C Bec
Be unde e Sp hbisisetion,
two
two
Kubnd ovlitol Ovlapp
Vtas
osbital
tomi tneas Compond. s B e - d
+2 + 2e
Mg Ne
w e 3s2
2c + 2 2C
CA
2
M + 2c
Mge
43
* bond is Stonge an
T bond
-
bond S
Becauße ,
b inea ovaxap
tovmad
of autoie os bib
Bond e nasa.1
MaMum
boeak Ong
r mole of
a bond Molacuyo
unt kTmol
45
eactos in
No oF
atom
Ha
deetbnie Cortiguato= s
No of eactrong 2
Molecala
Hydbna
4 H
LS
IS
IS
S
Electooaie Con tgumton = 2
oF Molecla
MOT of atom 2 2
lectaons n Ha
in
oF
No ekactonic Configuation IS2
in Ha Molecs4
No of Sectaons
Ha
is
LS
S
CovalanE bond
Lb Pola
Covalent bond
atoms,d e to
between tuoo
electaonagativity iffeena
Ps Chusges ase tomes
H F.Mor
TnnaRat e. elactonagatve
47
s 2P bond
i 2 Pe 2P bond
bond
2 P 2P
bond
S 2Pz
41 jetlere
rsbnd stat Conhgusation
2
oF Cos bon I s 2 s 2 p2
Dund State
1 2
2s2
Escited Stata
T 2 11
hbkeabion
nbndis
wnkqbrid Sed Poobtr
Tha
Cabon atom OVeslap
oF two
m TT bond
SidewaS
betuwean tam
H H
-C C C H
Bondi et lena
2 2
*
Cenfiqusaction oF
IS 2S 2p
Caxbon
* Gtound Stata
1 2p
2S
111 2P SP D
2s hbmdiscction unkyan
Casbon ctom
Orbit of bhot
oVelapTTbods Side
bertuwaan tam
two
H C Erc
50 ocahe dard Sp
Tetsaha.dra S pSp*
Planas d S p
e)Sq
5VsEPR acn
or molecules kpends
atom
electaon PS
Pus
*TyPe2
of
Bond,
Pair (bp)
)i)iLona Pair (2p)
3epusin, t a
avois
Te
ase
place
Parss
elact a r 3D Spao
tes a
p u l S ion
ot
lp-bp bp-bp
p- Sp
Hntagonal F bipye
F F
F
SFL
Octahadsak
F F
F
S2) Co
:o
Dpolemoman u ,+A2
, + (-M)
= O
H
H
=/.&5D
= , +M2
U
$3.Bod o
CI eectaons)
i ) N ( I E lacteons)
- 4 2.5
Bone ovrds 2
ekactaons
eloctaons
(15
ii ,
N-Na 105 25
Bond oscdas 2
= N
Highest bond ordas
cheachar 1
CDpound
Chasactes
Fatiak CoValent
*
in onC C6mpound
PoanSabm
exparned by
fn
ionic bond, Posi i v
Cation attacts t
chase ekeetams oP auon
Valanca shing or
1
* Ectent of latatio
OAiC bon isyan
aans Tule
b
ula
Rafes .no
chasse
* Polaisction Cahon %
Size ot auor
P o l a n S r i o n
Pola Sation S i z e of a t o n
nd
x
ns np
Polansetion Cethausation
. *-*
MOT N|
38
Refes eades Pa78