International Seminar and Workshop on Sustainable Management of Industrial Water and Wastewater: Investment and Operations

19/10/2019

joining forces in SUEZ

Reliable and Proven Solutions
for Wastewater Reuse and
Zero-Liquid Discharge SUEZ’s
industrial + GE
Water & Process
water Technologies
activities

Alessandro Monti, Ph.D. The combination of GE Water & Process Technologies’ and SUEZ’s industrial
Global Sales Leader – ZeeWeed
water activities enables SUEZ to strengthen its position as a worldwide
resource (water and waste) technology and solutions leader for
industry, dedicated to improve your economic and environmental performance
Dhaka - 19th October, 2019

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comprehensive equipment and systems portfolio

adding innovation and value to industrial
customers around the world Separations Biological Biosolids Disinfection

o Screening o Biofiltration (BAF) o Digestion o Oxidation Ozone

o Grease & Grit Removal o Memrbane Bioreactor (MBR) o Dewatering o Ultraviolet
o Clarification – Flotation / Settling o Membrane Aerated Bioreactor o Thermal Drying o Remediation
o Filtration (MABR) o Thermal Oxidation o Advanced Oxidation
o Oil / Water Separation o Moving Bed Biofilm Reactor (MBBR) o Biomethane production
o Oil Wellhead Water Treatment o Activated Sludge

Membranes Evaporators /
Deionization Crystallizers Oil & Gas treatment

a vast one of the largest state-of-the art expert R&D teams

geographical portfolios in the digital and smart and strong go-to-market
market to contribute to capabilities to drive capabilities to bring new
footprint to serve process optimization solutions to our
our customers around the circular economy –
the heart of the resource and resource customers faster o Mixed Bed o Brackish and Seawater RO o Forced Circulation Evaporators o Oil Desalter / Desander / Dehydrator
the world o SAC / WAC - SBA / WBA o Micro -, Ultra- and Nano-filtration o Mechanical Vapor o Deoiler Hydrocylones
revolution conservation o Pre-coat o Specialty membranes (hollow-fiber, Recompression o Gas Sweetening / Dehydration
o Softener spiral, etc.) o Vertical tube, falling film o LNG Pretreatment
o Electro separation: EDI o Electro separation: ED / EDR evaporators o Glycol Regeneration
o Dew Point Control

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Environmental Sustainability in Textile Industries (ESTex) www.estexbd.com
International Seminar and Workshop on Sustainable Management of Industrial Water and Wastewater: Investment and Operations
19/10/2019

SUEZ model and strike zones SUEZ Value Proposition

Textile, Pharmaceutical, F&B,

Take tough-to-treat wastewater Petro/chemical, Power 1. Treating tough-to-treat wastewater by leveraging strong process expertise

MBR 2. Ensuring reliability and process stability over the entire life-cycle
UF/NF
Leverage SUEZ advanced technologies RO/EDR/EDI
Evaporator/Crystallizers (ZLD) 3. Delivering high-quality effluent which meets the final user requirement

RO/EDR/EDI 4. Leveraging SUEZ comprehensive portfolio, one-stop shop

Aim for complete re-use, high quality Ozone/UV
Evaporators
Softened 5. Flexible delivering models to meet the customer specific needs
Demineralized

Design Build (Excl. civil), 1000+

6. Strong service component through digital tools and personnel to ensure
Design, Build, Operate
Tailored commercial models (DBO) 500+
maximum plant performance at the lowest ownership cost
BOO/ Mobile 200 +
O&M

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Wastewater Treatment & Reuse – ZLD

Process design

Pre-Treatment MBR RO/EDR

Proven Solution

Reject
Consumables
LIFECYLE

Boiler Feed
Service Water
Audit, Cooling Tower
Consulting & Flushing/ Gardening
Diagnostics ZLD

Maximize reuse of tough Wastewaters – Resource Recovery

Ready for resource revolution

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Environmental Sustainability in Textile Industries (ESTex) www.estexbd.com
International Seminar and Workshop on Sustainable Management of Industrial Water and Wastewater: Investment and Operations
19/10/2019

Typical ZLD Scheme

Evaporator/ Crystallizer
MBR/ UF
RO/EDR

MEMBRANE BIO REACTOR

Consumables

LIFECYLE
- BOD/COD Removal - TDS removal
- TSS Removal - RO rejects to BC Audit,
- Pre-conditioning to RO Consulting &
Diagnostics

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Membrane Bio-Reactor – The Application ZeeWeed® MBR

Filtrate
Influent 8,000 to (Effluent)
15,000 mg/l

Bioreactor Membrane
(liquid/solids separation)

• Combines physical membrane barrier

with biological treatment
• Replaces clarifiers and filters, and Hi-Rate Biological Treatment Absolute / Positive Filter
reduces bioreactor size
• large capacity throughput • high degree of biomass/solids control
• Produces high quality effluent at all
• consistently high effluent quality
times • compact footprint
• lower operator attention - less components
• advanced treatment

• simpler, more reliable process

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Environmental Sustainability in Textile Industries (ESTex) www.estexbd.com
International Seminar and Workshop on Sustainable Management of Industrial Water and Wastewater: Investment and Operations
19/10/2019

Why MBR versus Conventional Why Suez ZeeWeed MBR versus others suppliers

• It occupies half of the footprint, • We are the inventor, the pioneer of immersed ultra-
freeing up space for factory filtration for MBR application
expansion
• By far the largest reference install-base in the
• It delivers high-quality effluent world, more than 2000 MBR plants in any industry
through a very simple process 7 and any plant size
scheme ft
• Lowest ownership cost when energy, chemicals,
• It provides an extremely stable and replacement (>10 yrs life) is considered
biological performance despite ZeeWeed
• The most experienced team from conceptual &
fluctuations in the incoming feed 3 Membrane
ft process design, detailed engineering, execution
Membrane
• You forget the headaches of Fiber Membrane and lifecycle services…IT IS PROVEN, for your
Module 15 lb
operating secondary clarifiers (solids PIECE OF MIND bowling
escape, sludge blanket/rising, etc) Electron microscope view of ball!
• Flexible business models: direct, indirect, O&M,
membrane surface
BOO, etc…

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Textile Industry And Challenges

 Textile Dyeing Industry is among the top consumers of water, after Thermal
power plants
 75-85% of the water used by the Textile industry needs to be treated end-of-
pipe
Main Industrial Segments:
 Major challenges of Textile  Denim Washing
Effluent :  Denim Dyeing
Textile Industry  High COD  Knit Dyeing & Washing
 Low BOD/COD  Yarn Dyeing & Washing
 Suspended solids
Consumables  Diversity of Chemical Minimum Maximum
LIFECYLE

Species pH 6.8 11.5

 Residual Dye
Audit,
 High TDS TDS, ppm 460 6200
Consulting &
Diagnostics  Technology developments at Turbidity, NTU 10 400
Industry level to reduce use of
water during fabric processing COD, ppm 180 1400
 Need for technologies to meet the Color, PtCo 800 4200
Discharge Norms and reuse water

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Environmental Sustainability in Textile Industries (ESTex) www.estexbd.com
International Seminar and Workshop on Sustainable Management of Industrial Water and Wastewater: Investment and Operations
19/10/2019

Textile Industry And Challenges Solutions to Treat Effluents MBR

Objective: Aeration
High effluent temperature – Water temp can be > 90 Deg Feed
Outlet
Permeate
• Recover Heat and return to process Aerobic ZeeWeed
1) Reduction in COD & Color Chamber Membrane
• Waste Water Temperature has to be < 35 Deg COD <200 ppm
2) Reduction in TSS
Based on the complexity
3) Optimized Performance-Cost of
Hight Pollutants: COD > 1000 mg/l, High color, High TDS > 2000 mg/l of WW Chemical Treatment MBR
Treatment or Aeration
• Reduce waste water generation at source Conventional Biological Potential Solutions: Feed Outlet Permeate
Pretreatment Aerobic ZeeWeed
• Cannot be discharged without treatment for Color Chamber Membrane
Process is not good COD <200 ppm
• Reuse waste water through membrane solutions – overcome  Biological treatment followed by
water availability issues
enough to meet discharge
membrane separation : MBR Sludge Removal

• Recover salt through Thermal solutions standards

 Chemical Treatment : Coagulation-
Flocculation MBR

 Advanced Oxidation Aeration

Outlet
 MAC-MBR Feed
Aerobic ZeeWeed
Permeate
Post Treatment
Denim Denim Knit CETP  Combination of Technologies Chamber Membrane for color
Washing Dyeing Dyeing COD <200 ppm

Textile Effluent : Tough-to-Treat Water

No One Solution for ALL !!

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Epyllion – First Adopter of MBR for Textile Wastewater Treatment Running Cost of ETP – Knit & Yarn Dyeing

Cost Calculation
Sl No Total Total Total Treated
Name Of Chemical & Others Kg/Tk Total Cost 3
Consumption Treated Water Run Time water/ M
1 Sulfuric Acid 11.739 kg 30,00 taka 352.180,20
2 Water Decolornt 0 kg 84,00 taka -
3 Citric Acid (MBR Filter Maint.) 188 kg 95,00 taka 17.879,00
Chemical Sodium Hyphochloride
4 Consumption ( MBR Filter Maint. ) 461 kg 10,00 taka 4.610,00

5 Polymer 47,2 kg 250,00 taka 11.800,00

6 Molases 0,0 kg 29,00 taka -
7 Antifome 0 kg 200,00 taka -
8 Kluber Synth GEM 1-220 N 0 litter 1087,30 taka - 91.147,00 m3 614 Hr. 16,95 taka/m3
9 Kluber Sinth GH6-460 0 litter 1605,00 taka -
Maintenance
10 Cost
Kluber Synth GH 6-220 0,20 1605,00 taka 321,00
11 Shell Corena S3 R 68 - 600,00 taka -
12 Grease Petamo GHY 133N 0 kg 4142,00 taka -
13 REB 108.174 kw 10,00 taka 1.081.740,00
14 Electricity Fuel Cost 780 litter 65,00 taka 50.700,00
15 Cost Lube Oil Cost 79 litter 320,00 taka 25.152,00
16 Glysacor G93-94 (Colen Water) 0 litter 650,00 taka 156,00

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Environmental Sustainability in Textile Industries (ESTex) www.estexbd.com
International Seminar and Workshop on Sustainable Management of Industrial Water and Wastewater: Investment and Operations
19/10/2019

Ningbo Huamei Textile Wastewater Treatment Ningbo Huamei Textile Wastewater Treatment
Process Flow Sheet to meet the new regulation
100% Treatment

EQ Tank with Coagulation/Pri

Hydrolysis –
heat mary settling
Acidification
exchange tank

50% Reuse
Parameter Unit Design value MBR Outlet RO Outlet
PH 5 - 10 6-9 6-7
TSS mg/l < 250 < 5 mg/l BDL
Ammonia mg/l < 15 Aerobic
Total Nitrates mg/l < 12 MBR / UF RO
Total Phosphates mg/l <6 Process
Conductivity ms/cm <1500
BOD mg/l < 230 < 10 (actual)
COD mg/l < 1040 < 100 (<90 actual) RO WW Drain
Colour units < 160 < 30 Concentrate Tank
TDS mg/l < 900 - < 70
M. Alkalinity mg/l <80 -
Chlorides mg/l <190 - <5
Sulphates mg/l <250 - <5
Total Hardness mg/l < 85 - <2
Ozone

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Express denim & washing - Bangladesh Operating Cost – Denim Wash

Plant capacity – 7.2 MLD (300 m3/hr)
Category Item Consumption Unit Cost Per meter cube cost
BDT BDT/m3

Electricity - 214 KW 08.25 5.885

Maintenance Chemical Hypo Chloride 144 Kg/Week 07 0.02

(NaOCl)
Citric Acid 204 Kg/Week 80 0.323

Total Operating Cost 6.228

 Electricity Calculation: 382 (A) X 405 (V)X 1.73X 0.8= 214

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Environmental Sustainability in Textile Industries (ESTex) www.estexbd.com
International Seminar and Workshop on Sustainable Management of Industrial Water and Wastewater: Investment and Operations
19/10/2019

Textile References (Partial) – 24 MBRs only in Bangladesh Textile References (Partial)

Customer/ Country Startup Plant capacity
Location Startup Size (gpd)
Trident Group, India (thru OEM) (India) 2014 400 m3/hr
Drews Meerane, Germany June 2001 227,200
Epyllion Textiles, Bangladesh 2016 150 m3/hr
Express Dyeing & washing (Hameem Group), Bangladesh 2016 250 m3/hr Cousin Filterie, Wervicq, France Aug 2000 95,100
Metro Knitting & Dyeing, Bangladesh 2016 250 m3/hr Tavex, Alginet, Spain Sept 2004 217,900
Denimach Dyeing & Textiles, Bangladesh 2017 250 m3/hr Al Khazna Tannery, UAE (tertiary) Jan 2007 66,000
Coats, Sri Lanka (Thru OEM) 2015 100 m3/hr
Arch-Ibercolor, Spain July 2006 660,400
Blue Planet, Bangladesh 2018 150 m3/hr
Euro-D, Italy July 2007 158,500
Simba Denim Wash, Bangladesh 2018 60 m3/hr
Ring Shine Kint Dyeing, Bangladesh 2018 500 m3/hr WP Home Bahrain 607,600

Evince Dyeing, Bangladesh 2018 40 m3/hr

Argaon Denim, Bangladesh 2018 40 m3/hr Ningbo Huamei Textile Co, Ltd, China (MBR + RO) 2014 2.5 (MLD)
Pretty Knit Dyeing, Bangladesh 2018 400 m3/hr
Leading Yarn Dyeing company in China 2014 3.0 (MLD)
Nice Cottion Yarn Dyeing, Bangladesh 2018 250 m3/hr

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Nestle UK Ltd – Tutbury Coffee Processing Plant

Effluent Treatment Plant Upgrade with Waste Water Reuse
UK & Ireland Team

case background
o Existing ETP utilized conventional pre-treatment and DAF with high operating costs.
o Project required a turn key solution on a greenfield site within existing facility.
o Existing ETP undersized for current and future flows and loadings.

our solutions
Food & Beverage o 1200m3/day ETP with Reuse comprising of Centrifuges, Aerobic Treatment, LEAP MBR, Pro Series RO, UV,
Chemical Dosing Systems and CIP Systems.
o 15 months Service Contract with Insight Monitoring & Plant Optimisation & Operator Training.
o Capital sale value $3.3MM plus future Service & Chemicals revenue.
o Utilising Nestle’s on site Civils & MEICA partners.

Consumables value added

LIFECYLE

o Reduction in current operational costs related to incoming water purchase and wastewater discharge
+$2.3MM/year.
o Reusability of pre-treatment sludge to generate energy with associated operational cost reduction and reduced
Audit, sludge disposal costs.
Consulting &
o Waste water reuse to assist Nestle overall sustainability goals.

Diagnostics commercial tactics

o Developed a standardised P&ID for Nestle Water Reuse globally, which specifies our UF and RO membranes.
o Worked closely with Nestle to develop and optimize the business case, in particular to recognize the value of
reusability of pre-treatment sludge and wastewater reuse.
o Supported Nestle through half a year of challenge to meet available budget, re-design the system (remove
entirely the anaerobic component) and finally gain approval for project to proceed.

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Environmental Sustainability in Textile Industries (ESTex) www.estexbd.com
International Seminar and Workshop on Sustainable Management of Industrial Water and Wastewater: Investment and Operations
19/10/2019

SUEZ Solution - Refinery MBR

• SWTS has developed Refinery MBR

technology, which was specifically designed
to treat difficult wastewaters and to produce
treated effluent that meets the toughest
Refinery & Petro-Chemical standards and/or can reused at site.

• As the Russian standards for wastewater

discharge from petroleum refineries are the
Consumables
LIFECYLE

most stringent in the world SWTS has made

improvements to it’s MBR technology,
Audit,
Consulting &
specifically in response to these discharge
Diagnostics standards facing the Russian petroleum
industry

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What is Refinery MBR? Key features of Refinery MBR

Dosing to biological tank

• Incorporates innovative biofilm technology with membrane accommodating
carriers (MACarrier) and robust ZeeWeed membrane technology

• MACarrier has huge bacteria-friendly surface area where dense and strong biofilm
can be quickly formed

• MACarrier can adsorb and pre-concentrate the residual recalcitrant organic

Bioreactor compounds in the mixed liquor and remove toxicity

Membrane Tanks • Self-bioregeneration occurs on the MACarrier surface, reducing the cost for
regeneration

Ancillary Equipment Achieve stringent effluent requirements without

the need for post-treatment

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Environmental Sustainability in Textile Industries (ESTex) www.estexbd.com
International Seminar and Workshop on Sustainable Management of Industrial Water and Wastewater: Investment and Operations
19/10/2019

Refinery / Petrochemical Sites - WW Refinery / Petrochemical Sites - WW

Location Startup Size (m3/d) Application
Location Startup Size (m3/d) Application
OJSC Novokuibyshevsk Refinery, Russia 2014-2015 60000 ZW MBR (R)
ENI, Gela, Sicily, Italy 2007 7200 ZW MBR + RO (R)

Taneco Refinery, Russia Phase 1 2011 Phase1 16800 ZW MBR + EDR + RO (R) ENI R&M, Taranto, Italy 2006 13250 ZW tertiary + RO (R)
Phase 2 2013 Phase 2 33600 Sasol Secunda, South Africa 2006 12500 ZW tertiary + RO (R)
Phase 3 2014 Phase 3 50400
Syndial Manfredonia, Italy 2006 2900 ZW tertiary (P)
CJSC Antipinsky Refinery, Russia 9000 ZW MBR (R)
Formosa, Taiwan 2006 Ph.1 5000 ZW MBR + RO (P)
Bina Refinery, India 2011 9000 ZW MBR (R) Ph.2 20000
HPCL Mittal Refinery, India 2010 12000 ZW MBR + RO
Bashneft, Russia 2017 84000 ZW MAC-MBR+EDR+RO
HPCL Refinery, India 2010 7200 ZW MBR (R)
ExxonMobil Chemical, LA, USA 2005 152 Tubular MBR (P)
Petrobras REVAP, Brazil 2010 7200 ZW MBR (R)
Yanshan Petrochemical, China 2004 25800 ZW tertiary + RO (P)
ENI Priolo, Sicily 2009 7200 ZW MBR + RO (R)
Borsodchem, Hungary 2004 600 ZW MBR + RO (P)
Reliance Industry, Dahej – PTA Effluent 2013-14 28000 ZW MBR (R)
Marathon Oil, KY, USA 2003 190 ZW MBR (R)
Dangote Refinery - Nigeria Under Execution 12000 ZW MBR (R)
HMEL – Bhatinda, Petrochemical/Expansion Under Execution 5000 ZW MBR (R/P) MOL Rt., Zalai Finomítóban (ZAFI) 2003 480 ZW MBR (R)
Plant, Hungary
Changqing Refinery, China 2008 4800 ZW MBR + RO (R)
ExxonMobil Chemical, China 2001 48 ZW MBR (P)
Conoco Philips, Hull, UK 2007 14400 ZW tertiary + RO (R)
33 PEMEX, Minatitlan, Mexico 2001 26160 ZW tertiary + RO (R) 34

R = refinery; P = petrochemical R = refinery; P = petrochemical

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Salt Separation – Work in Progress

Evaporator/
MBR/ UF Nano RO Crystallizer
Filtration

THANK YOU
RO
• BOD/COD Removal NaCl recovery
• TSS Removal
Consumables

LIFECYLE
• Pre-conditioning to RO
alessandro.monti@suez.com
+39 340 8363225
Audit,
Consulting &
Na2SO4 recovery
mohammad.mohit@suez.com
Diagnostics

Plan for Zero Waste Discharge not just Zero Liquid Discharge

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Trident MBR Pitch

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Environmental Sustainability in Textile Industries (ESTex) www.estexbd.com