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Efraty 2011
Efraty 2011
To cite this article: Avi Efraty , Ran Natanel Barak & Zviel Gal (2011) Closed circuit desalination
— A new low energy high recovery technology without energy recovery, Desalination and
Water Treatment, 31:1-3, 95-101, DOI: 10.5004/dwt.2011.2402
Article views: 93
ab s t r ac t
Closed circuit desalination of Mediterranean water with 47.5±1.5% recovery was demonstrated in
the RO energy range 1.85–2.25 kWh/m3 for the respective flux range 6–18 lmh with head element
recovery of 7.0±0.5%.
Keywords: Closed circuit desalination; Seawater, Low energy; High recovery; No energy recover
1. Introduction
In contrast with widespread conventional RO, the
Since the inception of RO application for desalination terms closed circuit desalination (CCD) or closed loop
in the late fifties of the last century by Loeb and Sourira- desalination originated in the patent literature [2–4] for
jan [1], this technique remained essentially unchanged a rare class of batch RO processes of little if any com-
over the past 50 years, despite of great improvements of mercial prospects until recently. The typical apparatus
membranes and energy recovery means. Conventional for batch CCD displayed in Fig. 1 comprises a pressure
RO involves a hydrodynamic “plug flow” process with vessel with one or more membrane elements inside, a
pressurized feed (Qf) at inlet of modules containing semi- feed pressurizing pump (HP), a circulation pump (CP) for
permeable membranes splits at outlet into two streams, concentrate recycling from outlet to inlet of module(s) as
one of pressurized brine (Qb) and the other of none pres- well as for pressure loss compensation (Δp), and a 3-way
surized permeate (Qp). Recovery (Rec) in conventional RO valve to enable brine replacement with fresh feed when
[Eq. (1)] is a function of the number of membranes in line batch desalination completed at a desired recovery level.
through which feed passes with limitations imposed by Batch CCD operates on the basis of hydrostatic principles
the feed flow and recovery associated with the head ele- with same flow rates of pressurized feed and permeate.
ment. Flow balance of conventional RO [Eq. (2)] requires The cross flow over membranes is created in CCD by
continuous release of pressurized brine (Qb), and in order circulation means, instead of the excess feed flow require-
to make such a process energetically effective the power ment of conventional RO. Batch CCD takes place only
stored in Qb needs to be recovered. in the presence of concentrate recycling, without which
desalination stops due to immediate rise in concentration
( )
Rec (%) = Qp / Q f × 100 (1)
polarization. Batch CCD operates without need for energy
recovery since the compression and decompression of
Q f = Qp + Qb the batch reactor during the respective steps of actuation
(2)
and terminations involve the loss of negligible amounts
of hydrostatic energy.
* Corresponding author.
Presented at EuroMed 2010 — Desalination for Clean Water and Energy: Cooperation among Mediterranean Countries of Europe and
MENA Region, 3–7 October 2010, David Intercontinental Hotel, Tel Aviv, Israel. Organized by the European Desalination Society.
96 A. Efraty et al. / Desalination and Water Treatment 31 (2011) 95–101
Permeate
[A]
HP CP
Feed
BRP
Brine
Permeate
Permeate
[B] ME PV
HP CP
Feed
BRP
Brine
Brine
Permeate [C] CP
HP
HP
MF HPFS Lubrication Leakage
CP
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MF
Feed BRP
Feed
BRP
Brine Actuated valves (1/2”) for compression/decompression
Actuated valves (3.0”) for flow direction control
One-way check valve
Fig.2:2.[[A]
Fig. [A]CCD
CCD with
with SCstand-by
SC on on stand-by for engagement;
for engagement. [B] CCD with[B]SC
CCD
engaged. MF: 5μ Micronic Filters
with
[C] CCDSC withengaged; [C] CCD
SC disengaged with SC disengaged
decompressed and rechargeddecompressed
with fresh feed. HP: High Pressure Pump (Danfoss; max. 10 m3/h)
and recharged with fresh feed. CP: Circulation Pump (FEDCO; max. 50 m3/h)
BRP: Brine Replacement Pump (60 m3/h)
HPFS: High Pressure Feed Supply pump (max. 10 m3/h)
PV: 8” Pressure Vessels of 1,200 psi rating
ME: SWC6 Membrane Elements
and SC with fresh feed received in the former and brine
collected in the latter while desalination continued; and Fig. 3. Schematic
Fig. design
3: Schematic of the
Design SWRO-CCD
of the SWRO-CCD unit
Unitfor the for
used Medi-
the
[C] CCD experienced in the CC with disengaged decom- terranean desalination
Mediterranean trials Trials
Desalination reported herein.
reported herein
pressed SC recharged with fresh feed by the BRP, then
sealed, compressed and left on stand-by as in Fig. 2A for
next engagement displayed. of 4.1% and temperature range of 22–23°C) with 47.5±1.5%
The entire consecutive sequential SWRO-CCD process recovery (7.0±0.5% head element recovery) using the
performed with fixed flow rates of HP and CP under SWRO-CCD unit displayed in Fig. 3 (4 modules of 4 ele-
variable pressure conditions with engagement of SC ments each) gave the RO energy range 1.85–2.25 kWh/m3
initiated at a desired maximum applied pressure, and in the respective flux range 6–18 lmh (Fig. 4) with mean
with disengagement determined volumetrically when efficiency (Fig. 5) of 82.6% for HP and 29.3% for CP and
the recharge of the entire closed circuit volume of the without need for energy recovery. The RO energy range
apparatus with fresh feed completed. 1.65–1.87 kWh/m3 (Fig. 6) for the same feed under the
The new SWRO-CCD technology was ascertained by same desalination conditions is attainable by the SWRO-
trials on Mediterranean seawater feed (4.1%) using the CCD technology if efficiency of HP and CP increased
unit of the design displayed schematically in Fig. 3 with to 88% (instead of 82.6%) and 60% (instead of 28.3%),
four modules of four elements each (henceforth ME4 respectively. Ocean water (3.5%) SWRO-CCD with the
module configuration). The continuously monitored improved efficiency pumps is expected to proceed with
data included flow and electric conductivity (EC) of feed, RO energy in the range 1.5–1.7 kWh/m3 (Fig. 7). Other
permeate and recycled concentrate; pressure at inlet and noteworthy information concerning the SWRO-CCD
outlet of modules; pH of feed and permeate; and the trials includes the flow conditions (Fig. 8); the pressure
energy consumption of each of the pumps separately. conditions (Fig. 9); the consecutive sequential time inter-
The lubrication leakage of CP was determined from the vals (Fig. 10); the performance of membranes (Fig. 11);
flow rates difference of feed and permeate as well as by the electric conductivity of permeates and brine (Fig. 12);
direct measurements, and the results presented herein and percent recovery (Fig. 13).
are for zero leakage operation of CP. The performance
characteristics of the SWRO-CCD unit described herein
for the first time compare well with those of the similar 3. RO energy comparison between SWRO-CCD and
BWRO-CCD units [7]. conventional SWRO
Meaningful energy comparison between RO tech-
2. Summary of SWRO-CCD trials results and projections
niques should pertain to similar feed source salinity, flux
Desalination of Mediterranean feed (average salinity and recovery. Practical experience gained by operating
98 A. Efraty et al. / Desalination and Water Treatment 31 (2011) 95–101
1.2
kWh/m3
1.2
%
%
RO (HP+CP+HPFS)
RO (HP+CP+HPFS) CPCP
1.1 1.1
40 40 BRP
BRP
1.0 1.0 HPFS
HPFS
Service Pumps
Service (BRP)
Pumps (BRP)
0.9 0.9
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0.8 0.8 30 30
0.7 0.7
0.6 0.6
0.5 0.5 20 20
0.4 0.4
0.3 0.3
10 10
0.2 0.2
0.1 0.1
0.0 0.0 0 0
6 6
7 7
8 89 9
10 10
11 11
12 12
13 13
14 14
15 15
16 16
17 17
18 18 6 67 78 89 9 10 1011 1112 1213 13 14 14 15 15 16 16 1717 1818
FLUX
FLUX - lmh
- lmh FLUX
FLUX - lmh
- lmh
Fig. 4. Trials energies vs. flux. Fig. 5. Efficiency (Eff) of pumps vs. flux.
3 3
ME4: SWRO-CCD
ME4: SWRO-CCDkWh/m
kWh/mfor3 Med.(4.1% )- )-
for Med.(4.1% ME4: SWRO-CCD
ME4: kWh/m
SWRO-CCD kWh/mfor3 Ocean (3.5%
for Ocean )- )-
(3.5%
assuming
assuming CP Eff. 60%HP
CP Eff. 60% & Eff. Eff.
& HP 88%88% assuming CP Eff. 60% & HP&Eff.
assuming CP Eff. 60% HP 88%
Eff. 88%
2.3 2.3 2.3 2.3
2.2 2.2 2.2 2.2
2.1 2.1 2.1 2.1
2.0 2.0 2.0 2.0
1.9 1.9 1.9 1.9
1.8 1.8 1.8 1.8
1.7 1.7 1.7 1.7
1.6 1.6 1.6 1.6
1.5 1.5 1.5 1.5
1.4 1.4 1.4 1.4
1.3 1.3 1.3 1.3
kWh/m3
1.2 1.2
kWh/m3
1.2 1.2
kWh/m3
kWh/m3
RO RO
(HP+CP+HPFS)
(HP+CP+HPFS) RO (HP+CP+HPFS)
1.1 1.1 1.1 1.1 RO (HP+CP+HPFS)
1.0 1.0 Service Pumps (BRP) 1.0 1.0
Service Pumps (BRP) Service Pumps
Service (BRP)
Pumps (BRP)
0.9 0.9 0.9 0.9
0.8 0.8
0.8 0.8
0.7 0.7
0.7 0.7
0.6 0.6
0.6 0.6
0.5 0.5
0.5 0.5
0.4 0.4
0.4 0.4
0.3 0.3
0.3 0.3
0.2 0.2
0.2 0.2
0.1 0.1
0.1 0.1
0.0 0.0
0.0 0.0
6 7 8 9 10 11 12 13 14 15 16 17 18 6 7 8 9 10 11 12 13 14 15 16 17 18
6 7 8 9 10 11 12 13 14 15 16 17 18 6 7 8 9 10 11 12 13 14 15 16 17 18
FLUX - lmh FLUX - mh
FLUX - lmh FLUX - mh
Fig. 6. Med. (4.1%) energy if pumps Eff improved. Fig. 7. Ocean (3.5%) energy if pumps Eff improved.
A. Efraty et al. / Desalination and Water Treatment 31 (2011) 95–101 99
ME4: ME4:
SWRO-CCD
SWRO-CCD
FLOWFLOW
CONDITIONS
CONDITIONS ME4: ME4:
SWRO-CCD
SWRO-CCD
PRESSURE
PRESSURE
CONDITIONS
CONDITIONS
45 45 75 75
CP: RECYCLED
CP: RECYCLED
CONCENTRATE
CONCENTRATE Sequence
Sequence
Low Low
HP: FEED=PERMETAE
HP: FEED=PERMETAE Sequence
Sequence
meanmean
40 40 70 70
Sequence
Sequence
High High
35 35 65 65
30 30 60 60
25 25 55 55
m3/h
m3/h
bar
bar
20 20 50 50
15 15 45 45
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10 10 40 40
5 5 35 35
0 0 30 30
6 76 87 98 10
9 11
10 12
11 13
12 14
13 15
14 16
15 17
16 18
17 18 6 76 87 98 10
9 11
10 12
11 13
12 14
13 15
14 16
15 17
16 18
17 18
FLUXFLUX
- lmh - lmh FLUXFLUX
- lmh - lmh
Sequence Duration
Sequence Duration
Stand-By
Stand-By Time
Time for for Conduit
Conduit Engagement
Engagement
10 10
20 20
8 8
MR: Module
MR: Module Recovery
Recovery per Cycle
per Cycle
15 15
"MER:"MER: Maximum
Maximum Element
Element Recovery(head
Recovery(head element)"
element)"
6 6
%
%
minute
minute
10 10
4
4
5
5
2
2
0 0
0 0
6 7 8 9 10 11 12 13 14 15 16 17 18 6 7 8 9 10 11 12 13 14 15 16 17 18
6 7 8 9 10 11 12 13 14 15 16 17 18 6 7 8 9 10 11 12 13 14 15 16 17 18
FLUX - lmh FLUX - lmh
FLUX - lmh FLUX - lmh
Fig. 10. Trials sequential durations. Fig. 11. Trials performance of membranes.
100 A. Efraty et al. / Desalination and Water Treatment 31 (2011) 95–101
ME4: SWRO-CCD
ME4: SWRO-CCD ELECTRICELECTRIC CONDUCTIVITY
CONDUCTIVITY ME4:
ME4: SWRO- SWRO- DESALINATION
DESALINATION RECOVERYRECOVERY
110 110 65 65
100 100
60 60
90 90
55 55
EC unitsIndicated
% Recovery
% Recovery
70 70
45 45
60 60
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40 40
50 50
35 35
40 40
30 30 30 30
6 7 86 97 108 119 12
10 13
11 14
12 15
13 16
14 17
15 18
16 17 186 7 86 97 108 11
9 12
10 13
11 14
12 15
13 16
14 17
15 18
16 17 18
FLUX - lmh
FLUX - lmh FLUX - lmh
FLUX - lmh
Fig. 12. Trials electric conductivity data. Fig. 13. Trials recoveries.
large conventional SWRO plants in Israel and elsewhere DWEER plant in Ashkelon and 23.1% compared with
with average flux of 13–14 lmh and recovery of 46±2% the SWRO-PX plant in Hedera. RO energy savings by
revealed RO energies as follows (feed salinity in brack- the SWRO-CCD unit of improved pumps efficiency (1.80
ets): 2.73 kWh/m3 for SWRO-PX in Hedera,Israel (40,000 kWh/m3 at 13.4 lmh — Fig. 6) of 39.0%, 39.5% and 34.1%
ppm) [8]; 2.47 kWh/m3 for SWRO-PX in Perth,Australia are expected compared with reported data for respective
(34,000 ppm) [9]; 2.98 kWh/m3 for SWRO-DWEER in SWRO-Pelton, SWRO-DWEER and SWRO-PX desalina-
Ashkelon,Israel (40,500 ppm) [10]; 3.64 kWh/m3 for tion plants in Israel. Noteworthy is that the new SWRO-
SWRO-DWEER in Tuas, Singapore (max. 35,000 ppm) CCD technology allows high recovery operation at higher
[11]; 2.65 kWh/m3 projected for SWRO-DWEER in Soreq, flux with a small added energy increment and without
Israel (40,000 ppm) [7]; and 2.95 kWh/m3 for SWRO-Pelton exceeding the preferred test conditions specifications of
in Palmachim, Israel (max. 42,000 ppm) or 2.68 kWh/m3 membrane elements by their manufacturers.
for the expanded Palmachim plant when operated by
means of the Pelton-PX hybrid system [12]. The low-
4. Technology type
est RO energy of conventional SWRO according to the
aforementioned is that of the SWRO-PX technique with SWRO-CCD is a new technology of conduits and
consistent results reported for Hedera, Israel and Perth, valves which departs from the principles of conventional
Australia if account taken for feed salinity difference. RO and circumvents entirely the need for energy recovery
The RO energy projected for the currently constructed (ER). Brine release by the SWRO-CCD technology takes
Soreq, Israel SWRO-DWEER plant is well below the place through side conduits under hydrostatic pressure
value experienced already in the Ashkelon, Israel SWRO- conditions with a negligible waste of energy. ER means such
DWEER plant with the same feed salinity. Operated with as PX and/or DWEER apply only for conventional RO
the same Mediterranean feed under similar flux and but not for SWRO-CCD due to the absence of pressur-
recovery conditions of the large conventional SWRO ized brine flow. Evidently, the PX and DWEER devices
plants in Israel, the measured RO energy (2.10 kWh/m3 are essentially feed pressurizing pumps powered by the
at 13.4 lmh) of the small experimental SWRO-CCD unit pressurized brine flow of conventional RO; hence, such
(4 modules of 4 membrane elements each) implies en- devices can not function in the absence of pressurized
ergy saving of 28.8% compared with the SWRO-Pelton brine flow as in the case of SWRO-CCD. In contrast with
plant in Phalmachim, 29.5% compared with the SWRO- conventional RO, the recycled concentrate flow in the
A. Efraty et al. / Desalination and Water Treatment 31 (2011) 95–101 101
SWRO-CCD technology stores very little energy, since •• Reduced membrane fouling (both mechanical and
created by the CP at a small pressure difference (Δp < biofouling); hence, less CIP cleaning expenses.
1.0 bar). •• Superior permeate quality (at any given recovery level
due to prospects of high flux operation).
•• Reduced installation costs (~30%) due to higher flux
5. Scope and prospects
(less elements) smaller pressurizing pumps, absence
The new SWRO-CCD technology is not confined to of energy recovery means and simple designs without
the flow, flux, recovery and pressure conditions of the staging with common commercial components.
trials described in present document. Evidently, many of •• Membrane performance without exceeding test condi-
the SWRO-CCD trials performed thus far confirmed the tions specifications declared by the manufactures even
facile attainment of high desalination recovery (tried up to at high recovery and flux.
53%) of Mediterranean feed with head element recovery •• Modular and scalable designs of high cost effective-
maintained well under 10%, a feature impossible with ness for any production capacity, with simple and
conventional RO. Low recovery (e.g., 35%–38%) and flux efficient monitoring and control systems.
(e.g., 7–8 lmh) SWRO-CCD trials of Mediterranean feed,
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