Chemistry and Chemistry For Engineers Midterm Exam

Which of the following is not an exception to the octet rule?
-d. Molecules with eight electrons in its valence shell
Supersaturated solutions contain more than the maximum amount of solvent in a solution.
-false
The Brownian Model explains how the temperature affects the rate constants of a chemical reaction:
-false
Which of the following rules is not true with regards to assigning maximum number of electrons to
orbitals (given n)?
-no correct answer
Which theory states that the farther away the electron is from the nucleus, the higher the excited state
is?
-Bohrs Theory of the hydrogen atom
We cannot write Lewis symbols for what group of elements?
-all of the choices
Why can't we write Lewis structures for lanthanides, actinides, and transition metals?
-because of their incompletely filled inner shells
During a chemical equilibrium, concentrations of products and reactants no longer have apparent
change.
-true
What is the collective term for forces that attracts molecules together?
-dispersion(wrong)
Which of the following is NOT a type of concentration unit?
-boiling point elevation
The lack of molecules above the surface of liquids causes them to tighten and form an elastic-like film.
-true
This refers to the capacity of an atom to attract electrons to itself.
-electronegativity
this refers to a process where molecules of a solvent pass through a semipermeable membrane
-Osmosis
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During a chemical reaction, the concentration of the reacting species increase over time while it is being
consumed.
-false
what is the collective term for forces that attracts molecules together
-Intermolecular
This is a type of bond observed with two atoms sharing a pair of electrons.
-covalent bond
The direction of the reaction favored when stress is applied is towards the direction where the stress is
lessened
-true
Changes in concentration, temperature, pressure, and time are important factors to consider in chemical
equilibrium.
-false
which of the following intermolecular forces are observed in polar molecules
-Dipole Dipole forces
Direction : Identify if the following elements are metal, non-metal or metalloids:
Germanium
-metalloids
Chemical equilibrium is the state in which there is no apparent change in the products and reactants
over time, and the free energy of the reaction is at its lowest.
-true
What can affect the viscosity of a certain liquid?
-temperature
Solubilities of solids and gases affect differently with temperature.
-true
Colligative properties depend on the nature of the substances in a solution.
-false
Which of the following is true about d orbitals?
-all d orbitals have 2 different shapes
Bismuth
-metal
Water flow easier than honey because of its higher viscosity.
-false
Valence electrons are also known as the innermost electrons.
-false
Differential Rate Law expresses how the reaction rate depends on the concentration while the Integrated
Rate Law expresses how the concentrations depend on time.
-true
Henry Moseley proposed the law of octaves in which he explains that the atomic masses of the elements
when arranged in ascending order, elements falling in every eight position were deemed to have the
same properties.
-false
Le Chatelier's principle states that if stress (or a change in condition) is imposed on a system at
equilibrium, the equilibrium position shifts to a direction that tends to lessen the stress.
-true
The differential rate law expresses how the reaction depends on concentration while integrated rate law
expresses how concentration depends on temperature.
-false
Group IA elements have the lowest ionization energies
-true
Valence electrons are also known as the innermost electrons.
-false
Oxygen
-non metal
A homogeneous catalysis occurs using a catalyst that has a different phase as the reacting molecules
while a heterogeneous catalysis occurs when a catalyst has the same phase as the reactants.
-false
What is the energy required to completely break a mole of solid ionic compound into its individual
gaseous ions?
-lattice energy
Energy levels of orbitals determine the actual arrangement of electrons in atoms. Electrons will fill first
the most stable orbitals.
-true
Which of the following quantum numbers describes the orientation of the orbitals?
-magnetic quantum number
Due to little space in between molecules, solids and liquids lack shapes and volume
-false
The main difference between the condensed states and the gaseous state of matter is the distance
between molecules.
-true
For the given reaction mechanism, NO3 is one of the final products.
k1
NO2(g) + NO2(g) -> NO3(g) + NO(g)
k2
NO3(g) + CO (g) -> NO2(g) + CO2(g)
-false
In order for a given exothermic chemical reaction to proceed, heat must be supplied for the molecules to
collide.
-false
The energy of a single photon is described as E = hv
-true
Chemical equilibrium is the state at which the free energy of the reaction is at its highest possible value.
In order for a given exothermic chemical reaction to proceed, heat must be supplied for the molecules to
collide.
-false
The boiling-point temperature of a solution is higher than its pure solvent
-true
Effective nuclear charge is the nuclear charge felt by an electron when both the actual nuclear charge
and the repulsive effects of the other electrons are taken into account.
-true
The electron configuration influences the properties of the elements.
-true
Tellurium
-metalloids
Concentration of reactants is reduced over the course of reaction.
-true
Which of the following does not affect chemical equilibrium?
-concentration/time
The f-subshells of transition metals are incompletely filled
-false
What factor affect electronegativity?
-electron affinity and Ionization energy
The freezing-point temperature of a solution is lower as compared to its pure solvent.
-false
Increasing the temperature also speeds up the reaction, hence, increasing the rate constants
-true
Chemical equilibrium is the state in which there is no apparent change in the products and reactants
over time, and the free energy of the reaction is at its lowest.
-true
Which of the following is not a type of solution?
-Hypersaturated solution
The stronger the intermolecular forces, the higher the surface tension.
-true
In the following chemical reaction, what can be done to maintain the forward reaction?
-decrease concentration of PCI3
Which of the following affects the amount of lattice energy needed in breaking an anion bond?
- Product of charges of the two ions and Distance between two atoms
The magnetic quantum number describes the size of the orbital. It also indirectly describes the energy of
an orbital
-false
This type of bond happens when an electron from an atom transfers to another atom, forming ions and
creating electrostatic attraction:
-ionic bond
What is the energy required to completely break a mole of solid ionic compound into its individual
gaseous ions?
-lattice energy
What theory explains that when certain metals are exposed to light of at least a certain minimum
frequency, electrons are ejected from its surface.
-photoelectric effect
According to the quantum theory, energy is always expressed in integral multiples.
-true
During a chemical reaction, the concentration of the reacting species increase over time while it is being
consumed.
-false
What factor affects the polarizability of a certain nonpolar molecule? -all of the choices
Energy levels of orbitals determine the actual arrangement of electrons in atoms. Electrons will fill first
the most stable orbitals
-true
Hydrogenation of ethylene to ethane using Palladium as a catalyst is considereda heterogenous catalysis
Pd
C2H2(g) + H2(g) -> C2H4(g)
-True
Chemical equilibrium is the state at which the free energy of the reaction is at its highest possible value.
-False
Tellerium
-Metalloids
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Which of the following is not an exception to the octet rule?

-d. Molecules with eight electrons in its valence shell

-no correct answer

-Bohrs Theory of the hydrogen atom

We cannot write Lewis symbols for what group of elements?

-all of the choices

-because of their incompletely filled inner shells

Which of the following is NOT a type of concentration unit?

-boiling point elevation

This refers to the capacity of an atom to attract electrons to itself.

which of the following intermolecular forces are observed in polar molecules

-Dipole Dipole forces

Direction : Identify if the following elements are metal, non-metal or metalloids:

What can affect the viscosity of a certain liquid?

Solubilities of solids and gases affect differently with temperature.

Colligative properties depend on the nature of the substances in a solution.

Which of the following is true about d orbitals?

-all d orbitals have 2 different shapes

Direction : Identify if the following elements are metal, non-metal or metalloids:

Water flow easier than honey because of its higher viscosity.

Valence electrons are also known as the innermost electrons.

Group IA elements have the lowest ionization energies

Valence electrons are also known as the innermost electrons.

Direction : Identify if the following elements are metal, non-metal or metalloids:

-magnetic quantum number

NO2(g) + NO2(g) -> NO3(g) + NO(g)

NO3(g) + CO (g) -> NO2(g) + CO2(g)

The energy of a single photon is described as E = hv

The boiling-point temperature of a solution is higher than its pure solvent

The electron configuration influences the properties of the elements.

Direction : Identify if the following elements are metal, non-metal or metalloids:

Concentration of reactants is reduced over the course of reaction.

Which of the following does not affect chemical equilibrium?

The f-subshells of transition metals are incompletely filled

What factor affect electronegativity?

-electron affinity and Ionization energy

The freezing-point temperature of a solution is lower as compared to its pure solvent.

Which of the following is not a type of solution?

-decrease concentration of PCI3

According to the quantum theory, energy is always expressed in integral multiples.

Hydrogenation of ethylene to ethane using Palladium as a catalyst is considereda heterogenous catalysis

C2H2(g) + H2(g) -> C2H4(g)

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