which one of the following compounds gives a primary alcohol upon reaction with

methyl magnesium bromide?

Ethylene oxide
(B) Propylene oxide

(C)Ethyfomate
(D) Carbon dioxide

2. Which one of the following statements is correct for alkyl haljde7

A) Alkyl halide will always show S1 mechanism

not favour E1
(5) In a unimolecular reaction increasing the temperature does

mechanism

(C) E1 mechanism is favored over S1 mechanism for primary alkyl halides

(D) E1 mechanism is favored over S,1 mechanism for tertiary alkyl halides

halides less reactive towards nucleophilic substitution

reactions as compared
3: Aryl are

to alkyl halides. This is due to

(A) The formation of a less stable carbanion

(B) The inductive effect

(C) Longer carbon halogen bond

attached to the halogen
Dysphybridized carbon
in the following reaction sequence
4 Identity the reactant *

r
B
x 2 ,yNaNO z-H O H
HCI

(A) Benzoic acid

B) Salicylic acid

c Aniline

(D) Phenol

XL-25/10 (3) (Tumover)

V H t e h sna et #ie totowing structures represent the major products in the following

atoi

HOH Br
H,CH

rBrH

pH

)4,c 4,C
CHs

CH
netiyt tulane will be subjected to rmonobrornination, then how many isomers wll

fomm

A) 4

2/10 (Continued)
(4)
7 alculate the Ama, value for the following compound using Woodward and Fischer
rules

(A) 254 nm
(B) 279 nm

(C) 290 nm
(D) 315nm

which one of the following compounds with molecular fomula CH,NO, shows

H-NMR peaks at 5.30 (broad, 1H), 4.10( , 2H), 2.80 (d. 3H) and 1.20 (t, 3H)
ppm?

A) CH,CH,NHCOOCH
B) CH,OCH,CONHCH,
(C) CH,NHCOOCH,CH,
(D) CH,CH,OCH,CONH
The sodium extract of an organic compound develops a blood-red color on treatment
with FeCl, solution. The lon responsible for this color test is
(A) CN
(B) NCS

(C) CNO
D) s
10 Which one of the folliowing statements is correct regarding the following reaction?

- t-BuO 2
t-BuOH

(AMajor product is endocyclic alkene fomed according to Saytzeff

(B) Major product is exocyclic alkene formed according to Saytzeff

(C) Major product is endocyclic alkene formed according to Hoffmann,

()Major product is exocyclicalkene fomed according to Hoffmann

XL-25/10 (5) (Tum over

13 What is the correct statement for the given reactions?

0T
(A) CHcOO X
CH,cooM
CHcoo
CHcoOH
bcOCH, ocoCH
(A) B reacts faster than A

(B) Both give the same product

(C)A gives cis- and B gives trans-product

(D) A gives trans- and B gives cis-product

14. Which is the correct order of nucleophilicity in the following options?

) (CHy,c0> CH
() (CH,CH,),N> (CH,CH,),P
(C) CH,S > CH,SH

(D) CH,CH,CH,O (CH,,co

15 Which oneof the following statements is true about the reaction given below?

NaOCH
CHyOH
H,COA
(A) It proceeds via a concerted Sy2 pathway

(B) Itinvolves a carbanion intermediate

(C) Itinvoves
a carbocation intermediate
(D) It proceeds via a concerted S1 pathway

16. Which one of the following substituents on the benzene ring is not a meta directing

group in an electrophilic substtution reaction?

CF
(B) NO
(c) Br
(0) NH,
XL-25/10 (7) (Tum over
 1Suggestthe product ofthe following reaction

NaOCH ?
CH
OH

(A) CH,

H,CoOH
(B)
CH
OH

(C)

OCH

(D)

12. Which one of the following reactions is not an example of E 1CB reaction ?

(A) OH

(B) Ph Ph OHA

C) MsC
) NMe

D) -BuO
XL-25/10
(6)
(Continued)
 17 Which one of the folowing alkanes exhibile yptteal efvily

A) Neopentane
(B) sopentane
(C)3-Methylpentane
(D) 3-Methylhexane
tranoforinalknn
the followirng
18 Wnat witl be the most appropriate reagent for

(A) CHN
(8) PhP-CH
(C) CHyLi
(D)(CH),Culi
stable ?
19 Which one
of the following carbocations is the most

(A)

(B)

(C)

(0)

20. Name the process associated with acylation of benzene:

A) Frielel craft reaction

(B) Wurtz reaction

(C) Wurtz fting reaction

(D) Aldol reaction

XL-25/10 (8) (Continued)

21 Which one of the following statements is incorrect ?
(A) First step in photochemistry is the excitation of electron

When amolecule or atom in the ground state (S) absorbs light. one olectron is.
(B) excited to a higher orbital level

(C) Photochemical reactions are caused by absorption of ultraviolet light only

Itis possible for the excited state
(9 S, to undergo spin inversion
22 ArTange the following intermediates in the descending order of their stabilities

() (1) 0) (IV)
(A) 1>1>ll> V (8) II> > |ll>||
(C) Il>>V>|l (0) lI>1> ll > V

23 The lUPAC name of the

following compound is

(A) 5-bromo-4-chlorohept-1-en-6-yne
(B) 5-bromo-4-chlorohept-6-en-1-yne
(C) 3-bromo-4-chlorohept-6-en-1-yne
(D) 3-bromo-4-chlorohept-1-en-6-yne
24 Which type of macromolecule caries out catalysis in biological systems ?

(A) Proteins. ()Carbohydrates

(C)Lipids (Nucleicacids
25 Anucleotide is constituted from which of the following units?

(A) Nitrogen base and phosphate

(8) Nitrogen base, sugar and phosphate
C) Nitrogen base and sugar
(D) Sugar and phosphate
The change in free energy of a reaction at equilibrium is :

(A) Negative (B) Positive

(C) Zero (D) Difficult to predict

L-25/10 (9) (Turn over

 . f
doubling the initial concentration of a reactant doubles the haf-ie
the reaction, then the
order of the reaction is
pen1/2
(A) 3
(B) 2
(G1
(0)
28 Ify the
is wave function, then what is the
probability of finding an electron in a grven
region within the atom?

A)
(B)
(C)
D)
29 One coulomb the
is
charge of
(A) One mole of electron
(B) 1/96500 mole of electron
(C) 96500 mole of ectron
(D) None of these
30 The pressure correction in the van der Waals
A)
equation is due to the :

Attractive force of the

(B)
molecules toward the interior
Attractive force of the molecules toward the
(C) boundary wall
Repulsive force of the molecules toward the interior
(D) Repulsive force of the molecules toward the boundary wall
31 The relationship between
Cp and Cyfor n mole of ideal gas is
A) C,Cp *nR
(8) C, C,+ nR
(C)
C C, nRT (D) CC+ nRT
The
relationship between the contact angle and
(A) Proportional wettability of a is
(C) Independent (B) Inver_ely proportional
(D) None of these
33 What will be the amount of
work done if 10 moles of an ideal
atm pressure and 27C temperature monoatomic gas at 10
constant pressure of 1 atm ?
is allowed to expand
isothermally against a
(A) -5 36 kcal
(C) -4.32 kcal (B) 5.36 kcal
(0) 4.32 kcal
34. Which of the following is not
applicable to the adsorption
(A) Langmuir equation phenomena ?
(C) Henderson equation (B) BET equation
(D) Freundich equation
35 Which one of
the following terms is not associated with phase rule? 76tuT
(A) Triple point
(C) Critical point (B) Eutectic point
(D) Plait point
XL-25/10
10
(Continuedd)
 . Which of the following is an intensive property
(A) Specific heat (B) Molar volume
(C) Surface Tension (D) All of these

37 What is the degree of freedom of 0. 1N aqueous solution of NaCi ?

(A) (6) 2

(D) 1
(C)
38 What is the ionic strength of 0.2 M of Na HPO,?
(A) 0.4 M (B) 0.5 M

(C) 06M (D) 0.8M

reaction A+28 3P7

3S Which of the following is not the rate expression for a

dA dB
A) B) 2
dt

(D)
1dP
(C) 3 dt

40. At equilibrium, the process of adsorption involves

(A) AH0 (B) AH TAS
(D) AH TAS
(C) AH TAS
the colour of the solution ofAwill be
41.
fmolecule Aabsorbs light energy around 630 nm,
(B) Blue
yA)Red
() Yellow
Y C) Green
reduction potential. The
The half cell A+ e A has a large negative
42.
consequence will be

(A) Ais readily reduced (B) A is readily oxidized

(C) A is readily reduced (D) A is readily oxidized
acid and a strong base using
point of acid-base titration involving strong
a
43. At the end
an appropriate indicator, the pH
of the solution would be

(A) shightly alkaline (B) Slightly acidic

(C) Neutral (D) Strongly alkaline

for a bimolecular reaction, the activated complex has:

44 According to transition state theory
of freedom
(A) No vibrational degrees
of freedom but they never participate in product formation
(B) Vibrational degrees
(C) One high frequency vibration that leads to product fomation

(D) One low frequency vibration that leads to product formation

XL 25/10o (11) (Turn over )

 coefficient is
extinction
45 The unit of molar
(B) Lit mol"cm
(A) Ltmol cm (D) Limol cm
(C) Ltmol cm
statements is correct ?
of the following
(B)C"and ,N "are isotopes
46 Whch

,Hand ,He" are isotopes

(A) Na"are isobars
isotones (D) Fand ,,

(C)1K
and
Ca"are
47 Amolecule is Raman active, if

the molecule is polarisable

(A)
the molecule is paramagnetic
(8)
(C)the molecule contains non-bonding electrons
(D) the molecule contains centre of symmetry

48 Cathode rays are deflected towards

(A) Positive electrode
(B) Negative electrode

(C) Both (A) and (B) (D) None of these

49 Which is not a renewable energy?

(A) Solar Energy (B) Wind Energy
(C) Tidal Energy (D) LPG

50 Ater bubbling air through pure water (pH 7.0), its pH decreased. Which of the following
S responsible for the pH change ?

(A) (8) co,

(C) (D) O
51 Which of the following is the correct order with respect to their relative stabilities?
(A) O O2 > O5 > O
(C) O2 > O »Oz » 0~ (D) o> Oz > Oz » O2

52 According to Bohr's theory. the angular momentum of an electron in the 5" orbit is

(A) 25
(C) 10 () 25
53 In a crystal lattice, the Madelung constant depends on the :
(A) lonic radius of the cation
(B) lonic radius of the anion
(C Nature of the crystal system
(D) lonic radius of both cation and anions

XL-25/10 (12) (Continued)

 Which of the following is the correct order of ionic radi ?

(A) «Mg «AP S

Na' « (8) A S <Na'> Mg
(C) sA> Mg" >Na (D) Na'>Mg>A s
55 Which of the following pairs corresponds to soft base pair 7
(A) N,OT (8) RS. O
(C) Co. CH,cO0 (D) SCN S,05
56 The ionic compound which indicates pyrosilicate is

(A) (Sio (B) (Si,0)

(C) I(SiO, (D) (Si,0,
57 The reaction of XeF, with CsF produces a compound that undergoes decompo0stion
after 50°C The compound is

(A) Cs,XeF (B) Cs,XeF

(C) CsXeF, (D) Cs,Xe,F1s
8 What are the precursors used for the synthesis of borazine in Stock's process
(B) NHCI and NaBH,
(A) B,H and NH,
(0) NH, and BCl,
(C) NH,Cl and BCl
59 Which type of isomerism exists between [Co(NH,),BrSO, and [Co(NH,),(SO,JBr

compounds?
(A) Linkage isomeism

(B) Coordination isomerism

(C) onzation isomerism

(D) Coordination postion isomerism

60 The primary and secondary valences of cobalt atom

in
[Co(NH,),CI,JCI complex are
(8) 1 and 6
(A) 3 and 4
(C) 4 and 3 (D) 3 and6
of carbon dioxide is accelerated by which of the
61 The rate of reversible hydration
following biomolecules
(A) Carboxypeptidase (B) Carbonic anhydrase

(C) Haemoglobin (D) Catalase

62 Among the following complexes, the one which shows zero crystal fiekd stabilization
energy
(A) IMnH,0% (8) IFet,O%"
(C) CoH,O)" (0) ICo,O)"
XL -25/10 (13) (Turn over)
 electron rule Which of the following firs
63 The comples (n C",M(CO), follows 18
in t 7
row transition metal (M)
is present

8) Fo
Co

64 Ore mmole of [ C I , Whle reactig with two moles of NH,gives

A)o N,),C) (B) trans4PUNH,),CI,I

C)PN,,CH (0)PUNH,)C
65 The reacten of NaCi and K,C,0, n the presence of conc H,SO, producos a vapor
that tums aqueous solhution of NaaOH into yellow colour While treating this yellow
color soluton with aqueous lead acetate in the presence of excess CH,COOH
t gves yellow preciptate Which of the following cormpounds does correspond to
this va

(A) CrO,C (B) CrO,C,

C) Na,Cro, (D) CroCl,
66 The number of radial nodes present in 3s and 3d orbitals respectively are
(A) 2 and 0 (B) 0 and 2
3 and 2 (D) 2 and 1
(C)
67 The brown ring complex compound formuiated
is as [Fe(H,O),NO)Jso, The
Oxidation state of iron in this compound s
(A) 3 (B) 2
(C)1 (D) 0

68 Whwch of the folilowing hybrndization is present in CIF moecute ?

(A) dsp (B) spd
C) spd (D) sp
69 Which of the folowing sets of quantum numbers are correct for an electron present in
the 4f ortbital ?

(A)
n-4/=3. m= 4,$ = : *
(B) n 3. =2.m= -2.s=
C) n 4 (=3.m 1.s (D)n4 tr4, m= - 4 s
70 VWhch of the foliowing is the incorrect statement about Zerses sat 7

(A) Zese's salt is diamagnetic

B) Al the Pt-CI bond lengths in Zeise's salt are equal
C) Ovdation state of Pt in Zerse s salt rs 2
iength of ethylene movety Zerse sat is than the tree
D) CC
bond in s longer
etyiere molecuie

25/10 (14) (Continued)