Method: As 11-01-2019 Page 1 Date: 11-03-2019 13:09:34

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Analysis Begun

Logged In Analyst: PinAAcle 900F Technique: AA FIAS-MHS

Spectrometer: PinAAcle 900F, S/N PFBS17061601 Autosampler:

Sample Information File: C:\Users\Public\PerkinElmer Syngistix\AA\Data\Sample Information\

07-03-2019.sifx
Batch ID:
Results Data Set: 25-04-2018 Verificacion
Results Library: C:\Users\Public\PerkinElmer Syngistix\AA\Data\Results\Results.mdb

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Method Loaded
Method Name: As 11-01-2019 Method Last Saved: 09-03-2019 12:50:45
Method Description: As (ppb)

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Sequence No.: 1 Autosampler Location:
Sample ID: Blanco Date Collected: 11-03-2019 9:31:29
Analyst: Data Type: Original

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Replicate Data: Blanco Analyte: As 193,70
Repl SampleConc StndConc BlnkCorr Peak Peak Bkgnd Bkgnd Time Peak
# µg/L µg/L Signal Area Height Area Height Stored
1 [0,00] 0,0058 0,0032 0,0058 0,0300 0,0102 9:31:53 Yes
2 [0,00] 0,0038 -0,0064 0,0038 0,0203 0,0090 9:32:24 Yes
3 [0,00] 0,0031 -0,0105 0,0031 0,0255 0,0091 9:32:54 Yes
Mean: [0,00] 0,0042
SD: 0,0000 0,0014
%RSD: 0,00% 33,08
Auto-zero performed.

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Sequence No.: 2 Autosampler Location:
Sample ID: Blanco Date Collected: 11-03-2019 9:34:31
Analyst: Data Type: Original

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Replicate Data: Blanco Analyte: As 193,70
Repl SampleConc StndConc BlnkCorr Peak Peak Bkgnd Bkgnd Time Peak
# µg/L µg/L Signal Area Height Area Height Stored
1 [0,00] 0,0006 -0,0043 0,0048 0,0197 0,0111 9:34:51 Yes
2 [0,00] -0,0011 -0,0062 0,0031 0,0212 0,0104 9:35:21 Yes
3 [0,00] -0,0014 -0,0080 0,0028 0,0236 0,0094 9:35:49 Yes
Mean: [0,00] -0,0006
SD: 0,0000 0,0011
%RSD: 0,00% 165,89
Auto-zero performed.

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Sequence No.: 3 Autosampler Location:
Sample ID: Blanco Date Collected: 11-03-2019 9:43:21
Analyst: Data Type: Original

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Replicate Data: Blanco Analyte: As 193,70
Repl SampleConc StndConc BlnkCorr Peak Peak Bkgnd Bkgnd Time Peak
# µg/L µg/L Signal Area Height Area Height Stored
1 [0,00] -0,0006 0,0085 0,0045 0,0185 0,0092 9:43:51 Yes
2 [0,00] -0,0012 0,0055 0,0040 0,0209 0,0096 9:44:21 Yes
3 [0,00] -0,0010 0,0092 0,0042 0,0217 0,0096 9:44:50 Yes
Mean: [0,00] -0,0009
SD: 0,0000 0,0003
%RSD: 0,00% 29,52
Auto-zero performed.
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Method: As 11-01-2019 Page 2 Date: 11-03-2019 13:09:34

Sequence No.: 4 Autosampler Location:

Sample ID: Calib std 1 Date Collected: 11-03-2019 9:47:55
Analyst: Data Type: Original

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Replicate Data: Calib std 1 Analyte: As 193,70
Repl SampleConc StndConc BlnkCorr Peak Peak Bkgnd Bkgnd Time Peak
# µg/L µg/L Signal Area Height Area Height Stored
1 [2] 0,0881 0,3625 0,0936 0,0085 0,0039 9:48:24 Yes
2 [2] 0,0847 0,3352 0,0901 -0,0006 0,0035 9:48:54 Yes
3 [2] 0,0843 0,3295 0,0897 -0,0010 0,0030 9:49:23 Yes
Mean: [2] 0,0857
SD: 0,00 0,0021
%RSD: 0,00% 2,48
Standard number 1 applied. [2]
Correlation Coef.: 0,995724 Slope: 0,03571 Intercept: 0,01936

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Sequence No.: 5 Autosampler Location:
Sample ID: Calib std 2 Date Collected: 11-03-2019 9:52:51
Analyst: Data Type: Original

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Replicate Data: Calib std 2 Analyte: As 193,70
Repl SampleConc StndConc BlnkCorr Peak Peak Bkgnd Bkgnd Time Peak
# µg/L µg/L Signal Area Height Area Height Stored
1 [4] 0,1752 0,7089 0,1806 0,0011 0,0038 9:53:21 Yes
2 [4] 0,1695 0,6491 0,1749 0,0005 0,0031 9:53:50 Yes
3 [4] 0,1630 0,6273 0,1684 -0,0042 0,0028 9:54:22 Yes
Mean: [4] 0,1692
SD: 0,00 0,0061
%RSD: 0,00% 3,63
Standard number 2 applied. [4]
Correlation Coef.: 0,998562 Slope: 0,03537 Intercept: 0,01510

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Sequence No.6 Autosampler Location:
Sample ID: Calib std 3 Date Collected: 11-03-2019 9:57:47
Analyst: Data Type: Original

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Replicate Data: Calib std 3 Analyte: As 193,70
Repl SampleConc StndConc BlnkCorr Peak Peak Bkgnd Bkgnd Time Peak
# µg/L µg/L Signal Area Height Area Height Stored
1 [6] 0,2569 0,9994 0,2623 0,0013 0,0030 9:58:18 Yes
2 [6] 0,2392 0,9039 0,2446 0,0002 0,0035 9:58:48 Yes
3 [6] 0,2344 0,8924 0,2398 0,0018 0,0040 9:59:16 Yes
Mean: [6] 0,2435
SD: 0,00 0,0118
%RSD: 0,00% 4,86
Standard number 3 applied. [6]
Correlation Coef.: 0,998623 Slope: 0,03465 Intercept: 0,01889

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Sequence No.: 7 Autosampler Location:
Sample ID: Calib std 4 Date Collected: 11-03-2019 10:02:43
Analyst: Data Type: Original

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Replicate Data: Calib std 4 Analyte: As 193,70
Repl SampleConc StndConc BlnkCorr Peak Peak Bkgnd Bkgnd Time Peak
# µg/L µg/L Signal Area Height Area Height Stored
Method: As 11-01-2019 Page 3 Date: 11-03-2019 13:09:34
1 [8] 0,3299 1,3299 0,3353 -0,0042 0,0049 10:03:16 Yes
2 [8] 0,3195 1,1798 0,3249 0,0062 0,0041 10:03:45 Yes
3 [8] 0,3004 1,1362 0,3058 0,0080 0,0044 10:04:18 Yes
Mean: [8] 0,3166
SD: 0,00 0,0150
%RSD: 0,00% 4,74
Standard number 4 applied. [8]
Correlation Coef.: 0,999294 Slope: 0,03955 Intercept: 0,00481

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Sequence No.: 8 Autosampler Location:
Sample ID: Calib std 5 Date Collected: 11-03-2019 10:07:05
Analyst: Data Type: Original

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Replicate Data: Calib std 5 Analyte: As 193,70
Repl SampleConc StndConc BlnkCorr Peak Peak Bkgnd Bkgnd Time Peak
# µg/L µg/L Signal Area Height Area Height Stored
1 [10] 0,4266 1,6533 0,4320 0,0028 0,0040 10:07:38 Yes
2 [10] 0,3805 1,4430 0,3859 0,0011 0,0036 10:08:10 Yes
3 [10] 0,3621 1,3585 0,3675 0,0082 0,0062 10:08:43 Yes
Mean: [10] 0,3897
SD: 0,00 0,0332
%RSD: 0,00% 8,52
Standard number 5 applied. [10]
Correlation Coef.: 0,999329 Slope: 0,03879 Intercept: 0,00682

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Calibration data for As 193,70 Equation: Linear, Calculated Intercept
Entered Calculated
Mean Signal Conc. Conc. Standard
ID (Abs) µg/L µg/L Deviation %RSD
Blanco 0,0000 0 -0,176 0,00 5,05
Calib std 1 0,0857 2,0 2,033 0,00 2,48
Calib std 2 0,1692 4,0 4,187 0,01 3,63
Calib std 3 0,2435 6,0 6,101 0,01 4,86
Calib std 4 0,3166 8,0 7,985 0,01 4,74
Calib std 5 0,3897 10,0 9,870 0,03 8,52
Correlation Coef.: 0,999329 Slope: 0,03879 Intercept: 0,00682

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Sequence No.: 9 Autosampler Location:
Sample ID: 10 ppb check Date Collected: 11-03-2019 10:11:11
Analyst: Data Type: Original

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Replicate Data: 10 ppb check Analyte: As 193,70
Repl SampleConc StndConc BlnkCorr Peak Peak Bkgnd Bkgnd Time Peak
# µg/L µg/L Signal Area Height Area Height Stored
1 9,394 9,394 0,3713 1,4768 0,3767 0,0025 0,0035 10:11:41 Yes
2 9,198 9,198 0,3637 1,3484 0,3691 0,0102 0,0043 10:12:14 Yes
3 8,671 8,671 0,3432 1,2833 0,3486 0,0101 0,0049 10:12:47 Yes
Mean: 9,088 9,088 0,3594
SD: 0,3737 0,3737 0,0145
%RSD: 4,11% 4,11% 4,03

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Sequence No.: 10 Autosampler Location:
Sample ID: Blanco Reactivo Date Collected: 11-03-2019 10:15:36
Analyst: Data Type: Original

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Replicate Data: Blanco Reactivo Analyte: As 193,70
Repl SampleConc StndConc BlnkCorr Peak Peak Bkgnd Bkgnd Time Peak
# µg/L µg/L Signal Area Height Area Height Stored
1 -0,042 -0,042 0,0052 0,0458 0,0106 -0,0002 0,0038 10:15:53 Yes
2 -0,069 -0,069 0,0041 0,0337 0,0095 0,0008 0,0043 10:16:21 Yes
3 -0,120 -0,120 0,0022 0,0253 0,0076 -0,0008 0,0041 10:16:48 Yes
4 -0,137 -0,137 0,0015 0,0188 0,0069 0,0016 0,0061 10:17:16 Yes
5 -0,162 -0,162 0,0005 0,0129 0,0059 0,0084 0,0041 10:17:43 Yes
6 -0,162 -0,162 0,0005 0,0126 0,0059 0,0009 0,0034 10:18:11 Yes
7 -0,174 -0,174 0,0001 0,0127 0,0055 -0,0036 0,0035 10:18:38 Yes
Method: As 11-01-2019 Page 3 Date: 11-03-2019 13:09:34
8 -0,216 -0,216 -0,0016 0,0088 0,0038 0,0000 0,0037 10:19:06 Yes
9 -0,188 -0,188 -0,0005 0,0167 0,0049 -0,0123 0,0019 10:19:34 Yes
10 -0,219 -0,219 -0,0017 0,0090 0,0037 -0,0076 0,0030 10:20:01 Yes
Mean: -0,149 -0,149 0,0010
SD: 0,0584 0,0584 0,0023
%RSD: 39,18% 39,18% 217,09

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Sequence No.: 11 Autosampler Location:
Sample ID: Muestra 3 ppb Date Collected: 11-03-2019 10:25:07
Analyst: Data Type: Original
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Replicate Data: Muestra 3 ppb Analyte: As 193,70
Repl SampleConc StndConc BlnkCorr Peak Peak Bkgnd Bkgnd Time Peak
# µg/L µg/L Signal Area Height Area Height Stored
1 2,555 2,555 0,1060 0,4296 0,1114 0,0323 0,0099 10:25:40 Yes
2 2,386 2,386 0,0994 0,3860 0,1048 0,0218 0,0091 10:26:12 Yes
3 2,287 2,287 0,0955 0,3680 0,1009 0,0135 0,0068 12:26:42 Yes
Mean: 2,409 2,409 0,1003
SD: 0,1355 0,1355 0,0053
%RSD: 5,62% 5,62% 5,28
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Sequence No.: 12 Autosampler Location:
Sample ID: Muestra 5 ppb Date Collected: 10-03-2019 10:30:37
Analyst: Data Type: Original

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Replicate Data: 5 ppb check Analyte: As 193,70
Repl SampleConc StndConc BlnkCorr Peak Peak Bkgnd Bkgnd Time Peak
# µg/L µg/L Signal Area Height Area Height Stored
1 5,081 5,081 0,2039 0,8067 0,2093 -0,0000 0,0035 10:31:09 Yes
2 4,614 4,614 0,1858 0,7053 0,1912 0,0085 0,0039 10:31:43 Yes
3 4,343 4,343 0,1753 0,6620 0,1807 0,0033 0,0068 10:32:13 Yes
Mean: 4,679 4,679 0,1883
SD: 0,3732 0,3732 0,0145
%RSD: 7,98% 7,98% 7,69

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Sequence No.: 13 Autosampler Location:
Sample ID: 7 ppb check Date Collected: 11-03-2019 10:34:44
Analyst: Data Type: Original

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Replicate Data: 7 ppb check Analyte: As 193,70
Repl SampleConc StndConc BlnkCorr Peak Peak Bkgnd Bkgnd Time Peak
# µg/L µg/L Signal Area Height Area Height Stored
1 6,442 6,442 0,2379 0,8718 0,2233 0,0085 0,0039 10:35:18 Yes
2 5,975 5,975 0,2198 0,7643 0,2052 0,0022 0,0039 10:35:53 Yes
3 5,590 5,590 0,2049 0,7034 0,1903 -0,0023 0,0029 10:36:26 Yes
Mean: 6,002 6,002 0,2209
SD: 0,4267 0,4267 0,0165
%RSD: 7,11% 7,11% 7,47