Dote

AN HARMONIC CRYSTAL INTERACTIONJS.

he lattice uibiatíon
Theory o discussed
hus ay has been limitedin the Polen tial
eneyayto terms quadratic in mter-
he
atomic displatements This is he haxmonic
theory St Conseguence s aze

TLuo lattice waves do not mteroct a single a Ve

doesmat decay ox hange om wilh time
Thereis Mo hema OYpAnSÍon_
Adiaba batic and iso hemal elastc Constans
Are equal__
The elastic LOnsfants are independent opressu
Qnd TempeyaTu e
high
The heat Capacilybeiomes _Lonstant_at_high
TermpeYatuzes T

In real Cutas Mone_of the consequ ence s

is Sctistied accurately. The_deviations may be
attibrled to hemeglecf o anhamonic
Chighe than quad ratic) texms in The
interaomic displanemeni.hus Lwe dissuged
The Simpler aspects_o anhaamonic effecbs.

Beautihul_demonstrations o anhazmanic
eHeLt_Are fhe xpimentsem the inlexa tien
uo phonon o pmduLe a thixd phonon
 Dt
he mo evpanJ1Dn Pay

t a nequenc

THERMAL EXPANSION-
for undersfancding lhemal erpansion_we aave
Considered fo a closslcalescillatox the
he
etient_o40nhamonic temsIn Thepstential
energyon he Me an Sepanation_of_paiy ot
aTomi- t a empexalure T The poten tial
energyat
energ thealomiat a displate menf
fADM heiy euilibaium Jepovation_at absolute
Zem o
a)=cz-q'-fz
with all positive

Ohe team gi Lepaesentt fhe asym metry of fhe

fhe
nuituuaaepulsion_o the aoms andthe ferm_
epeacnk_the he softening ofthe yibxation
at large amplihude The minimu c =0is
mof an absoluTe mimimum_, but oz mall
Osillations the foxm í an adepuale
gepxesentatron o an m1eYatomiIc potential

The avP0ge_diAplatement bs using fhe

Boltzmann olisti bution unction which weihis
the pos Sible_Values o alLonding
 bate

theiy thermodyna mic pmbabiluty

=0 d exp-p UyJ
daexpl-p.a) ilh L
CO

kT
tor displace ments Such thaut the anharmo nic
exmsin fhe enerqy are Small in_
CoMpaison wth T

d e d e at Bzig +
5

=
3 2
,
FEdo e
hence the terma erpan sion is