BB SECOND pu PREPARATORY EXAMINA'TION — JANUARY 2023 Sub: CHEMISTRY (34) ‘Vine: 3 Hrs, 18 Miu, ‘Total Marks: 70 tusteuctions: (‘The question paper 9 ure compulsary Bart ~ A carries 20 1 Jes one mark Vart c ties (wwe muiths, Part 'stion entries Uhree marks, Vat ‘ » Live carries Five math, (i) Write the balanced eben WW wherever necessary, Use lag table and simple calculate if mecessiny (use of scientific calculation is nat allewedly Pal elect the correct aptton from the glven chalee Ie is=is 1. The contribution of the particles atthe edge centre in ECC is 1 1 1 byt 7 ‘i ws (oy © Orr 2. Whit ofthe fallowing statement is nat correct according to Henry's kaw, \ 1 1 bye — by ky ok hy eT ay Te — 0) Aa aby (b) ky ee () A, @ solubility 3. ‘The vant Hols fictor for glucase solution is (ayo (by (2 (os 4 When the concentration of eleetrolyte solution changes {rom 0.1 M t0 0,05 M, The conductance value decreases in (4) specitie conductance (b) equivalent conduetance (ec) molar conductance: (4) Both (a) and (c) 5. Fora eto order reaction with rate constant k the slope of the plot of renetant concentration against time is @) a Ab) k © en W)-k The coagulating power ofan electrolyte for arsenic sulphide decreases in the order (a) Na! > AP! > Ba” (by PC : {c) Cl >SO} > PO} (d) Al" > Ba” > Na’ 7. The metal extracted by leaching with eyanide is ay Cu (b) Aw (c) AL (d) Lu The steucture of Xe) (1) trigonal planar {b) Bent structure (c) pyramidal (d) linear 9. The element / metal having half filled d-orbital configuration in 43 oxidation state is (wer (b) Mn (cy Cu (d) Fe 10. The ligand! which show synergic effect / back bonding in is metal complexes is (a) Ny (b) CO. (e) Cl (d)Frr Which of the following is optically inactive / achiral 60 2-Rromo huane u (b) 1-Hroe butane (aly both (a) and fe) ©) CO, . anak = x 7 atm (ny the X in the Teachon is. (9 pert acta ; (h) saticylaldehyde (o) Dhyiltoxy benzoic acid (A) acetyl salicylic acid 13. The oxidized product obtained in the Cannizzaros reaction of Henzaldehyde with concentrated NaOll is (2) Benzyl alcohol (b) Hydroxy benzene (¢) sodium formate (d) sodium benzoate 14. The LUPAC name of trimethyl amine is (a) Nemethy! ethanamiine (b) N-Nedimethylmethanamine (ONN-Dimethy! ethanamine () N-methyl methanamine 1S, Ribotlayin is (2) Vitamin B12 (b) Vitamin-B, (©) Vitamin B; —— (d) Vitamin-D lanks by choosing appropriate word from those given in brackets. Aspirin, Remains same, Ethylene glycol, increases) 16. The annitiveze is used in car radiator is 17. The (half life) 1,2 OF first order reaction with increases in the initial concentration of reactants, 18. The boiling point from He to xenon 19, obtained when Ethyl aleohal reacts with lucas reagent. 20. The chemical used to relieve pain is : PART-B UL Answer any four of the following, Each question carries two marks. 4x2 21. How is ferromagnetism arises in substances? Give an example of substance showing ferromagnetism 22. (i) State Kohlrauseh 1; Or What is meant by limiting molar conductivity? (ii) What happens when a salt bridge is removed from Daniel cell? 23. 75% of the first order reaction is completed in 30 minutes. Calculate the rate constant of the reaction 24. Give reasons for the followin; {i) Actinoids show variable oxidation state Gi) Zeand have almost identical radii 25. What happens when phenol is treated with benzoic acid in presence of cone. 11:SO,. Write the equation. 26. Explain Gattermann — Koch reaction, 27. shat are antioxidants? Give an example. 28. Give an example for tranquilizers and biodegradable detergents.PART-C py. Anwser any Four of the following, Each question carries three marks. 9, Fyplain the process oF obtaining “blister copper” fi Sopper matte” with equations 20, Write the cations involved in the manufacture of sulphuric acid by contact process maintaining saction conditions, 4x3=12 uh (a) Give reasons for the following © (i) Dinitrogen is inert at room temperature, (ii) PCL, is known but not NCI, (h) What isthe basicity oF 11 PO, (orthophasphorous acid) 32, (a) How does chlorine reacts with excess of Ammonia? Give equations. (P) What is royal water oF aquaregia’? 33. (a) Transition elements forms complex compounds, Give two reasons (b) Name the 3d element which shows only +2 oxidation state 34, How is potassium permanganate prepared from pyrobusite ore write the equations? 38. On the basis of valence bond theory. Explain hybridization, geometry and magnetic property of the complex (CoF,]". 36. (a) In the given complex K, [Fe(Cn),] (i) Write / What is the secondary valency? (ii) What is the primary valency of metal? (b) Write the structure of trans isomer of [Ca(en), Cl J", PART-D V, Answer any Three of the following, Each question carries three marks, 37. (a) Calculate the packing efficiency in FCC. (b) Metallic iron erystallizes in a particular type of eubic unit cell. The uni cell edge length is 287 pm. The density of iron is 7.87 g cm’. How many iron atoms are there with in one unit cell? 3x5=15 @) [Given = Ny = 6.023 x 10", M = 55.845 g mol] Qy 38. (a) Addition of 0.643 g ofa compound ta 50 ml of a liquid (density = 0.879 g/mol) lowers the freezing point from 5,51°C to 5.03°C, Calculate the molar mass of the compound. (K, for benzene = 5.12 k kg mol!) (3) (6) Draw the graph to show non ideal solutions with negative deviations, @ 39. (a) Calculate the value of AG® at 298 k for the cell reaction. a 3Mg,,, + 2Al/,, —>3Mgj., +2Al, (Given = =-1.66V and F= 96487) (b) Name any two methods to prevent corrosion. Q 40. (a) Derive integrated rate equation for the rate constant of zero order reaction, @) (b) Write Arrhenius equation, Explain the terms, @ 41. (a) Write any two difference between physisorption and chemisorption. @Q (b)_ What is Brownian movement? What is the causes for the Brownian movement, Q) a (¢) Name the enzyme which converts ethanol into ethanoic acid.35°15 VL Answer any Three of the following, Enel question carries Five marks, 42. (a) Write the two steps reactions involved in mechanism of conversion of tertiary butyl bromide to tertiary butyl alcoho! (b) Complete the following reaction and name the reaction, Q) Na. Dry ether — ¢) ————— Q) (c) Give an example for allyt halides a) or Write any one condition for optical activity, (Molecule to be optically achieve) 43. (a) Write the mechanism of acid catalysed dehydration of ethanol to ethene. 6) Williamson's synthesis for the preparation af Anisole. Q) (a) Write the organic product formed in the following: reactions 6) (i) CH,COONa mo (ii) CH,CHO 24> oO (ii) ci -C-ct, (b) Among formic acid and benzoie acid which is more acidic. Give reason ey 45, (a) How would you prepare aniline by using Hoffman's bromamide reaction? Q) (b) Complete the following reactions. os NH, @ +HNO; + HCI» (ii) CH, -NH, + CH,COCI2+ (c) Name the organic product obtained when methyl amine is heated with chloroform and aleobo! KOH. a 46, (a) Write the Haworth structure of sucrose. 2 (b) What is meant by denaturation of proteins? Which level of structure remains intact during denaturation of globular proteins? @ (c) Give an example for basic ct - amino acid. a 47. (a) Name the monomers present in Buna-N, e) B) (b) (i) Give an example for non-biodegradable polymer. Name the functional group present in Nylon 6, 6 (iii) Write the partial structure of PVC KKK KE