Vosvabon Privciple fe « Pecordiug to ke Variation mothed also Called The Vaniahion Theovom , th oP ow an OPproxi mate. n i wove function op a Juan tum mackanical | stom , Ss om atm ey g tmolecwde , dercribed — by Yeo Haniltonian | Mon ft . then the orepyy alyenvalue | bt the Gysrern Oppo. ‘ Pprer’mately | JWvon by the integral, | BE. ZH 1H y> jv’ Hay dt | ———— - ae | <¥ [p> Star he etre Aplications of tia Voniotion methed invelves Aho follousing (Steps- 4 Clicoe @ trio) wove function ey dopondent on Nos vable. parameters. + Fvoluate the imbogered Syl tym Scanned with CamSeannerYo the variable posta motors. run yoowve fuunch'on ang the (owoar he true ones). Stoke creygy of Lydogon atom . ‘The Aderodlngen Usowo. Pyaation w a Heys Fay. wee Te 2 oy 1 Sind \ % Sie | & Minimise the above integcal with Hew co This principle wed | to find 9 treapoct « The function a wlth The ophimarn Value. Ot Tho Petamotors gy The bast Appoxim ation to Valuc ot Joplacten operator v2, polon Coordiucter , 26 a % OF ‘ Ly WWly> is fhe hotest Opprroxiim akon fo xno & 06 Scanned with CamSeanner 2], ‘the | Jeet Bye | > Oar Ow | : « > : a A Er A Bo ehy 2 <¥bNiv> Sati de ZVI > FS ayty dv | Spor cal | p polan Coordinates 6-9 - Volume — olernont- | es 2 gh a VANOdsdodd , wliote OSye MO, OL BET, eheoanr. | ty >t 2 fy de 4 Dor? Or De et Bainter). (-«)2 (92 on™ ge OO) = Et) Coen en etry Ss Lanse n hy Se (seer ea \ oer ant Tahar eM t gt f ong oe) = [tare] | ay 7 a aye a u aor -I q - Ee ab @ le a “ytd j vnodel 4g —_—— —___.. J Oa ads nm sinedo J. "de, — Scanned with Came‘The Intograss ‘eccuning ‘nthe hove eyuak'on Cay be evaluated ting 4h Atondosd integral , a rack Jrovnd (tate ory of | hydrogen odorn Covreapording fo ig crack Ground Soe Puncthon op 2 OTE tn au), Jagat _ on (é-1) tL - a 0 ae ae 22 2 ba? | aha «) . ty At? Bot (94> 2-4) / G00? —_——_ = —-— - 2 > Ys (x0 24 \f 423 Lyn? eae ° Fy Caw), | | Mle, othe | so eta Scanned with CamSeamerhi) (pron % Hore wo Ball tonsidor porton "en degoncrate enengyy ovals . dk eo to we the Wows functon DHelf Flordt Orden Correction to the Fiest Suton sader Cramaction to Teo Steond dedot Connection to thie Inbowa Dicew the Hor tee ‘Thavy with — Sulkable. anraus pl. [ Vasthoe. Propose! tthe ft - Field CSc) mottiod y ; Aeereding to dlectron wy aBumbed dytommate cal porentia) — quo ty the Explaun Peete. bahton method — few Non = fogewotate bation — on M1 be Convenient 30 label the Braker Eueny derdor Coimection fo {fhe Wave feanctton, Euargy 5 fant Hon. Foce salt consistant Field Consishaut which ach to move un @ Sphantcally Nucleus and fhe Scanned with CamSeannerelectrons ox copt the ona. undat—tonsidorta Hon ‘The , potential onomyy oF loch» Wathen ay, ° - -Zz Or Nye = ee Oar, \y Slaaly 1 QvOoy othet alechmn i in tho atom . 2. . Morea = J PS (i) | % oFY —— dt; | ay ‘The luto di i . | be odingen oystion for the“) electron | in on atom ; CEERI EW = 8. Gene, at OVO) 1 dycay, ), (3) one the YD = electron dastom S ren ly, VW etoeg ene ») Gonsi Stout orbitab. =H Og), byes). dnl), Scanned with CamSeannerTho Ceranperog orenayy apociated with this toe funclon ub, ee Sa Hig. zy? 5 = \ \ pe Whey 2 iy Orting further rathamaltca) detail? tho — firal crowult , @- \ Zeit FE <4 i) 8) | Ve Dee Corel ahion Fucssy Cee) = (exact) ~ an Though Corolation a appear $0 be Sirall they ane really Vary Aig Ficaub be = a = Scanned with CamSeannerDerivation of — lone function = for The fleltowing orbito) Hybri disatton “tipe- Sp (BoMs) SP (BF2) yp (chy) Hybrid fatiou : | a wow Procas ot mixing and ee casting OF atom't —rbtta) —ak Gown atom wrth shgtly ‘Aittoront: cronates to focrm opal number of naw Obital of od Enaray Oventot fon * e ay (pre Ye ot Hybrid Aaron k 8 hy beridhis abon (Bolte), maximum Symmetry ard | | ¥ 5p" hybrid; Sation ( BFy), * 3p hybatdi gation Coby), Scanned with CamSeanner')) Donivadion of — wave function fos 5p yy beri sation for Boa > Bo 2 ptomic Numbur - 4 Bleehrronic ConFigutadton = 13? 93? Graf tore ft) = OO O 93 3p 98 2p. —~— 8p Nybmdisation ait Yo OOOO x Spx % BeNo of Sp hybrid ovbitdh = 2 Iowa func hion (om 1% gp hybrid oubital - -p , Mlewe funch’on for oh 3p bybasd trbital ~ Vo fot the lcoftetiont fee 9 orbital tn pb, w M1 an the Coot. for '9' orbital un “Vy wb M5 Od Coot foe “p! omhital im Ag = by . Soy = Abs + bi dba. Vo = Arby + bo deo. S- Ae orbit uh Eqpaliy diate buted between two hybrid ovbi tal Q,2 Wo ths - Ag : 9,2 % 2 le Eo ‘Mo (urn ot Squoste oF — Coofl - oF ~—toane FuncHon domi c orbitals us al” f°. Gat oy ity. ee OP tbr = 4. | Scanned with CamSeanner91: a, - I 4 ' (eee =~ 4 by” =) 2 \op- Va Vy, and Vo Aste orto gona Voy by by =0 Subst ute fhe Valuo . \ (ae) GE) (ie) ba =e Sas ‘fo * Ma bs x0 by My NB /, Pasting The Vodun tk 9,0, + by by cpuation | O ad wm Get Ye Original Aolubron Vo Ye bbs t bey). | | | on Ks (4s - bray. Scanned with CamSeanner< Derivation oF 8p” hy bef sahion for BF B = Atomic No - 5 E lechronie Confiyartin - 19% 25? ap! Creed tate @ @ O O P Pexci tod (sro @ @ 4) O | Ph oy Pe | ~— OP bybatd ation . 3 8p? bybrif orbit © vy Pa VaVit Abs + bi bp, + t) OPa- Ya % do + ba py + Co Opa. Ve: Ab, + ba dry + 3b pw. &, Wass age 3 C\z0 Qt br + or = 4 CX)? + bX eo xt be = 1- (Mma)? Yu Vo 7 Ye oma Orthogonal 419, + bibs +e,05 -0 O,% t+ bibs -o. V(Sye0) Stmiloaly , Aide t bbs + City zo 143 + bbe = 6 creo), Scanned with CamSeannerSubst tuto fia \aluo , Ca )(a) V%) & =° be = > (MB) Fs) V2/ be Ye Stroilonly , bs he Now tn py, 2 he, Go* + b> + ey? = 1 le)" (Ma)?s oes Cos t Ap Simtlanly | Cg zr t ‘(a 5 Now tha putting Noluos of a, a, by bo bs Ca hs jet Original opuntion .» No 2 sae 2 : %. we br, a ) Ps Ves ' ie bey ee 3 ve 8S 9 brs Parivoh'on of wane function for xe hyberdisatten for CHy . OO Atomic oybitab involved =: 8, b, , bys Pe Wone functor for 4 ap? hybaid orbits are Viva Neg, vy. Yi = abs + be OP, 4 Oy bp, tdidpy. Yo Os by + bs Pz + CodPy + da bby Va: G9 + e, bs + bade + C34 Pa + de boy. Pye My bye by bre + Cyd Pee dy phy. Scanned with CamSeanner1) As ‘sorbitol is Eyrormete ca and cqually dish buted tn all foun hybrid oxbi tab O1- % = 4g= ay =e 4 VG +. 2 ?) Assim tng ‘thor Former along z ants Contreibuh'on femom Py aa Py =o a and $y ara a 8) Normalisation ot ay, give a? + b+ ¢2 4 d2_ © SOS ale Qe brco As, ays te. bye Way, 2 YM, ond es oy, ond apy , wv, ond Ay one Se ae 91% 4 brba tO tdidy co, As, eC1sq, =o 919, + bby -0. Scanned with CamSeanner 4hon[Subs Tuing the Valuo , Ch)(4) + (%) & = bo 2 7 al” Similonty , bo: by - x! 2vg 5) Assuming ‘hat Wo hi botwoen x5 plone Then Contribution foam Pa oo! Zoro , | 2 4 bj? + d.7 = 4 qo = V2/3 ° b) Yo and ae 1 “ya and Py ate orthogonal 9543 tha bs t+ Coca +dad, >0 Fadg a baby + Cyly tdady =o Co =O Rawat the ation , % 9 + babe tdodg =0 Gay + ba by + do dy 20. Scanned with CamSeannerSabstitab'eg Foo Qs a9 ay bo bs by, de ae a Sand Solving. dp - dh, TE ? for cP onbite) nowmalisatfen sequtned uf M7 + bg + C4? tds? = Subst tubtng fhe Value ot 4; , by 2 dz Cea 2 ¥ : ) fou Pu oxbitol Gyr byrt Cyt dy? =! a) Cyr Te E Pence the a hy bid orbited wowe fanchon Mey ye Lbs + WE, bP - 2k bp - 1 op, + Ma bPe i a ae? ° Ys = $s - de bPe te = Pye pre. vy e ato _t = i 2X3 Ph ve 8 - bee