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5070 w22 QP 12 PDF
5070 w22 QP 12 PDF
5070 w22 QP 12 PDF
CHEMISTRY 5070/12
Paper 1 Multiple Choice October/November 2022
1 hour
INSTRUCTIONS
• There are forty questions on this paper. Answer all questions.
• For each question there are four possible answers A, B, C and D. Choose the one you consider correct
and record your choice in soft pencil on the multiple choice answer sheet.
• Follow the instructions on the multiple choice answer sheet.
• Write in soft pencil.
• Write your name, centre number and candidate number on the multiple choice answer sheet in the
spaces provided unless this has been done for you.
• Do not use correction fluid.
• Do not write on any bar codes.
• You may use a calculator.
INFORMATION
• The total mark for this paper is 40.
• Each correct answer will score one mark.
• Any rough working should be done on this question paper.
• The Periodic Table is printed in the question paper.
IB22 11_5070_12/2RP
© UCLES 2022 [Turn over
2
1 Which piece of apparatus would be the most suitable for measuring exactly 37.00 cm3 of aqueous
ammonia?
A a 50 cm3 burette
B a 50 cm3 pipette
C a 50 cm3 gas syringe
D a 50 cm3 measuring cylinder
2 When iron reacts with dilute hydrochloric acid, hydrogen is formed. Impurities in the iron mean
that some hydrogen sulfide gas is also formed. Hydrogen sulfide gas is soluble in water. Water
vapour can be removed from a mixture of gases using concentrated sulfuric acid.
Which diagram shows apparatus suitable to prepare a pure, dry sample of hydrogen?
iron and
water concentrated
hydrochloric acid
sulfuric acid
The crystals are dissolved in water and the resulting solution is divided into two portions.
● Aqueous sodium hydroxide is added to the first portion. A green precipitate, soluble
in excess aqueous sodium hydroxide, is formed.
The solution formed is heated and a gas is produced which turns litmus paper blue.
● Dilute nitric acid is added to the second portion followed by aqueous barium nitrate.
A white precipitate is formed.
P Q
gas liquid solid
R S
P Q R S
For which of the elements nitrogen, phosphorus, sulfur and silicon could this information about
their oxides be correct?
A liquid
B solid
C solid insoluble
D solid
10 Which two pairs of atoms are held together by the same number of bonds?
11 Boron trifluoride, BF3, is a simple molecule. There are three covalent bonds in each BF3
molecule. Each of these bonds is made by sharing one electron from the boron atom and one
electron from a fluorine atom.
12 Which equation is correct for the reaction between carbon dioxide and magnesium hydroxide?
13 Which mass of oxygen gas combines with exactly 16 g of sulfur to form sulfur dioxide, SO2?
A 4g B 8g C 16 g D 32 g
14 Which compound has an empirical formula that is different from its molecular formula?
A butanol, C4H10O
B hydrogen peroxide, H2O2
C nitrogen dioxide, NO2
D water, H2O
15 4.0 g of sodium hydroxide, NaOH, is dissolved in 250 cm3 of water in a graduated flask.
A 25 cm3 sample of this solution is titrated with 0.50 mol / dm3 hydrochloric acid.
16 Dilute aqueous solutions of potassium chloride and magnesium chloride are mixed together.
anode cathode
A chlorine oxygen
B chlorine potassium
C oxygen hydrogen
D oxygen magnesium
17 The table gives some statements about electrolysis and the reason why each statement is true.
Which row shows a correct statement and the correct reason why the statement is true?
statement reason
A Aqueous copper(II) sulfate and Both solutions contain Cu2+(aq)
aqueous copper(II) nitrate are and can transfer copper from
suitable electrolytes when used the anode to the cathode.
to copper plate objects.
B During the extraction of The anodes gradually
aluminium from aluminium oxide dissolve in the molten cryolite.
the carbon anodes have to be
replaced regularly.
C In the electrolysis of concentrated H+(aq) is present in
aqueous sodium chloride and of both aqueous solutions.
dilute sulfuric acid the same
products are formed.
D When an aqueous mixture of Zinc is more
zinc nitrate and copper(II) sulfate reactive than copper.
is electrolysed, zinc is formed
on the cathode.
A B
V V
Cu Zn Cu Zn
CuSO4(aq) ZnSO4(aq)
C D
V V
Na Cu Mg Cu
CuSO4(aq) MgSO4(aq)
N2 + O2 → 2NO
A B
N2 + O2 N2 + O2
energy energy
2NO 2NO
C D
2NO 2NO
energy energy
N2 + O2 N2 + O2
Which changes in the conditions will result in the lowest rate of production of hydrogen?
acid solid
temperature
concentration particle size
22 Carbonates react with dilute acids to produce carbon dioxide. A student uses excess carbonate
and 100 cm3 of 0.1 mol / dm3 acid and measures the volume of gas produced at regular time
intervals.
The results give line X on the graph. The student repeats the experiment using 50 cm3 of
0.2 mol / dm3 acid whilst keeping everything else the same.
volume of
B X
gas / cm3
C
D
0
0 time / s
23 In the Contact process, sulfur is converted into sulfuric acid. A catalyst is added to the reaction
mixture shown in the equation.
2SO2 + O2 2SO3
25 Under certain conditions, iron reacts with chlorine to form iron(III) chloride.
A adding more O2
B increasing the pressure
C increasing the temperature
D removing SO3 from the reacting mixture
27 The table shows the pH values of some substances that can be consumed by humans.
substance pH value
P 6.6
Q 3.1
R 10.4
S 7.8
A P is alkaline.
B Q has the lowest concentration of hydrogen ions.
C R can neutralise excess stomach acid.
D S has a pH value closest to neutral.
X Y
29 Which substance reacts with dilute sulfuric acid in the preparation of a pure sample of
lead(II) sulfate?
temperature pressure
catalyst
/ °C / atm
A
B
C D
35 A river runs through an area of land that is used for growing cotton. The cotton farmers applied a
large amount of fertiliser to their fields. This caused eutrophication in the river water.
A CH2CHCH2CH3
B CH3CH(CH3)CH3
C CH3CHCHCH3
D (CH3)2CCH2
37 The equation shows the reaction that takes place when butanol is completely combusted in air.
x y z
A 4 6 5
B 5 4 6
C 5 6 4
D 6 4 5
38 Propanoic acid reacts with calcium carbonate. The products of this reaction are
calcium propanoate, carbon dioxide and water.
39 Which row shows all the elements present in the polymers listed?
• nylon
• poly(ethene)
• Terylene
A C, H C, H, O C, H, N, O
B C, H, N, O C, H C, H, N, O
C C, H, O C, H, N C, H, O
D C, H, N, O C, H C, H, O
H H
C N C N
O O
1 2 3
H O H H O O
N C N N C C
H OH H H HO OH
Permission to reproduce items where third-party owned material protected by copyright is included has been sought and cleared where possible. Every
reasonable effort has been made by the publisher (UCLES) to trace copyright holders, but if any items requiring clearance have unwittingly been included, the
publisher will be pleased to make amends at the earliest possible opportunity.
To avoid the issue of disclosure of answer-related information to candidates, all copyright acknowledgements are reproduced online in the Cambridge
Assessment International Education Copyright Acknowledgements Booklet. This is produced for each series of examinations and is freely available to download
at www.cambridgeinternational.org after the live examination series.
Cambridge Assessment International Education is part of Cambridge Assessment. Cambridge Assessment is the brand name of the University of Cambridge
Local Examinations Syndicate (UCLES), which is a department of the University of Cambridge.
© UCLES 2022
I II III IV V VI VII VIII
1 2
H He
hydrogen helium
Key 1 4
3 4 atomic number 5 6 7 8 9 10
Li Be atomic symbol B C N O F Ne
lithium beryllium name boron carbon nitrogen oxygen fluorine neon
7 9 relative atomic mass 11 12 14 16 19 20
11 12 13 14 15 16 17 18
Na Mg Al Si P S Cl Ar
sodium magnesium aluminium silicon phosphorus sulfur chlorine argon
23 24 27 28 31 32 35.5 40
19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36
K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
potassium calcium scandium titanium vanadium chromium manganese iron cobalt nickel copper zinc gallium germanium arsenic selenium bromine krypton
39 40 45 48 51 52 55 56 59 59 64 65 70 73 75 79 80 84
37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54
Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
rubidium strontium yttrium zirconium niobium molybdenum technetium ruthenium rhodium palladium silver cadmium indium tin antimony tellurium iodine xenon
16
85 88 89 91 93 96 – 101 103 106 108 112 115 119 122 128 127 131
55 56 57–71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86
5070/12/O/N/22
lanthanoids
Cs Ba Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn
caesium barium hafnium tantalum tungsten rhenium osmium iridium platinum gold mercury thallium lead bismuth polonium astatine radon
133 137 178 181 184 186 190 192 195 197 201 204 207 209 – – –
87 88 89–103 104 105 106 107 108 109 110 111 112 114 116
actinoids
Fr Ra Rf Db Sg Bh Hs Mt Ds Rg Cn Fl Lv
francium radium rutherfordium dubnium seaborgium bohrium hassium meitnerium darmstadtium roentgenium copernicium flerovium livermorium
– – – – – – – – – – – – –
57 58 59 60 61 62 63 64 65 66 67 68 69 70 71
lanthanoids La Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
lanthanum cerium praseodymium neodymium promethium samarium europium gadolinium terbium dysprosium holmium erbium thulium ytterbium lutetium
139 140 141 144 – 150 152 157 159 163 165 167 169 173 175
89 90 91 92 93 94 95 96 97 98 99 100 101 102 103
actinoids Ac Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr
actinium thorium protactinium uranium neptunium plutonium americium curium berkelium californium einsteinium fermium mendelevium nobelium lawrencium
– 232 231 238 – – – – – – – – – – –
The volume of one mole of any gas is 24 dm3 at room temperature and pressure (r.t.p.).