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EE 582 Solar PV Systems 4th Lecture
EE 582 Solar PV Systems 4th Lecture
4th Lecture
January 31st, 2023
PV Basics - Semiconductors
Today’s topics
Molecular
Bulk
heterojunction
Polymer
Solar Cells Organic
Molecular
Nanoparticle
Planar
concepts
Polymer
Silicon-based
Concentrating PV
III-V based Multijunction
Solar PV Technologies
https://app.sli.do/event/29RSJRVjq5qNLNz4ZRvB3Z
PV Basics - Semiconductors
Materials can be split into 3 categories:
a) Metals: electrons can move freely all the time
b) Semiconductors: electron needs to gain energy larger than Eg to become conductive
(i.e. bridges a band gap).
c) Insulators: band gap is so large, nearly impossible for electron to become conductive.
Semiconductors- Silicon Solar Cell
2018 global PV module shipment by product type
Silicon is commonly used as a semiconductor
material in solar cells.
8
PV Basics – Silicon Solar Cell
• Light incident on a solar cell must either be reflected, absorbed or transmitted
• To exploit the electrons and holes to produce an electric force and a current, another mechanism is needed-
a built-in "potential“ barrier.
• Doping modifies semiconductor properties
• N-type doping increases amount of free electrons
• Achieved in silicon through addition of phosphor.
• P-type doping increases amount of free “holes” (mobile positive charges)
• Achieved in silicon through addition of boron.
• Joining a p-type and n-type material produces a p-n junction (a diode), pushing electrons to flow from the N-
layer to the P-layer side while holes move in the opposite direction.
• The additional free electrons in the n-side and holes in the p-side by light incident together with charge
separation (p-n junction) causes the presence of uncombined excess negative charges on the n-layer side
and excess holes on the p-layer side, and thus results in a charge imbalance in the cell.
• When the n-layer side and the p-layer side of the cell is connected to an external electric circuit, electrons
(negative charges) will flow out from the n-type side, through a load and then flow into the p-type side,
where they recombine with holes.
PV Effect- Silicon Solar Cell
Legend
Homework
Assigned reading:
http://www.pveducation.org/
sections 3.1-3.2