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Solutions & Answers For Jee Mains-2021 26 August Shift 1: (Physics, Chemistry & Mathematics)
Solutions & Answers For Jee Mains-2021 26 August Shift 1: (Physics, Chemistry & Mathematics)
PART – A – PHYSICS
Section A
1− 3 − 2
Ans: tan−1
3 + 1 + 2
Sol: y
C
A
45 30
O x
60
1
OB = cos 60 î − sin 60 ĵ = î −
2
3
2
ĵ
( ) 1
OC = cos 45 − î + sin45 ĵ = − î +
1
ĵ
2 2
3 + 1 1 1 3 1
OA + OB − OC = + î + − − ĵ
2
2 2 2 2
Angle with x-axis
1 3 1
− −
2 2 2 2 − 6 − 2
−1 1 − 3 − 2
tan −1 −1
= tan = tan
3 +1+ 1 6 + 2 + 2 3 + 1 + 2
2 2 2
Ans: 0.9 mA
Sol: = 200 m
C = 2 10-12 F
V = 40 V
K = 56
t
q q
i= = 0 e k 0
k 0 k 0
2 10 −12 40 80
i max = = = 903A = 0.9mA
200 50 8.85 10 −12 10 4 8.85
Sol: Q = U + W
Q U W
= +
t t t
6000 J 2.5 103
= + 90
60 sec t
t = 250 sec
Ans: 2.2 W
Sol:
4
4
4 4 8
A B
2
8 12
8
6
r = 0.6
2.2 V, r = 0.6
2.2 V
1 1 1 1 1 6 + 3 + 2 + 4 15
= + + + = =
R eq 4 8 12 6 24 24
24
Req = = 1.6 RT = 1.6 + 0.6 = 2.2
15
V 2 (2.2)2
P= = = 2.2 W
RT 2.2
Ans: 4μF
Sol: XL = XC
1
250 =
2(50)C
C = 4 10-6 F
Ans: 5.15 mm
0 .5
Sol: Least count (L.C) =
50
0.5 0.5
True reading = 5 + 20 − 5
50 50
=5+
0.5
(15) = 5.15 mm
50
Ans:
kQ
R2
r=R r
-Q +Q
b R
a
r < R, E = 0
kQ
R r<a E=
r2
a r<b E=0
kQ
r b E=
r2
E
Ans: 0.2
1 2
Sol: U= Li = 64 L = 2
2
2
i R = 640
640
R= = 10
(8)2
L 1
= = = 0 .2
R 5
3RT
Sol: VRMS =
MW
1
When temperature is same VRMS
MW
VH > VO > VC
Ans: 1.3 V
hc
Sol: KEmax = eVs = −
1240
eVs = − 2.5 = 1.93 eV
280
→ Vs1 = 1.93 V − − − − − (i)
1240
→ eVs2 = − 2.5 = 0.6eV
400
Vs 2 = 0.6 V -----------(ii)
V = Vs1 − Vs 2 = 1.93 − 0.6 = 1.33 V
1 1
Sol: nf1 = k − 2
1 3
1
nf2 = k1 − 2
2
8
f1
= 9 f2 = 2.46 1015
f2 3
4
Ans: NOR
Sol:
A B X Y Z
1 1 0 0 0
1 0 0 1 0
0 1 1 0 0
0 0 1 1 1
Sol: Inside a spherical shell, gravitational field is zero and the gravitational potential remains same
everywhere.
Ans: 60 kg s−1
Sol:
Ft
mg
dm
Fthrust = Vrel
dt
dm
Vrel − mg = ma
dt
dm
500 − 103 10 = 103 20
dt
= (60 kg / s)
dm
dt
Sol: VB VA
B A
Ans: 2.19 mm
Sol: r1 r2
h
x
PA PB
Sol: E = ML2T-2
L = ML2T-1
m=M
G = M-1L+3T-2
EL2
P=
M5G2
(
M M LT )
0 0 0
−2 6 − 4
Sol: Pentavalent impurities have excess number of free e−. but the overall semiconductor will be
changeless or neutral
Ans: 97 m
R 1R 2
Sol: =3
R1 + R 2
(12 10 −6
)
10 −2 4
(51 10 −6
)
10 −2 4
(2) 10
2 −6
(2) 10
2 −6
−6 −2
63 10 10 4
(2) 10 2 −6
= 97 m
3 r2
Ans:
2 a2
0 iR 2
Sol: B axis =
(
2 R2 + x2 ) 3
2
i
Bcentre = 0
2R
i
Bcentre = 0
2a
0ia2
Baxis =
(
2 a2 + r 2 )
3
2
0i 0ia2
−
3 r2 3 r2
1 − 1 − =
2 a 2 2 a 2
Section B
Ans: 1.00
Ans: 2.00
Ans: 2025
Sol:
S O
Vs = 20 m/s VO = 20 m/s
C − V0
f ' = f
C + Vs
340 − 20
1800 = f
340 + 20
f = 2025 Hz
Ans: 40.00
2 m, 2 kg
Sol: From energy conservation
Ki + Ui = kf + Uf 3 m, 3 kg
1 3 1 m, 1 kg
0 + − 1 10 = k f + − 3 10
2 2
-5 = kf – 45
Kf = 40 J
Ans: 354.0
Sol: E0 = 200
1
= 0E02C
2
Radiation pressure
2 2 1
P= = 0E02C = 0E02 = 8.85 10-12 2002
C C 2
354
= 8.85 10-8 4 =
109
Ans: 52.00
5
2
13 r
2
Sol: = 1 + M r + 2 + M
2 2
=
( ) ( )
M 36r 2 M 25r 2 Mr 2 169Mr 2
+ + +
12 4 2 4
5
r
= 52 Mr2 2
1 2
13
r
2
Ans: 300.00
D
Sol: Position of bright fringe y = n
d
D
y1 of red = = 3.5 mm
d
d
r = 3.5 10-3
D
d
Similarly v = 2 10-3
D
0.3 10−3
r - v = (1.5 10-3)
1.5
= 3 10 = 300 nm
-7
Ans: 2.00
35t − 10 t 2 = 35(t − 3 ) − 10 (t − 3 )2
1 1
2 2
1 1 (1) (2)
35t − 10 t 2 = 35 − 10 t 2 t=0 t = 3 sec
2 2
1 2 1
− 10 3 + 10 6t
2 2
0 = 150 – 30 t
t = 5 sec
Height at which both balls will collide
1
h = 35t − 10 t 2
2
1
= 35 5 − 10 52
2
h = 50 m
Ans: 1.00
Sol: = M2 B1 M1
=M2B1 sin 90
M1 M2
= 1 0 1
4 (1)3
= 10-7 Nm
B1
PART – B – CHEMISTRY
Section A
Ans: 3
z
Sol: Velocity of an electron in Bohr’s atom is given by V
n
Where z → atomic number, which corresponds to number of protons (+ve charges)
Hence, as ‘z’ increases, velocity increases
As ‘n’ increases, velocity decreases
Ans: (IV)
Cl Cl
NaOH
Sol: + I−
CH2I CH2OH
AgNO3 dil.HNO3
AgI
(yellow
pr ecipitate)
Ans:
OH OH
Br2 (Excess) Br Br
Sol:
H2O
Br
(A)
2 ,4,6-tribromoph enol
OH OH
Br 2
Br
(B)
p-Bromoph enol
Sol: Interhalogen compounds are more reactive than respective halogens (except fluorine)
Ans:
O
COOH C
SOCl2 Cl
Sol: + HCl
NH2 CH3OH NH2
N N
H H
CH 3OH
O
C
OCH3
NH2.HCl
N
H
excess CO
Sol: Ca(OH)2 + CO2 ⎯⎯→ CaCO3 + H2O ⎯⎯⎯⎯⎯⎯
2
→ Ca(HCO3 )2
Ans:
Br
B2
Sol: CH3−CH−CH3 CH3−C−CH3
h /
CH3 CH3
(Excess)
Ans: CuCl2
Sol: For weak acid against strong base, indicator phenolphthalein is used and for a strong acid against
weak base, indicator methyl orange is used.
NO2 NO 2
CO 2 Mg
H3O + eth er
COOH MgBr
3- Nitrobe nzoi c acid
Ans: [Fe(CN)5NOS]4−
Ans: Bakelite
Sol: Novolac on heating with formaldehyde undergoes cross linking to form an infusible solid called
bakelite.
Ans:
CH2=C−CH=CH2 CH3−C=CH−CH2Br
HBr
Sol:
1,4 addition
CH3 takes place CH3
Ans: [3Ca3(PO4)2.Ca(OH)2]
O
C COOK
CH3 Br2
Sol: KOH
+ CHBr3
(B)
(A)
Sol: Limiting molar conductivity of KCl is less than that of acetic acid. Molar conductivity increases with
increase in dilution (i.e., decrease in concentration)
Ans: Synthetic resin method
Sol: Organic ion exchange method (synthetic resin method) is used for preparing deionised water.
Sol: For adsorption of gas at a given temperature, ∆H = −ve, since it is an exothermic process and
∆S = −ve, since randomness decreases during adsorption.
Section B
Ans: 3
E
⎯ M(+g) ⎯⎯hyd⎯
⎯→M(+aq)
H H
Sol: M(s) ⎯⎯sub⎯
⎯→M(g) ⎯⎯→
Electrode potential depends on sublimation enthalpy, ionization enthalpy and hydration enthalpy.
Ans: 2
Sol: For an interhalogen compound AB3, the central atom A undergoes sp3d hybridization and there are 3
bond pairs and 2 lone pairs around it.
B
A B
Ans: 7
Sol: Gd (Z = 64)
Electronic configuration − [Xe] 4f7 5d1 6s2
Gd2+ → [Xe] 4f7 5d1
Ans: 1
Ans: 4
CH2−COOH
O COOH
Sol: NH2−CH2−C−NH−CH−C−NH−CH−C−NH−CH
O O CH2
CH2−CH2−C−OH
O pH = 12
OH
CH2−COO
O COO
NH2−CH2−C−NH−CH−C−NH−CH−C−NH−CH
O O CH2
CH2−CH2−C−O
O
Ans: 718
fH
Sol: K(s) + ½Cl2 KCl
subH ½bondH
K(g) + Cl(g) - LE
ionisationH egH
K+(g) + Cl-(g)
According to Hess’s law
1
∆fH° = ∆subH° + ∆ionisationH° + ∆bondH° + ∆egH° − LE
2
1
LE = 89.2 + 419.0+ × 243 + (−348.6) + 436.7
2
= 717.8 kJ mol−1
Ans: 4
Ans: 3
Ans: 3
[NH+4 ][ OH− ]
Sol: Kb =
[NH3 ]
1.8 10 −5 2 0.021
[OH − ] = = 3 10 − 6
5 0.0504
PART – C – MATHEMATICS
Section A
Ans: −3
Sol: a = î + ĵ + k̂ b = ĵ − k̂
Let c = x î + yĵ + zk̂
a.c = 3
x+y+z =3 (1)
i j k
a c = 1 1 1 = î (z − y ) − ĵ(z − x ) + k̂ (y − x )
x y z
ac = b
z = y ; x = z +1
Sub in (1)
2 2 5
z= , y= , x=
3 3 3
5 2 2
c = î + ĵ + k̂
3 3 3
î ĵ k̂
4 5 5
b c = 0 + 1 − 1 = î − ĵ − k̂
5 2 2 3 3 3
3 3 3
( ) (
) 4
3
5 5
a. b c = î + ĵ + k̂ î − ĵ − k̂ = −2
3 3
11
Ans: −
30
cos x
Sol: = tan 2x
1 + sin x
sin − x
2 = tan 2x
1 + cos − x
2
x x
2 sin − cos −
4 2 4 2 = tan 2x
x
2 cos2 −
4 2
x
tan − = tan 2x
4 2
x
tan2 − = tan2 2x
4 2
x
2 x = n −
4 2
−3 −
x= , ,
10 6 10
−3 −11
Sum of solutions = − + =
10 6 10 30
4
Ans:
3
5
Ans:
12
1 2 22 2100
Sol: Let S = + 2 + 4 + − − − − − + 100
x +1 x +1 x +1 x 2
+1
1 −1 1 2 22 2100
S− = + + 2 + 4 + − − − − − + 100
1− x 1− x x + 1 x + 1 x + 1 x2 + 1
2 2 22 2100
= + + +−−−−−+
2
x −1 2
x +1 4
x +1 2100
x +1
2 2 100
2 2 2
= + +−−−−−+
4
x −1 4
x +1 2100
x +1
101
1 −2
S− = 101
1− x x2 − 1
Putting x = 2
1 − 2101
S− = 101
1− 2 4 − 1
− 2101 2101
S= 101
+ 1 = 1−
4 −1 4101
−1
(1 − x )2 f ' (x ) = −2 (1 − x )2
2
(1 + x )
(1 − x ) f ' (x ) + 2(f (x ))2 = 0
2
Sol: Putting z = x + iy
z − 1 x + iy − 1 x 2 − 1 − i (x − 1) y + i (x + 1) y + y 2
= =
z + 1 x + iy + 1 (x + 1)2 + y2
z − 1
arg =
z + 1 4
2y
2 =1
x + y2 − 1
x 2 + y 2 − 2y − 1 = 0
a circle with centre at (0, 1) and radius 2
Ans:
4
Solution is y tan x = − tan2 x + C
tan−1(4 )
1
Ans:
2
2n −1
n2
n2 + 4r 2 = nlim
1 1 1
Sol: lim 2
n→ n → n r
r =0
1 + 4
n
1 + x 2 dx = 4 2tan
2 2
1 1 1 1 2 1
1 + 4x 2
−1
= dx = 2x 0 = tan −1 4
4 2
0 0
4
Ans: 3 5
x2 y2
Sol: Given ellipse is + =1
8 4
1
a = 2 2 ,b = 2 e =
2
Let the point P be (a cos , b sin)
x y
Tangent at this point is given by cos + sin − 1 = 0
8 2
−1
Slope = cot = 2
2
3
1
cot = −2 2
−2 2 1
cos = , sin =
3 3 −2 2
−2 2 1 8 2
P = 2 2 ,2 = − ,
3 3 3 3
1 2 1 1 2 4
Area = 2ae = 2 2 2 =
2 3 2 2 3 3
(
) 1 4
Now 5 − e2 A = 5 − = 6
2 3
Ans: T F F
Sol:
p q r p q q → r (p q) (q → r ) r pq ( (p q) (q → r ) r) → p q
T T T T T F T T
T T F T F F T T
T F T T T F F T
T F F T T T F F
F T T T T F F T
F T F T F F F T
F F T F T F F T
F F F F T F F T
Ans: loge16
1 1
2 1 1
2 x + 1 2 x − 1 2 2
− 4x
2 2
− 2 dx =
4| x|
Sol:
+
x − 1 x + 1 2 =
x − 1 1 − x2
dx
− 1 − 1 − 1
2 2 2
1
( )
2 1
x
=8 1− x 2
= 4 ln 1 − x 2 0
2 = ln 16 = loge 16
0
Ans: (0,1,1)
Sol: Equation of the plane containing x + 2y + 3z + 1 = 0 and x − y − z − 6 = 0 is
x + 2y + 3z + 1+ (x − y − z − 6) = 0
(1+ )x + (2 − )y + (3 − )z + (1− 6) = 0
Since the plane is perpendicular to −2x + y + z + 8 = 0
−2(1+ ) + 1(2 − ) + 1(3 − ) = 0
3
=
4
Required plane is 7x + 5y + 9z = 14
(0,1,1) lie in the plane.
Ans: 420 218
20 20
r 2 20 Cr = r (r − 1) + r 20 Cr = r(r − 1) r(r − 1) 18Cr = r.
20.19 20 19
Sol: Cr
r =0 r =0
r
1 0
Ans:
− 2021i 1
1 2 1 2
−
Sol: AA T
= 5 5 5 5
− 2 1 2 1
5 5
5 5
T
Q = A BA
( )( )
Q2 = A TBA A TBA = A TB2 A
Q 3
= (A BA )(A B A ) = A B A
T T 2 T 3
Q2021 = A TB2021A
Now, P = AQ 2021A T
(
P = A A TB2021A A T = B2021 )
1 0 1 0 1 0
Now, B2 = =
i 1 i 1 2i 1
1 0 1 0 1 0
B3 = =
i 1 2i 1 3i 1
1 0
B2021 =
2021 i 1
(
P−1 = B2021 = )
−1
−
1 0
2021i 1
1
Ans:
2
a
Sol: = 15 . ....( 1)
1− r
a2
= 150 ....( 2)
1− r 2
(2) a
= 10 ....( 3)
(1) 1− r
Solving (1) and (3)
1
r = , a = 12
5
1
12
2 4 6 ar 2 25 1
Now ar + ar + ar + − − − − − = = =
1− r 2 1−
1 2
25
Ans: (10.5 , 26)
Sol:
x = 10
20
x = 200
Correct x =200-25+35=210
210
Correct x = = 10.5
20
x
2
− 100 = 6.25
20
x2 = 2125
Correct x 2 = 2125 − 625 + 1225 = 2725
− (10.5 )2 = 26
2725
Correct 2 =
20
= 10.5 , = 26
Section B
Ans: 40
Ans: 27
Ans: 36
2 1 2
Sol: − =
x −1 x − 2 k
Rearranging , we get
2x 2 − (6 + k )x + 3k + 4 = 0
Since there is no real root,
(6 + k )2 − 4.2(3k + 4) 0
k 2 + 12 k + 36 − 24 k − 32 0
k 2 + 12 k + 4 0
(k − 6 )2 − 32 0
Integral value of k = 1,2,3,……..11
Sum = 1+ 2 + − − − − +11
11 12
= = 66
2
Ans: 16
= 4 x 2 + 4 y 2 − 4 y − 4x = 14
7
x2 + y2 − x − y − =0
2
1 1 7
r= + + =2
4 4 2
d = 4 d2 = 16
Ans: 13
1− i 3
Sol: z= = −
2
3 3 3
1 1 1
Now 21 + z + + z2 + 2 + − − − − − + z21 + 21
z z z
3 3 3
1 1 1
= 21+ − − + 2 + 2 + − − − − + − 21 − 21 = 21 − 8 = 13
Ans: 136
1
Sol: P1 + 2 2P2 + 3 3P3 + − − − − − − +15 15 P15 = 1!+2 2! + 3 3!+-------+15 15!
15 15
= r r! = (r + 1− 1)r !
r =1 r =1
15 15
= (r + 1)r ! − r ! = (r + 1)! − r !
r =1 r =1
= 16! − 1!
16
= P16 − 1=qPr − s
q = 16 , r = 16 , s = 1
17 16
q+ s Cr −s =16 +1C16 −1=17 C15 =17 C2 = = 136
2
Ans: 52
Ans: 14
Sol: LHL = lim a sin (0 − 1) = −a , f (0) = −a
x →0 2
(2x )3 + (2x )3 8 8
+
2x − sin 2x 3 6 4
RHL= lim = lim = 3 6 =
x →0 bx3 x →0 bx3 b b
4
−a =
b
−ab = 4
10 − ab = 10 + 4 = 14
Ans: 26
Sol: Any point in the given line will be of the form (2k + 1, k + 3, 2k + 4)
Foot of the perpendicular in the plane is
x − (2k + 1) y − (k + 3 ) z − (2k + 4 ) k + 6
= = =
1 −2 −1 3
7k + 9 k −3 5k + 6
x= ,y = ,z =
3 3 3
x − 3 y +1 z − 2
Projection Line is = =
7 1 5
Distance ratio of line joining (0, 0, 6) and projection line is 7k + 3, k + 1, 5k − 4
Since projection line perpendicular to this , k = 0
Any arbitrary point in the projection line is (3, − 1, 2) d2 = 26