Professional Documents
Culture Documents
78e8258eac99400da9393f40410aed18
78e8258eac99400da9393f40410aed18
PART 1
NOMENCLATURE
The word organic signifies life - ie, compounds directly or indirectly derived from living
beings.
Lemery classified the naturally occurring substances into 3
1. Mineral substances
2. Vegetable substances
3. Animal substances
Lavoisier reclassified theses in to two based on a some elements common in vegetable and
animal substances
1. Compounds from living beings ( Organic compounds)
2. Compounds form non living beings ( Inorganic compounds)
Organic Chemistry- The branch of chemistry deals with study about organic
compounds.
Hybridisation influences the bond length and bond enthalpy (strength) in organic
compounds. The sp hybrid orbital contains more s character and hence it is closer to its
nucleus and forms shorter and stronger bonds than the sp3 hybrid orbital. The sp2 hybrid
orbital is intermediate in s character between sp and sp3 and, hence, the length and
enthalpy of the bonds it forms, are also intermediate between them. The change in
hybridisation affects the electronegativity of carbon. The greater the s character of the
hybrid orbitals, the greater is the electronegativity. Thus, a carbon atom having an sp hybrid
orbital with 50% s character is more electronegative than that possessing sp2 or sp3
hybridised orbitals.
SP3 hybridisation occurs when a C has 4 attached groups, it has 25%S and 75% P
character, each SP3 hybrid orbital is in sigma bond formation.
In these formulas the solid-wedge is used to indicate a bond projecting out of the
plane of paper, towards the observer. The dashed-wedge is used to depict the bond
projecting out of the plane of the paper and away from the observer. Wedges are
shown in such a way that the broad end of the wedge is towards the observer. The
bonds lying in plane of the paper are depicted by using a normal line (—).
Nomenclature
2 system of naming
1. TRIVIAL system
2. IUPAC system
ii) ALKENE
CH
, -_CHz
Ethylene
City -
cH=cHz Propylene
91-13
CH
}
-
c=cHz
lsobatglene
iii) ALKYNES
cH=cH
Acetylene
CH
,
-
CECH
Methyl acetylene
CH} - c :c -