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Use of Geometallurgy to Predict

Tailings Leach Acid Consumption at


Olympic Dam
E Macmillan1, K Ehrig2, V Liebezeit3, P Kittler4 and C Lower5

ABSTRACT
For any processing plant there will be deleterious elements or minerals which affect production or
quality, and a strategy to predict their occurrence and mitigate their impact is required. An early
objective of the Olympic Dam geometallurgy program was prediction of the acid consumption
and gelling behaviour of the ore, which affects leach recovery, throughput and circuit availability.
The geometallurgical test program measured the response of a wide range of ore types, and then
relationships between mineralogy, metallurgy and chemistry were developed. Thus the drivers of
acid consumption and triggers for gelling events could be described in ways that were meaningful
to plant operations.
To enable optimisation of the mine planning and ore blending processes, the parameters driving
metallurgical response must be translated to the block model. Data support is critical in populating
a block model. Assay information is easily obtained, but mineralogical and metallurgical
information is more expensive and time consuming to collect. Hence population of a block model
with mineralogical and metallurgical values using a conventional geostatistical approach is not
always possible.
An alternative approach employed at Olympic Dam was the development of a suite of assay-to-
mineral algorithms. These algorithms were calibrated using all available mineralogical information,
and this enabled the calculation of mineral abundances for more than 1.5 million assayed samples.
Estimation of the minerals in the block model, and the generation of acid consumption values for
each block could subsequently occur.
The use of back-calculated mineralogy from assays as part of process model generation is an
innovative tool which can be used for mine planning and optimisation and to ensure the plant
does not receive any unwelcome surprises. Ultimately, one purpose of geometallurgy is to predict
potential processing issues and their drivers so that these can be mitigated. A strategy to achieve
this is outlined hereafter.

INTRODUCTION
One of the objectives of geometallurgy is to develop gives an appreciation of the geological and processing
relationships between mineralogy, metallurgy, geology and complexities at Olympic Dam.
chemistry which can be used to explain and predict behaviour
of the ore in a process plant. The following paper aims to Geology
describe a geometallurgical strategy for a process issue, which The Olympic Dam breccia complex is a ‘granite’ which has
has resulted in the creation of a large resource block model been intensely brecciated and altered/mineralised to produce
populated with process plant information. localised iron oxide rich zones which may, or may not, be
economically mineralised. Minerals in the ‘granite’ have been
Background – Olympic Dam progressively replaced by iron oxides, hematite and magnetite,
Located 560 kilometres north of Adelaide, South Australia, and a suite of hydrothermal minerals.
Olympic Dam is a multi-mineral orebody. It is the world’s There are over 70 minerals which occur in Olympic Dam
fourth largest remaining copper deposit, fifth largest gold ores. These include, but are not limited to – economic minerals
deposit and the largest uranium deposit. It also contains (bornite, chalcocite, chalcopyrite, coffinite, brannerite,
significant quantities of silver. The subsequent description uraninite, Ag-Au bearing minerals); sub-economic minerals

1. MAusIMM, Project Geometallurgist, BHP Billiton, 55 Grenfell Street, Adelaide SA 5000. Email: edeltraud.macmillan@bhpbilliton.com
2. Principal Geometallurgist, BHP Billiton, 55 Grenfell Street, Adelaide SA 5000. Email: kathy.ehrig@bhpbilliton.com
3. Senior Engineer Long-Term Planning, BHP Billiton, 55 Grenfell Street, Adelaide SA 5000. Email: vanessa.liebezeit@bhpbilliton.com
4. MAusIMM, Senior Geometallurgist, BHP Billiton, 55 Grenfell Street, Adelaide SA 5000. Email: paul.kittler@bhpbilliton.com
5. Geometallurgist, BHP Billiton, 55 Grenfell Street, Adelaide SA 5000. Email: chantelle.lower@bhpbilliton.com

THE FIRST AUSIMM INTERNATIONAL GEOMETALLURGY CONFERENCE / BRISBANE, QLD, 5 - 7 SEPTEMBER 2011 93
E MACMILLAN et al

(Co-, Zn-, Mo-, REE-, As-, Se-, Bi-, Te-, Sb-, Pb- bearing In the current work, whole-rock assay information was
minerals), and gangue minerals (hematite, quartz, sericite, utilised and mineralogical algorithms generated from these
k-feldspar, chlorite, siderite, fluorite and barite). to predict mineral abundances in every assayed sample.
Felsic, mafic, and ultramafic volcanic rocks are also present Ultimately this mineralogical information is used in the
in the orebody and are an integral part of the genesis of the modelling process as input parameters so that equations
Olympic Dam breccia complex. The volcanic rocks have been can be developed which predict various geometallurgical
subjected to the same alteration processes as the granite. parameters (including acid consumption and recoveries).
These geometallurgical attributes are then modelled spatially
Processing so that their impacts can be recognised for mine planning and
The processing plant at Olympic Dam is complex, and includes: mineral processing purposes.
grinding, flotation, leaching, solvent extraction, smelting, and
refining. The saleable products are copper, uranium, gold and GEOMETALLURGY STRATEGY
silver. Figure 1 is a diagrammatic representation of the process
Grinding at Olympic Dam consists of crushing the ore used to populate the Olympic Dam block model. In practice,
in a primary crusher underground, then milling the ore there are numerous iterative steps in this process. The
in autogenous mills. Flotation of the ore then occurs to first step involves the collection of data from metallurgical
separate the valuable copper minerals (chalcopyrite, bornite, tests, assay, geological and also mineralogical information.
chalcocite) from the gangue minerals. The concentrate From these data, proxies are identified which can be used
produced from flotation is leached to extract the fluorine and to identify key parameters, which may be modelled to
uranium contained in the copper concentrate. The resultant predict geometallurgical parameters (acid consumption in
copper concentrate is processed in the smelter and refinery this case). All of these key input parameters, proxies and
to produce electrorefined copper cathode, gold bullion, and geometallurgical parameters can then be spatially modelled
silver bullion.
using geostatistics. From these spatial models, zones in the
The tailings leach process extracts copper and uranium orebody can be identified which may contain minerals that
from the flotation tailings. Leaching is conducted with sulfuric are deleterious to the plant. With this knowledge, optimised
acid and sodium chlorate. After leaching the slurry is sent to mine plans and schedules can be produced which reduce ore
a series of counter-current-decantation (CCD) units, with variability and take into consideration the location of these
the tailings being sent to deslimes and disposal, whilst the
deleterious minerals to reduce the likelihood that they will
liquor containing dissolved copper and uranium is sent for
significantly impact the operation.
clarification. The clarified pregnant leach solution is then sent
to copper solvent extraction and the electrowinning plant.
Finally, uranium solvent extraction occurs, producing yellow-
Data collection
cake, which is subsequently calcined to produce uranium The first part of the journey in creating a geometallurgy
oxide concentrate. enabled mine plan is the collection of data. There are
numerous sources of data that may be appropriate to predict
Leaching and acid consumption geometallurgical parameters. From this data, the rock to be
Sulfuric acid is used to leach both flotation concentrate and mined can be characterised.
tailings. Sulfuric acid is produced on site via treatment of Data support is the key in ensuring all models adequately
the smelter off-gases and supplementary sulfur burning. reflect the variability of the orebody. Assay information is
The prediction of acid demand is important in ensuring the most easily obtained, with mineralogical and metallurgical
leaching circuit has sufficient acid available. In terms of information being more expensive and time consuming to
acid consuming minerals, the dominant naturally occurring collect. Usually, due to the number of metallurgical tests
minerals are siderite, chlorite and sericite. Another acid which are carried out, this precludes direct estimation of the
consumer can be cement aggregate fill (CAF), which is used test result into the block model via the use of geostatistical
for stope backfill. methods because of a lack of sample support. This is dependent
Events termed ‘gelling’ and ‘thickening’ may occur in the on the orebody and the metallurgical parameter in question,
tailings leach circuit under certain conditions. These events and must therefore be determined on a case by case basis.
can lead to reduced throughput, reduced recoveries and Various approaches can be taken to overcome this limitation
significant equipment downtime. There is a requirement to when it is required to populate the block model with a
understand and predict the drivers of these events in order to metallurgical parameter. One approach is the development
eliminate, reduce or mitigate the effects of their occurrence. of a small-scale, cheap test which can be performed on a
Furthermore, in evaluating future options for expansion, it much larger number of samples without the cost becoming
was identified that acid consumption was a driver of value. prohibitive. An alternative is the determination of suitable
Therefore acid consumption and gelling propensity are proxies which can be used to predict the metallurgical
important metallurgical performance parameters which responses. Once these proxies have been validated by
influence the optimisation of the current Olympic Dam laboratory scale metallurgical tests, these can be scaled
operation and future possible expansions. up to yield relationships which can determine various
characteristics of the deposit (Dunham and Vann, 2007).
Geometallurgy There is also the approach taken by Olympic Dam which is
The geometallurgy program at Olympic Dam aims to quantify to develop a relationship between the required metallurgical
relationships between chemical assays, mineralogy and response and variables which are available in every block
metallurgical performance with the aim of populating the model (for example elements, minerals and density). In order
resource block model. As discussed by Dunham and Vann to develop a relationship which is valid across the required
(2007), geometallurgy is a field which looks at identifying range, sufficient metallurgical tests need to be performed on
either direct measures or proxies for throughput, recovery a wide range of samples. Hence, this information is usually
and concentrate quality from various forms of data. collected for selected samples and models are generated

94 THE FIRST AUSIMM INTERNATIONAL GEOMETALLURGY CONFERENCE / BRISBANE, QLD, 5 - 7 SEPTEMBER 2011
USE OF GEOMETALLURGY TO PREDICT TAILINGS LEACH ACID CONSUMPTION AT OLYMPIC DAM

FIG 1 - Geometallurgical strategy at Olympic Dam.

THE FIRST AUSIMM INTERNATIONAL GEOMETALLURGY CONFERENCE / BRISBANE, QLD, 5 - 7 SEPTEMBER 2011 95
E MACMILLAN et al

which may indicate potential key drivers for particular issues. Mineralogy algorithms
These models are then used to populate parameters in the In an ideal scenario, mineralogy would be measured on all
block model.
assayed samples so that the mineral abundances could be
estimated on all blocks in the block model. However, it is
Assays
not practical to directly measure mineral abundances on all
At Olympic Dam, over 1.5 million resource samples have been
assayed samples at Olympic Dam due to the large number of
assayed for 26 different elements (K, Al, Si, Fe, Ca, Ba, S, CO2,
samples which are routinely assayed. Fortunately, at Olympic
Cu, U3O8, Au, Ag, As, Co, Mo, Ni, Pb, Zn, La, Ce, Mg, Mn, Na,
Dam the concentrations of the 14 most abundant (and
P, Ti, Zr). Density and magnetic susceptibility data have also
important) minerals can be predicted on all samples that have
been collected for these samples. These samples have been
been assayed for the defined suite of elements.
sourced from approximately 10 000 diamond drill holes
which have been drilled within and around the periphery of The use of calculated mineralogy algorithms to estimate the
the deposit. abundance of various minerals in unaltered or unmineralised
rocks from whole-rock chemical assays has been used for
Mineralogy decades (Best, 1982; Carmichael, Turner and Verhoogen,
Fourteen minerals (hematite, quartz, sericite, feldspar, 1974). In order to create these mineralogy algorithms, it is a
chlorite, barite, fluorite, siderite, pyrite, chalcopyrite, bornite, requirement that all elements be unambiguously partitioned
chalcocite, sphalerite, and molybdenite) account for at least to minerals. After intense alteration and/or mineralisation of
98 per cent of the minerals in altered and mineralised breccias rocks this is often a difficult process to complete. At Olympic
at Olympic Dam. Mineralogical analyses are not conducted for Dam, many of the silicate minerals are not stoichiometric
every sample. However, metallurgical performance is a function which makes this process more difficult. However, in general
of the behaviour of minerals, not simply the concentration of terms many of the minerals at Olympic Dam are chemically
metals. The starting point at Olympic Dam was that whole- quite simple, and hence this partitioning of elements can
rock chemical assays could be used to calculate mineralogy, occur reasonably easily. Mineralogy algorithms that offer
producing sample support for block model estimation at the a good ‘global’ estimate of calculated mineralogy for in situ
same scale as assays. Sufficient measured mineralogy must be Olympic Dam ore have been produced. These algorithms
conducted to validate the mineralogy calculations. A variety can also be applied to calculate the mineralogy for some of
of techniques are used at Olympic Dam including automated the plant streams, including flotation streams, tailings/
mineralogy techniques (mineral liberation analyser or MLA, concentrate leach feeds and residues. The algorithms utilise
and QEMSCAN®), quantitative x-ray diffraction (QXRD) and head assay information to predict the mineral speciation in
use of an electron microprobe to define the stoichiometric a sample. This is advantageous, as it means that mineralogy
compositional ranges for key minerals. measurements do not need to be conducted for every sample,
but can be back-calculated from head assays. These assay-to-
Metallurgical test work mineral algorithms have been used at Olympic Dam for more
The cost, time and sample size required to conduct than 15 years and are validated from measured mineralogy
metallurgical laboratory tests generally limits the number of (e.g. QXRD and MLA) results.
samples that can be tested. The approach at Olympic Dam is
to relate the metallurgical response from the applicable test Process model generation
to the data about the primary sample which is available in the
Examination of the minerals present in Olympic Dam tailings
block model.
leach feed with respect to their solubility in sulfuric acid at
A set of tests under so-called ‘standard’ conditions form the current operating process temperatures suggest that carbonate
basis of the metallurgical test component of the Olympic Dam minerals (siderite, ankerite and dolomite), chlorite, fluorite,
geometallurgy program. Currently the leach test is executed sericite, and hematite (to some extent) could be soluble.
as a batch laboratory test on laboratory and plant generated Jansen and Taylor (2002) identify chlorites as powerful long-
flotation tailings. The laboratory leach uses conditions that term acid consumers in their discussion of gangue mineralogy
are in line with current plant practice, and the leach method issues in heap leaches.
has been validated using plant-generated tailings to show
Empirical models for acid consumption were generated
it gives a comparable result to the plant with respect to the
from the measured test data and the three aforementioned
key metallurgical responses. There has been some limited
sets of input parameters for the primary sample, namely:
investigation into development of a ‘diagnostic’ leach test for
measured mineralogy, assays, and calculated mineralogy.
Olympic Dam tailings. This methodology will continue to be
Various statistical programs are used for the generation
developed.
of model development initially focusing on multiple linear
The primary purpose of an Olympic Dam geometallurgy regression techniques. Minitab statistical software was used to
standard leach test is to determine acid consumption and identify correlations, construct model equations and calculate
uranium extraction under standard conditions. A wide statistical parameters.
range of other quantitative and qualitative data about the
leach behaviour is also collected, including the propensity The input parameter pool
of each sample to thicken or gel, reagent consumption, In order to use the acid consumption relationship to populate
minor element extraction and leach rate. This data is stored the block model, the input parameters to the model must
in the geometallurgical database. More than 1000 samples be constrained to the variables which are estimated in every
have been tested to date. As part of the wider geometallurgy block in the resource model. Currently for Olympic Dam,
program, the primary sample is also extensively characterised geostatistical estimation occurs for the 26 assayed elements,
using the assay and mineralogy techniques described in density and the 14 calculated minerals. The geometallurgy
previous sections. Data relating to the primary sample and its team also opted to use the measured mineralogy as an input
metallurgical response can then be analysed. data set.

96 THE FIRST AUSIMM INTERNATIONAL GEOMETALLURGY CONFERENCE / BRISBANE, QLD, 5 - 7 SEPTEMBER 2011
USE OF GEOMETALLURGY TO PREDICT TAILINGS LEACH ACID CONSUMPTION AT OLYMPIC DAM

Acid consumption not been significantly reduced. This therefore strengthens the
It was found that the best models produced were based on case that the parameters and coefficients in this model offer a
mineralogy rather than assays, and were of the form: robust representation for the prediction of acid consumption.
The acid consumption model is tested against each new data
Acid consumption = a + b × (% chlorite) + c × (% carbonates) set produced by the geometallurgy program which provides an
+ d × (% sericite) important model validation step. Figure 2 shows results from a
proposed new mine area at Olympic Dam where the measured
(where a, b, c and d are coefficients generated from statistical acid consumption is compared with the modelled value. Leach
analysis). tests were conducted on selected discrete geometallurgy
samples. These samples do not represent blended feed, but
When models were generated using only elemental feed
represent extreme examples of ore types present in the new
assays as inputs, the standard error for these models was high,
mine area. The acid consumption values from the new mine
and linear regression generally showed poor data fit. Therefore
area were not used to generate the model. Comparing the
the assay-based models were not pursued as an option.
predicted and measured acid consumptions for the new mine
This empirical mineral-based model makes logical sense area, as displayed in Figure 2, hence validates that the model
based on the theoretical knowledge about the solubility of the predicts acid consumption very well. The error of prediction
gangue minerals. Fluorite does not completely dissolve under can hence be assessed and compared against the known test
Olympic Dam standard leach conditions. The data did not precision to determine if model improvement opportunities
show a strong correlation of fluorite with acid consumption are possible.
despite an extremely wide range of fluorite concentrations,
and there was no benefit to the predictive power of the model Gelling and thickening
with its inclusion. The extent of dissolution of hematite is The ‘gelling’ phenomenon identified in the operational tailings
extremely low, but it is the dominant gangue mineral so its leach circuit was also identified in the laboratory leach test. In
contribution could be significant. However, as with fluorite, the laboratory it is often difficult to record these qualitative
the empirical data analysis showed no strong correlation of observations and hence a rating system (gel rank) was
hematite with acid consumption. developed whereby samples were assigned as: non-gelling,
Numerous revisions of the acid consumption models thickening or gelling samples. An example of a ‘gelled’ tailings
have occurred overtime as the data set of tested samples sample is shown in Figure 3, where the thickness of the slurry
has increased. For each of these revisions, the model terms can be appreciated by its ability to hold a spatula vertically
have not changed, with chlorite, siderite and sericite always without any assistance. The observations were confirmed
being the main drivers of predicted acid consumption. The using rheological measurements on a sub-set of the samples.
presence of all three minerals always improves the model (in Data analysis was conducted on these three groups of
terms of standard errors), hence showing that each mineral samples to determine whether or not any of these sample
makes an independent and quantifiable contribution to acid sets were statistically different based on both chlorite content
consumption. Also, the model coefficients changed only and acid consumption. From the results of this work, the
slightly with each model update and the standard error has propensity for a sample to thicken or form a gel during leach

350
predicted acid consumption from model (kg/t)

300

250

200

150

100

50

1:1 line new mine area


0
0 50 100 150 200 250 300 350
measured acid consumption (kg/t)

FIG 2 - Example of model validation with a new data set of discrete (unblended) geometallurgy samples.

THE FIRST AUSIMM INTERNATIONAL GEOMETALLURGY CONFERENCE / BRISBANE, QLD, 5 - 7 SEPTEMBER 2011 97
E MACMILLAN et al

FIG 3 - Photograph of ‘gelled’ Olympic Dam slurry in the laboratory.

was linked to chlorite content. The geometallurgical testing value is calculated on a block-by-block basis using the
program identified a higher likelihood of gelling in tailings relationship developed from empirical data.
leach when the chlorite abundance is greater than a threshold In terms of the estimation of minerals and elements at
value of 3 weight per cent. This threshold value is used by the Olympic Dam, numerous estimation techniques are used.
mine planning team as a blending constraint. Kriging and other common spatial estimators are all based on
weighted averages, which presume additivity of the attribute
Block modelling being estimated (Dunham and Vann, 2007). For this reason
One of the most critical parts of geometallurgical evaluation the properties of each parameter that are being modelled
is the spatial resource model. Grades of various elements must be well understood.
(both economic and deleterious), mineral abundances,
When creating spatial estimates for geometallurgical
metallurgical recoveries and throughputs are all parameters
variables, using proxies that rely on data measured directly
that may need to be represented spatially in a block model.
from the drill hole or rock samples will yield results that should
This can be done via estimation, simulation or by block
produce enough data density to enable adequate estimation.
calculation. The main purpose of incorporating all of the
Due to the plethora of assay results available for Olympic
geometallurgical parameters into the block model is to allow
Dam, there is sufficient data support to estimate any of the
for processing costs and predictions to be evaluated and taken
assayed elements. Samples used for estimation consist of 5 m
into consideration during the mine planning process.
drill hole composites. Measured mineralogical information
In order to achieve an estimate which best represents the is not as abundant as assay information, and for this reason
data, numerous iterations are required. The iterative nature the calculated mineralogy algorithms are used to predict the
of the estimation process allows flaws in each estimate to be minerals present in each sample. Subsequently, geostatistical
realised and will allow for the creation of a method that best estimation of these calculated mineralogy values can occur.
represents each variable. This method may be unique for each
Once mineralogy block models have been generated, these
variable, or very similar for each variable. If the estimation
may be used in conjunction with developed process models
process is considered as a continuum, then the application of
to yield a calculation for the acid consumption, or any other
a global value could be considered as representing the starting parameter on a block scale.
point of the spatial representation of a variable. After several
iterations, once the known geological/structural constraints Mineral and element block models
are well represented, the ideal estimate should be achieved.
At Olympic Dam numerous estimation techniques (ie inverse
Unlike grades, both proxies and absolute measures of distance, ordinary kriging and multiple indicator kriging) are
geometallurgical variables are not necessarily linear or additive used to produce spatial block models for each element/mineral.
and therefore require very careful geostatistical consideration Block model estimation at Olympic Dam occurs on a 5 m ×
(Dunham and Vann, 2007). To overcome this problem, as 10 m × 5 m block size. The estimation process is a continuum,
well as the issue of sample support, the geometallurgical the most basic method of element/mineral distribution across
parameters in the Olympic Dam block model have been block a deposit is to assume a global value over the entire deposit.
calculated. These block calculations use variables that have If further spatial resolution is required, an inverse distance
been geostatistically estimated. An example of this is with weighting (IDW) estimation method is performed. If geological
acid consumption, where chlorite, siderite and sericite are all or structural factors are well represented and constrained, the
estimated in the block model, whilst the acid consumption iteration process can be stopped and no further estimation

98 THE FIRST AUSIMM INTERNATIONAL GEOMETALLURGY CONFERENCE / BRISBANE, QLD, 5 - 7 SEPTEMBER 2011
USE OF GEOMETALLURGY TO PREDICT TAILINGS LEACH ACID CONSUMPTION AT OLYMPIC DAM

techniques need to be sought. This is rarely the case and hence processing certain materials, especially those containing
the complexity of the estimation technique is increased, but materials that are deemed to be deleterious, as a risk
so too is the computational time to attain an estimate. Due to management strategy. For this reason, production plans can
the complex nature of the Olympic Dam orebody, these more be generated which decrease variability via blending. An
complex estimation techniques are commonly used. alternative is to change the process in some way. These options
can be evaluated to determine the optimal result according to
Geometallurgical block calculations the business objectives.
The values that are estimated for various elements and minerals As described earlier, at Olympic Dam the acid consumption
on a block-by-block basis are available for use via block is calculated for each block in the resource block model and
calculations. In order to attain geometallurgical information in remains a scheduling variable throughout the medium- and
a block model, the easiest method to employ is the use of block long-term mine planning process. The acid consumption
calculations. Data support is the key in generating accurate in new mine areas can be examined at a preliminary design
block models, and even large geometallurgical programs may phase prior to obtaining results from expensive metallurgical
not provide sufficient data support to allow population of a testing.
block model with mineralogical and metallurgical values via Olympic Dam uses a value-based mine planning process
a conventional geostatistical approach. Hence via the use of which aims to optimise the Net Present Value to evaluate
block calculations, the block model can be populated with various long-term options for exploitation of the Olympic
various geometallurgical parameters. Dam resource. The acid consumption, and the resultant acid
An advantage of using block calculations to populate the balance, is an input to the overall optimisation model. It is
used to determine the requirements for site-generated acid
geometallurgical parameters is the ease in which changes
via sulfur-burning acid plants. The capital cost and timing of
to the process models can be updated in the block model.
building the acid plants were included in the high level mine
Geostatistical modelling takes a significant amount of time, but
planning software, so that for various configurations the value
block calculations are relatively quick as their only requirement could be maximised.
is that all input values for the process model are available
The amount of chlorite in the feed remains as a constraint,
in each block. For this reason, to generate geometallurgical
subject to process mitigation options. Hence the availability
parameters in a block model, a script is run which calculates
of any parameter in a block model which may yield insight
the appropriate geometallurgical parameters. When revision
into potential processing issues is a powerful way to minimise
of these models occurs, it is simply a case of modifying the
impact to an operation. By methods such as blending,
equations in these scripts and re-running the script to over-
knowledge of operating thresholds and reagent consumption
write the block calculated values. This ease of modification is
limits, these potential issues may be mitigated.
particularly important as block model iterations commonly
occur as new information is added to the database. As a result
the estimation of chlorite, siderite and sericite may change,
CONCLUSIONS
and these changes need to be updated in the determination of One purpose of geometallurgy is to identify and predict
acid consumption values on a block scale. Currently there are potential drivers of processing issues so that their effect can
over 50 calculated geometallurgical parameters in the block be evaluated and mitigation strategies developed. At Olympic
model, hence having a method of calculating these reasonably Dam, the acid balance and the related issue of gelling in the
quickly in the block model is vital. tailings leach circuit provides a relevant case study for the use
of geometallurgy and the production of a geometallurgically-
In terms of acid consumption, overall acid demand is enabled block model.
expressed as acid consumption per unit of mill feed. The
mass of concentrate and the mass of tailings, enabling the The geometallurgical test program results showed that acid
acid demand estimation, is explicitly calculated for each consumption is correlated with the abundance of chlorite,
block. Further, the acid generated from on-site smelting is siderite and sericite. A robust empirical model was developed
calculated and this allows an acid balance to be generated for to predict tailings leach acid consumption. The data was
each block. Two examples of acid consumption as populated further analysed to show that the likelihood of thickening or
in the Olympic Dam block model can be seen in Figure 4 gelling based on chlorite content could be predicted.
and Figure 5, with plan view sections of -350 mRL and The abundances of acid consuming minerals in all assayed
-450 mRL respectively. These have been coloured to samples at Olympic Dam are determined via the use of assay-
display the relative variations of acid consumption over the to-mineral algorithms, and minerals are therefore available at
deposit, such that black represents lower acid consumption the same level of data support as assays. Spatial block models
while lighter grey represents zones which have higher acid are produced for each element and mineral based on the most
consumption. From these two plan view sections it can be appropriate estimation techniques, which include: inverse
seen that higher acid consumptions are expected around the distance weighting (IDW), ordinary kriging (OK) or multiple
periphery of the deposit. The variation in acid consumption indicator kriging (MIK).
across the deposit can thus be realised. This further highlights The eight million 30 × 30 × 15 m block Olympic Dam
the necessity of acid consumption prediction at Olympic Dam, resource block model thus contains a value in each block
and the importance of mine planning in ensuring the mine for 26 elements and 14 minerals. The acid consumption and
delivers ore that can be processed in the plant. resultant acid balance is calculated for each block using the
geometallurgical model developed from the test data. There
MINE PLANNING AND OPTIMISATION are over 50 geometallurgical parameters in the block relating
Ultimately, the geometallurgy enabled block model can be to the metallurgical response of the four valuable minerals
used to optimise mine planning, so that there are no surprises at Olympic Dam, as well as the behaviour of deleterious
when it is time to process the ore. Geometallurgical data can elements and other metallurgical parameters which affect the
also be used to examine the likelihood and consequences of economics of the operation.

THE FIRST AUSIMM INTERNATIONAL GEOMETALLURGY CONFERENCE / BRISBANE, QLD, 5 - 7 SEPTEMBER 2011 99
E MACMILLAN et al

Mine N

True N

Low

Medium

High

400 m

FIG 4 - Plan view section (-350 mRL) of acid consumption for the Olympic Dam deposit.

100 THE FIRST AUSIMM INTERNATIONAL GEOMETALLURGY CONFERENCE / BRISBANE, QLD, 5 - 7 SEPTEMBER 2011
USE OF GEOMETALLURGY TO PREDICT TAILINGS LEACH ACID CONSUMPTION AT OLYMPIC DAM

Mine N

True N

Low Low
Medium
Medium

High High

400 m

FIG 5 - Plan view section (-450 mRL) of acid consumption for the Olympic Dam deposit.

THE FIRST AUSIMM INTERNATIONAL GEOMETALLURGY CONFERENCE / BRISBANE, QLD, 5 - 7 SEPTEMBER 2011 101
E MACMILLAN et al

The acid consumption value is carried in the medium- and in either data collection, generation of assay-to-mineral
long-term mine planning process and is reported as part of algorithms, process modelling, statistical analysis and
the standard mine schedule. The acid consumption for new geostatistical modelling. The authors would like to thank key
mine areas can therefore be reviewed based only on the collaborators – Tania Helms, Nick Green, Dave Hartman,
assay drilling which has occurred in that area. Validation Shane O’Connell, Colin Badenhorst, Anthony Bottrill and
geometallurgical testing and mineralogy measurements may Michelle Smith.
then occur. However, the operation planning cycle already has
valuable information about an important value driver, in this REFERENCES
case acid consumption, which can be incorporated into the
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economic analysis of the various mining options.
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This example is one method of generating a
Carmichael, I S E, Turner, F J and Verhoogen, J, 1974. Igneous
geometallurgically-enabled block model which has proved
Petrology, 739 p (McGraw-Hill Book Co: New York).
beneficial in an existing operation and future planning for the
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and Project Value – Does your block model tell you what you
need to know? in Proceedings Project Evaluation Conference,
ACKNOWLEDGEMENTS p 189-196 (The Australasian Institute of Mining and Metallurgy:
Permission from BHP Billiton to publish this paper is Melbourne).
gratefully acknowledged. Jansen, M, and Taylor, A, 2002. Overview of gangue mineralogy
Geometallurgy involves the cross pollination of many issues in oxide copper heap leaching, International Project
disciplines, and hence numerous people have been involved Development Services Pty Limited.

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