Professional Documents
Culture Documents
Kapok V Tehninih Tekstilijah
Kapok V Tehninih Tekstilijah
net/publication/279764141
CITATIONS READS
21 3,168
1 author:
Tatjana Rijavec
University of Ljubljana
54 PUBLICATIONS 232 CITATIONS
SEE PROFILE
Some of the authors of this publication are also working on these related projects:
Preparation of Shape Memory NiTiNOL Filaments for Smart Textiles View project
All content following this page was uploaded by Tatjana Rijavec on 15 February 2017.
5BUKBOB3JKBWFD
0EEFMFL[BUFLTUJMTUWP
/BSBWPTMPWOPUFIOJØLB
GBLVMUFUB
6OJWFS[BW-KVCMKBOJ
Figure 1: Closed (top) and halved (bottom) kapok seedpod with fibres (foto: T. Rijavec)
density 0.928 gcm–3, and relative velocity of fi- TQPWSØJOTLJNJMBTUOPTUNJWMBLFO
TFTUPKJJ[LSBULJINJLSPĐCSJMPW
LJ
bres wetting and submersion. TPPSJFOUJSBOJQSBWPLPUOPOBQPWSØJOPWMBLFO<>7TFLVOEBSOJDF-
The percentage of lignin is qualitatively evaluat- MJʅOJTUFOJQPUFLBKPNJLSPĐCSJMJTLPSBKW[QPSFEOP[PTKPWMBLOB<>
ed with the microchemical reaction with alcohol
solution of fluoroglucinol and HCl. When ka-
pok is heated with HCl, furfural (C4 H3O·CHO)
is produced from pentoses present in the fibres,
which becomes dyed in the presence of fluoro-
glucinol (C6H3(OH)3 ). Kapok of the best qual-
ity does not undergo any dyeing, whilst kapok
of inferior quality is dyed red-brown to magen-
ta red [5].
Kapok of the highest quality comes from Afri-
ca and Java. The kapok from Ceylon and In-
dia is of lower quality. Java kapok is classified
into three classes: Super Fine Quality (AJK),
Fine Quality (C-Min) and Standard Quality
(C-Off).
Qualitative fibres are produced only from rip- Figure 2: Kapok fibres observed under optical microscope (foto: T.
ened kapok seedpods (Fig. 1). Immature fibres Rijavec)
have low strength, inferior lustre and colour,
and do not withstand stress during compression
into bales. The appearance of immature fibres
can be improved by fermentation in the open
air, however, mechanical properties are not im-
proved with this process.
Figure 5: Longitudinal (a) and cross section (b) view of kapok under scanning electronic microscope at 2000×
magnification (foto: M. Leskovšek)
lignin in kapok dissolves during acid treatments. )FNJDFMVMP[F TP QPMJIPMPDFMVMP[F [ OJßKP TUPQOKP QPMJNFSJ[BDJKF
Lignin is well resistant at high temperatures but LPU BMGB DFMVMP[B 7 LBQPLV TP QSJTPUOF QSFEWTFN LTJMP[F PLSPH
is sensitive to UV rays. A high content of lignin
JONFUJMHMVLVSPOTLBLJTMJOB PLSPH
)FNJDFMVMP-
in kapok enhances its antimicrobial proper- [FTPIJUSPCJPSB[HSBEMKJWF"MGBDFMVMP[BJOIFNJDFMVMP[FTPPCʅV-
ties. The primary cell wall of kapok contains less UMKJWFKØF[BUFSNJʅOPSB[HSBEOKPLPUMJHOJO
WFOEBSNBOKOBHOKFOF
lignin and more polysaccharides than the sec- L67EFHSBEBDJKJLPUMJHOJO
ondary cell wall. A high content of lignin imparts ÂFMF[P JO ESVHJ NJOFSBMJ TF OBIBKBKP WFʅJOPNB W QSJNBSOJ DFMJʅOJ
good antibacterial resistance to kapok. Kapok is TUFOJ
WLBUFSJQSFETUBWMKBKPTLVQOPUVEJEPEFMFß7JTPLBWTFC-
resistant to usual bacteria, which digest cellu- OPTU BOPSHBOTLJI TOPWJ W QSJNBSOJ DFMJʅOJ TUFOJ JNB [B QPTMFEJDP
lose. It is attacked and degraded by wood micro- NBOKØPTQPTPCOPTUWF[BOKBWPEFJOQPWFʅBOPUPHPTUWMBLFO
mildew, erosion bacteria (almost anaerobic bac- ,BQPLWTFCVKFPLSPHBDFUJMOJI $)CO–) skupin, zaradi če-
teria), and tunnelling bacteria (bacteria which TBSJNBUVEJQPPETUSBOJUWJQPWSØJOTLJIWPTLPWIJESPGPCOFMBTUOP-
need high amount of oxygen) in the same way as TUJ
UP KF [NBOKØBOP TQPTPCOPTU QPWSØKB WMBLFO [B UWPSKFOKF WPEJ-
wood [12, 13]. LPWJIWF[J<>4VSPWBWMBLOBTPJ[SFEOPIJESPGPCOB PMFPĐMOB
JO
Hemicelluloses are polycholocelluloses with a JNBKPWJTPLPLBQBDJUFUPBCTPSQDJKFOFQPMBSOJIUFLPʅJO
lower degree of polymerisation than alpha cel- #BSWB TVSPWFHB LBQPLB KF SVNFOLBTUB
SKBWLBTUB BMJ CFMLBTUB 1P-
lulose. Kapok contains especially xyloses (about QPMOPNBCFMBCBSWBKFSFELB7MBLOBTPCSF[WPOKB
OFUPLTJʅOBJO
23%) and 4-0-methyil-glucuronic acid (about OFQPW[SPʅBKPBMFSHJK4P[FMPNFILFHBPUJQB
QVIBTUBJO[FMPMBI-
5.9%). Hemicelluloses are fast biodegradable. LB QSJCMJßOPØFTULSBUMBßKBPECPNCBßB
,BQPLWTFCVKFm
Alpha cellulose and hemicelluloses are more [SBLBUFSKF[BUPPEMJʅFOUPQMPUOJJO[WPʅOJJ[PMBUPS"CTPMVUOBHP-
sensitive to thermal degradation than lignin but TUPUBDFMJʅOFTUFOFLBQPLBKF
HDNm
HPTUPUBWMBLOB[VQPØUF-
more resistant to UV degradation than lignin. WBOKFNQSJCMJßOPMVNOBQBMF
HDNm<>,BQPLEPCSP
Iron and other minerals are concentrated most- QMBWBOBWPEJ7TUJTOKFOJPCMJLJ[ESßJKPWMBLOBOBWPEJEPLSBU
ly in the primary cell wall in which they might OPTWPKPUFßP4PLSBUCPMKQMPWOBLPUQMVUPWJOBJOTFTVØJKPIJUSF-
represent even a 20% share. Due to a high con- KFPEOKF1MPWOPTUPISBOJKPWMBLOBUVEJQPPETUSBOJUWJWPTLPW<>
tent of inorganic substances in the primary cell, ,BQPL KF OBSBWOP WPUMP WMBLOP [ PEMJʅOJNJ PMFPĐMOJNJ MBTUOPTU-
kapok fibres have lower capability of water ab- NJ
[WJTPLPTQPTPCOPTUKPWF[BOKBSB[OJIPMK,BQPLPMKBBCTPSCJSB
sorption and higher resilience. BETPSCJSBJOLBQJMBSOPWTSLBWB0MFPĐMOFMBTUOPTUJQSJQJTVKFKPWPT
Since kapok contains about 13% of acetyl (CH3 LBTUFNVQPWSØKVWMBLFOJOWJTPLJWTFCOPTUJBDFUJMOJITLVQJO
WFMJ-
CO–) groups, it preserves the hydrophobic LBLBQBDJUFUBBCTPSQDJKFPMKQBKFQPTMFEJDBØJSPLFHBMVNOBWMBLFO
properties even after the removal of waxes, 0QB[JMJTP
EBPMKFQSPESFTLP[JDFMJʅOPTUFOPWMVNFOWMBLOB
WPEB
which means the reduced capability of the fi- QBOF»FWFEOPOJQPQPMOPNBSB[KBTOKFOIJUFSJOVʅJOLPWJUNFIB-
bres surface to form hydrogen bonds [8]. Raw OJ[FNBCTPSQDJKFPMKBWLBQPLPWBWMBLOB<>
fibres are extremely hydrophobic (oleophyl- %PMßJOB LBQPLB KF m NN
QSFNFS WMBLFO m ϥN %FCFMJ-
lic) with a high capacity of absorbing non-po- OBDFMJʅOFTUFOFKFPLSPHmϥN3B[NFSKFNFEEPMßJOPJOQSF-
lar liquids. NFSPNWMBLFO BTQFLUOPSB[NFSKF
KFPLSPH*[NFSKFOBOBUF[
The colour of raw kapok is yellow to brownish, OB USEOPTU LBQPLB KF
D/UFYm
.1B
:PVOHPW NPEVM
or whitish. Pure white colour is rare. Fibres are (1BJOQSFUSßOJSB[UF[FL
<>
free of odour, non-toxic, and non-allergic. They
have very soft touch, are fluffy, and extremely
light (approximately six times lighter than cot- 6QPSBCBLBQPLB
ton). Kapok contains 70–80% of air and pro-
vides excellent thermal and acoustic insula- /BKTUBSFKØJQBUFOUJ[BQSFEFMBWPLBQPLBTFHBKPW[BʅFUFLQSFKØOKFHB
tion. The absolute density of a kapok cell wall TUPMFUKBUFSPCSBWOBWBKPQPTUPQFLQSFEFOKBLBQPLB<>JOEPEBKB-
is 1.474 gcm–3, whilst the density of fibres by OKFLBQPLBQBQJSOJNBTJ[BJ[CPMKØBOKFMFTLB[JEOJIUBQFU<>,B-
considering about 74% of lumen is only 0.384 QPLØFEBOFTOBKQPHPTUFKFVQPSBCMKBKPLPUQPMOJMP[BSBEJOKFHPWJI
gcm–3 [14]. Kapok boasts with excellent buoy- dobrih toplotnoizolacijskih lastnosti, za zvočno izolacijo ter zaradi
ancy on water. When compressed, kapok fibres PEMJʅOFQMPWOPTUJ[BSFØJMOFKPQJʅFJOPCSPʅF7TPEPCOPTUJLBQPL
can support up to 36 times their own mass on TFHB OB QPESPʅKF UFIOJʅOJI UFLTUJMJK [B ĐMUSBDJKP OFQPMBSOJI TOPWJ
water. They are five times more buoyant than JOOBQPESPʅKFLPNQP[JUPW
cork and dry more quickly than cork. They pre- 5.1 Toplotna in zvočna izolacija
serve buoyancy even after the removal of wax- ,BQPL[BQPMOJMPPʅJTUJKP
QPTVØJKPJOOBSFßFKP-BILPHBQSJQSBWJKP
es [5]. OBJTUJTUSPKOJPQSFNJLPUCPNCBß4VSPWBWMBLOBNJLBKP[VQPSB-
Kapok fibres are 10–35 mm long, their diameter CP[SBLB
TBKNFIBOTLPNJLBOKFOJQSJQPSPʅMKJWP[BSBEJMPNMKFOKB
is 20–43 μm. The cell wall thickness is about 1– LSILJI WMBLFO JO OBTUBKBOKB WFMJLJI LPMJʅJO QSBIV 4FNFOB JO OB-
3 μm. The length-to-diameter ratio (aspect ratio) TUBMJQSBIPETUSBOKVKFKP[PETFTBWBOKFN
is about 720. The measured tensile strength of ,BQPL VQPSBCMKBKP [B QPMOJMP WJTPLPLBLPWPTUOJI JHSBʅ ÂF MFUB
kapok is 0.84 cNdtex–1 (93.3 MPa), Young’s mod- KF .BSHBSFUF 4UFJć [BʅFMB ØJWBUJ CMB[JOJDF [B CVDJLF W PCMJLJ
ule 4 GPa, and breaking elongation 1.2% [3]. TMPOʅLPW
LJKJIKFQP[OFKFSB[WJMBWJHSBʅFJ[ßBNFUBJOQMJØB
OBQPM-
OKFOFTLBQPLPN
CPNCBßFNBMJĐOPWPMOP<>1PMOJMBJ[LBQP-
5 Use of Kapok LBTP[BPLSPHMBßKBPECPNCBßOJIJO[BPLSPHMBßKBPE
WPMOFOJIQPMOJM
The oldest patents dealing with the processing of 1SJCMJßOPEPMFUBTPLBQPLWFMJLPVQPSBCMKBMJLPUQPMOJMP[BPEF-
kapok go back to the beginning of the last cen- KF
CMB[JOFJOQPIJØUWP
QP[OFKFTPHBWWFMJLJNFSJOBEPNFTUJMBWP-
tury and describe the method of kapok spin- UMBLFNJʅOBWMBLOBJOEBOFTJ[KFNOPESBHFQPMJVSFUBOTLFQFOF
LJTP
ning [16] and its adding to the paper mass to CPMKQSFQSPTUF[BQSPJ[WPEOKPJOOJTPUBLPIJUSPWOFUMKJWFLPULBQPL
improve the lustre of wallpapers [17]. Due to Zaradi odličnih toplotnoizolacijskih sposobnosti, lahkosti in nealer-
its good thermal insulating properties, kapok is HFOPTUJKFOFOBEPNFTUMKJW[BMKVEJ
LJOFQSFOBØBKPEPCSPTJOUFUJʅOJI
still today mostly used as a stuffing and for in- NBUFSJBMPW%BOFTTFVQPSBCBLBQPLBQPOPWOPQPWFʅVKF
JOTJDFS[B
sulation of sound, and due to its excellent buoy- OPUSBOKPPQSFNPKBIUJOʅPMOPWUFSLPUQPMOJMPCMB[JO[BWSUOPQPIJ-
ancy, for life jackets and lifebelts. Modern use ØUWP,BQPLTLVQBK[ESVHJNJDFMVMP[OJNJWMBLOJWPCMJLJWMBLOPWJ-
of kapok is spreading into the field of techni- OF[BQPMOJMBWOPUSBOKJPQSFNJPNPHPʅBEPCSPVSBWOBWBOKFWMBHFJO
cal textiles for filtration of non-polar substances OBSBWOPQSPUJCBLUFSJKTLP[BØʅJUPCSF[VQPSBCFLFNJLBMJK<>
and into composites. Zaradi odlične toplotnoizolacijske sposobnosti uporabljajo kapok
LPUJ[PMBDJKTLJNBUFSJBMNBOKØJIIMBEJMOJITJTUFNPW6QPSBCMKBKPHB
ĂFSNBMBOE"DPVTUJD*OTVMBUJPO UVEJ[BQPEMPHFTQBMOJIWSFʅ
SPLBWJDF[BSBWOBOKFTTVIJNMFEPN
Kapok, which is used for stuffing, must be JQE7QSFUFLMPTUJTPHBVQPSBCMKBMJUVEJ[BUPQMPUOPJ[PMBDJKPWPEP-
cleaned, dried and cut. It can be prepared on WPEOJIDFWJ
the same machinery as cotton. Raw fibres are 7PCMBʅJMJIHBVQPSBCMKBKPLPUQPMOJMP[BQPEMPHF
WLBUFSJI[BSB-
carded by using air because mechanical carding EJEPCSFUPQMPUOFJ[PMBDJKFJOOFBMFSHFOPTUJOBEPNFØʅBQFSKF
QVI
is not recommended due to breaking of brittle JOTJOUFUJLP
fibres and formation of large quantities of dust. ,BQPLVQPSBCMKBKPUVEJ[B[WPʅOPJ[PMBDJKPCJWBMOJIQSPTUPSPW
Seeds and dust are removed by suction.
Kapok is used as a stuffing for high quality toys. 5.2 Plovnost
Already in 1879 Margarete Steiff began to sew ,BQPLKFDFOKFOLPUQPMOJMP[BSFØJMOFKPQJʅF
SFØJMOFQBTPWFJOQSF-
pincushions in the form of elephants, and de- OPTOFQPOUPOF[B[BØʅJUPQSFEVUPQJUWJKP/FTUJTOKFOKBWBOTLJLBQPL
veloped them later into velvet and fleece toys MBILPOPTJmLSBUOPMBTUOPNBTP
JOEJKTLJLBQPLQBMFm
stuffed with kapok, cotton, or fine wool [18]. LSBUOPMBTUOPNBTP
EBTFOFQPUPQJɂFKBWBOTLJLBQPLQPUPQJKPW
A kapok stuffing is by about 50% lighter than WPEP
J[HVCMKBQMPWOPTU[FMPQPʅBTJEOFWOJUFTUKFQPLB[BMMF
a cotton stuffing and by about 30% lighter than J[HVCPQMPWOPTUJ1MPWOPTULBQPLBQSFEVQPSBCP[BSFØJMOFPCSP-
a wool stuffing. ʅFP[JSPNBKPQJʅF[BOFQMBWBMDFWFEOPQSFJ[LVØBKP7MBLOBEBKPW
Kapok had been widely used as a stuffing in NSFßPJ[ßJDFBMJLMFULPTLPWJOTLJNJPKBʅBOJNJSPCPWJUFSKPQPUP-
quilts, pillows, and upholstery until approxi- QJKPWTWFßPWPEPDNQPEHMBEJOP[BVS1PVSBIEPMPʅJKP
mately 1950 when it was substituted by hollow QMPWOPTUWMBLFO
UBLPEBTUFIUBKPWMBLOBJOOKJIPWPNBTPQSJNFSKB-
manmade fibres and today very expensive poly- KP[NBTPWMBLFOQSFEUFTUJSBOKFNɂFWTFCOPTUWPEFWLBQPLVOF
urethane foams which were much simpler for VTUSF[BQSFEQJTPN
WMBLFOOFVQPSBCJKP[BSFØJMOFKPQJʅF<>
manufacture and less flammable than kapok.
Since kapok is an excellent thermal insulator, 5.3 Sorpcijske sposobnosti
extremely light, and does not cause allergies, it ,BQPLKFQSJNFSFO[BĐMUSBDJKPPMKOJITVTQFO[JK%BOFTTPPMKOJĐM-
is practically irreplaceable for the people who USJ [B ĐMUSBDJKP PEQBEOJI WPEB LPWJOTLF
QSFISBNCFOF
UFLTUJMOF
the high content of acetyl groups, whilst high ca- LBDJKPWMBLFO
QSFEWTFN[BMLBMJ[JSBOKFNBMJBDFUJMJSBOKFN<
>
pability of oil absorption is attributed to a wide "MLBMJ[JSBOKF LBQPLB WQMJWB OB UPQPHSBGTLF TQSFNFNCF QPWSØKB
lumen of fibres. It has been noticed that oil pen- WMBLFOJOOBJ[CPMKØBOKFLSJTUBMOFTUSVLUVSFSB[UPQJOB/B0)
etrates through the fibre cell wall into its lumen, OF QPW[SPʅJ WJEOJI TQSFNFNC OB QPWSØKV LBQPLB
SB[UPQJ-
which is not the case with water. However, OB/B0)QBQPW[SPʅJSB[CSB[EBOKFQPWSØKBJOQPWFʅBOKFTQFDJĐʅ-
quick and efficient mechanism of oil absorption OFQPWSØJOFLBQPLB<>
LBSKFQPTMFEJDBPETUSBOJUWFIFNJDFMVMP[
has not been completely explained yet [21]. JOMJHOJOB7JTPLFLPODFOUSBDJKFBMLBMJKMBILPQPTMBCØBKPUFSNJʅOP
Kapok is suitable for filtration of oil suspen- PEQPSOPTU LBQPLB "DFUJMJSBOKF IJESPLTJMOJI TLVQJO [NBOKØB QP-
sions. Oil filters for filtration of wastewaters MBSOPTULBQPLBJOQPWFʅBBEIF[JWOPTUTIJESPGPCOPQPMJNFSOPNB-
discharged by metal, food, textile, leather, pet- USJDP,FNJʅOBSFBLUJWOPTUKF[BSBEJWJTPLFWTFCOPTUJIFNJDFMVMP[
rochemical, and other industries are today in lignina ter nižje kristaliničnosti, s katero je povezana dosto-
made of synthetic fibres, such as polypropyl- QOPTUIJESPLTJMOJITLVQJOOBQPWSØKVJOWBNPSGOJIQSFEFMJIWMB-
ene, polyester, or polyamide fibres. In compar- LFO
VʅJOLPWJUFKØBQSJLBQPLVLPUQSJLPOPQMKJ
TJTBMVJOKVUJ
ison with synthetic fibres, natural cellulosic fi- 1SJ QSJQSBWJ UFSNPTUBCJMOJI QPMJFTUSTLJI LPNQP[JUPW
PKBʅBOJI T
bres absorb higher quantities of oils, are better ULBOJOPJ[LBQPLBJOCPNCBßB ,1$0
TP[BJ[CPMKØBOKFBEIF[J-
oil filters, and are also biodegradable. Raw, un- KFWMBLFOTQPMJFTUSPNULBOJOPOBKQSFKNFSDFSJ[JSBMJW/B0)
treated kapok retains oil longer than kapok ex- QSJʅFNFSTPPETUSBOJMJWPTLFJOQFLUJO<>/BUF[OBUSEOPTUP[J-
tracted in ethanol or chloroform. Kapok se- SPNBNPEVMTUBTFTQPWFʅFWBOKFNLPMJʅJOFWMBLFOQPTMBCØBMB
J[-
lectively absorbs about 40 g of oil per gram of CPMKØBMB QB TUB TF VQPHJCOB USEOPTU JO VQPHJCOJ NPEVM 6QPSBCB
fibres from freshwater or seawater [21]. When UFILPNQP[JUPW[BQPDFOJTJMPTF[BßJUP
[BØPMTLF[HSBECFJOPIJØ-
the density of fibres arrangement is 0.02 gcm–3, KBKFØFQPTFCFKTNPUSOBWSFWOJIEFßFMBI
WLBUFSJIUBWMBLOBUVEJ
the capability of Diesel fuel absorption is 36 g QSJEPCJWBKP
of oil per gram of fibres. At a higher density of 5LBOJOFJ[,1$0TPQSJNFSOF[BPKBʅJUFWJ[PUBLUJʅOFHBQPMJQSP-
fibres arrangement, i.e. 0.09 gcm–3, the capaci- QJMFOBWLPNQP[JUJI[OJßKPNFIBOTLPUSEOPTUKP<>"MLBMJ[JSBOKF
ty of Diesel fuel absorption is only 7.9 g of oil JOBDFUJMJSBOKFULBOJOFJ[,1$0TUB[BSBEJ[OJßBOKBEFMFßBLSJTUBMJ-
per gram of fibres [15]. Oils, which are retained OFGB[FWQMJWBMJOB[OJßBOKFOBUF[OFUSEOPTUJLPNQP[JUBWQSJNFSKB-
in a filter, can be extracted either by squeezing WJTLFNJʅOPOFPCEFMBOPULBOJOP
or more efficiently by centrifuging where even
more than 83% of oil can be extracted; the ex- 5.5 Kapok v prehrani
tracted oil can be reused [22]. Zaradi odličnega vezanja olj so kapok uporabili tudi za selektivno iz-
Kapok is also very suitable for smaller, mobile MPʅBOKFOBTJʅFOJINBØʅPCJ[ʅMPWFØLFHBUFMFTB,BQPLOFWFßFWPEF
water/oil separators [22]. Another field of use [BUP JNB QSFEOPTU QSFE LPOWFODJPOBMOJNJ SBTUMJOTLJNJ WMBLOJ ,B-
is for pre-filtration of waters, which is followed QPL [NFMKFKP W QSBI JO HB EPEBKP LSVIV
QJØLPUPN UFS QPEPCOJN
by membrane filtration [15]. It can be efficient- QSFISBNCFOJN J[EFMLPN ,PU PMKOJ BCTPSCFS LBQPLPW QSBI MBILP
ly used for collecting spilled oil on the surface of VʅJOLVKF[ESBWJMOP%PEBOßJWJMPN OQSLSVIV
BMJTUJTOKFOWUBCMF-
rivers and seas [23]. UBIWUFMFTVWFßFPEWFʅOBPMKB OBTJʅFOFNBØʅPCOFLJTMJOF
<>
Fully biodegradable oil sorbents of non-polar /B5BKTLFNTPPQSBWJMJVTQFØOFSB[JTLBWFQSFEFMBWFLBQPLBWNJ-
substances can be manufactured from 100% krokristalino celulozo, ki v zadnjih letih prodira na področje pre-
kapok without additives (glues) by heating the ISBOFJOGBSNBDJKFLPUQPMOJMP
[HPTUJMPBMJTUBCJMJ[BUPS[BSBEJTWPKF
material to the glass transition temperature of Đ[JPMPØLFJOFSUOPTUJ
WBSOPTUJJOTUBCJMOPTUJ<>
the contained hemicelluloses (it depends on the
degree of hydration of these hemicelluloses, and 5.6 Predenje kapoka
it decreases by wetting) and by compressing the Kapok le redko predejo, saj so vlakna krhka ter zato zdržijo nizke
heated material. During heating at 90–120 °C OBUF[OFJOUPS[JKTLFTJMF7MBLOBJNBKP[BSBEJHMBELFHBQPWSØKBJO
hemicelluloses pass over into gel, and during WJTPLFWTFCOPTUJWPTLPWTMBCPLPIF[JWOPTU;BUPLBQPLWFEOPQSF-
compressing at the temperture 170–190 °C for EFKP W NFØBOJDBI [ ESVHJNJ WMBLOJ
QSFEWTFN [ CPNCBßFN 4SF-
a short time interlinking of fibres occurs. [24] In EJQSFKØOKFHBTUPMFUKBTPHBQSFEFMPWBMJMFWHSPCFQSFKFEPUFY
this way, the strength of the end product is in- WNFØBOJDBI[CPNCBßFNQBEPUFY1SFEQSFEFOKFNTPLBQPL
creased. Temperatures above 220 °C induce ox- PCEFMBMJ [ BMLPIPMPN
FUSPN BMJ ESVHJNJ UPQJMJ
T LBUFSJNJ TP PE-
idative degradation of fibres. The addition of no TUSBOJMJ WPTLF JO EPTFHMJ CPMK ISBQBWP QPWSØKF 1SFKP J[ LBQPLB TP
cotton. In the middle of the last century kapok -*.
55BOE)6"/(
9&WBMVBUJPOPGIZESPQIPCJDJUZPMF-
was processed only into coarse yarns up to 25 PQIJMJDJUZPGLBQPLBOEJUTQFSGPSNBODFJOPJMZXBUFSĐMUSBUJPO
tex, and in blends with cotton up to 50 tex. Pri- DPNQBSJTPOPGSBXBOETPMWFOUUSFBUFEĐCFSTIndustrial Crops
or to spinning kapok was treated with alcohol, and Products
WPM
Qm
ether or other solvents in order to remove wax- 8"554
8 $ .FUIPE PG GPSNJOH LBQPL ZBSO US Patent
es and to achieve a coarse surface. Kapok yarn 2,292,500"VHVTU
was used for fleeces and ribbons to which it im- -&/%-&
" 1BQFS NBEF GSPN LBQPL ĐCFS US Patent
parted a typical lustre [26]. 1,450,600"QSJM
The United Kingdom patent from 1940 de- $JOFBTUFTQIPUPTUSFBNIUUQXXXēJDLSDPNQIPUPT
scribes the method of producing pure kapok DJOFBTUF<BDDFTTFE>
yarn from kapok fibres [27]. The US patent 0#&34$)&-1
" .JYFE ĐCFS ēFFDF PS GBCSJD US Patent
from 1942 [16] describes the manufacture of 20070082574. 7"VHVTU
wrapped yarn containing a cotton, wool, or silk &MFDUSPOJD DPEF PG 'FEFSBM 3FHVMBUJPO IUUQFDGSHQPBDDFTT
core and a kapok wrapping. Kapok fibres were HPWDHJUUFYUUFYUJEY DFDGSSHOEJWWJFXUFYUOPEF
stuck to the yarn core by pressing and without JEOP<BDDFTTFE>
twisting. Then, individual yarns were inter- )03*
,
'-"7*&3
.&BOE,6("
4&YDFMMFOUPJMBCTPS-
twisted into the threads for knitting or weav- CFOULBQPL $FJCBQFOUBOESB-
ĐCFSĐCFSTUSVDUVSF
DIFNJ-
ing. Yarns in knitwear were crossly interlaced DBM DIBSBDUFSJTUJDT
BOE BQQMJDBUJPO Journal of Wood Science,
with a reinforcing thread in order to prevent
WPM
Qm
kapok from falling out. These kapok yarns were -*.
55BOE)6"/(
9&WBMVBUJPOPGLBQPL $FJCBQFO-
suitable for manufacture of beddings, clothing, UBOESB -
(BFSUO
BTBOBUVSBMIPMMPXIZESPQIPCJDPMFPQIJ-
insulating linings for airplanes, refrigerators, MJDĐCSPVTTPSCFOUGPSPJMTQJMMDMFBOVQChemosphere
WPM
etc. During processing of such wrapped yarns
Qm
excessive twisting of fibres and yarn had to be )6"/(
9 BOE -*.
5 5 1FSGPSNBODF BOE NFDIBOJTN PG
avoided. BIZESPQIPCJDPMFPQIJMJDLBQPLĐMUFSGPSPJMXBUFSTFQBSBUJPO
There were trials to improve the spinnability Desalination
WPM
Qm
and mechanical strength of kapok by treating "$)5&3&&,5&
. ) # BOE "%*."3(0/0
4 7 .F-
it in emulsions of silicone, acrylonitrile, mela- UIPEBOEEFWJDFGPSNBOVGBDUVSJOHNBUFSJBMTGSPNIZESPQIP-
mine, formaldehyde, urea, and vinyl monomers CJD IPMMPX OBUVSBM ĐCSFT
BOE VTF UIFSFPG WO 2008/004863
[28]. When applying synthetic coatings, it is A1KBOVBS
important that penetration of the emulsion into ,)"/
&
,)"0%)*3
4 BOE 3058*30/
1 1PMZDZDMJD
the fibre lumen is prevented. The treated fibres BSPNBUJD IZESPDBSCPO SFNPWBM GSPN XBUFS CZ OBUVSBM ĐCFS
obtain coarse, unequal wavelike surface, which TPSQUJPOWater Environmental Research
WPM
Qm
improves the spinning properties, elasticity, and
water-resistance of kapok fibres. ,0ɂ&7"3
'Tekstilne surovine-KVCMKBOB%;4
The Japanese patent from 2001 deals with the 480:&3
+%1SPDFTTPGUSFBUJOHLBQPL641BUFOU
yarns in blends containing up to 20% of kapok, +BOVBS
and the fabrics made from such yarns, which 4",":"/(*
41SPDFTTPGJNQSPWJOHQSPQFSUJFTPGLBQPLĐ-
exhibit good fastness to light, whiteness, low CFSBOEMJLFĐCFSTBOEUFYUJMFNBUFSJBMTNBEFUIFSFPGUS Pa-
weight, better thermal insulating properties, hy- tent 3,032,855. 8.BZ
groscopicity, and good dyeability [29]. /"(")"36
:BOE/03*0
"'JCFSTUSVDUVSFNJYFEXJUI
In 2007 Ensheng Li and Longquan Xia (Kita- LBQPLTFFEIBJSĐCFSBOEDMPUIJOHQSPEVDUVTJOHUIFTBNFJP
jska) took out a patent for the kapok ring spin- 2001348743, 21%FDFNCFS
ning method. The initial raw material is the &/4)&/(
-
BOE-0/(26"/
9"NFUIPEGPSQSPEVDJOH
blend of kapok (20–80 wt.%) with cotton or LBQPLTDSJCCMFECZSJOHTQJOOJOHEP 1867763 A2
%FDFN-
other fibres. The fibre blend is carded two times, CFS
after that it is drawn two times and spun. The .8"*,".#0
-:BOE"/4&--
.1
+VOF
$IF-
breaking force of the yarn 25.36 tex was 275 NJDBMNPEJĐDBUJPOPGIFNQ
TJTBM
KVUF
BOELBQPLĐCFSTCZBM-
cN, its tenacity 10.7 cNdtex–1, and its breaking LBMJ[BUJPOJournal of Applied Polymer Science
WPM
Q
elongation 6.6% [30]. m
6 Conclusion .8"*,".#0
- : BOE "/4&--
. 1 ĂF FćFDU PG DIF-
NJDBMUSFBUNFOUPOUIFQSPQFSUJFTPGIFNQ
TJTBM
KVUFBOELB-
Kapok is a biodegradable organic fibre, which QPLGPSDPNQPTJUFSFJOGPSDFNFOUAngewandte Makromoleku-
can compete with synthetic materials also lare Chemie
WPM
Qm
in terms of price. Its good thermal insulating &*$))03/
4 +
#"*--*&
$ "
;"'&*30106-04
/
properties make kapok suitable for stuffing pil- .8"*,".#0
- :
"/4&--
. 1
%6'3&4/&
"
&/-
lows, clothing, toys, etc., its good buoyancy on 58*45-&
, .
)&33&3"'3"/$0
1 +
&4$".*--"
water makes it suitable for lifejackets, mat- ($
(300.
-
)6()&4
.
)*--
$
3*"-4
5(
BOE
tresses, and other water-safety equipment, and 8*-%
1.3FWJFX$VSSFOUJOUFSOBUJPOBMSFTFBSDIJOUPDFMMV-
its good sorptivity and antimicrobial prop- MPTJDĐCSFTBOEDPNQPTJUFTJournal of Materials Science
erties make it suitable for medical purposes. WPM
Qm
A high content of waxes, inorganic substanc- .8"*,".#0
-:BOE#*4"/%"
&5/ĂFQFSGPSNBO-
es and acethyl groups in the primary cell wall DF PG DPUUPOLBQPL GBCSJDQPMZFTUFS DPNQPTJUFT Polymer Te-
imparts to kapok fibres hydrophobic proper- sting
WPM
Qm
ties, which are exhibited in a low contact an- .8"*,".#0
- :
."3564$&--*
& BOE "7&--"
.
gle with various oils and a high contact angle ,BQPLDPUUPO GBCSJDQPMZQSPQZMFOF DPNQPTJUFT Polymer Te-
with water. The use of kapok for oil sorbents sting
WPM
Qm
is possible without previous chemical treat- ."460
, ,BQPL QMBOU ĐCFS QPXEFSDPOUBJOJOH GPPE JP
ment of fibres. Oil sorbents made of kapok are 2005013186
+BOVBSZ
a price effective alternative to synthetic sorb- 467"$)*55"/0/5
4 BOE 4655*1)0/1"3/*5
,
ents. A wide lumen (about 74% of a fibre) en- .JDSPDSZTUBMMJOFDFMMVMPTFGSPNLBQPLThe Fourth Asia Paci-
ables retention of high amounts of oils, which fic Conference on Sustainable Energy and Environmental Tech-
can be reused. nologies
.JF
+BQBO
.BZ
Kapok can be bleached and dyed. However, due
to low strength, smooth surface, and too short
length of its fibres, kapok has a low spinnability,
and cannot be, in general, spun by using con-
ventional spinning methods. No special technol-
ogy for kapok processing is available. In addi-
tion to high flammability, brittleness, and lack
of elasticity, it is also too short length and low
cohesivity of fibres, which impedes wider use of
kapok in the field of clothing.