CHEMISTRY SRI VIDYA ARADHANA ACADEMY, Latur

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Subject : CHEMISTRY ASSIGNMENT - 02 Prof. Jagdale Sir
01. Normal boiling point (TN) is defined as the temperature 06. The elevation in boiling point of a solution of 13.44 g
when V.R of liquid becomes equal to 1 atm and of CuCl2 (molecular weight = 134.4, Kb = 0.52 K
standard boiling point (Ts) is defined as the temperature molality–1) in 1 kg water using the following information
when V.P of liquid becomes equal to 1 bar. Which will be:
one is not conect if water is considered? 1) 0.16 2) 0.05
1) TN = 100°C 2) TS > 100°C 3) 0.1 4) 0.2
3) TS < 100°C 4) TS < TN
07. A solution of urea in water has boiling point of
02. A solution containing 28 g of phosphorus in 315 g 100.15°C. Calculate the freezing point of the same
CS2 (b.p. 46.3°C) boils at 47.98°C. If Kb for CS2 is solution if Kf and Kb for water are 1.87 K kgmol–1
2.34 K kg mol–1. The formula of phosphorus is (at. and 0.52 K kg mol–1 respectively
mass of P = 31). 1) – 0.54°C. 2) – 0.44°C.
1) P6 2) P4
3) – 0.64°C. 4) – 0.34°C.
3) P3 4) P2
08. Which will have largest Tb?
03. Elevation in boiling point of an aqueous solution of a
1) 180 g glucose in 1 kg water
non-electrolyte solute is 2.01°. What is the depression
in freezing point of this solution? 2) 342 g sucrose in 1,000 g water

Kb (H2O) = 0.52° mol–1 kg 3) 18 g glucose in 100 g water

Kf (H2O) = 1.86° mol–1 kg 4) 65 g urea in 1 kg water
1) 7.17° 2) 0.52° 09. An aqueous solution of glucose boils at 100.01°C.
3) 3.57° 4) 0.93° The molal elevation constant for water is 0.5 K mol–1
kg. The number of molecules of glucose in the solution
04. Y g of a non-volatile solute of molar mass Mis dissolved containing 100 g of water is
in 250 g of benzene. If Kb is molal elevation constant,
1) 6.023 × 1023 2) 6.023 × 1022
the value of T is given by:
1) 1.34 K 2) 0.98 K 3) 12.046 × 1020 4) 12.046 × 1023
b b
3) 2.40 Kb 4) K b 10. The molal boiling point constant for water is 0.513°C
kg mol–1. When 0.1 mole of sugar is dissolved in 200
05. 0.15 g of a substance dissolved in 15 g of solvent
ml of water, the solution boils under a pressure of one
boiled at a temperature higher by 0.216°C than that
atmosphere at
of the pure solvent. Calculate the molecular weight of
the substance. Molal elevation constant for the solvent 1) 100.513°C
is 2.16°C. 2) 100.0513°C
1) 216 2) 100 3) 100.256°C
3) 178 4) None of these 4) 101.025°C

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CHEMISTRY SRI VIDYA ARADHANA ACADEMY, Latur
11. The amount of urea to be dissolved in 500 cc of water 14. Two elements A and B from compounds having
(Kf = 1.86) to produce a depression of 0.186°C in formula AB2 and AB4, when dissolved in 20 g benzene,
the freezing point is: 1 g of AB2 lowers the freezing point by 2.3K . Whereas
1) 9 g 1 g of AB4 lowers it by 1.3K Kf of benzene is 5.1
K.Kg mol–1
2) 6 g
Calculate atomic weight of A and B
3) 3 g 1) cant predicted
4) 0.3 g 2) 42.6, 25.59
12. Ethylene glycol is used as an antifreeze in a cold climate. 3) 30, 60
Mass of ethylene glycol which should be added to 4 4) 25.59, 42.6
kg of water to prevent it from freezing at – 6°C will 15. How many moles of sucrose should be dissolved in
be (K- for water = 1.86 K kg mol–1 and molar mass 500g of water so as to get a solution which has a
of ethylene glycol = 62 g mol–1) difference of 104oC between boiling point and freezing
point Kf 1.86 Kkgmol–1, Kb 0.52KKgmol–1
1) 800 g
1) 1.68 2) 1.492
2) 204.30 g 3) 8.4 4) 0.840
3) 400.00 g 16. How many grams of sucrose should be dissolved in
4) 304.60 g 100 g water in order to produce a solution with 105oC
difference between the boiling point and freezing point
13. A solution containing 62 g ethylene glycol in 250 g
Kf 1.86 Kkgmol–1 Kb 0.52KKgmol–1
water is cooled to –10oc . If Kf for water 1.86 K.Kg
mol–1. Then calculate amount of water seperated as 1) 34.2 g 2) 72g
3) 342 g 4) 460g
ice
17. How much ethylene glycol must be added to 1 lit
1) 250
2) 186 water, so that solution will not freeze at –4oF
3) 64 1) 6 g 2) 60g
4) 32 3) 663 g 4) 100g

ANSWER-KEY
01. 2) 02. 2) 03. 3) 04. 2) 05. 2)
06. 1) 07. 1) 08. 4) 09. 3) 10. 3)
11. 3) 12. 1) 13. 3) 14. 4) 15. 4)
16. 2) 17. 3)
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