Копия hydratecpa

Spreadsheet for calculating hydrate dissociation
In general:
Cells with text or numbers in red can be changed by the user.
TIPS
The spreadsheet can be set for automatic recalculation of all worksheets using Tools\Options\Calculation\Automatic
However, this can be slow. Setting Tools\Options\Calculation to manual allows user to determine which worksheets are recalc
F9 updates all
Shift F9 only updates the current worksheet
To see effect of fluids giving different hydrate structures copy and paste the following into the hydrocarbon composition in "Co
TEST compositions
Hydrate2 Hydrate1 Mixed
2.1202 0 2.1202
0.65007 0 0.65007
92.369 100 2000
3.4103 0 3.4103
0.86009 0 0.86009
0.14001 0 0.14001
0.21002 0 0.21002
7.00E-02 0 7.00E-02
6.00E-02 0 6.00E-02
0 0 0
0 0 0
0 0 0
0 0 0
0.11001 0 0.11001
10 10 10
ation\Automatic
hich worksheets are recalculated
arbon composition in "Composition" worksheet

Water
Salt present (None, TDS, Ion(Ion Analysis), Salt(Salt analysis)) Salt
Salt Salt Model Electrolyte
Ion analysis mg/l Total dissolved solid TDS)

Na 62438 1.08E+04 mg/l
Ca 7500
Mg 3130
K 1022 Ion equivalent
Sr 0 TDS Ion Salt
Ba 0 Na+ #ADDIN? #ADDIN? #ADDIN?
Fe 9 CL- #ADDIN? #ADDIN? #ADDIN?
Cl 119200 K+ #ADDIN? #ADDIN? #ADDIN?
SO4 225 Ca++ #ADDIN? #ADDIN? #ADDIN?
HCO3 112
Br 0
Ions to be added to water

Salt Analysis mass frn Na+ #ADDIN?
NaCl 0.05 CL- #ADDIN?
CaCl2 0.03 K+ #ADDIN?
MgCl2 0 Ca++ #ADDIN?
KCl 0.02
SrCl2 0
BaCl2 0
FeCl2 0
Na2SO4 0
NaHCO3 0.02
NaBr 0
Hydrate calculations with no inhibitor present
Salt model Electrolyte
Fluid composition Hydrate dissociation temperature for given pres

Moles Hydrate2
1 #ADDIN? 2.1202 Pressure #ADDIN? 90
2 #ADDIN? 0.65007 Temperature #ADDIN? #ADDIN?
3 #ADDIN? 92.369
4 #ADDIN? 3.4103 If result is # followed by text then that hydrate structure is not present
5 #ADDIN? 0.86009 Hydrate dissociation pressure for given temper
6 #ADDIN? 0.14001 Hydrate2
7 #ADDIN? 0.21002 Pressure #ADDIN? #ADDIN?
8 #ADDIN? 0.070007 Temperature #ADDIN? 4
9 #ADDIN? 0.060006
10 #ADDIN? 0 If result is # followed by text then that hydrate structure is not present
11 #ADDIN? 0
12 #ADDIN? 0 Amount of hydrate formed at given conditions
13 #ADDIN? 0 Hydrate2
14 #ADDIN? 0.11001 #ADDIN?
15 #ADDIN? 10 Temperature #ADDIN? 4 #ADDIN?
16 #ADDIN? #ADDIN? Pressure #ADDIN? 50
17 #ADDIN? #ADDIN?
18 #ADDIN? #ADDIN?
19 #ADDIN? #ADDIN?
Total #ADDIN?
Hydrate Curve
Calculation of dissociation temperature as a function of pressure Plot Specification
Pressure Hydrate2 Hydrate1 Starting pressure 1
#ADDIN? #ADDIN? #ADDIN? Step 20
1 #ADDIN? #ADDIN?
21 #ADDIN? #ADDIN?
41 #ADDIN? #ADDIN?
61 #ADDIN? #ADDIN?
Hydrate dissociation
no inhibition
81 #ADDIN? #ADDIN?
101 #ADDIN? #ADDIN? 500
Pressure bar

Hy-
141 #ADDIN? #ADDIN? drate2
400
161 #ADDIN? #ADDIN?
201 #ADDIN? #ADDIN?
300
221 #ADDIN? #ADDIN?
281 #ADDIN? #ADDIN?
341 #ADDIN? #ADDIN?
50
361 #ADDIN? #ADDIN?
401 #ADDIN? #ADDIN? 0 5 10 15 20
421 #ADDIN? #ADDIN? Temperature degC
441 #ADDIN? #ADDIN?
If result is # followed by text then that hydrate structure is not present
rature for given pressure
Hydrate1
#ADDIN?
e structure is not present

ure for given temperature
Hydrate1
#ADDIN?
at given conditions
Hydrate1
#ADDIN?
#ADDIN?
PLOT
#ADDIN? Pressure Hydrate2 Hydrate1
bar degC #ADDIN?
1 #N/A #N/A
21 #N/A #N/A
41 #N/A #N/A
ciation 61 #N/A #N/A
on
81 #N/A #N/A
101 #N/A #N/A
121 #N/A #N/A
141 #N/A #N/A
161 #N/A #N/A
181 #N/A #N/A
201 #N/A #N/A
221 #N/A #N/A
241 #N/A #N/A
261 #N/A #N/A
281 #N/A #N/A
301 #N/A #N/A
321 #N/A #N/A
341 #N/A #N/A
361 #N/A #N/A
381 #N/A #N/A
15 20 25 401 #N/A #N/A
egC 421 #N/A #N/A
441 #N/A #N/A
Hydrate calculations with methanol present
Fluid composition Concentration of methanol in aqueous stream

moles Methanol MW #ADDIN?
1 #ADDIN? 2.1202 Methanol 15 wt% #ADDIN?
2 #ADDIN? 0.65007
3 #ADDIN? 92.369 Hydrate dissociation temperature for a given press
8 #ADDIN? 0.070007 Hydrate dissociation pressure for given temperatu
10 #ADDIN? 0 Pressure #ADDIN? #ADDIN?
11 #ADDIN? 0 Temperature #ADDIN? 4
15 #ADDIN? 10 mol
16 #ADDIN? #ADDIN? Temperature DegC 0 #ADDIN?
17 #ADDIN? #ADDIN? Pressure Bar 100
18 #ADDIN? #ADDIN?
19 #ADDIN? #ADDIN?
20 #ADDIN? #ADDIN?
Total #ADDIN?
Hydrate Curve
Hydrate dissociation temperature calculated as a function of pressure
No MeoH MeOH No MeOH MeOH

Pressure Hydrate2 Hydrate2 Hydrate1 Hydrate1
#ADDIN? #ADDIN? #ADDIN? #ADDIN? #ADDIN? Hydrate dissociation
1 #N/A #ADDIN? #N/A #ADDIN? with methanol
21 #N/A #ADDIN? #N/A #ADDIN?
500
Pressure Bar
450
81 #N/A #ADDIN? #N/A #ADDIN? Hydrate2
101 #N/A #ADDIN? #N/A #ADDIN? 400 Hydrate2 with MeOH
350 Hydrate1
161 #N/A #ADDIN? #N/A #ADDIN? Hydrate1 with MeOH
300
201 #N/A #ADDIN? #N/A #ADDIN? 250
100
-50 -40 -30 -20 -10 0
Temperature DegC
100
50
0
401 #N/A #ADDIN? #N/A #ADDIN? -50 -40 -30 -20 -10 0
421 #N/A #ADDIN? #N/A #ADDIN? Temperature DegC
in aqueous stream
mol%
rature for a given pressure

Hydrate1
#ADDIN?
Hydrate1
#ADDIN?

at given conditions
Hydrate1
mol
#ADDIN?
MeOH
Hydrate2
Hydrate dissociation ###
with methanol ###
###
###
###
Hydrate2 ###
Hydrate2 with MeOH ###
###
Hydrate1
###
###
###
###
###
###
###
###
###
###
###
###
-30 -20 -10 0 10 20 30
Temperature DegC
-30 -20 -10 0 10 20 30 ###
Temperature DegC ###
###
Hydrate calculations to determine the amount of methanol required to suppress h
Input stream
mol% Tol feed Hydrate2 suppression
1 #ADDIN? 2.1202 0 2.1202
2 #ADDIN? 0.65007 0 0.65007
3 #ADDIN? 92.369 0 92.369
4 #ADDIN? 3.4103 0 3.4103
5 #ADDIN? 0.86009 0 0.86009
6 #ADDIN? 0.14001 0 0.14001
7 #ADDIN? 0.21002 0 0.21002
8 #ADDIN? 7.00E-02 0 0.070007
9 #ADDIN? 6.00E-02 0 0.060006
10 #ADDIN? 0 0 0
11 #ADDIN? 0 0 0
12 #ADDIN? 0 0 0
13 #ADDIN? 0 0 0
14 #ADDIN? 0.11001 0 0.11001
15 #ADDIN? 10 0 10
16 #ADDIN? #ADDIN? 0 #ADDIN?
20 #ADDIN? 0 1 #ADDIN?
Hydrate Curve
hydrate dissociation temperature as a function of pressure with sufficient methanol to suppress hydrate formation at given
CALC CALC
No MeoH MeOH No MeOH MeOH
#ADDIN? #ADDIN? #ADDIN? #ADDIN? #ADDIN?
1 #N/A #ADDIN? #N/A #ADDIN? Hydrate dissoc
21 #N/A #ADDIN? #N/A #ADDIN? with methanol inhibition fo
Hydrate2
Hydrate2 with
Press/bar
400 MeOH
Hydrate1
141 #N/A #ADDIN? #N/A #ADDIN? 350 Hydrate1 with
MeOH
250
100
401 #N/A #ADDIN? #N/A #ADDIN? -50 -40 -30 -20 -10
421 #N/A #ADDIN? #N/A #ADDIN? Temp/Deg
50
0
-50 -40 -30 -20 -10
Temp/Deg

quired to suppress hydrates at given conditions
Input stream MW methanol #ADDIN?

Hydrate1 suppression Amount of methanol to suppress hydrate2 Amount of methanol to su
2.1202
0.65007 Conditions Conditions
92.369 Temperature DegC 4 Temperatu
3.4103 Pressure Bar 100 Pressure
0.86009
0.14001 Methanol mole #ADDIN? to total stream Methanol
0.21002 1.007819
0.070007 Methanol to be added in relation to water Methanol to be added in r
0.060006 (Mass MeOH/Mass H20+Mass MeOH)*100 (Mass MeOH/Mass H20+M
0 #ADDIN? wt% #ADDIN?
0
0 If the result of calculating the amount of methanol to suppress a hydrate is #NULL
0 this indicates that particular hydrate structure is not formed
0.11001
10
#ADDIN?
#ADDIN?
#ADDIN?
#ADDIN?
#ADDIN?
ess hydrate formation at given conditions
th methanol inhibition for set conditions
Hydrate2
Hydrate2 with
MeOH
Hydrate1
Hydrate1 with
MeOH
-30 -20 -10 0 10 20 30

Temp/DegC
-30 -20 -10 0 10 20 30
Temp/DegC
Amount of methanol to suppress hydrate1
Conditions
DegC 12
Bar 90
mole #ADDIN? to total stream
Methanol to be added in relation to water

(Mass MeOH/Mass H20+Mass MeOH)*100
wt%
Hydrate calculations with MEG present
Fluid composition Concentration of MEG in aqueous stream

moles MEG MW #ADDIN?
1 #ADDIN? 2.1202 MEG 15 wt% #ADDIN?
2 #ADDIN? 0.65007
3 #ADDIN? 92.369 Hydrate dissociation temperature for a given press
8 #ADDIN? 0.070007 Hydrate dissociation pressure for given temperatu
10 #ADDIN? 0 Pressure #ADDIN? #ADDIN?
11 #ADDIN? 0 Temperature #ADDIN? 4
15 #ADDIN? 10 mol
16 #ADDIN? #ADDIN? Temperature DegC -3 #ADDIN?
17 #ADDIN? #ADDIN? Pressure Bar 50
18 #ADDIN? #ADDIN?
19 #ADDIN? #ADDIN?
20 #ADDIN? #ADDIN?
Hydrate Curve
Hydrate dissociation temperature calculated as a function of pressure
No MEG MEG No MEG MEG

#ADDIN? #ADDIN? #ADDIN? #ADDIN? #ADDIN? Hydrate dissociation
1 #N/A #ADDIN? #N/A #ADDIN? with MEG
500
Pressure Bar
450
101 #N/A #ADDIN? #N/A #ADDIN? 400 Hydrate2 with MeOH
350 Hydrate1
161 #N/A #ADDIN? #N/A #ADDIN? Hydrate1 with MeOH
300
100
-50 -40 -30 -20 -10 0
Temperature DegC
100
50
0
401 #N/A #ADDIN? #N/A #ADDIN? -50 -40 -30 -20 -10 0
421 #N/A #ADDIN? #N/A #ADDIN? Temperature DegC
ueous stream
mol%
rature for a given pressure

Hydrate1
#ADDIN?
Hydrate1
#ADDIN?

at given conditions
Hydrate1
mol
#ADDIN?
MEG
Hydrate2
Hydrate dissociation ###
with MEG ###
###
###
###
Hydrate2 ###
###
Hydrate1
###
###
###
###
###
###
###
###
###
###
###
###
-30 -20 -10 0 10 20 30
Temperature DegC
-30 -20 -10 0 10 20 30 ###
Temperature DegC ###
###
Hydrate calculations to determine the amount of MEG required to suppress hydra
Input stream
mol% Tol feed Hydrate2 suppression
1 #ADDIN? 2.1202 0 2.1202
2 #ADDIN? 0.65007 0 0.65007
3 #ADDIN? 92.369 0 92.369
4 #ADDIN? 3.4103 0 3.4103
5 #ADDIN? 0.86009 0 0.86009
6 #ADDIN? 0.14001 0 0.14001
7 #ADDIN? 0.21002 0 0.21002
8 #ADDIN? 0.070007 0 0.070007
9 #ADDIN? 0.060006 0 0.060006
10 #ADDIN? 0 0 0
11 #ADDIN? 0 0 0
12 #ADDIN? 0 0 0
13 #ADDIN? 0 0 0
14 #ADDIN? 0.11001 0 0.11001
15 #ADDIN? 10 0 10
20 #ADDIN? 0 1 #ADDIN?
Hydrate Curve
hydrate dissociation temperature as a function of pressure with sufficient MEG to suppress hydrate formation at given cond
CALC CALC
No MEG MEG No MEG MEG
#ADDIN? #ADDIN? #ADDIN? #ADDIN? #ADDIN? Hydrate diss
1 #N/A #ADDIN? #N/A #ADDIN? with MEG inhibition fo
Hydrate2 with
Press/bar
400 MeOH
Hydrate1 with
141 #N/A #ADDIN? #N/A #ADDIN? MeOH
300
200
361 #N/A #ADDIN? #N/A #ADDIN? -50 -40 -30 -20 -
381 #N/A #ADDIN? #N/A #ADDIN? Temp

ed to suppress hydrates at given conditions
Input stream MW MEG #ADDIN?

Hydrate1 suppression Amount of MEG to suppress hydrate2 Amount of MEG to suppre
2.1202
0.65007 Conditions Conditions
92.369 Temperature DegC 5 Temperatu
3.4103 Pressure Bar 80 Pressure
0.86009
0.14001 MEG mole #ADDIN? to total stream MEG
0.21002 0.661299
0.070007 MEG to be added in relation to water MEG to be added in relati
0.060006 (Mass MEG/Mass H20+Mass MEG)*100 (Mass MEG/Mass H20+Ma
0 #ADDIN? % #ADDIN?
0
0 If the result of calculating the amount of MEG to suppress a hydrate is #NULL
0 this indicates that particular hydrate structure is not formed
0.11001
10
#ADDIN?
#ADDIN?
#ADDIN?
#ADDIN?
#ADDIN?
hydrate formation at given conditions
with MEG inhibition for set conditions
Hydrate2
Hydrate2 with
MeOH
Hydrate1
Hydrate1 with
MeOH
40 -30 -20 -10 0 10 20 30

Temp/DegC
Amount of MEG to suppress hydrate1
Conditions
DegC 12
Bar 90
mole #ADDIN? to total stream
MEG to be added in relation to water

(Mass MEG/Mass H20+Mass MEG)*100
%

Копия hydratecpa

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Копия hydratecpa

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Spreadsheet for calculating hydrate dissociation

arbon composition in "Composition" worksheet

Salt Salt Model Electrolyte

Ion analysis mg/l Total dissolved solid TDS)

Ions to be added to water

Fluid composition Hydrate dissociation temperature for given pres

121 #ADDIN? #ADDIN? 450

e structure is not present

e structure is not present

Fluid composition Concentration of methanol in aqueous stream

No MeoH MeOH No MeOH MeOH

rature for a given pressure

e structure is not present

If result is # followed by text then that hydrate structure is not present

Input stream MW methanol #ADDIN?

ess hydrate formation at given conditions

-30 -20 -10 0 10 20 30

mole #ADDIN? to total stream

Methanol to be added in relation to water

Fluid composition Concentration of MEG in aqueous stream

No MEG MEG No MEG MEG

rature for a given pressure

e structure is not present

If result is # followed by text then that hydrate structure is not present

Input stream MW MEG #ADDIN?

hydrate formation at given conditions

40 -30 -20 -10 0 10 20 30

mole #ADDIN? to total stream

MEG to be added in relation to water

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