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Olevel-Chemistry Practicals PDF
Olevel-Chemistry Practicals PDF
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“The purpose of education is to replace an empty mind with the new one”
1. VOLUMETRIC ANALYSIS
NECTA 2012
1. You are provided with the following solutions;
TZ: Containing 3.5g of impure sulphuric acid in 500 cm3 of solution;
LO: Contain 4g of sodium hydroxide in 1000 cm3 of solution
Phenolphthalein and methyl orange indicators.
Questions
a) i/ What is the suitable indicator for the titration of the given solution? Give a
reason for your answer
ii/ write a balanced chemical equation for the reaction between TZ and LO.
iii/ Why it is important to swirl or shake the contents of the flask during the
addition of acid?
b) Titrate the acid (in a burette) against the base (in a conical flask) using two drops
of your indicator and obtained three titre values.
c) i/ Cm3 of acid required Cm3 of base for complete reaction.
ii/ Showing your procedure clearly, calculate the percentage purity of TZ.
SOLUTION
a) i/ The suitable indicator fo the titration of the given solution is either of the two
indicators, it can be either methyl orange (mo) or phenolphthalein (p. o. p) indicators
because the titration involves strong acid against strong base.
iii/ It is important to swirl or shake the contents of the flask during the addition of the
acid to allow reaction to take place properly or completely as well as allowing easy
recognition of sharp end point during titration.
b) Table of results
(cm3)
Va = 25.16 cm3
c) i/ 25.16 cm3 of acid solution required 25.00 cm3 of base for complete reaction.
Given that
= 4g/dm3
40g/mol
Ma Va = na
Mb Vb nb
Where:
Ma = Molarity of Acid (TZ)
Va =Volume of Acid (TZ)
Mb =Molarity of Base (LO)
Vb=Volume of Base (LO)
Na =Number of Acid (TZ)
Nb =Number of Base (LO)
We have
Ma = ?
Va =25.16
Mb = 0.1
Vb=25
Nb =2
Na =1
Na= 1 Nb = 2
Ma Va = na
Mb Vb nb
Ma = Mb X Vb X na
Va X nb
Ma = 0.1 X 25 X 1
25.16 X 2
Ma = 0.05M
Then,
Therefore
Procedure:
Pipette 20 cm3 or 25cm3 of solution BB into a titration flask. Add two drops of POP
indicator. Titrate solution BB against solution AA from the burette until a colour change is
observed. Note the burette reading. Repeat the procedure to obtain three more readings.
Record your results as shown bellow.
a) Table of results
i) Burette readings
Titration Pilot 1 2 3
Final reading (cm3)
Intial reading (cm3)
SOLUTION
a) Table of results
i) Burette readings
Titration Pilot 1 2 3
Final reading (cm3) 24.00 48.10 23.70 47.00
Intial reading (cm3) 0.00 24.00 0.00 23.70
Va = 23.70 cm3
c)
(i) Molarity of solution AA
Where
Mc = Molarity of conc. Acid (AA)
Vc = Volume of conc. Acid (AA)
Md = Molarity of diluted Acid (AA)
Vd = Volume of diluted or final volume of Acid AA
We have
Mc =1M
Vc =100cm3
Vd =1000cm3
Md= ?
McVc = MdVd
1Mx100cm3 = Md x 1000cm3
Md = 1M x 100cm3
1000cm3
= 0.1M
Ma Va = na
Mb Vb nb
Where:
Ma = Molarity of Acid (AA)
Va =Volume of Acid (AA)
Mb =Molarity of Base (BB)
Vb=Volume of Base (BB)
Na =Number of Acid (AA)
Nb =Number of Base (BB)
Na= 1 N b= 1
We have
Ma = 0.1
Va =23.70
Mb = ?
Vb=25
Nb =1
Na =1
Mb = Ma X VaX nb
Vb X na
Mb = 0.1 X 23.70 X 1
25X 1
Mb = 0.0948 M = 0.1M
Conc = 0.1 x 40
= 4 g/dm3
Procedure:
Put the acid solution into the burette. Pipette 20 cm3 or 25cm3 of solution K into a titration
flask. Add few drops of methyl orange indicator. Titrate this base solution against the acid
solution until an end point is reached. Record your results as shown bellow and Repeat the
titration.
a) Table of results
Titration Pilot 1 2 3
Final reading (cm3)
Intial reading (cm3)
a) i/ The volume of acid solution E needed for complete neutralization was Cm3
ii/ Write down the balanced chemical equation for the reaction
b) Calculate the:
i/ Molarity of Acid solution E
ii/ Molarity of base solution K
iii/ Find the value of water crystallization in Na2CO3. XH2O
SOLUTION
a) Table of results
Titration Pilot 1 2 3
Final reading (cm3) 20.00 39.80 19.60 40.00
Intial reading (cm3) 0.00 20.00 0.00 20.00
Va = 19.93 cm3
b) i/ The colour change at the end point was from Yellow to pink
C) Calculate the;
Conc of E = 3.65g
1dm3
Conc of E= 3.65g/dm3
Therefore;
Molarity = 3.65g/dm3
36.5g/mol
Ma Va = na
Mb Vb nb
Where:
Ma = Molarity of Acid (E)
Va =Volume of Acid (E)
Mb =Molarity of Base (K)
Vb=Volume of Base (K)
Na =Number of Acid (E)
Nb =Number of Base (K)
Na= 2 N b= 1
We have
Ma = 0.1M
Va =19.93 cm3
Mb = ?
Vb=20.00 cm3
Nb =1
Na =2
Mb = Ma X VaX nb
Vb X na
Mb = 0.1 X 19.93 X 1
20X 2
Mb = 0.0498
Mb = 0.05 M
Then
Find the molar mass of Na2CO3. XH2O
From the formula
Molarity (mol/dm3) = Conc in g/dm3
Molar mass g/mol
Then
But
Concentration of solution K = Mass
Volume
Conc of k = 3.575g
0.25dm3
Conc of K= 14.3g/dm3
Also
Molar mass (g/mol) = Conc in g/dm3
Molarity (mol/dm3)
= 286g/mol
Molar mass of Na2CO3.xH2O is 286g/mol
Therefore,
Na2CO3.xH2O = 286
(23 X 2 +12+16X3 +(2+16) = 286
46 + 12 + 48 + 18x
106 + 18x = 286
18x = 286- 106
18x = 180
18x =180
18 18
X = 10
Procedure;
(i) Measure exactly 75 cm3 of acid by using measuring cylinder and then transfer it into
an empty clean beaker.
(ii) Measure exactly 75 cm3 of distilled water and then put it into the solution of the acid
in part (i) above.
(iii) Stir well the solution mixture in part (ii) above by means of a clean and dry
glass rod
Questions
a. (i) Why is it important to clean a conical flask at the end of each titration
before staring the subsequent titration?
(ii)State the role of white tile or white paper on which conical flask and its
contents is put during titration.
e. Classify acid H2Q according to its strength, basicity and origin respectively
and sate why in each case.
f. i/ Was methyl orange also a suitable indicator for this titration? Give
reasons.
ii/ What is the significance of the indicator in this experiment?
iii/ Why there a colour change when enough acid has been added into the
base
SOLUTION
a. (i) It is important to clean a conical flask at the end of each titration before
starting the subsequent titration in order to avoid the effect of impurities in
the conical flask which will turn the effect the titre value the acid used. Or to
avoid effect of diluting base solution in the next experiment due to waste
(ii)The role of white tile or white paper on which conical flask and its contents
is put during titration was to increase clear visibility end point of colour.
Titration Pilot 1 2 3
Final reading (cm3) 20.00 39.80 19.70 40.00
Intial reading (cm3) 0.00 20.00 0.00 20.00
Va = 19.97 cm3
c. (i) 20.00cm3 sodium hydroxide required 19.97cm3 of acid H2Q for complete
neutralization
(ii)Colour change from Pink to colourless point of equivalent
Ma Va = na
Mb Vb nb
Where:
Ma = Molarity of Acid (FF)
Va =Volume of Acid (FF)
Mb =Molarity of Base (EE)
Vb=Volume of Base (EE)
Na =Number of Acid (FF)
Nb =Number of Base (EE)
Na= 1 Nb= 2
We have
Ma = ?
Va =19.97 cm3
Mb = 0.2 M
Vb=20.00 cm3
Nb =2
Na =1
Ma= Mb X VbX na
Va X nb
Ma = 0.2 X 20.00 X 1
19.97X 2
Ma = 0.1 M
Ma= 0.1 M
But from
Find the molarity before diluting acid
Where
Mc = Molarity of conc. Acid (FF)
Vc = Volume of conc. Acid (FF)
Md = Molarity of diluted Acid (FF)
Vd = Volume of diluted or final volume of Acid FF
We have
Mc =?
Vc =75cm3
Vd =150cm3
Md=0.1
McVc = MdVd
Mc = 0.1M x 150cm3
75cm3
= 0.2M
Given that
4.50g = 250cm3
? = 1000
Concentration = 18g/dm3
Step 2:
Find the molar mass of H2Q
So,
H2Q =90
2 + Q=90
Q=90-2
Q= 88
❖ Acid H2Q is most probably oxalic acid with the formula H2C2O4
e. Acid H2Q which is H2C2O4 is weak acid, because its degree of dissociation is
low. For example dissociate partially compared to strong acids like
hydrochloric acid which dissociate fully.
• Basically of H2Q is two (2) because it contain two (2) number of
hydrogen atoms
• Original of oxalic acid or ethanedioic is organic acid or organic
compound with structure
C O
OH
C O
OH
f. i/ Methyl orange indicators are not suitable indicator because the titration
involves weak acid against strong base and if applied the colour will change
before equivalent or end point.
ii/ The significance of the indicator in this experiment was to show the end
point of the reaction. The indicator changes colour when the end point
reached. The colour changes from Yellow to pink
iii/ When enough acid has been added into the base the reaction will complete
or will neutralize base and reaction take place properly and the colour change to
show end point of titration.
NECTA 2015
1. You are provided with the following solutions;
G: Containing 0.1 mole hydrochloric acid per dm3 of solution;
B: Contain 2.65g M2CO3 per 0.5dm3 of solution
Methyl orange indicator.
Questions;
(a) Titrate G (in burette) against B (in conical flask) using two drops of your indicator
obtain three titre values. Record your data in a tabular form.
(iii)Showing your procedures clearly; calculate the molar mass of M2CO3 and hence
identify element M
SOLUTION
Titration Pilot 1 2 3
Final reading (cm3) 26.00 25.00 25.10 25.00
Intial reading (cm3) 0.00 0.00 0.00 0.00
Va = 25.03 cm3
(ii) 2Hcl (aq) + M2CO3 (aq) 2MCl (aq) + CO2 (g) + H2O (L)
2H+(aq) + 2Cl- (aq) + 2M+ (aq) + CO3+ (aq) 2M+ (aq) + 2Cl- (aq) + CO2 (g) + H2O (L)
Ionic equation: 2H+ (aq) + CO3+ (aq) CO2 (g) + H2O (L)
(iii) Calculate the molar mass of M2CO3 and hence identify element M
Ma Va = na
Mb Vb nb
Where:
Ma = Molarity of Acid
Va =Volume of Acid
Mb =Molarity of Base
Vb=Volume of Base
Na =Number of Acid
Nb =Number of Base
Na= 2 N b= 1
We have
Ma = 0.1M
Va =25.03 cm3
Mb = ?
Vb=25.00 cm3
Nb =1
Na =2
Mb = Ma X VaX nb
Vb X na
Mb = 0.1 X 25.03 X 1
25.00X 2
Mb = 0.05 M
Mb = 0.05 M
Then
Therefore
M2CO3 = 106
2M + 12 + (16 X 3) = 106
2M + 12 + 48 = 106
2M + 60 = 106
2M= 106 – 60
2M = 46
2M=46
2 2
Atomic mass of M = 23
❖ Molar mass of M2CO3 = 106g/mol and element M is Sodium (Na)
NECTA 2016
1. You are provided with the following solutions;
Q: Containing 36.5g of hydrochloric acid in 1 litre of solution;
P: Contain 4.0g of impure ammonium hydroxide per 0.25dm3 of solution
Methyl orange indicators.
Procedure;
(i)Measure exactly 10 cm3 of Q by using 10 cm3 measuring cylinder and pour
into100cm3 measuring cylinder. Carefully add distilled water to 100 cm3 mark then
stir. Fill the resulting into a burette.
(ii)Titrate Q against P using two drops of the indicators obtain three accurate values.
Record your results in a tabular form.
Questions;
(a) What if phenolphthalein indicator was used in place of methyl orange indicator for
the titration of the given solutions? Give reasons for your answer
(c) Showing your procedures clearly; calculate the percentage by weight of the impurity
in the ammonium hydroxide.
SOLUTION
Table of results
Titration Pilot 1 2 3
Final reading (cm3) 21.80 40.00 20.10 40.80
Intial reading (cm3) 0.00 20.00 0.00 20.00
Va = 20.30 cm3
(a) Phenolphthalein indicator is not suitable indicator for this titration the reaction
involves strong acid against weak base, so if phenolphthalein indicator was
used in place of methyl orange indicator we could have not get end point and
get wrong volume of acid.
(b) (i) 20 cm3 of P required 20.30 cm3 of Q for complete reaction
(c) Calculate for the percentage by weight of the impurity in the ammonium
hydroxide.
Step 1:
Then
Where
Mc = Molarity of conc. Acid (Q)
Vc = Volume of conc. Acid (Q)
Md = Molarity of diluted Acid (Q)
Vd = Volume of diluted or final volume of Acid Q
We have
Mc =1M
Vc =10cm3
Vd =100cm3
Md= ?
McVc = MdVd
1Mx100cm3 = Md x 1000cm3
Md = 1M x 10cm3
100cm3
= 0.1M
Step 2:
Find the molarity of base of solution P (Mb)
Ma Va = na
Mb Vb nb
Where:
Ma = Molarity of Acid (Q)
Va =Volume of Acid (Q)
Mb =Molarity of Base (P)
Vb=Volume of Base (P)
Na =Number of Acid (Q)
Nb =Number of Base (P)
Na= 1 N b= 1
We have
Ma = 0.1M
Va =20.30 cm3
Mb = ?
Vb=20.00 cm3
Nb =1
Na =1
Mb = Ma X VaX nb
Vb X na
Mb = 0.1 X 20.30 X 1
20X 1
Mb = 0.1
Mb = 0.1 M
Step 3:
Calculation for percentage purity of base of solution P
But
Concentration in g/dm3 of impure solution P
Conc of P = 4.0g
0.25dm3
From
So,
= 78.125%
NECTA 2018
Procedure
(i) Measure exactly 20 cm3 of X by using 100 cm3 measuring cylinder. Carefully
add distilled water to 100 cm3 mark then stir. Call this solution X1. Fill X1 into
the burrette.
(ii) Titrate X1 against 20.00 cm3 or 25.00 cm3 of Y using two drops of the
indicator; obtain three accurate values. Record your results in a tabular form.
Questions
(a) (i) The colour change at the end point was from to
(iii) Cm3 of Y required cm3 of X1 for complete reaction.
(b) Write a balanced chemical equation for the reaction between X1 and Y.
SOLUTION
(a) (i) The colour change at the end point was from Yellow to Pink
(ii) 25.00 Cm3 of Y required 12.50 cm3 of X1 for complete reaction.
(c)
i/ Molarity of X1 and Y;
Step 1;
Find the molarity of X1 after dilution
McVc = MdVd
Where
Mc = Molarity of conc. Acid (X)
Vc = Volume of conc. Acid (X)
Md = Molarity of diluted Acid (X1)
Vd = Volume of diluted or final volume of Acid (X1)
We have
Mc =0.5M
Vc =20cm3
Vd =100cm3
Md= ?
McVc = MdVd
0.5Mx20cm3 = Md x 100cm3
Md = 0.5M x 20cm3
100cm3
= 0.1M
Step 2;
Find the molarity of Y
Ma Va = na
Mb Vb nb
Where:
Ma = Molarity of Acid (X1)
Va =Volume of Acid (X1)
Mb =Molarity of Base (Y)
Vb=Volume of Base (Y)
Na =Number of Acid (X1)
Nb =Number of Base (Y)
Na= 1 N b= 2
We have
Ma = 0.1M
Va =12.50 cm3
Mb = ?
Vb=25.00 cm3
Nb =2
Na =1
Mb = Ma X VaX nb
Vb X na
Mb = 0.1 X 12.50 X 2
25X 1
Mb = 0.1
Mb = 0.1 M
Molarity (mol/dm3)
Therefore
MOH = 40
M + 16 + 1 = 40
M + 17= 40
M= 40 – 17
M = 23
❖ Atomic mass of M = 23
10. From obtained data what can you conclude the effect increasing temperature on the
rate of chemical reaction?
11. Cause the smell or irritant chocking smell
12. Is the graph is a straight line or curve
13. How was the factor of concentration varied in this experiment
14. Use the graph to explain how variation of concentration affects the rate of chemical
reaction
15. State the sources of errors in this experiment
16. From obtained data what conclusion can you make about the effect of increasing
temperature on the rate of the reaction
17. Why did the cross disappear?
18. Write two uses of the product which obscured the cross
19. Record the room temperature
20. State the product which causes the solution to cloud letter X
21. Plot the graph
22. Determine the slope
23. How was the factor of temperature varied in this experiment
NECTA 2012
2. You are provided with the following:
ZO: A solution of 0.13M of Na2S2O3 (Sodium thiosulphate)
UU: A solution of 2M HCl;
Thermometer
Heat source/ burner
Stop watch
Procedure
(i) Place a 500cm3 beaker, which is half- filled with water, on the heat source as a
water bath.
(ii) Measure 10cm3 of ZO and 10 cm3 of UU into two separate test tubes
(iii) Put the two test tubes containing ZO and UU solution into a water bath.
(iv) When the solutions attain a temperature of 600C, remove the test tubes from the
water bath and pour both solutions into 100 cm3 empty beaker and immediately
start the stop watch.
(v) Place the beaker with the contents on top of a piece of paper marked X
(vi) Note the time taken for themark X to disappear
(vii) Repeat procedures (i) to (vi) at temperature 700C, 800C and 900C.
(viii) Record your results as in table 1.
Table 1
Experiment Temperature Time (s)
1 600C
2 700C
3 800C
4 900C
QUESTIONS
b. What is the product which causes the solution to cloud the letter X?
SOLUTION
Table 1
Experiment Temperature Time (s)
1 600C 11.72
2 700C 7.62
3 800C 6.00
4 900C 3.22
b. The product which causes the solution to cloud the letter X was Sulphur (S).
d. conclusion
NECTA 2015
Questions:
a) What is the aim of the whole experiment
b) Complete table 1
c) Give reasons (s), identify the experiment in which the reaction was
i. Fast
ii. Slow
d) With state symbols write balanced chemical equation for the reaction between U
and V
e) List four factors which can affect rate of chemical reaction
f) Write the electronic configuration of the production which causes the solution to
cloud letter X
g) What can you conclude from the data obtain
SOLUTION
a) The aim of the whole experiment is to show the effect of concentration on the rate of
chemical reaction.
b) Table of results
Table 1
C)
i. The experiment in which the reaction was fast was experiment number 1
because it has higher concentration and the time taken for disappearance of
letter X was the shortest compared to others.
ii. The experiment in which the reaction was slow was experiment number 5
because it has lower concentration and the time taken for disappearance of
letter X was the longest compared to others.
d)
2HCl (aq) + Na2S2O3(aq) 2NaCl (aq) + H2O(L) + SO2(g) + S(s)
e)
i/ Concentration
ii/ Temperature
iii/ Pressure
iv/ Catalyst
f) The electronic configuration of the product which cause the solution to cloud letter
X , the product was Sulphur (S) and its electronic configuration = 2:8:6
g) Conclusion
NECTA 2016
A stop watch/ clock; a white plain paper with a cross and thermometer
Procedure
(i) Place a 100cm3 beaker on top of a cross on a plain paper provided such that the
cross is visible through the solution when viewed from above
(ii) Prepare a water bath using a 250 cm3 or 300 cm3 beaker
(iii) Measure exactly 10cm3 of BB and 10 cm3 of DD pour into separate boiling
test tubes
(iv) Put the two boiling test tubes into the water bath in (ii) above and warm the
contents to 400C.
(v) Immediately pour the hot solutions BB and DD into the 100 cm3 beaker in (i)
above and simultaneous start the stop watch/clock. Record the time taken in
seconds, for the cross to disappear completely.
(vi) Repeat procedures (iii) to (v) at different temperature, 500C, 600C and 700C.
Record your reading in a tabular form as shown in table 1.
Table 1
Temperature Time (sec) 1/time (sec)
40
50
60
70
Questions
a. (i) Record the room temperature
e. From obtained data what can you conclude the effect increasing
temperature on the rate of chemical reaction?
SOLUTION
C. Na2S2O3 (aq) + 2HCl (aq) 2NaCl (aq) + H2O (L) + SO2 (g) + S (s)
In ionic equation
NECTA 2017
Procedure
(i) Put a beaker (100cm3) on top of a cross on the given sheet of paper.
(ii) Measure 25 cm3 of E using measuring cylinder and pour into a beaker in (i).
(iii) Using another measuring cylinder measure 5 cm3 of F and pour it into a
beaker containing E and instantly, start a stop watch.
(iv) Stir the mixture with a glass rod while you keep on observing the cross from
above; record the time taken for the cross to disappear.
Questions
a) Complete filling the Table 1
b) (i) Using the data in the table, plot a volume time graph (volume on the y-axis
and time in second on the x-axis)
(ii) What does the shape of the graph indicate?
SOLUTION
a)
10 15 65.40
5 20 140.00
c)
. Na2S2O3 (aq) + 2HNO3 (aq) 2NaNO3(aq) + H2O (L) + SO2 (g) + S (s)
In ionic equation
2Na+ (aq) + S2O32- (aq) + 2H+ (aq) + 2NO3- (aq) 2Na+ + 2NO3- + H2O (L) + SO2 (g) + S(s)
e)
1. Sulphur is used in the manufacture of carbon disulphate, sodium
thiosulphate, gun powder, matches and in fireworks.
NECTA 2018
Procedure
Place 150cm3 of water in the 250cm3 beaker and use this as your water bath; heat
the water 800C. Measure 10cm3 of H1 and 25cm3 of water and pour the cotents into the
100cm3 beaker. Put the beaker with the contents ito a hot water bath. When the contents
attain a temperature of 700C, place the beaker on top of the marker X on the paper
provided. Add 10cm3 of H2 and immediately start the stop watch. Swirl the beaker twice
and look vertically on the top of the beaker so as to see X through the bottomof the beaker.
Stop thr clock when X is invisible. Record the time taken for X to disapper completely.
Repeat the experiment at different temperatures as shown in the table 1.
Table 1
QUESTIONS
a) Fill Table 1.
b) Write a balance equation for reaction between H1 and H2
c) Which product causes the solution to cloud the letter X?
d) Plot a graph of rate (1/t) against temperature
e) What conclusion can you draw from this experiment?
SOLUTION
a)
Table 1
Exp. No. Temperature of H1 Time (sec)
(0C) Rate 1/ t (S-1)
1 70 2.56 0.39
2 60 4.05 0.25
3 50 9.23 0.11
4 40 14.08 0.07
5 30 29.15 0.03
c) The product which causes the solution to cloud the letter X was Sulphur (S)
e) conclusion
TECHNIC QUESTION
Procedure
(i) Mark letter A on a piece of paper with black ink
(ii) Measure 50 cm3 of Z and pour it into a conical flask
(iii) Measure 10cm3 of U by using different measuring cylinder immediately start the
stop watch and observe the changes from above
(iv) Stand the conical flask on the paper above the cross. Look down vertically
through the mouth of the conical flask and make sure you can see the cros at the
bottom of the flask.
(v) Swirl the flask while keep on observing until the letter A disappears
(vi) Record the time taken for the disappearance of letter A
(vii) Repeat the whole procedure using 40 cm3, 30 cm3, 20 cm3 and finally 10 cm3.
Table 1
Questions
a) Complete filling the table of results showing your working for the fifth column
(conc. In mol/dm3)
b) Write the balance chemical equation between Z and U
c) Plot the graph of time (y-axis) against Concentration of Na2S2O3 (x- axis)
d) What substance was produced during the reaction which obscured the mark
A
e) What conclusion can you draw from the result of this experiments
f) Briefly explain the smell and color observed as the reaction take place
g) Explain how concentration changes affect the rate of chemical reaction
SOLUTION
a) Table of results
Molarity = 32.24g/dm3
248. 17g/mol
Molarity = 0.13mol/dm3
Experiment 1
0.13 x 50 = 6.5
6.5 ÷ 50 = 0.13
Experiment 2
0.13 x 40 = 5.2
5.2 ÷ 50 = 0.104
Experiment 3
0.13 x 30 = 3.9
3.9 ÷ 50 = 0.078
Experiment 4
0.13 x 20 = 2.6
2.6 ÷ 50 = 0.052
Experiment 5
0.13 x 10 = 1.3
1.3 ÷ 50 = 0.026
b)
d) Substance that was produced during the reaction which obscured the mark A
was Sulphur (S) (precipitation of sulphur)
e) Conclusion
3. QUALITATIVE ANALYSIS
Qualitative analysis it contain two questions only but (NECTA) it gives one Question
only
GUIDED UN GUIDED
Every student must have a Qualitative sheet guide – CSEE (Certificate of secondary
education examination).
REAGENTS MUST BE
➢ Conc. HCl
➢ Dilute HCl
➢ Dilute HNO3
➢ Conc. H2SO4 IZI REAGENTS NI LAZIMA MWALI
➢ NaOH (solution) MU WAKO ATAZIWEKA KWENYE MEZA
➢ NH3 (solution) NI KWA AJILI YA (PRELIMINARY TESTS)
➢ Distilled Water (H2O)
Anion
• Iron (ii) sulphate (FeSO4) (NO3- Confirmed)
• Magnesium sulphate (MgSO4) (CO32- Confirmed)
3. Sample F is a simple salt contain one cation and one anion. Carefully carry out the
experiments described below and record all your observations, inferences and hence
identify the cation and anion present sample salt F.
SOLUTION
S/N Experiment Observation Inference
1 Appearance of sample F White powder salt NH4+, Na+, Ca2+,
Zn2+, Pb2+ May be
present.
Or
Transition metals
Fe2+,Fe3+,Cu2+ may
be absent.
2 Action of heat Colourless gas CO32+,HCO3- May
evolves, which be present
turn lime water
milk and wet
litmus paper from
blue to red
3 Action of dilute HCl acid on a Effervescence of CO32-,HCO3- May
solid sample colourless gas be present
evolves, which
turns lime water
milky and wet
litmus paper from
blue to red
4 Action of concentrated H2SO4 on Effervescence of CO32-,HCO3- May
a solid sample colourless gas be presen
evolves. The gas
turns lime water
milky and wet
litmus paper from
blue to red
5 Flame test Golden yellow Na+ May be
flame present
6 Solubility of solid samples Soluble forming CO32-, HC03-, of
colourless Na+, NH4+ May be
solution present
7 Action of NaOH solution on a No precipitate is Na+ May be
sample solution formed, even on present
warming
8 Action of NH3 solution on a No precipitate is Ca2+, Na+, NH4+
sample solution formed May be present
NECTA 2015
3. Sample M contains one cation and one anion. Using systematic qualitative analysis
procedures carry out the experiment and record carefully your observations,
inferences and finally identify the cation and anion present sample M. Record your
work in a tabular form as shown in Table 2.
Table 2
S/N Experiment Observation Inference
Conclusion
(i) The cation sample M is
(ii) The anion sample M is
(iii)The chemical formula of sample M is
SOLUTION
S/N Experiment Observation Inference
1 Appearance of sample M White crystalline NH4+, Na+, Ca2+,
salt Zn2+, Pb2+ May be
present.
Or
Transition metals
Fe2+,Fe3+,Cu2+ may
be absent.
2 Action of heat Cracking sound NO3- of Pb2+ May
with brown gas be present
3 Action of dilute HCl acid on a Effervescence of CO32-,HCO3- May
solid sample colourless gas be present
evolves, which
turns lime water
milky
4 Action of concentrated H2SO4 on Evolution of NO3- May be
a solid sample brown fumes, presen
which turn wet
litmus paper from
blue to red
5 Flame test Blue-white (pale- Pb2+ May be
blue) flame present
6 Solubility of solid samples Insoluble in cold Cl- of Pb2+ May be
water but soluble present
in hot water
7 Action of NaOH solution on a White precipitate Zn2+, Pb2+ May be
sample solution is formed, soluble present
in excess
8 Action of NH3 solution on a White precipitate Pb2+ May be
sample solution is formed, present
insoluble in
excess
9 Confirmatory test for NO3- Brown rng is
formed at the NO3- Confirmed
junction of the
liquids
10 Confirmatory test for Pb2+ Yellow precipitate Pb2+ Confirmed
which disappears
on warming but
re-appears on
cooling
Conclusion
(i) The cation sample M is Pb2+
(ii) The anion sample M is NO3-
(iii)The chemical formula of sample M is Pb(NO3)2
NECTA 2016
3. You are provided sample R containing one cation and one anion. Carryvout the
guided systematic procedure in the table 2 to identify the cation and anion present in
the sample R.
Table 2
S/n Experiments Observation Inference
(a) Observe sample R
(b) Heat sample R in a dry test tube
(c) Prepare a stock solution of sample
R. Devide the resulting solution
into six portions then add:
(i) dilute HCl solution in small
quantities then in excess to the first
portion
(ii) Small amount of concentration
H2SO4 to the second portion, then
warm
(iii) NaOH solution to the third
portion, drop wise till excess
(iv) dilute NH4OH in small amount
then in excess to the fourth portion
(v) FeSO4 solution followed by
Conc.H2SO4 to the fifth portion
(vi) KI solution to the sixth portion,
warm then cool the mixture.
Conclusion
(i) The cation sample R is .
(ii) The anion sample R is .
(ii) Evolution of brown fumes, which turn wet NO3- May be presen
litmus paper from blue to red
Conclusion
(i) The cation of sample R is Pb2+
(iv) PbNO3 (aq) + H2SO4 (aq) PbSO4 (aq) + NO2 (g) + H2O (L)
NECTA 2017
3. Sample Q is a simple salt containing one cation and one anion. Carefully carry out
all the experiments described in the Table 2. Record all your observation and
appropriate inferences to identify the ions present in sample Q.
Table 2
S/n Experiments Observation Inference
(a) Observe sample Q
(b) Put a spatulaful of sample Q in a
test tube and add distilled water.
(c) Transfer 0.5g of sample Q in a test
tube, add dilute HCl
(d) Transfer 0.5g of sample Q in a test
tube, add concentrated sulphuric
acid.
(e) Dissolve sample Q then divide the
resulting solution into three
portions.
(i) To the first portion add sodium
hydroxide solution.
(ii) To the second portion add
ammonia solution
(iii) To the third portion add
potassium ferricyanide solution
[K3Fe(CN)6].
(iv) To the fourth portion add lead
acetate solution followed by acetic
acid solution.
Conclusion
(a) (i) The cation sample Q is
(ii) The anion sample Q is
(iii)The Compound Q is
(b) Write the reaction equation that took place at experiments (c)
SOLUTION
Conclusion
(b) Write the reaction equation that took place at experiments (c)
NECTA 2018
3. Sample N is a simple salt containing one cation and one anion. Carefully carry out
all the experiments described in the Table 2. Record all your observations and
appropriate inferences to identify the cation and anion present in sample N.
Table 2
S/n Experiments Observation Inference
(a) Appearance of the solid sample N
(b) Put a spatulaful of sample N in a
test tube and heat.
(c) Add dilute hydrochloric acid to the
solid sample N
(d) Perform flame test on the sample.
(e) Dissolve the sample in water.
Divide the resulting solution into
two portions:
Conclusion
(i) The cation is and the anion is .
(ii) The sample N is .
(iii) Write chemical equations (with state symbols) to show reactions which took
place in the experiments (b) and (c).
(iv) Describe three uses of sample N
SOLUTION
S/N Observation Inference
Conclusion
(i) The cation is Na+ and the anion is CO32-
(iii) Na2CO3 (aq) + 2HCl (aq) 2NaCl (aq) + H2O (L) + CO2 (g)
NECTA 2011
2. You are provided with the following;
AA: Containing 0.2 mole HN03 per dm3 of solution;
BB: Contain 4.2g NaxCO3 per 0.5dm3 of solution
MO is Methyl orange indicator.
Questions:
(c) Write a balanced chemical equation for the reaction in this experiment.
(e) Why is there a colour change when enough acid has been added to the base?
NECTA 2014
1. You are provided with the following solutions;
H: Containing 6.3 g of hydrated oxalic acid, (COOH)2.XH2O in 1 dm3 of solution.
M: Contain 1.4 g of potassium hydroxide in 0.5dm3 of solution.
Phenolphthalein indicator.
Questions;
(a) Titrate the acid (in a burette) against the base (in conical flask) using two drops
of the indicator and obtain three titre values.
(b) (i) 25.00 cm3 of M required 12.50 cm3 of H for complete reaction.
(ii) The colour changed at the end point was from to
(iii) Is the use of methyl orange indicator in this experiment as suitable as the use
phenolphthalein? Give a reason for your answer
(c) Showing your procedures clearly, determine the value of X in the form
(COOH)2.XH2O Give that the equation for the reaction
(COOH)2(aq) + 2KOH(aq) (COOK)2(aq) + 2H2O(L)
(d) State any four precautions you would observe to ensure accuracy in this
experiment.
NECTA 2017
Questions
a) (i) Titrate solution PP against 20 cm3 or 25 cm3 of RR until the colour change.
Record the burette readings. Repeat the procedure to obtain three accurate readings
and record your results in a tabular form.
(ii) Why did the colour of the solution changed.
(iii) Determine the average titre volume.
(iv) 25.00 cm3 of solution RR required 25.40 cm3 of solution PP for complete
reaction.
(v) Assume that sulphuric acid of the same molarity was used in the place of
hydrochloric acid, would it be difference in the titre volume used? Give reason.
c) Write a balanced chemical equation of the reaction between the solutions PP and
RR.
d) Calculate the following and write your answer in two decimal places
(i) Molarity of RR.
(ii) Percentage purity of RR.
Procedure
(i) Measure 50cm3 of solution P into a 250 cm3 conical flask.
(ii) Place the flask on top of gauze on a tripod stand. Heat the flask with a gentle
Bunsen burner flame.
(iii) Draw a cross on to paper stir the solution in the conical flask until the
temperature reaches 300C
(iv) Stand the flask on to paper above the cross and immediately add 5 cm3 of
solution Q at the same time start the stop clock stir the mixture up the
thermometer.
(v) Observe the cross through the mouth of the flask as before. Stop the clock
immediately as soon as the cross is obscured. Record the time. Read the
temperature in a table.
(vi) Repeat procedure three more times temperature of 400C, 500C, 600C and
700C. Record your reading in a tabular form as shown in table 1.
Table 1
Questions
d) Dial the time until the cross disappeared, increase or decrease as the
temperature was raised?
f) Use the graph to explain how variation of concentration affects the rate of
chemical reaction
SOLUTION