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9.RA 6969 HAzardous Wastes Engr - Jean Borromeo
9.RA 6969 HAzardous Wastes Engr - Jean Borromeo
Agriculture
Medicine
Industries
Households
POISON
Enters blood stream
Causes illness first
Usually prolonged
cumulative
ACUTE vs CHRONIC EFFECTS
ACUTE EFFECTS CHRONIC EFFECTS
Acetone Methanol (wood
irritation of the eyes alcohol)
(possible corneal
damage), and
digestive tract and dermatosis
respiratory tract; possibility of
headache
depression of the
dizziness
central nervous
system: headache, vision disorders
nausea, vomiting, digestive
loss of coordination, disturbances
dizziness, narcosis insomnia.
(severe intoxication).
PROLONGED EXPOSURES: Some Chronic Health Effects
Carcinogenic
Teratogenic
Mutagenic
HEALTH EFFECTS OF COMMON INORGANIC
CONTAMINANTS
CONTAMINANT SOURCE PATHWAYS HEALTH EFFECTS
Arsenic Pesticides Air, water Gastrointestinal disorder,
Ore smelting/refining lower-limb disorder
Asbestos Heat/flame resistant Air Asbestosis (scarring of lungs)
applications
Cadmium Electroplating, battery Air, biota, Joint pain, lung, kidney
manufacturing water disease
Lead Gasoline, batteries, Air, biota, Impairs nervous system, red
solder, radiation water blood cell synthesis
shielding
Mercury Electrical goods, chlor- Water, biota Inorganic: disorder of central
alkali plants nervous system, psychoses
(inorganic); fungicides, Organic: numbness, impaired
slimicides (Organic) speech, deformity, death
HEALTH EFFECTS OF COMMON ORGANIC
CONTAMINANTS
CONTAMINANT SOURCE PATHWAYS HEALTH EFFECTS
DDT(dichlorodiphe Application of Water, food Bioaccumulates in fatty
nyltrichloroethane pesticide worldwide chain tissues, nervous disorders,
persistent
Contaminated Soil
Contact with Water
Contaminated
ground water
Ground Water Flow
BIOACCUMULATION/BIOMAGNIFICATION
*Bioaccumulation has increased POPs Concentration
100 million times (ppb)
Fish-eating
birds 3,530,000
Plankton 1,880
Sediments 150
COVERAGE of RA 6969
PICCS
PMPIN
PCL
CCO
PICCS
Philippine Inventory of Chemicals & Chemical
Substances
It is a list of all existing chemicals & chemical
substances used, sold, distributed, imported,
processed, manufactured, stored, exported, treated or
transported in the Philippines
It serves as a guide for manufacturers and importers of
chemicals
Importation of chemicals not listed in the PICCS must
be covered by a Small Quantity Importation Clearance
(SQI) - limited to 1000 Kg/Annum
PMPIN
Pre-Manufacturing & Pre-Importation Notification
M - manufacture
I - importation
PMPIN: Types of Notification
There are two types of PMPIN for new substances manufactured or
imported with volume(>=1,000kg/y): abbreviated form and detailed
form.
Users/Importers/Manufacturers/Distributors of
chemicals included in the PCL are required to register
their hazardous wastes & chemical substances &
submit annual report (Prescribed Form) beginning Sept.
1996 on production and management information
CRITERIA for PCL
The following criteria has been established by DENR for PCL based
on the selection criteria used in other industrial nations such as
Australia, Japan, Canada and the United States:
environment
Salient Features of the CCO for Cyanide and
Cyanide Compounds
Limitation of use to:
Electroplating industries;
Mining & metallurgical industries;
Steel manufacturing;
Synthetic fibers & chemicals;
Plastic production;
Other industry sub-sectors; and legitimately using
cyanide such as jewelry making.
Salient Features of the CCO for Cyanide and
Cyanide Compounds
Prohibitions:
Use or made available to the fishery sector
Stop upon No longer Stop upon Stop upon Stop upon Stop upon
Stop upon
1. Importation effective allowed 3 effective effective effective effective
effective date
date yrs after date date date date
the
Stop upon effective Stop upon Stop upon Stop upon Stop upon
2. Trade/ Sale/ Stop upon date (Y
effective effective effective effective effective
Distribution effective date 2007)
date date date date date
No longer
allowed Stop upon
3. Domestic
Stop upon effective date after 10 effective
Production
yrs date
(2014)*
Stop upon
effective date -
No longer Can be No longer use in open-
No longer ended and
partially
allowed used until allowed Stop upon Stop upon enclosed
allowed after applications
4. Use after 10 its after 10 effective effective Closed
10 years Applications
are no
years retirement years date date longer
(2014)* allowed
(2014)* period (2014)* after 10
years
5. Recycling/ Use
Stop upon effective date
as raw mats
*Consult EMB Memorandum Circular 2015-004: Clarification to the CCO for PCBs
EMB Memorandum Circular 2015-004:
Clarification to the CCO for PCBs
All PCB owners who have not yet registered pursuant
to DAO 2004-01 (CCO for PCB) must register online
through the EMB Online PCB Database
(www.emb.gov.ph/philpcbtracker);
Those who were previously registered shall review and
update the required information through the same
online database not later than April 9, 2015;
Those who were previously registered shall review and
update the required information through the same
online database not later than April 9, 2015;
Salient Features of the CCO for Lead
(Pb) and Lead Compounds
Prohibited use in the following production/
manufacturing:
Packaging for food and drinks
Fuel additives
Water pipes
School supplies
Cosmetics
Paints (with more than 90 ppm threshold limit)
2013-2016: architectural, decorative, household
HAZARDOUS WASTE
HAZARDOUS WASTE CLASS:
_______________________
HW SUB-CATEGORY:
______________
CHARACTERISTIC: HW #:
_________
______________ FORM:
VOLUME/WEIGHT:
___________
DATE ___________
START OF
ACCUMULATION:
DATE CONTAINER FILLED:
________________
_________________
SHIPPING DATE:
_________________
CONTAINER’S CAPACITY:_______
CONTAINER’S MATERIAL: _________
GENERATOR’S HW ID #:
COMPANY _____________ NAME:
___________________________
ADDRESS:
______
___________________________
CONTACT #/s:
____________
___________________________
CONTACT PERSON:
________
___________________________
HANDLE WITH CARE
___
“RULE OF THUMB”
EMB
9 Hazard Categories
Generator Transporter Treater
Corrosive
Reactive
DAO 2013-22
Revised Procedures and Standards for the
Management of Hazardous Waste
Table 2.1 Classification of Hazardous Wastes
WASTE
CLASS DESCRIPTION
NUMBER
D: Wastes with Inorganic Chemicals
Chromium Compounds* Includes all wastes with a total Cr concentration D405
> 5 mg/L based on analysis of an extract
Lead compounds* Includes all wastes with a total Pb concentration D406
> 1 mg/L based on analysis of an extract.
Mercury and mercury Includes all wastes with a total Hg concentration
compounds > 0.1 mg/l based on analysis of an extract. D407
These also includes organomercury compounds.
Refer to CCO.
DAO 2013-22
Revised Procedures and Standards for the
Management of Hazardous Waste
Table 2.2 Exempted Wastes
Household wastes such as garbage under RA 9003 except special
wastes
Treated industrial or commercial wastewater that are disposed of on-
site through the sewerage system
Industrial & commercial solid wastes that do not contain hazardous
wastes as identified in Table 2.1
Materials from building demolition except those that contain asbestos
Septic tank effluents & associated sullage wastewaters
Untreated spoils from mining, quarrying & excavation works but not
materials in the nature of tailings, commercially treated materials and
mine facility consumables
DAO 2013-22
Revised Procedures and Standards for the
Management of Hazardous Waste
Table 3.1 Categories of Hazardous Wastes Generators
Hazardous Large Medium Small
Waste Type
Waste No. Kg/yr Kg/yr Kg/yr
A101 Waste with Cyanide
L403 ODS
L404 PCB Wastes >10,000 10,000- <5000
M502 Asbestos Wastes 5,0000
M501 Pathological or Infectious Wastes
M503 Pharmaceuticals and Drugs
D401-D499 Waste with Inorganic chemicals
E501-E599 Reactive Chemical Wastes
F601-F699 Inks/Dyes/Pigments/Paints/Resins/Latex/Adhe
sives/Organic Sludge >20,000 20,000- <10,000
G703-G704 Waste Organic Solvents 10,0000
K301-K303 Stabilized Waste
L401-L402 Other Organic Chemicals
M504-M506 Miscellaneous Wastes
DAO 2013-22
Revised Procedures and Standards for the
Management of Hazardous Waste
Table 3.1 Categories of Hazardous Wastes Generators
Hazardous Large Medium Small
Waste Type
Waste No. Kg/yr Kg/yr Kg/yr
B201-B299 Acid Wastes
C301-C399 Alkali Wastes >36,000 36,000- <18,000
I101-I104 Used or Waste Oil 18,000
J201 Empty Chemical Containers
H802 Grease Wastes >500,000 500,000- <250,000
250,000
???In case of establishments generating two types of wastes, the establishment is classified as
a large generator. The Bureau may from time to time update the categories of waste
generators, once data becomes available.
DAO 2013-22
Revised Procedures and Standards for the
Management of Hazardous Waste
Table 3.2 Compliance Requirements of Hazardous Wastes Generators
Category Reporting Storage Time Limit
Large quantity generators Quarterly 6 months
Shipping date Date on which waste must be removed from the storage
excludes importation of
tanker sludge
DENR Administrative Order No. 06, Series of 2010:
Guidelines on the Use of Alternative Fuels and Raw
Materials in Cement Kilns
HW Materials Acceptable for Co-
processing:
It qualifies as alternative fuel or raw
material as defined;
Its use in the cement kiln complies with
applicable environmental standards
provided for in RA 8749 and RA 6969;
It should pass waste acceptance criteria
based on calorific value, mineral oxides,
heavy metal content and other
substances, and impacts on kiln
operation, clinker and cement quality.
DENR Administrative Order No. 06, Series of 2010:
Guidelines on the Use of Alternative Fuels and Raw
Materials in Cement Kilns
Hazardous Waste Materials Not
Acceptable for Co-processing
Health care wastes
Asbestos-containing wastes
All types of batteries
Electronic assemblies and scraps
Explosives
Cyanide wastes
Mineral acids
Radioactive wastes
Unsegregated Municipal solid wastes
Joint DENR-DOE Administrative Order (JAO) 2013-09-0001
Lighting Industry Waste Management Guidelines
Lighting products contain mercury, arsenic, and other
compounds that are toxic to human and aquatic life even at low
concentrations.
Regulates the end-of-life disposal of lighting products to control
the dispersion of these toxic substances into the environment to
avoid these adverse consequences for the protection of the
environment and public health.
Defines “lighting” (those covered by this JAO)
Joint DENR-DOE Administrative Order (JAO) 2013-09-0001
Lighting Industry Waste Management Guidelines
Obligations of Stakeholders
All producers shall jointly work together in coming up with a
Lamp Waste Management Plan and in setting-up a Lamp Wastes
Management System Operator as defined in this Order. The
producers and Lamp Wastes Management System Operator are
responsible for the preparation, implementation, and review
and monitoring of the Lamp Management System Plan.
Site Inspection
Interviews
Update CSM
Implementation of RemAP
Secure Regulatory Procurement
Prepare Work Plan
Permits Process
Site Validation
Recommendation(s) on further
Sampling Activities Site Management and Long
term Monitoring (if required)
Speaker:
ENGR. JEAN C. BORROMEO
OIC- Environmental Monitoring and Enforcement Division
DENR EMB-NCR