1 ClF5 is a inter-halogen compound.

It reacts with AsF5as,

ClF5 + AsF5 ⎯→ X. Then

(a) X is AsF3 and reaction represents reducing nature of ClF5

(b) X is [CIF4][AsF6] and reaction represents oxidizing nature of ClF5

(c) X is [CIF4][AsF6] and reaction represents fluoride donor ability of ClF5
 (d) X is [CIF4][AsF6] and reaction represents reducing nature of ClF5
2. A brownish yellow gas X with characteristic penetrating odor on hydrolysis produces
a golden yellow solution of compound Y. X can be prepared by reacting HgO with
chlorine gas (dry). Then X and Y are:
(a) X = ClO2; Y = HClO2 (b) X = ClO2; Y = HClO3

(c) X = Cl2O; Y = HClO (d) X = Cl2O; Y = HClO2

3. Which of the following will produce ammonia on heating?

(a) (NH4)2SO4 (b) NH4ClO4 (c) (NH4)2Cr2O7 (d) (NH4)2HPO4

4. Which of these reactions illustrate the reducing nature of NO?

(a) NO + I2 + H2O ⎯→ (b) NO + KMnO4 + H2SO4 ⎯→

(a) NO + FeSO4 + H2O ⎯→ (d) NO + K2Cr2O7 + H2SO4 ⎯→

5. Nitrogen sesquioxide can be obtained by:

(a) HNO3 + As2O3 ⎯→ (b) HNO3 + SO2 ⎯→

(c) Cu + 50% cold HNO3 ⎯→ (d) NO2 + SO2 ⎯→

6. Two oxides of nitrogen, NO and NO2 are allowed to react together at 243K and form a
coloured compound of nitrogen X. When compound X reacts with water to yield
another compound of nitrogen Y. The shape of the anion of Y molecule is:

(a) triangular planar (b) triangular pyramidal

(c) tetrahedron (d) square planar

7. Consider the following sequence of reaction, the shape of Y is expected to be

Na + NH3(g) X N2O
Y  Z(gas pure)

(a) Triangular Planer (b) Linear (c) Pyramidal (d) Tetrahedral

8. Which of the following on heating produces NO2?

(a) NaNO3 (b) AgNO3 (c) NH4NO3 (d) NH4NO2

9. Among the following compounds, which on heating do not produce N2? (a)

(NH4)2Cr2O7 (b) NH4Cl + NaNO2 (c) NH4Cl + CaO (d) Ba(N3)2

10. The correct order of S––S bond length in following oxyanions is:

(I) S2O42– (II) S2O52– (III) S2O62–

(a) I > II > III (b) I > III > II (c) III > II > I (d) III > I > II
11. In which of the following reaction product does not contain ‘Peroxy’ linkage?

(a) 2OF Dimerisation (b) H4P2O8 + H O (c) 2Na excess O (d) 2NO2 Dimerisation
2 2
12. Consider the following statements in respect of oxides of sulphur.
(1) In gas phase SO2 molecule is V-shape.
(2) In gas phase SO3 molecule is planar.
(3) g-SO3 is cyclic trimer.
Which of the above statements are correct ?

(a) 1 and 2 only (b) 2 and 3 only (c) 1 and 3 only (d) 1, 2 and 3
13. A tin chloride Q undergoes the following reactions (not balanced)

Q + CI– ⎯→ X Q + Me3N ⎯→ Y Q + CuCl2 ⎯→ Z + CuCI

X is a monoanion having pyramidal geometry. Both Y and Z are neutral compounds.

Choose the correct option(s)

(a) The central atom in Z has one lone pair of electrons

(b) The central atom in X is sp3 hybridized
(c) There is a coordinate bond in Y
(d) The oxidation state of the central atom in Z is +2

[IIT-
 JEE Advance, 2019]
14. Choose the correct statement(s) among the following

( a) SnCl .2 H O is a reducing agent .

2 2
( b) SnO reacts with KOH to form K [ Sn(OH ) ].
2 2 6
( c) A solution of PbCl in HCl contains Pb 2+ and CI – ions.
2
( d) The reaction of Pb O with hot dilute nitric acid to give PbO is a redox reaction .
3 4 2

[IIT-
 JEE Advance, 2020]
15. With respect to hypochlorite, chlorate and perchlorate ions, choose correct
statement(s).

(a) The hypochlorite ion is strongest conjugate base

(b) The molecular shape of only chlorate ion is influenced by the lone pair of
electrons of Cl
(c) The hypochlorite and chlorate ions disproportionate to give rise to identical set of
ions
(d) The hypochlorite ion oxidizes the sulfite ion

[IIT-
 JEE Advance, 2020]

[IIT-