Unknown Compand tests

Beilstein o Ignition NHz

(met
hel
↑H
↓
n 1 ctz0H. ↑ Of L
↑01
0007
OH

I
st ! ↓
OH crotonic acid ethylcrotonate ethyl lewlinate nexanal cyclohexanecarboxylic acid cyclohexanone cyclohexylamine
2- hexanol levulinic acid
(carb.acid) Ester) Lester glucose (carb.acid)

-
no heat generated heatgenerated +

acetyl chloride
COHPphenols)
ethylcrotonate 2-hexanol
ethylevulinate crotonic acid
hexanal levulinic acid

glucose cyclohexanecarb.acid
cyclohexanone
cyclohexylamine

⑩bubblesobubbles +
yellow magentaburgundy + bicarbonate
(carb. acid)
hydroxamic
Lester) 1 crotonic acid

↑ylcrotonate
n levulinic acid
hexanal
glucose one OH
cyclohexanecarb.acid
cyclohexanone 2-hexanol

cyclohexylamine
brown precipitate t
no precipitate yellow precipitate +
no
precipitate
1 kMnoy(c 0)
tone
=

isdoform
<methyl
* ↑
ethylcrotonate "ethyl lewlinate OH
levolinic acid crotonic acid
insoluble soluble +
cyclohexanecarb. acid
solubility
Lether
(H20H
o
cyclonexylamine
·!,"vi,i cyclohexanone
hexanal insoluble soluble +
glucose
solubility
(water)

no precipitate brightorange precipitate +

1 2,4 1ND
-

Caldehydes ketones) ⑭
0
↑ OH
hexanal OH
↓ !
↓
cyclohexylamine cyclohexanecarboxylic acid levulinic acid

cyclohexanone

insoluble soluble +

solubility
(water)
⑧ NHz

nexanal L

cyclonexylamine
 Beilstein +
iquition
Br
H OH 0H
a - 0 Cl
↑H2qH
-
3r
0 0
=

4
Broomaophenomepanoramline
p-bromoanisole
1
2-bromoethylbenzene
isromoseraldehyde-bombozakonolacorobenzoicacid methylchlorobenzoate
of chlorotoluene
p-cupidpanone
(phenol)

no heat
generated heat generated +

acetyl chloride
COH's Aphenols
2-bromoethylbenzne
4-bromobenzyl alcohol
7-bromobenzaldehyde 1-chlorobenzoic acid
methylo chlorobenzoate p-chloropheno
o-chlorotoluene o-chloroaniline
p-bromoacetophenone
p-bromoanisole 9orange/yellow solution blue/green precip. +

yellow magenta/burgundy + Ichromic

(10,20,300H's)
acid

hydroxamic p-chlorophenol H-bromobenzyl alcohol

Lester) o-chloroaniline 7-chlorobenzoic acid
2-bromoethylbenzne
0 0
7-bromobenzaldehyde
=

o-chlorotoluene no CO2 bubbles CO2 bubbles +

p-bromoacetophenone 4 bicarbonate
(carb. acid)
p-bromoanissle methylo-chlorobenzoate OH 0 -
0H

yellow precipitate
Br

no precipitate + 7-bromobenzyl alcohol n-chlorobenzoic acid

iodeform colorless, pale yellow, fan blue, violet, purple, green,brown +

(methyl ketone) Ferric chloride/
2-bromoethylbenzne chloroform
7-bromobenzaldehyde
o-chlorotoluene all NH2 ·H
p-bromoanisole p-bromoacetophenone

p-chloroaniline p-chlorophenol
no precipitate brightorange precipitate +

2,4 1ND
-

Laldehydes & Retores) H

2-bromoethylbenzne a -

o-chlorotoluene
p-bromoanissle

n-bromoblecaldehyde

no precipitate yes precipitate+

1 1 gNOs
-

aromatic halides directly attached

reactive)
or
Cl to halogen are in 3r

1
o -chlorotoluene p-bromoanisole
2-bromoethylbenzene

faster slowest

! NaI

Cl

chlorotoluene
↓

p-bromoanisole
 Beilstein Ignition
O CI

Br
Br d
&X
1-bromobsn tchbrobutane
Br

1-bromo-2-ethoxyethane isdobutanechloro-propanol Br

Ether (10a(c)
a-chloro-a-butanone
(methyl ketone) allylbromide chloroacet,ethyls-bromopropionate - butylbromideand
(30nalide)

-
yellow solution blue/green precip. I

chromic acid
(10,20,308Hs) chloroacetic acid
1-bromo-2-ethoxyethane 3-chloro-2-butanone
1 bromobutane
allyl bromide 3-chloro-propanol
-

chlorobutane
ethyl 3-bromopropionate
1-

1 iodobutane
t-brtubromide CO2 bubbles CO2 bubbles
-

no +

bicarbonate
(carb, acids)
21 Cl
magenta/burgundy
Ot
yellow +
OH
3-chloro-propanol
hydroxamic chloroacetic
Lester) acid

Br
1-
bromo-2-ethoxyethane &X
I-bromobutane
3-chloro-2-butanone
1- chlorobutane allyl bromide
1
-
iodobutane t-butyl bromide
ethyl 3-bromopropionate

no yellow precipitate +
precipitate
iodeform
(methyl ketone)
CI
1-
bromo-2-ethoxyethane
1 -

bromobutane
allyl bromide
1- chlorobutane t-butyl bromide
1
-
iodobutane
3-chloro-2-butanone

brown precipitate t

precipitate
no

KMnoy(c c) =

1
1-
bromo-2-ethoxyethane Br
1 -

bromobutane
1- chlorobutane
1 iodobutane
allyl bromide
-

t-butyl bromide

stays red disappearance of red +

Br2/CCI
1 -

bromobutane
O
1- chlorobutane
Br iodobutane
1
-

1-
bromo-2-ethoxyethane t-butyl bromide

fastest white bright

how
1 AgN03.> 1.

niht>Bto conte
CI Br
chbrobutane I bromobrtane isdobutane
--buybromide
 Beilstein
↑Ignition

Doheranos
benza n carnaini. w.emma acpanini "**anethole
01
-
-

anisole
on

naphthalene o-tolvic acid

p-amhophenol P-tolvidine

no heat
generated heat generated +

acetyl chloride
COH's Aphenols
3-phenyl-1-propanol

&etophenonenapthalebenzasee
p-aminopheno
methyl
benzaldehyde-7-cawb.acid p-hydroxyacetophenone
cinnamyl alcohol o-tolvic acid

p-tolvidine

no precipitate brightorange precipitate + 9orange/yellow solution blue/green precip. +

1 2,4 1ND
15
-

chromic acid
↑ Caldehydes & Retores)
anethole (10,20,300H's)
anisole acetophenone p-aminophenol 3-phenyl-1-propanol
methylbenzoate
napthalene p-tolual dehyde P-hydroxyacetophenone benzaldehyde-7-cawb.acid
p-toluidine cinnamyl alcohol

no yellow precipitate noprecipitate

precipitate yellow precipitate +
cyclohexanecarb. acid
O-tolvic acid
iodeform iodeform

1
(methyl ketone) (methyl ketone)
H ↑
↑ p-aminophenol
p-tolvidine HOP-hydroxyacetophenome
no CO2 bubbles CO2 bubbles +

p-tolval dehyde acetophenone bicarbonate

colorless,tan, yellow +
blue, violet, purple, green,brown (carb, acids)
ferric chloride/
3-phenyl-1-propanol benzglaldehyde.e
chloroform
yellow magenta/burgundy + (phenol) NHz cinnamyl alcohol Cyclohexanecarb.acis)
NH2 O-toluicacid
hydroxamic
Lester)
P-tolvidine p-amthophenol
anethole no
precipitate brown precipitate t

anisole
- 1 KMnoy(c c) =

1
0x/
hapthalene OH

methyl benzoate
3-menyI-propanol cinnamyl alcohol

no precipitate brighto range precipitate +

1 2,4 1ND
-

no
precipitate brown precipitate t
Caldehydes & Retores)
1 KMnoy(c c) =

1 H0
-04 7
anisole
napthalene
o-tolvic acid benzaldehyde-4-carb.acid
-
insoluble table anethole
solubility
CH2SOn)
x.

naphthalene anisole