EY Heet

Sec: OSR.
IIT_COSC GTM-39 Date: 30-05-21

Time: 3 Hrs Max.Marks: 300
KEY SHEET
PHYSICS
1 2 2 1 3 4 4 1 5 2
6 4 7 2 8 3 9 3 10 2
11 3 12 3 13 1 14 2 15 3
16 3 17 4 18 3 19 2 20 2
21 3 22 70 23 1 24 20 25 3
26 8 27 4 28 2 29 80 30 5
CHEMISTRY
31 2 32 1 33 1 34 2 35 2
36 2 37 3 38 1 39 4 40 4
41 3 42 4 43 2 44 3 45 4
46 2 47 2 48 2 49 4 50 3
51 4 52 4 53 5 54 4 55 2.4
56 5 57 12 58 2 59 69 60 20
MATHEMATICS
61 2 62 1 63 4 64 2 65 2
66 1 67 3 68 2 69 2 70 2
71 4 72 3 73 2 74 3 75 4
76 2 77 4 78 3 79 3 80 2
81 8 82 2 83 4 84 0.60 85 3
86 3 87 0.34 88 3.54 89 5 90 28.8
Narayana IIT Academy 30-05-21_OSR.IIT CO SC_ JEE-MAIN_GTM-39_Key & Sol
SOLUTIONS
PHYSICS
1. As magnets are perpendicular to each other, the resultant magnetic moment
M '  M 2  M 2  2M
2I
T1  2

2M H 
I
In the second case, T2  2
MH
T2 I

 2
1/4
T1
4
T2   3.36 s
 2
1/4
1 1 1 2 L
2.     Lp 
Lp L L L 2
Where L is inductance of each part,
1.8  104
  0.9  104 H
2
L 0.9  104
 Lp    0.45  104
2 2
H
6
Resistance of each part, r   3
2
1 1 1 2
Now,   
rp 3 3 3
Lp 0.45  104
Time constant of circuit,    3  105 s .
rp 1.5
3. When the spherical conductors are connected by a conducting wire, charge is redistributed and the
spheres attain a common potential V.
1 QA
 Intensity E A 
4 0 RA2
1  C AV  4 0 RA  V
or E A   
4 0 RA2 4 0 RA2 RA
V
Similarly EB 
RB
SR.IIT_N-SC Page. No. 2
Believe you can and you’re halfway there.

E A R0 2
   .
E B RA 1
Areal vectors will be  to the plane. Area vector is at 60 angle with x-axis and 30 angle with –
0 0
4.
z-axis.
 
M
  NI A
M  10  102 Am 2
M
  0.1 Am 2
M  M xiˆ  M z kˆ  M cos 60iˆ

 M cos300 kˆ


M  0.05 iˆ  3kˆ . 
5. The block will just start sliding when the angle  made by the inclined plane with the horizontal will
be equal to the angle of repose.
   repose  tan 1   
 tan  
3

4
6. If final temp is T
PV
0 0
Cv  4T0  T 
4 RT0
PV
 0 0 Cv T  T0 
RT0
4T0  T
 T  T0
4
4T0  T  4T  4T0
8T0  5T
8T
T 0
5
Final pressure
8
Tf T0
5 2
In left Pf  Pi  P0  P0
T0 4T0 5
8
T0
5 8
In right Pf  P0  P0
T0 5
 8P 2 P  6P A
Force   0  0  A  0 .
 5 5  5

7. p  h g  3 p
h g  2 p …(1)
4
p '  p  h g …(2)
5
From (1) and (2)
4 13 p
p'  p   2p  p' 
5 5
F
8. Stress 
A
Elastic limit is 379 MPa
400 400
 379  106  
A d2 / 4
400  4
d
  379  106
 1.16  103 m
 1.16mm
1 2 hc
9. mv    ....(i )
2 
1 ,2 4 hc
mv    ....(ii )
2 3 
hc 1 2
From Eqn. (i)  mv  
 2
On putting this Eqn. (ii)
1 ,2 4  1 2 
mv   mv     
2 3 2 
4 2
v,2  v 2 
3 3m
4
 v,  v
3
10.  K  U  mgH & K  2U
mgH mgH
 2U  U  mgH  U   mgh  h
3 3
H /3
1 2mgH gH
 mv 2  2U  v2
2 3 3

A sin   B cos 
11. Z ; Dimensions of A and B would be same as two quantites can be added only
A B
when they have same dimensions. So from given equation, we can say that Z is
dimensionless.
12.
2h
The time, the particle takes to go through h is t  and in one complete oscillation, the particle
g
travels thorugh h four times.
For the motion of the particle through the tunnel, the force acting on the be like an SHM.
GMm
F  3 x
R
GM
a 3 x
R
R3 R
TSHM  2  2
GM g
So the time period of the particle is
2h
T  TSHM  4
g
R 2h
T  2 4
g g
13.
For maxima x  n
dy
 n
D

For n  4
dy

4D
0.032 102  1.06  102

4 1.6
 530 nm
14. In steady state, the capacitors are fully charged and act as open circuit, so the equivalent circuit in
steady state would be as shown:
 Steady state current is

12
I  2A
24
 Potential difference across AB is
V  2  4  8V
 Sum of potential difference across 2  F and 4  F capacitors is 8V. As these are in series, so
charges on them would be same. Let q be the charge on them, then
From KVL,
q q
 8
2 4
32
 q  C
3
15. Probability for a particular nucleus to decay in any time interval dt is
dN
  dt
N
0.693
 4
T1
2
 12.4 104
V  VR2  VL  VC 
2
16.
 VR VL  VC 
VR  V  200 volt
    340   340 
17. f1    f   f  f&
   s   340  34   306 
 340   340 
f2    f  f
 340  17   323 
f1 19

f 2 18

18. Fraction of supplied energy which increases the internal energy is given by
u CV T 1
f   
(Q) P CP T 
[Here according to definition of sp. Heat at constant pressure (Q ) p  c  nc p T ]
7
For diatomic gas  
5
5
 f 
7
19. Given E  E0 Sin(1.57  107 )( x  ct ).....(i )

 E  E0 Sin ( x  ct )....(ii )
c
On comparing Equations (i) and (ii), we get

 1.57 107
c

 107
2
  4  10 7 m
 400mn
hc
As, 0   EK

1242
1.9   EK
400
EK  (3.1  1.9)eV  1.2eV
20.
Velocity of image of the point in the first mirror with respect to

the image of the point in the
Second mirror is

 
V I1  V0 3i  V0 3 j
I2

(VI1 ) I2  V0 6
4
21. Wavelength of K line is given by  
3R  Z  1
2

For  , between 250 and 179 pm three elements are possible
(Z = 24, 25 and 26)
Q nCP T
22. 
W nRT
C
 Q  P .W
R
7
  20 = 70 J.
2
23.
Conservation of linear momentum:

3u   3u / 2   mv  mv
  3u / 2  ...1
Newton’s experimental law:

u  e  u / 2  v 
Putting e = 1 for elastic collision we obtain,
3u
v .... 2 
2
Using (1) and (2), we obtain m = 1 kg.
24. Using the concept of reduced mass, we obtain :-
k 2k
 
mreduced m
 mm m 
 mreduced   
 mm 2 
2  200
   20 rad s 1
1
2T cos 
25. h
r lg
4
26. x AD   100  80cm  8  10cm
5

2
 3R 
27. I AB  I disc  I plate  M  
 2 
(From Parallel Axis Theorem)
2
1 MR 2  3R 
 MR 2  M 
4 12  2 
31
 MR 2
12
V
28.  open 
2L
V
 closed 
4L
  open  vclosed  4
V V
  4
2L 4L
 V  16 L
Now in 2nd case
V
 'open 
4L
V
 'closed 
8L
V V V 16 L
 'open  'closed     2
8L 4 L 8L 8L
29.
F  10  g  20  g  10a......(i )
10 g  10a.................(ii )
From (i) and (ii)
F  40 g
F  80 N

30.
V  20 V
 V  5  0
2 2
V  20  V  2(V  5)  0
 4V  20  10  0
30 15
V  V
4 2
15  10 5
I  A
2 2
 2I  5 A
CHEMISTRY
P  Ps n
0
31. 
Ps N
10  5 9  200

5 M  20
M  90amu
32. structure not clarity
33. Given, 2C  3H 2  C2 H 6 ; H  21.1
C  O2  CO2 ; H  94.1
1
H 2  O2  H 2O; H  68.3
2
Eqs. 2   ii   3   iii    i 
7
C2 H 6  O2  2CO2  3H 2O
2
H  2  94.1  3  68.3   21.1
 372kcal / mol
34.  0.05 g /100mL
 0.5 g / L
0.5
  5  103 mol / L
100
K sp  4 s 3  4   5  103   5  107
3

35. 4 LiH  AlCl3  Li  AlH 4   3LiCl
Tetrahedral and Hydride ligand
n2
36. rn
z
For Hydrogen atom, rn n
2
r1  x
r3  9 x
Now,  2 p3  n
2 r3
 
3
2
     9x
3
    x .
37. It gives D.D.T (p,P-dichlorodiphenly-Itrichloroethane)
u1 n1T1 n T 1 1
38.    
u2 n2T2 2n  2T 4 2
 u2  2u1
Therefore, if the temperature is doubled and the nitrogen molecules dissociate into nitrogen atoms,
the rms speed becomes double.
39. According to the given data standard reduction potential of Cr is lowest. Lower the standard
reduction potential, stronger the reducing agent. Therefore Cr is the strongest reducing agent.
40. Dry air contains N 2 and O2 . Na does not form nitride.
41.

2 MnO2  2 K 2CO3  O2   2 K 2 MnO4  2CO2  g 
X   air  green
 y
2 K 2 MnO4  Cl2 
 2 KMnO4  2 KCl
Y   y  Pink
42. Phosphorus being a non-metal always forms acidic oxides like P4O6 , P4O10, etc. Where as Al, Sn and
Sb are amphoteric elements.
Al2O3 , SnO and Sb2O3 are amphoteric oxides i.e., they can react with both acids as well a bases.

43.
44. Tollen’s reagent is a solution of ammonia cal silver nitrate and used for the detection of
-CHO group . Aldehydes reduces Tollen’s reagent and itself get oxidized to give Ag 
Colored mirror in the test tube . So this test is also known as silver mirror test.
45.
46.
47.

48.
49. Co. number is 12 means it is fcc lattice

Co. number is 8 means it is bcc lattice fcc bcc
4  at.mass 2  at.mass
1  2 
N a  a1
3
N a  a23
3
 4r 
2 
 1 4 a2
3
 3
  3
 2 2 a1
 
3
2 2r
2 4 4 4


2 2 2 2 2 3 3 
 
3
4 2 2 2
 
 
3
3 3 3

50.
51.
52. Histidine, Valine, Lysine, Methionine

53.

54. PCl5 on reaction with these 4 compounds gives POCl3
PCl5  SO2  POCl3  SOCl2
PCl5  H 2 o  POCl3  2 HCl
PCl5  H 2 SO4  SO2Cl2  2 POCl3  2 HCl
6 PCl5  P4O10  10 POCl3
55.
 0.8
Number of moles at 300 k=1
No .of moles at 600 K= 0.8  0.4  1.2
V is constant
P2 n2T2

P1 n1T1
P2 1.2  600
  2.4 atm
1 1 300
56. Eq of Fe2  C2O4 3  eq. of K 2Cr2O7
5  6  mol  6
Mol of K 2Cr2O7  5
1 16
57.   ln
t 0.5
  5  ln 2
ln 2 1
t1   hr  12 min
2  5
58. DOU = 1
Only aldehyde give 20 alocohol
Will give 20 alcohols on reaction with CH 3 MgBr .

59. 69
60. 20

MATHS
 y
61. Given equation is 2 xdx  2 ydy  d    0
x
Integrating, we get,
y
x2  y 2   c
x
As 1, 0  lies on it, hence, c  1 .
10
62. Total cases = C6
Favourable cases  4C2 . 1C1. 5C3
4
C2 . 1C1. 5C3 2
Required probability  10

C6 7
63. Any general point on the line is  2  2, 2  2,   1
This point most satisfy
x  y  z  21
Hence 2  2  2  2    1  21    4
So, the point of intersection of line and plane is 10, 6,5 
So, equation of plane P  0 is
2  x  10   2  y  6   1 z  5   0
 2 x  2 y  z  37  0
Hence, distance of P  0 from origin is
37 37
 
3 3
64. Let 15 observations are x1 , x2 .......x15
x1 , x2 .......x15
 15
15
If x15  15
x  x  x .....x15  15  6  8 224
x new  1 2 3   14
16 16
 xi2  x 2  5

15
 x12  x22 .....x142  15   230  15
2
 x12  x22 .....x142  3225

x12  x22 ......x142  62  82
 
2
New variance =  x new
16
3325
  196
16
 11.8125
65. Let mid point be  x1 , y1 
 Equation of chord is T  S1

yy1  2a  x  x1   y12  4ax1
Since, it passes through origin
2ax1  y12  4ax1
 y12  2ax1
 Locus is y 2  2ax
z  3  4i   z  3  16
2
66.
 z 2  6 z  25  0
 z 4  3 z 3  3 z 2  99 z  95
  z 2  3 z  4  z 2  6 z  25   5
  z 2  3z  4   0   5  5
67.
h h
Let  a , then tan    a
x x
3h
tan 2   3a
x
2 tan  2a 1
3a  tan 2   a
1  tan  1  a
2 2
3
68. Number of ways   3  1 5  1 6  1  1  167
69. Since there is no constant term the coefficient of 8th and 19th term are same as the binomial
coefficients of 8th and 19th term.
n
C7  nC18  n  7  18  25
25  r r
 4   15 
Tn 1  Cr  x 5 
25
r 
   
4 r
25  25 r  
Cr x 5 5
100  5r
To be independent of x,  0  r  20
5
Hence, the required term is 25 C20
70. Centre C of the required circle lies on the perpendicular bisector of the line segment joining
(0,5)&(6,1)
The midpoint of line segment joining A &B IS(3,3)=D

2
Slope of AB is 
3
3
Slope of DC IS
2
 equation of DC is 3 x  2 y  3  0
5 
C is the point of intersection of 3 x  2 y  3  0 and 12 x  5 y  25  C   ,1
3 
25 13
Radius  AC   16 
9 3
2 2
 5  13 
 equation of the circle is  x     y  1   
2
 3  3
 3 x 2  3 y 2  10 x  6 y  45  0
71. Let  ,  ,  be the required roots       b,       c,    d

Also,     2   3  b
 b   b 
        c    2      c
 3   3 
2b 2 d 2b 2 d
  c  c
9  9 
b
3
2
2b 3d
   c  2b3  27 d  9bc
9 b
72. For Tr 1  nCr x r , coefficient  nCr
nCr 1 : nCr : nCr 1  1: 7 : 42
nCr 7 nC 42
  and r 1 
nCr 1 nCr 7
n  r 1 nr
  7 and 6
r r 1
 n  r  1  7 randn  r  6r  6
 n  8r  1andn  7 r  6
 8r  1  7 r  6  r  7
 n  55
2
73.
  2 x  1 4x2  4x
dx  2

dx

 2 x  1  2 x  1 1
2
1
 2  sec 1  2 x  1  c
2
74.
     3
      4
  4
 2 1 1 1
1  1
2
1
1 1  12
  2  1   2  1  2  1  1  1  2   1   2 
  2  1   2   2   2 2    2   2
  2  2   2 2   2  2 2   2   2   2 2   2   2
2
  2  2   2 2   2 2   
      
2
2         
2
 16  8  3  16
 56
 x  x
75. f  x    x   x  sin  x 
f  x   3x 3   x  3  sin  x  , x   3,4 
3
f '  x   3x 3 In3  3  x  3   cos  x 

3
7 3
 f '    3In3 
2 4
76. Equation of the given line is ax  by  c  1  0
 20ax  20by  20c  20  0..... i 
From the given relation, substituting value of c, we get,
20ax  20by  t  5a  4b  20  0
 1  1
 20a  x    20b  y     t  20   0
 4  5
1 1
Clearly for t  0 , the given line will pass through the point  ,  for all the values
 4 5
of a & b
77.

Let CP  r1 be inclined to transverse axis at an angle  such that P  r1 cos , r1 sin  

lies on the hyperbola. Therefore,
2  cos  sin 2  
2
r1  2  2   1
 a b 
Replacing  by 900   , we get,
2  sin  cos 2  
2
r2  2  2  1
 a b 
(Where, CQ  r2 )
1 1 cos 2  sin 2  sin 2  cos 2 
    2  
r12 r22 a2 b a2 b2
1 1  1 1  1 1
 2  2  cos 2   2  2   sin 2   2  2 
r1 r2 a b  a b 
1 1 1 1
 2 2 2 2
r1 r2 a b
1 1 1 1
 2
 2
 2 2
CP CQ a b
4 7 10
78. S  1   2  3  ...  ...1
5 5 5
S 1 4 7
 0   2  3  ...  ... 2 
5 5 5 5
On subtracting both the eq (1) and (2),
We get,
4 3 3
S  1   2  ...  
5 5 5
35
S
16
I  2   x sin  x   dx
1
79.
0
Now, x sin  x    0,1 as x   0,1

 sin  x    0

1
 I  2  0dx  0
0
80. We have p is false, q is true and r is also a true statement
1) p    q  r   T   F  T   F  F  F
2)  p   q  r   T  T  T   T  T  T
3)  p  q    r   F  T   F  F  F  F
4)  p  q    r   F  T   F  T  F  F
81.  f  x  is continuous at x  3
 LHL  RHL  f  3
 2  3  3    3  12
     4... 1
Also f  x  is differentiable at x  3
 at x  3LHD  RHD

.2      3 ....  2 
2 2  3  3
By 1 &  2 
  2,   6
x  p 1
82. I  dx
1  x  p 
q
Let, 1  x  p  t
1 dt
p  tq

t  q 1
 c
p 1  q 
2
 1

83. 2 cos 2   cos   1
 cos  1 
 2  cos 2    
 2 2
 1
2
7 
2  cos     
 4  16 
1
Given expression is maximum when cos   1 and minimum when cos   
4
  5 2 7   32  7 7
 M  2       2    4 and m  2   
  4  16   16   16  8
 
 M   32 
Hence,       4
m  7 

84.  
f  x   cos 1 sin x 3  4sin 2 x 

 cos 1 3sin x  4sin 2 x

f  x   cos 1  sin 3 x  
2
 sin 1 sin 3 x  
In the neighbourhood of
 
x   f  x      x 
3 2

f  x   3x 
2
 
 f '   3
3
In the neighbourhood of
 
x   f  x      x 
10 2
    3 
f    
 10  2 10 5
85.
1
 f  x  dx  shaded area
1
1 
 2  base.height 
2 
1 1 1
 2  .1.  
2 2 2
86.
dy
dx

 3 x2  4 x  3 
 3  x  2   1  3
2
 
So, minimum value is -3 when x  2 at x  2 , y  3
Hence, equation of tangent is 3 x  y  9
So, x-intercept = 3

 x3 
e.e x log  x  1
87. Given, lim e 
 sin 2 x 
3
x 
 x3 
e log  x  1
 2x
3
 lim  e   
1
x   sin 2 x  8
3 3
x 
 x
e 
1 e
 e  1 1 
8 8
 x 3

 x  0ifx   
 e 
88. Let,
S  3  7  13  21  31  43  ......  Tn 1  Tn
Subtracting both the equation , we get 0  3   4  6  8  10  ........  Tn  Tn 1    Tn
 Tn  3   4  6  8  10  .......  n  1 terms 
 n  1 8 
 3  n  2  2
2 
 3   n  1 4  n  2 
 3  n2  n  2
 n2  n  1
S n   Tn   n 2   n   1
n  n  1 2n  1 n  n  1
   nifn  50
6 2
50  51 101 50  51
Sn    50
6 2
 25 17 101  25  51  50
 44250
89. Given, f  3x   2 f  x 
Also ,  f  x  dx  1
1
0
1
f  3 x  dx  1
1
2 0

dt 1 3
Substituting , 3x  t , dx  , we get ,  f  t  dt  1
3 6 0
  f  t  dt  6
3
  f  t  dt   f  t  dt  6
1 3
0 1
  f  t  dt  6  1  5
3

5 2 5
90. The equation of the tangent to 3 x 2  2 y  5 in slope from is y  mx  m 
3 2
5 5
If it passes through (1,2) then  2  m   m 2 
2
3 2
2
2m 3
  4m   0
3 2
3
4
 m1  m2   & m1m2   2
2 2
3 3
9
 m1  m2  6 & m1m2  
4
 m1  m2   4m1m2
2
tan  
1  m1m2 
36  9 45 16 144
tan 2   2
   28.8
 5 25 5
 
 4

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Sec: OSR.

IIT_COSC GTM-39 Date: 30-05-21

SR.IIT_N-SC Page. No. 2

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M  M xiˆ  M z kˆ  M cos 60iˆ

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 Steady state current is

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Velocity of image of the point in the first mirror with respect to

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Conservation of linear momentum:

Newton’s experimental law:

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49. Co. number is 12 means it is fcc lattice

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52. Histidine, Valine, Lysine, Methionine

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Will give 20 alcohols on reaction with CH 3 MgBr .

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 x12  x22 .....x142  3225

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71. Let  ,  ,  be the required roots       b,       c,    d

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  2  1   2  1  2  1  1  1  2   1   2 

f '  x   3x 3 In3  3  x  3   cos  x 

SR.IIT_N-SC Page. No. 19

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Let CP  r1 be inclined to transverse axis at an angle  such that P  r1 cos , r1 sin  

Now, x sin  x    0,1 as x   0,1

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