b6-석유화학플랜트 (1 73)

HVAC/Plant Eng. Lab., Hanyang Univ.

비중확대
가스田 가스분리 에탄 에틸렌
천연가스
석유화학
原油처리 Naphtha Cracking Downstream

Saudi Arabia Market Trend

Terminology
Dehydration; i; iso
Sweetening; ( ) N; Normal
Stripper; MMSCFD; ft3/day
Cracking; ( -> ) Cascade process;
Visbraking; AR; Atmosphric Residiuum
Coking; ARU; Atmosphric Residiuum Unit
Reforming; ( ) OCU; Olefin’s Conversion Unit
Fractionator; FCC; Fluidized Catalytic Cracking
Molecular sieve; AR; Atmosphric Residuum
Hydrosulfurization; BTX; Bensen, Toluen, Xylen
BPSD; Baral per day
Flash; ,
C2; C 2

AA : Acetic Anhydride EBHP : Ethylbenzene Hydroperoxyde
AB : Akylbenzene EDC : Ethylene Dichloride
ABS : Acrylonitrile Butadiene Styrene EG : Ethylene Glycol
copolymer EH : Ethylhexanol
ACP : Acetophenone EO : Ethylene Oxide
ADN : Adiponitrile( ) EPDM: Ethylene Propylene Diene Monomer
AGO : Atmospheric Gas Oil EPR : Ethylene Propylene Rubber
AN : Acrylonitrile EPT: Ethylene Propylene Terpolymer
BDO : Butanediol( ) FCC : Fluid bed Catalytic Cracking
BPA : Bisphenol FRN : Full Range naphtha
BR : Butadiene Rubber FT : Fischer-Tropsch
BTX : Benzene Toluene Xylene HCN : Hydrogen Cyanide
CBA : 4-Carboxy benzaldehyde HAD : Hydrodealkylation
CHP : Cumene Hydroperoxide( ) HDPE : High Density Polyethylene
CTBN : Carboxy-terminated HMDA : Hexamethylenediamine
Butadiene Acrylonitrile HR : High Resiliency
DEA : Diethanolamine IPA : Isopropyl Alcohol
DIPA : Di-isopropylamine LAB : Linear Alkylbenzene
DMPC : Dimethylphenylcarbinol LAS : Linear Alkylbenzene Sulfonate
DMT : Dimethyl Therephthalate LDPE : Low Density Polyethylene

LGN : Liquefied Petroleum Gas PTAL : p-Tolualdehyde
LVN : Light Virgin naththa PCV : Polyvinyl Chloride
MA : Maleic Anhydride PX : Paraxylene
MDI : Methylene Diphenyl Diisocynate RIM : Reaction Injection Molding
MEA : Monoethanolamine RON : Research Octane Number
MEK : Methyl Ethyl Ketone ROSE : Residual Oil Supercritical
MFI : Melt Fluid Index Extraction
MMA : Methyl Methacrylate SAN : Styrene Acrylonitrile
MTBE : Methyl tert-Butyl Ether SBA : Sec-Butyl Alcohol
NBR : Acrylonitrile Butadiene Bubber SBR : Styrene Butadiene Rubber
NGL : Natural Gas Liquid SCP : Single Cell Protein
PA : Phthalic Anhydride SM : Stylene Monoma
PABA : p-Aminobenzoic Acid
SN : Sulfer Nitride
PAO : Poly-Alpha Olefin
TAME : tert-Amylmethyl Ether
PBT : Polybutylene Terephthalath
TBA : tert-Butyl Alcohol
PET : Polyethylene Terephthalath
TDI : Toluene Diisocyanate
PO; Propylene Oxide
TPA : Terephthalic Acid
PP : Polypropylene
TPR : Transpolypentamer Rubber
PS : Polystyrene
VCM : Vinyl Chloride Monomer
PTA : Pure Terephthalic Acid
VGO : Vacuum Gas Oil

HVAC/Plant Eng. Lab., Hanyang Univ. 4-9
HALLIBURTON
KBR

LDPE ,
HDPE , ,
EDC , ,
VCM PVC , ,
NAPHTHA
E O ,
GAS OIL
, ,
, ,
EPR ,
P P , ,
NAPHTHA , ABS, NBR

CRACKING PPG
CENTER ,
P O
P G
/ ,
, ,
. , ,
C4 M M A PMMA ,
To BTX Extraction Plant S B R , ,
SB-LATEX , ,
B R , ,
, ,

NAPHTHA
GAS OIL
SAN
MBS
NAPHTHA
CRACKING
CENTER P S , ,
S M ABS , ,
N-
/ /
MDI
M A , , FRP
BENZENE
EXTRACTION DNT TDI
PLANT
O-XYLENE P A ,
XYLENE
P-XYLENE TPA ,
DMT ,

STRATEGY FRAME - PLANT CATEGORY
Date : 2007-08-24
Gas Plant
No. Process Description Major Licensor Category Experience
A B C
1 H2 Hydrogen Plant CDTech, Haldor Topsoe •
2 H2/CO CO2 Removal from H2 rich gas Haldor Topsoe •
3 SRU Sulfur Recovery Unit TPA, Lurgi •
4 AGRP Acid Gas Removal Plant •
5 LNG Liquified Natural Gas Plant •
6 LPG Liquified Petroleum Gas Plant •
7 PSA Pressure Swing Absorption UOP, Linde •
Chemical Plant
No. Process Description Licensor Category Experience
A B C
1 AMMONIA & UREA Urea : Snamprogetti •
2 SULFURIC ACID Monsanto
•
3 NITRIC ACID
•
4 PHOSPHORIC ACID
•
5 SOLVENT RECOVERY Sumitomo Chemical •
6 ALCOHOL PROCESS •
7 DETERGENT •
8 주정공장 •
9 제지공장 •
10 MSG Mono Sodium Glutamate •
Industrial Plant
No. Process Description Licensor Category Experience
A B C
1 POWER PLANT •
2 저유소 •

Refinery Process
Process Description Major Licensor Category Experience
A B C
Topping
1. CDU or Topping Unit Crude Distillation Unit •
Unit
2. VDU Vacuum Distillation Unit •
•
3. GCU Gas Concentration Unit
Gas Recovery Unit
•
1. Naphtha HDS Naphtha Hydrosulfurization unit UOP: Unifiner
HDS Unit
IFP: NHT
2. Kerosene or Diesel HDS Kero/Diesel Hydrosulfurization unit UOP: MDU (Middle Distillate Unifiner) •
•
3. AR HDS Atmospheric Residuum Chevron
Hydrodesulfurization Unit
•
1. LPG Sweetening Unit LPG Sweetening UOP: LPG Merox
ing Unit
Sweeten
Merichem: Napfining unit
•
2. Naphtha Sweetening LSR Naphtha Sweetening
1. Reformer Reforming Unit UOP: Platformer
•
IFP: Aromizer
Reforming Unit
Chevron: Rheniformer
Engelhard: Magnaformer
2. Isomerization Paraffin Isomerization UOP, Shell
BP •
3. Alkylation Alkylation of Olefin with iso-paraffin UOP, Phillips
•
•
1. FCC/RFCC Fluid Catalytic Cracking Unit UOP: RCC
Upgrading
Heavy Oil
Residuum Fluid Catalytic Cracking Unit

Unit
2. VGO Hydrocracker Hydrocracking of H.C UOP: Hydrocracking

Unocal: Unicracking
Chevron: Isocracking
•
•
1. Visbreaking Unit Thermal cracking of H.C UOP : Thermal Process
Cracking
Thermal
Unit
•
2. Delayed Coker Thermal cracking to produce coke FW
1. Lube Base Oil Lube Base Oil Catalytic Dewaxing Unit Mobil, Chevron
•
Miscellaneous LBO
1. MTBE Methyl Tertiary Butyl Ether Unit UOP, IFP, BP, CDTech •
2. TAME Tertiary Amyl Methyl Ether CDTech •
3. SWTU Sour Water Treating Unit •
4. Residue Solvent Deasphalting Unit Solvent extraction of deasphalted oil KBR: ROSE Unit
from asphaltene rich feedstock (Residuum Oil Superextraction) •

Petrochemical Process
A B C
1 Ethylene Naphtha/Gas Oil Cracking Kellog, ABB Lummus,
Stone & Webster, Linde •
2 BTX Aromatics Benzene, Toluene, Xylene UOP, IFP
•
3 Tatoray BTX Aromatics UOP
•
4 Sulfolane BTX Aromatics UOP, Shell
•
5 Parex Selective adsorption of paraxylene UOP
•
6 Isomar Xylene Isomerization UOP
•
7 Butadiene Extraction Distillation BASF, Exxon, Shell
n-Butene Dehydrigenation Air Products, Nippon Zeon •
8 Benzene Benzene Recovery Krup Koppers
•
9 EB/SM Ethyl Benzene, Stylene Monomer Mobil, Monsanto, Basf, UOP
•
10 PO/SM Propylene Oxide, Stylene Monomer ABB Lummus, Union Carbide,
BASF, Mitsui Toatsu •
11 EO/EG Ethylene Oxide, Ethylene Glycol Snamprogetti, Union Carbide
•
12 TPA/DMT Terephthalic Acid/Dimethyl Amoco, Toray Industries,
terephthalate Maruzen Oil •
13 Caprolactam Caprolactam BASF, Toray Industries, Zimmer
•
14 Methanol Methyl Alcohol ICI, Snamprogetti, Lurgi, Kellog,
Haldor Topsoe, BASF •
15 Ethylamine DEA,MEA,MDEA,TEA
•
16 Ammonia Ammonia Kellog, Lurgi, Haldor Topsoe,
Snamprogetti, ICI, Uhde •

Polymer & Synthetic Rubber
A B C
1. PE Poly-Ethylene BASF, Sumimoto, Uhde, Mitsui,
Solvay •
2. PP Poly-Propylene BASF, Sumimoto, Uhde, Mitsui,
Solvay •
3. HDPE High Density Poly-Ethylene BP Chemical, Asahi Chemical,
Solvay, Mitsubishi Chemicals •
4. LDPE Low Density Poly-Ethylene BASF, Dow Chemical, ICI,
Snamprogetti, Sumimoto •
Polymer
5. LLDPE Linear Low Density Poly-Ethylene BP Chemical, BASF

•
6. PET PolyEthylene Terephthalate Eastman Chemical
•
7. ABS Acrylonitrile-Butadiene-Stylene resins Monsanto, Toray Industries,
Dow Chemicals •
8. PS Poly-Stylene
•
9. EPS Elastic Poly-Stylene
•
10. PVC Poly-Vinyl Chloride ATOCHEM, BASF, Mitsui Toatsu,
Solvay/ICI •
1. BR Butadiene Rubber BASF, Mitsui
•
2. SBR Styrene Buradiene Rubber Japan Syhthetic Rubber
•
3. EPR
•
Synthetic Rubber
4. EPDM
•
5. URETHANE
•
6. MNB
•
7. ANILINE
•
8. MDI
•
9. PUR
•

LNG생산공정 자료에서 설명

GTL 공정 흐름

GTL 세부공정

Deisobutanizer NC4 C4
Isomerization N-Butane
iC4
Alkylation Alkylate
C
MTBE MTBE
D
U
C4’s C3’s
LPG Propylene
Recovery Recovery Propylene
Propane
LPG
Sweetening
Gasoline LCN
Sweetening (FCC Gasoline)
VDU VGO FCC LCO
AR To Diesel HDS
Fuel Oil
Delayed Naphtha Naphtha Reformer

Coker HDS Feed
Gas Oil
GO HDS
VRDS
Naphtha
Visbreaker
Visbreaker
Residue
Fuel Oil

(Refinery) : Hydroskimming
LPG LPG Propane

Sweetening Sweetening
Butane
LSR LSR Naphtha H2

Sweetening
Naphtha
H2
*
Naphtha Naphtha Reformer Reformate Gasoline Gasoline
HDS Pool
H/S C Kerosene Kerosene

Sweetening Jet Fuel
Crude D
U H2 *
Kerosene
HDS Kerosene
H2
*
Diesel Diesel HDS Diesel
ARU SRP Sulfur
*
H2 LPG,NG H2 Plant
Naphtha H2
AR ARDS Low Sulfur

Fuel Oil
VDU VGO
VR Asphalt Asphalt
Blowing

(Refinery) : Residue Upgrading ; ARDS+RFCC
Deisobutanizer NC4 C4
Isomerization N-Butane
iC4
Alkylation Alkylate
MTBE MTBE
C
D LPG Propylene
U Recovery Recovery Propylene
Propane
LPG
Sweetening
Gasoline LCN
Sweetening (FCC Gasoline)
H
AR ARDS RFCC LCO

To Diesel HDS
Fuel Oil

나프텐의 탈수소 반응
나프텐의 이성화 탈수소 반응
파라핀의 이성화 반응
파라핀의 탄화 탈수소 반응
파라핀의 수소화 분해반응
코크스 생성 및 탈황반응
•
• 45 kg/cm2 ( 500°C)
• 3~4
• -
• ,
•
• : LPG
• : ( )
• : ,
• : ,


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HVAC/Plant Eng. Lab., Hanyang Univ.

HVAC/Plant Eng. Lab., Hanyang Univ.

HVAC/Plant Eng. Lab., Hanyang Univ.

HVAC/Plant Eng. Lab., Hanyang Univ.

HVAC/Plant Eng. Lab., Hanyang Univ.

HVAC/Plant Eng. Lab., Hanyang Univ.

HVAC/Plant Eng. Lab., Hanyang Univ.

HVAC/Plant Eng. Lab., Hanyang Univ.

NAPHTHA , ABS, NBR

To BTX Extraction Plant S B R , ,

HVAC/Plant Eng. Lab., Hanyang Univ.

HVAC/Plant Eng. Lab., Hanyang Univ.

HVAC/Plant Eng. Lab., Hanyang Univ.

Merichem: Napfining unit

1. Reformer Reforming Unit UOP: Platformer

Residuum Fluid Catalytic Cracking Unit

2. VGO Hydrocracker Hydrocracking of H.C UOP: Hydrocracking

HVAC/Plant Eng. Lab., Hanyang Univ.

HVAC/Plant Eng. Lab., Hanyang Univ.

5. LLDPE Linear Low Density Poly-Ethylene BP Chemical, BASF

HVAC/Plant Eng. Lab., Hanyang Univ.

HVAC/Plant Eng. Lab., Hanyang Univ.

HVAC/Plant Eng. Lab., Hanyang Univ.

HVAC/Plant Eng. Lab., Hanyang Univ.

Delayed Naphtha Naphtha Reformer

HVAC/Plant Eng. Lab., Hanyang Univ.

LPG LPG Propane

LSR LSR Naphtha H2

H/S C Kerosene Kerosene

AR ARDS Low Sulfur

HVAC/Plant Eng. Lab., Hanyang Univ.

AR ARDS RFCC LCO

HVAC/Plant Eng. Lab., Hanyang Univ.

HVAC/Plant Eng. Lab., Hanyang Univ.

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