SAFETY DATA SHEET

Issue date 30-Apr-20 Revision Date 30-Apr-20 Revision Number 1

Section 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE

COMPANY/UNDERTAKING
Product identifier
Product name Super Cleaner

Recommended use of the chemical and restrictions on use

Recommended use Cleaner

Details of the supplier of the safety data sheet

Supplier
ThreeBond Singapore Pte.Ltd.
Research and Development Department
5, Joo Koon Crescent, Jurong,
Singapore 629009

Emergency telephone number

TEL: 65-264-0022

Registration Number(s) No information available

Section 2: HAZARDS IDENTIFICATION

Classification of the substance or mixture
Aerosols Category 1
Skin corrosion/irritation Category 2
Eye damage/ irritation Category 2
Germ cell mutagenicity Category 1
Specific target organ toxicity (single exposure) Category 3 (Narcotic effects)
Specific target organ toxicity (repeated exposure) Category 2
Aspiration toxicity Category 1
Chronic aquatic toxicity Category 2

Label elements

Signal word Danger

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Hazard statements
H222 - Extremely flammable aerosol
H229 - Pressurized container: May burst if heated
H304 - May be fatal if swallowed and enters airways
H315 - Causes skin irritation
H319 - Causes serious eye irritation
H336 - May cause drowsiness or dizziness
H340 - May cause genetic defects
H361 – Suspected of damaging fertility or the unborn child
H373 - May cause damage to organs through prolonged or repeated exposure
H411 - Toxic to aquatic life with long lasting effects

Precautionary Statements - Prevention

• Obtain special instructions before use
• Do not handle until all safety precautions have been read and understood
• Use personal protective equipment as required
• Wash face, hands and any exposed skin thoroughly after handling
• Do not breathe dust/fume/gas/mist/vapors/spray
• Use only outdoors or in a well-ventilated area
• Avoid release to the environment.
• Keep away from heat/sparks/open flames/hot surfaces. — No smoking
• Do not spray on an open flame or other ignition source
• Do not pierce or burn, even after use
Precautionary Statements - Response
• IF exposed or concerned: Get medical advice/attention
• For first aid procedure, refer to this SDS.
• IF ON SKIN: Wash with plenty of soap and water
• If skin irritation occurs: Get medical advice/attention
• Take off contaminated clothing and wash before reuse
• IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
• IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician
• Do NOT induce vomiting
• Collect spillage
Precautionary Statements - Storage
• Store locked up
• Store in a well-ventilated place. Keep container tightly closed
• Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F
Precautionary Statements - Disposal
• Dispose of contents/container to an approved waste disposal plant

Other hazards which do not result in classification

• May be harmful in contact with skin

Section 3: COMPOSITION/INFORMATION ON INGREDIENTS

Chemical name CAS No Weight-%

Iso-Hexane 107-83-5 60 – 70
Liquified Petroleum Gas 68476-85-7 20 – 30
Absolute alcohol 64-17-5 3 – 10
Acetone 67-64-1 1 – 10
Carbon dioxide 124-38-9 2–5

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Section 4: FIRST AID MEASURES

Description of first aid measures

Eye contact For eyes, immediately flush with plenty of water for at least 15 minutes & call Physician.

Skin contact In case of contact with skin, wash thoroughly with soap and water. If irritation continues get
medical attention. Wash contaminated clothing before reuse. (May need to discard
contaminated shoes).

Inhalation After high vapor exposure, remove victim to fresh air. If breathing is difficult, give oxygen. If
breathing has stopped give artificial respiration. CALL A PHYSICIAN IMMEDIATELY!

Ingestion Call a physician or poison control center immediately for instruction. this material contains
both methanol and petroleum distillates. Aspiration of material into the lungs due to
vomiting can cause chemical pneumonitis which can be fatal.

For emergency responders

Self-protection of the first aider Ensure that medical personnel are aware of the material(s) involved and take precautions
to protect themselves

Most important symptoms and effects, both acute and delayed

Symptoms No information available

Indication of any immediate medical attention and special treatment needed

Note to physicians Keep victim warm and quiet

Section 5: FIRE FIGHTING MEASURES

Flammable properties
◦
Contents and propellant are inflammable. On the location above 50 C ,it may cause rupture

Suitable extinguishing media

Use extinguishing agent suitable for type of surrounding fire Dry chemical or CO2 Water spray, fog or regular foam Move
containers from fire area if you can do it without risk Damaged cylinders should be handled only by specialists

Unsuitable extinguishing media

No information available

Specific hazards arising from the chemical

Some may burn but none ignite readily Ruptured cylinders may rocket

Protective equipment and precautions for firefighters

Wear self-contained breathing apparatus and protective suit

Section 6: ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures
Personal precautions Do not touch or walk through spilled material Stop leak if you can do it without risk

Environmental precautions
Environmental precautions Use water spray to reduce vapors or divert vapor cloud drift. Avoid allowing water runoff to
contact spilled material Prevent entry into waterways, sewers, basements or confined areas
See Section 12 for additional ecological information

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Methods and material for containment and cleaning up

Methods for containment If possible, turn leaking containers so that gas escapes rather than liquid Allow substance
to evaporate

Methods for cleaning up Do not direct water at spill or source of leak

Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations.

Other information Ventilate the area

Section 7: HANDLING AND STORAGE

Precautions for safe handling
Advice on safe handling Ensure adequate ventilation, especially in confined areas

Conditions for safe storage, including any incompatibilities

Storage conditions Store in tightly closed containers in a cool, dry place, away from incompatible materials or
sources of heat, ignition or strong oxidizers. Ground and bond all transfer and storage
equipment. Empty containers may contain residue (liquid and/or vapor) and can be
dangerous. Do not pressurize, cut, puncture, incinerate, weld, braze, solder, drill, grind or
expose such containers to heat, flame, sparks or other sources of ignition; they may
◦
explode and cause injury or death. Do not store at temperatures above 50 C or in aluminum
storage vessels.

Incompatible materials Strong oxidizing agents

Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters

Exposure guidelines
Chemical name ACGIH TLV OSHA PEL Japan
Acetone STEL: 500 ppm TWA: 1000 ppm TWA: 200 ppm
3 3
67-64-1 TWA: 250 ppm TWA: 2400 mg/m TWA: 470 mg/m
(vacated) TWA: 750 ppm ISHL/ACL: 500 ppm
3
(vacated) TWA: 1800 mg/m
(vacated) STEL: 2400 mg/m3
The acetone STEL does not apply
to the cellulose acetate fiber
industry. It is in effect for all other
sectors.
(vacated) STEL: 1000 ppm
Absolute alcohol STEL: 1000 ppm TWA: 1000 ppm -
64-17-5 TWA: 1900 mg/m3
(vacated) TWA: 1000 ppm
(vacated) TWA: 1900 mg/m3

Appropriate engineering controls

Engineering controls Ensure adequate ventilation, especially in confined areas

Personal protective equipment

Eye/face protection Tight sealing safety goggles
Skin and body protection Suitable protective clothing
Hand protection Rubber gloves
Respiratory protection No information available

General hygiene considerations

Handle in accordance with good industrial hygiene and safety practice

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Section 9: PHYSICAL AND CHEMICAL PROPERTIES

Physical state Liquid
Odor Aliphatic solvent odor
Color Colorless
Property Values Remarks
pH No data available
Melting point/freezing point No data available
Boiling point / boiling range 60.3 °C
Flash point <-7 °C (Isohexane) /-104.4°C (LPG)
Evaporation rate No data available
Flammability (solid,
gas)
Flammability limit in air
Upper flammability limit: No data available
Lower flammability limit: No data available
Specific gravity 0.665-0.705
Water solubility Insoluble in water
Autoignition temperature No data available
Decomposition temperature No data available
Dynamic viscosity No data available

Section 10: STABILITY AND REACTIVITY

Stability Stable under normal conditions.

Possibility of hazardous reactions React with strong acid. Could cause fire.

Conditions to avoid Strong oxidizing agents, heat, sparks, arcs and flame.

Incompatible materials Strong oxidizing agents.

Hazardous decomposition products Carbon monoxide, carbon dioxide, and various hydrocarbons

Section 11: TOXICOLOGICAL INFORMATION

Product Information

Chemical name Oral LD50 Dermal LD50 Inhalation LC50

Acetone = 5800 mg/kg ( Rat ) > 15700 mg/kg ( Rabbit ) = 50100 mg/m3 ( Rat ) 8 h

Absolute alcohol = 7060 mg/kg ( Rat ) - = 124.7 mg/L ( Rat ) 4 h

Irritation May cause slight irritation

Corrosivity No information available

Sensitization No information available

Neurological effects No information available

Germ cell mutagenicity No information available

Developmental toxicity No information available

Target organ effects No information available

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Section 12: ECOLOGICAL INFORMATION

Ecotoxicity

Chemical name Algae/aquatic plants Fish Crustacea

Acetone - LC50: 4.74 - 6.33mL/L (96h,
Oncorhynchus mykiss) LC50: 6210 -
8120mg/L (96h, Pimephales
promelas) LC50: =8300mg/L (96h,
Lepomis macrochirus)
Absolute alcohol - LC50: 12.0 - 16.0mL/L (96h,
Oncorhynchus mykiss) LC50: 13400
- 15100mg/L (96h, Pimephales
promelas) LC50: >100mg/L (96h,
Pimephales promelas)
10294 - 17704: 48 h Daphnia
magna mg/L EC50 Static 12600 -
12700: 48 h Daphnia magna mg/L
EC50
EC50: =10800mg/L (24h, Daphnia
magna) EC50: =2mg/L (48h,
Daphnia magna)
9268 - 14221: 48 h Daphnia magna
mg/L LC50

Persistence and degradability No information available.

Bioaccumulation No information available.

Mobility No information available.

Chemical name Partition coefficient

Acetone -0.24
Absolute alcohol -0.32

Section 13: DISPOSAL CONSIDERATIONS

Waste from residues / unused Disposal should be in accordance with applicable regional, national and local laws and
products regulations

Section 14: TRANSPORT INFORMATION

IMDG
UN/ID No. UN1950
Proper shipping name Aerosols
Hazard class 2.1
EmS-No F-D, S-U
Marine pollutant P

ICAO/IATA (air)
UN/ID No. UN1950
Proper shipping name Aerosols
Hazard class 2.1

ADR
UN/ID No. UN1950
Proper shipping name Aerosols
Hazard class 2.1
Environmental hazard Yes

Section 15: REGULATORY INFORMATION

Follow all regulation in your country

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Section 16: OTHER INFORMATION

Key literature references and sources for data
ACGIH - Threshold Limit Values
U.S. - OSHA - Final PELs
Japan - Recommended Exposure Limits

Issue date 30-Apr-2020

Revision Date 30-Apr-2020

Revision note The symbol (*) in the margin of this SDS indicates that this line has been revised.

End of Safety Data Sheet

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