COL ICSD Collection Code 9368

DATE Recorded Aug 12, 1986; updated Aug 12, 1986

NAME Aluminium silicate hydroxide *
MINR Chlorite - from Novaya Zemlya
FORM Al4.5 (Al.8 Si3.2) O10 (O H)8
= H8 Al5.3 O18 Si3.2
FORM (Al4.10 Fe.05 Mg.08 Li.26) (Al.86 Si3.14) O10 (O H)8
TITL Structural features of Dioctahedral one-packet chlorite
REF Kristallografiya
KRISA 17 (1972) 525-532
AUT Aleksandrova V A, DritsÿVÿA, SokolovaÿGÿV
CELL a=5.174 b=8.956 c=14.260 à=90.0 á=97.8 ç=90.0
V=654.6 Z=2
SGR C 1 2 1 (5) - monoclinic
CLAS 2 (Hermann-Mauguin) - C2 (Schoenflies)
PRS mC69
ANX A8B9X36
PARM Atom__No OxStat Wyck ---X--- ---Y--- ---Z--- -SOF-
Al 1 3.000 2a 1/2 0.8333 0.
Al 2 3.000 2a 1/2 0.1666 0.
Al 3 3.000 2b 1/2 0.0055 1/2
Al 4 3.000 2b 1/2 0.3369 1/2
Al 5 3.000 2b 1/2 0.6723 1/2 0.5
Al 6 3.000 4c 0.3836 0.6697 0.191 0.4
Si 1 4.000 4c 0.3836 0.6697 0.191 0.6
Si 2 4.000 4c 0.3849 0.3293 0.192
O 1 -2.000 4c 0.3287 0.3056 0.0755
O 2 -2.000 4c 0.3321 0.693 0.078
O 3 -2.000 4c 0.1233 0.289 0.2341
O 4 -2.000 4c 0.474 0.4954 0.222
O 5 -2.000 4c 0.6141 0.223 0.2426
OH1 6 -2.000 4c 0.4118 -0.0027 0.0714
OH1 7 -2.000 4c 0.6185 0.1688 0.4261
OH1 8 -2.000 4c 0.1691 -0.016 0.4344
OH1 9 -2.000 4c 0.1642 0.3674 0.4257
H 1 1.000 16 Atoms not located in Unit Cell
WYCK c11 b3 a2
RVAL 0.099
TEST At least one temperature factor missing in the paper. (Code 53)
TEST Deviation of the charge sum from zero tolerable. (Code 22)

COL ICSD Collection Code 16732

DATE Recorded Aug 12, 1986; updated Mar 18, 1987
NAME Magnesium Iron(II) Iron(III) aluminium silicate hydroxide*
MINR Chlorite - from Waterworks Tunnel, Washington D.C.
FORM Mg2.5 Fe1.65 Al1.5 Si2.2 Al1.8 O10 (O H)8
= H8 Al3.3 Fe1.65 Mg2.5 O18 Si2.2
TITL The Crystal Structure of Chlorite. I. A Monoclinic Polymorph
REF Acta Crystallographica (1,1948-23,1967)
ACCRA 11 (1958) 191-195
AUT Steinfink H
CELL a=5.370 b=9.300 c=14.250 à=90.0 á=96.3 ç=90.0
V=707.4 Z=2
SGR C 1 2 1 (5) - monoclinic
CLAS 2 (Hermann-Mauguin) - C2 (Schoenflies)
PRS mC71
ANX A3BC2D4X18
PARM Atom__No OxStat Wyck ---X--- ---Y--- ---Z--- -SOF-
Mg 1 2.000 2a 0. 0. 0.
Mg 2 2.000 2a 0. 1/3 0. 0.75
Fe 1 3.000 2a 0. 1/3 0. 0.25
Fe 2 3.000 2a 0. 2/3 0. 0.9
Al 1 3.000 2b 0. 1/2 1/2 0.75
Fe 3 2.000 2b 0. 1/2 1/2 0.25
Al 2 3.000 2b 0. 1/6 1/2 0.75
Fe 4 2.000 2b 0. 1/6 1/2 0.25
Mg 3 2.000 2b 0. 5/6 1/2 0.75
Si 1 4.000 4c 0.226 1/2 0.193 0.3
Al 3 3.000 4c 0.226 1/2 0.193 0.7
Si 2 4.000 4c 0.226 1/6 0.193 0.8
Al 4 3.000 4c 0.226 1/6 0.193 0.2
O 1 -2.000 4c 0.19 0.17 0.072
O 2 -2.000 4c 0.19 1/2 0.072
O 3 -2.000 4c 0.017 0.068 0.235
O 4 -2.000 4c 0.517 0.117 0.235
O 5 -2.000 4c 0.192 0.328 -0.235
OH1 6 -2.000 4c 0.707 0.314 0.072
OH1 7 -2.000 4c 0.117 -0.025 0.435
OH1 8 -2.000 4c 0.157 1/3 0.435
OH1 9 -2.000 4c 0.117 0.683 -0.435
H 1 1.000 4c 16 Atoms not located in Unit Cell
WYCK c11 b3 a3
ITF Mg 1 B=1.7
ITF Mg 2 B=1.7
ITF Fe 1 B=1.7
ITF Fe 2 B=1.7
ITF Al 1 B=1.7
ITF Fe 3 B=1.7
ITF Al 2 B=1.7
ITF Fe 4 B=1.7
ITF Mg 3 B=1.7
ITF Si 1 B=1.7
ITF Al 3 B=1.7
ITF Si 2 B=1.7
ITF Al 4 B=1.7
ITF O 1 B=1.7
ITF O 2 B=1.7
ITF O 3 B=1.7
ITF O 4 B=1.7
ITF O 5 B=1.7
ITF O 6 B=1.7
ITF O 7 B=1.7
ITF O 8 B=1.7
ITF O 9 B=1.7
REM SFP (structure from projections)
RVAL 0.148
TEST Deviation of the charge sum from zero tolerable. (Code 22)
COL ICSD Collection Code 16733
DATE Recorded Aug 12, 1986; updated Aug 12, 1986
NAME Magnesium aluminium iron(III) iron(II) chromium silicate hydrate *
MINR Corundophilite - from the Mochako District, Kenya
MINR Chlorite
FORM Mg5.0 Al.6 Fe.4 Si2.5 Al1.5 O10 (O H)8
= H8 Al2.1 Fe.4 Mg5 O18 Si2.5
TITL The Crystal Structure of Chlorite. II. A Triclinic Polymorph
REF Acta Crystallographica (1,1948-23,1967)
ACCRA 11 (1958) 195-198
AUT Steinfink H
CELL a=5.340 b=9.270 c=14.360 à=90.0 á=97.4 ç=90.0
V=705.0 D=2.71 Z=2
SGR C 1 (1) - triclinic
CLAS 1 (Hermann-Mauguin) - C1 (Schoenflies)
PRS aC72
ANX A2B3X9
PARM Atom__No OxStat Wyck ---X--- ---Y--- ---Z--- -SOF-
Mg 1 2.000 2* 0. 0. 0. 0.8333
Mg 2 2.000 2* 0. 1/3 0. 0.8333
Mg 3 2.000 2* 0. 2/3 0. 0.8333
Mg 4 2.000 2* 0. 1/6 1/2 0.8333
Mg 5 2.000 2* 0. 1/2 1/2 0.8333
Mg 6 2.000 2* 0. 5/6 1/2 0.8333
Fe 1 3.000 2* 0. 0. 0. 0.0667
Fe 2 3.000 2* 0. 1/3 0. 0.0667
Fe 3 3.000 2* 0. 2/3 0. 0.0667
Fe 4 3.000 2* 0. 1/6 1/2 0.0667
Fe 5 3.000 2* 0. 1/2 1/2 0.0667
Fe 6 3.000 2* 0. 5/6 1/2 0.0667
Al 1 3.000 2* 0. 0. 0. 0.1
Al 2 3.000 2* 0. 1/3 0. 0.1
Al 3 3.000 2* 0. 2/3 0. 0.1
Al 4 3.000 2* 0. 1/6 1/2 0.1
Al 5 3.000 2* 0. 1/2 1/2 0.1
Al 6 3.000 2* 0. 5/6 1/2 0.1
Si 1 4.000 2* 0.27 0.332 -0.192 0.625
Si 2 4.000 2* 0.77 0.168 -0.192 0.625
Si 3 4.000 2* 0.237 0.503 0.192 0.625
Si 4 4.000 2* 0.735 0.337 0.192 0.625
Al 7 3.000 2* 0.27 0.332 -0.192 0.375
Al 8 3.000 2* 0.77 0.168 -0.192 0.375
Al 9 3.000 2* 0.237 0.503 0.192 0.375
Al 10 3.000 2* 0.735 0.337 0.192 0.375
O 1 -2.000 2* 0.01 0.406 0.233
O 2 -2.000 2* 0.53 0.443 0.233
O 3 -2.000 2* 0.71 0.168 0.233
O 4 -2.000 2* 0.99 0.268 -0.233
O 5 -2.000 2* 0.49 0.23 -0.233
O 6 -2.000 2* 0.803 0. -0.233
O 7 -2.000 2* 0.69 -0.002 0.072
O 8 -2.000 2* 0.69 0.668 0.072
 O 9 -2.000 2* 0.69 0.336 0.072
O 10 -2.000 2* 0.298 -0.004 -0.072
O 11 -2.000 2* 0.31 0.33 -0.072
O 12 -2.000 2* 0.81 1/6 -0.072
O 13 -2.000 2* 0.144 -0.007 0.433
O 14 -2.000 2* 0.143 0.673 0.433
O 15 -2.000 2* 0.14 0.335 0.433
O 16 -2.000 2* 0.851 -0.004 -0.433
O 17 -2.000 2* 0.858 0.676 -0.433
O 18 -2.000 2* 0.857 0.34 -0.433
H 1 1.000 16 Atoms not located in Unit Cell
REM REF (refinement of earlier measured intensity data)
RVAL 0.121
TEST Calculated density unusual but tolerable. (Code 23)
TEST At least one temperature factor missing in the paper. (Code 53)
TEST Deviation of the charge sum from zero tolerable. (Code 22)

COL ICSD Collection Code 26850

DATE Recorded Aug 8, 1986; updated Aug 8, 1986
NAME Dialuminium pentamagnesium trisilicate octahydroxide
MINR Leuchtenbergite - from Philipsburg, Mont.
MINR Chlorite
FORM Al2 Mg5 Si3 O10 (O H)8
= H8 Al2 Mg5 O18 Si3
TITL The Crystal Structure of the Chlorite Minerals.
REF Zeitschrift fuer Kristallographie, Kristallgeometrie,
Kristallphysik, Kristallchemie (-144,1977)
ZEKGA 88 (1934) 420-432
AUT McMurchy G C
CELL a=5.304 b=9.187 c=28.494 à=90.0 á=97.1 ç=90.0
V=1377.7 Z=4
SGR C 1 2/c 1 (15) - monoclinic
CLAS 2/m (Hermann-Mauguin) - C2h (Schoenflies)
PRS mC144
ANX A2B3X9
PARM Atom__No OxStat Wyck ---X--- ---Y--- ---Z--- -SOF-
Mg 1 2.000 4a 0. 0. 0. 0.8333
Al 1 3.000 4a 0. 0. 0. 0.1667
Mg 2 2.000 8f 0. 1/3 0. 0.8333
Al 2 3.000 8f 0. 1/3 0. 0.1667
Mg 3 2.000 4e 0. 1/6 1/4 0.8333
Al 3 3.000 4e 0. 1/6 1/4 0.1667
Mg 4 2.000 4a 0. -1/6 1/4 0.8333
Al 4 3.000 4a 0. -1/6 1/4 0.1667
Mg 5 2.000 4e 0. 1/2 1/4 0.8333
Al 5 3.000 4e 0. 1/2 1/4 0.1667
Si 1 4.000 8f -0.269 0. 0.094 0.75
Al 6 3.000 8f -0.269 0. 0.094 0.25
Si 2 4.000 8f -0.269 -1/3 0.094 0.75
Al 7 3.000 8f -0.269 -1/3 0.094 0.25
OH1 1 -2.000 8f -0.308 1/3 0.039
O 2 -2.000 8f -0.308 -1/3 0.039
O 3 -2.000 8f -0.308 0. 0.039
 O 4 -2.000 8f -0.006 0.083 0.114
O 5 -2.000 8f -0.006 -0.417 0.114
O 6 -2.000 8f -0.256 -1/6 0.114
OH1 7 -2.000 8f 0.142 0. 0.211
OH1 8 -2.000 8f 0.142 1/3 0.211
OH1 9 -2.000 8f 0.142 -1/3 0.211
H 1 1.000 8f 32 Atoms not located in Unit Cell
WYCK f12 e2 a2
REM XDP (X-ray diffraction from a powder)
TEST No R value given in the paper. (Code 51)
TEST At least one temperature factor missing in the paper. (Code 53)

COL ICSD Collection Code 33214

DATE Recorded Dec 6, 1984; updated Jun 25, 1985
NAME Aluminium iron magnesium titanium alumosilicate hydroxide *
MINR Chamosite
MINR Chlorite
FORM (Al0.76 Fe0.02 Fe1.73 Mg0.16 Ti0.15) (Si1.24 Al0.76) O5 (O H)4
= H4 Al1.52 Fe1.75 Mg.16 O9 Si1.24 Ti.15
TITL The crystal structure of some chamosite minerals
REF Mineralogical Magazine and Journal of the Mineralogical Society
(1876-1968)
MIASA 29 (1951) 502-522
AUT Brindley G W
CELL a=5.380 b=9.314 c=7.026 à=90.0 á=90.0 ç=120.0
V=304.9 Z=0
TEST Coordinates or space group or lattice parameters are not
determined. (Code 71)
TEST No R value given in the paper. (Code 51)

COL ICSD Collection Code 38503

DATE Recorded Jan 1, 1980; updated Aug 10, 1989
NAME Magnesium iron aluminium alumosilicate hydroxide*
MINR Daphnite - from the southern of Brieuc, Bretagne, France
MINR Chlorite
FORM Si4.5 Al3.5 Mg0.7 Fe9.5 Fe0.1 Al1.6 (O H)13.9 O0.2 O20
= H13.9 Al5.1 Fe9.6 Mg.7 O34.1 Si4.5
TITL Die Strukturen von Thuringit, Bavalit und Chamosit und ihre
Stellung in der Chloritgruppe
REF Zeitschrift fuer Kristallographie, Kristallgeometrie,
Kristallphysik, Kristallchemie (-144,1977)
ZEKGA 104 (1942) 142-159
AUT Engelhardt W von
CELL a=5.397 b=9.348 c=14.100 à=90.0 á=97.4 ç=90.0
V=705.4 Z=1
SGR C 1 2/m 1 (12) - monoclinic
CLAS 2/m (Hermann-Mauguin) - C2h (Schoenflies)
TEST No R value given in the paper. (Code 51)
TEST Coordinates or space group or lattice parameters are not
determined. (Code 71)
COL ICSD Collection Code 38943
DATE Recorded Nov 6, 1984; updated Jun 25, 1985
NAME Iron(III) phyllo-disilicate tetrahydroxide
MINR Chamosite
MINR Chlorite
FORM Fe2 (Si2 O5) (O H)4
= H4 Fe2 O9 Si2
TITL Mineralogy and crystal structure of chamosite
REF Nature (London)
NATUA 164 (1949) 319-320
AUT Brindley G W
CELL a=5.390 b=9.330 c=7.040 à=90.0 á=90.0 ç=120.0
V=306.6 Z=0
TEST No R value given in the paper. (Code 51)
TEST Coordinates or space group or lattice parameters are not
determined. (Code 71)

COL ICSD Collection Code 38944

DATE Recorded Nov 6, 1984; updated Jun 25, 1985
NAME Iron(III) phyllo-disilicate tetrahydroxide
MINR Chamosite
MINR Chlorite
FORM Fe2 (Si2 O5) (O H)4
= H4 Fe2 O9 Si2
TITL Mineralogy and crystal structure of chamosite
REF Nature (London)
NATUA 164 (1949) 319-320
AUT Brindley G W
CELL a=5.410 b=9.330 c=7.040 à=90.0 á=104.5 ç=90.0
V=344.0 Z=0
TEST No R value given in the paper. (Code 51)
TEST Coordinates or space group or lattice parameters are not
determined. (Code 71)

COL ICSD Collection Code 45247

DATE Recorded Jan 1, 1980; updated Jun 25, 1985
NAME Magnesium aluminium iron chromium silicon oxide hydroxide
(4.9/2.2/0.3/0.2/2.6/10/8)
MINR Corundophilite - from Mochako District, Kenya
MINR Chlorite
FORM (Mg4.9 Al0.8 Fe0.3 Cr0.2) (Si2.6 Al1.4) O10 (O H)8
= H8 Al2.2 Cr.2 Fe.3 Mg4.9 O18 Si2.6
TITL The crystal structures of the monoclinic and triclinic forms of
chlorite.
REF Acta Crystallographica (1,1948-23,1967)
ACCRA 10 (1957) 767
AUT Steinfink H
CELL a=5.340 b=9.270 c=14.360 à=90.0 á=97.4 ç=90.0
V=705.0 Z=2
SGR P 1 (1) - triclinic
CLAS 1 (Hermann-Mauguin) - C1 (Schoenflies)
TEST No R value given in the paper. (Code 51)
 TEST Coordinates or space group or lattice parameters are not
determined. (Code 71)

COL ICSD Collection Code 100230

DATE Recorded Dec 31, 1980
NAME MAGNESIUM ALUMINIUM IRON ALUMOSILICATE HYDROXIDE *
MINR Pennine
MINR Chlorite
FORM Mg9.8 Al1.6 Fe0.6 (Si6.32 Al1.68 O19.96) (O H)15.84
= H15.84 Al3.28 Fe.6 Mg9.8 O35.8 Si6.32
FORM Mg9.8 Al1.64 Fe0.57 Mn0.01 (Si6.32 Al1.68 O20) (O H)16
TITL A neutron diffraction study of a one layer triclinic chlorite
(penninite)
REF American Mineralogist
AMMIA 65 (1980) 349-352
AUT Joswig W, FuessÿH, RothbauerÿR, TakeuchiÿY, MasonÿSÿA
CELL a=5.327 b=9.232 c=14.399 à=90.0 á=97.2 ç=90.0
V=702.6 Z=1
SGR C -1 (2) - triclinic
CLAS -1 (Hermann-Mauguin) - Ci (Schoenflies)
PRS aC72
ANX A2B3X9
PARM Atom__No OxStat Wyck ---X--- ---Y--- ---Z--- -SOF-
Mg 1 2.000 2* 0. 0. 0. 0.8
Fe 1 2.000 2* 0. 0. 0. 0.1
Al 1 3.000 2* 0. 0. 0. 0.1
Mg 2 2.000 4* 0.0007 0.3336 -0.00004 0.8
Fe 2 2.000 4* 0.0007 0.3336 -0.00004 0.1
Al 2 3.000 4* 0.0007 0.3336 -0.00004 0.1
Mg 3 2.000 4* 0.0004 0.1667 0.5 0.875
Al 3 3.000 4* 0.0004 0.1667 0.5 0.125
Mg 4 2.000 2* 0. 1/2 1/2 0.75
Al 4 3.000 2* 0. 1/2 1/2 0.25
Si 1 4.000 4* 0.231 0.1672 0.1917 0.79
Al 5 3.000 4* 0.231 0.1672 0.1917 0.21
Si 2 4.000 4* 0.7314 0.0007 0.1917 0.79
Al 6 3.000 4* 0.7314 0.0007 0.1917 0.21
O 1 -2.000 4* 0.1932 0.1671 0.07697
O 2 -2.000 4* 0.6922 0.0002 0.07689
O 3 -2.000 4* 0.212 0.3341 0.23254
O 4 -2.000 4* 0.5114 0.1003 0.23259
O 5 -2.000 4* 0.0112 0.0676 0.23249
O 6 -2.000 4* 0.6914 0.3334 0.073 0.99(1)
O 7 -2.000 4* 0.1465 -0.0002 0.4301
O 8 -2.000 4* 0.1417 0.3346 0.4301
O 9 -2.000 4* 0.6413 0.1649 0.4301
H 1 1.000 4* 0.7139 0.3339 0.1399 0.93(2)
H 2 1.000 4* 0.1193 0.0054 0.3632
H 3 1.000 4* 0.1303 0.3353 0.3629
H 4 1.000 4* 0.6143 0.1594 0.3635
ÿ
TF Atom U(1,1) U(2,2) U(3,3) U(1,2) U(1,3) U(2,3)
Mg 1 0.0038 0.0051 0.0094 0.0015 0.0008 0.0006
 Fe 1 0.0038 0.0051 0.0094 0.0015 0.0008 0.0006
Al 1 0.0038 0.0051 0.0094 0.0015 0.0008 0.0006
Mg 2 0.0061 0.0052 0.0069 -0.0002 0.0002 -0.0003
Fe 2 0.0061 0.0052 0.0069 -0.0002 0.0002 -0.0003
Al 2 0.0061 0.0052 0.0069 -0.0002 0.0002 -0.0003
Mg 3 0.0051 0.0041 0.0122 0.0001 0.0016 0.0009
Al 3 0.0051 0.0041 0.0122 0.0001 0.0016 0.0009
Mg 4 0.0049 0.0051 0.0104 -0.0001 0.0011 -0.0004
Al 4 0.0049 0.0051 0.0104 -0.0001 0.0011 -0.0004
Si 1 0.0042 0.0026 0.0073 0.0005 0.0020 0.0011
Al 5 0.0042 0.0026 0.0073 0.0005 0.0020 0.0011
Si 2 0.0044 0.0019 0.0072 -0.0004 0.0012 -0.0011
Al 6 0.0044 0.0019 0.0072 -0.0004 0.0012 -0.0011
O 1 0.0053 0.0058 0.0064 -0.0008 0.0006 -0.0003
O 2 0.0059 0.0061 0.0066 0.0001 0.0015 0.0003
O 3 0.0209 0.0091 0.0119 0.0010 0.0040 -0.0001
O 4 0.0143 0.0169 0.0110 0.0038 0.0008 -0.0014
O 5 0.0135 0.0185 0.0107 -0.0029 0.0013 0.0010
O 6 0.0073 0.0061 0.0064 0.0015 0.0011 0.0004
O 7 0.0164 0.0133 0.0075 0.0002 0.0009 0.0006
O 8 0.0170 0.0142 0.0074 0.0000 0.0018 -0.0006
O 9 0.0104 0.0147 0.0090 0.0007 0.0001 -0.0005
H 1 0.0360 0.0364 0.0046 0.0017 -0.0002 -0.0005
H 2 0.0381 0.0384 0.0100 -0.0014 0.0034 0.0002
H 3 0.0430 0.0380 0.0115 0.0000 0.0010 -0.0001
H 4 0.0381 0.0383 0.0175 0.0041 0.0012 -0.0011
REM NDS (neutron diffraction from a single crystal)
RVAL 0.024
TEST Difference between the formula calculated from the PARM record and
the FORM record tolerable. (Code 21)
TEST Deviation of the charge sum from zero tolerable. (Code 22)
TEST Deviation of the charge sum from zero tolerable. (Code 22)

COL ICSD Collection Code 63193

DATE Recorded Jun 8, 1990
NAME Magnesium aluminium iron(III) iron chromium nickel alumosilicate
hydroxide * - IIb-4
MINR Chlorite - from Kinyiki Hill, Mochako Destrict, Kenya
FORM (Mg4.715 Al.694 Fe.269 Fe.109 Cr.128 Ni.011) (Si3.056 Al.944) O10
(O H)8
= H8 Al1.638 Cr.128 Fe.378 Mg4.715 Ni.011 O18 Si3.056
TITL Structures of intergrowth triclinic and monoclinic IIb chlorites
from Kenya
REF Clays and Clay Minerals (29,1981-)
CLCMA 37 (1989) 308-316
AUT Zheng H, BaileyÿSÿW
CELL a=5.328 b=9.228 c=14.368 à=90.5 á=97.4 ç=90.0
V=700.5 Z=2
SGR C -1 (2) - triclinic
CLAS -1 (Hermann-Mauguin) - Ci (Schoenflies)
PRS aC72
ANX A2B8C9X36
PARM Atom__No OxStat Wyck ---X--- ---Y--- ---Z--- -SOF-
 Mg 1 2.000 2a 0. 0. 0. 0.715
Mg 2 2.000 4* 0.0012 0.3338 0.
Mg 3 2.000 4* -0.0005 0.1667 0.5
Al 1 3.000 2* 0. 1/2 1/2 0.694
Fe 1 3.000 2* 0. 1/2 1/2 0.269
Fe 2 2.000 2* 0. 1/2 1/2 0.109
Cr 1 2.000 2* 0. 1/2 1/2 0.128
Ni 1 2.000 2* 0. 1/2 1/2 0.011
Si 1 4.000 4* 0.2328 0.1692 0.1922 0.764
Al 2 3.000 4* 0.2328 0.1692 0.1922 0.236
Si 2 4.000 4* 0.7336 0.0023 0.1921 0.764
Al 3 3.000 4* 0.7336 0.0023 0.1921 0.236
OH1 1 -2.000 4* 0.6922 0.334 0.0741
OH1 2 -2.000 4* 0.1595 -0.0012 0.4299
OH1 3 -2.000 4* 0.1339 0.3406 0.4298
OH1 4 -2.000 4* 0.6336 0.1565 0.4305
O 5 -2.000 4* 0.1936 0.1673 0.0771
O 6 -2.000 4* 0.6931 0.0008 0.0773
O 7 -2.000 4* 0.2114 0.3363 0.2333
O 8 -2.000 4* 0.5145 0.1034 0.2336
O 9 -2.000 4* 0.0152 0.0687 0.2335
H 1 1.000 4* 0.705 1/3 0.13
H 2 1.000 4* 0.127 0.018 0.368
H 3 1.000 4* 0.131 0.341 0.37
H 4 1.000 4* 0.595 0.15 0.369
WYCK a
ÿ
TF Atom á(1,1) á(2,2) á(3,3) á(1,2) á(1,3) á(2,3)
Mg 1 0.0032 0.0014 0.0011 0.0014 0.0002 0.0002
Mg 2 0.0033 0.0014 0.0012 0.0012 0.0004 0.0001
Mg 3 0.0032 0.0013 0.0015 0.0013 0.0005 0.0001
Al 1 0.0052 0.0021 0.0016 0.0014 0.0004 0.0001
Fe 1 0.0052 0.0021 0.0016 0.0014 0.0004 0.0001
Fe 2 0.0052 0.0021 0.0016 0.0014 0.0004 0.0001
Cr 1 0.0052 0.0021 0.0016 0.0014 0.0004 0.0001
Ni 1 0.0052 0.0021 0.0016 0.0014 0.0004 0.0001
Si 1 0.0053 0.0021 0.0015 0.0015 0.0004 0.0002
Al 2 0.0053 0.0021 0.0015 0.0015 0.0004 0.0002
Si 2 0.0054 0.0021 0.0015 0.0015 0.0004 0.0002
Al 3 0.0054 0.0021 0.0015 0.0015 0.0004 0.0002
O 1 0.0068 0.0029 0.0016 0.0018 0.0007 0.0002
O 2 0.0107 0.0031 0.0014 0.0012 0.0004 0.0001
O 3 0.0094 0.0037 0.0014 0.0011 0.0004 0.0001
O 4 0.0093 0.0037 0.0014 0.0022 0.0005 0.0000
O 5 0.0059 0.0026 0.0015 0.0016 0.0004 0.0002
O 6 0.0063 0.0026 0.0016 0.0018 0.0005 0.0001
O 7 0.0157 0.0041 0.0019 0.0015 0.0006 0.0000
O 8 0.0119 0.0052 0.0019 0.0027 0.0004 0.0001
O 9 0.0126 0.0051 0.0019 0.0009 0.0002 0.0002
RVAL 0.042
TEST Deviation of the charge sum from zero tolerable. (Code 22)
TEST At least one temperature factor missing in the paper. (Code 53)
 COL ICSD Collection Code 65719
DATE Recorded Jun 8, 1990
NAME Magnesium aluminium iron(III) iron chromium nickel phyllo-
alumosilicate hydroxide *
MINR Clinochlore - from Kinyiki Hill, Mochako Destrict, Kenya
MINR Chlorite
FORM (Mg4.715 Al.694 Fe.269 Fe.109 Cr.128 Ni.011) (Si3.056 Al.944) O10
(O H)8
= H8 Al1.638 Cr.128 Fe.378 Mg4.715 Ni.011 O18 Si3.056
TITL Structures of intergrowth triclinic and monoclinic IIb chlorites
from Kenya
REF Clays and Clay Minerals (29,1981-)
CLCMA 37 (1989) 308-316
AUT Zheng H, BaileyÿSÿW
CELL a=5.328 b=9.228 c=14.363 à=90.0 á=96.8 ç=90.0
V=701.2 Z=2
SGR C 1 2/m 1 (12) - monoclinic
CLAS 2/m (Hermann-Mauguin) - C2h (Schoenflies)
PRS mC72
ANX A2B8C9X36
PARM Atom__No OxStat Wyck ---X--- ---Y--- ---Z--- -SOF-
Mg 1 2.000 2a 0. 0. 0. 0.715
Mg 2 2.000 4g 0. 0.3327 0.
Mg 3 2.000 4h 0. 0.1665 1/2
Al 1 3.000 2d 0. 1/2 1/2 0.694
Fe 1 3.000 2d 0. 1/2 1/2 0.269
Fe 2 2.000 2d 0. 1/2 1/2 0.109
Cr 1 2.000 2d 0. 1/2 1/2 0.128
Ni 1 2.000 2d 0. 1/2 1/2 0.011
Si 1 4.000 8j 0.2279 0.1667 0.1918 0.764
Al 2 3.000 8j 0.2279 0.1667 0.1918 0.236
OH1 1 -2.000 4i 0.1889 1/2 0.074
OH1 2 -2.000 4i 0.1542 0. 0.4299
OH1 3 -2.000 8j 0.1394 0.339 0.4297
O 4 -2.000 8j 0.191 0.1669 0.077
O 5 -2.000 4i 0.2064 0. 0.2331
O 6 -2.000 8j 0.5074 0.2325 0.2333
H 1 1.000 4i 0.261 1/2 0.128
H 2 1.000 4i 0.141 0. 0.368
H 3 1.000 8j 0.171 0.276 0.401
WYCK j4 i3 h g d a
ÿ
TF Atom á(1,1) á(2,2) á(3,3) á(1,2) á(1,3) á(2,3)
Mg 1 0.0036 0.0014 0.0009 0.0000 0.0007 0.0000
Mg 2 0.0031 0.0015 0.0010 0.0000 0.0005 0.0000
Mg 3 0.0020 0.0013 0.0011 0.0000 0.0004 0.0000
Al 1 0.0116 0.0041 0.0023 0.0000 0.0007 0.0000
Fe 1 0.0116 0.0041 0.0023 0.0000 0.0007 0.0000
Fe 2 0.0116 0.0041 0.0023 0.0000 0.0007 0.0000
Cr 1 0.0116 0.0041 0.0023 0.0000 0.0007 0.0000
Ni 1 0.0116 0.0041 0.0023 0.0000 0.0007 0.0000
Si 1 0.0048 0.0020 0.0011 0.0001 0.0004 0.0001
Al 2 0.0048 0.0020 0.0011 0.0001 0.0004 0.0001
O 1 0.0064 0.0027 0.0012 0.0000 0.0009 0.0000
 O 2 0.0137 0.0033 0.0012 0.0000 0.0004 0.0000
O 3 0.0105 0.0046 0.0014 -0.0008 0.0002 -0.0002
O 4 0.0052 0.0026 0.0013 0.0002 0.0007 -0.0001
O 5 0.0151 0.0039 0.0015 0.0000 0.0010 0.0000
O 6 0.0110 0.0052 0.0016 -0.0008 0.0004 0.0001
REM POL IIb-2
RVAL 0.059
TEST Deviation of the charge sum from zero tolerable. (Code 22)
TEST At least one temperature factor missing in the paper. (Code 53)

COL ICSD Collection Code 68942

DATE Recorded Jan 20, 1992
NAME Magnesium aluminium iron(II) iron(III) manganese phyllo-
alumosilicate hydroxide *
MINR Clinochlore - from Achmatow mine, Ural, USSR
MINR Chlorite
FORM Mg4.54 Al0.97 Fe0.46 Mn0.03 (Si2.85 Al1.15 O10) (O H)8
= H8 Al2.12 Fe.46 Mg4.54 Mn.03 O18 Si2.85
TITL Refinement of a one-layer triclinic chlorite
REF Clays and Clay Minerals (29,1981-)
CLCMA 38 (1990) 216-218 Issue 2
AUT Joswig W, FuessÿH
CELL a=5.325 b=9.234 c=14.358 à=90.3 á=97.4 ç=90.0
V=700.1 Z=2
SGR C -1 (2) - triclinic
CLAS -1 (Hermann-Mauguin) - Ci (Schoenflies)
PRS aC72
ANX AB4C5X18
PARM Atom__No OxStat Wyck ---X--- ---Y--- ---Z--- -SOF-
Mg 1 2.000 2a 0. 0. 0. 0.908
Fe 1 2.000 2a 0. 0. 0. 0.056
Fe 2 3.000 2a 0. 0. 0. 0.036
Mg 2 2.000 4i 0.00127 0.33382 0.00003 0.908
Fe 3 2.000 4i 0.00127 0.33382 0.00003 0.056
Fe 4 3.000 4i 0.00127 0.33382 0.00003 0.036
Si 1 4.000 4i 0.23211 0.16809 0.19257 0.712
Al 1 3.000 4i 0.23211 0.16809 0.19257 0.288
Si 2 4.000 4i 0.73204 0.00138 0.19252 0.712
Al 2 3.000 4i 0.73204 0.00138 0.19252 0.288
O 1 -2.000 4i 0.1925 0.1679 0.077
O 2 -2.000 4i 0.6927 0.0008 0.0769
O 3 -2.000 4i 0.2081 0.3348 0.2337
O 4 -2.000 4i 0.5146 0.1033 0.2341
O 5 -2.000 4i 0.0153 0.0664 0.2338
O 6 -2.000 4i 0.6919 0.3338 0.0733
H 1 1.000 4i 0.717 0.34 0.135
Mg 3 2.000 4i 0.99956 0.16666 0.49994 0.908
Fe 5 2.000 4i 0.99956 0.16666 0.49994 0.056
Fe 6 3.000 4i 0.99956 0.16666 0.49994 0.036
Al 3 3.000 2g 0. 1/2 1/2 0.97
Mn 1 2.000 2g 0. 1/2 1/2 0.03
O 7 -2.000 4i 0.1528 -0.0007 0.4301
O 8 -2.000 4i 0.1374 0.337 0.4302
 O 9 -2.000 4i 0.6382 0.1617 0.4306
H 2 1.000 4i 0.128 -0.001 0.369
H 3 1.000 4i 0.125 0.335 0.375
H 4 1.000 4i 0.613 0.151 0.369
WYCK i13 g a
ITF H 1 U=0.02
ITF H 2 U=0.02
ITF H 3 U=0.02
ITF H 4 U=0.02
ÿ
TF Atom U(1,1) U(2,2) U(3,3) U(1,2) U(1,3) U(2,3)
Mg 1 0.0048 0.0047 0.0096 0.0005 0.0009 0.0004
Fe 1 0.0048 0.0047 0.0096 0.0005 0.0009 0.0004
Fe 2 0.0048 0.0047 0.0096 0.0005 0.0009 0.0004
Mg 2 0.0044 0.0052 0.0098 -0.0002 0.0012 0.0006
Fe 3 0.0044 0.0052 0.0098 -0.0002 0.0012 0.0006
Fe 4 0.0044 0.0052 0.0098 -0.0002 0.0012 0.0006
Si 1 0.0059 0.0051 0.0093 -0.0002 0.0013 0.0005
Al 1 0.0059 0.0051 0.0093 -0.0002 0.0013 0.0005
Si 2 0.0059 0.0055 0.0088 0.0001 0.0014 0.0001
Al 2 0.0059 0.0055 0.0088 0.0001 0.0014 0.0001
O 1 0.0078 0.0082 0.0114 -0.0008 0.0020 0.0002
O 2 0.0082 0.0082 0.0113 0.0002 0.0012 0.0005
O 3 0.0192 0.0129 0.0154 -0.0004 0.0030 0.0001
O 4 0.0101 0.0180 0.0159 0.0038 0.0019 -0.0007
O 5 0.0124 0.0193 0.0162 -0.0037 0.0010 0.0012
O 6 0.0106 0.0102 0.0112 0.0012 0.0025 0.0011
Mg 3 0.0066 0.0069 0.0144 -0.0004 0.0018 0.0006
Fe 5 0.0066 0.0069 0.0144 -0.0004 0.0018 0.0006
Fe 6 0.0066 0.0069 0.0144 -0.0004 0.0018 0.0006
Al 3 0.0033 0.0038 0.0101 -0.0009 0.0012 0.0005
Mn 1 0.0033 0.0038 0.0101 -0.0009 0.0012 0.0005
O 7 0.0169 0.0166 0.0120 -0.0030 0.0012 0.0012
O 8 0.0195 0.0184 0.0096 -0.0014 0.0015 0.0001
O 9 0.0120 0.0182 0.0112 0.0064 0.0008 -0.0013
REM POL IIb-4
RVAL 0.047

COL ICSD Collection Code 66258

DATE Recorded Aug 20, 1992
NAME Magnesium iron aluminium iron(III) phyllo-alumosilicate hydroxide *
MINR Clinochlore - from Wisconsin Geology Museum Nr.1769/6, U.S.A.
MINR Chlorite
FORM (Mg2.96 Fe1.55 Fe.136 Al1.275) (Si2.622 Al1.376 O10) (O H)8
= H8 Al2.651 Fe1.686 Mg2.96 O18 Si2.622
FORM (Mg2.847 Fe1.533 Fe.222 Al1.316 Cr.002) (Si2.622 Al1.378 O10) (O
H)8
TITL Refinement of the crystal structure of a monoclinic ferroan
clinochlore
REF Clays and Clay Minerals (29,1981-)
CLCMA 35 (1987) 129-138
AUT Rule A C, BaileyÿSÿW
CELL a=5.350 b=9.267 c=14.270 à=90.0 á=96.3 ç=90.0
 V=703.1 Z=2
SGR C 1 2/m 1 (12) - monoclinic
CLAS 2/m (Hermann-Mauguin) - C2h (Schoenflies)
PRS mC72
ANX AB4C5X18
PARM Atom__No OxStat Wyck ---X--- ---Y--- ---Z--- -SOF-
Mg 1 2.000 2a 0. 0. 0. 0.5
Fe 1 2.000 2a 0. 0. 0. 0.39
Al 1 3.000 2a 0. 0. 0. 0.07
Mg 2 2.000 4g 0. 0.3322 0. 0.59
Fe 2 2.000 4g 0. 0.3322 0. 0.26
Al 2 3.000 4g 0. 0.3322 0. 0.08
Fe 3 3.000 4g 0. 0.3322 0. 0.068
OH1 1 -2.000 4i 0.185 1/2 0.0743
O 2 -2.000 8j 0.189 0.1667 0.0774
Si 1 4.000 8j 0.2248 0.1669 0.1937 0.656
Al 3 3.000 8j 0.2248 0.1669 0.1937 0.344
O 3 -2.000 4i 0.197 0. 0.2357
O 4 -2.000 8j 0.511 0.228 0.2363
OH1 5 -2.000 4i 0.172 0. 0.4289
OH1 6 -2.000 8j 0.131 0.3463 0.4285
Mg 3 2.000 4h 0. 0.1664 1/2 0.64
Fe 4 2.000 4h 0. 0.1664 1/2 0.32
Al 4 3.000 4h 0. 0.1664 1/2 0.04
Al 5 3.000 2d 0. 1/2 1/2 0.965
H 1 1.000 4i 0.2113 1/2 0.1448
H 2 1.000 4i 0.1623 0. 0.3661
H 3 1.000 8j 0.1586 0.3359 0.3698
WYCK j4 i3 h g d a
ITF H 1 B=2.
ITF H 2 B=2.
ITF H 3 B=2.
ÿ
TF Atom á(1,1) á(2,2) á(3,3) á(1,2) á(1,3) á(2,3)
Mg 1 0.0038 0.0026 0.0030 0.0000 0.0009 0.0000
Fe 1 0.0038 0.0026 0.0030 0.0000 0.0009 0.0000
Al 1 0.0038 0.0026 0.0030 0.0000 0.0009 0.0000
Mg 2 0.0051 0.0029 0.0031 0.0000 0.0010 0.0000
Fe 2 0.0051 0.0029 0.0031 0.0000 0.0010 0.0000
Al 2 0.0051 0.0029 0.0031 0.0000 0.0010 0.0000
Fe 3 0.0051 0.0029 0.0031 0.0000 0.0010 0.0000
O 1 0.0098 0.0057 0.0033 0.0000 0.0013 0.0000
O 2 0.0093 0.0044 0.0037 0.0004 0.0010 0.0000
Si 1 0.0058 0.0034 0.0030 0.0001 0.0005 -0.0001
Al 3 0.0058 0.0034 0.0030 0.0001 0.0005 -0.0001
O 3 0.0125 0.0046 0.0044 0.0000 0.0016 0.0000
O 4 0.0088 0.0061 0.0049 -0.0006 0.0013 0.0000
O 5 0.0071 0.0042 0.0031 0.0000 0.0001 0.0000
O 6 0.0067 0.0045 0.0032 0.0002 0.0009 -0.0004
Mg 3 0.0035 0.0033 0.0035 0.0000 0.0070 0.0000
Fe 4 0.0035 0.0033 0.0035 0.0000 0.0070 0.0000
Al 4 0.0035 0.0033 0.0035 0.0000 0.0070 0.0000
Al 5 0.0039 0.0033 0.0030 0.0000 0.0006 0.0000
REM F POL IIb-2
 RVAL 0.076
TEST Deviation of the charge sum from zero tolerable. (Code 22)

COL ICSD Collection Code 74009

DATE Recorded Jan 10, 1995
NAME Magnesium aluminium iron phyllo-alumosilicate hydroxide *
MINR Clinochlore (Cr-bearing) - from Day Book Body, North Carolina,
U.S.A.
MINR Chlorite
FORM (Mg0.99 Al0.01)5 (Al0.67 Fe0.33) (Si3.02 Al0.98) O10 (O H)8
= H8 Al1.7 Fe.33 Mg4.95 O18 Si3.02
TITL Inferred limitations to the oxidation of Fe in chlorite: a high-
temperature single-crystal X-ray study
REF American Mineralogist
AMMIA 78 (1993) 1197-1207
AUT Nelson D O, GuggenheimÿS
CELL a=5.344 b=9.256 c=14.422 à=90.3 á=97.3 ç=90.0
V=707.6 Z=2
SGR C -1 (2) - triclinic
CLAS -1 (Hermann-Mauguin) - Ci (Schoenflies)
PRS aC72
ANX AB4C5X18
PARM Atom__No OxStat Wyck ---X--- ---Y--- ---Z--- -SOF-
Mg 1 2.000 2a 0. 0. 0. 0.99
Al 1 3.000 2a 0. 0. 0. 0.01
Mg 2 2.000 4i 0.0007 0.3337 0. 0.99
Al 2 3.000 4i 0.0007 0.3337 0. 0.01
Mg 3 2.000 4i -0.0008 0.167 0.5 0.99
Al 3 3.000 4i -0.0008 0.167 0.5 0.01
Al 4 3.000 2g 0. 1/2 1/2 0.67
Fe 1 2.790 2g 0. 1/2 1/2 0.33
Si 1 4.000 4i 0.2316 0.1678 0.1914 0.755
Al 5 3.000 4i 0.2316 0.1678 0.1914 0.245
Si 2 4.000 4i 0.7315 0.0011 0.1914 0.755
Al 6 3.000 4i 0.7315 0.0011 0.1914 0.245
OH1 1 -2.000 4i 0.6915 0.3332 0.0727
OH1 2 -2.000 4i 0.1475 -0.0007 0.4296
OH1 3 -2.000 4i 0.1405 0.3346 0.4295
OH1 4 -2.000 4i 0.6403 0.163 0.43
O 5 -2.000 4i 0.1949 0.1671 0.0772
O 6 -2.000 4i 0.6938 0.0004 0.0766
O 7 -2.000 4i 0.2212 0.3325 0.2325
O 8 -2.000 4i 0.5079 0.0948 0.2323
O 9 -2.000 4i 0.0102 0.0731 0.233
H 1 1.000 4i 0.232 0.848 0.142
H 2 1.000 4i 1/6 0.977 0.36
H 3 1.000 4i 0.115 0.305 0.367
H 4 1.000 4i 0.616 0.149 0.365
WYCK i13 g a
ÿ
TF Atom U(1,1) U(2,2) U(3,3) U(1,2) U(1,3) U(2,3)
Mg 1 0.0050 0.0060 0.0280 0.0050 0.0030 -0.0010
Al 1 0.0050 0.0060 0.0280 0.0050 0.0030 -0.0010
 Mg 2 0.0050 0.0040 0.0290 0.0040 0.0040 0.0000
Al 2 0.0050 0.0040 0.0290 0.0040 0.0040 0.0000
Mg 3 0.0050 0.0070 0.0280 0.0030 0.0040 0.0000
Al 3 0.0050 0.0070 0.0280 0.0030 0.0040 0.0000
Al 4 0.0270 0.0350 0.0470 0.0020 0.0050 0.0000
Fe 1 0.0270 0.0350 0.0470 0.0020 0.0050 0.0000
Si 1 0.0040 0.0070 0.0240 0.0030 0.0030 -0.0010
Al 5 0.0040 0.0070 0.0240 0.0030 0.0030 -0.0010
Si 2 0.0060 0.0100 0.0280 0.0060 0.0040 0.0000
Al 6 0.0060 0.0100 0.0280 0.0060 0.0040 0.0000
O 1 0.0040 0.0120 0.0320 0.0040 0.0040 0.0000
O 2 0.0240 0.0210 0.0320 -0.0010 0.0010 0.0000
O 3 0.0300 0.0210 0.0220 0.0020 0.0000 -0.0020
O 4 0.0190 0.0200 0.0330 0.0100 0.0060 -0.0010
O 5 0.0030 0.0090 0.0270 0.0040 0.0020 0.0010
O 6 0.0060 0.0090 0.0300 0.0060 0.0060 0.0010
O 7 0.0280 0.0190 0.0410 0.0020 0.0080 0.0010
O 8 0.0120 0.0320 0.0430 0.0130 0.0050 0.0010
O 9 0.0230 0.0260 0.0320 -0.0060 0.0050 0.0000
REM TEM 823
RVAL 0.085
TEST At least one temperature factor missing in the paper. (Code 53)