P Hazard Identification and Risk Assessment 6 Honeman Close Huntingwood Arcidiacono

Hazard Identification
and Risk Assessment
Prepared for
John and Anna Arcidiacono
BP Huntingwood
6 Honeman Close, Huntingwood, NSW
Date: 13/07/2017
Project No: 11034 Revision: A
Cadway Project No 10909

Enviropacific Services Pty Ltd 11034 – BP Huntingwood - NSW
Prepared by:
Authored by Approved by Approval Date
C. Karageorgos C. Rogers 14/07/17
History:
Rev Nature of Change/Issue Author Date
A Issued for DA C. Karageorgos 14/07/17
Disclaimer
This report is based on information provided by the Client in terms of the types of dangerous goods and the
quantities to be stored and handled on site. A facility management plan shall include the quantities of
dangerous goods stored and any relevant information contained in this report so that users are aware of these
requirements. This report assesses only the situations indicated and does not address all possible scenarios or
catastrophic events which may be possible but have a very low likelihood of occurring. Assumptions have
been made, as indicated and these need to be considered in management practices. The report outcomes
do not totally eliminate the risks, but rather present a risk management approach intended to mitigate risks to
as low as practicable to achieve compliance with the appropriate standards for the facility. If the activities or
dangerous goods or quantities change then this assessment shall be updated to ensure compliance is
maintained and safety is properly considered.
Huntingwood Hazard Identification And Risk Assessment Report - Fuel Based Activities Page 1 of 39
Contents
1. Scope of this Report ....................................................................................................................................... 3
2. Description of Site ........................................................................................................................................... 4
3. Description of the Proposed Fuel Facilities ................................................................................................ 5
4. Findings and Recommendations ................................................................................................................ 7
5. Methodology................................................................................................................................................. 11
6. Site Manifest .................................................................................................................................................. 12
7. Hazard Identification and Risk Assessment ............................................................................................. 14
8. SEPP 33 Preliminary screening .................................................................................................................... 31
9. Appendix A - Legislation ............................................................................................................................. 32
10. Appendix B - Proposed Site Plan ............................................................................................................... 33
11. Appendix C - Safety Data Sheets ............................................................................................................. 34
12. Appendix D - Enviropacific Services Fuel Experience ........................................................................... 35
13. Appendix E - Enviropacific Services Fuel Industry Clients ..................................................................... 36
14. Appendix G - Enviropacific Services Fuel Industry Projects .................................................................. 37
1. Scope of this Report

A Hazard Identification and Risk Assessment of the proposed BP Huntingwood Service station 6
Honeman Close, Huntingwood, NSW, 2148 was carried out by Enviropacific Services Pty Ltd on the
13/07/17 on behalf of John and Anna Arcidiacono. The purpose of this Hazard Identification and
Risk Assessment is to report on the compliance of the Hazardous Chemical storage, and the fuel
dispensing system at this facility as required by current National and relevant State Acts,
Regulations, Codes, and Australian Standards and Local Authority Approvals (refer to Appendix A).
The observations and comments in this Hazard Identifications and Risk Assessment Report are based
on information supplied to Enviropacific Services by the client and the proposed works to be
undertaken on site. This report has reviewed the proposed service station and does not assess the
hazards and risks outside of the service station boundary in relation to the adjoining development.
Enviropacific’s duty is to ensure that all information contained in this Hazard Identification and Risk
Assessment Report is accurate and current. Enviropacific Services recommendations are
applicable only to matters relevant to the National and State Acts, Regulations, Codes, Australian
Standards (refer to Appendix A), and Local Authority Approvals made available by the Client.
While this report identifies intentional criminal activities such as vandalism and theft, deliberate acts
of sabotage or terrorism are outside the scope of this document and should be addressed by a
specialist consultant if required. Work Health and Safety risk assessments should be carried out in
addition to this Hazard Identification and Risk Assessment Report.
Items not specifically mentioned in this Hazard Identification and Risk Assessment Report should not
be regarded as having been inspected by Enviropacific Services. Recommendations are not
exhaustive, and when applicable, all recommended works are subject to approval and full
compliance by the National and State Authorities.
Enviropacific Services Pty Ltd is a registered Building Design Company which has worked for and
within the Retail Petroleum Industry for more than 20 years (refer to Appendix D for Enviropacific
Services company profile). The recommendations contained within this document are based on
Enviropacific Services industry experience and on sound professional practice. Opinions and
advice given by Enviropacific Services in the following report represents Enviropacific Services best
judgement, but (to the permitted extent by law) Enviropacific Services accepts no liability for
claims or damages caused by its negligence (or that of its employees or agents) or otherwise. As
such, the reader is invited to obtain any supporting information he or she feels is necessary before
making any decisions.
The following report is confidential and not to be made available to other parties unless under the
consent of the Client.
2. Description of Site
Address: BP Huntingwood Service station
6 Honeman Close,
Huntingwood
NSW, 2148
Site Area of proposed works: 15032 m2
Real Property Description: Lot 2 on DP229466
Local Authority: Blacktown Council
Owner: John and Anna Arcidiacono
Operator: John and Anna Arcidiacono
PROPOSED SITE
Figure 1 Aerial Photo of Site Locality
3. Description of the Proposed Fuel Facilities

The following is a description of the facilities based on the findings and recommendation contained
within this report which when implemented mitigate the identified risks to an acceptable level.
 This is a new service station development consisting of a shop building, car canopy and
truck canopy.
 The sales building has an area of 475m2.
 The car canopy covers has an area 420m2.
 The truck canopy covers has an area 380m2.
 The car canopy will have 6 x 8 hose fuel dispensers.
 The truck canopy will have 5 x 6 hose fuel dispensers.
 The Underground Petroleum Storage System (UPSS) consists of 5 x 110kL double contained
skin fibreglass tanks complying with AS 1692-2006 and AS 1940-2004.
 A gravity flow, containment and treatment device shall be installed to collect any potential
contamination or spills to prevent hydrocarbons from entering the council stormwater
system. This system shall have a minimum spill capacity of 9,500 litres in the event of a fuel
tanker compartment rupture as required by AS 1940-2004.
 The UPSS remote fill points are contained within a spill safe fill box and located within the spill
containment area.
 A stainless steel DEF remote fill point is contained within a spill safe fill box and located within
the spill containment area.
 Filling of the underground fuel tanks will be conducted by a tanker that will enter in a
forward direction onto the hardstand area. The tanker discharge area will contain an
emergency stop, automatic tank gauging panel, fire hydrant with foam making facilities,
fire extinguishers, and associated compliant signage.
 Vents for the UPSS and treatment system shall be located in a landscaping island and
protected by bollards or equivalent.
 Vapour Recovery Stage 1 shall be installed on site.
 Pipe work shall be installed on site to allow for the installation of Vapour Recovery Stage 2.
 Sufficient bollards shall be installed to provide adequate vehicle impact protection to
vulnerable equipment.
 Impervious concrete pavements will be installed on site.
 1 x emergency stops shall be located under the truck canopy. 1 x emergency stop shall be
located at the shopfront directly accessible from the car canopy. 1 x emergency stop shall
be located on the console.
 3 x 9kg ABE fire extinguishers in break glass cabinet shall be located on columns under the
car canopy. 5 x 9kg ABE fire extinguishers in break glass cabinet shall be located on
columns under the truck canopy.
 A fire hose reel will be provided at the forecourt and readily accessible.
 A spill kit shall be located in the forecourt.
 An air/water point will be located adjacent the car parking bay.
 There will be landscaping around the street frontages of the site.
 There will be 2 x LPG exchange gas bottle cage located at the front of the shop.
 An ice freezer will be located on the plinth at the front of the shop.
4. Findings and Recommendations

This report is to be referenced in its entirety by the project design team. Excerpts shaded in yellow
however are items to be specifically considered & included as part of the project scope for the
entire multi-disciplinary design team. The relevant disciplines to consider these shaded items
include: civil, electrical, structural & architectural.
The proposed facility can be classified as a Manifest Quantity Workplace as defined in the New
South Wales Work Health and Safety Regulations 2011.
The risk to persons, property, and the environment posed by this proposed service station are
mitigated to an acceptable level of risk provided the following recommendations are
implemented.
 A spill containment holding tank of 9,500 litre capacity shall be provided to mitigate the risk
of a fuel tanker compartment sized major spill event from migrating off site and
contaminating the environment or causing damage to persons and/or property.
 Instructional signage and training in the use of the facilities shall be provided and
maintained.
 Hazchem signage and placarding to be installed in accordance with the New South Wales
Work Health and Safety Regulations 2011.
 CCTV with remote monitoring; back-to-base alarm systems and emergency stop button
activation; remote automatic tank gauging for net stock management; active leak
monitoring on the product delivery systems, all with 24 hour reporting and response
capabilities, mitigate the risks present in a service station facility such as this.
 A site manifest shall be provided to reflect the on-site refuelling facilities.
 An Emergency Plan shall be provided to ensure procedures are in place if an incident was
to occur. Staff training in the implementation of this emergency procedure shall be carried
out and recorded. This Emergency Plan shall be reviewed on a regular basis, when changes
occur on site, or after an incident has occurred.
General:
 Provide line marking and directional signage on the forecourt.

 Forecourt hardstand surfaces to be designed to be as slip resistant as possible.
 Clearly identify entry to shop with pedestrian line marking.
 Minimise use of kerbs in areas commonly used by pedestrians. Kerbs in paths of travel shall
be painted in high visibility colour (yellow). Install tactile indicators to Australian Standards.
Spill Containment:
 Install an under canopy catchment area that drains to a stormwater treatment system
where the spillage is contained and dealt with in line with specifically formulated
Emergency Plan. Impervious concrete pavements will be installed on the tanker hardstand
and fuel compound areas.
 Fill points are to be installed within a spill safe fill box draining back into the fuel system. This
spill safe fill box is to be located within the under canopy catchment area.
 Provide an emergency spill kit on site that is directly accessible from the dispensers. Provide
training on its use to site staff and tanker drivers.
 Console operator to monitor forecourt and immediately clean up any minor spill using
existing on site spill kit.
 If a major spill occurs, operator to shut down site and follow emergency procedures.
 Check tank excavation observation wells and ground water monitoring wells regularly for
contamination.
 Provide product reconciliation procedures (auto tank gauging, manual dip) and ensure
product reconciliation is performed daily.
 Provide accurately calibrated tank dips or auto tank gauging.
 Provide overfill protection within the tanks.
Fuel System
 Install sufficient bollards around dispensers and vents to provide mechanical protection.
 Shear valves and flame arrestors are to be provided at the dispenser bases.
 Provide dispenser nozzles with safety cut out attitude valve.
 Remove latching mechanism from dispenser nozzles.
 The fuel tanks are made from non-corrosive materials.
 Fuel supply pressure pipework shall be:
I. Double contained underground, non-corrodible pipes
 Pressure line leak detection shall be installed to all fuel supply pressure pipework.
 Auto tank gauging and line leak detection is to be provided to tanks and pipework.
 Vents shall be installed to Australian Standards in a well-ventilated location, away from
potential ignition sources and in a protected area away from vehicles in a landscaping
area of the site.
Statutory Signage
 Provide statutory signage at dispensers forbidding smoking on site, use of mobile phones or
other electronic device at dispensers, and the filling of non-compliant containers.
 Provide signage on dispensers stating that the latch is not to be locked open and left
unattended.
 Provide signage near the vents forbidding smoking on site.
 Fill points are to be clearly marked to Australian Standards.
 Placarding shall be provided.
 Emergency contact details shall be provided.
Tanker unloading:
 Implement strict tanker unloading operation controls.

 Provide suitable driver training as to traffic awareness and unloading procedures.
 Ensure tanker drivers are trained in site-specific conditions.
 Place signage at crossovers warning entering traffic of the presence of the tanker.
 Fuel tanker driver to place traffic cones 4m from fuel fill point area and tanker. Close off any
refuelling positions within 4m of the tanker unloading position.
 Tanker driver to stand by to monitor fuel transfer operation.
 Provide tanker drivers with high visibility clothing.
Operation:
 Console operator to shut down dispenser if someone is smoking at dispenser.

 Console operator to shut down dispenser if someone is using a mobile phone or other
electronic device at dispenser.
 Console operator to shut down dispenser if someone is attempting to fill non-compliant
containers.
 Console operator to shut down dispenser if the dispenser is not used appropriately.
 Console operator to shut down site and proceed with emergency plan, evacuate if
necessary.
 Ensure all staff are trained in spill response.
Maintenance:
 Ensure maintenance personnel use traffic cones and signage to barricade off dispenser.
 Ensure maintenance personnel use high visibility clothing while on site.
 Ensure any electrical work done on dispensers is performed by maintenance personnel with
suitable qualifications and training.
 Ensure appropriate work permits are obtained.
 Ensure area around the dispensers is adequately ventilated and there is no vehicle parked
close by during maintenance.
 Ensure all potential ignition sources are excluded from the area while maintenance is
conducted.
 Only appropriately qualified personnel to access confined spaces after a thorough risk
assessment has been completed.
 Ensure breathing apparatus and P.P.E. is used where required for confined space entry.
 Ensure an appropriately qualified observer is present with appropriate training in emergency
response.
Manifest and Emergency Plan.
 Locate the red weatherproof manifest box immediately adjacent the entry to the site from
the direction of approach of the emergency vehicles.
 Ensure the manifest for the site is reviewed at regular intervals.
 Provide an emergency plan and ensure training of workers in its use. Records of this training
are maintained on site.
 Ensure the Emergency Plan for the site is reviewed at regular intervals.
Security:
 Provide CCTV monitoring of the console area.

 Provide safe haven behind counter for physical protection.
 Provide duress button behind counter and within safe haven.
 Provide training to console operators to help recognise suspicious behaviour.
 Provide "dead man" system at console.
 Fire extinguishers are visible from the console or security camera.
 Fire extinguishers to be located in highly visible locations within the viewing range of the
security cameras.
 Fire extinguishers are installed in a well-lit area.
 Ensure fire fighting equipment is tested regularly to Australian Standards.
LPG Exchange Bottle Cages:
 Locate LPG exchange bottle cages in an area with good ventilation, away from ignition
sources, and where they are unlikely to be struck by vehicle.
 Provide heavy duty bollards around LPG exchange bottle cages.
 Perform a visual check on LPG exchange bottles at delivery to ensure that all have factory
seals on their valves, also check for LPG odours.
5. Methodology
Risks associated with the hazards identified in this report have been rated using a
frequency/severity matrix illustrated below.
RISK LEVEL GUIDE: FREQUENCY
V LOW → EXTREME
Low, risk level acceptable, no

0-3 1 2 3 4 5
action required.
V LOW
Medium, requires monitoring, may
4-6 2 4 6 8 10
require minor remedial action.
7-10 High, requires action. ↓ 3 6 9 12 15
Unacceptable, activity must stop,

11 + 4 8 12 16 20
immediate action required.
EXTREME
SEVERITY
5 10 15 20 25
Risks have been grouped into one or more of the following risk categories:
1. People - The risk is to any person who may be on site whether they are employees,
maintenance personnel or the general public accessing the site.
2. Property - The risk is to assets of the owner, operator, supplier or any person accessing the
site for any reason.
3. Environment - The risk poses potential harm to the environment including potentially harmful
emissions to air, water or ground. Risks can be both catastrophic, and systemic.
The Risk Assessment process is designed to minimise risks to people, property, and the environment
by the implementation of the following steps as outlined in AS/NZS ISO 31000 - Risk Management -
Principles and guidelines.
 Identify all hazards

- Assess all the risks with the use of the hierarchy of control measures of:
- Elimination
- Substitution
- Engineering Controls
- Administration Controls
- Personal Protection Equipment
 Document, maintain and monitor the control measures implemented on a regular basis to
ensure associated risks are kept to a minimum.
6. Site Manifest
Tank/ Type Description Capacity (litres) Average Type or category of Equivalent UN No. Hazchem
Storage hazardous chemical Dangerous Goods
Storage
(litres) Class/ Division/
No.
Packaging Group
1/a Underground Automotive Ultimate Diesel 50,000 47,500 Flammable Liquids C1 UN 3082 •3Z
[Diesel] Category 4
1/b Underground Automotive Diesel 40,000 38,000 Flammable Liquids C1 UN 3082 •3Z
[Diesel] Category 4
1/c Underground AdBlue 20,000 19,000 N/A N/A N/A N/A
[Diesel Exhaust Fluid]
2/a Underground Automotive Ultimate Diesel 60,000 57,500 Flammable Liquids C1 UN 3082 •3Z
[Diesel] Category 4
2/b Underground Automotive Diesel 50,000 47,500 Flammable Liquids C1 UN 3082 •3Z
[Diesel] Category 4
3/a Underground Automotive Diesel 60,000 57,500 Flammable Liquids C1 UN 3082 •3Z
[Diesel] Category 4
3/b Underground Automotive Ultimate Diesel 50,000 47,500 Flammable Liquids C1 UN 3082 •3Z
[Diesel] Category 4
4/a Underground Premium Unleaded 40,000 38,000 Flammable Liquids 3 PGII UN 1203 3[Y]E
Petrol(95 Octane) Category 2
4/b Underground Unleaded Petrol (91 40,000 38,000 Flammable Liquids 3 PGII UN 1203 3[Y]E
Octane) Category 2
4/c Underground Ethanol Blended Unleaded 30,000 28,500 Flammable Liquids 3 PGII UN 1203 3[Y]E
Petrol (E10) Category 2
5/a Underground Premium Unleaded 60,000 57,500 Flammable Liquids 3 PGII UN 1203 3[Y]E
Petrol(98 Octane) Category 2
5/b Underground Automotive Ultimate Diesel 50,000 47,500 Flammable Liquids C1 UN 3082 •3Z
[Diesel] Category 4
6 Exchange bottle Liquefied Petroleum Gas <528` <528 Flammable Gases 2.1 UN 1075 2YE
cage (30 bottles) Category 1
Huntingwood Hazard Identification and Risk Assessment Report - Fuel Based Activities Page 12 of 39
7 Small Package Miscellaneous Automotive 270 270 Flammable Liquids C2 Varies Varies
Store Fluids Category 4
7. Hazard Identification and Risk Assessment
No Hazard Risks Consequences Risk Level Action Re-assessment of Consequences Revised Risk
and Type Level
Section 1 - Operation
1.1 Vehicle Dispenser is struck Dispenser requires repair or Level 8. Install bollards around Dispensers are physically Level 2-3.
movements on replacement. dispensers to provide protected. People.
People.
site mechanical protection. Property.
Spilt fuel is ignited causing Property. Intent for the correct use of site is
injury or death and Environment. Provide line marking and made obvious through signage. Environment.
destruction of property. directional signage on the
Risk of spill and explosion is
forecourt.
People in vehicle are injured. minimised by the installation of
Shear valves and flame shear valves.
Vehicle is damaged.
arrestors are to be provided
Risk of fuel spill is minimised
Product is spilt to the at the dispenser bases.
through collection of spills by the
environment.
Install spill containment treatment system.
catchment area that drains
to a treatment system where
the spillage is contained
and dealt with in line with
specifically formulated
emergency procedures.
and Type Level
Tanker parked on Rupture of tanker Level 10. Lower speed limit on site to Low speed of traffic on site allows Level 4.
site is struck compartment causing major 10km/hour. collisions to be avoided, allows
People. People.
spill. people time to get out of the
Property. Implement strict tanker Property.
way of moving vehicles and
Spilt fuel is ignited causing Environment. unloading operation
minimises the effects of collisions.
injury or death and controls.
destruction of property. Entering traffic has plenty of
Fuel tanker driver to place
warning that there is a tanker on
Damage to tanker trailer traffic cones from fill point
site.
requiring repair. area and tanker.
Visual cues are in place directing
People in vehicle are injured Place signage at crossovers
traffic away from the tanker
or killed. warning entering traffic of
location.
the presence of the tanker.
The physical presence of the
Close off any refuelling
tanker vehicle also provides a
positions within 4m of the
deterrent to irresponsible vehicle
fuel tanker unloading
operation on site.
position.
Appropriate procedures and
Locate fill point within the
physical controls are in place to
compound catchment area
enable major spills to be
that drains to a treatment
managed as safely as possible.
system where the spillage is
contained and dealt with in Risk of fuel spill is minimised
line with specifically through collection of spills by the
formulated emergency treatment system.
procedures.
Tanker driver is Tanker driver is injured or Level 10. Lower speed limit on site to Low speed of traffic on site allows Level 5.
struck killed. 10km/hour. collisions to be avoided, allows
People. People.
people time to get out of the
Provide suitable driver
training as to traffic
awareness and unloading
procedures. Driver is visible and traffic is aware
of driver’s presence.
Provide tanker drivers with
high visibility clothing.
and Type Level
Tanker transfer Transfer hose is ruptured Level 8. Implement strict tanker Entering traffic has plenty of Level 4.
hose is struck causing major spill. unloading operation warning that there is a tanker on
People. People.
controls. site.
Spilt fuel is ignited causing Property. Property.
injury or death and Environment. Access to tanker hardstand Visual cues are in place directing Environment.
destruction of property. is to be secured so no traffic away from the tanker
vehicle is allowed during location.
Transfer hose is damaged
fuel unloading.
requiring repair or The physical presence of the
replacement. Fuel tanker driver to place tanker vehicle also provides a
traffic cones 4m from fill deterrent to irresponsible vehicle
point area and tanker. operation on site.
Place signage at crossovers Tanker driver is positioned such
warning entering traffic of that he is protected and can
the presence of the tanker. direct traffic away from
unloading area.
Close off any refuelling
positions within of the fuel Appropriate procedures and
tanker unloading position. physical controls are in place to
enable major spills to be
Tanker driver to stand by to
monitor fuel transfer
operation. Risk of fuel spill is minimised
through collection of spills by the
Locate fill point within the
treatment system.
compound catchment area
that drains to a treatment
system where the spillage is
contained and dealt with in
line with specifically
formulated emergency
procedures.
Person using the Person is injured or killed. Level 10. Limit speed on site to Low speed of traffic on site allows Level 2-3.
site or their vehicle 10km/h. collisions to be avoided, allows
Damage to private property People. People.
is struck. people time to get out of the
on site. Property. Property
and Type Level
1.2 Use of dispensers Smoking at Vapour ignites causing injury Level 12. Provide statutory signage at People are made aware of the Level 1.
dispenser or death and damage to dispensers forbidding danger regarding smoking on
People. People.
property. smoking on site. site.
Property. Property.
Console operator to shut The situation is able to be
down dispenser if someone controlled by the console
is smoking at dispenser. operator by shutting down the
dispenser.
Provide CCTV monitoring at
refuelling position. Risk eliminated if there is no
smoking on site.
Use of mobile Vapour ignites causing injury Level 8. Provide statutory People are made aware of the Level 1.
phone or potential or death and damage to signage/highly visible danger regarding the use of
People. People.
source of flame at property. signage at dispensers mobile phones and other
Property. Property.
dispenser forbidding use of mobile electronic devices at dispenser.
User is distracted from the
phones or other potential
task of fuelling. The situation is able to be
source of flame such as pilot
controlled by the console
lights, gas refrigerators and
operator by shutting down the
other electrical device at
dispenser.
dispensers
Risk eliminated if there is no use of
Console operator to shut
mobile phones and other
down dispenser if someone
electronic devices on site.
is using a mobile phone or
other electronic device at
dispenser.
refuelling position.
Filling of non- Hydrocarbons may dissolve Level 6. Provide statutory signage at People are made aware of the Level 3.
compliant container causing spillage dispensers forbidding the danger regarding the filling of
People. People.
container(s) and releasing vapour. filling of non-compliant non-compliant container(s).
Property. Property.
containers.
Hydrocarbons may react The situation is able to be
with container causing fire. Console operator to shut controlled by the console
down dispenser if someone operator.
is attempting to fill non-
compliant containers.
and Type Level
Misuse of nozzle or Spillage of fuel onto Level 9. Provide highly visible The situation is able to be Level 4.
leaving dispenser forecourt or people causing warning signage and controlled by the console
People. People.
unsupervised while fire hazard and risk of injury. instructions at the dispenser. operator.
Property. Property.
discharging fuel
Damage to nozzle requiring Environment. Console operator to monitor Risk of fuel spill is minimised
repair or replacement. forecourt and shut down through collection of spills by the
dispenser is not used treatment system.
Release of vapour leading to
appropriately.
fire hazard and risk of injury Appropriate procedures and
and damage to property. Install nozzles with safety cut physical controls are in place to
out attitude valve enable major spills to be
Hydrocarbons could find
their way into waterways Remove latching
causing environmental harm. mechanism from nozzle.
Provide signage stating that
the latch is not to be locked
open and left unattended.
Provide readily accessible
spill kit on site.
and Type Level
Product spill onto Slip hazard leading to risk of Level 9. Console operator to monitor Any minor spills are contained Level 6.
forecourt. injury. forecourt activity and and removed quickly.
People. People.
immediately clean up any
Release of vapour leading to Property. Risk of fuel spill is minimised Property.
minor spill using the spill kit
fire hazard and risk of injury Environment. through collection of spills by the Environment.
readily accessible from the
and damage to property. treatment system.
dispenser.
Hydrocarbons could find Appropriate procedures and
If a major spill occurs,
their way into waterways physical controls are in place to
operator to shut down site
causing environmental harm. enable major spills to be
and follow emergency
procedures.
Install a under canopy
catchment area that drains
to a treatment system where
the spillage is contained
and dealt with in line with
Provide highly visible
warning signage and
instructions at the dispenser.
Drive-off fuel theft Loss of income. Level 8. Console operator to monitor If a ‘drive off ‘occurs the number Level 4.
forecourt activity for ‘drive plate of the vehicle is recorded
Property. Property.
offs’. and is likely to be witnessed.
Installation of CCTV Incident is recorded and
monitoring of refuelling offenders are identified.
positions to capture ‘drive
offs’/theft.
and Type Level
1.3 Tanker Minor fuel spill (up Vapour from spill could ignite Level 6. Provide an emergency spill Appropriate procedures and Level 3.
unloading to 20l.) causing injury or damage to kit on site that is readily physical controls are in place to
People. People.
property. accessible from the enable minor spills to be
Property. Property.
dispensers. Provide training managed as safely as possible.
Hydrocarbons could find Environment. Environment.
on its use to site staff and
their way into stormwater
tanker drivers.
system and waterways
causing environmental harm. Fill points are to be located
within a spill safe fill box
draining back into the fuel
system.
Major fuel spill Vapour from spill could ignite Level 10. Provide an emergency plan Appropriate procedures and Level 5.
(over 20l.) causing injury or damage to and ensure training of physical controls are in place to
People. People.
property. workers in its use. enable major spills to be
Property. Property.
Hydrocarbons could find Environment. Console operator to shut Environment.
their way into stormwater down site and proceed with
system causing a potential emergency plan, evacuate
explosive atmosphere within if necessary.
pipework.
Ensure all fill points are
Hydrocarbons could find installed within the
their way into waterways catchment area that drains
causing environmental harm. to a treatment system.
Spillage is contained and
dealt with in line with
and Type Level
Incorrect product Possible damage to private Level 6. Ensure tanker drivers are Tanker driver can clearly see the Level 3.
introduced into property caused by use of trained in site-specific product arrangement and has
Property. Property
storage tank incorrect fuel. conditions. the ability to cross check the fill
point arrangement.
Fill points are clearly marked
to Australian Standards.
Provide tanker driver with
correct, up to date fill point
sketch.
Any discrepancy between
the fill point markers and the
fill point sketch to be notified
and fuel transfer is not to
proceed.
Storage tank is Potential fuel spillage Level 9. Ensure product Overfilling of the tanks becomes Level 3.
overfilled causing risk of ignition or reconciliation is performed very difficult.
Property. Property.
harm to the environment. daily.
Environment. Environment.
Lack of ullage space may Provide accurately
cause storage tank to calibrated tank dips or auto
rupture due to thermal tank gauging.
expansion of hydrocarbon.
Tanker driver to confirm
product volumes prior to
performing a fuel transfer.
Provide overfill protection
within the tanks.
and Type Level
1.4 Console Robbery Physical and psychological Level 12. Provide CCTV monitoring of Console operator has the means Level 8.
operation harm to the console the console area. to protect their self.
People. People.
operator.
Property. Provide safe haven behind Level of security has a deterrent Property.
Loss of income. counter for physical effect.
protection.
Provide duress button
behind counter and within
safe haven.
Provide training to console
operators to help recognise
suspicious behaviour.
Operator is Operator may be unable to Level 8. Provide "dead man" system In the case of incapacitation, Level 4.
incapacitated access emergency medical at console. emergency services are notified
People. People.
during lone shift help. automatically, although the time
Property. Property.
lapse still represents a risk.
Potential for theft if there is
no one visibly on duty.
1.5 Maintenance Maintenance Maintenance person could Level 12. Ensure maintenance The work area and personnel are Level 4.
access to person being struck be injured or killed. personnel use traffic cones highly visible to any traffic on site.
People. People.
dispensers by vehicle and signage to barricade
off dispenser.
Ensure maintenance
personnel use high visibility
clothing while on site.
Ensure an appropriately
qualified observer is present
with appropriate training in
emergency response.
Ensure appropriate work
permits are obtained.
and Type Level
Electrocution Maintenance person could Level 12. Ensure any electrical work Risks to maintenance personnel Level 3.
be injured or killed. done on dispensers is and equipment are minimised
People. People.
performed by maintenance through the use of correctly
Equipment is damaged. Property. Property.
personnel with suitable trained personnel and safe work
qualifications and training. procedures.
Exposure to Maintenance person could Level 16. Ensure area around the Vapours are being dispersed. Level 6.
explosive be injured or killed. dispensers is adequately
People. The potential for ignition is greatly People.
atmosphere within ventilated and that there
Possible damage to Property. reduced. Property.
dispenser housing are no vehicles parked
property.
close by during
maintenance.
Ensure all potential ignition
sources are excluded from
the area.
1.6 Maintenance Exposure to Maintenance person could Level 10. Only appropriately qualified Risks to personnel are minimised Level 4.
entry into tanks explosive be injured or killed. personnel to access through the use of correctly
People. People.
atmosphere confined spaces. trained personnel and safe work
Possible damage to Property. Property.
procedures.
property. Ensure appropriate entry
and work permits are
obtained.
Ensure all safety clothing
and breathing apparatus
are used.
emergency response.
and Type Level
Inhalation of Could result in various health Level 10. Ensure breathing apparatus Risks to personnel are minimised Level 4.
vapour problems relating to is used. through the use of appropriate
People. People.
respiration and central safety equipment and safe work
nervous system, potential for practices.
fatality.
emergency response.
Maintenance Maintenance person could Level 12. Ensure maintenance The work area and personnel are Level 4.
person being struck be injured or killed. personnel use traffic cones highly visible to any traffic on site.
People. People.
by vehicle and signage to barricade
off dispenser.
Ensure maintenance
personnel use high visibility
clothing while on site.
emergency response.
1.7 Customer safety Customer being Customer could be injured or Level 12. Clearly identify entry to shop Customer is visible and traffic is Level 5.
struck by tanker or killed with pedestrian line marking. aware.
People. People.
other vehicle
Limit speed on site to Low speed of traffic on site allows
10km/h. collisions to be avoided, allows
people time to get out of the
Keep area clear of trip
hazards and unnecessary
items.
Activity at the forecourt is
monitored and the console
forecourt.
operator is made aware of
potential danger.
and Type Level
1.8 Manual Car Chemical Handling Eye & Skin irritation caused Level 6. Eye wash available Risk minimised by employee Level 4
Wash by exposure from cleaning training.
People Gloves available if required People.
chemicals
(must be used for sensitive PPE available to minimise
skin) exposure.
Employees to be trained to Eyewash can be administered to
used equipment safely avoid injury.
High pressure hose Injury to employees Level 6. Employees to be trained to Risk minimised by employee Level 4
used equipment safely training.
Damage to Cars by loss of People People.
pressure hose control Eye protection must be worn PPE available to minimise
Property Property
exposure.
Wet Surfaces Slips/Trips Level 8. Slip resistant surfaces Work surface minimised to Level 3.
(coarse broom finished reduce slipping.
Personal Injury People People
concrete).
Public access restricted.
Signage to restrict public
PPE required.
access.
Area clean of hazards by
Appropriate Safety
mechanical sweeping to
footwear.
minimise incidents.
Mechanical Sweep and
Scrub
Insure floors are well drained
to avoid water pooling
and Type Level
Electrocution Employee could be injured Level 12. Circuit RCD protected. Risks to maintenance personnel Level 3.
or killed. and equipment are minimised
People. Equipment is serviced every People.
through the use of correctly
Equipment is damaged. Property. six months. Property
trained personnel and safe work
Safety training to employees procedures.
on how to operate
electrical equipment.
Minimise water where
electrical connections are
by means of safety
procedures
Vehicle Damage to vehicles driving Level 9. Speed limits in place. Limited to employers only by use Level 3.
thru carwash of signage.
People. Signage to restrict non- People.
Damage to Property employers from driving in & Speed bumps and limits enforced Property
buildings/surrounds from to restrict pedestrian access. to reduce speeds to harmful
vehicles accidents occurring.
Install speed bumps.
People being injured from Bollards in place to protect
Install bollards.
vehicles. surrounding buildings.
Section 2 – The Installation
2.1 Concrete Slippery surfaces Possible slip and fall causing Level 8. Spill kits are provided on site The time between a spill and Level 4.
forecourt due to spillage injury. and are readily accessible clean-up is minimised.
People. People.
from the dispensers.
Vehicle accessing the site Property. Surface provides as much grip as Property.
could lose control causing Ensure all staff is trained in possible.
possible injury to persons on spill response.
site or damage to property.
Forecourt surfaces to be
designed to be slip resistant.
and Type Level
Trip hazard at kerbs Possible trip and fall causing Level 8. Kerbs in paths of travel to be Trip hazards are visible and their Level 3.
injury. painted in high visibility number is minimised.
People. People.
colour (yellow).
Install indicators to Australian
Standards.
Minimise use of kerbs in
areas commonly used by
pedestrians.
2.2 Underground Structural failure of Possibility of hydrocarbon Level 8. The liquid fuel tanks are Should failure occur checks are in Level 3.
fuel tanks and tanks and/or being spilt to ground causing made from non-corrosive place for product reconciliation,
Property. Property.
pipework pipework environmental harm. materials. leak detections, and the
Environment. Environment.
surrounding area is being
Auto tank gauging and line
monitored to minimise harm.
leak detection is to be
provided to tanks and
pipework.
Provide product
reconciliation procedures
(auto tank gauging, manual
dip).
Check tank excavation
observation wells regularly.
2.3 Fire extinguishers Misuse of May cause extinguisher to Level 6. Fire extinguishers are visible Fire extinguishers can be Level 4.
equipment fail or run out during from the console or security monitored.
Property. Property.
emergency. camera.
Location in well-lit area acts as a
Fire extinguisher discharge Fire extinguishers are deterrent to potential misuse.
would require clean up. installed in a well-lit area.
Location where visible increases
Fire extinguisher would likelihood of any misuse being
require recharging. witnessed.
and Type Level
Theft of equipment Fire fighting equipment may Level 6. Fire extinguishers are visible Fire extinguishers can be Level 3.
be unavailable during an from the console or security monitored.
Property. Property.
emergency. camera.
Cost of replacing fire Fire extinguishers are deterrent to potential theft.
extinguisher. installed in a well-lit area.
likelihood of any theft being
witnessed.
Failure of Personnel unable to respond Level 8. Ensure fire fighting If fire extinguishers are required Level 2.
equipment to a fire emergency causing equipment is tested their correct operation is ensured.
People. Property.
damage to property and regularly to Australian
Property.
possible injury or death. Standards.
Vandalism Fire extinguisher could fail Level 6. Fire extinguishers are visible Fire extinguishers can be Level 3.
during emergency. from the console or security monitored.
Property. Property.
camera.
Fire extinguishers are deterrent to potential vandals.
installed in a well-lit area.
likelihood of any vandalism being
witnessed.
2.4 Tank vents Vents being struck Could result in injury and Level 6. Vents are installed in a It is very unlikely that the vents will Level 2.
by vehicle damage to property. protected area away from be struck.
People. Property.
vehicles in a landscaping
Property.
area of the site.
Install bollards around vents
to provide mechanical
protection.
and Type Level
Vapour igniting Could result in injury and Level 8. Vents are installed away Risk of ignition is minimal. Level 2.
damage to property. from any potential ignition
People. Property.
source.
Property.
Vents are installed to
appropriate Australian
Standards.
Provide signage near the
vents forbidding smoking on
site.
Inhalation of Vapour inhalation can result Level 10. Vents are installed to The likelihood of vapour Level 2.
vapour in headaches, dizziness, appropriate Australian inhalation is minimal.
People. People.
weakness, nausea, blurred Standards.
vision, shortness of breath
Vents are installed in a well-
and effects to central
ventilated location.
nervous system. Refer to
material safety data sheets.
2.5 LPG exchange LPG exchange Could result in explosion, Level 10. Locate LPG exchange The likelihood of LPG exchange Level 3.
bottle cages bottle cages being injury and damage to bottles in an area unlikely to bottle cage and cylinders being
People. People.
struck by vehicle property. be struck by vehicle. struck is minimal.
Property. Property.
Install bollards around LPG
exchange bottle cage and
cylinders to provide
mechanical protection.
and Type Level
LPG exchange Could result in explosion, Level 10. LPG exchange bottles are Good ventilation reduces the risk Level 3.
bottle leaking injury and damage to located in an area with of leaking gas pooling.
People. People.
property. good ventilation.
Property. The likelihood of leaking LPG Property.
LPG exchange bottles are exchange bottles being ignited is
located away from ignition reduced.
sources.
Ensure statutory signage on
the LPG exchange bottle
cage forbidding smoking.
Perform a visual check on
LPG exchange bottles at
delivery to ensure that all
have factory seals on their
valves, also check for LPG
odours.
2.6 Site Manifest An emergency Emergency services unable Level 8. Locate the red The manifest is easy to find and Level 3.
situation could to access site specific weatherproof manifest box accessible.
People. People.
occur requiring information for the immediately adjacent the
Property. The manifest is up to date with Property.
information of site hazardous chemical storage entry to the site from the
product types and volumes
specific hazards. in the event of an direction of approach of the
stored on site.
emergency. emergency vehicles.
Ensure the manifest for the
site is reviewed at regular
intervals.
2.7 Emergency Plan An emergency Workers are unaware of Level 8. Ensure the Emergency Plan In the event of an incident, Level 3.
situation could emergency response for the site is reviewed at workers know what procedures
People. People.
occur requiring a procedures. regular intervals. are in place and how to respond
Property. Property.
site specific to minimise the effects of the
Ensure workers on site are
response. incident.
trained in the Emergency
Plan and records of this
training are maintained on
site.
8. SEPP 33 Preliminary screening
Refer to SEPP 33 Preliminary screening report attached
29 May 2017
Level 4
66 Clarence Street
Sydney NSW
Australia 2000
www.meinhardtgroup.com
SEPP33 Preliminary Screen; Tel: 61 (02) 9699 3088
Fax: 61 (02) 9319 7508
Project No. 117878
Proposed BP Service Station Development; 6 Honeman Close, Huntingwood, NSW

(11034 SK009, Issue D 17/05/2017).
Introduction
This letter report sets out the results of the SEPP33 preliminary screening on the proposed service station
development at 6 Honeman Close, Huntingwood, NSW.
The Hazardous and Offensive Development Application Guidelines - Applying SEPP 33 (January 2011)
NSW Dept. of Planning (the guidelines) provides a risk screening method to assist in determining whether
a proposed development is potentially hazardous and thus determine whether SEPP 33 applies.
For development proposals classified as ‘potentially hazardous industry’ the policy establishes a
comprehensive test by way of a preliminary hazard analysis (PHA) to determine the risk to people,
property and the environment at the proposed location and in the presence of controls. SEPP 33 applies
to any proposals which fall under the policy’s definition of ‘potentially hazardous industry’ or ‘potentially
offensive industry’.
Hazard Identification – Preliminary Screening

To determine if a proposed facility is potentially hazardous a number of steps are followed using the risk
screening method given in the guideline.
The steps include;
o collate information;
o identify hazardous materials and the type of hazard;
o group and total by class, activity and location;
o compare with screening threshold;
o consider transportation issues; and
o determine whether SEPP 33 applies
A preliminary screen of the proposed development has found that the proposed service station
development at 6 Honeman Close, Huntingwood, NSW is “not potentially hazardous” as defined under
SEPP33.
Assessment of Data.
Table 1 displays hazardous materials to be stored on-site and quantities.
Table 1: Material quantities and classifications.
Quantity
Tank Material Classification Mode of storage
Volume (kL) Mass (tonnes)
T1a Diesel 3PGII 50 42# Underground tank
T1b Diesel 3PGII 40 34# Underground tank
T1c AdBlue - 20 - Underground tank
T4a ULP95 3PGIII 40 30* Underground tank
T4b ULP91 3PGIII 40 30* Underground tank
T4c E10 3PGIII 30 22* Underground tank
T5a ULP95 3PGIII 60 44* Underground tank
# Specific gravity used was 0.84. *Specific gravity used was 0.737
As petrol and diesel belong to Class 3 Flammable liquids stored in the same general location, the
quantities are normally assessed as a whole. In this instance, since each tank compartment has
separate isolation valve the quantities can be treated separately. The greatest mass of fuel is
stored in tank compartments T2a and T3a and since each compartment has an isolation valve, the
screen will be conducted using the mass of diesel found in compartment T2a. As the diesel is to be
stored underground, the total mass is divided by 5 and multiplied by 0.95 to reflect 95% safe filling
limit ((50/5)0.95 = 9.5 Tonnes) for screening purposes.
The critical locations within the service station in terms of screening for diesel and petrol are the
location of the dispenser/pump positions and the tank fill points with respect to the site boundary.
The shortest distance to a site boundary is 20m between a fuel dispenser (diesel) and the
boundary (southern side). The fill point is approximately 40m from the closest boundary (southern
side). Undeveloped bushland adjoins on the southern and western boundaries. Reservoir Road
adjoins the eastern boundary and The Great Western Highway the northern boundary. Commercial
properties are located to the east beyond Reservoir Road and to the north beyond The Great
Western Highway.
The guidelines specify that for class 3PGII and 3PGIII chemicals (e.g. petrol and diesel), Figure 9
in the guidelines is to be used for screening purposes (Dept. Planning 1993).
Considering a total effective mass of 9.5 tonnes and a minimum distance of 20m from the adjoining
property, the proposal is not considered potentially hazardous for surrounding sensitive or
commercial uses.
117878 - l01 - huntingwood sepp33 2

Finally in consideration of the transportation issues, the number of vehicle movements were
considered against the transportation screening thresholds (Table 2 in the guidelines). The
expected deliveries of 3 per week are below the number required to trigger SEPP33.
Conclusions
A preliminary SEPP33 screen was carried out to assess the proposed service station development
at 6 Honeman Close, Huntingwood, NSW. The proposed service station was found to be non
hazardous for surrounding residential and commercial industrial uses as defined under SEPP33.
As the service station is bounded by roads to the north and east and the nearest adjoining property
to the diesel tank fill points and fuel dispensers is at least 20 m, the proposed service station is
considered non-hazardous and so will not be subject to SEPP33.
Should you have any queries regarding this report, please contact undersigned on
(02) 8252 0442.
Regards,
Meinhardt Infrastructure & Environment Pty Ltd
Dr. Santo Ragusa

Senior Associate Environment
117878 - l01 - huntingwood sepp33 3

9. Appendix A - Legislation
The design, construction, operation and supply of Hazardous Chemicals to service stations in New
South Wales shall comply with, but not be limited to, the latest edition of the following legislation,
regulations, standards and codes.
 New South Wales Occupational Health and Safety Regulation 2000

 New South Wales Occupational Health and Safety Amendment (Dangerous Goods) Act
2003
 New South Wales EPA – Protection of the Environment Operations Act
 Australian Dangerous Goods Code 7th edition.
 National Construction Code.
 AS1692-2006 Tanks for flammable and combustible liquids.
 AS1940-2004 The storage and handling of flammable and combustible liquids.
 AS4897-2008 Design Installation and Operation of Underground Petroleum Storage Systems.
 AS4977-2008 Petroleum Products - Pipeline, road tanker compartment and underground
tank identification.
 AS/NZS60079.10.1-2009 Explosive atmospheres - Classification of areas - Explosive gas
atmospheres (IEC 60079-10-1, Ed.1.0(2008) MOD).
 AS/NZS1841.5-2007 Portable fire extinguishers - Specific requirements for powder type
extinguishers.
 AS2444-2001 Portable Fire Extinguishers and fire blankets
Huntingwood Hazard Identification and Risk Assessment Report - Fuel Based Activities Page 32 of 39
10. Appendix B - Proposed Site Plan
Refer to Proposed Site plan drawings attached
Membership No. 563
QBCC Lic. No. 1272165
building designers' DO NOT SCALE

association of
queensland inc. COPYRIGHT © 2016
CKD
JC
JC
AMENDMENT
ISSUE FOR CLIENT APPROVAL
ISSUE FOR DA APPROVAL
DATE
09.06.17
02.06.17
ISS
B
A
C:\Users\jcroft\Documents\11034-m01_jcroft@cadway.com.au.rvt
DEVELOPMENT APPROVAL
ISSUED FOR
INTERSECTION RESERVOIR ROAD AND GREAT WESTERN HIGHWAY
1 PERSPECTIVE
@ A1
9/06/2017 12:34:43 PM
FULL SIZE @ A1
Studio 24/115 Wickham Street,

PO Box 724,
Fortitude Valley, QLD 4006
T: 1800 616 760
E: info@cadway.com.au
W: www.cadway.com.au
acn: 111 372 064 abn: 43 111 372 064
project description
BP HUNTINGWOOD
SERVICE STATION
project address
GREAT WESTERN HIGHWAY,
HUNTINGWOOD,
NSW, 2148
client
JOHN AND ANNA

ARCIDIACONO
drawing title
PERSPECTIVES - SHEET 1
@ A1 scale
05/24/17 date
2 SERVICE STATION SITE ENTRY PERSPECTIVE AC drawn
@ A1
JC checked
11034 job no.
11034 SK018 dwg no.
B issue
Membership No. 563
QBCC Lic. No. 1272165
112° 35' 15"
121.52 m
building designers' DO NOT SCALE
association of
queensland inc. COPYRIGHT © 2016
LANDSCAPING
CKD
JC
JC
JC
136
°2
29.6 1' 00"
MID SIGN 4m
AIR/WATER
CAR PARK(7)
AMENDMENT
CAR PARK(9)
ISSUE FOR CLIENT APPROVAL
ISSUE FOR DA APPROVAL

FLOOR PLAN DETAILS
LINE
OF
CAR PARK(11)
EST
SERVICE
IMA
CAR CANOPY
DATE
(REFER DRAWING 11034-SK014)
09.06.17
06.06.17
02.06.17
TED
STATION
PROPOSED BOUNDARY
RMS
ISS
C
B
A
ROA
CAR WASH
475m² C:\Users\jcroft\Documents\11034-m01_jcroft@cadway.com.au.rvt
D RE
DEVELOPMENT APPROVAL
(REFER DRAWING
ENTRY
SUM
11034-SK013)
PTIO
(TO N
BE
ISSUED FOR
CON
PLANT AREA
BIN STORE/
DELIVERY
FIRM
LANDSCAPING
ED W
ITH
FUEL VENTS
RMS
)
SIGN
WEIGHBRIDGE
DUAL FILLPOINT
9/06/2017 12:40:35 PM
FULL SIZE @ A1
5x110KL TANK FARM
TRUCK CANOPY
RY
DA

UN
BO
Studio 24/115 Wickham Street,

PO Box 724,
ED
Fortitude Valley, QLD 4006

OS
T: 1800 616 760

OP
E: info@cadway.com.au
PR
W: www.cadway.com.au
acn: 111 372 064 abn: 43 111 372 064
R
SS CA
project description
RE N
BP HUNTINGWOOD
EG IO
Y/ AT
SERVICE STATION
TR ST
EN ICE
project address
RV
GREAT WESTERN HIGHWAY,

SE
G
IN
HUNTINGWOOD,
AP
NSW, 2148
SC
ND
LA
client
JOHN AND ANNA

ARCIDIACONO
drawing title
STAGE 1 SITE PLAN
SERVICE STATION MID 1 : 200 @ A1 scale
TRUCK EGRESS SIGN 05/24/17 date

LANDSCAPING
AC drawn
JC checked
SERVICE STATION ENTRY
1 CONCEPT MASTER PLAN 11034 job no.
1 : 200 @ A1
0 10m 20m
11034 SK012 dwg no.
1:200 C issue
11. Appendix C - Safety Data Sheets
Refer to Company Safety Data sheets attached
Material Safety Data Sheet
1 . Identification of the material and supplier

Product name AdBlue
SDS no. 0000003947
Product use Reactant for reducing NOx-emissions.
Supplier BP Australia Pty Ltd
Level 17, 717 Bourke Street
Docklands, Victoria 3008
ABN 53 004 085 616
Technical Helpline Number: 1300 139 700

www.bp.com.au
EMERGENCY TELEPHONE 1800 638 556
NUMBER
Product code 0000003947
2 . Hazards identification
Statement of hazardous/ NON-HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS.
dangerous nature
3 . Composition/information on ingredients
Water and Urea (31.8 - 33.2%)
This product does not contain any hazardous ingredients at or above regulated thresholds.
4 . First-aid measures
Eye contact In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Eyelids should
be held away from the eyeball to ensure thorough rinsing. Check for and remove any contact lenses.
Get medical attention if irritation occurs.
Skin contact Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Wash
clothing before reuse. Clean shoes thoroughly before reuse. Get medical attention if irritation
develops.
Inhalation If inhaled, remove to fresh air. Get medical attention if symptoms appear. In case of inhalation of
decomposition products in a fire, symptoms may be delayed. The exposed person may need to be
kept under medical surveillance for 48 hours.
Ingestion Do not induce vomiting unless directed to do so by medical personnel. Get medical attention if
symptoms occur.
Advice to doctor Treatment should in general be symptomatic and directed to relieving any effects.
5 . Fire-fighting measures
Extinguishing media
Suitable In case of fire, use foam, dry chemical or carbon dioxide extinguisher or spray.
Not suitable Do not use water jet.
Hazardous decomposition Combustion products may include the following:
products carbon oxides (CO, CO2) (carbon monoxide, carbon dioxide)
nitrogen oxides
Unusual fire/explosion In a fire or if heated, a pressure increase will occur and the container may burst.
hazards
Special fire-fighting No action shall be taken involving any personal risk or without suitable training. Promptly isolate the
procedures scene by removing all persons from the vicinity of the incident if there is a fire.
Protection of fire-fighters Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus
(SCBA) with a full face-piece operated in positive pressure mode.
Product name AdBlue Product code 0000003947 Page: 1/5

Version 1 Date of issue 16 September 2013 Format Australia Language ENGLISH
(Australia) (ENGLISH)
6 . Accidental release measures
Personal precautions No action shall be taken involving any personal risk or without suitable training. Evacuate
surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or
walk through spilt material. Put on appropriate personal protective equipment (see Section 8).
Environmental precautions Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers.
Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways,
soil or air).
Large spill Stop leak if without risk. Move containers from spill area. Prevent entry into sewers, water courses,
basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows.
Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or
diatomaceous earth and place in container for disposal according to local regulations. Dispose of via
a licensed waste disposal contractor.
Small spill Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-
soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an
appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.
7 . Handling and storage

Handling Put on appropriate personal protective equipment.
Storage Store and use only in equipment/containers designed for use with this product. Keep away from heat
and direct sunlight. Keep container tightly closed and sealed until ready for use. Containers that
have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in
unlabelled containers. Store in accordance with local regulations. Store in a dry, cool and well-
ventilated area, away from incompatible materials (see Section 10).
Not suitable Prolonged exposure to elevated temperature.
8 . Exposure controls/personal protection

Occupational exposure limits No exposure standard allocated.
Biological Limit Values No biological limit allocated.
Exposure controls
Occupational exposure Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of
controls vapours below their respective occupational exposure limits.
All activities involving chemicals should be assessed for their risks to health, to ensure exposures are
adequately controlled. Personal protective equipment should only be considered after other forms of
control measures (e.g. engineering controls) have been suitably evaluated. Personal protective
equipment should conform to appropriate standards, be suitable for use, be kept in good condition
and properly maintained.
Your supplier of personal protective equipment should be consulted for advice on selection and
appropriate standards. For further information contact your national organisation for standards.
The final choice of protective equipment will depend upon a risk assessment. It is important to ensure
that all items of personal protective equipment are compatible.
Hygiene measures Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking
and using the lavatory and at the end of the working period. Ensure that eyewash stations and safety
showers are close to the workstation location.
Personal protective equipment
Respiratory protection Respiratory protective equipment is not normally required where there is adequate natural or local
exhaust ventilation to control exposure.
In case of insufficient ventilation, wear suitable respiratory equipment.
The correct choice of respiratory protection depends upon the chemicals being handled, the
conditions of work and use, and the condition of the respiratory equipment. Safety procedures should
be developed for each intended application. Respiratory protection equipment should therefore be
chosen in consultation with the supplier/manufacturer and with a full assessment of the working
conditions.
Skin and body Use of protective clothing is good industrial practice.
Personal protective equipment for the body should be selected based on the task being performed
and the risks involved and should be approved by a specialist before handling this product.
Cotton or polyester/cotton overalls will only provide protection against light superficial contamination
that will not soak through to the skin. Overalls should be laundered on a regular basis. When the risk
of skin exposure is high (e.g. when cleaning up spillages or if there is a risk of splashing) then
chemical resistant aprons and/or impervious chemical suits and boots will be required.
Hand protection Wear protective gloves if prolonged or repeated contact is likely.
The correct choice of protective gloves depends upon the chemicals being handled, the conditions of
work and use, and the condition of the gloves (even the best chemically resistant glove will break
down after repeated chemical exposures). Most gloves provide only a short time of protection before
they must be discarded and replaced. Because specific work environments and material handling
practices vary, safety procedures should be developed for each intended application. Gloves should
therefore be chosen in consultation with the supplier/manufacturer and with a full assessment of the
working conditions.
Eye protection Safety glasses with side shields.

9 . Physical and chemical properties
Physical state Liquid.
Colour Clear. Colourless.
Odour Ammoniacal. [Slight]
Vapour pressure Not available.
Vapour density Not available.
pH 9.5
Boiling point / range Not available.
Melting point / range Not available.
Relative density/Specific Not available.
gravity
Density 1094 kg/m³ (1.094 g/cm³) at 20°C
Solubility Soluble in water.
Partition coefficient <1
(LogKow)
10 . Stability and reactivity

Stability The product is stable.
Conditions to avoid Avoid contamination by any source including metals, dust and organic materials.
Incompatibility with various No hazardous reactions identified.
substances/Hazardous
Reactions
Hazardous decomposition Combustion products may include the following:
products carbon oxides (CO, CO2) (carbon monoxide, carbon dioxide)
nitrogen oxides
11 . Toxicological information
Eyes No significant health hazards identified.
Skin No significant health hazards identified.
Inhalation No significant health hazards identified.
Ingestion Ingestion of large quantities may cause nausea and diarrhoea.
Acute toxicity Unlikely to cause more than transient stinging or redness if accidental eye contact occurs.
Unlikely to cause harm to the skin on brief or occasional contact but prolonged or repeated exposure
may lead to dermatitis.
Unlikely to cause harm if accidentally swallowed in small doses, though larger quantities may cause
nausea and diarrhoea.
At normal ambient temperatures this product will be unlikely to present an inhalation hazard because
of its low volatility. May be harmful by inhalation if exposure to vapour, mists or fumes resulting from
thermal decomposition products occurs.
Chronic toxicity
Other chronic toxicity data Overexposure to the inhalation of airborne droplets or aerosols may cause irritation of the respiratory
tract.
Carcinogenic effects No component of this product at levels greater than or equal to 0.1% is identified as a carcinogen by
ACGIH, the International Agency for Research on Cancer (IARC), the European Commission (EC),
or the National Occupational Health and Safety Commission (Australia).
Mutagenic effects No known significant effects or critical hazards.
12 . Ecological information
Ecotoxicity Not classified as environmentally hazardous in accordance with the ‘Approved Criteria for Classifying
Hazardous Substances’ [NOHSC (1008)/2004 as amended and adapted].
Biodegradability
Bioaccumulative potential
Product/ingredient name LogPow BCF Potential
AdBlue <1 - low
Persistence/degradability Expected to be biodegradable.
Mobility Soluble in water.
Bioaccumulative potential This product is not expected to bioaccumulate through food chains in the environment.

13 . Disposal considerations
Disposal considerations / The generation of waste should be avoided or minimised wherever possible. Disposal of this product,
Waste information solutions and any by-products should at all times comply with the requirements of environmental
protection and waste disposal legislation and any regional local authority requirements. Dispose of
surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be
disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with
jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a safe way.
Empty containers or liners may retain some product residues. Avoid dispersal of spilt material and
runoff and contact with soil, waterways, drains and sewers.
Special Precautions for No additional special precautions identified.
Landfill or Incineration
14 . Transport information
International transport regulations
Not classified as dangerous for transport (ADG, IMDG, ICAO/IATA).
Special precautions for user No known special precautions required. See Section: "Handling and storage" for additional
information.
15 . Regulatory information
Standard Uniform Schedule of Medicine and Poisons
Not regulated.
Control of Scheduled Carcinogenic Substances
Ingredient name Schedule
No Listed Substance
Other regulations
REACH Status For the REACH status of this product please consult your company contact, as identified in Section 1.
United States inventory All components are listed or exempted.
(TSCA 8b)
Australia inventory (AICS) All components are listed or exempted.
Canada inventory All components are listed or exempted.
China inventory (IECSC) All components are listed or exempted.
Japan inventory (ENCS) All components are listed or exempted.
Korea inventory (KECI) All components are listed or exempted.
Philippines inventory All components are listed or exempted.
(PICCS)
16 . Other information
Key to abbreviations AMP = Acceptable Maximum Peak
ACGIH = American Conference of Governmental Industrial Hygienists, an agency that promulgates
exposure standards.
ADG = Australian Code for the Transport of Dangerous Goods by Road and Rail
ADG Code = Australian Code for the Transport of Dangerous Goods by Road and Rail
CAS Number = Chemical Abstracts Service Registry Number
HAZCHEM Code = Emergency action code of numbers and letters which gives information to
emergency services. Its use is required by the ADG Code for Dangerous Goods in bulk.
ICAO = International Civil Aviation Organization.
IATA = International Air Transport Association, the organization promulgating rules governing
shipment of goods by air.
IMDG = International Maritime Organization Rules, rules governing shipment of goods by water.
IP 346 = A chemical screening assay for dermal toxicity. The European Commission has
recommended that Method IP 346 be used as the basis for labelling certain lubricant oil base stocks
for carcinogenicity. The EU Commission has stipulated that the classification as a carcinogen need
not apply if it can be shown that the substance contains less than 3% DMSO extract as measured by
IP 346. (See Note L, European Commission Directive 67/548/EEC as amended and adapted.)
DMSO is a solvent.
NOHSC = National Occupational Health & Safety Commission, Australia
TWA = Time weighted average
STEL = Short term exposure limit
UN Number = United Nations Number, a four digit number assigned by the United Nations Committee
of Experts on the Transport of Dangerous Goods.
History
Date of issue 16/09/2013.
Date of previous issue No previous validation.
Prepared by Product Stewardship
Notice to reader

All reasonably practicable steps have been taken to ensure this data sheet and the health, safety and environmental information
contained in it is accurate as of the date specified below. No warranty or representation, express or implied is made as to the accuracy
or completeness of the data and information in this data sheet.
The data and advice given apply when the product is sold for the stated application or applications. You should not use the product other
than for the stated application or applications without seeking advice from us.
It is the user’s obligation to evaluate and use this product safely and to comply with all applicable laws and regulations. The BP Group
shall not be responsible for any damage or injury resulting from use, other than the stated product use of the material, from any failure to
adhere to recommendations, or from any hazards inherent in the nature of the material. Purchasers of the product for supply to a third
party for use at work, have a duty to take all necessary steps to ensure that any person handling or using the product is provided with the
information in this sheet. Employers have a duty to tell employees and others who may be affected of any hazards described in this sheet
and of any precautions that should be taken.

SAFETY DATA SHEET
Ultimate 98 petrol
Section 1. Identification
GHS product identifier Ultimate 98 petrol
SDS no. 0000002791
Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/ Fuel for spark ignition engines. NOT for aviation use.
mixture For specific application advice see appropriate Technical Data Sheet or consult our
company representative.
Manufacturer
ABN 53 004 085 616
www.bp.com.au

NUMBER
Section 2. Hazard(s) identification

Classification of the FLAMMABLE LIQUIDS - Category 1
substance or mixture SKIN CORROSION/IRRITATION - Category 2
GERM CELL MUTAGENICITY - Category 1B
CARCINOGENICITY - Category 1B
TOXIC TO REPRODUCTION (Fertility) - Category 2
TOXIC TO REPRODUCTION (Unborn child) - Category 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) -
Category 3
ASPIRATION HAZARD - Category 1
Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 1%
GHS label elements

Hazard pictograms
Signal word DANGER

Hazard statements H224 - Extremely flammable liquid and vapour.
H315 - Causes skin irritation.
H340 - May cause genetic defects.
H350 - May cause cancer.
H361 - Suspected of damaging fertility or the unborn child.
H304 - May be fatal if swallowed and enters airways.
H336 - May cause drowsiness or dizziness.
Precautionary statements
General P103 - Read label before use.
P102 - Keep out of reach of children.
P101 - If medical advice is needed, have product container or label at hand.
Product name Ultimate 98 petrol Product code 0000002791 Page: 1/15

Version 1 Date of issue 09/11/2016 Format Australia Language ENGLISH
Prevention P201 - Obtain special instructions before use.
P261 - Avoid breathing vapour.
P280 - Wear protective gloves. Wear eye or face protection. Wear protective
clothing
P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking.
P240 - Ground/bond container and receiving equipment.
P273 - Avoid release to the environment.
Response P304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for
breathing.
P301 + P310 + P331 - IF SWALLOWED: Immediately call a POISON CENTER or
doctor/physician. Do NOT induce vomiting.
P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated
clothing. Rinse skin with water or shower.
Storage P403 + P233 - Store in a well-ventilated place. Keep container tightly closed.
P235 - Keep cool.
P405 - Store locked up.
Disposal P501 - Dispose of contents and container in accordance with all local, regional,
national and international regulations.
Supplemental label Not applicable.
elements
Other hazards which do not Contains Benzene. Prolonged or repeated exposure to benzene can cause
result in classification anaemia and other blood diseases, including leukaemia.
Section 3. Composition and ingredient information

Substance/mixture Mixture
Ingredient name % (w/w) CAS number
Gasoline > 99 86290-81-5
Contains:
toluene < 20 108-88-3
n-hexane <5 110-54-3
Benzene <1 71-43-2
tert-butyl methyl ether(MTBE) <1 1634-04-4
2-methylpropan-2-ol <1 75-65-0
diisopropyl ether <1 108-20-3
Polycyclic aromatic hydrocarbons (PAHs) <1 mixture
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require
reporting in this section.
Occupational exposure limits, if available, are listed in Section 8.
Section 4. First aid measures

Description of necessary first aid measures
Eye contact In case of contact, immediately flush eyes with plenty of water for at least 15
minutes. Eyelids should be held away from the eyeball to ensure thorough rinsing.
Check for and remove any contact lenses. Get medical attention.
Inhalation If inhaled, remove to fresh air. Get medical attention.
If exposure to vapour, mists or fumes causes drowsiness, headache, blurred vision

or irritation of the eyes, nose or throat, remove immediately to fresh air. Keep patient
warm and at rest. If any symptoms persist obtain medical advice.

Skin contact In case of contact, immediately flush skin with plenty of water for at least 15 minutes
while removing contaminated clothing and shoes. Clean shoes thoroughly before
reuse. Drench contaminated clothing with water before removing. This is necessary
to avoid the risk of sparks from static electricity that could ignite contaminated
clothing. Contaminated clothing is a fire hazard. Contaminated leather, particularly
footwear, must be discarded. Get medical attention.
Ingestion Do not induce vomiting. Never give anything by mouth to an unconscious person. If
unconscious, place in recovery position and get medical attention immediately.
Aspiration hazard if swallowed. Can enter lungs and cause damage. Get medical
attention immediately.
Most important symptoms/effects, acute and delayed

See Section 11 for more detailed information on health effects and symptoms.
Indication of immediate medical attention and special treatment needed, if necessary
Notes to physician Treatment should in general be symptomatic and directed to relieving any effects.
Product can be aspirated on swallowing or following regurgitation of stomach
contents, and can cause severe and potentially fatal chemical pneumonitis, which
will require urgent treatment. Because of the risk of aspiration, induction of vomiting
and gastric lavage should be avoided. Gastric lavage should be undertaken only
after endotracheal intubation. Monitor for cardiac dysrhythmias.
Specific treatments No specific treatment.
Protection of first-aiders No action shall be taken involving any personal risk or without suitable training. If it
is suspected that fumes are still present, the rescuer should wear an appropriate
mask or self-contained breathing apparatus. It may be dangerous to the person
providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing
thoroughly with water before removing it, or wear gloves.
Section 5. Firefighting measures

Extinguishing media
Suitable extinguishing In case of fire, use water fog, foam, dry chemical or carbon dioxide extinguisher or
media spray.
Unsuitable extinguishing Do not use water jet.
media
Specific hazards arising Extremely flammable liquid and vapour. In a fire or if heated, a pressure increase
from the chemical will occur and the container may burst, with the risk of a subsequent explosion.
Runoff to sewer may create fire or explosion hazard. Liquid will float and may
reignite on surface of water.
Hazardous thermal Combustion products may include the following:
decomposition products carbon dioxide
carbon monoxide
other hazardous substances.
Special protective actions Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without
suitable training. Move containers from fire area if this can be done without risk.
Use water spray to keep fire-exposed containers cool.
Special protective Fire-fighters should wear positive pressure self-contained breathing apparatus
equipment for fire-fighters (SCBA) and full turnout gear.
Hazchem code 3YE

Section 6. Accidental release measures
Personal precautions, protective equipment and emergency procedures
For non-emergency Immediately contact emergency personnel. No action shall be taken involving any
personnel personal risk or without suitable training. Evacuate surrounding areas. Keep
unnecessary and unprotected personnel from entering. Do not touch or walk
through spilt material. No flares, smoking or flames in hazard area. Avoid breathing
vapour or mist. Provide adequate ventilation. Put on appropriate personal
protective equipment. Floors may be slippery; use care to avoid falling. Eliminate
all ignition sources.
For emergency responders Entry into a confined space or poorly ventilated area contaminated with vapour, mist
or fume is extremely hazardous without the correct respiratory protective equipment
and a safe system of work. Wear self-contained breathing apparatus. Wear a
suitable chemical protective suit. Chemical resistant boots. See also the
information in "For non-emergency personnel".
Environmental precautions Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air). In case of small spillages in closed waters
(i.e. ports), contain product with floating barriers or other equipment. Collect spilled
product by absorbing with specific floating absorbents. If possible, large spillages in
open waters should be contained with floating barriers or other mechanical means.
If this is not possible, control the spreading of the spillage, and collect the product by
skimming or other suitable mechanical means. The use of dispersants should be
advised by an expert, and, if required, approved by local authorities. Collect
recovered product and other contaminated materials in suitable tanks or containers
for recycle, recovery or safe disposal.
Methods and material for containment and cleaning up

Small spill Eliminate all ignition sources. Stop leak if without risk. Move containers from spill
area. Absorb with an inert material and place in an appropriate waste disposal
container. Use spark-proof tools and explosion-proof equipment. Dispose of via a
licensed waste disposal contractor. The method and equipment used must be in
conformance with appropriate regulations and industry practice on explosive
atmospheres.
Large spill Eliminate all ignition sources. Stop leak if without risk. Move containers from spill
area. Approach the release from upwind. Prevent entry into sewers, water courses,
basements or confined areas. Dike spill area and do not allow product to reach
sewage system and surface or ground water. Contain and collect spillage with non-
combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth
and place in container for disposal according to local regulations. Use spark-proof
tools and explosion-proof equipment. Contaminated absorbent material may pose
the same hazard as the spilt product. The method and equipment used must be in
atmospheres. Dispose of via a licensed waste disposal contractor.
Section 7. Handling and storage

Precautions for safe handling
Protective measures Do not fill container while it is in or on a vehicle. Static electricity may ignite vapour
and cause fire. Place container on ground when filling and keep nozzle in contact
with container.
Put on appropriate personal protective equipment (see Section 8). Do not get in
eyes or on skin or clothing. Avoid breathing vapour or mist. Use only with adequate
ventilation. Wear appropriate respirator when ventilation is inadequate. Take
precautionary measures against electrostatic discharges. Empty containers retain
product residue and can be hazardous. Keep in the original container or an
approved alternative made from a compatible material, kept tightly closed when not
in use. Do not reuse container. Store and use away from heat, sparks, open flame

or any other ignition source. Use explosion-proof electrical (ventilating, lighting and
material handling) equipment. Use only non-sparking tools. Avoid exposure -
obtain special instructions before use. Do not handle until all safety precautions
have been read and understood. Avoid exposure during pregnancy. Do not
swallow. Aspiration hazard if swallowed. Can enter lungs and cause damage.
Never siphon by mouth.
Advice on general Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Wash thoroughly after handling. Remove
contaminated clothing and protective equipment before entering eating areas. See
also Section 8 for additional information on hygiene measures.
Conditions for safe storage, Store in accordance with local regulations. Store in a segregated and approved
including any area. Store in original container protected from direct sunlight in a dry, cool and well-
incompatibilities ventilated area, away from incompatible materials (see Section 10) and food and
drink. Store locked up. Eliminate all ignition sources. Separate from oxidising
materials. Keep container tightly closed and sealed until ready for use. Store and
use only in equipment/containers designed for use with this product. Containers
that have been opened must be carefully resealed and kept upright to prevent
leakage. Do not store in unlabelled containers. Use appropriate containment to
avoid environmental contamination.
Light hydrocarbon vapours can build up in the headspace of tanks. These can
cause flammability/explosion hazards even at temperatures below the normal flash
point (note: flash point must not be regarded as a reliable indicator of the potential
flammability of vapour in tank headspaces). Tank headspaces should always be
regarded as potentially flammable and care should be taken to avoid static electrical
discharge and all ignition sources during filling, ullaging and sampling from storage
tanks. Do not enter storage tanks. If entry to vessels is necessary, follow permit to
work procedures. When the product is pumped (e.g. during filling, discharge or
ullaging) and when sampling, there is a risk of static discharge. Ensure equipment
used is properly earthed or bonded to the tank structure. Electrical equipment
should not be used unless it is intrinsically safe (i.e. will not produce sparks).
Explosive air/vapour mixtures may form at ambient temperature. If product comes
into contact with hot surfaces, or leaks occur from pressurised fuel pipes, the
vapour or mists generated will create a flammability or explosion hazard. Product
contaminated rags, paper or material used to absorb spillages, represent a fire
hazard, and should not be allowed to accumulate. Dispose of safely immediately
after use. Entry into a confined space or poorly ventilated area contaminated with
vapour, mist or fume is extremely hazardous without the correct respiratory
protective equipment and a safe system of work.
Section 8. Exposure controls and personal protection

Control parameters
Occupational exposure limits
Ingredient name Exposure limits
Gasoline ACGIH TLV (United States).
TWA: 300 ppm 8 hours. Issued/Revised:
5/1996
TWA: 890 mg/m³ 8 hours. Issued/Revised:
5/1996
STEL: 500 ppm 15 minutes. Issued/
Revised: 5/1996
STEL: 1480 mg/m³ 15 minutes. Issued/
Revised: 5/1996
toluene Safe Work Australia (Australia). Absorbed
through skin.

Revised: 8/2005
Revised: 8/2005
8/2005
8/2005
n-hexane Safe Work Australia (Australia).
11/2001
11/2001
Polycyclic aromatic hydrocarbons (PAHs) Safe Work Australia (Australia).
TWA: 0.2 mg/m³ 8 hours.
Benzene Safe Work Australia (Australia).
TWA: 3.2 mg/m³ 8 hours. Issued/Revised:
4/2003
4/2003
tert-butyl methyl ether(MTBE) Safe Work Australia (Australia).
Revised: 4/2002
STEL: 75 ppm 15 minutes. Issued/Revised:
4/2002
4/2002
4/2002
2-methylpropan-2-ol Safe Work Australia (Australia).
Revised: 5/1995
Revised: 5/1995
5/1995
5/1995
diisopropyl ether Safe Work Australia (Australia).
Revised: 5/1995
Revised: 5/1995
5/1995
5/1995
Appropriate engineering All activities involving chemicals should be assessed for their risks to health, to
controls ensure exposures are adequately controlled. Personal protective equipment should
only be considered after other forms of control measures (e.g. engineering controls)
have been suitably evaluated. Personal protective equipment should conform to
appropriate standards, be suitable for use, be kept in good condition and properly
maintained.
Your supplier of personal protective equipment should be consulted for advice on
selection and appropriate standards. For further information contact your national
organisation for standards.
Provide exhaust ventilation or other engineering controls to keep the relevant
airborne concentrations below their respective occupational exposure limits.

The final choice of protective equipment will depend upon a risk assessment. It is
important to ensure that all items of personal protective equipment are compatible.
Environmental exposure Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation.
Individual protection measures

Hygiene measures Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and
safety showers are close to the workstation location.
Eye/face protection Recommended: splash goggles
Skin protection
Hand protection Wear chemical resistant gloves.
Do not re-use gloves. Protective gloves must give suitable protection against
mechanical risks (i.e. abrasion, blade cut and puncture). Protective gloves will
deteriorate over time due to physical and chemical damage. Inspect and replace
gloves on a regular basis. The frequency of replacement will depend upon the
circumstances of use.
Recommended: Gloves made from fluoroelastomer resistant to hydrocarbons
and a wide range of chemicals.
Wear a chemically resistant multi-layer laminate inner glove
inside an outer nitrile glove. The purpose of the outer glove is to
protect the inner glove from cuts and mechanical damage. The
presence of aromatic hydrocarbons in the product will
significantly shorten the length of time that nitrile gloves will
provide protection. Do not re-use nitrile gloves if exposed to
aromatic hydrocarbons.
Skin protection Use of protective clothing is good industrial practice.
Cotton or polyester/cotton overalls will only provide protection against light
superficial contamination that will not soak through to the skin. Overalls should be
laundered on a regular basis. When the risk of skin exposure is high (e.g. when
cleaning up spillages or if there is a risk of splashing) then chemical resistant aprons
and/or impervious chemical suits and boots will be required.
Wear suitable protective clothing.
Footwear highly resistant to chemicals.
When there is a risk of ignition from static electricity, wear anti-static protective
clothing. For greatest effectiveness against static electricity, overalls, boots and
gloves should all be anti-static.
When there is a risk of ignition wear inherently fire resistant protective clothes and
gloves.
Work clothing / overalls should be laundered on a regular basis. Laundering of
contaminated work clothing should only be done by professional cleaners who have
been told about the hazards of the contamination. Always keep contaminated work
clothing away from uncontaminated work clothing and uncontaminated personal
clothes.
When the risk of skin exposure is high (from experience this could apply to the
following tasks: cleaning work, maintenance and service, filling and transfer, taking
samples and cleaning up spillages) then a chemical protective suit and boots will be
required.
Personal protective equipment for the body should be selected based on the task
being performed and the risks involved and should be approved by a specialist
before handling this product.
Recommended: overall
Other skin protection Appropriate footwear and any additional skin protection measures should be
selected based on the task being performed and the risks involved and should be
approved by a specialist before handling this product. Recommended: nitrile rubber

Respiratory protection Use with adequate ventilation.
If there is a requirement for the use of a respiratory protective device, but the use of
breathing apparatus (independent of ambient atmosphere) is not required, then a
suitable filtering device must be worn.
The filter class must be suitable for the maximum contaminant concentration (gas/
vapour/aerosol/particulates) that may arise when handling the product.
The correct choice of respiratory protection depends upon the chemicals being
handled, the conditions of work and use, and the condition of the respiratory
equipment. Safety procedures should be developed for each intended application.
Respiratory protection equipment should therefore be chosen in consultation with
the supplier/manufacturer and with a full assessment of the working conditions.
Recommended: full-face mask
Recommended: Avoid breathing of vapours, mists or spray. Select and use
respirators in accordance with AS/NZS 1715/1716. When mists
or vapours exceed the exposure standards then the use of the
following is recommended: Approved respirator with organic
vapour and dust/mist (Type P1) filters. Filter capacity and
respirator type depends on exposure level.
Refer to standards: Respiratory protection:AS/NZS 1715 and AS/NZS 1716
Gloves:AS/NZS 2161.1
Eye protection:AS/NZS 1336 and AS/NZS 1337
Section 9. Physical and chemical properties

Appearance
Physical state Liquid. Clear and Bright
Colour Pale Yellow.
Odour Hydrocarbon.
Odour threshold Not available.
pH Not available.
Melting point Not available.
Boiling point >30 to < 210°C (>86 to < 410°F)
Flash point Closed cup: <-40°C (<-40°F)
Evaporation rate Not available.
Flammability (solid, gas) Not applicable. Based on - Physical state
Lower and upper explosive Lower: 1.4%
(flammable) limits Upper: 7.6%
Vapour pressure 30 to 100 kPa (225 to 750 mm Hg)
Relative density Not available.
Density 750 kg/m³ (0.75 g/cm³)
Solubility insoluble in water.
Partition coefficient: n- Not available.
octanol/water
Auto-ignition temperature >350°C (>662°F)
Decomposition temperature Not available.
Viscosity Kinematic: 0.4 to 0.55 mm2/s (0.4 to 0.55 cSt) at 40°C
Remarks Reid vapor pressure (RVP): 55 to 100 kPa (40 oC )

Section 10. Stability and reactivity
Reactivity No specific test data available for this product. Refer to Conditions to avoid and
Incompatible materials for additional information.
Chemical stability The product is stable.
Possibility of hazardous Under normal conditions of storage and use, hazardous reactions will not occur.
reactions Under normal conditions of storage and use, hazardous polymerisation will not
occur.
Conditions to avoid Avoid all possible sources of ignition (spark or flame). Avoid excessive heat.
Incompatible materials Reactive or incompatible with the following materials: oxidising materials.
Hazardous decomposition Under normal conditions of storage and use, hazardous decomposition products
products should not be produced.
Section 11. Toxicological information

Information on toxicological effects
Specific target organ toxicity (single exposure)
Name Category Route of Target organs
exposure
Gasoline Category 3 Not applicable. Narcotic effects
toluene Category 3 Not applicable. Narcotic effects
n-hexane Category 3 Not applicable. Narcotic effects
Benzene Category 3 Not applicable. Respiratory tract
irritation and
Narcotic effects
tert-butyl methyl ether(MTBE) Category 3 Not applicable. Narcotic effects
diisopropyl ether Category 3 Not applicable. Narcotic effects
Specific target organ toxicity (repeated exposure)
exposure
toluene Category 2 Not determined hearing organs
n-hexane Category 2 Inhalation peripheral nervous
system
Benzene Category 1 Not determined blood system
Aspiration hazard
Name Result
Gasoline ASPIRATION HAZARD - Category 1
toluene ASPIRATION HAZARD - Category 1
n-hexane ASPIRATION HAZARD - Category 1
Information on likely routes Routes of entry anticipated: Dermal, Inhalation.

of exposure
Potential acute health effects
Eye contact No known significant effects or critical hazards.
Inhalation Can cause central nervous system (CNS) depression. May cause drowsiness or
dizziness.
Skin contact Causes skin irritation.
Ingestion Irritating to mouth, throat and stomach. Aspiration hazard if swallowed -- harmful or
fatal if liquid is aspirated into lungs.
Symptoms related to the physical, chemical and toxicological characteristics

Eye contact Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation Adverse symptoms may include the following:
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
Skin contact Adverse symptoms may include the following:
irritation
redness
reduced foetal weight
increase in foetal deaths
skeletal malformations
Ingestion Adverse symptoms may include the following:
nausea or vomiting
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Eye contact Vapour, mist or fume may cause eye irritation. Exposure to vapour, mist or fume
may cause stinging, redness and watering of the eyes.
Inhalation Vapour, mist or fume may irritate the nose, mouth and respiratory tract.
Skin contact Prolonged or repeated contact can defat the skin and lead to irritation, cracking and/
or dermatitis.
Ingestion If swallowed, may irritate the mouth, throat and digestive system. If swallowed, may
cause abdominal pain, stomach cramps, nausea, vomiting, diarrhoea, dizziness and
drowsiness.
General This product contains n-hexane. Overexposure to n-hexane may cause progressive
and potentially irreversible damage to the peripheral nervous system, particularly in
the arms and legs. Animal studies have also shown that n-hexane overexposure
may cause testicular injury. However, animal studies conducted with commercial
hexane, containing 53% n-hexane, showed neither peripheral nervous system
damage nor testicular injury at inhalation exposures up to 9000 ppm. Solvent
"sniffing" (abuse) or intentional overexposure to vapours can produce serious
central nervous system effects, including unconsciousness, and possibly death.
Carcinogenicity May cause cancer. Risk of cancer depends on duration and level of exposure.
Mutagenicity May cause genetic defects.
Teratogenicity Suspected of damaging the unborn child.
Developmental effects No known significant effects or critical hazards.
Fertility effects Suspected of damaging fertility.
Other information Gasoline - Excess exposure to vapors may produce headaches, dizziness, nausea,
drowsiness, irritation of eyes, nose and throat and central nervous system
depression. Aspiration of this material into the lungs can cause chemical pneumonia
and can be fatal. Aspiration into the lungs can occur while vomiting after ingestion of
this product. Inhalation of unleaded gasoline vapors did not produce birth defects in
laboratory animals. Ingestion of this material can cause gastrointestinal irritation and
diarrhea.
In a long-term inhalation study of whole unleaded gasoline vapors, exposure-related

kidney damage and kidney tumors were observed in male rats. Similar kidney
effects were not seen in female rats or in mice. At the highest exposure level (2056
ppm), female mice had an increased incidence of liver tumors. Results from
subsequent scientific studies have shown that a broad variety of chemicals cause
these kidney effects only in the male rat. Further studies have discovered the means
by which the physiology of the male rat uniquely predispose it to these effects.
Consequently, the Risk Assessment Forum of the Environmental Protection Agency
has recognized that these responses are not predictive of a human health hazard.
The liver tumors that were increased in the high-dose female mice are likewise of
questionable significance because of their high spontaneous occurrence even
without chemical exposure and because the rate of their occurrence is accelerated
by a broad spectrum of chemicals not commonly considered to be carcinogens (e.g.,
phenobarbital).
Thus, the significance of the mouse liver tumor response in terms of human health
is questionable.
Gasoline is a complex mixture of hydrocarbons and contains benzene (typically no

more than 2 volume%), toluene, and xylene. Chronic exposure to high levels of
benzene has been shown to cause cancer (leukemia) in humans and other adverse
blood effects (anemia). Benzene is considered a human carcinogen by IARC, NTP
and OSHA. Over exposure to xylene and toluene can cause irritation to the upper
respiratory tract, headache and narcosis. Some liver damage and lung inflammation
were seen in chronic studies on xylene in guinea pigs but not in rats.
Solvent "sniffing" (abuse) or intentional overexposure to vapors can produce serious

Gasoline: Additional toxicity information on the components:
Benzene: Acute toxicity of benzene results primarily from depression of the central
nervous system (CNS). Inhalation of concentrations over 50 ppm can produce
headache, lassitude, weariness, dizziness, drowsiness, or excitation. Exposure to
very high levels can result in unconsciousness and death.
Benzene: Long-term overexposure to benzene has been associated with certain

types of leukemia in humans. In addition, the International Agency for Research on
Cancer (IARC), the National Toxicology Program, and OSHA consider benzene to
be a human carcinogen. Chronic exposures to high levels of benzene have been
reported to cause adverse blood effects including anemia. Benzene exposure can
occur by inhalation and absorption through the skin.
Inhalation and forced feeding studies of benzene in laboratory animals have
produced a carcinogenic response in a variety of organs, including possibly
leukemia, other adverse effects on the blood, chromosomal changes and some
effects on the immune system. Exposure to benzene at levels up to 300 ppm did not
produce birth defects in animal studies; however, exposure to higher dosage levels
resulted in a reduction of body weight of the rat pups (fetotoxicity). Changes in the
testes have been observed in mice exposed to benzene at 300 ppm, but
reproductive performance was not altered in rats exposed to benzene at the same
level. Aspiration of this material into the lungs can cause chemical pneumonia and
can be fatal. Aspiration into the lungs can occur while vomiting after ingestion of this
material.
Toluene: Aspiration of this material into the lungs can cause chemical pneumonia
and can be fatal. Aspiration into the lungs can occur while vomiting after ingestion
of this material. Deliberate inhalation of high concentrations of toluene has been
linked to damage of the brain, liver and kidney. Inhalation of very high
concentrations of toluene, such as in cases of solvent abuse, has resulted in
sudden death which may be a result of cardiac arrhythmia or central nervous
system depression. Mental and/or growth retardation has been reported in children
of women who deliberately inhale toluene during pregnancy (usually at thousands of
ppm). Foetal developmental toxicity was observed when pregnant rats were
exposed to toluene at levels of 1500 ppm. Maternal toxicity was also observed at
this concentration. Prolonged, high level exposure to toluene in laboratory animals

has resulted in hearing loss. Exposure studies in rats have resulted in adverse
effects on the kidney, liver and central nervous system. Studies in occupationally
exposed individuals indicate that toluene exposure has been associated with
impaired colour vision and decreased performance in some neurobehavioural tests.
There are occupational studies which report an association between inhalation
exposure to toluene and adverse effects on reproduction including spontaneous
abortion. The methodology of these studies and the reliability of the results have
been questioned. In a two-generation study in rats, inhalation of toluene at levels up
to 2000 ppm did not produce adverse effects on fertility or reproductive performance.
Xylenes: Xylene has been reported to cause central nervous system effects at
concentrations above the recommended exposure limit. Xylene vapour becomes
irritating at relatively high levels. In one study, eye irritation was reported at
exposures of 460 ppm and in one person at 230 ppm after 15 minutes. In another
study, no one reported eyes, nose and throat irritation at mixed xylene exposures up
to 230 ppm for 30 minutes. Dermal LD50 is expected to be greater than 10g/kg in
rabbits, based on test results from similar materials.
Mixed xylenes caused slight hearing loss in rats exposed to 800 ppm in the air for
14 hours/day for six weeks. There is no information available for lower
concentrations; however, similar chemicals that have caused these hearing effects
at similar concentrations have not caused effects at lower concentrations.
Pregnant animals exposed to xylene or its isomers have been reported to cause
development toxicity in rodents when exposed by inhalation. The developmental
effects observed consisted of delayed development and minor skeletal variations,
but no malformations. Because of the high exposure levels used in these studies,
we do not believe that these results imply an increased risk of reproductive toxicity
to workers exposed to xylene levels at or below the exposure limits.
Xylene and its isomers are not genotoxic.
Technical grade xylene has been tested in a National Toxicology Program

carcinogenicity study in rats and mice dosed orally for two years. There was no
evidence of carcinogenicity.
Ethylbenzene - The National Toxicology Program (NTP) conducted a 13-week

inhalation study with male and female rats and mice at exposure concentrations
ranging from 100 to 1000 ppm ethylbenzene. No rats or mice died during the study.
Kidney, liver, and lung weights were increased in the exposed rats, while weight
increases were observed only in the livers of exposed mice. Treatment-related
histopathologic changes were not observed in any tissues of rats and mice.
NTP also exposed male and female rats and mice by inhalation to 0, 75, 250, or 750
ppm ethylbenzene for 2 years. There was a statistically significant increase in the
number of kidney tumors in male and female rats at 750 ppm. There were also
increased incidences of lung tumors in male mice and liver tumors in female mice
that were statistically significant at 750 ppm. Except for the male rat kidney tumors,
the incidence of the tumors were within the range observed for non-exposed
animals from other studies conducted by NTP. The significance of these findings to
humans is unknown. Ethylbenzene is not genotoxic. The International Agency for
Research on Cancer (IARC) has evaluated ethylbenzene and found it to be possibly
carcinogenic to humans (Group 2B).
Ethylbenzene is not genotoxic.
Naphthalene has been reported to cause developmental toxicity in mice after oral
exposure to relatively high dose levels, but developmental toxicity was not observed
in NTP (National Toxicology Program) sponsored studies in rats and rabbits.
Ingestion or inhalation of naphthalene can result in hemolysis and other blood
abnormalities, and individuals (and infants) deficient in glucose-6-phosphate
dehydrogenase may be especially susceptible to these effects. Inhalation of
naphthalene may cause headache and nausea. Airborne exposure can result in eye

irritation. Naphthalene exposure has been associated with cataracts in animals and
humans.
Section 12. Ecological information
Persistence and degradability

Expected to be biodegradable. Non-persistent per IMO criteria
Product/ingredient name Aquatic half-life Photolysis Biodegradability
Gasoline - - Inherent
This product is not expected to bioaccumulate through food chains in the environment.
Mobility in soil
Soil/water partition Not available.
coefficient (KOC)
Mobility Spillages may penetrate the soil causing ground water contamination.
Other ecological information Spills may form a film on water surfaces causing physical damage to organisms.
Oxygen transfer could also be impaired.
Section 13. Disposal considerations

Disposal methods The generation of waste should be avoided or minimised wherever possible.
Significant quantities of waste product residues should not be disposed of via the
foul sewer but processed in a suitable effluent treatment plant. Dispose of surplus
and non-recyclable products via a licensed waste disposal contractor. Disposal of
this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Waste packaging should be recycled.
Incineration or landfill should only be considered when recycling is not feasible. This
material and its container must be disposed of in a safe way. Care should be taken
when handling emptied containers that have not been cleaned or rinsed out. Empty
containers or liners may retain some product residues. Vapour from product
residues may create a highly flammable or explosive atmosphere inside the
container. Do not cut, weld or grind used containers unless they have been cleaned
thoroughly internally. Avoid dispersal of spilt material and runoff and contact with
soil, waterways, drains and sewers.
Section 14. Transport information

ADG IMDG IATA
UN number UN1203 UN1203 UN1203
UN proper MOTOR SPIRIT or MOTOR SPIRIT or MOTOR SPIRIT or

shipping name GASOLINE or PETROL GASOLINE or PETROL GASOLINE or PETROL
MARINE POLLUTANT
Transport hazard 3 3 3
class(es)

Packing group II II II
Environmental No. Yes. No.
hazards
Additional Hazchem code The marine pollutant mark is The environmentally
information 3YE not required when transported hazardous substance mark
in sizes of ≤5 L or ≤5 kg. may appear if required by
Initial emergency response other transportation
guide Emergency schedules regulations.
14 (EmS)
F-E; S-E
Special precautions for user Not available.
Transport in bulk according Proper shipping name MARPOL Annex 1 rules apply for bulk shipments
to Annex II of Marpol and by sea.
the IBC Code Category: gasoline and spirits
Section 15. Regulatory information

Not scheduled When packed in containers having capacity of greater than 20 litres.
S5. When packed in containers having capacity of less than 20 litres.

Consumer products - This product is exempt per Appendix A of the SUSMP.
Industrial Products - Labelling requirements for SUSMP do not apply to a poison that is packed and sold solely for
industrial, laboratory or manufacturing use. However, this product is labelled in accordance with NOSHC National
Code of Practice for labelling of workplace substances.
Model Work Health and Safety Regulations - Scheduled Substances
No listed substance
International lists
National inventory
REACH Status For the REACH status of this product please consult your company contact, as
identified in Section 1.
Australia inventory (AICS) Contact local supplier or distributor.
Canada inventory
China inventory (IECSC) At least one component is not listed.
Japan inventory (ENCS) At least one component is not listed.
Korea inventory (KECI) At least one component is not listed.
Philippines inventory At least one component is not listed.
(PICCS)
Taiwan Chemical Not determined.
Substances Inventory
(TCSI)
United States inventory Not determined.
(TSCA 8b)

Section 16. Any other relevant information
History
Date of printing 09/11/2016
Date of issue/Date of 09/11/2016
revision
Date of previous issue No previous validation
Version 1
Key to abbreviations ADG = Australian Dangerous Goods
ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships,
1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)
NOHSC = National Occupational Health and Safety Commission
SUSMP = Standard Uniform Schedule of Medicine and Poisons
UN = United Nations
VOC = Volatile Organic Compound
SADT = Self-Accelerating Decomposition Temperature
Varies = may contain one or more of the following 101316-69-2, 101316-70-5,
101316-71-6, 101316-72-7, 64741-88-4, 64741-89-5, 64741-95-3, 64741-96-4,
64741-97-5, 64742-01-4, 64742-44-5, 64742-45-6, 64742-52-5, 64742-53-6,
64742-54-7, 64742-55-8, 64742-56-9, 64742-57-0, 64742-58-1, 64742-62-7,
64742-63-8, 64742-64-9, 64742-65-0, 64742-70-7, 72623-85-9, 72623-86-0,
72623-87-1, 74869-22-0, 90669-74-2
Procedure used to derive the classification
Classification Justification
Flam. Liq. 1, H224 Expert judgment
Skin Irrit. 2, H315 Expert judgment
Muta. 1B, H340 Expert judgment
Carc. 1B, H350 Expert judgment
Repr. 2, H361 (Fertility) Expert judgment
Repr. 2, H361 (Unborn child) Expert judgment
STOT SE 3, H336 Expert judgment
Asp. Tox. 1, H304 Expert judgment
Indicates information that has changed from previously issued version.
Notice to reader
All reasonably practicable steps have been taken to ensure this data sheet and the health, safety and environmental
information contained in it is accurate as of the date specified below. No warranty or representation, express or implied
is made as to the accuracy or completeness of the data and information in this data sheet.
The data and advice given apply when the product is sold for the stated application or applications. You should not use
the product other than for the stated application or applications without seeking advice from BP Group.
It is the user’s obligation to evaluate and use this product safely and to comply with all applicable laws and regulations.
The BP Group shall not be responsible for any damage or injury resulting from use, other than the stated product use
of the material, from any failure to adhere to recommendations, or from any hazards inherent in the nature of the
material. Purchasers of the product for supply to a third party for use at work, have a duty to take all necessary steps to
ensure that any person handling or using the product is provided with the information in this sheet. Employers have a
duty to tell employees and others who may be affected of any hazards described in this sheet and of any precautions
that should be taken. You can contact the BP Group to ensure that this document is the most current available.
Alteration of this document is strictly prohibited.

SAFETY DATA SHEET
BP Ultimate Diesel
GHS product identifier BP Ultimate Diesel
SDS no. 0000002790
Use of the substance/ Fuel for compression ignition diesel engines.
mixture
Manufacturer
ABN 53 004 085 616
www.bp.com.au

NUMBER

substance or mixture ACUTE TOXICITY (inhalation) - Category 4
SKIN CORROSION/IRRITATION - Category 2
CARCINOGENICITY - Category 2
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (bone marrow,
liver and thymus) - Category 2
GHS label elements

Hazard pictograms
Signal word DANGER

Hazard statements H227 - Combustible liquid.
H332 - Harmful if inhaled.
H351 - Suspected of causing cancer.
H373 - May cause damage to organs through prolonged or repeated exposure.
(bone marrow, liver, thymus)
Product name BP Ultimate Diesel Product code 0000002790 Page: 1/13

P260 - Do not breathe vapour.
clothing.
P241 - Use explosion-proof electrical, ventilating, lighting and all material-handling
equipment.
P273 -Avoid release to the environment.
Response P314 - Get medical attention if you feel unwell.
P308 + P313 - IF exposed or concerned: Get medical attention.
P304 + P340 + P312 - IF INHALED: Remove victim to fresh air and keep at rest in a
position comfortable for breathing. Call a POISON CENTER or physician if you feel
unwell.
physician. Do NOT induce vomiting.
P302 + P352 + P362-2 + P363 - IF ON SKIN: Wash with plenty of soap and water.
Take off contaminated clothing. Wash contaminated clothing before reuse.
P332 + P313 - If skin irritation occurs: Get medical attention.
Storage P405 - Store locked up.
P403 - Store in a well-ventilated place.
P235 - Keep cool.
elements
Other hazards which do not This material may contain significant quantities of polycyclic aromatic hydrocarbons,
result in classification some of which have been shown by experimental studies to induce skin cancer.
Note: High Pressure Applications
Injections through the skin resulting from contact with the product at high pressure
constitute a major medical emergency.
See 'Notes to physician' under First-Aid Measures, Section 4 of this Safety Data
Sheet.

May also contain small quantities of proprietary performance additives. Contains small quantities of polycyclic aromatic
hydrocarbons (PAHs).
Fuels, diesel > 95 68334-30-5
Alkanes, C10-20-branched and linear 0 - 20 928771-01-1

Inhalation If inhaled, remove to fresh air. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.
Get medical attention.



constitute a major medical emergency. Injuries may not appear serious at first but
within a few hours tissue becomes swollen, discoloured and extremely painful with
extensive subcutaneous necrosis.
Surgical exploration should be undertaken without delay. Thorough and extensive
debridement of the wound and underlying tissue is necessary to minimise tissue
loss and prevent or limit permanent damage. Note that high pressure may force the
product considerable distances along tissue planes.
providing aid to give mouth-to-mouth resuscitation.

Extinguishing media
media spray.
media
Specific hazards arising Combustible liquid. Fire water contaminated with this material must be contained
from the chemical and prevented from being discharged to any waterway, sewer or drain. In a fire or if
heated, a pressure increase will occur and the container may burst, with the risk of a
subsequent explosion. Runoff to sewer may create fire or explosion hazard. Liquid
will float and may reignite on surface of water.
carbon monoxide


pollution (sewers, waterways, soil or air). Water polluting material. May be harmful
to the environment if released in large quantities. In case of small spillages in
closed waters (i.e. ports), contain product with floating barriers or other equipment.
Collect spilled product by absorbing with specific floating absorbents. If possible,
large spillages in open waters should be contained with floating barriers or other
mechanical means. If this is not possible, control the spreading of the spillage, and
collect the product by skimming or other suitable mechanical means. The use of
dispersants should be advised by an expert, and, if required, approved by local
authorities. Collect recovered product and other contaminated materials in suitable
tanks or containers for recycle, recovery or safe disposal.

atmospheres.

Protective measures Put on appropriate personal protective equipment (see Section 8). Do not get in
eyes or on skin or clothing. Use only with adequate ventilation. Wear appropriate
respirator when ventilation is inadequate. Avoid contact of spilt material and runoff
with soil and surface waterways. Empty containers retain product residue and can
be hazardous. Keep in the original container or an approved alternative made from
a compatible material, kept tightly closed when not in use. Do not reuse container.
Store and use away from heat, sparks, open flame or any other ignition source. Use
explosion-proof electrical (ventilating, lighting and material handling) equipment.
Use only non-sparking tools. Do not breathe vapour or mist. Avoid exposure -
have been read and understood. Do not swallow. Aspiration hazard if swallowed.
Can enter lungs and cause damage. Never siphon by mouth.
As a precaution, tank headspaces should always be regarded as potentially

flammable and care should be taken to avoid static electrical discharge and all
ignition sources during filling, ullaging and sampling from storage tanks. Do not
enter storage tanks. If entry to vessels is necessary, follow permit to work
procedures. When the product is pumped (e.g. during filling, discharge or ullaging)
and when sampling, there is a risk of static discharge. Ensure equipment used is
properly earthed or bonded to the tank structure. Electrical equipment should not be
used unless it is intrinsically safe (i.e. will not produce sparks). Explosive air/vapour
mixtures may form at ambient temperature. If product comes into contact with hot
surfaces, or leaks occur from pressurised fuel pipes, the vapour or mists generated
will create a flammability or explosion hazard. Product contaminated rags, paper or
material used to absorb spillages, represent a fire hazard, and should not be
allowed to accumulate. Dispose of safely immediately after use. Entry into a
confined space or poorly ventilated area contaminated with vapour, mist or fume is
extremely hazardous without the correct respiratory protective equipment and a safe
system of work.

Control parameters
Fuels, diesel ACGIH TLV (United States). Absorbed
through skin.
TWA: 100 mg/m³, (measured as total
hydrocarbons) 8 hours. Issued/Revised:
1/2007 Form: Inhalable fraction and vapor

maintained.
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process
equipment will be necessary to reduce emissions to acceptable levels.

Eye/face protection Chemical splash goggles.
Skin protection
Protective gloves must give suitable protection against mechanical risks (i.e.
abrasion, blade cut and puncture). Protective gloves will deteriorate over time due
to physical and chemical damage. Inspect and replace gloves on a regular basis.
The frequency of replacement will depend upon the circumstances of use.
Recommended: Nitrile gloves.
gloves.
clothes.
required.

approved by a specialist before handling this product.
Recommended: If ventilation is inadequate, use respirator that will protect against
organic vapour and dust/mist.

Appearance
Colour Clear and Bright
Odour Mild
pH Not available.
Boiling point 108 to 380°C (226.4 to 716°F)
Flash point Closed cup: >61.5°C (>142.7°F) [Pensky-Martens.]
Vapour pressure 0.1 kPa (0.755 mm Hg)
Relative density 0.83
Density 820 to 850 kg/m³ (0.82 to 0.85 g/cm³) at 15°C
Solubility Very slightly soluble in water
octanol/water
Auto-ignition temperature Not available.
Viscosity Kinematic: 2 to 4.5 mm2/s (2 to 4.5 cSt) at 40°C

occur.

Acute toxicity
Product/ingredient name Result Species Dose Exposure
Fuels, diesel LC50 Inhalation Dusts and mists Rat 4.1 mg/l 4 hours
LD50 Dermal Rabbit >4300 mg/kg -
LD50 Oral Rat 17900 mg/kg -
Irritation/Corrosion
Product/ingredient name Result Species Score Exposure Observation
Fuels, diesel Skin - Irritation Rabbit - - -
Skin - Irritation Rabbit - - -
Eyes - Non-irritating to the Rabbit - - -
eyes.
eyes.
Skin Causes skin irritation.
Sensitisation
Product/ingredient name Route of Species Result
exposure
Fuels, diesel skin Guinea pig Not sensitising
skin Guinea pig Not sensitising
Mutagenicity
Product/ingredient name Test Experiment Result
Fuels, diesel OECD 471 Experiment: In vitro Positive
Subject: Non-mammalian species
Equivalent to OECD Experiment: In vitro Negative
476
Subject: Mammalian-Animal
Cell: Germ
not guideline Experiment: In vivo Negative
Subject: Unspecified
Cell: Somatic
Conclusion/Summary Not classified. Based on available data, the classification criteria are not met.
Carcinogenicity
Fuels, diesel Positive - Dermal - Mouse - 2 years
Unspecified
Conclusion/Summary Suspected of causing cancer.

Reproductive toxicity
Product/ingredient name Maternal Fertility Developmental Species Dose Exposure
toxicity toxin
Fuels, diesel - - Negative Rat Dermal 20 days
- - Negative Rat Dermal 10 days
Conclusion/Summary Development: Not classified. Based on available data, the classification criteria are
not met.
Fertility: Not classified. Based on available data, the classification criteria are not
met.
Effects on or via lactation: Not classified. Based on available data, the classification
criteria are not met.
exposure
Fuels, diesel Category 2 Not determined bone marrow, liver
and thymus
Aspiration hazard
Name Result
Fuels, diesel ASPIRATION HAZARD - Category 1
Alkanes, C10-20-branched and linear ASPIRATION HAZARD - Category 1
Information on likely routes Routes of entry anticipated: Oral, Dermal, Inhalation.

of exposure
Inhalation Harmful if inhaled.

pain or irritation
watering
redness
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
irritation
redness
nausea or vomiting

Inhalation Vapour, mists or fumes may contain polycyclic aromatic hydrocarbons some of
which are known to produce skin cancer. Vapour, mist or fume may irritate the nose,
mouth and respiratory tract.
Skin contact As with all such products containing potentially harmful levels of polycyclic aromatic
hydrocarbons, prolonged or repeated skin contact may eventually result in dermatitis
or more serious irreversible skin disorders including cancer.
drowsiness.
General May cause damage to organs through prolonged or repeated exposure. Vapour,
mists or fumes may contain polycyclic aromatic hydrocarbons some of which are
known to produce skin cancer.
Carcinogenicity Suspected of causing cancer. Risk of cancer depends on duration and level of
exposure.
Mutagenicity No known significant effects or critical hazards.
Teratogenicity No known significant effects or critical hazards.
Fertility effects No known significant effects or critical hazards.
Numerical measures of toxicity

Acute toxicity estimates
Route ATE value
Inhalation (dusts and mists) 2.211 mg/l

Toxicity
Product/ingredient name Result Species Exposure
Fuels, diesel EL50 >1000 mg/l Nominal Fresh water Micro-organism 40 hours
NOELR 3.217 mg/l Nominal Fresh Micro-organism 40 hours
water
Acute EL50 22 mg/l Nominal Fresh Algae 72 hours
water
Acute EL50 210 mg/l Nominal Fresh Daphnia 48 hours
water
water
Acute ErL50 78 mg/l Nominal Fresh Algae 72 hours
water
Acute LL50 65 mg/l Nominal Fresh Fish 96 hours
water
water
Acute NOELR 10 mg/l Nominal Fresh Algae 72 hours
water
water
Acute NOELR 46 mg/l Nominal Fresh Daphnia 48 hours
water
Chronic NOEL 0.083 mg/l Nominal Fish 14 days
Fresh water
Chronic NOELR 0.2 mg/l Nominal Daphnia 21 days
Fresh water
Conclusion/Summary Toxic to aquatic life with long lasting effects.

Partially biodegradable.
Product/ingredient name Test Result Dose Inoculum
Fuels, diesel OECD 301 F 60 % - Readily - 28 days 30 mg/l -
OECD 301 F 57.5 % - Not readily - 28 days 25 mg/l -
Equivalent to 35 % - Not readily - 28 days 5 mg/l -
EPA OTS 796.
3100
Conclusion/Summary Non-persistent per IMO criteria
Mobility in soil
coefficient (KOC)
Mobility Spillages may penetrate the soil causing ground water contamination. This material
may accumulate in sediments.

Special Precautions for Empty packages may contain some remaining product. Hazard warning labels are a
Landfill or Incineration guide to the safe handling of empty packaging and should not be removed.

ADG IMDG IATA
UN number Not regulated. UN3082 UN3082
UN proper - ENVIRONMENTALLY ENVIRONMENTALLY

shipping name HAZARDOUS SUBSTANCE, HAZARDOUS SUBSTANCE,
LIQUID, N.O.S. (Fuels, diesel) LIQUID, N.O.S. (Fuels, diesel)

Transport hazard - 9 9
class(es)
Packing group - III III

Environmental No. Yes. Yes.
hazards
Additional Remarks This product is not regulated This product is not regulated
information Combustible liquid Class C1 as a dangerous good when as a dangerous good when
(AS 1940). transported in sizes of ≤5 L or transported in sizes of ≤5 L or
≤5 kg, provided the ≤5 kg, provided the
packagings meet the general packagings meet the general
provisions of 4.1.1.1, 4.1.1.2 provisions of 5.0.2.4.1, 5.0.2.6.
and 4.1.1.4 to 4.1.1.8. 1.1 and 5.0.2.8.
Emergency schedules
(EmS)
F-A, S-F
the IBC Code Category: gas oils, including ship's bunkers

Not scheduled

No listed substance
International lists
National inventory
Australia inventory (AICS) Contact supplier for regulatory information.
Canada inventory At least one component is not listed.
China inventory (IECSC) Not determined.
Philippines inventory Not determined.
(PICCS)
(TCSI)
(TSCA 8b)

History
revision
Date of previous issue 07/04/2016
Version 2
Product Stewardship
UN = United Nations
101316-71-6, 101316-72-7, 64741-88-4, 64741-89-5, 64741-95-3, 64741-96-4,
64741-97-5, 64742-01-4, 64742-44-5, 64742-45-6, 64742-52-5, 64742-53-6,
64742-54-7, 64742-55-8, 64742-56-9, 64742-57-0, 64742-58-1, 64742-62-7,
64742-63-8, 64742-64-9, 64742-65-0, 64742-70-7, 72623-85-9, 72623-86-0,
72623-87-1, 74869-22-0, 90669-74-2
Flam. Liq. 4, H227 On basis of test data
Acute Tox. 4, H332 Calculation method
Skin Irrit. 2, H315 Calculation method
Carc. 2, H351 Calculation method
STOT RE 2, H373 (bone marrow, liver and thymus) Calculation method
Asp. Tox. 1, H304 Calculation method
Notice to reader

SAFETY DATA SHEET
Premium Unleaded 95
GHS product identifier Premium Unleaded 95
SDS no. 0000002734
Historic SDS no. 876
Use of the substance/ Fuel for spark ignition engines. NOT for aviation use.
mixture For specific application advice see appropriate Technical Data Sheet or consult our
Manufacturer
ABN 53 004 085 616
www.bp.com.au

NUMBER

TOXIC TO REPRODUCTION (Fertility) - Category 2
Category 3
Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 1%
GHS label elements

Hazard pictograms
Signal word DANGER

H361 - Suspected of damaging fertility or the unborn child.
Product name Premium Unleaded 95 Product code 0000002734 Page: 1/15

clothing
breathing.
P235 - Keep cool.
elements

Gasoline > 99 86290-81-5
Contains:
toluene < 20 108-88-3
n-hexane <5 110-54-3
Benzene <1 71-43-2





Extinguishing media
media spray.
media
Specific hazards arising Extremely flammable liquid and vapour. In a fire or if heated, a pressure increase
from the chemical will occur and the container may burst, with the risk of a subsequent explosion.
Runoff to sewer may create fire or explosion hazard. Liquid will float and may
reignite on surface of water.
carbon monoxide
Hazchem code 3YE

pollution (sewers, waterways, soil or air). In case of small spillages in closed waters
(i.e. ports), contain product with floating barriers or other equipment. Collect spilled
product by absorbing with specific floating absorbents. If possible, large spillages in
open waters should be contained with floating barriers or other mechanical means.
If this is not possible, control the spreading of the spillage, and collect the product by
skimming or other suitable mechanical means. The use of dispersants should be
advised by an expert, and, if required, approved by local authorities. Collect
recovered product and other contaminated materials in suitable tanks or containers
for recycle, recovery or safe disposal.

atmospheres.

with container.
precautionary measures against electrostatic discharges. Empty containers retain

should not be used unless it is intrinsically safe (i.e. will not produce sparks).

Control parameters
5/1996
5/1996
Revised: 5/1996
Revised: 5/1996
toluene Safe Work Australia (Australia). Absorbed
through skin.

Revised: 8/2005
Revised: 8/2005
8/2005
8/2005
n-hexane Safe Work Australia (Australia).
11/2001
11/2001
4/2003
4/2003
Revised: 4/2002
4/2002
4/2002
4/2002
Revised: 5/1995
Revised: 5/1995
5/1995
5/1995
Revised: 5/1995
Revised: 5/1995
5/1995
5/1995
maintained.


Skin protection
Do not re-use gloves. Protective gloves must give suitable protection against
mechanical risks (i.e. abrasion, blade cut and puncture). Protective gloves will
deteriorate over time due to physical and chemical damage. Inspect and replace
gloves on a regular basis. The frequency of replacement will depend upon the
circumstances of use.
gloves.
clothes.
required.


Appearance
Colour Pale Yellow.
Odour Hydrocarbon.
pH Not available.
Boiling point >30 to < 210°C (>86 to < 410°F)
Vapour pressure 30 to 100 kPa (225 to 750 mm Hg)
octanol/water

occur.

exposure
toluene Category 3 Not applicable. Narcotic effects
n-hexane Category 3 Not applicable. Narcotic effects
irritation and
Narcotic effects
exposure
toluene Category 2 Not determined hearing organs
n-hexane Category 2 Inhalation peripheral nervous
system
Aspiration hazard
Name Result
toluene ASPIRATION HAZARD - Category 1
n-hexane ASPIRATION HAZARD - Category 1

of exposure
dizziness.

pain or irritation
watering
redness

nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
irritation
redness
nausea or vomiting
or dermatitis.
drowsiness.
General This product contains n-hexane. Overexposure to n-hexane may cause progressive
and potentially irreversible damage to the peripheral nervous system, particularly in
the arms and legs. Animal studies have also shown that n-hexane overexposure
may cause testicular injury. However, animal studies conducted with commercial
hexane, containing 53% n-hexane, showed neither peripheral nervous system
damage nor testicular injury at inhalation exposures up to 9000 ppm. Solvent
"sniffing" (abuse) or intentional overexposure to vapours can produce serious
Fertility effects Suspected of damaging fertility.
diarrhea.


phenobarbital).
is questionable.



material.




humans.

Mobility in soil
coefficient (KOC)


ADG IMDG IATA

MARINE POLLUTANT
class(es)

hazards
14 (EmS)
F-E; S-E

Not scheduled When packed in containers having capacity of greater than 20 litres.

No listed substance
International lists
National inventory
(PICCS)
(TCSI)
(TSCA 8b)

History
revision
Date of previous issue No previous validation
Version 1
Product Stewardship
UN = United Nations
101316-71-6, 101316-72-7, 64741-88-4, 64741-89-5, 64741-95-3, 64741-96-4,
64741-97-5, 64742-01-4, 64742-44-5, 64742-45-6, 64742-52-5, 64742-53-6,
64742-54-7, 64742-55-8, 64742-56-9, 64742-57-0, 64742-58-1, 64742-62-7,
64742-63-8, 64742-64-9, 64742-65-0, 64742-70-7, 72623-85-9, 72623-86-0,
72623-87-1, 74869-22-0, 90669-74-2
Repr. 2, H361 (Fertility) Expert judgment
Notice to reader

SAFETY DATA SHEET
Unleaded 91
GHS product identifier Unleaded 91
Other means of regular unleaded petrol
identification
SDS no. 0000002733
Historic SDS no. 875; 0000002889
Use of the substance/ Use only as a motor fuel for spark ignition engines. NOT for aviation use. Should
mixture NOT be used as a solvent nor cleaning agent.
For specific application advice see appropriate Technical Data Sheet or consult our
Manufacturer
ABN 53 004 085 616
www.bp.com.au

NUMBER

Category 3
GHS label elements

Hazard pictograms
Signal word DANGER

H361 - Suspected of damaging the unborn child.
Product name Unleaded 91 Product code 0000002733 Page: 1/18

clothing
breathing.
P235 - Keep cool.
elements

A complex mixture of volatile hydrocarbons containing paraffins, naphthenes, olefins and aromatics with carbon
numbers predominantly between C4 and C12. May contain oxygenates. May also contain small quantities of
proprietary performance additives.
Gasoline >90 86290-81-5
Contains:
Benzene <1 71-43-2





Extinguishing media
media spray.
media
Specific hazards arising Extremely flammable liquid and vapour. Fire water contaminated with this material
from the chemical must be contained and prevented from being discharged to any waterway, sewer or
drain. In a fire or if heated, a pressure increase will occur and the container may
burst, with the risk of a subsequent explosion. Runoff to sewer may create fire or
explosion hazard. Liquid will float and may reignite on surface of water.
carbon monoxide
Hazchem code 3YE

to the environment if released in large quantities. In case of small spillages in
closed waters (i.e. ports), contain product with floating barriers or other equipment.
Collect spilled product by absorbing with specific floating absorbents. If possible,
large spillages in open waters should be contained with floating barriers or other
mechanical means. If this is not possible, control the spreading of the spillage, and
collect the product by skimming or other suitable mechanical means. The use of
dispersants should be advised by an expert, and, if required, approved by local
authorities. Collect recovered product and other contaminated materials in suitable
tanks or containers for recycle, recovery or safe disposal.

container. Use explosion-protected equipment. Dispose of via a licensed waste
disposal contractor. The method and equipment used must be in conformance with
appropriate regulations and industry practice on explosive atmospheres.
and place in container for disposal according to local regulations. Use explosion-
protected equipment. Contaminated absorbent material may pose the same hazard
as the spilt product. The method and equipment used must be in conformance with
appropriate regulations and industry practice on explosive atmospheres. Dispose of
via a licensed waste disposal contractor.

with container.
precautionary measures against electrostatic discharges. Avoid contact of spilt
material and runoff with soil and surface waterways. Empty containers retain

should not be used unless it is explosion-protected (i.e. will not produce sparks).

Control parameters
5/1996
5/1996
Revised: 5/1996
Revised: 5/1996

4/2003
4/2003
Revised: 5/1995
Revised: 5/1995
5/1995
5/1995
Revised: 5/1995
Revised: 5/1995
5/1995
5/1995
Revised: 4/2002
4/2002
4/2002
4/2002
maintained.

Skin protection

gloves.
clothes.
required.


Appearance
Colour Pale Yellow. to Pale Red.
Odour Hydrocarbon.
pH Not available.
Boiling point >30 to 210°C (>86 to 410°F)
Vapour pressure 30.1 to 100.3 kPa (225.6 to 752 mm Hg)
Density 710 to 750 kg/m³ (0.71 to 0.75 g/cm³)
octanol/water

occur.

Acute toxicity
Gasoline LC50 Inhalation Vapour Rat >7630 mg/m³ 4 hours
Nominal
LC50 Inhalation Vapour Rat >5610 mg/m³ 4 hours
analytical
LD50 Oral Rat >5000 mg/kg -
diisopropyl ether LC50 Inhalation Vapour Rat 40.5 mg/m³ 1 hours
LD50 Dermal Rabbit 2000 mg/kg -
2-methylpropan-2-ol LD50 Oral Rabbit 3559 mg/kg -
tert-butyl methyl ether LC50 Inhalation Vapour Rat 85 mg/l 4 hours
(MTBE)
LD50 Dermal Rat >2000 mg/kg -
LD50 Oral Rat >2000 mg/kg -
Gasoline Skin - Irritant Rabbit - - -
eyes.
tert-butyl methyl ether Skin - Irritation Rabbit - - -
(MTBE)
eyes.
Mutagenicity
Gasoline Equivalent to OECD Experiment: In vitro Negative
476
Subject: Mammal - species
unspecified
471
EPA OPPTS 870.5395 Experiment: In vivo Negative
Cell: Germ
Equivalent to OECD Experiment: In vivo Negative
475
Cell: Germ
tert-butyl methyl ether EU B 13/14 Experiment: In vitro Negative
(MTBE)
OECD 471 Experiment: In vitro Negative
OECD 476 Experiment: In vitro Negative
473
Equivalent to OECD Experiment: In vivo Negative
486
Cell: Somatic
Equivalent to EPA Experiment: In vivo Negative
OPPTS 870.5385
Cell: Somatic
Equivalent to EPA Experiment: In vivo Negative
OPPTS 798.5385
Cell: Somatic
Conclusion/Summary May cause genetic defects.
Carcinogenicity
Gasoline Negative - Inhalation - Rat - 113 weeks
Unspecified
Negative - Dermal - Mouse - 102 weeks
Unspecified
tert-butyl methyl ether Positive - Inhalation - Rat - 2 years
(MTBE) Unspecified
Conclusion/Summary May cause cancer
toxicity toxin
Gasoline - Negative - Rat Inhalation 2
generation
- - Negative Rat Inhalation 14 days
tert-butyl methyl ether - Negative - Rat Inhalation 2
(MTBE) generation
- - Negative Rat Inhalation 9 days
exposure
irritation and
Narcotic effects
exposure
Aspiration hazard
Name Result

of exposure
dizziness.


pain or irritation
watering
redness
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
irritation
redness
nausea or vomiting
or dermatitis.
drowsiness.
General Solvent "sniffing" (abuse) or intentional overexposure to vapours can produce
serious central nervous system effects, including unconsciousness, and possibly
death.
diarrhea.

phenobarbital).
is questionable.



material.




humans.

Toxicity
Gasoline Acute EC50 15.41 mg/l Nominal Fresh Micro-organism 40 hours
water
Acute EL50 3.1 mg/l Nominal Fresh Algae 72 hours
water
Acute EL50 3.7 mg/l Nominal Fresh Algae 96 hours
water
Acute EL50 4.5 mg/l Nominal Fresh Daphnia 48 hours
water
water
Acute LL50 8.2 mg/l Nominal Fresh Fish 96 hours
water
Acute NOELR 0.5 mg/l Nominal Fresh Algae 72 hours
water
Acute NOELR 0.5 mg/l Nominal Fresh Daphnia 48 hours
water
Chronic EL50 10 mg/l Nominal Fresh Daphnia 21 days
water
Chronic EL50 >40 mg/l Nominal Fresh Daphnia 21 days
water
Chronic EL50 10 mg/l Nominal Fresh Fish 21 days
water
Chronic LL50 5.2 mg/l Nominal Fresh Fish 14 days
water
Fresh water
Chronic NOELR 16 mg/l Nominal Daphnia 21 days
Fresh water
Chronic NOELR 2.6 mg/l Nominal Fish 14 days
Fresh water
Chronic NOELR 2.6 mg/l Nominal Fish 21 days
Fresh water
Chronic PNEC >0.4 mg/kg soil, plants -
tert-butyl methyl ether(MTBE) Acute EC50 472 mg/l Fresh water Daphnia 48 hours
Acute LC50 200 mg/l Marine water Crustaceans 96 hours
Acute LC50 672 mg/l Fresh water Fish 96 hours
Acute LC50 574 mg/l Marine water Fish 96 hours
Chronic NOEC 26 mg/l Marine water Crustaceans 28 days
Chronic NOEC 51 mg/l Fresh water Daphnia 21 days


tert-butyl methyl ether(MTBE) not guideline 100 % - 1.25 days - -
Modelled data 61 to 69 % - 151 days - -
OECD 301 D 9.24 % - Not readily - 28 days - -
OECD 301 D 1.8 % - Not readily - 28 days - -
OECD 301 D 0 % - Not readily - 28 days - -
Modelled data 0 % - 250 days - -
Product/ingredient name LogPow BCF Potential
Gasoline 2 to 7 - high
Benzene 2.13 11 low
diisopropyl ether 2.4 - low
2-methylpropan-2-ol 0.317 - low
tert-butyl methyl ether(MTBE) 1.04 - low
Mobility in soil
coefficient (KOC)


ADG IMDG IATA

MARINE POLLUTANT
class(es)
hazards
14 (EmS)
F-E,S-E

Not scheduled. When packed in containers having capacity of greater than 20 litres.

No listed substance -
International lists
National inventory

(PICCS)
(TCSI)
(TSCA 8b)

History
revision
Version 3
Product Stewardship
UN = United Nations
101316-71-6, 101316-72-7, 64741-88-4, 64741-89-5, 64741-95-3, 64741-96-4,
64741-97-5, 64742-01-4, 64742-44-5, 64742-45-6, 64742-52-5, 64742-53-6,
64742-54-7, 64742-55-8, 64742-56-9, 64742-57-0, 64742-58-1, 64742-62-7,
64742-63-8, 64742-64-9, 64742-65-0, 64742-70-7, 72623-85-9, 72623-86-0,
72623-87-1, 74869-22-0, 90669-74-2
Notice to reader


Material Safety Data Sheet
1 . Identification of the material and supplier

Product name BP Unleaded 91 with up to 10% Ethanol
SDS no. 0000002889
Product use Use only as a motor fuel for spark ignition engines. NOT for aviation use. Should NOT be used as a
solvent nor cleaning agent.
Synonyms E10, E10M
Supplier BP Australia Pty Ltd (ABN 53 004 085 616)
717 Bourke Street
Docklands VIC 3008
Australia
Tel: +61 (03) 9268 4111
Fax: +61 (03) 9268 3321
NUMBER
2 . Hazards identification
Statement of hazardous/ HAZARDOUS SUBSTANCE. DANGEROUS GOODS.
dangerous nature
Risk phrases R12- Extremely flammable.
R45- May cause cancer.
R46- May cause heritable genetic damage.
R63- Possible risk of harm to the unborn child.
R65- Also harmful: may cause lung damage if swallowed.
R38- Irritating to skin.
R67- Vapours may cause drowsiness and dizziness.
R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety phrases S2- Keep out of the reach of children.
S16- Keep away from sources of ignition - No smoking.
S23- Do not breathe gas/fumes/vapour/spray.
S24- Avoid contact with skin.
S29- Do not empty into drains.
S36/37- Wear suitable protective clothing and gloves.
S45- In case of accident or if you feel unwell, seek medical advice immediately (show the label where
possible).
S61- Avoid release to the environment. Refer to special instructions/safety data sheet.
S62- If swallowed, do not induce vomiting: seek medical advice immediately and show this container
or label.
3 . Composition/information on ingredients
A complex mixture of volatile hydrocarbons containing paraffins, naphthenes, olefins and aromatics with carbon numbers predominantly
between C4 and C12. May contain oxygenates. May also contain small quantities of proprietary performance additives.
Ingredient name CAS no. %
Gasoline 86290-81-5 > 90
Ethanol 64-17-5 < 10
Contains:
Toluene 108-88-3 5 - 15
Benzene 71-43-2 <1
tert-butyl alcohol 75-65-0 <1
tert-butyl methyl ether 1634-04-4 <1
diisopropyl ether 108-20-3 <1
Polycyclic aromatic hydrocarbons (PAHs) mixture <1
Product name BP Unleaded 91 with up to 10% Ethanol Product code 0000002889 Page: 1/7
Version 3 Date of issue 5 October 2012 Format Australia Language ENGLISH
4 . First-aid measures
Eye contact In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical
attention if irritation occurs.
Skin contact In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing
contaminated clothing and shoes. Wash clothing before reuse. Clean shoes thoroughly before reuse.
Get medical attention immediately.
Inhalation If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen. Get medical attention.
Ingestion If swallowed, do not induce vomiting. Never give anything by mouth to an unconscious person.
Aspiration hazard if swallowed. Can enter lungs and cause damage. Get medical attention.
Advice to doctor Treatment should in general be symptomatic and directed to relieving any effects.
Product can be aspirated on swallowing or following regurgitation of stomach contents, and can
cause severe and potentially fatal chemical pneumonitis, which will require urgent treatment.
Because of the risk of aspiration, induction of vomiting and gastric lavage should be avoided. Gastric
lavage should be undertaken only after endotracheal intubation. Monitor for cardiac dysrhythmias.
5 . Fire-fighting measures
Extinguishing media
Suitable In case of fire, use water fog, foam, dry chemical or carbon dioxide extinguisher or spray.
Not suitable Do not use water jet.
Hazardous decomposition Decomposition products may include the following materials:
products carbon dioxide
carbon monoxide
Unusual fire/explosion Extremely flammable liquid and vapour. Vapour may cause flash fire. Vapours may accumulate in
hazards low or confined areas or travel a considerable distance to a source of ignition and flash back. Runoff
to sewer may create fire or explosion hazard.
Special fire-fighting DO NOT FIGHT FIRE WHEN IT REACHES MATERIAL. Withdraw from fire and let it burn. Promptly
procedures isolate the scene by removing all persons from the vicinity of the incident if there is a fire. First move
people out of line-of-sight of the scene and away from windows.
Protection of fire-fighters Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus
(SCBA) with a full face-piece operated in positive pressure mode.
Hazchem code 3YE
6 . Accidental release measures

Personal precautions No action shall be taken involving any personal risk or without suitable training. Evacuate
surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or
walk through spilt material. Shut off all ignition sources. No flares, smoking or flames in hazard area.
Do not breathe vapour or mist. Provide adequate ventilation. Wear appropriate respirator when
ventilation is inadequate. Put on appropriate personal protective equipment (see Section 8).
Environmental precautions Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers.
Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways,
soil or air). Water polluting material. May be harmful to the environment if released in large
quantities.
Large spill Stop leak if without risk. Eliminate all ignition sources. Move containers from spill area. Approach the
release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash
spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-
combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations. Use spark-proof tools and explosion-proof
equipment. Dispose of via a licensed waste disposal contractor. Contaminated absorbent material
may pose the same hazard as the spilt product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.
Small spill Stop leak if without risk. Eliminate all ignition sources. Move containers from spill area. Absorb with
an inert material and place in an appropriate waste disposal container. Use spark-proof tools and
explosion-proof equipment. Dispose of via a licensed waste disposal contractor.
7 . Handling and storage

Handling Aspiration hazard if swallowed. Can enter lungs and cause damage. Do not ingest. If ingested, do
not induce vomiting. Avoid contact with skin and clothing. Use only with adequate ventilation. Do not
breathe vapour or mist. Keep away from heat, sparks and flame. To avoid fire or explosion, dissipate
static electricity during transfer by earthing and bonding containers and equipment before transferring
material. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Avoid
contact of spilt material and runoff with soil and surface waterways. Wash thoroughly after handling.
Storage Store in a segregated and approved area. Keep container in a cool, well-ventilated area. Keep
container tightly closed and sealed until ready for use. Avoid all possible sources of ignition (spark or
flame). Store and use only in equipment/containers designed for use with this product. Do not remove
warning labels from containers.
Do not enter storage tanks without breathing apparatus unless the tank has been well ventilated and
the tank atmosphere has been shown to contain hydrocarbon vapour concentrations of less than 1%
of the lower flammability limit and an oxygen concentration of at least 20% volume.
Light hydrocarbon vapours can build up in the headspace of tanks. These can cause flammability/
explosion hazards even at temperatures below the normal flash point (note: flash point must not be
regarded as a reliable indicator of the potential flammability of vapour in tank headspaces). Tank
headspaces should always be regarded as potentially flammable and care should be taken to avoid
static electrical discharge and all ignition sources during filling, ullaging and sampling from storage
tanks.
When the product is pumped (e.g. during filling, discharge or ullaging) and when sampling, there is a
risk of static discharge. Ensure equipment used is properly earthed or bonded to the tank structure.
If product comes into contact with hot surfaces, or leaks occur from pressurised fuel pipes, the vapour
or mists generated will create a flammability or explosion hazard.
Product contaminated rags, paper or material used to absorb spillages, represent a fire hazard, and
should not be allowed to accumulate. Dispose of safely immediately after use.
Additional information- This product must be handled in compliance with Australian Standard: The storage and handling of
Storage flammable and combustible liquids [Standard 1940-2004 as amended and adapted].
8 . Exposure controls/personal protection

Ingredient name Occupational exposure limits
Ethanol Safe Work Australia (Australia).
TWA: 1880 mg/m³ 8 hour(s). Issued/Revised: 5/1995
TWA: 1000 ppm 8 hour(s). Issued/Revised: 5/1995
TWA: 3.2 mg/m³ 8 hour(s). Issued/Revised: 4/2003
Toluene Safe Work Australia (Australia). Absorbed through skin.
STEL: 574 mg/m³ 15 minute(s). Issued/Revised: 8/2005
STEL: 150 ppm 15 minute(s). Issued/Revised: 8/2005
tert-butyl alcohol Safe Work Australia (Australia).
tert-butyl methyl ether Safe Work Australia (Australia).
TWA: 0.2 mg/m³ 8 hour(s).
For information and guidance, the ACGIH values are included. For further information on these please consult your supplier.
Whilst specific OELs for certain components are included in this SDS, it should be noted that other components of the preparation will be
present in any mist, vapour or dust produced. For this reason, the specific OELs may not be applicable to the product and are provided
for guidance purposes.
Biological Limit Values Benzene :S-Phenylmercapturic acid in urine - End of shift: 25 µg/g creatinine (ACGIH)
t,t-Muconic acid in urine - End of shift: 500 µg/g creatinine (ACGIH)
Polycyclic aromatic hydrocarbons (PAHs): 1-Hydroxypyrene (1-HP) in urine (with hydrolysis) - End of
shift at end of workweek: Nonquantitative (ACGIH)
ACGIH “Nonquantitative” Biological Exposure Indices (BEI®): Biological monitoring should be
considered for this compound based on the review; however, a specific BEI® could not be determined
due to insufficient data.
Exposure controls
Occupational exposure Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of
controls vapours below their respective occupational exposure limits.
Ensure that eyewash stations and safety showers are close to the workstation location.
All chemicals should be assessed for their risks to health and appropriate control measures put in
place to prevent or adequately control exposure. A hierarchy of control measures exists (e.g.
elimination, substitution, general ventilation, containment, systems of work, changing the process or
activity) that must be considered before use of personal protective equipment. Personal protective
equipment should conform to appropriate standards, be suitable for use, be kept in good condition
and properly maintained.
The final choice of protective equipment will depend upon a risk assessment. It is important to ensure
that all items of personal protective equipment are compatible. The above information is provided to
assist the customer in conducting its own assessment of risk to the health and safety of workers for
the substance or preparation, and protection of the environment.
Hygiene measures Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking
and using the lavatory and at the end of the working period.
Personal protective equipment
Respiratory protection Use only with adequate ventilation. Avoid breathing of vapours, mists or spray. Select and use
respirators in accordance with AS/NZS 1715/1716. When mists or vapours exceed the exposure
standards then the use of the following is recommended: Approved respirator with organic vapour
and dust/mist filters. Filter capacity and respirator type depends on exposure level.
Skin and body Do not get on skin or clothing. Wear clothing and footwear that cannot be penetrated by chemicals or
oil. Wear face shield.
Hand protection Wear gloves that cannot be penetrated by chemicals or oil.
The correct choice of protective gloves depends upon the chemicals being handled, the conditions of
work and use, and the condition of the gloves (even the best chemically resistant glove will break
down after repeated chemical exposures). Most gloves provide only a short time of protection before
they must be discarded and replaced. Because specific work environments and material handling
practices vary, safety procedures should be developed for each intended application. Gloves should
therefore be chosen in consultation with the supplier/manufacturer and with a full assessment of the
working conditions.
Eye protection Safety glasses with side shields.
9 . Physical and chemical properties

Colour Purple. or Red.
Odour Gasoline [Strong]
Flash point <-40 °C (Closed cup) Pensky-Martens.
Vapour pressure Not available.
pH Not available.
Boiling point / range 30 to 210°C (86 to 410°F)
Melting point / range Not available.
Relative density/Specific Not available.
gravity
10 . Stability and reactivity

Stability The product is stable.
Incompatibility with various Reactive or incompatible with the following materials: oxidising materials.
substances/Hazardous
Reactions
Hazardous decomposition Decomposition products may include the following materials:
products carbon dioxide
carbon monoxide
11 . Toxicological information
Effects and symptoms
Eyes Unlikely to cause more than transient stinging or redness if accidental eye contact occurs.
Skin Likely to result in chemical burns following prolonged wetting of the skin. (eg. after a road traffic
accident).
Inhalation Likely to be irritating to the respiratory tract if high concentrations of mists or vapour are inhaled. May
cause nausea, dizziness, headaches and drowsiness if high concentrations of vapour are inhaled.
Ingestion Aspiration hazard if swallowed -- harmful or fatal if liquid is aspirated into lungs.
Chronic toxicity
Carcinogenic effects Gasoline as a mixture is classified as a 2B (possible human) carcinogen by IARC.
Gasoline engine exhaust is classified as possibly carcinogenic to humans by IARC (2B). This
classification is based primarily on animal and in vitro studies of gasoline engine exhaust
condensates/extracts. Studies of the gaseous exhaust stream in animals did not provided sufficient
evidence for classification as a carcinogen.
Exposure to benzene may result in effects to the hematopoietic system causing blood disorders
including anaemia and leukaemia.
Benzene is classified by EEC as a category 1 carcinogen - substances known to be carcinogenic to
man.
IARC assessment: benzene - carcinogenic to humans (Group 1)
Mutagenic effects Contains material which may cause heritable genetic effects. (Benzene)
Other information Contains material which may cause birth defects based on animal data. (Toluene)
Excess exposure to vapors may produce headaches, dizziness, nausea, drowsiness, irritation of eyes,
nose and throat and central nervous system depression. Aspiration of this material into the lungs can
cause chemical pneumonia and can be fatal. Aspiration into the lungs can occur while vomiting after
ingestion of this product. Inhalation of unleaded gasoline vapors did not produce birth defects in
laboratory animals. Ingestion of this material can cause gastrointestinal irritation and diarrhea.
In a long-term inhalation study of whole unleaded gasoline vapors, exposure-related kidney damage
and kidney tumors were observed in male rats. Similar kidney effects were not seen in female rats or
in mice. At the highest exposure level (2056 ppm), female mice had an increased incidence of liver
tumors. Results from subsequent scientific studies have shown that a broad variety of chemicals
cause these kidney effects only in the male rat. Further studies have discovered the means by which
the physiology of the male rat uniquely predispose it to these effects. Consequently, the Risk
Assessment Forum of the Environmental Protection Agency has recognized that these responses are
not predictive of a human health hazard. The liver tumors that were increased in the high-dose female
mice are likewise of questionable significance because of their high spontaneous occurrence even
without chemical exposure and because the rate of their occurrence is accelerated by a broad
spectrum of chemicals not commonly considered to be carcinogens (e.g., phenobarbital).
Thus, the significance of the mouse liver tumor response in terms of human health is questionable.
Gasoline is a complex mixture of hydrocarbons and contains benzene (typically no more than 2
volume%), toluene, and xylene. Chronic exposure to high levels of benzene has been shown to cause
cancer (leukemia) in humans and other adverse blood effects (anemia). Benzene is considered a
human carcinogen by IARC, NTP and OSHA. Over exposure to xylene and toluene can cause
irritation to the upper respiratory tract, headache and narcosis. Some liver damage and lung
inflammation were seen in chronic studies on xylene in guinea pigs but not in rats.
Solvent "sniffing" (abuse) or intentional overexposure to vapors can produce serious central nervous
system effects, including unconsciousness, and possibly death.
Gasoline: Additional toxicity information on components.
Overexposure to n-hexane may cause progressive and potentially irreversible damage to the
peripheral nervous system, particularly in the arms and legs.
Studies in occupationally exposed individuals indicate that toluene exposure has been associated
with impaired color vision and decreased performance in some neurobehavioral tests.
Prolonged high level exposure to toluene or xylene has caused some degree of hearing loss in
experimental animals.
Inhalation of very high concentrations of gasoline vapors and some of its components can result in
cardiac sensitization and irregular heartbeats, leading to potentially fatal changes in heart rhythms.
Injection of adrenaline-like agents may enhance this effect.
12 . Ecological information
Ecotoxicity Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Biodegradability
Persistence/degradability The biodegradability of this material has not been determined.
Bioaccumulative potential This product is not expected to bioaccumulate through food chains in the environment.
Other ecological information Spills may form a film on water surfaces causing physical damage to organisms. Oxygen transfer
could also be impaired.
13 . Disposal considerations
Disposal considerations / The generation of waste should be avoided or minimised wherever possible. Empty containers or
Waste information liners may retain some product residues. This material and its container must be disposed of in a
safe way. Significant quantities of waste product residues should not be disposed of via the foul
sewer but processed in a suitable effluent treatment plant. Dispose of surplus and non-recyclable
products via a licensed waste disposal contractor. Disposal of this product, solutions and any by-
products should at all times comply with the requirements of environmental protection and waste
disposal legislation and any regional local authority requirements. Avoid dispersal of spilt material
and runoff and contact with soil, waterways, drains and sewers.
14 . Transport information
International transport regulations
Regulatory UN number Proper shipping name Class PG* Label Additional information
information
ADG UN 1203 PETROL 3 II Hazchem code
Classification 3YE
Initial emergency
response guide
14
IMDG UN 1203 Gasoline or Motor Spirit. 3 II Emergency schedules

Classification Marine pollutant (EmS)
F-E, S-E
IATA/ICAO UN 1203 Gasoline or Motor Spirit 3 II -

Classification
PG* : Packing group

Special precautions for user No known special precautions required. See Section: "Handling and storage" for additional
information.
15 . Regulatory information
Standard for the Uniform Scheduling of Medicines and Poisons
5
Control of Scheduled Carcinogenic Substances

Benzene Schedule: 2. when used as a
feedstock containing more than
50% of benzene by volume
Other regulations
REACH Status For the REACH status of this product please consult your company contact, as identified in Section 1.
United States inventory At least one component is not listed.
(TSCA 8b)
Canada inventory Not determined.
Japan inventory (ENCS) Not determined.
Korea inventory (KECI) Not determined.
(PICCS)
16 . Other information
Key to abbreviations AMP = Acceptable Maximum Peak
ACGIH = American Conference of Governmental Industrial Hygienists, an agency that promulgates
exposure standards.
ADG = Australian Code for the Transport of Dangerous Goods by Road and Rail
ADG Code = Australian Code for the Transport of Dangerous Goods by Road and Rail
CAS Number = Chemical Abstracts Service Registry Number
HAZCHEM Code = Emergency action code of numbers and letters which gives information to
emergency services. Its use is required by the ADG Code for Dangerous Goods in bulk.
ICAO = International Civil Aviation Organization.
IATA = International Air Transport Association, the organization promulgating rules governing
shipment of goods by air.
IMDG = International Maritime Organization Rules, rules governing shipment of goods by water.
IP 346 = A chemical screening assay for dermal toxicity. The European Commission has
recommended that Method IP 346 be used as the basis for labelling certain lubricant oil base stocks
for carcinogenicity. The EU Commission has stipulated that the classification as a carcinogen need
not apply if it can be shown that the substance contains less than 3% DMSO extract as measured by
IP 346. (See Note L, European Commission Directive 67/548/EEC as amended and adapted.)
DMSO is a solvent.
NOHSC = National Occupational Health & Safety Commission, Australia
UN Number = United Nations Number, a four digit number assigned by the United Nations Committee
of Experts on the Transport of Dangerous Goods.
History
Date of issue 05/10/2012.
Date of previous issue 10/02/2011.
Notice to reader
All reasonably practicable steps have been taken to ensure this data sheet and the health, safety and environmental information
contained in it is accurate as of the date specified below. No warranty or representation, express or implied is made as to the accuracy
or completeness of the data and information in this data sheet.
The data and advice given apply when the product is sold for the stated application or applications. You should not use the product other
than for the stated application or applications without seeking advice from us.
It is the user’s obligation to evaluate and use this product safely and to comply with all applicable laws and regulations. The BP Group
shall not be responsible for any damage or injury resulting from use, other than the stated product use of the material, from any failure to
adhere to recommendations, or from any hazards inherent in the nature of the material. Purchasers of the product for supply to a third
party for use at work, have a duty to take all necessary steps to ensure that any person handling or using the product is provided with the
information in this sheet. Employers have a duty to tell employees and others who may be affected of any hazards described in this sheet
and of any precautions that should be taken.
SAFETY DATA SHEET
Automotive Diesel Fuel
GHS product identifier Automotive Diesel Fuel
Other means of G10, BP 10 ppm diesel fuel,Ultra Low Sulphur diesel Fuel, Automotive Diesel Fuel
identification AD 20 , AD40, ALPINE DIESEL, Biodiesel B5
SDS no. 0000002718
Historic SDS no. AD0K1
Use of the substance/ Fuel for compression ignition diesel engines.
mixture
Manufacturer
ABN 53 004 085 616
www.bp.com.au

NUMBER

substance or mixture ACUTE TOXICITY (inhalation) - Category 4
SKIN CORROSION/IRRITATION - Category 2
CARCINOGENICITY - Category 2
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (bone marrow,
liver and thymus) - Category 2
GHS label elements

Hazard pictograms
Signal word DANGER

Hazard statements H227 - Combustible liquid.
H332 - Harmful if inhaled.
H351 - Suspected of causing cancer.
H373 - May cause damage to organs through prolonged or repeated exposure.
(bone marrow, liver, thymus)
Product name Automotive Diesel Fuel Product code 0000002718 Page: 1/13
P260 - Do not breathe vapour.
clothing.
P241 - Use explosion-proof electrical, ventilating, lighting and all material-handling
equipment.
P273 -Avoid release to the environment.
Response P314 - Get medical attention if you feel unwell.
P308 + P313 - IF exposed or concerned: Get medical attention.
P304 + P340 + P312 - IF INHALED: Remove victim to fresh air and keep at rest in a
position comfortable for breathing. Call a POISON CENTER or physician if you feel
unwell.
physician. Do NOT induce vomiting.
P302 + P352 + P362-2 + P363 - IF ON SKIN: Wash with plenty of soap and water.
Take off contaminated clothing. Wash contaminated clothing before reuse.
P332 + P313 - If skin irritation occurs: Get medical attention.
Storage P405 - Store locked up.
P403 - Store in a well-ventilated place.
P235 - Keep cool.
elements
Other hazards which do not This material may contain significant quantities of polycyclic aromatic hydrocarbons,
result in classification some of which have been shown by experimental studies to induce skin cancer.
constitute a major medical emergency.
See 'Notes to physician' under First-Aid Measures, Section 4 of this Safety Data
Sheet.

May contain Fatty Acid Methyl Esters (FAME). May also contain small quantities of proprietary performance additives.
Contains small quantities of polycyclic aromatic hydrocarbons (PAHs).
Fuels, diesel > 95 68334-30-5
Alkanes, C10-20-branched and linear 0 - 20 928771-01-1

Inhalation If inhaled, remove to fresh air. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.
Get medical attention.


constitute a major medical emergency. Injuries may not appear serious at first but
within a few hours tissue becomes swollen, discoloured and extremely painful with
extensive subcutaneous necrosis.
Surgical exploration should be undertaken without delay. Thorough and extensive
debridement of the wound and underlying tissue is necessary to minimise tissue
loss and prevent or limit permanent damage. Note that high pressure may force the
product considerable distances along tissue planes.
providing aid to give mouth-to-mouth resuscitation.

Extinguishing media
media spray.
media
Specific hazards arising Combustible liquid. Fire water contaminated with this material must be contained
from the chemical and prevented from being discharged to any waterway, sewer or drain. In a fire or if
heated, a pressure increase will occur and the container may burst, with the risk of a
subsequent explosion. Runoff to sewer may create fire or explosion hazard.
carbon monoxide
Hazchem code 3z

to the environment if released in large quantities.

atmospheres.

Protective measures Put on appropriate personal protective equipment (see Section 8). Do not get in
eyes or on skin or clothing. Use only with adequate ventilation. Wear appropriate
respirator when ventilation is inadequate. Avoid contact of spilt material and runoff
with soil and surface waterways. Empty containers retain product residue and can
be hazardous. Keep in the original container or an approved alternative made from
a compatible material, kept tightly closed when not in use. Do not reuse container.
Store and use away from heat, sparks, open flame or any other ignition source. Use
explosion-proof electrical (ventilating, lighting and material handling) equipment.
Use only non-sparking tools. Do not breathe vapour or mist. Avoid exposure -
have been read and understood. Do not swallow. Aspiration hazard if swallowed.
Can enter lungs and cause damage. Never siphon by mouth.
As a precaution, tank headspaces should always be regarded as potentially

flammable and care should be taken to avoid static electrical discharge and all
ignition sources during filling, ullaging and sampling from storage tanks. Do not
enter storage tanks. If entry to vessels is necessary, follow permit to work
procedures. When the product is pumped (e.g. during filling, discharge or ullaging)
and when sampling, there is a risk of static discharge. Ensure equipment used is
properly earthed or bonded to the tank structure. Electrical equipment should not be
used unless it is intrinsically safe (i.e. will not produce sparks). Explosive air/vapour
mixtures may form at ambient temperature. If product comes into contact with hot
surfaces, or leaks occur from pressurised fuel pipes, the vapour or mists generated
will create a flammability or explosion hazard. Product contaminated rags, paper or
material used to absorb spillages, represent a fire hazard, and should not be
allowed to accumulate. Dispose of safely immediately after use. Entry into a
confined space or poorly ventilated area contaminated with vapour, mist or fume is
extremely hazardous without the correct respiratory protective equipment and a safe
system of work.

Control parameters
Fuels, diesel ACGIH TLV (United States). Absorbed
through skin.
TWA: 100 mg/m³, (measured as total
hydrocarbons) 8 hours. Issued/Revised:
1/2007 Form: Inhalable fraction and vapor
maintained.
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process
equipment will be necessary to reduce emissions to acceptable levels.

Eye/face protection Chemical splash goggles.
Skin protection
Recommended: Nitrile gloves.
gloves.
clothes.
required.
approved by a specialist before handling this product.
Recommended: If ventilation is inadequate, use respirator that will protect against
organic vapour and dust/mist.

Appearance
Colour Water white to straw including fluorescent green, blue or yellow.
Odour Mild
pH Not available.
Boiling point 180 to 380°C (356 to 716°F)
Flash point Closed cup: >61.5°C (>142.7°F) [Pensky-Martens.]
Vapour pressure 0.1 kPa (0.755 mm Hg)
Relative density 0.83
Density 820 to 850 kg/m³ (0.82 to 0.85 g/cm³) at 15°C
Solubility Not available.
octanol/water
Auto-ignition temperature 240°C (464°F)
Viscosity Kinematic: 2 to 4.5 mm2/s (2 to 4.5 cSt) at 40°C

occur.
Acute toxicity
Fuels, diesel LC50 Inhalation Dusts and mists Rat 4.1 mg/l 4 hours
Fuels, diesel Skin - Irritation Rabbit - - -
Skin - Irritation Rabbit - - -
eyes.
eyes.
Sensitisation
Product/ingredient name Route of Species Result
exposure
Fuels, diesel skin Guinea pig Not sensitising
skin Guinea pig Not sensitising
Mutagenicity
Fuels, diesel OECD 471 Experiment: In vitro Positive
476
Subject: Mammalian-Animal
Cell: Germ
not guideline Experiment: In vivo Negative
Cell: Somatic
Conclusion/Summary Not classified. Based on available data, the classification criteria are not met.
Carcinogenicity
Fuels, diesel Positive - Dermal - Mouse - 2 years
Unspecified
Conclusion/Summary Suspected of causing cancer.
toxicity toxin
Fuels, diesel - - Negative Rat Dermal 20 days
Conclusion/Summary Development: Not classified. Based on available data, the classification criteria are
not met.
Fertility: Not classified. Based on available data, the classification criteria are not
met.
Effects on or via lactation: Not classified. Based on available data, the classification
criteria are not met.
exposure
Fuels, diesel Category 2 Not determined bone marrow, liver
and thymus
Aspiration hazard
Name Result
Fuels, diesel ASPIRATION HAZARD - Category 1
Alkanes, C10-20-branched and linear ASPIRATION HAZARD - Category 1
Information on likely routes Routes of entry anticipated: Oral, Dermal, Inhalation.

of exposure
Inhalation Harmful if inhaled.

pain or irritation
watering
redness
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
irritation
redness
nausea or vomiting
Inhalation Vapour, mists or fumes may contain polycyclic aromatic hydrocarbons some of
which are known to produce skin cancer. Vapour, mists or fumes may contain
polycyclic aromatic hydrocarbons some of which are known to produce skin cancer.
Vapour, mist or fume may irritate the nose, mouth and respiratory tract.
Skin contact As with all such products containing potentially harmful levels of polycyclic aromatic
hydrocarbons, prolonged or repeated skin contact may eventually result in dermatitis
or more serious irreversible skin disorders including cancer.
drowsiness.
General May cause damage to organs through prolonged or repeated exposure. Vapour,
mists or fumes may contain polycyclic aromatic hydrocarbons some of which are
known to produce skin cancer. Vapour, mists or fumes may contain polycyclic
aromatic hydrocarbons some of which are known to produce skin cancer.
Carcinogenicity Suspected of causing cancer. Risk of cancer depends on duration and level of
exposure.
Mutagenicity No known significant effects or critical hazards.
Teratogenicity No known significant effects or critical hazards.
Numerical measures of toxicity

Acute toxicity estimates
Route ATE value
Inhalation (dusts and mists) 1.895 mg/l

Toxicity
Fuels, diesel EL50 >1000 mg/l Nominal Fresh water Micro-organism 40 hours
NOELR 3.217 mg/l Nominal Fresh Micro-organism 40 hours
water
Acute EL50 22 mg/l Nominal Fresh Algae 72 hours
water
water
water
Acute ErL50 78 mg/l Nominal Fresh Algae 72 hours
water
water
water
water
water
Acute NOELR 46 mg/l Nominal Fresh Daphnia 48 hours
water
Chronic NOEL 0.083 mg/l Nominal Fish 14 days
Fresh water
Fresh water

Partially biodegradable.
Fuels, diesel OECD 301 F 60 % - Readily - 28 days 30 mg/l -
OECD 301 F 57.5 % - Not readily - 28 days 25 mg/l -
Equivalent to 35 % - Not readily - 28 days 5 mg/l -
EPA OTS 796.
3100
Conclusion/Summary Non-persistent per IMO criteria
Mobility in soil
coefficient (KOC)
Mobility Spillages may penetrate the soil causing ground water contamination. This material
may accumulate in sediments.

Special Precautions for Empty packages may contain some remaining product. Hazard warning labels are a
Landfill or Incineration guide to the safe handling of empty packaging and should not be removed.

ADG IMDG IATA
UN number Not regulated. UN3082 UN3082
UN proper - ENVIRONMENTALLY ENVIRONMENTALLY

shipping name HAZARDOUS SUBSTANCE, HAZARDOUS SUBSTANCE,
LIQUID, N.O.S. (Fuels, diesel) LIQUID, N.O.S. (Fuels, diesel)
Transport hazard - 9 9
class(es)
Packing group - III III

Environmental No. Yes. Yes.
hazards
Additional Remarks This product is not regulated This product is not regulated
information Combustible liquid Class C1 as a dangerous good when as a dangerous good when
(AS 1940). transported in sizes of ≤5 L or transported in sizes of ≤5 L or
≤5 kg, provided the ≤5 kg, provided the
Hazchem code packagings meet the general packagings meet the general
3Z provisions of 4.1.1.1, 4.1.1.2 provisions of 5.0.2.4.1, 5.0.2.6.
and 4.1.1.4 to 4.1.1.8. 1.1 and 5.0.2.8.
Initial emergency response
guide Emergency schedules
47 (EmS)
F-A, S-F
the IBC Code Category: gas oils, including ship's bunkers

Not scheduled

No listed substance
International lists
National inventory
Canada inventory All components are listed or exempted.
China inventory (IECSC) Not determined.
Japan inventory (ENCS) Not determined.
Korea inventory (KECI) Not determined.
(PICCS)
Taiwan Chemical All components are listed or exempted.
(TCSI)
(TSCA 8b)
History
revision
Version 1
Product Stewardship
UN = United Nations
101316-71-6, 101316-72-7, 64741-88-4, 64741-89-5, 64741-95-3, 64741-96-4,
64741-97-5, 64742-01-4, 64742-44-5, 64742-45-6, 64742-52-5, 64742-53-6,
64742-54-7, 64742-55-8, 64742-56-9, 64742-57-0, 64742-58-1, 64742-62-7,
64742-63-8, 64742-64-9, 64742-65-0, 64742-70-7, 72623-85-9, 72623-86-0,
72623-87-1, 74869-22-0, 90669-74-2
Flam. Liq. 4, H227 On basis of test data
Acute Tox. 4, H332 Calculation method
Skin Irrit. 2, H315 Calculation method
Carc. 2, H351 Calculation method
STOT RE 2, H373 (bone marrow, liver and thymus) Calculation method
Asp. Tox. 1, H304 Calculation method
Notice to reader
12. Appendix D - Enviropacific Services Fuel Experience

Enviropacific Services has contributed to the success of hundreds of convenience store, service
station, truck stop, highway service centre and retail food projects throughout Australia. Since 1989
our architectural design abilities have been well known within the retail petroleum industry. Our
project list boasts major oil companies, government organisations and independent operators alike
and currently shows in excess of 900 projects, the vast majority of these Oil Industry projects.
As an experienced service station design consultancy, our clients have access to the latest ideas
and innovations as they happen within the industry. Enviropacific Services is at the forefront of
many of these innovations. We aim to give our clients “something special”, something the market
will notice and admire. The Enviropacific Services design skills and attention to detail has been
recognized by many BDAQ State and Regional Design Awards. We are currently working with
clients in Queensland, New South Wales and Victoria on numerous service station, convenience
store and highway service centre projects.
Fuel system design and services co-ordination is another area of extensive experience for
Enviropacific Services. We have delivered scores of highly successful projects. We were, for
example, engaged as fuel system designers for the four Major BP highway service centres
completed in 2001 in Queensland. These are some of the largest retail petroleum facilities in
Australia and have set a new benchmark for highway service centres in this country.
Enviropacific Services, as a registered nationwide building design practice, performs a Lead

Consultant role in most projects we are involved with. As a sub-consultant, we also provide
specialist service station and fuel system design and certification services. Another project role
Enviropacific Services performs is that of the architectural documentation consultant working within
the project design team, under the control of the leader consultant.
High quality project design coordination is a priority for all Enviropacific Services projects. All
services and design drawings from all consultants should read together without error or conflicting
information. This is our goal and although many acknowledge its importance, few actual achieve
consistent success. At Enviropacific Services coordination is not simply a concept – it is an
OBSESSION!
13. Appendix E - Enviropacific Services Fuel Industry Clients

Enviropacific Services oil Industry clients include (independent operators excluded):
• BP Australia • Caltex Australia • Pacific Petroleum • Avis Australia

Products
• Air BP • Woolworths Ltd • United Petroleum • ECL Fuelquip
• Reliance • Caltex Energy • Advance Petroleum • Gilbarco

Petroleum
• Westoil Petroleum • Central Petroleum • Independent Fuel • JF TA
Queensland Supplies
• AA Petroleum • Matilda Petroleum • Ergon Energy • Tank Solutions
• Jasbe Petroleum • Qld Fuels Group • Energex • Lanskey

Constructions
• SEQ Fuel Supplies • Shell Australia (Go • Emerald Shire Council • Petroleum
Gas) Constructions
• Central Petroleum • Rampage Pty Ltd • Night Owl
Queensland Convenience Stores
• Castrol • Pacific Fuels • Swap n’ Go
14. Appendix G - Enviropacific Services Fuel Industry Projects

Below are details of a select number of Oil Industry projects that Enviropacific Services has provided
design services for:
Project Scope Client Site Scope of Services Project

Value
Brisbane Area
Fuel System Design BP Australia Pty Caboolture North & South Proposed twin highway $25m
Ltd service centres & WBC
counter upgrades
Fuel System Design BP Australia Pty Coomera, Staplyton Proposed twin highway $25m
Ltd service centres & WBC
counter upgrades
Lead Consultant BP Australia Pty Whinstanes, Hendra Office Fitouts $250k

Ltd
Architectural BP Australia Pty Helensvale, Major Modifications $500k

Design Ltd
Architectural BP Australia Pty Various Sites including Ferny Connect Upgrades, Juice $30m
Design Ltd Grove, Springwood, Offers, Wild Bean
Maroochydore, Hamilton, Upgrades, Major
Fuel System Design
Virginia, Bribie Island, Palms Modifications, Raze &
Corner, Oxenford, Morayfield, Rebuilds, Café Zips
Loganholme, Aspley,
Narangba, Labrador, Moggill
Road, Blacksoil, Nerang,
Chinderah South (NSW)
Fuel System Woolworths Various Sites including Fuel System License $5m
Certification Petroleum Chermside, Bowen, Mackay, Compliance Checks
Dalby, Noosaville, Gladstone,
Gympie
Lead Consultant United Ayr, Springfield, Crestmead, New Service Station $5m
Petroleum Maryborough Developments and Fuel
System Upgrades
Lead Consultant Swap ‘N’ Go Hemmant LPG Cylinder Processing -

Plant
Fuel System Design Shell Engineering Tewantin, Burleigh Waters, Autogas Installation $1m
Victoria Point, Toowoomba,
Loganholme, Kallangur
Lead Consultant South East Yatala Proposed Truck Refuelling $300k

Queensland Facility and Unmanned
Fuels Refuelling facility
Lead Consultant PHF East Brisbane, Wamuran Autogas and Pump & $1m
Tank Layout
Master Planning Colin Loel Gateway Motorway, Nundah Highway Service Centre $8m
Architects
Fuel System Design Pratt & Whitney Eagle Farm Fuel Farm and Spill Trench $500k
Fuel System Design PECC Burbank, Eagle Farm Proposed Diesel $250k
Refuelling Facility
Lead Consultant Pinnaroo Estate Rainbow Waters Resort Multi Residential $25m
Documentation
Lead Consultant Freedom Fuels Inala, Beenleigh, Acacia Food Offer Revitalisation $1m
Ridge
Fuel System Design Caltex Carseldine Service Station $1m
Master Planning Hallmark Plainland Highway Service Highway Service Centre $6m
Properties Centre
Sydney Area
Lead Consultant XL Development Newcastle Proposed Truck Stop $6m

Group
Architectural Merino Golburn Proposed Service Station $5m

Design Properties Development
Architectural Jasbe Petroleum Auburn, Silverwater, Oakes, Raise & Rebuilds $10m
Design Baulkham Hills, Warwick Farm,
Lansvale, Willoughby
Lead Consultant Westoil Young, Lithgow, Mudgee Retail Network Review & $3m
Petroleum Revitalisation
Fuel System GOGAS Strathfield, Terrigal, Berkshire Autogas Installation $500k

Designer Australia Park, Buladelah
Melbourne Area
Lead Consultant Jasbe Petroleum Frankston (Big Pine) Proposed Service Station $2m
Redevelopment
Lead Consultant Jasbe Petroleum Highbluff Proposed Service Station $1m

Redevelopment
Lead Consultant AA Petroleum Pakenham Zip/Connect Upgrade $2m
Architectural BP Australia Pty Standards ST29, ST31 Drawings -

Documentation Ltd (MEL)
and Coordination
Lead Consultant AA Petroleum Oakleigh, Burwood East Proposed Service Station $2.5m
Redevelopment
Lead Consultant Morphic Capital Longworry Proposals for twin $12m

Highway Service Stations
Architectural Jasbe Petroleum Supremacy, Lyndhurst, Service Station Interior $10m

Design Fitouts
Lead Consultant Rampage Rockbank Proposal for twin Highway $15m

Enterprises Pty Service Stations
Ltd
Fuel System Design Advance Geelong Depot Upgrade to existing diesel $250k
Petroleum facility
Darwin Area
Architectural BP Australia Pty Nightcliff Raise & Rebuild -

Design Ltd
Architectural BP Australia Pty Ludmilla Raise & Rebuild -

Design Ltd
Architectural Gilbarco RAAF Base Tindal As Constructed $5.5m

Design
Perth Area
Fuel System Design Cronin Star Track Fuel System & Autogas $500k
Construction facilities
Townsville Area
Fuel System Design BP Australia Pty BP Cluden Truck stop Truck Stop $8m
Ltd
Lead Consultant BP Australia Pty BP Express Aitkenvale Service Station $3m

Ltd
Lead Consultant BP Australia Pty BP Southern gateway Service Station $1.5m

Ltd
Please visit our Company Website at www.cadway.com.au for additional information about
Enviropacific Services, our expertise, experience and previous project involvement.

P Hazard Identification and Risk Assessment 6 Honeman Close Huntingwood Arcidiacono

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P Hazard Identification and Risk Assessment 6 Honeman Close Huntingwood Arcidiacono

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Hazard Identification

and Risk Assessment

John and Anna Arcidiacono

6 Honeman Close, Huntingwood, NSW

Project No: 11034 Revision: A

Cadway Project No 10909

Authored by Approved by Approval Date

C. Karageorgos C. Rogers 14/07/17

Rev Nature of Change/Issue Author Date

A Issued for DA C. Karageorgos 14/07/17

2. Description of Site ........................................................................................................................................... 4

3. Description of the Proposed Fuel Facilities ................................................................................................ 5

4. Findings and Recommendations ................................................................................................................ 7

6. Site Manifest .................................................................................................................................................. 12

7. Hazard Identification and Risk Assessment ............................................................................................. 14

8. SEPP 33 Preliminary screening .................................................................................................................... 31

9. Appendix A - Legislation ............................................................................................................................. 32

10. Appendix B - Proposed Site Plan ............................................................................................................... 33

11. Appendix C - Safety Data Sheets ............................................................................................................. 34

12. Appendix D - Enviropacific Services Fuel Experience ........................................................................... 35

13. Appendix E - Enviropacific Services Fuel Industry Clients ..................................................................... 36

14. Appendix G - Enviropacific Services Fuel Industry Projects .................................................................. 37

1. Scope of this Report

Site Area of proposed works: 15032 m2

Real Property Description: Lot 2 on DP229466

Local Authority: Blacktown Council

Owner: John and Anna Arcidiacono

Operator: John and Anna Arcidiacono

Figure 1 Aerial Photo of Site Locality

3. Description of the Proposed Fuel Facilities

4. Findings and Recommendations

 Provide line marking and directional signage on the forecourt.

 Emergency contact details shall be provided.

 Implement strict tanker unloading operation controls.

 Console operator to shut down dispenser if someone is smoking at dispenser.

Manifest and Emergency Plan.

 Provide CCTV monitoring of the console area.

LPG Exchange Bottle Cages:

RISK LEVEL GUIDE: FREQUENCY

Low, risk level acceptable, no

7-10 High, requires action. ↓ 3 6 9 12 15

Unacceptable, activity must stop,

 Identify all hazards

7. Hazard Identification and Risk Assessment

Section 2 – The Installation

8. SEPP 33 Preliminary screening

Refer to SEPP 33 Preliminary screening report attached

Proposed BP Service Station Development; 6 Honeman Close, Huntingwood, NSW

Hazard Identification – Preliminary Screening

Table 1 displays hazardous materials to be stored on-site and quantities.

Table 1: Material quantities and classifications.

117878 - l01 - huntingwood sepp33 2

Dr. Santo Ragusa

117878 - l01 - huntingwood sepp33 3

 New South Wales Occupational Health and Safety Regulation 2000

10. Appendix B - Proposed Site Plan

Refer to Proposed Site plan drawings attached

building designers' DO NOT SCALE

Studio 24/115 Wickham Street,

JOHN AND ANNA

11034 job no.

11034 SK018 dwg no.

ISSUE FOR CLIENT APPROVAL