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Dental Waxes
Dental Waxes
Dental Waxes
PHYSICAL PROPERTIES.
COMPOSITION OF WAXES
COMPONENTS OF WAXES
CLASSIFICATION
DENTAL WAXES.
CONCLUSION
REFERENCES
INTRODUCTION
WAXES are thermoplastic materials which are normally solids at room temperature but
melt without decomposition to form mobile liquids.
DEFINITION
A thermoplastic molding material that is solid at room
temperature and when subjected to moderate temperatures
become low viscosity liquid. Waxes are esters of fatty acid,
alcohol, or hydrocarbons. They are insoluble in water but
soluble in most organic solvents.
Dental wax
A low molecular weight ester of fatty acids derived from natural or synthetic components,
such as petroleum derivatives , that soften to a plastic state at relatively low temperature.
A mixture of two or more waxes and additives used as an aid for the production of gypsum
casts, productions of non-metallic denture bases, registering jaw relation, and laboratory
work
DESIRABLE PROPERTIES OF
WAXES
MELTING RANGE
Waxes do not melt at a single temperature . So they do not have a melting point ,they have a melting
range.
Temperature at which a sharp increase in coefficient of thermal expansion occurs indicating increased
molecular mobility
In waxes, at this temperature , transition from a stable crystal lattice (orthorhombic) to hexagonal form
occurs which is present below the melting point of wax and thus it allows the wax to be manipulated easily
without flaking or tearing.
Linear coefficient of expansion –change in length per unit of the original length of a material when its temperature is raised by
1˚C
For most solid materials, the volumetric coefficient of thermal expansion can be considered to be thrice of that linear CTE
Waxes have very high CTE, particularly around the melting range, and very high residual stress ; they have the
highest CTE as compared to all other materials used in dentistry.
CTE of typical pattern wax is 323x10/ C but that the dental porcelain is 20 times less 14x10/C
Small changes in temperature can cause a sufficient change in dimension to make the pattern inaccurate
Thermal conductivity
The thermal conductivity of the waxes is low, and sufficient time must be
allowed both to heat them uniformly throughout and to cool them to body
or room temperature
Mechanical properties
Residual stress
It is the stress remaining in a wax as a result of manipulation during
heating, cooling, bending, carving or other manipulation
The release of residual stress at higher temperature causes an irreversible
deformation that can destroy the fit of a wax pattern
The warpage is due to the residual stresses which result from the heating
of a wax specimens formed under compression or tension
It will result in a dimensional inaccuracy and is undesirable . The longer the wax pattern is left before being
invested , the greater the distortion that must be result
Crystalline waxes develop more internal stresses when manipulated below the transition temperature
Time and
Composition
The dental waxes are composed of natural waxes and synthetic waxes,
gums, fats, fatty acids, oils.
Natural waxes are derived from mineral , vegetable and animal origins
Synthetic waxes are chemically synthesized from natural wax molecules
and are typically composed of hydrogen, carbon, oxygen and chlorine
Colouring agents are added for contrast of wax patterns against tooth, die,
and model surfaces
Most dental waxes contain 40%- 60% paraffin by weight , which is derived
from high boiling fraction of petroleum
They are composed mainly of a complex mixture of hydrocarbons together
with minor amounts of amorphous and microcrystalline phases
The melting temperature generally increases with increasing molecular
weight
Paraffin wax is likely to flake when it is trimmed , and it does not produce
a smooth, glossy surface which is desirable for an inlay wax
Gum dammar – or dammar resin is a natural resin. It is added to the paraffin to improve the
smoothness in moulding and to render it more resistant to cracking and flaking.
It also increases the toughness of the wax and enhances the smoothness and lustre of the surface.
Carnauba wax occurs as a fine powder on the leaves of certain topical palms. This wax is very hard
, and it has a relatively high melting point and has an agreeable odour
Candelilla wax can also be added partially or entirely to replace carnauba wax. Candelilla wax
provides the same general qualities as carnauba wax but its melting point is lower and it is not as hard as
carnauba wax.
Ceresin is typically a white wax extracted from ozokerite, a waxy mineral mixture of hydrocarbons that is
colourless or white when pure but it has a somewhat unpleasant odour.
Montan waxes are hard brittle and lustrous ; they blend with other waxes and therefore often
substitute to increase the melting range of paraffin waxes.
Classification OF WAX
Uses:
It is used to make pattern for metallic restoration
Pattern for inlay
Crown and bridges are first made in wax and then converted into
metal or ceramic by casting
The colour should be contrast with the die or prepared teeth. A defined colour contrast helps in identifying
and finishing.
The wax should be able to disintegrate and volatilize so that it could be eliminated completely without
residue during burn out or wax elimination procedure.
The wax pattern should be completely rigid and dimensionally stable at all times until it is eliminated
Composition
Inlay wax is composed of paraffin wax, gum dammar, carnauba or candelilla and colouring agent.
Paraffin wax is the main component (40% - 60%) which is used to establish the melting range
Being the main component ,gum dammar, carnauba , candeililla wax are added to modify its properties
Colouring agents are added for contrast of wax patterns against the tooth, die or model surface.
Classification
TYPE I : Medium wax employed in direct technique
TYPE II : Soft wax used for indirect technique , for inlays and crowns.
DIRECT TECHNIQUE- A wax pattern made in the mouth for producing wax inlay
patterns within prepared teeth.
Because the thermal expansion coefficient of wax is extremely high compared with
the values for other dental materials, a wax pattern made in mouth will shrink
appreciably as it cooled to room temperature
Indirect technique : The cavity is prepared in the tooth and the pattern is carved directly on a die
that is a reproduction of the prepared tooth and dental tissues.
A regular or soft type of a wax is typically used for indirect work at room temperature or in a cool weather.
A harder or medium type with a flow property is indicated for use in warmer climates.
The first procedure in casting of an inlay or crown for the lost wax process is the preparation of dental wax
pattern by direct or indirect technique.
The wax pattern forms the outline of the mould into which an alloy is cast or a ceramic is hot-isostatically
pressed.
The pattern should be well adapted to the prepared cavity or replica cavity and properly carved without any
significant distortion.
Before the adaptation of the wax pattern within a tooth or a die, a separating medium must be used
After the pattern is removed from the prepared cavity, it is encased in a gypsum or phosphate- based
refractory material known as an investment which is called investing the pattern.
After investing anatomically accurate wax or resin patterns for inlays, onlays, crowns, bridges and
framework for removal partial dentures, the invested material must be eliminated completely before
molten metal is cast or core ceramic is hot- pressed into the mould cavity.
Waxes oxidizes on heating, and on prolonged heating some waxes evaporate, so that the storage
container for melted wax will be coated by gummy deposits.
Therefore care should be exercised to use the lowest temperature possible and to clean the wax pot
and replace the wax periodically.
To manipulate inlay wax , dry heat is preferred to the use of water bath
The later can result in the inclusion of droplets of water, which can splatter on flaming , smear the
wax surface during polishing, and distort the pattern during temperature changes
To avoid distortion during removal of the pattern, it should be penetrated slightly with an explorer
point and carefully removed from the cavity
After removal touching the pattern with fingers should be avoided as much as possible to prevent any
temperature changes and distortion.
To fabricate indirect patterns, the die should be lubricated preferably with a lubricant containing a
wetting agent.
Any excess must be avoided because it will prevent intimate adaptation to the die.
The melted wax may be added in layers with spatula or a waxing instrument.
The prepared cavity should be overfilled and the wax then carved to the proper contour.
A silk or other fine cloth may be used for a final polishing of the pattern, rubbing towards the margin.
Some clinician prefer to apply finger pressure as the wax is cooling to help fill the cavity and prevent
distortion during cooling. The fingers also accelerate the cooling rate.
Regardless of the method chosen , the most practical method for avoiding any possible delayed
distortion is to invest the pattern immediately after removal from the mouth or die.
Once the investment hardens (sets), no distortion of the pattern will occur
Wax Distortion
Distortion of a wax pattern results from occluded air in the pattern, physical deformation ( during
moulding, carving or removal) release of stresses “trapped” during previous cooling, excessive storage
time, and extreme temperature changes during storage.
It is important that the wax pattern be retained on the die for several hours to avoid distortion and
ensure that equilibrium condition are established.
Waxes tend to return partially to their original shape after manipulation. This is known as elastic
memory.
Casting wax
USES:
To make patterns of the metallic framework and sprues of removable partial denture
SUPPLIED AS:
● Preformed shapes
● Bulk form
●Rolls or coils of various diameters ranging from 2-5 mm for forming sprue
CLASSIFICATION:
COMPOSITION:
PROPERTIES:
Baseplate waxes
ADA specification no 24
USES:
To establish the initial arch form in construction of complete denture and used to produce desired contour of the denture after teeth set in position
SUPPLIED AS
Sheets of pink or red color having 1-2 mm thickness
COMPOSITION
Paraffin wax -75%
Both to set denture teeth and to adapt around these teeth and to develop proper contour
Wax rim ( bite rim)
USES:
Arrangement of teeth
Processing waxes
USES
Beading was is adapted around the impression borders to create the land
area of the cast.
Boxing wax is used to build up vertical walls around the impression in order
to pour the gypsum product to make a cast base
SUPPLIED AS:
Properties:
They are pliable and can be adapted easily.
Utility wax
Composition:
Consist mainly of beeswax and petrolatum and soft waxes in varying proportion.
Supplied as:
It is available in the form of sticks and sheets . Orange or dark red in colour.
Flow at 37.5˚C – minimum 65% and maximum 80%
Pliable and tacky at 21-24˚C
USES:
It can be used to alter the stock tray extension.
It is pliable and can easily be molded
It is adhesive and can stick to the tray
Sticky wax
It is a type of processing wax.
It is sticky when melted with a max 5% flow at 30˚c and 90% flow at 43˚c and
adheres closely to the surfaces when applied to it
USES:
Sticky wax is used to join and stabilize temporarily the components of a bridge
before soldering and also to stabilize pieces of a broken denture before the
repair
It is quite tacky when melted , but firm and brittle when cooled.
Carding wax
It is used by manufacturers for the packaging of acrylic or porcelain teeth.
Corrective wax:
Wax in combination with resins of low melting range can be used in corrective
impression technique in partial and complete denture prosthesis
28 gauze casting wax or hard base plate wax , bees wax , hydrocarbons are used in bite registration wax.
Occlusal registration made from addition silicon, elastomers become more popular because of their high
elastic recovery and dimensional stability.
Conclusion
References