Chemistry answer key

Q1.
. C6H5NH2>C6H5NHCH3>C2H5−NH2>(C2H5)2NH
Q3.(I)

(II) R-CO-NH 2+ Br 2 + 4NaOH → R-NH + 2

Na CO + 2NaBr + 2H O
2 3 2

Q.4(I) Ethylamine and aniline :

Azo dye test.
Aniline on diazotization ( ice cold nitrous acid solution) followed by coupling
with 2-naphthol (in alkaline solution) forms brilliant orange or red dye.
Ethylamine will not form dye. It will give brisk effervescence (due to liberation of
nitrogen gas) but solution remains clear.
(II) Aniline and benzylamine :
Azo dye test.
Aniline on diazotization ( ice cold nitrous acid solution) followed by coupling
with 2-naphthol (in alkaline solution) forms brilliant orange or red dye.
Benzylamine will not give such test
Q5(I)
(ii)

Q.6

Q.7(i) Sandmeyer reaction:

It converts aryl diazonium salts to aryl halides. An aromatic amino group is
substitued with a nucleophile (such as halide anions, cyanide, thiols, water, and
others) via diazonium salt intermediate. The reaction is catalyzed by cuprous
compounds.
PhN2+Cl−CuCl−N2Ph−Cl
(ii)

Q.8(i)

(ii)
Q.9(i)

(ii)

Q.10
Q.11(i) Methylamine and dimethylamine :
Carbylamine test.
Methylamine, on heating with alc. KOH solution and chloroform form foul-
smelling methyl isocyanide. This test is not given by dimethylamine.
(ii) Aniline and N-methylaniline :
Carbylamine test.
Aniline, on heating with alc. KOH solution and chloroform form foul-smelling
methyl isocyanide. This test is not given by N-methyl aniline.
Q.12
Q.13

Q.14(i)

(ii)
Q.15(I)
In diazonium salt, the structure goes under resonance due to which the dispersal of positive
charge is more and we know that higher is the resonance higher is the stability. Therefore
diazonium salt of aromatic amines is more stable than those of aliphatic amines

(ii) Reason for Amine more Basic than Alcohol:

 Because amino acids are less electronegative than alcohols, they are more basic.
 In aqueous solutions, alcohols break down to give H+ ions, whereas amines do not
dissociate and have a tendency to donate electrons.
 As a result, amines are more basic than alcohol.

Q.16(i) Aniline does not undergo Friedal-Crafts reaction because Aniline forms salt with
AlCl3, the Lewis acid.

(ii) Aromatic primary amines cannot be prepared by Gabriel’s phthalimide synthesis because Aryl
halides do not undergo nucleophilic substitution with the anion formed by phthalimide

Q.17(I)

(ii)
Q.18(I)

(ii)