JEE-Main-28-07-2022-Shift-2 (Memory Based) Physics Question: Two photons, first has energy twice the other. If energy of first photon is 5 times its work function, find the ratio of maximum velocities Options: Answer: (6) Solution: Max. KE. of electron Question: A capacitor has capacity Ca, When a dielectric of constant K& width 3/4” of sepatation between plates is inserted, then find the new eapacity.Answer: (J) Solution Question: A chain of uniform mass desity with length ‘L*, mass M is hanging over an ideal L find x? smooth pulley. When , the aeccleration of chain is ws Options: @ tb) o @ Answ Solution: FIs Gin sin Bie 2)Question: Time period of a pendulum is measured on surface of a planet with a stop watch of 1 sec isolation is found to be 200 sec, Its length was measured as [+ 0.00, percentage error in measurement of are due to gravity is Options: (a) 1.1% (b)03% 125% 52% gt= 2x 1904 2001 200 100 AL) ayaa 7 1.2% Question: Water lows out of a pipe and hits a wall, it has horizontal velocity v and eross- sectional area A. The deasity of the water isp. The water does not rebound from the wall ‘What is the fore exerted on the wall by the water? Options: Time period of a pendulum is measured on surface of a planet with a stop watch of 1 see resolution in found to be 200 see. Its length was measured as [-+0.00Ln. Percentage cerrorin measurement of are duc to gravity isOptions: (a) 1.4% () 11% ©22% (2.1% Answer: (0) Solution: =—L+0001=0011 100 error = L.1% Quest achieved from point of projection? (xy = 9.8m /s) Options: (a) 196m (6)2.9m (©) 196m (6) 12.96m Answer: (¢) Solution: Maximum height = ir(say) ah At topmost point v= 0 And 1 = 19.6m/s (given) Ball thrown upwards from a building with speed 19.6 m/s. Find maximum height @ (19.6) =-2(9.8)(H) (19.6)" Yanna Question: Time period of a simple pendulum on earth's surface is 4 see and at height h above the earth's surface is 6 sec. Find the value of h if R = 6400 km. Options: (a) 1200 (e) 2400(©) 3200 (@)3500 Answer: Solution: 4 * 6 R+h SAR 4h=6R=4h= 28 »=2—3200 2 Question: For the given equation, please sclectincorset statement, where K is Boltzmann constant, Tis absolute temperature Bx sind= eon| 3] Options: (a} Dimension of is same as force (b) Dimension of axis same as energy (6) Dimension of zand fis same (@ Dimension of KT is same as energy Answer: Solution: [xT] [=H bs] wert [acters] Question: Assertion: Resistance of 800 is cut equally in 4 parts and all resistances ane kept parallelly the net resistance is SO Reason: When 2R and 3R connected in parallel, ratio of heat dissipated in them is 3 2 correct statement is/are Options: (a) Ifboth assertion and reason are true and the reason isthe correet explanation of the assertion, (b) If both assertion and reason are truo, but the reason is not the correct explanation of the assertion. (¢) If assertion is true, but reason is false (@) If both the assertion and reason are true.Answer: (J) Solution: Assertion: Lot r be sesistance of each eut part then 20 Now 4 resistors of 2002 in parallel Ry =P =50 Question: Two light rays incident on surface of « metal with energies $ times and 6 times the work function f metal zespectively. The ratio of speeds of electrons, ejected with maximum kinctic energies in each case, respectively is Options: 4 ws Answer: Solution: AS KE,., ==mv" dwt = SW = 2 Le a9 And Lin =6W7 1 =51 2 ele Question: Work done by gas in expansion iy 150J and degrees of freedom = 8 find heat (q) Options: (a) 250 (b) 350 (©) 650 (e750Answer: (J) Solution: a= pAY =ARAT =150J ..(I) Q=nC,AT (£2) RAT (a) 750) (b) 6501 (©) 550) (4503 Answer: (a) Solution au=“Lrar=4nkar AW =150J = nRAT AQ= AW +AU = nRAT +4nRAT = SnRAT =5(150) 50d Question: The ratio of magnetic field at the centre of cireular coil and at a distance of V3R from cenite on axis ofthe coil is Options: (it=i abR +e)" 16k Bae 8 2,JEE-Main-28-07-2022-Shift-2 (Memory Based) Chemistry Cone. HINO) reacts with Ip to give (a) HI () HOI (c) Hl (@) IO, Solution; Iodine reacts with concentrated nitric acid according to the following equation IOHNOs + fp > 2HIOs + LONO: +4110 Question: White phosphorus reacts with thionyl chloride to give Options: (a) POC, (b) PC Solution: Ps + SSOCI: + 4PCls 4 4802 + 282Cle Question: Produets obtained during trestment of hard water using Clark's method are Options: (a) CaCOx, Mg(OH)» (b) Ca(OH}, MCOs (©) €xCOs, MgCOs (a) Ca(OH, MgiOH}2 a) Solution: In Clark's method calculated amount of lime is added to hard water, It precipitates out calcium carbonate and magnesium hydroxide which ean be filtered off. Ca(HCOs)2 + Ca(OH)2 > 2CaCOs | + 2H20 Mg(HCOs)s + 2Ca(OH)2 — 2CaCOs | + Mg(OH}2 | +220 Question: Decreasing onder of metallic character Na, Mg, Be, Si, P Options: (a) Na> Mg> Be> P>Si (b) Mg Na> Si> Be> P (6) Na> Mg > Bo> Si> P (@)P > Si> Be> Mg>Na Answer: (¢)Solution: Metallic character increases down the group and decreases along the period as we move left to right Hence, order of decreasing: metalic character is Na > Mg > Be > Si> P Question: Assertion: Permanganate titrations are not performed in presence of HCL Reason: Chlorine is formed as a consequence of oxidation of HC] Options: (a) Both assertion and reason are true, reason is correct explanation of assertion (b) Both assertion and reason are true, but reason is not a correct explanation of the assertion, (©) Assertion is true, but reason is false (@) Assertion is false, but reason is true Answer: (a) Solution: Permanganate titrations are not performed in presence of HCI because HCI oxidises to form closing, Quest OT iiesteo0s CVG Werte a @ , O> (by) . (&) (d) OO Answer: (a) Solution:or Lao, COSY ° Re / 1 Pandine OO Question: Match the following, (Column J) (Calnmn Iy Compounds Hybridizations (A) NiCO}e (dsp B) [Ni(CN)eP isp" (©) [CCN Gli) dsp? | Option (@) A Gi); Br Gi} C> @ () A > Gill); B> @); C— Gi) (9) A= Gills B (i); CG) (@) A> (i B Gils C Fi A) Ni(CO}s=> sp* B) [Ni(CN)s]*" = dy ©) [Co(CNys]* = ?sp* Question: Assertion: Aniline on nitration gives o, p, m products, Reason: Mixture used in nitration is acidic Options: (a) Both assertion and reason are true, reason is correct explanation of assortion (b) Both assertion and reason are true, but reason is nota correct explanation of the assertion. (6) Assertion is true, but reason is false (@) Assertion is false, but reason is true Answ Solution: Dizoct nitration of aniline yiolds tarry oxidation products in addition tothe nitra derivatives. Moreover, in the strongly acidie medium, aniline is protonated to form the snilinium ion which is meta directing, That is why besides the ortho and para derivatives, significant amount of meta derivative is also formed.NE NE, H, NH, NO, HNO, H,S0, 288K. . . ‘NO, No, (519%) (47%) 2%) Question: Assertion: Zero orbital overlap is an out of phase overlap Reason: It results due to different orientation / direction of approach of orbitals, Options: (a) Both assertion and reason are true, reason is correct explanation of assertion (b) Both assertion and reason are true, but reason is not a correct explanation of the assertion (©) Assertion is true, but reason is false (@) Assertion is false, but reason is truc Answi Solution: Zero overlap is out of phase due to different orientation direction of approach Find the change in oxidation state of oxygen when KIQ« reacts with Hs0x? Answer: (c) Solution: KIO, +H, 0 KIO, +H,0+0: Question: Heat B Options: (a) iO}on | Zo dust © Question: Matching of polymers: Column 1) (Column I} A) Nylon, |) Thermioseiting (B) Bakelite a Thermoplastic (C) Polythene Gii) Elastomer (D} Natural rubber (iv) Fibers: Options: (a) A (9: B> Git}: © — Gis D > Civ) (b) A (ins Bri}, © Gil D> ii) (8) A> Giik B (i: C > Gv DG) @A= (is B > WC > Civ; D > Ga) Answer: (6) Solution: Nylon = Fibers Bakelite = Thermosetting Polythene = Thermoplastic Natural rubber > Elastomer Question: Arrange the following according to the rate of nitration: 1) p-xylene2) bromobenzene 3) mesitylene 4) benone Options: (@)3>1>4>2 ()2>1>4>3 (1>3>2>4 (@)4>2>3>1 Answer: (a) cH, br cu, 6 6 ony ‘cH, cH, o Q 6) a) More is the electron density groups attached, higher is the rate of nitration. Question: Find the molarity of Na2SOs formed upon mixing of 0.2 M, 2 L HeSOs and 0.1 M, 2LNaOH, Options: (a) 0.05 M (b) 0.03 M (©) 0.04 M. H2S04-+ 2NaOH — NasSO4 +2120 Initial moles 04 0.2 = - NaOH is the limiting reagent 2 moles of NaOH > | mole of NazSO« 0.2 0.2 moles of NaOH 1 moles of NaxSO« 0.025M&) Answer: (c) Solution:Z ier AY Carbocation @ sentrangement [v= fA ‘Br Question: The temperature at which rms speed of gas molecules becomes double of its value at O°C is Option (a) 819°C (b) 760°C (©)273°C (@) 224°C 273 4=1092K = 819°C Question: In the reaction, No + O22 2NO IFinitial moles of No and Oz are 2 mol and | mol, then find the value of Ke, The moles of Oz at equilibrium is 0.6 mol. Answer: 01.67Solution: Net Ore 2NO Initial moks 21 . Final moles 2-04 1-04 0.42 = 16-06 0.8 Question: In a FCC lattice a molecule, density = 9.03 giew?,a=4= 10 "em, Find molecular weight Answer: 87.00 Solution zM an, * 10% em, density = 9.03 cnr d= dein, 903%(4x10° 6.0210" rr = 86.97 glmol M=87 pmol Question: How many of the following are not isoelectronic species? Ayyb? B) Tb ©) Eu? D) Tb? Answ Solution: Yb" — 41? (67 electrons) Th’ 477(61 electrons) Eu’? 41° (60 electrons) Tb’? 4 (63 electrons) None of them is isoelectronic species 00JEE-Main-28-07-2022-Shift-2 (Memory Based) MATHEMATICS a of BY_S. of #)_2 7 Question: If ofS)-8 os \eza Given = P(A Optio (a) Both S, and S, are correct (b) 5, is tc and 5, is false (6) S, is false and S, is true (@ Both 5, and S, are false As P(A 8) =h we get r= Ze P(a)=2 P(A B=1-P(ANB) fn B=4, then (4oB)= 7 0 As Plae)=1 we get P(A) Jer P(A'UB)=1-(P(A)-P(An8)} a 45 5 is wrong, Question: Absolute maximum value of f(x) =tan""(sin.r~cos.x) issOptions: @o @) wn" oF @ tan Answer: () Solution: siny-oosx [V3.3] ‘So maximum value of tant (sin x—cos.x) is tan! V2 Question: The values of A for which the line are coplanar, are: Options: @ ANT (b) 4y5, @2 (@) 4v2 Answer: () Solution: For coplanatity 12 a 1 2 2=0 ho 4 > 1(42°)-2(a) +27 (-22°) =0 Question: From point (2,0) tangents are drawn on 2y* =—x. These tangents also touches the The value of 1777 is: Answer: (¢)Solution Equation of angen 16n? =1> m= a Tangent are Fquation of tangent 1 (x~5}*-+y? =r! are s-dya? & Aytr=2 Using d, =r, we get Question Let fx) = fn S082 FSCS) Options: (a) R-fI} ) R-(-11} (©) R-{0.3} (@ R-{0} Answer: (b) Solution: For |x|<1,f(x) =cos2ax is continuous at: S(s)=A im f(x) 2 So F(x) i dssomrimions atQuestion: A class have B boys and G girls, 3 boys and 2 girls selected at random and number of ways of selecting 3 boys and 2 girls are 168. Then B+3G is equal to Answer: 17.00 Solution Given that > B(B-1)(B-2)G(G-1) =7-6-4.3-2.2 = B(B-1)(B-2)G(G-1)=8-7-6-3-2 B=8&G=3 3 B+3G=84917 Question: Let f (x)= ax" +br+e and ()=3, f(-2)=2./(3)=4 then the valucof 4 for which £(0)+ £()+4(2)+/(3)=14 is__. Answer: 4.00 Solution: Given, f (x)= av +bx 4c £0 s(=arb+e=3 fl) f(2)=4a-26+e=A (2) {(3)=9a+30+e=4 ...(3) By solving (2) & (3) asp=t4 5 Also, c=34244=14 e=T-A Putting in (1)