A.

ANALISIS DATA
1. Erlenmeyer 1
Dik : [CH3COOH] = 0,5000 M
Mr CH3COOH = 60 g/mol = 60 mg/mol
V CH3COOH = 100 mL
[NaOH] = 0,1 M
V NaOH = 45,8 mL
W arang = 1,0004 gram
V CH3COOH = 10 mL (filtrat)
x
Dit : log C dan log …..?
m
Penyelesaian :
mmol CH3COOH = (M × V) CH3COOH
= 0,5000 mmol/mL × 100 mL
= 50 mmol
mmol NaOH = (M × V) NaOH
= 0,1 mmol/mL × 45,8 mL
= 4,58 mmol
Reaksi : CH3COOH + NaOH → CH3COONa + H2O
Mula – mula : 50 mL 4,58 mmol - -
Bereaksi : 4,58 mmol 4,58 mmol 4,58 mmol 4,58
mmol
Setimbang : 45,42 mmol - 4,58 mmol 4,58
mmol
mmol CH3COOH yang teradsorpsi = mmol CH3COOH - mmol NaOH
= 45,42 mmol – 4,58 mmol
= 40,84 mmol
Massa CH3COOH yang teradsorpsi = mmol CH3COOH yang teradsorpsi × Mr
= 40,84 mmol × 60 mg/mmol
= 2.450,4 mg
= 2,4504 gram
 x massa yang teradsorpsi
=
m massa arang
2,4504 gram
=
1,0004 gram
= 2,4494
x
log = log 2,4494
m
= 0,3890
mmolCH 3COOH yang teradsorpsi
C =
V CH 3COOH
40,84 mmol
=
10 mL
= 4,084 M
log C = log 4,084
= 0,6110 M
2. Erlenmeyer 2
Dik : [CH3COOH] = 0,2500 M
Mr CH3COOH = 60 g/mol = 60 mg/mol
V CH3COOH = 100 mL
[NaOH] = 0,1 M
V NaOH = 21,3 mL
W arang = 1,0158 gram
V CH3COOH = 10 mL (filtrat)
x
Dit : log C dan log …..?
m
Penyelesaian :
mmol CH3COOH = (M × V) CH3COOH
= 0,2500 mmol/mL × 100 mL
= 20 mmol
mmol NaOH = (M × V) NaOH
= 0,1 mmol/mL × 21,3 mL
= 2,13 mmol
Reaksi : CH3COOH + NaOH → CH3COONa + H2O
Mula – mula : 25 mL 2,13 mmol - -
Bereaksi : 2,13 mmol 2,13 mmol 2,13 mmol 2,13
mmol
Setimbang : 22,87 mmol - 2,13 mmol 2,13
mmol
mmol CH3COOH yang teradsorpsi = mmol CH3COOH - mmol NaOH
= 22,87 mmol – 2,13 mmol
= 20,74 mmol
Massa CH3COOH yang teradsorpsi = mmol CH3COOH yang teradsorpsi × Mr
= 20,74 mmol × 60 mg/mmol
= 1.244,4 mg
= 1,2444 gram
x massa yang teradsorpsi
=
m massa arang
1,2444 gram
=
1,0158 gram
= 1,2250
x
log = log 1,2250
m
= 0,0881
mmolCH 3COOH yang teradsorpsi
C =
V CH 3COOH
20,74 mmol
=
10mL
= 2,074 M
log C = log 2,074
= 0,3168 M
3. Erlenmeyer 3
Dik : [CH3COOH] = 0,1250 M
Mr CH3COOH = 60 g/mol = 60 mg/mol
V CH3COOH = 100 mL
[NaOH] = 0,1 M
 V NaOH = 24 mL
W arang = 1,0041 gram
V CH3COOH = 25 mL (filtrat)
x
Dit : log C dan log …..?
m
Penyelesaian :
mmol CH3COOH = (M × V) CH3COOH
= 0,1250 mmol/mL × 100 mL
= 12,5 mmol
mmol NaOH = (M × V) NaOH
= 0,1 mmol/mL × 24 mL
= 2,4 mmol
Reaksi : CH3COOH + NaOH → CH3COONa + H2O
Mula – mula : 12,5 mL 2,4 mmol - -
Bereaksi : 2,4 mmol 2,4 mmol 2,4 mmol 2,4 mmol
Setimbang : 10,1 mmol - 2,4 mmol 2,4 mmol
mmol CH3COOH yang teradsorpsi = mmol CH3COOH - mmol NaOH
= 10,1 mmol – 2,4 mmol
= 7,7 mmol
Massa CH3COOH yang teradsorpsi = mmol CH3COOH yang teradsorpsi × Mr
= 7,7 mmol × 60 mg/mmol
= 462 mg
= 0,462 gram
x massa yang teradsorpsi
=
m massa arang
0,462 gram
=
1,0041 gram
= 0,4601
x
log = log 0,4601
m
= -0,3371
 mmolCH 3COOH yang teradsorpsi
C =
V CH 3COOH
7,7 mmol
=
25 mL
= 0,308 M
log C = log 0,308
= -0,5114 M
4. Erlenmeyer 4
Dik : [CH3COOH] = 0,0625 M
Mr CH3COOH = 60 g/mol = 60 mg/mol
V CH3COOH = 100 mL
[NaOH] = 0,1 M
V NaOH = 20,4 mL
W arang = 1,0200 gram
V CH3COOH = 50 mL (filtrat)
x
Dit : log C dan log …..?
m
Penyelesaian :
mmol CH3COOH = (M × V) CH3COOH
= 0,0625 mmol/mL × 100 mL
= 6,25 mmol
mmol NaOH = (M × V) NaOH
= 0,1 mmol/mL × 20,4 mL
= 2,04 mmol
Reaksi : CH3COOH + NaOH → CH3COONa + H2O
Mula – mula : 6,25 mL 2,04 mmol - -
Bereaksi : 2,04 mmol 2,04 mmol 2,04 mmol 2,04
mmol
Setimbang : 4,21 mmol - 2,04 mmol 2,04
mmol
mmol CH3COOH yang teradsorpsi = mmol CH3COOH - mmol NaOH
= 4,21 mmol – 2,04 mmol
 = 2,17 mmol
Massa CH3COOH yang teradsorpsi = mmol CH3COOH yang teradsorpsi × Mr
= 2,17 mmol × 60 mg/mmol
= 130,2 mg
= 0,1302 gram
x massa yang teradsorpsi
=
m massa arang
0,1302 gram
=
1,0200 gram
= 0,1276
x
log = log 0,1276
m
= -0,894
mmolCH 3COOH yang teradsorpsi
C =
V CH 3COOH
2,17 mmol
=
50 mL
= 0,0434 M
log C = log 0,0434
= -1,3625 M
5. Erlenmeyer 5
Dik : [CH3COOH] = 0,0313 M
Mr CH3COOH = 60 g/mol = 60 mg/mol
V CH3COOH = 100 mL
[NaOH] = 0,1 M
V NaOH = 5,6 mL
W arang = 1,0081 gram
V CH3COOH = 50 mL (filtrat)
x
Dit : log C dan log …..?
m
Penyelesaian :
mmol CH3COOH = (M × V) CH3COOH
= 0,0313 mmol/mL × 100 mL
 = 3,13 mmol
mmol NaOH = (M × V) NaOH
= 0,1 mmol/mL × 5,6 mL
= 0,56 mmol
Reaksi : CH3COOH + NaOH → CH3COONa + H2O
Mula – mula : 3,13 mL 0,56 mmol - -
Bereaksi : 0,56 mmol 0,56 mmol 0,56 mmol 0,56
mmol
Setimbang : 2,57 mmol - 0,56 mmol 0,56
mmol
mmol CH3COOH yang teradsorpsi = mmol CH3COOH - mmol NaOH
= 2,57 mmol – 0,56 mmol
= 2,01 mmol
Massa CH3COOH yang teradsorpsi = mmol CH3COOH yang teradsorpsi × Mr
= 2,01 mmol × 60 mg/mmol
= 120,6 mg
= 0,1206 gram
x massa yang teradsorpsi
=
m massa arang
0,1206 gram
=
1,0081 gram
= 0,1196
x
log = log 0,1196
m
= -0,9222
mmolCH 3COOH yang teradsorpsi
C =
V CH 3COOH
2,01mmol
=
50 mL
= 0,0402 M
log C = log 0,0402
= -1,3957 M
6. Erlenmeyer 6
Dik : [CH3COOH] = 0,0156 M
Mr CH3COOH = 60 g/mol = 60 mg/mol
V CH3COOH = 100 mL
[NaOH] = 0,1 M
V NaOH = 1 mL
W arang = 1,0151 gram
V CH3COOH = 50 mL (filtrat)
x
Dit : log C dan log …..?
m
Penyelesaian :
mmol CH3COOH = (M × V) CH3COOH
= 0,0156 mmol/mL × 100 mL
= 1,56 mmol
mmol NaOH = (M × V) NaOH
= 0,1 mmol/mL × 1 mL
= 0,1 mmol
Reaksi : CH3COOH + NaOH → CH3COONa + H2O
Mula – mula : 1,56 mL 0,1 mmol - -
Bereaksi : 0,1 mmol 0,1 mmol 0,1 mmol 0,1 mmol
Setimbang : 1,46 mmol - 0,1 mmol 0,1 mmol
mmol CH3COOH yang teradsorpsi = mmol CH3COOH - mmol NaOH
= 1,46 mmol – 0,1 mmol
= 1,36 mmol
Massa CH3COOH yang teradsorpsi = mmol CH3COOH yang teradsorpsi × Mr
= 1,36 mmol × 60 mg/mmol
= 81,6 mg
= 0,0816 gram
x massa yang teradsorpsi
=
m massa arang
0,0816 gram
=
1,0151 gram
 = 0,0803
x
log = log 0,0803
m
= -1,0952
mmolCH 3COOH yang teradsorpsi
C =
V CH 3COOH
1,36 mmol
=
50 mL
= 0,0272 M
log C = log 0,0272
= -1,5654 M

No [CH3COOH] x C (M) x log C (M)

. log
m m
.
1. 0,5000 M 2,4494 4,084 0,3890 0,6110
2. 0,2500 M 1,2250 2,074 0,0881 0,3168
3. 0,1250 M 0,4601 0,308 -0,3371 -0,5114
4. 0,0625 M 0,1276 0,0434 -0,894 -1,3625
5. 0,0313 M 0,1196 0,0402 -0,9222 -1,3957
6. 0,0156 M 0,0801 0,0272 -1,0952 -1,5654
Grafik hubungan antara x/m terhadap c
Persamaan garis pada grafik G.1
Dik : y = 0,5629 x + 0,1267
y = ax + b
Dit : k….?
n….?
Penyelesaian :
log k =b
b = log k
k = anti log 0,1267
= 1,3387
1
a =
n
 1
n =
0,5259
n = 1,7765
x
Grafik hubungan antara log terhadap C
m
Persamaan garis pada grafik G.2
Dik : y = 0,6417 x + 0,044
y = ax + b
Dit : k….?
n….?
Penyelesaian :
log k =b
b = log k
k = anti log 0,044
= 0,9036
1
a =
n
1
n =
0,6417
n = 1,5583