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Safety Data Sheet

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1 Identification
· Product identifier
· Trade name: BINSOV HI-087
· Application of the substance / the mixture Hardener for flooring applications
· Details of the supplier of the safety data sheet
· Manufacturer/Supplier:

· Information department:
· Emergency telephone number:

2 Hazard(s) identification
· Classification of the substance or mixture

GHS08 Health hazard

Repr. 1 H360 May damage fertility or the unborn child.

GHS05 Corrosion

Skin Corr. 1B H314 Causes severe skin burns and eye damage.
Eye Dam. 1 H318 Causes serious eye damage.

GHS09 Environment

Aquatic Chronic 2 H411 Toxic to aquatic life with long lasting effects.

GHS07

Acute Tox. 4 H302 Harmful if swallowed.

Acute Tox. 4 H312 Harmful in contact with skin.
Skin Sens. 1 H317 May cause an allergic skin reaction.
· Label elements
· GHS label elements
The product is classified and labeled according to the Globally Harmonized System (GHS).
· Hazard pictograms

GHS05 GHS07 GHS08 GHS09

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· Signal word Danger
· Hazard statements
H302+H312 Harmful if swallowed or in contact with skin.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H360 May damage fertility or the unborn child.
H411 Toxic to aquatic life with long lasting effects.
· Precautionary statements
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P260 Do not breathe dusts or mists.
P264 W ash thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P272 Contaminated work clothing must not be allowed out of the workplace.
P273 Avoid release to the env ironment.
P280 W ear protective gloves/protective clothing/eye protection/face protection.
P301+P312 If swallowed: Call a poison center/doctor if you feel unwell.
P301+P330+P331 If swallowed: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353 If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with
water/shower.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remov e contact lenses, if
present and easy to do. Continue rinsing.
P308+P313 IF exposed or concerned: Get medical advice/attention.
P310 Immediately call a poison center/doctor.
P321 Specific treatment (see on this label).
P333+P313 If skin irritation or rash occurs: Get medical advice/attention.
P362+P364 Take off contaminated clothing and wash it before reuse.
P363 W ash contaminated clothing before reuse.
P391 Collect spillage.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
· Classification system:
· NFPA ratings (scale 0 - 4)
Health = 3
1
3 0 Fire = 1
Reactivity = 0
· HMIS-ratings (scale 0 - 4)
HEALTH *3
Health = *3
FIRE 1
REACTIVITY 0
Fire = 1
Reactivity = 0
· Other hazards
· Results of PBT and vPvB assessment Not applicable.
· PBT: Not applicable.
· vPvB: Not applicable.
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3 Composition/information on ingredients
· Chemical characterization: Mixtures
· Description: Mixture: consisting of the following components.
· Components:
CAS: 9046-10-0 Poly(oxy(methyl-1,2-ethanediyl)), alpha-(2-aminomethylethyl) 50-70%
omega-(2-aminomethylethoxy)-
Skin Corr. 1C, H314; Aquatic Chronic 3, H412
CAS: 84852-15-3 4-nonylphenol, branched 10-30%
Repr. 2, H361; Skin Corr. 1B, H314; Aquatic Chronic 1,
H410; Acute Tox. 4, H302
CAS: 80-05-7 4,4'-isopropylidenediphenol 10-30%
Reg.nr.: 01-2119457856-23-0022 Repr. 1A, H360; Eye Dam. 1, H318; Aquatic Chronic 2,
H411; Skin Sens. 1, H317; STOT SE 3, H335
CAS: 140-31-8 2-piperazin-1-ylethylamine <5%
Skin Corr. 1B, H314; Acute Tox. 4, H302; Acute Tox. 4,
H312; Skin Sens. 1, H317; Aquatic Chronic 3, H412

4 First-aid measures
· Description of first aid measures
· General information:
Immediately remove any clothing soiled by the product.
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48
hours after the accident.
· After inhalation:
Supply fresh air and to be sure call for a doctor.
In case of unconsciousness place patient stably in side position for transportation.
Supply fresh air; consult doctor in case of complaints.
· After skin contact: Immediately wash with water and soap and rinse thoroughly.
· After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor.
· After swallowing:
Immediately call a doctor.
Drink copious amounts of water and provide fresh air. Immediately call a doctor.
· Information for doctor:
· Most important symptoms and effects, both acute and delayed
No further relevant information available.
· Indication of any immediate medical attention and special treatment needed
No further relevant information available.

5 Fire-fighting measures
· Extinguishing media
· Suitable extinguishing agents:
CO2, extinguishing powder or water spray. Fight larger fires with water spray.
Use fire fighting measures that suit the environment.
· For safety reasons unsuitable extinguishing agents: Water with full jet
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· Special hazards arising from the substance or mixture No further relevant information available.
· Advice for firefighters
· Protective equipment: Wear self-contained respiratory protective device.

6 Accidental release measures

· Personal precautions, protective equipment and emergency procedures
Wear protectiv e equipment. Keep unprotected persons away.
· Environmental precautions:
Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to enter sewers/ surface or ground water.
· Methods and material for containment and cleaning up:
Use neutralizing agent.
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
· Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
· Protective Action Criteria for Chemicals
· PAC-1:
9046-10-0 P ol y (ox y (m et hy l -1, 2-et hanedi yl )) , al pha-( 2- am i nomet hyl eth y l )om ega-(2- 4.8 mg/m³
aminomethylethoxy)-
84852-15-3 4-nonylphenol, branched 3.9 mg/m³
80-05-7 4,4'-isopropylidenediphenol 15 mg/m³
140-31-8 2-piperazin-1-ylethylamine 6.4 mg/m³
· PAC-2:
9046-10-0 P ol y( ox y (m et hy l- 1,2- ethanedi yl )) , al pha- (2-am i nomet hyl ethy l )om ega- (2- 53 mg/m³
aminomethylethoxy)-
84852-15-3 4-nonylphenol, branched 43 mg/m³
80-05-7 4,4'-isopropylidenediphenol 110 mg/m³
140-31-8 2-piperazin-1-ylethylamine 71 mg/m³
· PAC-3:
9046-10-0 P ol y( ox y (m et hy l- 1,2- ethanedi yl )) , al pha- (2-am i nomet hyl ethy l )om ega- (2- 320 mg/m³
aminomethylethoxy)-
84852-15-3 4-nonylphenol, branched 260 mg/m³
80-05-7 4,4'-isopropylidenediphenol 650 mg/m³
140-31-8 2-piperazin-1-ylethylamine 420 mg/m³

7 Handling and storage

· Handling:
· Precautions for safe handling Ensure good ventilation/exhaustion at the workplace.
· Information about protection against explosions and fires: Keep ignition sources away - Do not smoke.
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· Conditions for safe storage, including any incompatibilities

· Storage:
· Requirements to be met by storerooms and receptacles: Store in a cool location.
· Information about storage in one common storage facility:
Do not store together with oxidizing and acidic materials as well as heavy-metal compounds.
· Further information about storage conditions:
Keep receptacle tightly sealed.
Store receptacle in a well ventilated area.
· Specific end use(s) No further relevant information available.

8 Exposure controls/personal protection

· Additional information about design of technical systems: No further data; see item 7.
· Control parameters
· Components with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of m aterials with critical v alues that hav e to be
monitored at the workplace.
· Additional information: The lists that were valid during the creation were used as basis.
· Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Av oid contact with the eyes.
Av oid contact with the eyes and skin.
· Breathing equipment: Use suitable respiratory protective device in case of insufficient ventilation.
· Protection of hands:

Protective gloves

The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due t o missing test s no recomm endation to the glov e m aterial c an be gi v en f or t he produc t/ t he
preparation/ the chemical mixture.
Selection of the gl ove mat erial on considerat ion of the penetrati on t imes, rat es of dif fusion and the
degradation
· Material of gloves
The selection of the suitable glov es does not only depend on the material, but also on further marks of
quali ty and v aries f rom m anufact urer to m anuf actur er. As t he product is a preparation of sev eral
substances, the resistance of the glove material can not be calculated in advance and has therefore to be
checked prior to the application.
· Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective glov es and has to
be observed.
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· Eye protection:
Safety glasses

Tightly sealed goggles

· Body protection: Protective work clothing

9 Physical and chemical properties

· Information on basic physical
· General Information
· Appearance:
Form:
Color:
· Odor:
· Change in condition
Boiling point/Boiling range: Undetermined.
· Flash point:
· Auto igniting:
· Danger of explosion:
· Density at 25 °C (77 °F):
· Solubility in / Miscibility with
Water:
· Other information
and chemical properties
Liquid
Light yellow
Amine-like
Undetermined
Product is not selfigniting.
Product does not present an explosion hazard.
0.989 g/cm³ (8.25321 lbs/gal)
Practically Insoluble
No further relevant information available.

10 Stability and reactivity

· Reactivity No further relevant information available.
· Chemical stability
· Thermal decomposition / conditions to be avoided:
No decomposition if used and stored according to specifications.
· Possibility of hazardous reactions Reacts with alcohols, amines, aqueous acids and alkalis.
· Conditions to avoid No further relevant information available.
· Incompatible materials: Acids, bases, amines and oxidizing agent.
· Hazardous decomposition products: Carbon monoxide and carbon dioxide

11 Toxicological information
· Information on toxicological effects
· Acute toxicity:
· LD/LC50 values that are relevant for classification:
Acute dermal toxicity: LD50, rat, intravenous, 115 mg/kg
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80-05-7 4,4'-isopropylidenediphenol
Oral LD50 3,250 mg/kg (rat)
Dermal LD50 3,000 mg/kg (rabbit)
· Primary irritant effect:
· on the skin: Caustic effect on skin and mucous membranes.
· on the eye:
Strong caustic effect.
Strong irritant with the danger of severe eye injury.
Irritating effect.
· Sensitization: Sensitization possible through skin contact.
· Additional toxicological information:
The pr oduct shows the foll owing dangers according to internally approv ed calculation m ethods for
preparations:
Harmful
Corrosive
Irritant
Swallowing will lead to a strong caustic effect on mouth and throat and to the danger of perforation of
esophagus and stomach.
· Carcinogenic categories
· IARC (International Agency for Research on Cancer)
None of the ingredients is listed.
· NTP (National Toxicology Program)
None of the ingredients is listed.
· OSHA-Ca (Occupational Safety & Health Administration)
Not applicable

12 Ecological information
· Toxicity
· Aquatic toxicity: No further relevant information available.
· Persistence and degradability No further relevant information available.
· Behavior in environmental systems:
· Bioaccumulative potential No further relevant information available.
· Mobility in soil No further relevant information available.
· Ecotoxical effects:
· Remark: Toxic for fish
· Additional ecological information:
· General notes:
Water hazard class 3 (Self-assessment): extremely hazardous for water
Do not allow product to reach ground water, water course or sewage system, even in small quantities.
Must not reach bodies of water or drainage ditch undiluted or unneutralized.
Danger to drinking water if even extremely small quantities leak into the ground.
Also poisonous for fish and plankton in water bodies.
Toxic for aquatic organisms
· Results of PBT and vPvB assessment Not applicable.
· PBT: Not applicable.
· vPvB: Not applicable.
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· Other adverse effects No further relevant information available.

13 Disposal considerations
· Waste treatment methods
· Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
· Uncleaned packagings:
· Recommendation: Disposal must be made according to official regulations.

14 Transport information
· UN-Number
· DOT, ADR/RID/ADN, IMDG, IATA UN2735
· UN proper shipping name
· DOT Ami nes, l iqui d, cor rosi v e, n.o. s. (P oly( ox y(m et hyl-1, 2-
et han e di y l ) ) , a l ph a - (2 - am i n om et hy l e t h y l ) om e ga -( 2 -
aminomethylethoxy)-, N-Aminoethylpiperazine)
· ADR/RID/ADN UN2735 Amines, liquid, corrosiv e, n.o.s. (Poly(oxy(methyl-
1,2-ethanediyl )) , al pha-(2-am inomet hyl ethyl) omega- (2-
am i n o me th yl e t ho xy )-, N -A m i n oe t hyl pi p er azi ne ),
ENVIRONMENTALLY HAZARDOUS
· IMDG AMINES, LIQUID, CORROSIVE, N.O.S. (Poly(oxy(methyl-
1,2-ethanediyl )) , al pha-(2-am inomet hyl ethyl) omega- (2-
am i nom et hy let hox y ) -, N- A M INO ETH Y LPIP E RAZ INE ),
MARINE POLLUTANT
· IATA AMINES, LIQUID, CORROSIVE, N.O.S. (Poly(oxy(methyl-
1,2-ethanediyl )) , al pha-(2-am inomet hyl ethyl) omega- (2-
aminomethylethoxy)-, N-AMINOETHYLPIPERAZINE)
· Transport hazard class(es)
· DOT, ADR/RID/ADN, IMDG, IATA
· Class 8 Corrosive substances
· Label 8
· Packing group
· DOT, ADR/RID/ADN, IMDG, IATA II
· Environmental hazards:
· Marine pollutant: Yes (DOT)
· Special precautions for user Warning: Corrosive substances
· Danger code (Kemler): 80
· EMS Number: F-A,S-B
· Segregation groups Alkalis
· Segregation Code SG35 Stow "separated from" acids.
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· Transport in bulk according to Annex II of

MARPOL73/78 and the IBC Code Not applicable.

15 Regulatory information
· Safety, health and environmental regulations/legislation specific for the substance or mixture
· Sara
· Section 313 (Specific toxic chemical listings):
84852-15-3 4-nonylphenol, branched
80-05-7 4,4'-isopropylidenediphenol
· TSCA (Toxic Substances Control Act):
All ingredients are listed.
· GHS label elements
The product is classified and labeled according to the Globally Harmonized System (GHS).
· Hazard pictograms

GHS05 GHS07 GHS08 GHS09

· Signal word Danger

· Hazard statements
H302+H312 Harmful if swallowed or in contact with skin.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H360 May damage fertility or the unborn child.
H411 Toxic to aquatic life with long lasting effects.
· Precautionary statements
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P260 Do not breathe dusts or mists.
P264 W ash thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P272 Contaminated work clothing must not be allowed out of the workplace.
P273 Avoid release to the env ironment.
P280 W ear protective gloves/protective clothing/eye protection/face protection.
P301+P312 If swallowed: Call a poison center/doctor if you feel unwell.
P301+P330+P331 If swallowed: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353 If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with
water/shower.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remov e contact lenses, if
present and easy to do. Continue rinsing.
P308+P313 IF exposed or concerned: Get medical advice/attention.
P310 Immediately call a poison center/doctor.
P321 Specific treatment (see on this label).
P333+P313 If skin irritation or rash occurs: Get medical advice/attention.
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P362+P364 Take off contaminated clothing and wash it before reuse.
P363 W ash contaminated clothing before reuse.
P391 Collect spillage.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
· Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
· Contact: E-mail :
· Date of preparation / last revision 09/19/2018 / -
· Abbreviations and acronyms:
ADR: Ac cord européen sur le tr ans port des marchandises Dangereuses par Route (European Agreement concerning the International
Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit REL:
Recommended Exposure Limit Acute
Tox. 4: Acute toxicity – Category 4
Skin Corr. 1B: Skin corrosion/irritation – Category 1B
Skin Corr. 1C: Skin corrosion/irritation – Category 1C
Eye Dam. 1: Serious eye damage/eye irritation – Category 1
Skin Sens. 1: Skin sensitisation – Category 1
Repr. 1: Reproductive toxicity – Category 1
Repr. 1A: Reproductive toxicity – Category 1A
Repr. 2: Reproductive toxicity – Category 2
STOT SE 3: Specific target organ toxicity (single exposure) – Category 3
Aquatic Chronic 1: Hazardous to the aquatic environment - long-term aquatic hazard – Category 1
Aquatic Chronic 2: Hazardous to the aquatic environment - long-term aquatic hazard – Category 2
Aquatic Chronic 3: Hazardous to the aquatic environment - long-term aquatic hazard – Category 3
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