Unitwise Evaluation and Additional One Mark Questions With Answer Key

l l l l l
a daadsaasa a daadsaasa a daadsaasa a daadsaasa a daadsaasa

p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
t t t t t t t t t t
a l a il.ani.ene a l a il.ani.ene a l a il.ani.ene a l a il.ani.ene a l a il.ani.ene
adsa s adsa s adsa s adsa s adsa s
w .wp.apda w .wp.apda w .wp.apda w .wp.apda w .wp.apda w
ww ww ww ww ww ww
etet etet etet etet etet

s asl ail.ani.n s asl ail.ani.n s asl ail.ani.n s asl ail.ani.n s asl ail.ani.n
ada ada ada ada ada
w .wp.apda w .wp.apda w.wp.apda w .wp.apda w .wp.apda w
ww ww ww ww ww ww
t t t t t
l a i
l .ani.ente l a i
l.ani.ente l ail.ani.ente l ail.ani.ente l a i
l .ani.ente
sas sas sas sas sas
.
w p.apdaada .
w p.apdaada .
w p.apdaada .wpapdaada
. .
w p.apdaada
w w w w w w
ww ww ww ww ww ww
t t t t t t t t t t
a l a il.ani.ene a l ail.ani.ene a l a il.ani.ene a l a il.ani.ene a l a il.ani.ene
adsas adsas adsas adsas adsas
ww ww ww ww ww ww
t t t t
UNITWISE t t t t t t
a l ail.ani.ene a l a il.ani.ene a l a il.ani.ene a l a il.ani.ene a l a il.ani.ene
adsa s adsa s adsas adsa s adsa s
w.wp.apda w .wp.apda .p.apda
ww .p.apda ww w .wp.apda w
ww ww ww ww ww ww
EVALUATION
etet
ail.ani.n
etet
ail.ani.n
and ail.ani.n
eteADDITIONAL
t etet
ail.ani.n ail.ani.n
etet
Padasalai.Net
s asl s asl s asl s asl s asl
ada ada ada ada ada
.wp.apda .wp.apda .wp.apda .wp.apda .wp.apda
ww
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ONE ww
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MARK ww QUESTIONS
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ww
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withww
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sas ANSWER KEY

t t t t t
l ail.ani.ente l a i
l.ani.ente l a i
l .ani.ente l ail.ani.ente l a i
l .ani.ente
sas sas sas sas
.
wp.apdaada .wp.apdaada .wp.apdaada .wp.apdaada . wp.apdaada
w w w w w w
ww ww ww ww ww ww
t t t t t t t t t t
a la il.ani.ene a l a il.ani.ene a la il.ani.ene a l a il.ani.ene a l a il.ani.ene
w .wp.apda w .wp.apda w.wp.apda w.wp.apda w .wp.apda w
ww ww ww ww ww ww
t t t t t t t t t t
a l a il.ani.ene a l a il.ani.ene a la il.ani.ene a l a il.ani.ene a l a il.ani.ene
adsa s adsas adsa s adsa s adsa s
w.wp.apda w .wp.apda w.wp.apda w .wp.apda w .wp.apda w
ww ww ww ww ww ww

s asl ail.ani.n s aslail.ani.n s asl ail.ani.n s aslail.ani.n s asl ail.ani.n
ada ada ada ada ada
w.wp.apda w .wp.apda w .wp.apda w .wp.apda w.wp.apda w
ww ww ww ww ww ww
t t t t t
l a i
l.ani.ente l a i
l .ani.ente l a i
l .ani.ente
sas sas sas sas sas
.
w p.apdaada .
wp.apdaada .
w papdaada
. .
w p.apdaada .
w p.apdaada
w w w w w w
ww ww ww ww ww ww
1
t t t t t t t t t t
a l ail.ani.ene a l ail.ani.ene a l a il.ani.ene a l a il.ani.ene a l a il.ani.ene
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
t t t t etet t t t t
a l a il.ani.ene a l a il.ani.ene lail.ani.
CONTENTS n
l a il.ani.ene l a il.ani.ene
adsa s adsa s
adad asaas a
adsa s a
adsa s
w .wp.apda w .wp.apda w.wp.p w .wp.apda w .wp.apda w
ww ww w w ww ww ww

aada
.wp.apdSN .wp.apda
ada
.wp.apda
ada
.wp.apda
ada ada
.wp.apdaNO
w w TOPIC
w w PAGE
w w
ww ww ww ww ww ww
t t t t t
l a i
l .ani.ente l a i
l .ani.ente
1 sas Metallurgy sas sas sas 3 sas
.
w p.apdaada .
w p.apdaada .
. .
w p.apdaada
w w w w w w
ww ww ww ww ww ww
t t t t t t t t t t
2
a l a il.ani.ene Elements-I alail.ani.ene
p-Block
a l a il.ani.ene a l a il.ani.ene 7
a l a il.ani.ene
ww ww ww ww ww ww
3 p-Block Elements - II 11
t t t t t t t t t t
w.wp.apda w .wp.apda w.wp.apda w.wp.apda w .wp.apda w
ww ww ww ww ww 15 ww
4 Transition and Inner Transition Elements
ail.ani.n ail.ani.n ail.ani.n ail.ani.n ail.ani.n
Padasalai.Net
aa aa ada ada aa
w pdad
.wp.a5 w p.apdad
.w w .wp.apda w .wp.apda w .apdad
.wp19 w
ww Coordination
ww Chemistry ww ww ww ww
t t t t t
l.ani.ente l a i
l .ani.ente
a a sas sas sas
.p.a6
pdaadsas Solid State .p.apdaadsas . p.apdaada . p.apdaada . p.apdaada
23
w w w w w w w w w w w
ww ww ww ww ww ww
t t Kinetics lail.ani.ente
t t t t t t t
7
a la il.ani.ene
Chemical
a a la il.ani.ene a l a il.ani.ene 27
a l a il.ani.ene
ww ww ww ww ww ww
t t t t t t t t t t
ww ww ww ww ww ww

ada ada ada ada ada
ww ww ww ww ww ww
t t t t t
l a i
l.ani.ente l a i
l .ani.ente l a i
l .ani.ente
sas sas sas sas sas
.
w p.apdaada .
wp.apdaada .
w papdaada
. .
w p.apdaada .
w p.apdaada
w w w w w w
ww ww ww ww ww ww
2
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
t t t t tet t t t t
il.ani.ene il.ani.ene i.ani.en
1. METALLURGY il.ani.ene il.ani.ene
a
adsa sl a a
adsa sl a saaslal
ad a
adsa sl a a
adsa sl a
ww ww ww ww ww ww
Choose the correct answer:
t t.ni.ene .ni.ene t t etet etet etet
1. Bauxite
s aslaila has the composition
aslaila s s asl ail.ani.n s asl ail.ani.n s asl ail.ani.n
ada ada ada aa aa
w .wp.apda a) Al O w pdad
.wp.apda b) Al O .nH O w.wp.apdac) Fe O .2H O w.wp.ad)None w .
w p.apdad w
ww 2 3 ww 2 3 2ww 2 3 2 ww of theseww ww
2. Roasting of sulphide ore gives the gas (A).(A) is a colourless gas. Aqueous solution of (A)
t t t t t
l a i
l .ani.ente l a i
l .ani.ente
saas The gas (A) aisdaadsaas sas sas sas
apdaisadacidic. apdaada apdaada apdaada
w .
w p. w.wp.p w .
w p. w.wp. w .
w p. w
ww a)CO2 ww b)SO3 ww c)SO2 ww d)H2S ww ww
3. Which t of the followingn.ereaction

tone t t t
represents icalcinations? t t t t
i.ni.ene
a a i. i ne .ni.ente a il.ani.ene il.ani.ene
dadsaaslal d a
dsaaslal a
adsas
l a l a
adsas
l a a
adsas
l a
a a a) 2Zn + O2 → 2ZnO
w.wp.p
aa
w.wp.p .wp.apda + 3O2 → 2ZnO +w2SO
b)w2ZnS .wp.apd2a w .wp.apda w
ww ww ww ww ww ww
c) MgCO3 → MgO + CO2 d) Both (a) and (c)
.n etet etet etet etet t t
il.ani.ene
slail.animetal
4.saThe oxide which sas ail.ani.n be reduced to
lcannot s ametal
s
n
lail.ani. by carbon is saaslail.ani.
n
a sl a
a
adad a a
adad a a
adad a a
apdad adsa
w.wp.p w.wp.p b) Al O w.wp.p c) ZnO w.wp.d) w .wp.apda w
w w a) PbO w w 2 3 w w w w FeO ww ww
5. Whicht of
t the metal is extracted
t t
by Hall-Herold process?
t t
ee ee ee etet etet
Padasalai.Net
ada a) Al a Ni
adb) adaCu
c) da
d)aZn ada
w.wp.apda w .wp.apda w .wp.apda w .wp.apda w .wp.apda w
ww ww ww ww ww ww
6. Which of the following statements, about the advantage of roasting of sulphide ore before
reduction t t .ani.ente
t
.ani.ente
t
.ani.ente
t
.ani.ente
t
l i.ani.eneis not true?
a l l a i
l l a i
l l ail l a i
l
sas adsaas sas sas sas
.
wp.apdaada a) ΔGfo of sulphide
.
w p.apdais greater than those
.
w p. aadaCS and H S . .p.apdaada
apdfor w .wp.apdaada
w w w 2 2 w w w
ww ww ww ww ww ww
b) ΔGro is negative for roasting of sulphide ore to oxide
t t t t t t t t t
c)
la .ani.ente
ilRoasting of the sulphide
l a il.ani.entoe its oxide is thermodynamically
la il.ani.ene feasible. l a il.ani.ene l a il.ani.ene
a
adsas a
adsas a
adsas a
adsas a
adsas
ww d) Carbon and ww hydrogen are suitable ww reducing agents for wwmetal sulphides ww ww
7.Matchteitems
t in column - I with
tet the items of columnte–t II and assign the correct
tet code t t
a
en
lail.ani. a
en
lail.ani. a
en
lail.ani. a
en
lail.ani. a l a il.ani.ene
a s
a s asa s a s
a s a s
a s C adsa Ds
adad Column – I adad Columnadad– 2 adad A B
.wp.apda
w w.wp.p w w.wp.p w w.wp.p w w.wp.p w w
w w w w ww ww
A Cyanide process (i) Ultrapure Ge a) (i) (ii) (iii) (iv)
t t etet ntet t
.ani.ente (iv) (v) (i)ail.ani.entet
a l il.ani.ene flotation process
BaFroth
a lail.ani.n il.ani.eZnS
(ii) Dressingaof
a l a
b)
a lail(iii) l
s
ada s s
ada s s
ada s s
ada s adsaas
w.wp.apda C Electrolytic w .wp.apda
refining (iii) a
.pda
w.wpExtraction
apd
of Al ww.wp.c)
a
(iv) (ii) ww.w a
p.p d
(iii)
a
(i) w
ww ww ww w w ww
D Zone refining (iv) Extraction of Au d) (ii) (iii) (i) (v)
t t t t t
l a i
l.ani.ente l a i
l .ani.ente l a i
l .ani.ente
sas sas (v) Purification
sas of Ni sas sas
.
w p.apdaada .
wp.apdaada .
w papdaada
. .
w p.apdaada .
w p.apdaada
w w w w w w
ww ww ww ww ww ww
3
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
t t
.ni.ene .ni.ene t t ene t t t t t t
8. Wolframite
aslaila ore is separated ail.ani.process
aslaila from tinstone byaslthe of a l a il.ani.ene a l a il.ani.ene
adsa adsa adsa asa s asa s
w .wp.apda a) Smelting w.wp.apda b) Calcination w.wp.apdac) Roasting w pdad
.wp.ad) w .
w p.apdad w
ww ww ww ww Electromagnetic ww separation ww
9. Which one of the following is not feasible
asl ail.ani.n 2+ asl ail.ani.n 2+ asl ail.ani.n 2+ asl ail.ani.n 2+ asl ail.ani.n
ada a) Zn(s) + Cu (aq)ad→
s adaCu(s) + Zn (aq) adaada
s s b) Cu(s) + Zn a(aq) ada→ Zn(s) + Cu (aq)
s s
ada
w .wp.apda w .wp.pa w.wp.p w .wp.pda w .wp.apda w
ww ww +
c) Cu(s) + 2Ag (aq) →Ag(s) + Cu (aq) 2+ww ww 2+ w
w2+
d) Fe(s) + Cu (aq) →Cu(s) + Fe (aq) ww
t t
10. Electrochemical tet to extract
processi.nisi.enused .ani.ente
t
.ani.ente
t
.ani.ente
t
i.ni.ene
lala lala l ail l ail l a i
l
a daadsaas a daadsaas adsaas
apdac) ad) dsaas
daasilver sas
apdaada
w.wp. p a) Iron w.wp.p b) Lead w .
w p. Sodium w.wp. p w .
w p. w
ww ww ww ww ww ww
11. Flux is a substance which is used to convert
t t t et t t t
a)
l a .ani.ente
ilMineral into silicate l ail.ani.ene l a i.entInfusible
il.anb) impurities l a i.entesoluble impurities
il.anto l a il.ani.ene
a
adsas a
adsas a
adsas a
adsas a
adsas
ww ww
c) Soluble impurities to infusible w w
impurities w
d) All ofwthese ww ww
12. Which
t t
one of the followingt ores
t is best concentrated
t t
by froth – floatation
t t
method? t t
s
adsa a) Magnetite adsb)s
a Hematite s
adsaGalena
c) dsa s
d)aCassiterite adsa s
ww ww ww ww ww ww
13. In the extraction of aluminium from alumina by electrolysis, cryolite is added to
a) iLoweretet the melting point tetalumina
eof t
b)eteRemove impuritiesi.anfrom etet alumina etet
al.ani.n ail.ani.n ail.ani.n al i.n ail.ani.n
Padasalai.Net
ada aa ada ada ada
w.wp.apda c) Decrease the w .apdad
.wpelectrical conductivityw .wp.apda d) Increase
w .wp.apdarate of reductionw.wp.apda
the w
ww ww ww ww ww ww
14. Zinc is obtained from ZnO by
entet
.ani. entet entet .ani.ente
t
.ani.ente
t
lailCarbon
saasa) reduction saaslail.ani. b) Reduction i.ani.
saaslal using silver sasl ail sasl a i
l
adaad .wp.apda
ad
.wp.apda
ad apdaada apdaada
w w.wp.p w w w w w .
w p. w.wp. w
w c) Electrochemical
w process wd) Acid leaching ww ww ww
15. Extraction
tet of gold and silverteinvolves
t leaching with
tetcyanide ion. silver is tlater
et
recovered By t t
a
en
lail.ani. a
en
lail.ani. a la il.ani.en a l a il.ani.en a l a il.ani.ene
s
a s s
a s adsas with zincp.apdaadsas d) liquation p.apdaadsas
adaad a) Distillation b).wpZone
adaad refining c) Displacement
.wp.apda
w w.wp.p w w .p w w.w w.w w
w w ww ww ww ww
16. Considering Ellingham diagram, which of the following metals can be used to reduce
t t t t t t t t t t
a l il.ani.ene
alumina?
a a) Fe
a l a il.ani.ene b) Cu
a la il.ani.ene c) Mg a l a il.ani.ene d) Zn a l a il.ani.ene
adsa s daadsas adsa s adsa s adsa s
w.wp.apda17.The following w .wp.apof
set reactions are used
w
apdarefining
.wp.in Zirconium
w .wp.apda w .wp.apda w
ww ww ww ww ww ww

ada ada ada ada ada
ww a) Liquation ww w
b) van Arkel wprocess w
c) Zonewrefining w
d)wMond’s process ww
18. Which
eteof
t the following is used
etet for concentrating eore
tet in metallurgy? t t
l a i
l .ani.n l ail.ani.n l a i
l.ani.n l a i
l .ani.ente l a i
l .ani.ente
sas saasRoasting as
adsaFroth as
floatation .p.apdaadsa d) Both (a) and
a
daadsas
.
w p.apdaada a) Leaching .
wp.apdaadb) .
w papdac)
. w .
w p.ap(c)
w w w w w w
ww ww ww ww ww ww
4
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
ene t t .ni.ene t t t t t t t t
lail.ani.incorrect statement
19.asThe aslailaamong the following il.ani.ene
aslais a l a il.ani.ene a l a il.ani.ene
adsa adsa adsa s s asa s
.wp.apda a) Nickel is refined
.wp.apdaby Mond’s process.wp.apdab) Titanium is refined aada
.wp.apdby . p.apdad
w w w w Van Arkel’swprocess w w w
ww ww ww ww w ww
c) Zinc blende is concentrated by froth floatation
asl ail.ani.n asl ail.ani.n asl ail.ani.n asl ail.ani.n asl ail.ani.n
adad) In the metallurgy
s adof
sa gold, the metal isadleacheds
ada with dilute sodium ada chloride solution
s s
ada
w .wp.apda w .wp.apda w.wp.pa w .wp.apda w .wp.apda w
ww ww ww ww
20. In the electrolytic refining of copper, which one of the following is used as anode? ww ww
a) iPure t t t t t
l a .ni.ente copper
l a
b) Impure
l a i
l.ani.ente copper c) Carbon l ail.ani.enterod d) Platinum
l ail.ani.enteelectrode l a i
l .ani.ente
adsaas
apda21.
a
daadsas for the formation
adiagram,
sas
apdaada of carbon monoxide
sas
apdaada
sas
apdaada
w .
w p. In the Ellingham
w .
w p. p w .
w p. w.wp. w .
w p. w
ww ww ww ww ww ww
o o
a)ΔS /ΔT is negative b) ΔG /ΔT is positive
t tet o i.ni.entet o i.ni.enteot t t
c)
l a .ani.enote/ΔT is negative lail.ani.end)
ilΔG initially ΔT/ ΔG l ais
l a positive, after 700 lCa l ,
a ΔG /ΔT is negative l a il.ani.ene
a
adsas a
adsas a
adsas a
adsas a
adsas
ww 22.Which of the wwfollowing plot gives wEllingham
w diagram ww ww ww
o o o 2
a)ΔS Vs
t t
T b) ΔG Vs T t t c) ΔG Vs 1/T is negative t t d) ΔG Vs Tt tis negative t t
n
il.ai e
. ne n
il.ai e
. n e n
il.ai e
. n e il.ani.ene il.ani.ene
a sl a asl a asl a a sl a a sl a
dsa
a23.Which of the following adsa reduction is notathermodynamically
adsa adsa
feasible? adsa
w.wp.apda w .wp.apda w .wp.pda w.wp.apda w .wp.apda w
ww ww ww ww ww ww
a) Cr2O3+ 2Al → Al2O3 + 2Cr b) Al2O3 + 2Cr → Cr2O3 + 2Al
c) i3TiO etet + 4Al → 2 Al2O3 i+.ani3Ti etet d) none tetthese
eof etet etet
al.ani.n 2 al .n ail.ani.n ail.ani.n ail.ani.n
Padasalai.Net
ada ada aa aa ada
w.wp.apda24.Which of the w .wp.apda
following is not true with
w pdad
.wp.arespect to Ellinghamw .apdad
.wpdiagram? w .wp.apda w
ww ww ww ww ww ww
a) Free energy changes follow a straight line. Deviation occurs when there is a phase change.
.ni. entet .ni. entet .ani. almost parallel to entet
.ani. energy axis. .ni. entet entet
alailagraph for the formation
b) The alaila of CO2 is a straight
alailline alailfree alaila
a daadsas a daadsas .p.ap daadsas.p.ap daadsas
a daadsas
w.wp.p c) Negative slopew.wp.p ww w w.wp.p
ww wincrease in temperature. w
ww ww of CO shows that itwbecomes more stablewwith ww ww
d) Positive
tetslope of metal oxidesteshows
t that their stabilities
tet decrease with increase
tet in t t
a
en
lail.ani. a
en
lail.ani. a
en
lail.ani. a
en
adsa s sa s sa s sa s adsas
adatemperature. adaad adaad adaad .wp.apda
w w w w ww ww
ADDITIONAL QUESTIONS :
t t .entet tet t t t t
a l a il.ani.ene metal is usedafor
1.Which
l a il.aniextraction of Au andail.Ag
a l ani.enand also for galvanization
a l a il.ani.ene of iron object? a l a il.ani.ene
w.wp.apda a)Mg w .wp.apda b) Zn w.wp.apda c)Cr w .wp.apda d)Co w .wp.apda w
ww ww ww ww ww ww
2.Which of the following is not a mineral of aluminium?
etet etet i.ente
t entet etet
s asl ail.ani.n a)Bauxite s aslail.ani.nb) Cryolite s asl ail.anc) China clay s asl il.ani.Malachite
ad) s asl ail.ani.n
ada ada ada ada ada
ww 3.Name the wwprocess by which elements ww such as germanium ww ,silicon and galium ww
are refined. ww
a)
t Vapour phase method t b) Electrolytic
t refining etet t
l a i
l.ani.ente l ail.ani.n l a i
l .ani.ente
s as s as s as s as sas
adaada adaada
c) Zone refining adaada d) Van–Arkel daada
amethod. apdaada
w w.wp.p w w.wp.p w w.wp.p w w.wp.p w .
w p. w
w w w w ww ww
5
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
4.In
a il.ani.entet extraction of copper
the a
t t
il.ani.enefrom its sulphide a ilore,
t
.ani.entethe metal is finally a i.ente
t
il.anobtained
t t
by the aslail.ani.ene
a sl a sl asl a sl
adsa adsa s
aada daadsa asa
w .wp.apda reduction of cuprous w .wp.apda oxide with a)Iron w .wp.apdsulphide(FeS) w .wp.apb) w .
w p.apdad w
ww ww ww ww Carbon monoxide(CO) ww ww
c) Copper (I)sulphide (Cu2S) d) Sulphur dioxide (SO2)
ada 5.Concentration 0f
s acopper
s
da glance is done aby
s
da s
ada s
ada
ww ww
a) leaching ww
b) magnetic separation ww
c) froth flotation ww
d) hydraulic washing ww
6. iZone t ni.entet t t t t
lala .ni.ente refining is basedi.onlala
a) fractional idistillation
.ni.ente
lala
b) simple
l a l
distillation
i.ni.ene
a l a i
l .ani.ente
a daadsaas a daadsaas a daadsaas ad)daadsaas sas
apdaada
w.wp. p w.wp.p c)wsublimation
.wp. p w.wp. p fractional crystallization
w .
w p. w
ww ww ww ww ww ww
7.The process of heating of copper pyrites to remove sulphur is called
t t tet t t t t t t
a l a il.ani.enea)froth flotation a l ail.ani.enb)roasting c) a l il.ani.ene
calcination
a d) smelting
a l a il.ani.ene a l a il.ani.ene
ww 8.Malachite wwhas ___________ composition. ww ww ww ww
a)
t 2CuCO3.Cu(OH)2n.entet b) CuCO3Cu(OH)t2 t 2c) Cu O d) Cu S
2
n e
. nte n ene
. n entet
. t t
il.ani.ene
lail.ai
saas9.Zinc
i.ai
saaslal asl a i
l .
a i
asl a i
l.a i
a sl a
d ad blende is ___________
d ad a)ZnSapdaadsa b) PbS dsa2S
c) aAg d) Cu2S apdaadsa
a
w.wp.p
a a
w.wp.p
a
w.wp. w.wp.apda w.wp. w
ww ww ww ww ww ww
10.In acid leaching process, the insoluble sulphide is converted into soluble sulphate and
elemental etet ___________a)Carbon etet b) Lead etet c) Sulphur t t
i.ani.ene d) Zinc i.ani.entet
ail.ani.n ail.ani.n ail.ani.n
Padasalai.Net
a l a l a l lal alal
s
ada s s
ada s s
ada s adsaas daadsas
w.wp.apda 11.Gibb’s freewenergy .wp.apda is given by __________w .wp.apda a
w.wp.p
da .
ww p.ap w
ww ww ww ww ww ww
a) ΔGo = -nFEo b) ΔGo = nF c) Δ Go = nFEo d) ΔEo = -nFGo
entet entet entet entet .ani.ente
t
lail.ani. the metallurgy sof
saas12.In ail.ani.
aasl iron, limestone is added
i.ani.
saaslal to coke .which acts
i.ani.
saaslaasl a________ sasl a i
l
adaad .wp.apda
ad
.wp.apda
ad
.wp.apda
ad apdaada
w w.wp.p w w w w w w d) Flux www
.wp. w
w a) reducing
w agent b) oxidizing
w agent c) slag w ww
13.Froth
tet flotation process istesuitable
t for concentrating
tet ___________ore.tet t t
a la il.ani.en a l a il.ani.en a la il.ani.en a l a il.ani.en a l a il.ani.ene
adsas a) Oxide p.apdaadsas b) Carbonate adsas c) Sulphide adaadsas d)Halide adsas
w .wp.apda w .w w.wp.apda w.wp.p w .wp.apda w
ww ww ww ww ww ww
14.Metal oxide is converted into metal by
t t tetRoasting et
i.entSmelting ntet t t
a l a il.ani.enea) Calcination alail.ani.enb) a la il.anc) a l a il.ani.e
d) Bessemerisation
a l a il.ani.ene
adsa s daadsas adsa s adsa s adsa s
w.wp.apda 15.In Hall-Herold w .wp.approcess, __________act
w .wp.apda as an anode. w.wp.apda w .wp.apda w
ww ww ww ww ww ww
a)Carbon blocks b) Hydrogen c)Copper rods d)Zinc rods
t etet ni.entet etet etet
l i.ente
ail.anIn lail.ani.n ethyl Xanthate l ail.aused lail.ani.n l ail.ani.n
s
ada a16.
s froth floatation s
ada asodium
s s
ada as is as a s
ada as s
ada as
ww ww
a) Collector ww
b) depressing agent c) frothing ww agent d) Flux ww ww
17. Which
etet method is basedeton
et the solubility of the
eteore
t in a suitable solvent
etet t
l ail.ani.n l ail.ani.n l ail.ani.n l a i
l .ani.n l a i
l .ani.ente
s as s as s as sas sas
adaada a) Gravity daada
aseparation adaada wash
b) Hydraulic apdaada d) Magnetic separation
c) Leaching apdaada
w w.wp.p w w.wp.p w w.wp.p w .
w p. w .
w p. w
w w w ww ww ww
6
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
t t t t .entet t t
18.
l a i.ente stone , Chromite
il.anTin l a .ani.entePyrolusite are concentrated
iland l a il.ani.ene by -------------l a il.aniprocess. l a il.ani.ene
a
adsa s a
asa s a
asa s a
asa s a
asa s
w .wp.apda w .
w p.apdad w .
w p.apdad w .
w p.apdad w .
w p.apdad w
ww a) Gravity
ww separation wwb) Hydraulic wash c) wwFroth flotation d) Magnetic ww separation ww
19.The process of ore into metal oxide with absence of air is called
s
ada a) Oxidation s
ada b) Cementation s
ada c) Galvanization s
ada d) Calcination s
ada
ww w
20. Metalswhaving low melting points ww such as tin, lead, mercury ww and bismuth are ww refined by ww
t tetLiquation t entet refining t

l a i
l .ani.entea) Distillation lail.ani.enb) l ail.anic)
.enteElectrolytic l a
d)
il.ani.Zone l a i
l .ani.ente
sas a
daadsasin the manufacture saas sas sas
.
w p.apdaada 21. Which one is .
w p.aused
p .
w p.apdaadof many products .
w apdaadaas paints, rubber,
such
p. .
w p.apdaada
w w w w w w
ww ww ww ww ww ww
cosmetics. a) Zinc carbonate b) Zinc oxide c) Zinc metal d) Zinc sulphide
t t t t t t t t
22.
l a i.ente
il.anWhich one is used for
l a i.ente
il.ancutting tools and il.ani.ene machines. alail.ani.ene
crushing
l a l a il.ani.ene
a
adsas a
adsas a
adsas adsas a
adsas
ww ww steel
a) Nickel ww steel
b) Chrome c) Chromeww vanadium steel ww d) Nichrome ww
23.Elingham t t diagram helps to t t select a) suitablen.ereducing
t t agent b) appropriate t t temperature t t
n
il.ai e
. n e n
il.ai e
. n e il.ai n e n
il.ai e
.n e il.ani.ene
s asl a sasl a asl a asl a asl a
apdaada apdaada asa
c) aboth s
apdaadd)a oxidizing agent apdaada
s
w.wp. w.wp. pdad (a) and (b)
w.wp. w.wp. w.wp. w
ww ww ww ww ww ww
24. The complex formed when NaCN is added to galena in which ZnS is the impurity
t 2Na[Zn(CN)4] n.enb)
etea) tetNa2[Zn(CN)4] et
c)et2Zn[Na(CN) 2] d) Na etet [Zn(CN)4] etet
ail.ani.n ail.ani.n ail.ani.n 4 ail.ani.n
Padasalai.Net
s asl s asl ail.ai s asl s asl s asl
ada aa daada ada ada
w.wp.apda 25. Depressing w p.apdad used to separate
agents
.w w .wp.apZnS from PbS is w .wp.apda w .wp.apda w
ww ww ww ww ww ww
a) NaCN b) NaCl c) NaNO3 d) NaNO2
t tet t .entet t
26.
l ail i.ente type of leaching
.anWhich l a i
l.ani.enprocess convert a i
l .ani.ente sulphide ore into
insoluble
l l ail.anisoluble sulphates? l a i
l .ani.ente
sas sas sas sas sas
.
wp.apdaada .wp.apdaada .
w p.apdaada .
w p.apdaada .
w p.apdaada
w w leaching b)walkali leaching w leaching ww picking w
ww ww
a) cyanide ww c)wacid
w d)whand ww
t t t t t t t t t t
adsas adsas 2. P BLOCK adsas adsas adsas
w .wp.apda w .wp.apda w.wp.apda ELEMENTS w–.wpI.apda w .wp.apda w
ww ww ww ww ww ww
1. An aqueous
t t
solution of boraxt ist ………… t t t t t t
s
adsa (a) neutral s
ads(b)
a acidic s
adsabasic
(c) s
(d)adsamphoteric
a adsa s
ww ww ww ww ww ww
2. Boric acid is an acid because its molecule …………
t + t t t
i.ente
(a)i.ancontains replaceable iH
.ani.enion
e etegives
(b) up a proton i.ani.entet etet
a l al a lal a l ail.ani.n lal l ail.ani.n
d s
ada s d s
ada s d s
ada s d adsaas s
ada as
a
w.wp.p
a a a
w.wp.pproton to form water
(c) combineswwith a a
w.wp.pmolecule
a
w.wp.p
a
w.wp.apda w
ww w ww ww ww ww
(d) accepts OH– from water, releasing proton.
entet
i.ni. i.ani. enteti.ani. entet i .ani.ente
t
i .ani.ente
t
slala among the following
3.saaWhich saaslal is not a borane?
saaslal sasl a l sasl a l
adaad adaad adaad apdaada apdaada
w w.wp.p w w.wp.p (b) B H w w.wp.p (C) B H .
w p.
w (d) none of theseww .
w p. w
w (a) B2H6 w 3 6 w 4 10 ww w ww
7
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
t t
ene t t t t t t t t
lail.ani. of the following
4.asWhich il.ani.ene has the largest
aslametals il.ani.ene
aslaabundance in the earth’s .ni.ene
aslaila crust? a l a il.ani.ene
adsa adsa adsa asa adsa s
w .wp.apda (a) Aluminiumw.wp.apda (b) calcium w pdad
.wp.apda(c) Magnesium w.wp.a(d) w .wp.apda w
ww ww ww ww Sodium ww ww
5. In diborane, the number of electrons that accounts for banana bonds is …………
ada (a) six
s ad(b)
sa two (c)
adafour
s (d)adthree
sa s
ada
ww ww ww
6. The element that does not show catenation among the following p-block elements is ………… ww ww ww
(a)i.nCarbon t (b) silicon t (c) Lead t (d) germanium t t

l a l ai.ente l a i
l .ani.ente
p. dsaaCarbon
apdaa7.
s
atoms in p.
sas
apdaada
fullerene with formula p.
adsaas
apCda60 have ………… p. p
saas3
daadsp
a(a) hybridised p.
sas
apdaada
w .
w w .
w w .
w w.w w .
w w
ww ww ww ww ww ww
2 2 3
(b) sp hybridized (c) sp hybridised (d) partially sp and partially sp hybridised
t t et
i.entits t t t t t t
l il.ani.ene state of carbon
8.saOxidation
a a l ail.anin hydrides ………… a l a il.ani.ene a l a il.ani.ene a l a il.ani.ene
adas adsas adsas adsas adsas
ww (a) +4 ww (b) -4 ww (c) +3 ww (d) +2 ww ww
9. The basic
t t
structural unit of silicates
t t
is ………… t t t t t t
a l ail.ani.ene 2- a l a il.ani.ene 2- a l a il.ani.e–ne a l a il.ani4-.ene a l a il.ani.ene
s
adsa (a) (SiO3) s
ads(b)
a (SiO4) s
adsa(SiO)
(c) s
(d)ads(SiO
a 4) adsa s
ww ww ww ww ww ww
10. The repeating unit in silicone is …………
Padasalai.Net
ada ada ada ada ada
ww ww ww ww ww ww

t
11. lail.ani. of these is notsaaaslamonomer
saasWhich
il.ani. i.ni.
slala
for a highsaamolecular il.ani.
saaslapolymer?
mass silicone sasl a i
l
adaad .wp.apda
ad
.wp.apda
ad apdaad apdaada
w w.wp.p w w w w w w.wp.(d) w.wp. w
w (a) Me3SiClw (b) PhSiCl3 w (c) MeSiCl3 w Me3SiCl3 ww ww
2
12. Which
tetof the following is not
tet sp hybridised? t t t t t t
a la il.ani.en a l a il.ani.en a la il.ani.ene a l a il.ani.ene a l a il.ani.ene
adsas(a) Graphite as grapheme
ads(b) s
adsaFullerene
(c) as ice
(d)adsdry adsas
ww ww ww ww ww ww
13. The geometry at which carbon atom in diamond are bonded to each other is …………
t t t t t t t t
(a)
l a i.ente
il.anTetrahedral l il.ani.ene
(b)ahexagonal
la il.ani.ene
(c) Octahedral (d) none
l a .entethese
il.aniof l a il.ani.ene
a
adsa s a
adsas a
asa s a
adsa s a
adsa s
w.wp.apda14. Which of thewfollowing .wp.apda statements is
w .apdadcorrect?
.wpnot w .wp.apda w .wp.apda w
ww ww ww ww ww ww
(a) Beryl is a cyclic silicate (b) Mg2SiO4 is an orthosilicate
l ni.entet4-
ail.aSiO l
etet
ail.ani.n unit of silicates l
etet
ail.ani.n lail.ai n.entet lail.ai n.entet
s
ada a(c)
s 4 is the basic structural
s
ada as s
ada as (d) Feldspar
asaasis not aluminosilicate
asaas
d d
ww ww ww ww ww ww
t t t t t
l a i
l.ani.ente l a i
l .ani.ente l a i
l .ani.ente
sas sas sas sas sas
.
w p.apdaada .
wp.apdaada .
w papdaada
. .
w p.apdaada .
w p.apdaada
w w w w w w
ww ww ww ww ww ww
8
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
enet t .ni.ene t t ene t t

.ene t t t t
lail.ani. items in column
15.asMatch lail.ani. – II ans assignasthe
asla–ilaI with the items ofascolumn lail.anicorrect code a l a il.ani.ene
adsa adsa adsa adsa adsa s
ww ww ww ww ww ww

ada ada ada ada ada
ww ww ww ww ww ww
t t t t t
l a i
l .ani.ente l a i
l .ani.ente
sas sas sas sas sas
.
w p.apdaada .
w p.apdaada .
. .
w p.apdaada
w w w w w w
ww ww ww ww ww ww
t t t t t t t t t t
ww ww ww ww ww ww
t t t t t t t t t t
ww 16. Duraluminwis w an alloy of ………… ww ww ww ww
(a) Cu,t Mn
t (b) Cu, Al, tet
Mg (c) Al, Mnt t (d) Al, Cu, Mn, tet
Mg
e
n e en e ne e n etet
n . n . n . n . ail.ani.n
Padasalai.Net
l .
aila i l .
aila i l .
aila i l .
aila i l
s as
a The compound athat
ad17. s as
adais used in nuclearareactors s
ada as s as
ada and control rods
as protectiveapshields s as
adisa…………
w.wp.apda w .wp.pda w .wp.pda w .wp. da w .wp.apda w
ww ww ww ww ww ww
(a) Metal borides (b) metal oxides (c) Metal carbonates (d) metal carbide
18. The tet
.ani.enstability of +1 oxidation t
.ani.entestate increases in
t
ni.entesequence
the
.a ………… i.ani.entet .ani.ente
t
l ail l a i
l l a i
l l a l l a i
l
sas a
daadsas
a
daadsas sas saas
.
wp.apdaada (a) Al < Ga < In .<wp.aTl p (b) Tl < In <
.
w p.a
p
Ga < Al (c) In < Tl < Ga
.
w p.apd<aadAla (d) Ga<
.wp apda<adAl
.
In < Tl
w w w w w w
ww ww ww ww ww ww
ADDITIONAL QUESTIONS :
entet entet entet t t
il.ani.ene
t t
il.ani.ene
lail.ani. common oxidation
1. saasMore i.ani.
saaslal state for halogenssaais
il.ani.
sla………… a l a a l a
adaad adaad adaad adsas adsas
w.wp.p w.wp.p (b) +2 w.wp.p (c) -1 w.wp.apda w .wp.apda w
w w (a) +1 w w w w ww (d) -2 ww ww
2. Electronic configuration of noble gases is ………… tet
n entet n entet en t t
il.ani.ene
t t
il.ani.ene
s asl a i
l .
a i .
s as a i
l
l 2 5.
a i .
s asla1il.ani. 6 asl a a sl a
.p.apda
a a
d (a) ns 2
.p.apda
a a
d(b) ns np
.p.apda
a
(c)a
d ns np (d)adsns
.wp.apda
2
a np 6
.wp.apda
adsa
ww ww ww w w w
ww ww ww ww ww ww
3. Noble gases are chemically inert. This is due to …………
t etet t t t etet
(a)
l i.ente
ail.anunstable electronic configuration
lail.ani.n l i.entestable electroniclaconfiguration
ail.an(b) il.ani.ene l ail.ani.n
s
ada as s
ada as s
ada as s
aa as s
ada as
w.wp.apda (c) only filled p-orbital
w .wp.apda w .wp.apda (d) only filled
w pdad
.wp.a5-orbital w.wp.apda w
ww ww ww ww ww ww
4. Noble gases are chemically inert. This is due to …………
t t t t t
l a i
l.ani.ente l a i
l .ani.ente l a i
l .ani.ente
sas(a) unstable electronic sasconfiguration sas (b) stable electronic sas configuration dadsaas
apdaada apdaada apdaada apdaada aa
w .
w p. w .
wp. w .
w p. w .
w p. w.wp.p w
ww w w
(c) only filled p-orbital w w w w
(d) only filled 5-orbital w w ww
9
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
ene t t .ni.ene t t .ni.ene agent? t tt t t t

lail.ani. one of the following
5. asWhich aslaila is the strongest oxidising
aslaila a l a il.ani.ene a l a il.ani.ene
adsa adsa adsa asa s adsa s
w .wp.apda (a) Fluorine w.wp.apda (b) Chlorine w .wp.apda(c) Bromine w pdad
.wp.a(d) w .wp.apda w
ww ww ww ww Iodine ww ww
6. Some elements exist in more than one crystalline or molecular forms in the same physical state
isadcalled
sa …………(a) isomerism s
ada (b) allotropism
s
ada (c) isomorphism s
ada (d) isoelectronicss
ada
ww ww
7. How many allotropes possible for boron? ww (a) 1 ww (b) 4
w
(c)w6 (d) 7 ww
8. Important t ore of boron isn.en(a) t t t boron i.ni.entet

l a i
l .ani.ente l a i
l.ai te bauxite (b) borosilicate
l ail.ani.ente (c) borax (d)laP-tetragonal
i
l .ani.ente lala
a daadsaas a daadsaas a daadsaas a d
a adsaas a daadsaas
w.wp. 9. Borontrifluoride
p w.wpreacts
.p with sodiumwhydride
.wp. p at 450 K givesw………… .wp. p w.wp. p w
ww ww ww ww ww ww
(a) diborane (b) tetraborane (c) pentaborane (d) decaborane
etet t
.ani.ente hydroxide tolaforms t t
il.ani.ene …………
t t
il.ani.ene
t t
il.ani.ene
l ail.ani.n reacts with fused
10.sasBoron a l ailsodium a a l a a l a
ada adsas adsas adsas adsas
ww (a) Borax ww (b) Boric acidww (c) Sodium borate ww (d) Sodium tetraborate ww ww
11. Whicht isotope t is used as moderator t t in nuclear reactors? t t t t t t
n
il.a10ie
. ne n
il.ai e
. n e il.ani.ene i.ni.ene il.ani.ene
s asl a asl
sa C6a
n as
4l a
adsa He2 slal2a
saaCa
40 a
adsa sl a
apdaada (a) B5 apdaad(b) apda(c) (d)
apdaad
.wp.apda
w.wp. w.wp. w.wp. w.wp. w w
ww ww ww ww ww ww
12. Compounds used as an eye lotion …………
et 3
(a)i.anHi.e3ntBO (b) HBO etet (c) H2B etet
O (d) B2O3i.ani.entet etet
ail.ani.n 2 ail.an4i.n7 ail.ani.n
Padasalai.Net
a l al a l a l lal l
d s
ada s d s
ada s d s
ada s d adsaas s
ada as
a a
w.wp.p13. Which one of
a a a a
.wp.pfollowing is called was.wpinorganic
the
w .p benzene? a
w.wp.p
a
w .wp.apda w
ww ww ww ww ww ww
(a) B2H6 (b) BN (c) H2B4O7 (d) B3N3H6
entet t
.ani.enteammonia at highlatemperature
.ani.ente
t
.ani.ente
t
.ani.ente
t
lail.ani.
14.saasDiborane reacts withsaexcess
asl a i
l sas
i
l to give a
…………
sasl il sasl a i
l
.
wp.apdaad .
w p.apdaad .
w p.apdaada .
w p.apdaada .wp.apdaada
w w w (c) Borazole www (d) Diborane diammonate w w
ww ww
(a) Boron nitride (b) Boron oxide ww ww ww
15. Consider
tet the following statements.
tet t t t t t t
adsas(i) Diborane contains s centre-two electron
adsatwo adsas bond. adsas adsas
ww ww 3w
w ww ww ww
(ii) In diborane, the boron has sp hybridis ed.
t t t t t t t t
(iii)
l a i.ente
il.anDiborane has two terminal
l a il.ani.ene B – H bonds and la i.ente B – H – B bonds.
il.anfour l a il.ani.ene l a il.ani.ene
a
adsa s a
adsas a
asa s a
adsa s a
adsa s
w.wp.apda Which of the above w .wp.apdastatement(s) is/are w pdad
.wp.acorrect. w .wp.apda w .wp.apda w
ww ww ww ww ww ww
(a) (i) and (iii) (b) (ii) and (iii) (c) (i) only (d) (i) and (ii)
l .entet
ail.anistructure l
etet
ail.anisi.n………… l
etet
ail.ani.n la(b)
tet
il.ani.enhexagonal l
etet
ail.ani.n
16. s
ada aThe
s of graphite
s
ada as (a)s
ada planner
as s
ada as s
ada as
ww ww ww (c) octahedralww (d) buckywballsw ww
17. CO and
eteN
t 2 mixture is …………etet t t t
l a i
l.ani.ente l a i
l .ani.ente l a i
l .ani.ente
sas saas producer gas dadsaas (c) water gas dadsaas (d) LPG sas
.
w p.apdaada (a) natural gas .wp.apdaad(b) .
w papa
. .
w p.apa .
w p.apdaada
w w w w w w
ww ww ww ww ww ww
10
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
t t
.ene is …………(a) COla+il.ani.ene t t t t
ene t t
.ni.ene t t
lail.anigas
18. asSyn as N2 lail.an+i. H2
(b)asCO (c) CO
asla2 il+a H2 (d) COa2sl+ail.aNni2.ene
daadsa
.wp.ap19. .
asa
p.apdad .
asa
p.apdad .wp.apda
adsa
.wp.apda
adsa
w w w
Critical temperature of CO2 is ………..w w w w w
ww ww ww ww ww ww
(a) -31°C (b) -13°C (c) 31°C (d) 13°C
20.
ada Ortho silicates are
s also
ada called as ……….. ada(a)
s adaIno silicates
s ada (b) Soro silicates
s s
ada
ww ww ww ww
(c) Neso silicates ww (d) Cyclic silicates ww
21. Example t .entet (a) Olivine i.ni.entet t t t

l a i
l .ani.ente of Ring silicatelaisi
l.ani………. lala
(b) Beryl
i.ni.ene
lala l a i
l .ani.ente
a daadsaas a daadsaas a daadsaas a daadsaas sas
apdaada
w.wp. p w.wp.p (c)wSpodumene
.wp. p w.wp.(d) Asbestos
p w .
w p. w
ww ww ww ww ww ww
22. Compound used to remove the permanent hardness of water is ………..
t t t t t etet t t
(a)
l a i.ente
il.anZeolite (b)l ail.ani.ene
Feldspar (c) Talc
l a il.ani.ene (d) Mica saslail.ani.n l a il.ani.ene
a
adsas a
adsas a
adsas a
adsas
.wp.apda .wp.apda .wp.apda daada
.wp.ap .wp.apda
w w w w w w
ww 23. Pick out the wwthree dimensional silicates? ww (a) Talc ww Mica
(b) (c) Quartzww (d) Asbestos ww
t t t t t t t t t t
adsa s adsa s 3. P BLOCK s
adsa ELEMENTS – aIIdaadsa s adsa s
w.wp.apda w .wp.apda w.wp.apda w.wp.p w .wp.apda w
ww ww ww ww ww ww
1. In which of the following, NH3 is not used?
t etet t etet etet
i.ente
ail.anNessler’s ail.ani.n(b) Reagent for sthe .ani.ente ail.ani.nradical ail.ani.n
Padasalai.Net
s asl
(a) reagent s asl a sl ailanalysis of IV group s asl
basic s asl
ada ada ada ada ada
ww (c) Reagentww for the analysis of III wgroup w basic radical (d) ww Tollen’s reagent ww ww
2. Which
entetis time regarding nitrogen?
entet t t t
l ail.ani. l a i
l.ani. l a i
l .ani.ente
sas sas adsaashas low ionisation sas sas
.
wp.apdaada (a) least electronegative
.
w p.apdaada element .
w p.apda(b) .
w p. aada
apdenthalpy than oxygen
.
w p.apdaada
w w w w w w
ww ww ww ww ww ww
(c) d-orbitals available (d) ability to form pπ – pπ bonds with itself
t t t t t t
i.ente
lail.anelement
3. An belongs tolagroup t
il.ani.ene 15 and 3 rd period ente
lail.ani.of the periodic table, .enteelectronic
lail.aniits l a il.ani.ene
a
adsas a
adsas adsaas adsaas a
adsas
p a
. pd
a p a
. pda p.apda p a
. pda .wp.apda
w.w configurationw.w (a)w.1s
w 2s22p4
2
w.w
2 2 3
w w
ww ww would be ………… ww (b)
ww 1s 2s 2p ww ww
(c) 1s22s22p63s23p2 (d) 1s22s22p63s23p3
t t t t t t t t t t
4.
adsa Solid (A) reacts with
s adsstrong
a s aqueous NaOH adsaliberating a foul smelling
s adsa gas(B) which adaadsa
s s
.wp.apda .wp.apda .wp.apda .wp.apda .p.p
ww
w
w w w
w w w
w w w
w ww w ww
w
spontaneously bum in air giving smoky rings. A and B are respectively …………
ete(a)
t P4(red) and PH3n.entet (b) P4(white)
n.entet and PH3 etet etet
s asl ail.ani.n s
.i
aslaila s asl ail.ai s aslail.ani.n s asl ail.ani.n
a
d a ada ada aa ada
ada
w.wp.p (c) S8 and .apd2aS
w.wpH w .wp.apda(d) P4(white) andwH.w .apdad
2pS w.wp.apda w
ww ww ww ww ww ww
5. On hydrolysis, PCl3 gives (a) H3PO3 (b) PH3 (c) H3PO4 (d) POCl3
6. Pas4lO
a .entet with cold water
il6.anireacts l ail ntetgive …………
.ani.eto l a i
l.ani.ente
t
l a i
l .ani.ente
t
l a i
l .ani.ente
t
s sas sas sas sas
.
w p.apdaada .
wp.apdaada .
w papdaada
. .
w p.apdaada .
w p.apdaada
w (a) H3PO3 www (b) H4P2O7 www (c) HPO3 w (d) H3PO4 w w
ww ww ww ww
11
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
t t
.ani.ene t t
.ni.ene acid ( H4P2O5)laisil.an…………
i.ene t t t t t t
7. The
aslailbasicity of pyrophosphorous
aslaila as a l a il.ani.ene a l a il.ani.ene
w .wp.apda (a) 4 w .wp.apda (b) 2 w .wp.apda(c) 3 w pdad
ww ww ww ww 5 ww ww
8. The molarity of given orthophosphoric acid solution is 2M. its normality is …………
ada (a) 6N
s ad(b)
sa 4N (c)
ada2N
s (d)adnone
s
a of these s
ada
ww ww ww
9. Assertion – bond dissociation energy of fluorine is greater than chlorine gas ww ww ww
Reason t –t chlorine has more t t

electronic ni.entet fluorine
repulsioni.than .ani.ente
t
.ani.ente
t
li.ni.ene
a l a i.ni.ene
l a l a l a la l ail l a i
l
saas saas adsaas a
daadsas sas
.
w p.apdaad(a) Both assertion.
w p.apdaadreason
and are true and
.
w p.apdareason is the correct
.wpapexplanation
. of .
w p.apdaada
assertion.
w w w w w w
ww ww ww ww ww ww
(b) Both assertion and reason are true but reason is not the correct explanation of assertion.
etet
il.ani.n i.ni.n etet t t
il.ani.ene
t t
il.ani.ene
t t
il.ani.ene
(c)
saslaAssertion is true butsareason
slala is false. a l a a l a a l a
ada ada adsas adsas adsas
ww ww and reason are false.
(d) Both assertion ww ww ww ww
10. Amongt tthe following, which tist the strongest oxidizing
t t
agent? t t t t
s
adsa (a) Cl2 s
ads(b)
a F2 s
adsaBr2
(c) (d)adsIa2 s adsa s
ww ww ww ww ww ww
11. The correct order of the thermal stability of hydrogen halide is …………(a) HI > HBr > HCl > HF
ete>t HCl > HBr > HI i.ani.en(c)
(b)i.anHF tet HCl > HF > HBr > .HI etet (d) HI > HCl > HF t
e>teHBr etet
al i.n ailani.n ail.ani.n ail.ani.n
Padasalai.Net
s asl s asl al s asl s asl s asl
aadaWhich one of the
.wp.apd
12. .wp.apdaada
following compounds .wp.ais
ada
pdanot formed? .wp.apda
ada
.wp.apda
ada
w w w w w w
ww ww ww ww ww ww
(a) XeOF4 (b) XeO3 (c) XeF2 (d) NeF2
entet t
.ente………… .ani.ente
t
.ani.ente
t
.ani.ente
t
lsail.ani. easily liquefiable
13.saaMost gas
sasl a i
l.aniis
sasl a i
l sasl ail sasl a i
l
.
wp.apdaad .
w p.apdaada .
w p.apdaada .
w w w w (d) Kr w w
ww (a) Ar ww (b) Ne ww (c) He ww ww ww
14. XeF6 on complete hydrolysisteproduces …………
i.ani.entet i .
a ni en t
. t t
il.ani.ene
t t
il.ani.ene
t t
il.ani.ene
a la l a l a l a la a l a a l a
asas asas s
adsaXeO as 2
(d)adsXeO adsas
w.w p.apdad (a) XeOF4 p.apdad(b) XeO2F4
w.w p.apda(c) w.w
3
w.wp.apda w .wp.apda w
ww ww ww ww ww ww
15.Which of the following is strongest acid among all?
t t t t t (d) HClail.ani.entet t t
(a)
l a i.ente
il.anHI l il.ani.ene
(b)aHF (c) HBr
la il.ani.ene l l a il.ani.ene
s as as a s a s a s
aada
.wp.apd .wp.apdaadsa adsa
.wp.apda for the bond dissociation .wp.apda
adsa
.wp.apda
adsa
w 16. Which one of the
w following orders iswcorrect w enthalpy of
w halogen w
ww ww ww ww ww ww
molecules? (a) Br2 > I2 > F2 > Cl2 (b) F2 > Cl2 > Br2 > I2 (c) I2 > Br2 > Cl2 > F2 (d) Cl2 > Br2 > F2 > I2
etet ni.entet .entet etet etet
17. s asl ail.ani.n the followingsthe
Among a slail.acorrect order of acidity
s asl ail.aniis ………… s aslail.ani.n s asl ail.ani.n
ada ada ada ada ada
ww (a) HClO2 <wHCIO w < HClO3 < HClO4ww (b) HClO4 < HClO ww2 < HCIO < HClO3 ww ww
(c) HClO
etet 3 < HClO4 < HClO2 <etHCIO
et (d) HCIO
t < HClO2 < HClOe3te<t HClO4 t
l ail.ani.n l ail.ani.n l a i
l.ani.ente l a i
l .ani.n l a i
l .ani.ente
s as s as sas sas sas
adaada adaada apdaada apdaada apdaada
w w.wp.p w w.wp.p w .
w p. w .
w p. w .
w p. w
w w ww ww ww ww
12
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
enet t t t t t t t t t
lail.ani. copper is heated
18.asWhen il.ani.enecone HNO3 it produces
aslawith
.ni.ene …………
adsa asa adsa asa s adsa s
w .wp.apda (a) Cu(NO ) , w .
w p.apdad w .wp.apda(b) Cu(NO ) and w .
w p.apdad w .wp.apda w
ww 3w2w NO and NO2 ww 3 2 ww N2O ww ww
(c) CU(NO3)2 and NO2 (d) Cu(NO3)2 and NO
ADDITIONAL
s
ada QUESTIONS a:da
s s
ada s
ada s
ada
ww ww ww
1. Nitrogen gas in atmosphere is separated industrially from liquid air by ………… ww ww ww
(a) simple t tdistillation .ani.ente

t t
(b) Fractionali.ndistillation
i.ente .ani.ente
t
.ani.ente
t
l i.ni.ene
a l a l a i
l l a la l ail l a i
l
p. dsaasSublimation p.apdaadsaas
apdaa(c) asaas
p.apdad
(d)w.w
Distillation under reduced
papdaad
.
saas
pressure p.
sas
apdaada
w .
w w.w w .
w w .
w w
ww ww ww ww ww ww
2. Which one of the following is used in cryosurgery?
t tet ni.entet etet t t
i.enteN2
il.anLiq il.ani.enNH il.aNa .ni.n il.ani.ene
a(a)
adsas
l a (b)
a
adsas
l aLiq 3 (c) aLiq
adsas
l a
ada aslaHila2
(d) sLiq a
adsas
l a
ww 3. The dielectricwconstant w of ammoniawisw(K) ………… ww ww ww
(a) 10t-30t (b) 10 t t -14
(c) 10 t t 30
(d) 10 t t
14
t t
n
il.ai e
. ne n
il.ai e
. n e n
il.ai e
. ne il.ani.ene il.ani.ene
asl a asl a asl a asl a a sl a
4. aH dsa– N – H bond angle adsaNH3 is …………(a) 109°
in adsa28’ (b) 107° 28’ adaa(c) dsa 104° (d) 107° apdaadsa
w.wp.apda w .wp.apda w.wp.apda w.wp.p w.wp. w
ww ww ww ww ww ww
5. Shape of ammonia is ……(a) Planar (b) Square planar (c) Pyramidal (d) Square pyramidal
etet prepared in largei.anscales
6. Nitrici.anacid etet using …………(a) etet
Ostwald’s process (b) tet
eHaber’s process i.ani.entet
al i.n al i.n ail.ani.n ail.ani.n
Padasalai.Net
a l a l a l a l lal
a d
a
s
ada s
a da
s
ada s
a da
s
ada s
a da
s
ada s
a daadsaas
.p.p .p.p .p.p (c) Contact process.p.p (d) Deacon’s .wp.p
wwww w ww w ww ww w ww ww w ww wwprocess ww ww
w
7. Benzene undergoes nitration reaction to form nitrobenzene in this reaction takes place due to
entet
il.ani. i.ani. entet i .ani.ente
t
i.ni. entet i .ani.ente
t
saaslaformation
the saaslalHydronium ion
of …………(a) sasl a l slala
(b) Hydridesaaion sasl a l
adaad apdaad apdaada .wp.apda
ad apdaada
w w.wp.p w .
w p. w .
w p. w w.wp. w
w ww wwion
(c) Nitronium w
(d)
w Nitrasonium ion ww ww
8. Compound used in photography is …………(a) AgNO3 tet (b) AgBr (c) AgCl (d) AgI
i.ani.entet i .
a ni entet
. i .
a ni en
. i .
a ni entet
. t t
il.ani.ene
a la l a l a l a la l a l a l a l a
adsas asas asas (c) Royal water asas asas
w.w p9.
.apdaSodium nitrate (a)p.aPhotography
w.w pdad (b) Firearms
p.apdad
w.w p.apdad (d) Cryosurgery
w.w p.apdad w.w w
ww ww ww ww ww ww
10. White (Yellow) phosphorous glows in the dark due to oxidation which is called …………
etet
(a) phosphorescence tet phosphorus
il.ani.en(b)
t
i.enteFluorescence la(d)
il.an(c)
tet
il.ani.enLiminoscence
t t
il.ani.ene
a slail.ani.n
a asl a a sla a s a sl a
adsa s
aada asa adsa adsa
w .apdaYellow
.wp11. w .wp.apdreacts
phosphorous with alkali on
w .apdad in an inert atmosphere
.wpboiling w .wp.apda liberates .wp.apda
…………
w w
ww ww ww ww ww ww
(a) Phosphorous acid (b) Phosphoric acid (c) Phosphine (d) Pyrophosphoric acid
etet etet etet nte3t 3
il.ani.esp 3 ail.ani.en
tet
s asl ail.ani.n
12.aHybridisation of P in s asl
phosphineail.ani.n is …………(a) spsa3sdlail.ani.n (b) sp 3 2
d s asla(c) d (d) sp s asl
da ada ada ada ada
ww 13. Compounds used ww in Holme’s signal w w …………(a) Phosphine
are ww+ Acetylene w PO +H PO
(b)wH 3 3 3 3 ww
(c)eCalciumt carbide + calcium t phosphide (d) Calcium

t carbonate +etcalcium t phosphate etet
l a i
l .ani.nte l ail.ani.ente l a i
l.ani.ente l a i
l .ani.ne l ail.ani.n
s
da as saas s as s as s as
adaaShape
14. of ozone ……(a)adaadV-shape adaadashape
(b) .Linear (c) bent aada
adshape adaada
(d) spherical.pshape
w w.wp.p w w.wp.p w w wp.p w w.wp.p w w w.p w
w w w w w ww
13
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
.ni.ene t t .ni.ene t t ee t t t t t t
15. Sulphur
aslaila di oxide, how many ail.ani.n
aslailatimes heavier thanaslair? a l a il.ani.ene a l a il.ani.ene
w .wp.apda(a) 2 times w .wp.apda (b) 2.5 times w.wp.apda(c) 2.2 times w pdad
ww ww ww ww 2.3 times ww ww
16. Sulphuric acid can be manufactured by …………(a) Ostwald’s process (b) Lead chamber process
ete t etet etet etet etet
s
ada s
ada (c)
adaDeacon’s processadaada (d) Haber’s process
s s s
ada
w .wp.apda w .wp.apda w.wp.apda w .wp.p w .wp.apda w
ww ww ww
17. Sulphuric acid is manufactured by contact process, catalyst used in contact process is …………ww ww ww
l a lni.e5ntet
(a) V2i.O
a
(b) TiCl4 i.ni.entet
l a l a
(c) Fe
l ail.an(d)
t
i.enteMo l ail.ani.ente
t
l a i
l .ani.ente
t
p. dsaas
apdaaDeacon’s
18. process is
p.apused
a
.
sas
daadsasto manufacture.p…………(a)
apdaada Cl pa(b)
. p
a
daadsFas (C) Br p.
sas
apdaada (d) I2
w .
w w .
w w w 2 w.w 2 w .
w w
ww ww ww ww ww ww
19. Catalyst used in Deacon’s process is …………(a) CuCl2 (b) Cu2Cl2 (c) CuBr (d) Cu2Br2
tet ntet slaked lime to produce t t t t t t
20. Passing
a l a il.ani.enchlorine gas through
a l ail.ani.e
dry a l a il.ani.ene …………(a) CaOCl a l a il.ani.ene (b) CaOCl2 alail.ani.ene
ww ww ww ww (c) CaO w 2
(d)wCaCl ww
21. Which one
t t
of the following is at weak
t acid? (a) HF t t
(b) HCl (c) HBr
t t
(d) HI t t
dsa s
22.aReagent not stored ain s
dsa bottles?
aglass s
adsaHCI
(a) s
(b) HBrapdaadsa (c) HF (d) HI adsa s
w.wp.apda w .wp.pda w.wp.apda w.wp. w .wp.apda w
ww ww ww ww ww ww
23. The correct order of the acidity of hydrohalic acids? (a) HF > HCI > HBr > HI
(b) HCI ntet >HBr >HI
i.ani.e>HF
tet HBr > HCI >HF > HI
e(c)
ail.ani.n
etet (d) HI > HBr > HCI
ail.ani.n ail.ani.n
etHF
et> etet
ail.ani.n
Padasalai.Net
s asl al s asl s asl s asl s asl
ada ada aa ada ada
w .apdaShape
.wp24. of ClF 3 is w .wp.apda
…………(a) Linear (b)
w p.apdad
T-shape
.w (c) Pyrimidal
w .wp.apda (d) Square .wp.apda
planar
w w
ww ww ww ww ww ww
25. Which one of the following is more acidic? (a) HOCl (b) HCIO2 (c) HClO3 (d) HClO4
t
.enteXeF t t t t
26. Shape l ail.aniof is …………(a) l a i
l.ani.ente
Octahedron (b) a i
l .ani.ente octahedron lail.ani.ente
Distorted
l l a i
l .ani.ente
sas 6 sas sas sas sas
.
wp.apdaada .
w p.apdaada .
w p.apdaada .
w w (c) Pyramidalwww w w w
ww ww (d) Tetrahedron ww ww ww
27. Which one
tet of the following cantepenetrate
t through dense
tet fog? t t t t
a
en
lail.ani. a
en
lail.ani. a
en
lail.ani. a l a il.ani.ene a l a il.ani.ene
s
a s sa s s
a s adsas adsas
adaa(a)
d He daad
(b) aNe (c) Kr ad Rn
ada(d) .wp.apda .wp.apda
w w.wp.p w w.wp.p w w.wp.p w w w
w w w ww ww ww
28. Aquaregia a) 3 parts of con.HCl, one part of con.HNO3 b) 1 part of con.HCl, 3 parts of con.HNO3
c)a ntet of con.HCl, one
il.a3ni.eparts a .entet of con.H2SO4 lad)
il.anipart il.ani1 et of con.H2SO4,ione
.entpart a l
t
.ani.entepart of con.HNOla3 il.ani.ente
t
a sl asl a s a sl a s
adsa adsa adsa adsa adsa
w.wp.apda29. Shape of AX7winter .wp.apda halogen compound w.wp.apda w .wp.apda w .wp.apda w
ww ww ww ww ww ww
a) Square pyramidal b) pentagonal bipyramidal c) T shaped d) Linear
il.ai n.entet ail.ai n.entet .i n.entet
il.aiT shaped d) Linear .i n.entet n.entet
30.
a
dsaaslaStructure of XeOF4aa)
ds
a aslSquare pyramidal b) ads
a aslaila
pentagonal bipyramidaladsaaslac) adsaaslaila
ada ada .p.apda p.apda ada
w.wp.p w.wp.p 3 ww w w.w w.wp.p w
ww w
31. Hybridisation in XeF4
w (a) sp d
w (b) sp d 3 2 w 3 3
(c) sp d
w (d) sp 3
w w ww
t t t t t
l a i
l.ani.ente l a i
l .ani.ente l a i
l .ani.ente
sas sas sas sas sas
.
w p.apdaada .
wp.apdaada .
w papdaada
. .
w p.apdaada .
w p.apdaada
w w w w w w
ww ww ww ww ww ww
14
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
t t tet tet tet t t

il.ani.ene i.ani.en
4. TRANSITION AND INNER i.ani.en i.ani.en il.ani.ene
a
adsa sl a
adsaaslal saaslal TRANSITION ELEMENTS
adsaaslal ad a
adsa sl a
ww ww ww ww ww ww
1. Sc ( Z=21) is a transition element but Zinc (z=30) is not because ……………..
t t 3+ t t t etet
il.ani.eneSc and Zn ions .ani.entecolourless and form ente ente
2+
s
(a)laboth
as s alailare
s s as lail.ani.white compounds.lail.ani.
s as s asl ail.ani.n
ada daada aa daada ada
w .wp.apda (b) in case of Sc,w3d
.wp.aporbital are partially
w p.apdadbut in Zn theseware
.w
filled .wp.apcompletely filled w .wp.apda w
ww ww ww ww ww ww
(c) last electron as assumed to be added to 4s level in case of zinc
t t t t t
l a i
l .ani.ente l a i
l.ani.ente l ail.ani.ente l a i
l .ani.ente
l ail.ani.ente
sas both Sc and Zn do
(d) sas exhibit variable oxidation
not sas states sas sas
.
w p.apdaada .
w p.apdaada .
w p.apdaada .
w p.apdaada.wpapdaada
.
w w w ww w w
ww ww ww
2. Which of the following d block element has half filled penultimate d sub shell aswwell ww
as half filled ww
valence
n.entesub
t shell? (a) Crn.entet (b) Pd (c)t Ptt (d) nonenof t these
t t t
a l a il.ai a l ail.ai a l a il.ani.ene a l a il.ai.ene a l a il.ani.ene
asas adsas s
daadsaone adsas ss
apdaada
pdadAmong the transition
2+
w .wp.a3. w .wp.apda metals of 3d series,
w .wp.apthe w .wp.apda negative (M / M)
that has highest w .wp.standard w
ww ww ww ww ww ww
electrode potential is …………….. (a) Ti (b) Cu (c) Mn (d) Zn
.ni.ene t t .ni.ene t tene of unpaired electrons t t
.ni.ene as present in Vl3+ .ni.ene t t t t
4. Which
aslaila one of the following lail.ani.
aslailaions has the sameasnumber aslaila asail?a
adsa adsa asa asa adsa
w.wp.apda (a) Ti3+ w .
wp.apda3+ w .
w pdad
p.a2+ w.wp3+.apdad w .wp.apda w
ww ww (b) Fe (c) Ni
ww (d)
ww Cr ww ww
5. The magnetic moment of Mn2+ ion is ……………..
Padasalai.Net
asl asl asl asl asl
ada (a) 5.92BM
s ad(b)
sa 2.80BM (c)
ada8.95BM
s (d)ad3.90BM
s
a s
ada
ww 6. The catalytic w
w w
behaviour of transitionwmetals and their compounds ww is ascribed mainly ww due to ww
(a)i.ntheir t t t t t t
l a l a i.ente magnetic behavior
l i.ni.ene
a la
(b) their unfilled
l a i
l .ani.ented orbitals l ail.ani.ente l a i
l .ani.ente
sas a
daadsas variable oxidation saas sas sas
.
wp.apdaada (c) their ability .to
wp.apadopt .
w p.apdaadstates(d) their .
w .apdaada reactivity
chemical
p .wp.apdaada
w w w w w w
ww ww ww ww ww ww
7. The correct order of increasing oxidizing power in the series ……………..
t t t tet t t t t
(a)
la i.ente+2 < Cr2O7−2 < MnO
il.anVO l a il4.an–i.ene .ani.en+2 < MnO4–
(b) Cr2O7s−2asl<ailVO l a il.ani.ene l a il.ani.ene
a
adsas a
adsas ada a
asas a
adsas
.wp.apda −2 .wp.apd–a .wp.apda – p.apdad
+2.w .wp.apda
ww
w (c) Cr2O7 w < wMnO4 < VO+2
w w −2
(d) MnO4 < Cr2O7 < wVO
ww w w
ww
w
ww
w
8. In acidenmedium,
tet potassium permanganate
entet oxidizes eoxalic
ntet acid to ……………..
entet t t
a l a il.ani. a l a il.ani. a la il.ani. a l a il.ani. a l a il.ani.ene
adsa s adsas adsa s s s s s
.wp.apda (a) Oxalate w.wp.apda (b) Carbon dioxide .wp.apda (c) acetate .wp.apdaada (d) acetic acid.wp.apdaada
w w w w w
ww ww ww ww ww ww
9. Which of the following statements is not true?
t etet etet a milky colour is .entet etet
(a)
l i.entepassing H2S, through
ail.anon lail.ani.nacidified K2Cr2Os7assolution,
l ail.ani.n lail.aniobserved. l ail.ani.n
s
ada as s
ada as ada s
ada as s
ada as
w.wp.apda (b) Na Cr O iswpreferred .wp.apda over K Cr w
O .apdavolumetric
.wpin w
analysis.wp.apda w.wp.apda w
ww 2 2 w7w 2 ww2 7 ww ww ww
(c) K2Cr2O7 solution in acidic medium is orange in colour
t t t t t
l a i
l.ani.ente l a i
l .ani.ente l a i
l .ani.ente
sas(d) K2Cr2O7 solution sas
becomes sas
yellow on increasing the pH beyond sa7s sas
.
w p.apdaada .
wp.apdaada .
w papdaada
. .
w p.apdaada .
w p.apdaada
w w w w w w
ww ww ww ww ww ww
15
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
.ni.ene t t .ni.ene t t t t t t t t
10. Permanganate
aslaila ion changes
aslailato in acidic medium il.ani.ene
asla…………….. a l a il.ani.ene a l a il.ani.ene
w .wp.apda (a) MnO −2 w.wp.apda (b) Mn2+ w .wp.apda(c) Mn3+ w pdad
ww 4 ww ww ww MnO2 ww ww
11. How many moles of I2 are liberated when 1 mole of potassium dichromate react with
etet etet etet
etet etet
asl ail.ani.n asl ail.ani.n aslasl ail.ani.n
ail.ani.n asl ail.ani.n
potassiums
ada iodide? (a) a1daada
s (b) 2adaada
(c) 3 adaadas s (d) 4 adaada
s
.wp.apda w.wp.p w.wp.p
.wp.p .p.p
ww
w
ww w w w
ww w ww w ww
w
12. The number of moles of acidified KMnO4 required to oxidize 1 mole of ferrous oxalate(FeC O ) 2 4
is …………..i.ni.entet (a) 5 i
tet 3
.ani.en(b) (c) 0.6i.ni.entet (d) 1.5 i .ani.ente
t
i .ani.ente
t
l a l a l a l l a la l a l l a l
aas
daadsWhich
a13.
sas
apdaada
sas a
daadsas
apdaada to lanthanons.wpis.apincorrect?
sas
apdaada
w .
w p. p one of the
w .
w pfollowing
. statements w .
w related
p. w w .
w p. w
ww ww ww ww ww ww
(a) Europium shows +2 oxidation state.
t t t t t t t t
(b)
l a i.ente basicity decreases
il.anThe l a .entethe
il.anias ionic radius l a il.ani.ene
decreases from Pr to Lu.
l a il.ani.ene l a il.ani.ene
a
adsas a
adsas a
adsas a
adsas a
adsas
ww ww
(c) All the lanthanons are much more ww reactive than aluminium. ww ww ww
(d) Cet4+t solutions are widelyt used
t as oxidising agents
t t
in volumetric analysis.
t t t t
sa s
14.adWhich of the following s
adsalanthanoid ions is adiamagnetic?
adsas adsa s adsa s
w.wp.apda w .wp.apda w.wp.pda w.wp.apda w .wp.apda w
ww 2+ ww 2+ ww 2+ ww 2+ ww ww
(a) Eu (b) Yb (c) Ce (d) Sm
15. Which t t t t t t t t etet
i.ani.enofe the following oxidation
i.ani.ene states is most common
i.ani.ene among the lanthanoids?
i.ani.ene ail.ani.n
Padasalai.Net
lal lal lal lal l
d adsaas d adsaas d adsaas d adsaas s
ada as
a
w.wp.p
a (a) 4 a a
w.wp.p (b) 2
a a
w.wp.p (c) 5
a a
p 3
w.wp.(d) w .wp.apda w
ww ww ww ww ww ww
16. Assertion: Ce4+ is used as an oxidizing agent in volumetric analysis.
entet entet .ani.ente
t entet .ani.ente
t
ail.ani. Ce4+ has the tendency
sReason:
i.ani. of attaining +3aoxidation
saaslal
i.ani.
saslal ail
state. a i
l
apdaad aasl apdaad apdaad
sas
apdaada
l sas
apdaada
l
w .
wp. .
w p.
w and reason are true
w .
w p. .
w p. .wp.
ww ww
(a) Both assertion ww
ww and reason is thewcorrect explanation of ww
w
assertion. ww
w
(b) Both assertion and reason are true but reason tisetnot the correct explanation of assertion. tet
n entet n entet n en n entet en
saas
i
lal.a i.
s
a as
i
lal .
a i .
s
a as
i
lal .
a i .
s
a as
i
lal .
a i .
s
a aslail.ani.
a a a a a
w.w p.apdad (c) Assertion is true p.apdadbut reason is false.p.a.pdad
w.w w.w p.apdad w.w p.apdad w.w w
ww ww ww ww ww ww
(d) Both assertion and reason are false.
t etet t (b) +3 ail.ani.entet (c) +4 t
l a.ani.ente common oxidation
17. Theailmost ail.ani.nstate of actinoids is
l a l a i.ente+2
ail.an(a) l
(d)
l a i.ente
il.an+6
a
asa s a
adsas a
adsa s a
adsa s a
adsa s
w .apdadThe actinoid elements
.wp18. w .wp.apda which show thewhighest
.wp.apda oxidation state
w .apda+7
.wpof are …………… w .wp.apda w
ww ww ww ww ww ww
(a) Np, Pu, Am (b) U, Fm, Th (c) U, Th, Md (d) Es, No, Lr
etet i.ente
t etet etet etet
19.aWhich
s asl ail.ani.none of the following s aslail.anis not correct? s asl ail.ani.n s aslail.ani.n s asl ail.ani.n
da ada ada ada ada
ww (a) La(OH)2wiswless basic than Lu(OH) ww3 (b) In lanthanoid series ww ionic radius of Lnwwions decreases
3+
ww
(c) Laetis
et actually an elementetof
et transition metal series
etet rather than lanthanide
etet series t
l ail.ani.n l ail.ani.n l ail.ani.n l ail.ani.n l a i
l .ani.ente
adaada (d) Atomic radii.wpof adaand Hf are same because
adaZr adaada of lanthanide.wpcontraction
adaada apdaada
w w.wp.p w w .p w w.wp.p w w .p w .
w p. w
w w w w ww ww
16
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
t t t t t t t t t t
ADDITIONAL
a l a il.ani.eneQUESTIONS : alail.ani.ene a l a il.ani.ene a l a il.ani.ene a l a il.ani.ene
asa s asa s asa s asa s adsa s
w pdad
.wp.a1. w .
w p.apdad w .
w p.apdad w .
ww Identify the transition
ww metal present
wwin Hemoglobin ………….. ww ww ww
(a) Cobalt (b) Iron (c) Manganese (d) Copper
2. adWhich
s
a of the following adatransition metal isad
s present
s
ada in Vitamin B12a?daada
s s
ada
w .wp.apda w .wp.apda w.wp.pa w.wp.p w .wp.apda w
ww (a) Cobalt ww (b) Platinum ww (c) Copper ww (d) Iron ww ww
l a l ni.entet electronic configuration

3. Thei.correct
a l a i
l.ani.ente
t of Cr is …………..
l ail.ani.ente
t
l ail.ani.ente
t
l a i
l .ani.ente
t
sas saas dsaa5s 4s1 aas
daads[Ar] sas
.
w p.apdaada (a) [Ar] 3d4 4s2 .wp.apdaad(b) [Ar] 3d 5
(c) [Ar]
.
w p.apdaa3d .wpa(d)
. p 3d6 .
w p.apdaada
w w w w w w
ww ww ww w w ww ww
4. Which of the following is the correct electronic configuration of copper?
t tet 10 1 .ente9t 4s2 tet t t
(a)
l a i.ente 3d5 4s1
il.an[Ar] (b)l a il.ani.en3d
[Ar] 4s (c) [Ar]
l a il.ani3d l a il.ani.en[Ar]
(d) 3d8
4s 2
4p 1
l a il.ani.ene
a
adsas a
adsas a
adsas a
adsas a
adsas
ww 5. Which one of ww the following is the general ww electronic configuration ww of transition welements?w ww
(a) [Noble
t t
gas] ns2 np6 t t (b) [Noblet tgas] ( n – 2 ) f (n-l)d 1-14
t t
1-10
ns2 t t
n
il.ai e
. ne n
.ai
il1-10e
. n e il.ani.ene il.ani.e2ne il.ani.ene
as l a asl a 1-14 2 asl a asl
1-10a a sl a
adsa (c) [Noble gas] ( nad–aad1sa) d (n-l)f ns apda(d) adsa[Noble gas] ( n – 1 )addsa ns adsa
w.wp.apda w .wp.p w.wp. w.wp.apda w .wp.apda w
ww ww ww ww ww ww
6. Which of the following d-block elements has the highest electrical conductivity at room
temperature? etet (a) Copper i.ani.entet (b) Silver i.ani(c) t
eteAluminium tet
(d)eTungsten etet
ail.ani.n a l .n ail.ani.n ail.ani.n
Padasalai.Net
aa aa ada ada ada
w pdadWhich one of the
.wp.a7. w .apdad
.wpfollowing is .wp.apdain nature?
diamagnetic
w w .wp.apda w .wp.apda w
ww ww ww ww ww ww
(a) Ti3+ (b) Cu2+ (c) Zn2+ (d) V3+
t
ail.ani. of the followingsapair
8. sWhich ail.ani. i.ani. i.ani.
saaslal of unpaired electrons?
saaslal a i
l
adaad aasl ad asl has maximum number
a a sas
apdaada
l
w.wp.p 2+ 3+ w .wp.apda 3+ p.apdad 3+
2+ ww.w p.apdad 2+ 3+
4+ ww.w w.wp. w
w w (a) Mn , Fe
w w (b) CO , Fe w (c) Cr , Mn w (d) Ti , V ww ww
9. Which one of the following is tZeigler – Natta catalyst?
i.ani.entet i .
a ni enet
. t t
il.ani.ene
t t
il.ani.ene
t t
il.ani.ene
asas asas asas (c) TiCl4 + Al(Ca2dHasas adsas
w.w p.apdad (a) CO2(CO)8 p.apdad(b) Rh/Ir complexp.apdad
w.w w.w p.pad5)3 (d) Fe / Mo w.w w .wp.apda w
ww ww ww ww ww ww
10. Which one of the following is used as a catalyst in the polymerisation of propylene?
t t t t nte5)t3 ni.entet t t
a
(a)
l a il.anVi.e2nOe5 a l il.ani.ene
(b)aPt (c) TiCl4 + Al(C
a la il.an2i.eH (d) Fe a/il.aMo
a l a l a il.ani.ene
asa s asas adsa s adsa s adsa s
.wp.a11. w .apdad
.wpfollowing oxide is .wp.apda
amphoteric
w in nature? w .wp.apda w .wp.apda w
ww ww ww ww ww ww
(a) CrO (b) Cr2O3 (c) Mn2O7 (d) MnO
l ni.entet
ail.a l
etet
ail.ani.n −2
l ail.anCr
t
i.ente −2 l
etet
ail.ani.n l
etet
ail.ani.n
12.asThe
as oxidation state of Chromium
s as in CrO 4 ands as in 2 O 7 are ………….. s as s as
da ada ada ada ada
ww (a) +3, +6 ww (b) +7, +4 ww (c) +6, +6 ww (d) +4, +6 ww ww
13. Whicheone
tet of the following isetthe
et formula of chromyl
etetchloride? t t
l ail.ani.n l ail.ani.n l ail.ani.n l a i
l .ani.ente l a i
l .ani.ente
s as s as s as sas sas
adaada (a) CrOCl2 a CrCl
adaad(b) a
ada2adCl
(c) CrO (d) CrCl apdaada apdaada
w.wp.p w.wp.p w.wp.p p. p.
3 2 . .
w w w w w w w w
w w w ww ww ww
17
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
.ni.ene t t .ni.ene t t.ni.ene t t t t t t

14. Which
aslaila one of the following
aslailageometry is possesed i.ni.ene
aslailaby permanganateaion? il.ani.ene
adsa adsa adsa slala
asa a
adsa sl a
w pdad
.wp.apda (a) Pyramidal w.wp.apda (b) Tetrahedral w.wp.apda(c) Octahedral w.wp.a(d) w .wp.apda w
ww ww ww ww linear ww ww
15. Which one of the following is known as Baeyer’s reagent?
ada (a) Cold dilute alkaline
s ada KMnO4
s s
ada (b) Chromyl Chloride s
ada s
ada
ww ww
(c) Acidified potassium dichromate ww ww
(d) Acidified potassium manganate ww ww
16. Baeyer’s t treagent is used to.ndetect

t t unsaturation in an t torganic compound. t t .ani.ente
t
i.ni.ene
lala i i.ene
lala i.ni.ene
lala i.ni.ene lala l a i
l
a adsaas sas
apdaada
w.wp. p (a) Chloride ion
w.wp.p (b) unsaturated
w.wp. p organic compound
w.wp. p w .
w p. w
ww ww ww ww ww ww
(c) Sulphate ion (d) Chromate ion
tet et
i.entthe t t t t t t
17. sWhich
a l a il.ani.enone of the followinga l ail.anis main cause aof
l a il.ani.ene
lanthanoid contraction? a l a il.ani.ene a l a il.ani.ene
ww (a) Poor shielding ww effect of 5f sub-shell ww (b) More wwshielding effect of 4fwsub-shell w ww
(c) Poor
t t
shielding effect of 4ft tsub-shell (d)t More
t shielding effectt of t 5f sub-shell t t
n
il.ai e
. ne n
il.ai e
. n e n
il.ai e
. ne n
il.ai e
.n e il.ani.ene
a sl a asl a asl a asl a a sl a
18.adsWhich
a of the following adsapair has more or less adssame
a adsa to lanthanide contraction?
atomic radiusapdadue adsa
w.wp.apda w .wp.apda w.wp.apda w.wp. w .wp.apda w
ww ww ww ww ww ww
(a) Ti and V (b) Fm and Md (c) No and Lr (d) Zr and Hf
19. Which tet of the following.nis tet t t etet etet
i.ani.enone iai.enmore basic in nature?
i.ani.ene ail.ani.n ail.ani.n
Padasalai.Net
lal lal lal l l
adsaas adsaas adsaas s
aa as s
ada as
a
w.wp.p
da a d
a a d
a
(a) La(OH)3 ww.wp.p (b) Ce(OH)3 ww.wp.p (c) Gd(OH)3 w pdadLu(OH)3
ww w w ww ww ww
20. Assertion (A) – In transition metal series, the ionization enthalpy increases.
entet entet entet entet entet
ail.ani. (R) – This is due
sReason saasto
ni.
lail.aincrease in nuclear lail.ani. corresponding
saascharge
ni. filling of d electrons.
lail.athe
saasto
i.ani.
saaslal
adaad aasl ad ad adaad adaad
w.wp.p (a) Both (A) and .wp.apda
w(R) w .wp.apda w.wp.p w.wp.p w
w w w w w
are correct andw(R) explains (A). w w w w ww
(b) Bothte(A)
t and (R) are correct
tetbut (R) is not the correct
tet explanation of (A).tet t t
a
en
lail.ani. a
en
lail.ani. a
en
lail.ani. a
en
sa s s
a s sa s sa s adsas
adaad(c) (A) is correct but ad is wrong.
ada(R) adaad adaad .wp.apda
w w w w ww ww
(d) (A) is wrong but (R) is correct.
21. Which etet i.ente
t
.ani.ente
t etet t t
il.ani.ene
aail.ani.none of the following
sl a aslail.anelements
a
show highailnegative
a sl a
electrode potential?
ail.ani.n
a sl a a sl a
w.wp.apda (a) Copper w .wp.apda (b) Manganese w.wp.apda (c) Cobalt w .wp.apda (d) Zinc w .wp.apda w
ww ww ww ww ww ww
22. Which one of the following transition element has maximum oxidation states?
t t t t i.ente
t tet etet
(a)
a l il.ani.ene
aManganese (b)
a l il.ani.ene
aCopper a l ail.an(c) Scandium a l il.ani.enTitanium
a(d) a l ail.ani.n
s
ada s s
ada s s
ada s s
ada s s
ada s
ww ww ww ww ww ww
t t t t t
l a i
l.ani.ente l a i
l .ani.ente l a i
l .ani.ente
sas sas sas sas sas
.
w p.apdaada .
wp.apdaada .
w papdaada
. .
w p.apdaada .
w p.apdaada
w w w w w w
ww ww ww ww ww ww
18
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
t t tet tet tet t t

il.ani.ene il.ani.en5. COORDINATION i.ani.en CHEMISTRY alail.ani.en il.ani.ene
a
adsa sl a a
adsa sl a saaslalad sas ad a
adsa sl a
ww ww ww ww ww ww
1. The sum of primary valance and secondary valance of the metal M in the complex
t ente t
ente t t t etet
[M(en)
lail.an2i.(Ox)]Cl is ……………..lail.ani. (a) 3 (b) 6lail.ani.ente (c) -3 l il.ani.en9e
a(d) l ail.ani.n
s
ada as s as s as s as s as
.wp.apda2. An excess of silver daada
.wp.apnitrate
ada
.wp.apda of a 0.01M solution
ada
.wp.apdaof penta aquachlorido .wp.apda
ada
ww
w
ww
w is added
wwtow100ml ww
w
ww
w
ww
w
chromium (III) chloride. The number of moles of AgCl precipitated would be ……………..
t t t t t
l a i
l .ani.ente l a i
l .ani.ente
sas(a) 0.02 as 0.002
s(b) (c)sa0.01
s as
(d) s0.2 sas
.
w p.apdaada .
w p.apdaada .
. .
w p.apdaada
w w w w w w
ww 3. A complex has ww a molecular formula wwMSO4Cl. 6H2O. The aqueous ww solution of it gives ww white ww
precipitate
n.entet with Barium chloride
n.entetsolution and no precipitate
n.entet is obtained when
n.entet it is treated with n.entet
i.ai i.ai i.ai i.ai i.ai
dadsaaslal d a
dsaaslal dadsaaslal d adsaaslal d a
d saaslal
a asilver nitrate solution.
a aIf the secondary valence
a a of the metal is six, a
a which aa
one of the following
w.wp.p w.wp.p w.wp.p w.wp.p w.wp.p w
ww ww ww ww ww ww
correctly represents the complex?
t t t t t t t t t
(a) i.ente 2O)4Cl] SO2. 2Hla2O
il.an[M(H il.ani.ene (b) [M(H2O) .ni.ene il.ani.ene il.ani.ene
a
adsa sl a a
asa s asla6il]aSO4
asa a
asa sl a a
adsa sl a
w.wp.apda (C)[M(H O) Cl]w.SO wp.apdad w .
w p.apdad w.wp.apdad w .wp.apda w
ww 5w
2 w 4. H 2O (d) [M(H2O)3Cl] SO4. 3H
ww ww2O ww ww
4. Oxidation state of Iron and the charge on the ligand NO in [Fe(H 2O)5NO] SO4 are ……………..
Padasalai.Net
asl asl asl asl asl
ada (a) +2 and 0 respectively
s s
ada (b)
ada+3 and 0 respectively
s s
ada s
ada
ww (c) +3 and w
w
-1 respectively ww ww
(d) +1 and +1 respectively ww ww
5. As per t
tIUPAC guidelines, the t
tname of the complex t t
[CO(en) 2 (ONO)Cl]Cl.is t t
…………….. t
i.ni.ene
lala i.ni.ene
lala i.ni.ene
lala lalai ni.ene l a i
l .ani.ente
a daadsaas a daadsaas a daadsaas a daadsaas sas
apdaada
w.wp. p (a) chlorobisethylenediaminenitritocobalt
w.wp. p w.wp. (III) chloride ww.wp.
p p w.wp. w
ww ww ww w ww ww
(b chloridobis (ethane-1, 2-diamine) nitro k – Ocobaltate (III) chloride
(c)
la ni.entet
il.achloridobis (ethane-1, l a i.ente
t
il.an2-diammine) nitrito lak
tet
il.an–i.enOcobalt (II) chloride l a
t t
il.ani.ene l a
t t
il.ani.ene
a
adsas a
adsas a
adsas a
adsas a
adsas
ww (d) chloridobis ww (ethane-1, 2-diamine) ww nitro k – Ocobalt (III) ww chloride ww ww
6. IUPAC tname
t of the complex Kt 3t[Al(C2O4)3] is ……………..
t t t t t t
s
adsa (a) potassiumtrioxalatoaluminium
adsas s
(III) apdaadsa (b) potassiumtrioxalatoaluminate
adsa s (II) adsa s
w.wp.apda w .wp.apda w .wp. w .wp.apda w .wp.apda w
ww ww ww ww ww ww
(c) potassiumtrisoxalatoaluminate (III) (d) potassiumtrioxalatoaluminate (III)
7. A magnetic t t moment of 1.73BM t t t
i.ente among the following t t etet
lali.ani.ene i.ani.ene will be shown byi.anone
lal l al i.ani.ene……………..
lal l ail.ani.n
d adsaas s
ada as s
ada as s
ada as s
2- apdaada
as
a
w.wp.p
a (a) TiCl4 w .wp.apda (b) [COCl6]4- w.wp.apda(c) [Cu(NH3)4]2+ w.wp.apda (d) [Ni(CN) p.
4]w.w w
ww ww ww ww ww ww
8. Crystal field stabilization energy for high spin d5 octahedral complex is ……………..
t
lail.an–i. 0.6∆0
saas(a) s(b) ail.ani.
aasl 0 (c) 2 (P –sa∆as0la) il.ani. (d) 2 (P + ∆sa0a)slail.ani. sasl a i
l
adaad adaad adaad adaad apdaada
w p. w
w w w w ww ww
19
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
t t t t t t t t t t
9. In il.ani.ene of the following
aslawhich
ee
l.ani.n
aslaicoordination entities
aslathe
e
il.ani.enmagnitude .enemaximum?
i.nibe
of ∆0awill il.ani.ene
adsa adsa asa slala asa a
asa sl a
w .wp.apda (a) [CO(CN) ]3-w.wp.apda w .
w p.apdad3- w .
w p.apdad 3+ w .
w p.apdad 3+ w
ww w6w (b) [CO(C
ww 2O4)3] (c)
ww[CO(H2O)6] (d)w[CO(NH
w 3)6] ww
10. Which one of the following will give a pair of enantiomorphs?
ada (a) [Cr(NH3)6][CO(CN)
s ada6]
s (b)
ada[CO(en)2Cl2]Cl adaada
s s s
ada
w .wp.apda w .wp.apda w.wp.apda w.wp.p w .wp.apda w
ww ww
(c) [Pt(NH3)4][PtCl4] ww ww
(d) [CO(NH3)4Cl2]NO2 ww ww
11. Which t ttype of isomerism.nis t

texhibited et2] ?
by [Pt(NHi.3ni).e2ntCl .ani.ente
t
.ani.ente
t
i.ni.ene
lala i i.ene
lala l a la l ail l a i
l
apda(b)
sas
apdaada
sas
apdaada
w.wp. p (a) Coordination
w.wp.isomerism
p w .
w p. Linkage isomerism
w.wp. w .
w p. w
ww ww ww ww ww ww
(c) Optical isomerism (d) Geometrical isomerism
tet t t tet ntet t t
12. aHow
l a il.ani.enmany geometrical a l ail.ani.ene are possiblealfor
isomers a il.ani[.enPt (Py) (NH 3 ) (Br)a (Cl)
l a il.ani.e]? a l a il.ani.ene
ww (a) 3 ww (6) 4 (c) 0 ww (d) 15 ww ww ww
13. Whicht tone of the following tpairs
t represents linkage
t t
isomers? t t t t
s
adsa (a) [Cu(NH3)4] [PtCl s
sand [Pt(NH3)4] [CuCld4a]dsa
4a]da
s adsa s adsa s
w.wp.apda w .wp.apda aa
w.wp.p w.wp.apda w .wp.apda w
w w w w w w ww ww ww
(b) [CO(NH3)5(NO3)]SO4 and [CO(NH3)5(ONO)]
etet 3)4(NCS)2]Cl and
(c)i.a[CO(NH tet
e[CO(NH 3)4(SCN)2]Cl i.ni.ente
t etet etet
al ni.n ail.ani.n ail.ani.n ail.ani.n
Padasalai.Net
s asl s asl s asl a la s asl s asl
ada aa ada ada ada
w.wp.apda (d) both (b) and w .apdad
.wp(c) w .wp.apda w .wp.apda w .wp.apda w
ww ww ww ww ww ww
14. Which kind of isomerism is possible for a complex [CO(NH3)4Br2]Cl ?
t
lail.angeometrical
saas(a)
i. i.ani.
saaslal
and ionization lail.ani.
(b)saasgeometrical and optical i.ani.
saaslal sasl a i
l
adaad .wp.apda
ad adaad adaad apdaada
w w.wp.p w w w w.wp.p (d) geometrical wonly
w.wp.p w.wp. w
w (c) optical and
w ionization w w ww ww
15. Whichtetone of the following tcomplexes
et
is not expected
tet to exhibit isomerism?
tet t t
adsas(a) [Ni(NH3)4(H2O)a2da]adsas
2+
ads]as (C) [CO(NH3)5SO
(b) [Pt(NH3p).2apdCl sas (d) [Fe(en)3]
ad]Cl 3+
adsas
w .wp.apda w .wp.p w.w a 2 w.wp.apda4 w .wp.apda w
ww ww ww ww ww ww
16. A complex in which the oxidation number of the metal is zero is ……………..
tet t t t
i.ente[Fe(CO)5] tet (b) and (c) t t
a
(a)
l a il.anKi.e4n[Fe(CN)6]
a l il.ani.ene 3(NH3)3]
(b)a[Fe(CN)
a la il.an(c) a l a il.ani.enboth
(d)
a l a il.ani.ene
adsa s asas asa s adsa s adsa s
w.wp.apda17. Formula of tris w p.apdad
.w
(ethane-1, 2-diamine)
w .apdad(II) phosphate ……………..
.wpiron w .wp.apda w .wp.apda w
ww ww ww ww ww ww
(a) [Fe(CH3 – CH(NH2)2)3] (PO4)3 (b) [Fe(H2N – CH2 – CH2 – NH2)3] (PO4)
l ni.entet
ail.a[Fe(H l ni.entet
a–il.aNH l i.ente
ail.an(d)
t
l
etet etet
ail.an2i.n– NH2)3](PO4)2 saslail.ani.n
s
ada a(c)
s 2 N – CH 2 – CHs
ada as
2 2 )3 ](PO 4 )2 s
ada as [Fe(H 2 N – CH 2s
ada–as CH ada
ww 18. Which of the ww following is paramagnetic ww in nature? ww ww ww
2+ 3+ 2+
(a) [Zn(NH
etet 3)4] (b) [CO(NH
etet 3)6] (c) [Ni(He2tO)
et 6] (d) [Ni(CN)et4e]2-
t t
l .ani.ente
adaada adaada adaada adaada apdaada
w p. w
w w w w ww ww
20
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
t t
ene .ni.ene t t t t t t t t
lail.ani. isomerism is shown
19.asFacmer aslaila by …………….. a l a il.ani.ene a l a il.ani.ene a l a il.ani.ene
adsa adsa adsa s asa s asa s
w .wp.apda (a) [CO(en) ]3+w.wp.apda (b) [CO(NH ) (Cl)
w .wp]+.apda(c) [CO(NH ) (Cl) w .
w p.apdad w .
w p.apdad w
ww w3 w 3w4w 2 3 3 ww3] (d) [CO(NH3w )5w
Cl]SO4 ww
20. Choose the correct statement.
a(a)
da Square planar complexes
s s
ada are more stable adthan
sa octahedral complexes s
ada s
ada
ww ww ww 2- ww
(b) The spin only magnetic moment of [Cu(Cl) 4] is 1.732 BM and it has square planar structure. ww ww
(c) Crystal t
t field splitting energy t(Δt ) of [FeF6]4- is higher t tthan the (Δ0) of [Fe(CN) t t ]4- .ani.ente
t
i.ni.ene
l a l a i.ni.ene 0
l a l a i.ni.ene
l a la i.ni.ene 6
l a l a l a i
l
adsaas
apda(d)
sas
apdaada energy of [V(H
as
daadsa]2+
a2pO)
saas
apdaadcrystal
sas
apdaada of
w .
w p. crystal field stabilization
w .
w p. w .
w p. 6 is higher than
w.wthe
p. field stabilization
w .
w p. w
ww ww ww ww ww ww
2+
[Ti(H2O)6]
etet
i.ani.n QUESTIONS : alail.ani.n etet t t
il.ani.ene
t t
il.ani.ene
t t
il.ani.ene
ADDITIONAL
saslal ss a l a a l a a l a
ww wwprimary and secondary
1. What are ww valency of cobalt in ww
COCl3.6NH3? ww ww
(a)t 3,
t 3 (b) 6, 3 t t (c) 3, 6 (d)t 6,t 6 t t t t
n
il.ai e
. ne n
il.ai e
. n e n
il.ai e
asl a a sl a asl a a sl a a sl a
adsa 2. Consider the following adsa statements. apdaadsa adsa adsa
w.wp.apda w .wp.apda w .wp. w.wp.apda w .wp.apda w
ww ww ww ww ww ww
(i) The outer sphere in coordination compound is called ionisation sphere.
t primary valences
eteThe
(ii) t non directional nwhile
eteare etet secondary valences etetare directional. i.ani.entet
ail.ani.n ail.ani.n ail.ai.n ail.ani.n
Padasalai.Net
a l a l a l a l lal
a da
s
ada s
a d
a
s
ada s
a d
a
s
ada s
a d
a
s
ada s
a daadsaas
w.wp.p w.wp.p valances of a metal
(iii) The primary w.wp.pion is negative and .psatisfied by positive
wit.wpis .p
w.wpions. w
ww ww ww ww ww ww
Which of the above statements is/are not correct? .
t tet t t t
l ail i.ente(i) and (ii)
.an(a) l a i
l.ani.en(b) (ii) and (iii) l a i
l i.ente(iii) only (d) (ii)laonly
.an(c) i
l .ani.ente l a i
l .ani.ente
sas sas sas sas sas
.
w p.apdaada .
w w w w w w
ww 3. Which of wwthe following is called wwLewis acid in [Ni (CO) w4w]? ww ww
2+ 4+
(a)teNi (b) CO tet (c) Ni tet (d) CO
i.ani.en t i .
a ni en
. il.ani.en
t t
il.ani.ene
t t
il.ani.ene
adsas4. The oxidationastate adsas of Fe in [Fe(CN)6a]daadissa……………..
4- s adsas adsas
w .wp.apda w .wp.pda w.wp.p w.wp.apda w .wp.apda w
ww ww ww ww ww ww
(a) II (b) III (c) VI (d) IV
t t t t t t t t t
l i.ente is the coordination
5.ail.anWhat
l a il.ani.enenumber of Pt inal[Pt(NO
a il.ani.ene 2)(H2O)(NH3)2]Br? l a il.ani.ene l a il.ani.ene
a
adsa s a
adsas adsa s a
adsa s a
adsa s
w.wp.apda (a) 3 w .wp.apda (b) 4 w.wp.apda(c) 2 (d) 5
ww ww ww ww ww ww
6. Which one of the following is a homoleptic complex?
t etet t entet n.entet
l i.ente
ail.an(a) l i.ente
ail.ani.n(b) [Pt (NH3)2 Cls2]aslail.an(c) lai3l.a)n2i.]Br lail.ai
s
ada as [CO(NH 3 ) 3 ](Cl 3s
ada)]
as ada [Pt(NO 2 )(H 2 O)(NH
s
ada as (d) [Co (NH
asa3as)6]Cl3
d
ww 7. Which one ww of the following is wcalled w as Zeise’s salt? ww ww ww
(а) [Ptt (NH3)4] [Pt Cl4] n.en(b) t K[PtCl3(C2H4)] n(c) Kt4[Fe(CN)6] (d)e[Fe t (CO)5] t
l a i
l .ani.ente l ail.ai te l a i
l.ai.ente l a i
l .ani.nte l a i
l .ani.ente
sas sas sas sas sas
.
w p.apdaada .
wp.apdaada .
w papdaada
. .
w p.apdaada .
w p.apdaada
w w w w w w
ww ww ww ww ww ww
21
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
t t t t t t t t t
8.
l a i.ente(NH3)4] [Pt Cl4] islacalled
il.an[Pt il.ani.ene as …………….. alail.ani.ene l a il.ani.ene l a il.ani.ene
a
adsa s a
asa s asa s a
asa s a
asa s
w .wp.apda w .
w p.apdad w .
w p.apdad w .
w p.apdad w .
w p.apdad w
ww (a) Zeigler
ww Natta Catalyst ww(b) Zeises’ salt (c) Magnus’s
ww green salt (d) wwMohr’s salt ww
9. The IUPAC name of K4[Fe (CN)6] is ……………..
s
ada (a) Potassiumahexacyanido
s
ada Ferrate (III) s
ada (b) Potassiumahexacyanidoferrate
s
ada (II) ada
s
w .wp.apda w .wp.pda w.wp.apda w .wp.pda w .wp.apda w
ww ww
(c) Potassium ferrocyanide ww ww
(d) Potassium ferricyanide ww ww
10.i.nThe t t t ) Cl ] Cl is …………….. t t t t
l a l ai.ente IUPAC name of [CO(NH
i.ni.ene 3 4 2
l a l a i.ni.enel a la l ail.ani.ente l a i
l .ani.ente
sas dsaas adsaas dsaas saas
.
w p.apdaada (a) Tetrammine
.
w p.apdaadichlorido cobalt .w .apdachloride
(III)
p (b) .wpapdaatetrammine
Dichlorido
. cobalt.
w p.apdaadchloride
(III)
w w w w w w
ww ww ww ww ww ww
(c) Tetrammine cobalt (III) trichloride (d) Tetrammine dichlorido cobaltate (III)
t t t ntet t t t t
11.
l a i.ente formula of Hexafluorido
il.anThe l ail.ani.ene ferrate (II) ion l a .ani.e……………..
ilis l a il.ani.ene l a il.ani.ene
a
adsas a
adsas a
adsas a
asas a
asas
w .wp.apda w
4- .wp.apda w .wp.apda
3- p.apdad
2-w.w p.apdad
3+ w.w w
ww (a) [Fe Fw6w
] (b) [Feww
F6] (c) [FeFw6]w (d) [FeF6]ww ww
12. [Crt (NH
t 3)4Cl Br]NO, and [Cr
t t
(NH3)4Cl NO2] Br aret examples
t of ……………..
t t t t
adsa s adsa
(a) Linkage isomerism s s
adsaIonisation isomerism
(b) adsa s adsa s
ww ww ww ww ww ww
(c) Coordination isomerism (d) Hydrate isomerism
etet planar complexes
13.i.anSquare t
etehave type of hybridisation etet …………….. i.ani.entet etet
al i.n ail.ani.n ail.ani.n ail.ani.n
Padasalai.Net
a l a l a l lal l
d s
ada s d s
ada s d s
ada 3s d adsaas3 2 s
ada as
a
w.wp.p
a 3 a a
(a) sp ww.wp.p (b) dsp 2 a a
w.wp.p (c) sp d
a a
p sp d
w.wp.(d) w .wp.apda w
ww w ww ww ww ww
14. In octahedral geometry, the type of hybridisation involved is ……………..
t t t t t
l ail i.entesp3d2
.an(a) (b)l adi
l i.ent3e
.a2nsp (c) dsp
l a i
l .an3i.ente (d) a or
l ail.abni.ente l a i
l .ani.ente
sas sas sas sas sas
.
wp.apdaada .
w p.apdaada .
w p.apdaada .
w p.apdaada .
w p.apdaada
w w of [Fe (CN) ]3- is w w w ww w
ww 15. The geometry ww 6 w…………….. ww
(a) Tetrahedral (b)wOctahedral ww
(c)teSquare planar (d) Trigonamal bipyramidaltet
n entet n entet n en t n entet en
s
a as
i
lal.a i.
s
a as
i
lal .
a i .
saas
i
lal .
a i .
saas
i
lal .
a i .
s
a aslail.ani.
adaad 16. Which is used daad the separation of
afor adaad
lanthanides, in softeningadaadof hard water and.wpalso adaadin
w w.wp.p w w.wp.p w w.wp.p w w.wp.p w w .p w
w w w w w ww
removing lead poisoning?
t t t t t ent5e)t3 t t
l a i.ente[Ni (CO)4]
il.an(a) l il.ani.ene
(b)aEDTA (c) [Ni(DMG)
la il2.an]i.ene (d) Ti Cl4 + AI l
(C
a il.an2i.H l a il.ani.ene
a
adsa s a
adsas a
adsa s a
adsa s a
adsa s
w.wp.apda 17. Which complex w .wp.apdais used as an antitumorw .wp.apda drug in cancer w .wp.apda
treatment? w .wp.apda w
ww ww ww ww ww ww
(a) Ca – EDTA chelate (b) EDTA (c) Ti Cl4 + Al(C2H5)3 (d) Cis – Platin
t t t etet etet etet
l i.ente
ail.anThe l il.ani.ene salt is ……………..
aZeise’s l ail.ani.n lail.ani.n l ail.ani.n
s
ada a18.
s IUPAC name of
s
ada as s
ada as s
ada as s
ada as
ww ww
(a) Tetramminecopper ww
(II) sulphate ww
(b) FerrousAmmoniumsulphate ww ww
(c) Tetracyanocopper
t (II) Sulphate
t (d) Potassiumtrichloro
t (ethene)
t platinate (II) etet
l a i
l.ani.ente l a i
l .ani.ente l ail.ani.n
s as s as s as s as s as
adaada adaada adaada adaada adaada
w w.wp.p w w.wp.p w w.wp.p w w.wp.p w w.wp.p w
w w w w w ww
22
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
t ntet …………….. t t t t t t
19.
l a i.ente CFSE is the highest
il.anThe l a il.ani.efor l a il.ani.ene l a il.ani.ene l a il.ani.ene
a
adsa s a
asa s asa as a
asa s a
adsa s
w .wp.apda w p.apdad
2- .w w .
w p.apdad2- w .
w p.apdad 3+ w .
w p.apda2- w
ww (a) [CO wFw4] (b) [CO
ww(NCS)4] (c)
ww[CO (NH3)] (d)w[CO
w Cl4] ww
20. The hybridization involved in the complex [Ni (CN)4]2- is ……………..
etet etet etet n.entet etet
asl ail.ani.n 3 asl ail.a2ni.n 3+ asl ail.an2i.n as 2i
3ail.a
l asl ail.ani.n
s
ada (a) sp ad(b)
sa d sp (c)
adadsp
s (d)adsp
a d
s s
ada
ww 21. Assertion ww(A) – [CO(NH ) Br ]CI wwand [CO(NH ) Cl Br] w w
Br are examples of ionisation ww isomers. ww
3 4 2 3 4
t t t tetthe coordination .ni.entet

i
l .anReason
i.ente (R) – The exchange i
l.ani.ente of counter ionslawith
i
l .ani.enteone or more ligands il.ani.enin ia
d a
dsaasl a
dadsaasl a
d a
d saas d a
dsaasl a
d a
d saaslal
aa entity will w .wp.apa in ionisation isomers.
result aa aa aa
w.wp.p w.wp.p w.wp.p w.wp.p w
ww ww ww ww ww ww
(a) Both A and R are correct and R is not the correct explanation of A.
t t t t t t t t t
l a i.enteBoth A and R arelacorrect
il.an(b) il.ani.ene but R is the a l a il.ani.eneexplanation ofaA.
correct l a il.ani.ene l a il.ani.ene
a
adsas a
adsas adsas adsas a
adsas
ww (c) A andwwR are wrong. ww ww ww ww
(d)t At is wrong but R is correct. t t t t t t t t
a l ail.ai.ene
n
a l a il.ani.ene a l a il.ani.ene a l a il.ani.ene a l a il.ani.ene
ww ww ww ww ww ww
6. SOLID STATE
Padasalai.Net
1. asl asl asl asl asl
ada Graphite and diamond
s ada are ……….. (a) Covalent
s ada and molecular acrystals
s s
ada s
ada
w.wp.apda w .wp.apda w .wp.apda w .wp.pda w .wp.apda w
ww (b) ionic and wwcovalent ww
(c) both covalent crystals ww ww
(d) both molecular crystals ww
2. An iionic t ni.entet t ntet at the centre ofi.ni.entet

lala.ni.ente compound Ax Byi.crystallizes
lala
in fee typei.ncrystal
lala i.ente structure withi.Bni.eions
lala lala
a daadsaas a daadsaas a daadsaas a daadsaas a daadsaas
w.wp. each face and Awion
p w.wpoccupying
. p centre ofwthe
.wp. cube, the correctwformula
p .wp. p of A B is ………..
w.wp. p w
ww w ww ww ww ww
(a) AB (b) AB3 (c) A3B (d) A8B6
t t t t ni.entet t t
3.sThe
la i.ente of close packed
il.anrano l a .ani.ente to tetrahedrallahole
ilatoms il.ani.enein cubic packingalis a il.a……….. l a il.ani.ene
a
adas a
adsas a
adsas adsas a
adsas
w .wp.apda w .wp.apda w .wp.apda w.wp.apda w .wp.apda w
ww (a) 1:1 ww (b) 1:2 ww(c) 2:1 (d)
ww 1:4 ww ww
4. Solid CO
t t2
is an example of ………..
t t t t t t t t
s
adsa (a) Covalent solidadaadsa s adsa
(b) metallic asolid s (c) molecular asolid adsa s adsa
(d) ionic asolid s
w.wp.apda w .wp.p w .wp.pda w .wp.pda w .wp.pda w
ww ww ww ww ww ww
5. Assertion: monoclinic sulphur is an example of monoclinic crystal system.
Reason: tet a monoclinic system, t t et , β ≠ 90°.
.ent90° etet etet
a li.ani.enfor
al a lal i.ani.ene a ≠ b ≠ c and α = iγ.ani=
a l al a lail.ani.n a l ail.ani.n
s
ada s s
aa s s
daada s s
aa s s
ada s
w.wp.apda(a) Both assertion
w p.apdad
and
.w reason are true w .wp.apreason
and is the correct
w .apdad
.wpexplanation of .wp.apda
assertion.
w w
ww ww ww ww ww ww
(b) Both assertion and reason are true but reason is not the correct explanation of assertion.
entet entet
.ani.ente
t
.ani.ente
t
.ani.ente
t
(c) lail.ani.
saasAssertion is true butsareason .ni.
aslaila is false.
sasl a i
l sasl a i
l sasl a i
l
.
w p.apdaad .
wp.apdaad .
w papdaada
. .
w p.apdaada .
w p.apdaada
w w w w w w
ww ww and reason are false.
(d) Both assertion ww ww ww ww
23
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
t t t t t t t t t t
6. In il.ani.ene fluoride, having
aslacalcium
.ni.ene
aslailathe flurite structure
aslathe
e
il.ani.encoordination number .ni.ene 2+ ene
lail.ani.
aslaila of Ca ion and FasIon
adsa adsa asa asa asa
w .wp.apdaare ……….. (a) 4 and
w .wp2.apda w .
w p.apdad w .
w p.apdad w .
w p.apdad w
ww ww (b) 6 and
ww 6 (c) 8 and
ww4 (d) 4 andw8w ww
7. The number of unit cells in 8gm of an element X (atomic mass 40) which crystallizes in bcc
pattern
s
ada is (NA is the Avogadro s
ada number) adaada s s
ada s
ada
w .wp.apda w .wp.apda w.wp.p 22 w .wp.apda w .wp.apda w
ww (a) 6.023 x 10 ww23 ww
(b) 6.023 x 10 ww 23
(c) 60.23 x 10 ww 23
(d) (6.023×10 / (8×40) ww
8. In ai.nsolid t t t lattice and (1/3) of t t t t by atom N.i.ni.entet

lala i.ente atom M occupies
lala
ccp
i.ni.ene lala
tetrahedral
i.ni.ene
voids are occupied
i.ni.ene lala lala
a adsaas a daadsaas
w.wp. Find the formula
p of.wpsolid
w .p formed by M and
w.wp.N.
p w.wp. p w.wp. p w
ww ww ww ww ww ww
(a) MN (b) M3N (C) MN3 (d) M3N2
t t .entet x 10-10 m , thelacoordination t t t t
9.sThe
l a i.ente radii of A+ andlaBil.–anare
il.anionic i.ente 0.98 x 10-10 m and l a il.ani1.81 il.ani.ene number lof
a il.ani.ene
a
adas a
adsas a
adsas a
adsas a
adsas
ww each ion in ABwisw……….. (a) 8 ww
(b) 2 (c) 6 ww (d) 4 ww ww
10. CsCl has t t bcc arrangement, its
t tunit cell edge length t
ist 400pm, its inter atomic t t distance is ……….. t t
n
il.ai e
. n e n
il.ai e
. n e n
il.ai e
. n e n
il.ai e
.n e il.ani.ene
s asl a asl a
sa 800pm asl a asl a a sl a
apdaada (a) 400pm apdaad(b) adsa√3 x 100pm
apda(c)
s
apdaada (d) (√3/2) x 400appm daadsa
w.wp. w.wp. w.wp. w.wp. w.wp. w
ww ww ww ww ww ww
11. A solid compound XY has NaCl structure, if the radius of the cation is 100pm , the radius of the
t ………..
ni.entebe
anioni.awill etet
(a) (100/0.414) (b) (0.732/100) etet (c) 100 x 0.414 etet (d) (0.414/100) i.ani.entet
Padasalai.Net
a l al a l a l a l lal
a d
a
s
ada s
a da
s
ada s
a da
s
ada s
a d
a
s
ada s
a daadsaas
w.wp.p 12. The vacant space
w.wp.pin bcc lattice unitwcellw.wp.pis ……….. w.wp.p w.wp.p w
ww ww w ww ww ww
(a) 48% (b) 23% (c) 32% (d) 26%
ail ntet
.ani.eradius a i
l ni.entet if it crystallizes
.a a i
l .enteat face centered cubic
.aniin ail
et
.ani.entlattice, a i
l .ani.ente
t
13. The
sasl of an atom sasis
l 300pm, sasl sasl the length
sasl of
.
wp.apdaada .
w p.apdaada .wp.apdaada .
w p.apdaada .
w p.apdaada
w w w w w w
ww the edge of the wwunit cell is ……….. ww ww ww ww
(a) 488.5pm
tet (b) 848.5pm (c) 884.5pm (d) 484.5pm
i.ani.en i .
a ni entet
. i .
a ni entet
. t t
il.ani.ene
t t
il.ani.ene
a la l a l a l a la l a l a a l a
adsasThe fraction of total
14. as
adsvolume occupiedpby adsasatoms in a simple
the adsas is ………..
cubic adsas
w .wp.apda w .wp.apda w .w.apda w.wp.apda w .wp.apda w
ww ww ww ww ww ww
(a) (π/ 4√2 ) (b) (π/6) (c) (π/4) (d) (π/ √3/2)
15. The entet .entet is due to ……….. etet t t
il.ani.ene
t t
il.ani.ene
a slail.ani.yellow
a
colour in NaCl
asl aail.anicrystal aail.ani.n
sl a asl a a sl a
adsa asa adsa daadsa – adsa
w.wp.apda (a) excitation w
of .apdad
.wpelectrons in F centers
w .wp.apda(b) reflection of light
w .wp.apfrom Cl ion on the
w .wp.apda
surface w
ww ww ww ww ww ww
(c) refraction of light from Na+ ion (d) all of the above
tet
.ani.enstands ni.entet etet etet .ani.ente
t
16.s asl
If ail’a’ for the edge
s aslail.alength of the cubic s a l ail.ani.n sc ,bcc, and fcc.
system;
s s asl l.ani.n the ratio of radii
aiThen s asl ailof
ada ada ada ada ada
ww spheres in these wwsystems will be respectively. ww ww ww ww
t t t t t
l a i
l.ani.ente l a i
l .ani.ente l a i
l .ani.ente
sas sas sas sas sas
.
w p.apdaada .
wp.apdaada .
w papdaada
. .
w p.apdaada .
w p.apdaada
w w w w w w
ww ww ww ww ww ww
24
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
t t e t t
e t t
ene between the body .ni.ene t t
.ni.ene t t
17.asIflaila.aniis.enthe length of the il.ani.enof
aslaside lail.ani.
the cube, theasdistance aslaila centered atom and
aslaila
adsa asa asa adsa adsa
w .wp.apdaone comer atom w .
w p.apdad w .
w p.apdad w .wp.apda w .wp.apda w
ww ww in the cube will be ………..
ww ww ww ww
(a) (2/√3)a (b) (4/√3)a (c) (√3/4)a (d) (√3/2)a
18.
ada Potassium has a abcc
s adstructure
s
a with nearest adaneighbor distancea4.52
s ada A. its atomic weight
s adais 39.
s
w .wp.apda w .wp.pda w.wp.apda w .wp.pda w .wp.apda w
ww ww
Its density will be ……….. ww ww ww ww
-3
(a)i.n915 t
i.ente kg m . ni e
. ntet 2142 kg m-3
(b) .ani.ente
t (c) 452 kg m-3 i.ni.entet (d) 390 kg m-3 i.ni.entet
l a l a l a i
l a l ail aslala aslala
adsaas
apda19.
saas
apdaaadcrystal ap
a
daadsas ……….. s
apdaada
s
apdaada
w .
w p. Schottky defect
w .
w pin
. is observed
w .
w p. when w.wp. w .
w p. w
ww ww ww ww ww ww
(a) unequal number of anions and anions are missing from the lattice
t tet t t t t t t
(b)
l a i.ente number of anions
il.anequal l ail.ani.enand anions are il.ani.enefrom the latticealail.ani.ene
missing
l a l a il.ani.ene
a
adsas a
adsas a
adsas adsas a
adsas
ww (e) an ion leaves ww its normal site and ww occupies an interstitial ww site ww ww
(d) not ion
t is missing from itst lattice.
t t t t t t t
20. s
adsa The cation leavesadits s
adsanormal position inathe s
adsacrystal and movesato s
adssome
a s
adsa the
interstitial position,
w.wp.apda w .wp.pa w.wp.pda w.wp.pda w .wp.apda w
ww ww ww ww ww ww
defect in the crystal is known as ………..
etet
(a)i.anSchottky defect tet F center (c) Frenkel
e(b) etet defect (d) non-stoichiometric
etet defect i.ani.entet
al i.n ail.ani.n ail.ani.n ail.ani.n
Padasalai.Net
a l a l a l a l lal
a d
a
s
ada s
a d
a
s
ada s
a d
a
s
ada s
a d
a
s
ada s
a daadsaas
w.wp.p 21. Assertion – w .p Frenkel defect, density
w.wpto
due w.wp.p of the crystalline p.p decreases.
solid
w.w w.wp.p w
ww w ww ww ww ww
Reason – in Frenkel defect cation and anion leaves the crystal.
lail.anBoth
saas(a)
i. assertion and lail.ani. are true and sreason
saasreason aasl
ail.ani. is the correct explanation
i.ani.
saaslal
i.ani.
saaslal
of assertion.
adaad .wp.apda
ad
.wp.apda
ad
.wp.apda
ad
.wp.apda
ad
w w.wp.p w w w w w w w w w
w (b) Both assertion
w and reason arewtrue but reason is notwthe correct explanation
w of assertion. ww
(c) Assertion
tet is true but reason
tet is false. t t t t t t
adsas(d) Both assertionadand adsasreason are false adaadsas adsas adsas
w .wp.apda w .wp.pa w.wp.p w.wp.apda w .wp.apda w
ww ww ww ww ww ww
22. The crystal with a metal deficiency defect is ………..
t t t t t (a) KCIail.ani.entet t t
(a)
l a i.ente
il.anNaCI l il.ani.ene
(b)aFeO (c) ZnO
la il.ani.ene l l a il.ani.ene
a
adsa s a
adsas a
adsa s a
adsa s a
adsa s
w.wp.apda23. A two dimensional w .wp.apdasolid pattern formed w.wp.apda
by two different .wp.apda X and Y is shownwbelow.
atoms
w .wp.apda The w
ww ww ww ww ww ww
black and white squares represent atoms X and Y respectively. The simplest formula for the
n.entet
lail.ai i. i n.entetlail.ai n.entet etet
ail.ani.n
etet
ail.ani.n
d
compound
asaas based on the slalacell from the pattern
asaaunit d asaas is ……….. d s
ada asl s
ada asl
ww ww ww ww ww ww
(a) XY8 etet (b) X4Y9 t (c) XY2 t (d) XY4 t t

l ail.ani.n l ail.ani.ente l a i
l.ani.ente l a i
l .ani.ente l a i
l .ani.ente
s as sas sas sas sas
adaada apdaada apdaada apdaada apdaada
w w.wp.p w .
wp. w .
w p. w .
w p. w .
w p. w
w ww ww ww ww ww
25
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
t t t t t t t t t t
ADDITIONALa l a il.ani.eneQUESTIONS : alail.ani.ene a l a il.ani.ene a l a il.ani.ene a l a il.ani.ene
adsa s asa s asa s adsa s adsa s
w .wp.apda1. Which one of w .
w p.apdad w .
ww ww the following is an wamorphous
w solid? ww ww ww
(a) Glass (b) SiO 2 (c) NaCl (d) Na
e ntet e ntet etet etet etet
asl .
aila ni .
asl .
ailani .
asl ail.ani.n asl ail.ani.n asl ail.ani.n
2.
ada Which one of theafollowing
s s
ada is an example afor
da molecular crystals?
s s
ada s
ada
w .wp.apda w .wp.pda w.wp.apda w .wp.apda w .wp.apda w
ww (a) Diamond ww (b) Silica ww (c) Glass ww (d) Naphthalene ww ww
3. Which t
t one of the following t ta covalent crystal?
is t t t t
i.ni.ene
l a l a i.ni.ene
l a l a i.ni.ene
l a la l ail.ani.ente l a i
l .ani.ente
sas saas adsaas aas
daadsGlucose sas
.
w p.apdaada (a) Glass .
w p.apdaad(b) Diamond .
w p.apda(c) Anthracene .wpa(d)
. p .
w p.apdaada
w w w w w w
ww ww ww ww ww ww
4. In an ionic crystal, both cations and anions are bound together by ………..
t t t t .entet t t
(a)
l a i.ente electrostaticlaattractive
il.anStrong il.ani.ene forces l a i.enteWeak electrostatic
il.an(b) l a il.aniattractive forces l a il.ani.ene
a
adsas a
adsas a
adsas a
adsas a
adsas
ww (c) Vanderwaals ww forces of attraction ww (d) Weakwwcohesive forces ww ww
5. In nont polar
t molecular solids,
t t
molecules are held together
t t
by ……….. t t t t
s
adsa (a) London forcesadaadsa s (b) weak s
adsavanderwaals forces adsa s adsa s
w.wp.apda w.wp.p w .wp.apda w.wp.apda w .wp.apda w
ww ww ww ww ww ww
(c) Strong electrostatic forces (d) strong cohesive forces
6. Solid tet 3 solid CO2 are examples t t of ……….. etet etet etet
i.ani.enNH i.ani.ene ail.ani.n ail.ani.n ail.ani.n
Padasalai.Net
s asl al s asl al s asl s asl s asl
ada ada daada aa ada
w.wp.apda (a) Covalent solid
w .wp.apda (b) polar molecular
w .wp.apsolids (c) molecular
w pdad (d) ionic solids
.wp.asolids w .wp.apda w
ww ww ww ww ww ww
7. Each atom in the comer of the cubic unit cell is shared by how many unit cells?
entet entet .ani.ente
t entet .ani.ente
t
lail.an8i.
saas(a) (b) 6 saaslail.ani. (c) 1 sasl ail lail.ani.
(d)saas12 sasl a i
l
.
wp.apdaad .
w p.ap .
w
daad
p.apdaad .
w w wwunit cell is ……….. www w w
ww wwof atoms belongs towfcc
8. The number ww ww
(a) 2 tet (b) 4 (c) 6 (d) 12 tet
n en n entet en t t
il.ani.ene
t t
il.ani.ene
as
i
lal.a i.
as
i
lal .
a i .
aslail.ani. a l a a l a
a s
a s
a
acentre is being shared a s
a adsas adsas
w.w p.apda9.d The atoms the face
p.apdad w.w p.apdadby ……….. w.w w.wp.apda w .wp.apda w
ww ww ww ww ww ww
(a) 4 (b) 8 (c) 2 (d) 6
10. Which etet etet etet t t
il.ani.ene
t t
il.ani.ene
alaail.ani.n is the packing fraction
ala ail.ani.n in simple cubic unit
ail.ani.ncell? ala a l a a l a
. p.apdaadsas . p.apdaadsas . p.apdaadsas .wp.a(d)
asa
pdad75%
s
.wp.apda
adsa s
ww (a) 52.31% ww w (b) 100% w w (c) 68% w w w
ww w ww ww ww ww
11. The packing fraction in bcc arrangement is ………..
l i.ente
ail.an52.3 l il.ani.ene
a68% l ail.ani.n lail.ani.n l ail.ani.n
s
ada a(a)
s 1% (b)
s
ada as (c)s
ada 100%
as (d) 80%
s
ada as s
ada as
ww 12. Which is the wwcoordination number wwin both hep and ccp w w
arrangements? ww ww
(a) 12
etet (b) 6 etet (c) 4 t (d) 8 t t
l ail.ani.n i.ani.n
la l l a i
l.ani.ente l a i
l .ani.ente l a i
l .ani.ente
s as adsaas sas sas sas
adaada a da apdaada apdaada apdaada
w w.wp.p w.wp. p w .
w p. w .
w p. w .
w p. w
w ww ww ww ww ww
26
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
t t
ene .ni.ene t t ene t t t t t t
lail.ani.coordination number
13.asThe lail.ani.
aslaila of zinc sulphide isas……….. a l a il.ani.ene a l a il.ani.ene
w .wp.apda (a) 3 w .wp.apda (b) 4 w .wp.apda(c) 6 w pdad
ww ww ww ww 8 ww ww
14. Which one of the following is the coordination number of NaCl?
ada (a) 3
s ad(b)
sa 4 (c)
ada6
s (d)ad8a
s s
ada
ww ww ww
15. Which one of the following is an example for Frenkel defect? ww ww ww
(a)i.nNaCl t (b) AgCI t (c) AgBr t (d) AgNO t t

l a l i.ente
a l a i
l.ani.ente l ail.ani.ente l ail.ani3.ente l a i
l .ani.ente
adsaas
apda16.
a
daadsas
apfollowing
a
daadsas
apdeficiency
sas
apdaada
sas
apdaada
w .
w p. Which one of the
w .
w p. is the metal
w .
w p. defect?w.wp. w .
w p. w
ww ww ww ww ww ww
(a) FeO (b) ZnO (c) KCl (d) NaCl
t t tet t t t t t t
17. aWhich
l a il.ani.eneone of the following
a l ail.ani.enshows non- a l il.ani.ene defect?
stoichiometric
a a l a il.ani.ene a l a il.ani.ene
ww (a) FeO ww (b) AgBr ww (c) ZnO ww (d) Both a and cww ww
18. Whicht one
t of the following is
t t
the packing efficiency
t t
in fcc unit cell? t t t t
s
adsa (a) 74% s
ads(b)
a 52.6 1% s
adsa100%
(c) s
(d)ads68%
a adsa s
ww ww ww ww ww ww
19. The coordination number of CSCI ¡s ………..
(a)i.an3i.entet (b) 4i.ani.entet (c) 6 i.ani.entet (d) 8 i.ani.entet etet
ail.ani.n
Padasalai.Net
s asl al s asl al s asl al s asl al s asl
ada daada aa aa ada
w.wp.apda20. Which one of w .wp.apfollowing
the formula is
w .apdad to calculate thew.w
.wpused p.apdad of the unit cell
density w .wp?.apda w
ww ww ww ww ww ww
(a) ρ = nMa3/NA (b) ρ = a3NA/ nM (c) ρ = NAa3/ NM (d) ρ = a3NAn
entet entet entet
.ani.ente
t
.ani.ente
t
21. lail.ani. one of the following
saasWhich
i.ani.
saaslal is known as Bragg’s
i.ani.
saaslal equation’? sasl ail sasl a i
l
.
wp.apdaad .
w p.apdaad .
w p.apdaad .
w p.apdaada .
w p.apdaada
w w w (c) d = dsinθ www (d) d = 2sinθnλ www w
ww ww
(a) d = 2sinθnλ ww
(b) d = nλ2sinθ ww
22. Naphthalene
tet is an example tof
et
……….. (a) ionic solid t t t t t t
a la i
l.ani.en
a l a i
l .
a ni en
.
a la il.ani.ene a l a il.ani.ene a l a il.ani.ene
adsas(b) covalent solidadaadsas (c) non polar adsas
molecular solid as molecular solid
(d)adspolar adsas
w .wp.apda w .wp.p w.wp.apda w.wp.apda w .wp.apda w
ww ww ww ww ww ww
7. CHEMICAL KINETICS
t t
ni.ene order reaction A t t
.ani.enBethe rate constant t t
e t t
ni.ene .ani.ene t t
1. For a sl ail.afirst
a asl a il→ a sla ani.exn min-1. If the initial
il.is a sl a il.aconcentration of Aais
sl a il0.01
adsa adsa asa asa asa
w.wp.apdaM, the concentration w .wp.apdaof A after one hour w .apdad
.wpis w .
w p.apdad w .
w p.apdad w
ww ww ww given by the expression.
ww ww ww
(a) 0.01 e-x (b) 1 x 10-2 (1 – e-60x) (c) (1 x 10-2) e-60x (d) none of these
asl ail.ani.n aslail.ani.n asl ail.ani.n aslail.ani.n asl ail.ani.n
2.adAa zero order reaction
s adXa→ Product, with an
s ainitial
s
da concentrationad0.02M
ada has a half life of
s a10
da min. If
s
w.wp.apda w .wp.apda w .wp.apda w .wp.pa w.wp.apda w
ww w w
one starts withwconcentration 0.04M,wthen the half life is ……………. ww ww ww
(a).n10 t tet 20 min t ntet given information t

ia i.entes (b) 5 min .ni.en(c)
laila
(d) cannot
ia.ni.ente be predicted using the
.ni.e ia .ni.ente ia
saaslal sas saaslal saaslal saaslal
aad a
d apdaada aadad aad a
d aad a
d
w.wp.p w .
wp. w.wp.p w.wp.p w.wp.p w
ww ww ww ww ww ww
27
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
.ni.enet t .ni.ene t t i.ene constant with temperature

.ni.ene t t t t t t
3. Among
aslaila the following graphs ail.anrate
aslaila showing variationaslof aslaila (T) for aaslail.ani.ene
daadsa
.wp.apreaction, .
asa
p.apdad .
asa
p.apdad .
asa
p.apdad .
asa
p.apdad
w the one w w w w w w w w w
ww wwthat exhibits Arrhenius
ww behavior over the w
entire
w temperature range
ww is …………… ww

ada ada ada ada ada
ww ww ww ww ww ww
t t t t t
l a i
l .ani.ente l a i
l .ani.ente
sas sas sas sas sas
.
w p.apdaada .
w p.apdaada .
. .
w p.apdaada
w w w w w w
ww ww ww ww ww ww
etet
i.ani.n i.ani.n eteti.ani.n i.an-1i.n etet i.ani.n etet etet
4. For
saslaal first order react ion
saslaAl → product with initial
saslal concentration x mol
saslalL , has a half life period
saslal of
ada ada ada aa ada
w .wp.apda w .wp.apda w .wp.apda w p.apdad
.w
-1 w .wp.apda w
ww ww same reaction withwinitial
2.5 hours. For the w ww L the half life is ww
concentration mol ww
(a) (2.5
t t
x 2) hours (b)
t t (2.5/2) hours t t (c) 2.5 hours n.entet t t
n
il.ai e
. ne n
il.ai e
. n e n
il.ai e
. n e il.ai il.ani.ene
as l a asl a asl a asl a a sl a
adsa (d) Without knowing adsathe rate constant,atda1/2 adsacannot be determined adsa from the given data adsa
w.wp.apda w .wp.apda w .wp.p w .wp.apda w .wp.apda w
ww ww ww ww ww ww
5. For the reaction, 2NH3 → N2 + 3H2, if
Padasalai.Net
ada ada ada ada ada
ww ww ww ww ww ww
then the relation between k1, k2 and k3 is
t t t tet t
(a)
l ail i.ente= k2 = k3
.ank1 (b)l a i
l
k1.ani.e=nte3 k2 = 2 k3 (c) 1.5k1 l a i
l .ani.ent=e 3 k2 = k3 l ail.ani.en2k1
(d) = k2 = 3 k3 l a i
l .ani.ente
sas sas sas sas sas
.
wp.apdaada .
w p.apdaada .
w p.apdaada .
w 6. The decomposition w of phosphine (PH3) w w w w
ww ww ww on tungsten at low wwpressure is a first order ww reaction. It is ww
because the t…………….
et t t t t t t t t
a la il.ani.en a l a il.ani.ene a la il.ani.ene a l a il.ani.ene a l a il.ani.ene
adsas(a) rate is proportional adsasto the surface coverage adsas adsas adsas
ww ww ww ww ww ww
(b) rate is inversely proportional to the surface coverage
(c)
l a ni.entetis independentlaofil.anthe
il.arate
t
i.ente surface coverage la
t t
il.ani.ene l a
t t
il.ani.ene l a
t t
il.ani.ene
a
adsa s a
adsas a
adsa s a
adsa s a
adsa s
w.wp.apda (d) rate of decomposition w .wp.apda is slow w.wp.apda w .wp.apda w .wp.apda w
ww ww ww ww ww ww
7. For a reaction Rate = k [acetone]3/2 then unit of rate constant and rate of reaction respectively is
t et t tet etet
l i.ente -1 -1
ail.an(mol .ani.enst-1
-1/2 ail1/2
l l i.ente
ail.an(b) -1/2 1/2 -1 ail.ani.en -1 -1
l l ail.ani.n
s a(a)
s L s ), (mol s as L ) s as (mol L s ),
s as(mol L s ) s as
. p.apdaada . p.apdaada .wp.apda
ada ada
.wp.apda 1/2 1/2 .wp.apda
ada
ww wwsw w w w w
ww (c) (mol1/2 w L1/2 -1
), (mol L-1 s-1) ww (d) (molwLws ), (mol L s) ww
-1
ww
8. The addition
etet of a catalyst during
eteta chemical reactionetalters
et which of the following
etet quantities? t
l .ani.ente
s as s as s as s as saas
adaada (a) Enthalpy .wp.apdaad(b)
a Activation energy adaada adaada
(c) Entropy (d) Internalapdaadenergy
w w.wp.p w w w w.wp.p w w.wp.p w .
w p. w
w w w w ww ww
28
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
.ni.ene t t .ni.ene t t t t t t t t
9. Consider
aslaila the following statements:
aslaila a l a il.ani.ene a l a il.ani.ene a l a il.ani.ene
adsa adsa asa s asa s asa s
w .wp.apda (i) increase in wconcentration
.wp.apda w .
w p.apdad w .
w p.apdad w .
w p.apdad w
ww ww of the
wwreactant increases the wwrate of a zero orderwreaction. w ww
(ii) rate constant k is equal to collision frequency A if Ea = o
ada (iii) rate constantakdaais
s daequal to collisionp.frequency
s s
ada A if Ea = o adaada
s s
ada
w .wp.apda w .wp.p w.wapda w.wp.p w .wp.apda w
ww ww ww
(iv) a plot of ln (k) vs T is a straight line. ww ww ww
tet of In (k) vs (1T) .isni.eantestraight

(v)i.nai.enplot t t
line with ai.npositive
i.ente slope. .ani.ente
t
.ani.ente
t
lala lala i lala l ail l a i
l
a daadsaas a daadsaas a daadsaas sas
apdaada
sas
apdaada
w.wp. Correct statements
p w.wpare
.p w.wp. p w.wp. w .
w p. w
ww ww ww ww ww ww
(a) (ii) only (b) (ii) and (iv) (c) (ii) and (v) (d) (i), (ii) and (v)
10. In a ntet
il.ani.ereversible reaction, ailthe
t
.ani.enteenthalpy changelaand tet
il.ani.enthe activation energya
t t
il.ani.enine the forward direction a
t t
il.ani.ene
a l a l a a l a l
w .wp.apda w .wp.apda -1 w .wp.apda
-1 w .wp.apda w .wp.apda w
ww are respectively ww– x kJ mol and y kJ w w . Therefore, the energy
mol ww of activation in w w backward
the ww
directiontist ……….. t t t t t t t t
s -1 s
adsa (a) (v – x)kJ mol adaads(b)
a (x + y) J mol -1 s
adsa(x – y) kJ mol
(c) -1
(d)ads(xs -1
a + y) x 103 J mol adaadsa s
w.wp.apda w .wp.p w .wp.apda w.wp.apda w.wp.p w
ww ww ww ww ww ww
11. What is the activation energy for a reaction if its rate doubles when the temperature is raised
t t -1 t -1
from 200K i.ente mol )
i.ani.ene to 400K? (R 8.314i.anJK etet etet etet
Padasalai.Net
lal lal l l l
adsaas ad-1saas s
aa as s
aa as s
ada as
a
w.wp.p
da a
-1da
w.wp.p K
(a) 234.65 kJwmol (b)
w p.apdad kJ mol-1 K-1 w.wp.apdad
434.65
.w w .wp.apda w
ww w ww ww ww ww
(c) 434.65 J mol-1 K-1 (d) 334.65 J mol-1 K-1
entet .ani.ente
t
.ani.ente
t
.ani.ente
t
.ani.ente
t
12.saaslail.ani. sasl a i
l sasl a i
l sasl ail sasl a i
l
adaad apdaada apdaada apdaada apdaada
w w.wp.p w .
w p. w .
w p. w .
w p. w.wp. w
w ww ww ww ww ww
t t ntet t t t t -t t
a l il.ani.ene follows first order
This reaction
a a l a il.ani.ekinetics. The rate constant
a la il.ani.ene at particularatemperature
l a il.ani.ene is 2.303 x la10
a il.ani.ene
2 dadsas adsas of cyclopropane adsas adsasthe concentrationadof adsas
w .apa
.wphours. .wp.apda
The initial concentration
w w .wp.apda is 0.25 M. Whatw.will wp.apdabe w .wp.pa w
ww cyclopropane after ww1806 minutes? (Log w w
2 = 0.30 10) ww ww ww
(a) 0.125 tet M (b) 0.215 tetM (c) 0.25 xte2.303 t M (d) 0.05 tet M tet
en en en en en
s
a aslail.ani. saaslail.ani. s
a aslail.ani. s
a aslail.ani. s
a aslail.ani.
a
adad a a a a
.apdad adad adad dad
-1
w w.wp.p 13. For a first order
w w.wpreaction, the rate constant
w w.wp.p is 6.909 min w.The w.wp.ptime taken for 75% w wp.ap
w.conversion in w
w w w w w ww
minutes is ………… (a) (32) log 2 (b) (32) log 2 (c) (32) log (3 (d) (23) log (43)
tet tet tet tet tet
14. Ini.ani.efirst
saslal sasl
i.en y; if k is the rate lconstant
n order reactionaxil.an→
sasal
i.ani.en and the initial i.ani.en
concentration
saslal
of the i.ani.en
saslal
ada ada ada ada ada
ww reactant x is 0.1
wwM, then, the half lifewis
w …….. ww ww ww
(a) (log2k)
t (b) (0.693(0.1)k)
t (c) (In2k) (d) none of these
ete ete e tet e tet .ani.ente
t
s asl ail.ani.n s asl ail.ani.n sasl a i
l.ani . n
sasl a i
l .
a ni . n
sasl a i
l
w p. w .
w p. w .
w p. w
w w ww ww ww ww
29
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
t t
ene e t t t t t t t t
il.ani.en
lail.ani. the rate law ofaslathe
15.asPredict following reaction il.ani.ene on the data given
aslabased
.ni.ene
aslailabelow: a l a il.ani.ene
adsa asa adsa adsa adsa s
w .wp.apda w .
w p.apdad w .wp.apda w .wp.apda w .wp.apda w
ww 2A +wBw → C + 3D ww ww ww ww
(a) rate = k [A]2 [B]
asl ail.ani.n 2 asl ail.ani.n asl ail.ani.n asl ail.ani.n asl ail.ani.n
(b)
adarate = k [A][B] adaada
s s s
ada s
ada s
ada
w .wp.apda w.wp.p w.wp.apda w .wp.apda w .wp.apda w
ww (c) rate = k [A][B]ww ww ww ww ww
(d) rate =t kt [A]1/2 [B]3/2

i.ni.ene i.ani.ente
t
i .ani.ente
t
i .ani.ente
t
i .ani.ente
t
l a l a l a l l a l l a l l a l
adsaas
apda16.
sas
aada
apdreaction dsaas concentration pof.apdthe
apdaathe
sas
aada reactant is doubles dsaaits is a
apdaaif
w .
w p. Assertion: rate
w .
wof
p. doubles when
w .
w p. w.w w .
w p. w
ww ww ww ww ww ww
first order reaction.
i.ani.netet il.ani.n etet t t
il.ani.ene
t t
il.ani.ene
t t
il.ani.ene
Reason:
saslal rate constant also
sasladoubles a l a a l a a l a
ww ww and reason are true
(a) Both assertion wwand reason is the correct ww explanation of assertion. ww ww
(b) Both assertion
t t
and reason are
t t
true but reason is not
t t
the correct explanation
t t
of assertion. t t
(c) s
adsaAssertion is true but s
adsreason
a is false. adsas adsa s adsa s
ww ww ww ww ww ww
(d) Both assertion and reason are false.
-2 -1
17. The ntet constant of a reaction
i.ani.erate
t t t
.ani.enteorder of the reaction
i.ani.ene is 5.8 x 10 s . iThe
tist ………….
i.ani.ene etet
ail.ani.n
Padasalai.Net
ada ada ada aa ada
w pdadThird order
.wp.apda (a) First orderw.wp.apda (b) zero order w.wp.apda(c) Second order w.wp.a(a) w .wp.apda w
ww ww ww ww ww ww
18. For the reaction N2O5(g) → 2NO2(g) +1/2 O2(g) the value of rate of disappearance of N2O5 is
entet
.ani. 6.5 x 10-2 mol L-1sla-1il.aThe entet
ni. rate of formation .ni. entet .ni. entet
.ni. entet
alailas
given a alailaof NO2 and O2 is agiven
alailarespectively as adsaaslaila
a daadsas daadsas
.wp.ap daadsas .wp.ap dadsas a da a
w.wp.p 10w-2wmol L-1s-1) and (1.3wxw10
w -2 mol L-1s-1) w.wp.p w.wp.p w
ww (a) (3.25 x w ww ww ww
-2 -1 -1
(b) (1.3
tetx 10 mol L s ) andt(3.25
et
x 102 mol L-1s-1) tet t t t t
a
en
lail.ani. a
en
lail.ani. a l-1
e
ail.an-1i.n a l a il.ani.ene a l a il.ani.ene
s
a s -1 -1 sa
-1s -2 s
a s adsas adsas
adaad (c) (1.3 x 10 mol aLdaads ) and (3.25 x 10.wp.apmol
daad L s ) .wp.apda .wp.apda
w w.wp.p w w.wp.p w w w w w
w w w ww ww ww
(d) None of these
19. During etet entetH2O2 to give dioxygen, etet t
ni.enteminute etet
alaail.ani.n the decomposition
ala ail.ani.of ala ail.ani.n 48g O2 is formed
ala ail.aper at certain
ail.ani.n ala
. p.apdaadsas . p.apdaadsas . p.apdaadsas . p.apdaadsas . p.a
p daadsas
w w point of time. The
wrate
w of formation ofwwater
w w at this point is w
…………….
ww ww w
ww ww w w ww ww
(a) 0.75 mol min-1 (b) 1.5 mol min-1 (c) 2.25 mol min-1 (d) 3.0 mol min-1
n.entet
lail.ai n.entet
lail.ai of the reactant is lail.ai n.entet
i. i i.ai n.entet n.entet
d
20.
asaasIf the initial concentration
d asaas d asaasdoubled, the time for slala reaction is also adoubled.
asaahalf saaslal
d d
ww Then the orderww ww
of the reaction is ………… ww ww ww
(a) Zero
etet (b) oneetet (c) Fraction
etet (d) none etet t
l ail.ani.n l ail.ani.n l ail.ani.n i.ani.n
lal l a i
l .ani.ente
s as s as s as adsaas sas
adaada adaada adaada a da apdaada
w w.wp.p w w.wp.p w w.wp.p w.wp. p w .
w p. w
w w w ww ww ww
30
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
enet t .ni.ene t t t t t t t t
lail.ani.homogeneous reaction
21.asIn aslaila A ? B + C + D, the il.ani.ene pressure was P0
aslainitial
.ani.eneafter time t it was
aslailand
.ni.ene
aslailaP.
adsa asa asa asa adsa
w .wp.apdaExpression for rate
w .apdad
.wpconstant w .
w p.apdad w .
ww ww in termswof
w P0, P and t will be w
……….
w ww ww

ada ada ada ada ada
ww ww ww ww ww ww
t t t t t
l a i
l .ani.ente l a i
l .ani.ente
sas sas sas sas sas
.
w p.apdaada .
w p.apdaada .
. .
w p.apdaada
w w w w w w
ww ww ww ww ww ww
t t t t t t t t t t
ww 22. If 75% of awfirst w order reaction was wwcompleted in 60 minutes, ww 50% of the sameww reaction under ww
the samet conditions
t would be completed
t t
in ……… t t t t t t
s
adsa (a) 20 minutes adaads(b) s
a 30 minutes s
adsa35 minutes
(c) (d)ads75s
a minutes adsa s
w.wp.apda w .wp.p w.wp.apda w.wp.apda w .wp.apda w
ww ww ww ww ww ww
23. The half life period of a radioactive element is 140 days. After 560 days, 1 g of element will be
reduced tet
(a) 12 g i.ani.entet etet (c) 18 g etet (d) 116 g etet
i.ani.ento (b) 14 g
Padasalai.Net
ada ada ada ada ada
w.wp.apda24. The correct difference
w .wp.apda between firstwand
.wp.apdasecond order reactions w .wp.apda is that ………… w.wp.apda w
ww ww ww ww ww ww
(a) A first order reaction can be catalysed a second order reaction cannot be catalysed.
lail.anThe
saas(b)
i. half life of a first i.ani.
saaslalorder reaction does lail.ani.depend on [A0] sthe
saasnot ail.ani.
aasl half life of a second lail.ani.
saasorder
adaad adaad adaad adaad adaad
w w.wp.p reaction does depend
w w.wp.p on [A0]. w w.wp.p w w.wp.p w w.wp.p w
w w w w w ww
(c) The
tetrate of a first order reaction
tet does not depend
tet on reactant concentrations;
tet the rate of a tet
en en en en en
saaslail.ani. s
a aslail.ani. s
a aslail.ani. saaslail.ani. saaslail.ani.
ad
adasecond order reactionadaa
does
d adaad concentrations..wp.apdaad
depend on reactant adaad
w w.wp.p w w.wp.p w w.wp.p w w.wp.p w
w w w ww w w ww
(d) The rate of a first order reaction does depend on reactant concentrations; the rate of a
second entet reaction does inotetet entet t t
il.ani.ene
t t
il.ani.ene
a sail.ani.order
l a aal.ani.n depend on reactant
sl a aail.ani.concentrations,
sl a a sl a a sl a
adsa asa asa adsa adsa
w .apdad
.wp.apda25. After 2 hours,wa.wpradioactive w .apdad
.wpbecomes
substance (116)th of
w .wp.apda amount. Thenwthe
original .wp.apdahalf life w
ww ww ww ww ww ww
(in mm) is ………………
n.entet
i
lail.aminutes .i n.entet lail.ai n.entet lail.ai n.entet etet
ail.ani.n
d a(a)
saas60 (b) 120 aslaila
asaminutesd
(c) 30 minutes
asaas
d
(d) 15 minutes
asaasd s
ada asl
ww ww ww ww ww ww
t t t t t
l a i
l.ani.ente l a i
l .ani.ente l a i
l .ani.ente
sas sas sas sas sas
.
w p.apdaada .
wp.apdaada .
w papdaada
. .
w p.apdaada .
w p.apdaada
w w w w w w
ww ww ww ww ww ww
31
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
t t t t t t t t t t
ADDITIONAL
a l a il.ani.eneQUESTIONS : alail.ani.ene a l a il.ani.ene a l a il.ani.ene a l a il.ani.ene
asa s asa s asa s asa s adsa s
w pdad
.wp.a1. w .
w p.apdad w .
w p.apdad w .
ww Which one of wwthe following is the unit
ww of rate of reaction?ww ww ww
(a) s-1 (b) mol s-1 (c) mol L-1 s-1 (d) mol L s
etet etet etet etet n.entet
asl ail.ani.n asl ail.ani.n asl ail.ani.n asl ail.ani.n –aslail.ai
2. adWhich
s
a of the following adais the order of decomposition
s s
ada of hydrogen adperoxide
sa catalysed aby adI a
s
w .wp.apda w .wp.apda w.wp.apda w .wp.apda w .wp.pda w
ww (a) First order ww ww
(b) Second order ww
(c) Zero order ww
(a) Third order ww
3. Which t t of the following.nis

one t unit of rate constant
tthe t t for a first order reaction?
t t .ani.ente
t
i.ni.ene
l a l a i i.ene l a l a i.ni.ene l a la i.ni.ene l a l a l a i
l
saas saas sas sas sas
.
w p.apdaad(a) mol -1
L s-1
.
w p.apdaad(b) mol L -1 -1
s .
w p.apdaada (c) s -1
.wpapdaada (d) mol L S .wp.apdaada
.
w w w w w w
ww ww ww ww ww ww
4. What is the order of isomerisation of cyclopropane to propene?
etet
il.ani.n etet
il.ani.n
t
i.ente5/2
il.an(c)
t t
il.ani.en1e
t t
il.ani.ene
adas(a)
asla1.5 ada s(b)
asla3/2 a
adsas
l a a
adsas
l a(d) a
adsas
l a
ww ww
5. Which one of ww
the following is called pseudo first order reaction? ww ww ww
(a) Decomposition
t t
of acetaldehyde
t t
(b)t Acid
t hydrolysis of an tester t t t
n
il.ai e
. ne n
il.ai e
. n e n
il.ai e
asl a a sl a asl a asl a a sl a
ads(c) adsa
a Isomerisation ofadcyclopropane to propene adsa (d) Decomposition adsa of hydrogen peroxide adsa
w.wp.apda w .wp.pa w.wp.apda w.wp.apda w .wp.apda w
ww ww ww ww ww ww
6. The half life period of first order reaction is 10 seconds. What is the time required for 99.9%
completion etet of that reaction? etet etet etet etet
Padasalai.Net
ada ada ada ada ada
w.wp.apda (a) 20 seconds w.wp.apda (b) 1000 seconds w .wp.apda (c) 100 w .wp.apda
seconds (d) 999 .wp.apda
seconds
w w
ww ww ww ww ww ww
7. Which one of the following does not affect the rate of the reaction?
t
s(a) ail.ani. i.ani.
saaslal lail.ani. .ni.
aslaila a i
l
adaad aasl Nature of the reactant
ad ad
(b)saasConcentration
ad
of thesareactants sas
apdaada
l
w.wp.p (c) Surface area .wp.apda
wand w .wp.apda w .wp.apda w.wp. w
w w w w temperature w w (d) pressure w w ww ww
8. What istethe order of radioactive decay?
i.ani.en t i .
a ni entet
. t t
il.ani.ene
t t
il.ani.ene
t t
il.ani.ene
asas asas s
adsasecond adsas (d) third order adaadsas
w.w p.apdad(a) first order p.apdad(b) zero order
w.w p.apda(c)
w.w
order
w.wp.apda w.wp.p w
ww ww ww ww ww ww
9. t1/2 of the reaction increases with increase in initial concentration of the reaction means the
t reaction will ben.e…………
entethe tet t t t t t t
a
order
lail.ani.of
a a l ail.ai n
a a la il.ani.ene a l a il.ani.ene a l a il.ani.ene
w.wp.apda (a) first order w.wp.apda (b) zero order w.wp.apda(c) second order w.wp.apda (d) third order
w .wp.apda w
ww ww ww ww ww ww
10. Identify the reaction order if the unit of rate constant is s-1 ……….
t t t t n.entet n.entet etet
(a) l il.ani.eneorder reaction alail.ani.ene
azero (b) lail.ai lail.ai l ail.ani.n
s
ada as s
ada s dasaassecond order reaction
asaas
d s
ada as
ww (c) first orderww reaction ww w
(d) third orderwreaction ww ww
11. What eisteunit

t of zero order reaction?
etet t t t
l .ani.n
ail-1 l ail.ani.n l a i
l.ani.ente l a i
l .ani.ente l a i
l .ani.ente
s as
a s saas mol-1 L-1 s-1 sas (c) mol L-1 s-1 dadsaas (d) mol L s-1 sas
adaad(a) apdaad(b) apdaada apa apdaada
w w.wp.p w .
wp. w .
w p. w .
w p. w .
w p. w
w ww ww ww ww ww
32
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
.ni.enet t t t t t t t t t
12. Polymerisation
aslaila reactions il.ani.ene ………………. order
aslafollows
.ni.ene
aslaila kinetics. a l a il.ani.ene a l a il.ani.ene
adsa adsa adsa asa s asa s
w .wp.apda (a) fractional w.wp.apda (b) first w .wp.apda w .
w p.apdad w .
w p.apdad w
ww ww ww (c) zeroww (d) Pseudo wwfirst ww
13. Activation energy of a chemical reaction can be determined by ……….
ad(a)
sa changing concentration s
ada of the reactants s
ada s
ada s
ada
ww ww ww
(b) Evaluating rate constants at standard temperature ww ww ww
t t
(c) Evaluating rate constants t ttwo different temperature
at t t .ani.ente
t
.ani.ente
t
l ai.ni.ene
l a i.ni.ene
l a l a i.ni.ene
l a la l ail l a i
l
saas sas adsaas sas sas
.
w p.apdaad(d) Evaluating .
w p.apdaada of reaction at two
reIocities .
w p.apdadifferent temperature
.wpapdaada
. .
w p.apdaada
w w w w w w
ww ww ww ww ww ww
14. A large increase in the rate of a reaction for a rise in temperature is due to ………
etet
il.ani.ndecrease in the number n etet n etet t t
il.ani.ene
t t
il.ani.ene
(a)
aslathe aslail.ani. of collisions saaslail.ani. a l a a l a
ada adsa apda adsa ad adsas adsas
w.wp.p (b) increase inwthe
w.wp.number w .wp.apda w .wp.apda w .wp.apda w
w w w w
of activated
w molecules ww ww ww
(c) the shortening
t t
of mean free
t t
path t t t t t t
s
ads(d) adsa
a the lowering ofaactivation s energy adsas adsa s adsa s
w.wp.apda w .wp.pda w.wp.apda w.wp.apda w .wp.apda w
ww ww ww ww ww ww
15. The minimum energy of a molecule would possess in order to enter into a fruitful collision is
known et (a) Reaction energy
etas t collision energyn.e(c)
ete(b) tetActivation energy.ni.(d) etetThreshold energyi.ani.entet
ail.ani.n ail.ani.n ail.ai n aila n
Padasalai.Net
a l a l a l a l lal
a d
a
s
ada s
a da
s
ada s
a d
a
s
ada s
a da
s
ada s
a daadsaas
p Assertion (A): Powdered
w.wp.16. w.wp.p calcium carbonatew.wp.p reacts much faster p
w.wp.with dilute w.wp.p w
ww ww ww ww ww ww
HCL than with the same mass of CaCO3 as marble.
ail.ani. (R): For a givensamass
sReason ail.ani. of a reactant, when i.ani. i.ani.
saaslal the particle size decreases,
saaslal surface areasaaslail.ani.
adaad aasl adaad asl adaad ad ad
w.wp.p increases. Increase
w.wp.pin surface area ofwthe
w.wp.p w .wp.apda w.wp.apda w
w w w w w reactant leads tow w
w more collisions per litre
w per second ww
and hence the rate of the reaction also increases. tet
i.ani.entet i .
a ni entet
. il.ani.en
t t
il.ani.ene
t t
il.ani.ene
asas adsas asas explanation of aA.daadsas adsas
w.w p.apdad(a) Both A and R are p.apdacorrect
w.w
and R is thepcorrect
.apdad
w.w p.p w.w w .wp.apda w
ww ww ww ww ww ww
(b) Both A and R arc correct but R is not correct explanation of A
tet etet .entet R is correct lail.ani.entet t t
a
(c)aAil.anisi.encorrect
l a a
but R is wrong
l a
(d) A is wrong
ail.ani.n a la il.anibut a a l a il.ani.ene
daadsa s daadsas daadsa s daadsas adsa s
. p.ap . p
w w 17. Assertion (A): wOrder.ap
w w of the reaction w
can . p.ap
w wbe zero or fractional ww. p.ap w .wp.apda w
ww w w ww ww ww
Reason (R): We cannot determine order from balanced chemical equation
t t entet t t etet etet
(a)
a l il.ani.eneA and R are correct
aBoth a lail.ani.but R is not correct a l il.ani.ene
aexplanation of A. a lail.ani.n a l ail.ani.n
s
ada s s
ada s s
ada s s
ada s s
ada s
ww (b) Both A and wwR are correct and R w iswthe correct explanation ww of A ww ww
(c) A isecorrect
tet but R is wrongetet t t t
l.ani.ente l a i
l .ani.ente l a i
l .ani.ente
s as
a A is wrong but Rada s
a as sas sas sas
adaad(d) isadcorrect apdaada apdaada apdaada
w p. w .
w p. w .
w p. w
w w ww ww ww ww
33
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
t t
.ni.ene (A): If the activation
.ni.ene t t
.ni.ene t t
.ani.enehave no effect on .ani.ene t t t t
18. Assertion
aslaila aslaila enery of a reaction
aslailais zero, temperature
aslailwill aslailthe
w .wp.apda rate constant w.wp.apda w .wp.apda w .wp.apda w .wp.apda w
ww ww ww ww ww ww
Reason (R): Lower the activation energy, faster is the reaction.
ad(a)
sa Both A and R are correct
s
ada and R is the correct
ada explanation of aA.daada
s s s
ada
w .wp.apda w .wp.apda w.wp.apda w.wp.p w .wp.apda w
ww ww ww
(b) Both A and R are correct but R is not correct explanation of A ww ww ww
tet
(c) Ai.nisi.encorrect but R is wrong t t .ani.ente
t
.ani.ente
t
.ani.ente
t
lala lala i.ni.ene l ail l ail l a i
l
a daadsaas a daadsaas sas
apdaada
sas
apdaada
sas
apdaada
w.wp. (d) A is wrongwbut
p w.wpR
. is correct
p w .
w p. w.wp. w .
w p. w
ww w ww ww ww ww
t t t t ANSWER t
t KEY t t t t
il.ani.ene il.ani.ene i.ni.ene
a il.ani.ene il.ani.ene
a
adsas
l a a
adsas
l a
adsaaslal a
adsas
l a a
adsas
l a
w .wp.apda w .wp.apda aa
w.wp.p
d
ww ww ww ww ww ww
1. METALLURGY 20. b) Impure copper 19. d) Calcination
t t t t t t tet t t
a l ail.ani.ene a l a il.ani.ene21. c) ΔGo/ΔT is negative
a l a il.ani.ene a l ni.enLiquation
20. i.ab)
a l a l a il.ani.ene
1. b) Al2O3.nH2O
adsa s adsa s 22. b) ΔGopVs aTdsas s
adsa21. b) Zinc oxide adaadsa s
w p.apdac)SO2
.w
2. w .wp.apda w .w.apda w.wp.apda w.wp.p w
ww ww b)wAl2O3 + 2Cr → Cr2O3 + w
23. w w
2Al 22. b) Chrome ww
steel ww
3. c) MgCO3 → MgO + CO2
24. b) The graph for the formation 23. c) both (a) and (b)
4. b) Al2O3 tet t t tet
e e te of CO2 is a straight e te
line almost 24. i.b) eNa2[Zn(CN)4] etet
ail.ani.n ail.ani.n ail.ani.n alani.n ail.ani.n
Padasalai.Net
5. a) s a
Alsl s asl s asl s asl s asl
aa daada parallelato da energy
afree ada25. a) NaCN ada
w .wp.apdad)d Carbon and hydrogen
6. w .wp.apare w .wp.pda w .wp.apda w .wp.apda w
ww ww w
axis.
w ww ww
26. c) acid leaching ww
suitable reducing agents for
metal sulphides t t t tet t t
7. c) sA l
– a il.ani.en,tBe – (ii) , C – (iii) , D –lail.ani.ente
(iv)
ADDITIONAL QUESTONS
l a il.ani.ente l a il.ani.e
2. PnBLOCK ELEMENTS –laI il.ani.ene
adaas
apda(i)
sas
apdaada 1. b) Zn adaadsaas sas
apdaada1. (c) basic.
sas
apdaada
w .p
w . w .wp. w .wp. p w .wp. w.wp. w
w w w w 2. wd)wMalachite ww ww ww
8. d) Electromagnetic separation 2. (d) accepts OH– from water,
3. c) Zone refining
9. b) Cu(s) + Zn2+(aq) → Zn(s) + releasing proton
t t t
t 4. c)Copper (I)sulphide t
ente(Cu2S) entet t t
l
Cu2+(aq)
a a il.ani.ene a l a il.ani.ene a l a il.ani . 3.
a l a il.an
(a)i . B2H6 a l a il.ani.ene
asas adsas 5. asas
c) froth flotation asas asas
w .wp.apdac)dSodium
10. w .wp.apda w .wp.apdad w .wp.apdad 4. (a) Aluminiumw.wp.apdad w
ww 11. b) Infusible impurities ww to 6. wd)wfractional crystallizationww w ww
5. (c) four w
7. b)roasting
soluble impurities 6. (c) Lead
t t t 8.
t b) CuCO3Cu(OH)2 entet tet t t
12. c) Galena
a l a il.ani.ene a l a il.ani.ene a l a n
il.ai . 7.
a l a .ani.ensp2
il(c) hybridised a l a il.ani.ene
asa s adsa s 9. a)ZnS dadsa s adsa s adsa s
w p.apdaa)dLower the meltingwpoint
13.
.w .wp.apdaof 10. c) w .wp.apa
Sulphur w .wp.apda 8. (a) +4 w .wp.apda w
ww alumina ww ww ww 9. (d) (SiO4)4- ww ww
11. a) ΔGo = -nFEo
14. a) Carbon reduction 12. d) Flux
t t etet etet etet
l a i
15. c) Displacementl.ani.ente with zinc l a il.ani.ente l ail.ani.n 10.l ail.ani.n l ail.ani.n
aas as s
ada as 13. c) Sulphide s as s as s as
p.apdac)dMg
16. .wp.apda adaada .wp.apda
ada
.wp.apda
ada
w .w w 14. w.wp.p
c)wSmelting w w w
ww 17. b) van Arkel process ww w ww ww ww
15. a)Carbon blocks
18. d) Both (a) and (c) 11. (a) Me3SiCl
.entet t 16.
t a) Collector t t tet ice .ani.ente
t
19. d) Inlthe a il.animetallurgy of gold, lail.ani.ene17. c) Leachingsaaslaila
.ni. en e 12.l a il.ani.endry
(a) l a il
adsaasmetal is leached withaddilute
apdathe
sas
aada apdaad separation
sas
apdaada13. (a) Tetrahedral .wp.apdaada
sas
w .wp. .wp. p 18. . p.
d)wMagnetic
w .wp.
ww sodium chloride w ww
solution ww
w
wwww wwww ww
w
34
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
t t t t t t t t t t
14. (d) Feldspar
a l a il.ani.eneis a three a l a il.ani.ene8. (a) 6N
a l a il.ani.ene 28.
a l a ila) e
.ani.e3nparts of con.HCL, one
a l a .ani.ene
ilpart
adsa s adsa s daadsa s s s s s
.wp.apdadimensional silicate w.wp.apda 9. (d) Both
.wp.apassertion and reason .p.apdaada of con.HNO3 .p.apdaada
w w w w
w false. The converse is true. w w w w w
w 15. (a) A – 2, B – 1, Cw– 4, D – 3 w
are ww 29. b) pentagonal ww bipyramidal ww
16. (d) Al, Cu, Mn, Mg 10. (b) F2 30. a) Square pyramidal
e te t e te t e te t tet etet
17. (a) Metal
l ail.ani.nborides l ail.ani.n 11. (b) HF > HCl > HBr
l ail.ani>.nHI 31.ail(d)
l .ani.ensp3 l ail.ani.n
s as
adaAl < Ga < In < Tl s
ada as s
ada as s
ada as adas as
w .w p.apda(a)
18.
w .wp.apda 12. .wp.apda
(d) NeF2
ww ww 13. (c)wHe
w ww 4. Transition ww and Inner ww
ADDITIONAL QUESTONS 14. (c) XeO3 Transition Elements
1. (c) -1 i.ani.entet i ente
.ani. 15.
t (a) HI i .ani.e nte t
i .ani.ente
t
i .ani.ente
t
l a l l a l l a l l a l l a l
2. adsaans2np6
apda(d)
s sas
apdaada 16. (d) Cl2p>apd sas
aada> F2 > I2
Br2 sas
apdaada1. (c) in case of Sc,.wp3d adsaas are
apdaorbital
. wp.
w 3. (b) stable electronic w .wp. w .w . w .wp. w . w
w w w w 17. (d)wHCIO < HClO2 < HClO3 w
w <w ww but in Zn these
partially filled ww
configuration HClO4 are completely filled
tet t t i.ente
t 2. (a) t t
Cr t t
4. (b) stable
a l a il.ani.enelectronic a l a il.ani.ene18. (c) CU(NO3)2 and
a l a il.anNO2 a l a il.ani.ene a l a il.ani.ene
adsas
configuration adsas adsas adsa3.s (a) Ti adsas
w .wp.apda w .wp.apda w .wp.apda w .wp.apda 4. (c) Ni2+ w .wp.apda w
ww 5. (a) Fluorine ww w w
ADDITIONAL QUESTONS w
w ww ww
6. (b) allotropism 5. (a) 5.92BM
1. (b) Fractional distillation
7. (c) 6 .ni.entet te t t t 6. (c)entheir t t ability to adopt .ni.entet
ila n .e
il.ai 2.n (a) Liq N2 il.ani.ene il.ani. e ia
8. (c) asl a
adsaborax adsaasl a
adsaasl a
ad as l a
sa variable oxidation states ad saaslal
w .wp.apda w .wp.apda 3. (a) 10-30
w.wp.p
a da a da
w.wp.p 7. VO+2 < Cr2O2−7 w.wp.p
a da
w
w w 9. (a) diborane w w 4. (d)w107°
w ww ww < MnO–4 ww
10. (c) Sodium borate 8. (b)Carbondioxide
5. (c) Pyramidal
11. (a) 10B5n.entet t t t 9. (b)eNa2Cr2O7 t is preferred over etet
e e
il.ani.n 6. (a) Ostwald’s process .ani.ente .ani.nte ail.ani.n
Padasalai.Net
a l a il.ai a l a a l a il a l a il a l
12.d(a) s s
a aH3BO3 s
ada s s
ada s s
ada s K2Cr2O7 in volumetric adas analysis
s
w .wp.apad w .wp.apda 7.
w .wp.apda ion
(c) Nitronium
w .wp.apda 10. (b) Mn2+ w .wp.apda w
ww 13. (d) B3N3H6 ww 8. (a)wAgNO3
w ww ww ww
14. (c) Borazole 11. (c) 3
9. (b) Firearms
15. (d) (i) anden(ii) t t t 12. (c) 0.6 t t
l a il.ani. te l a il.ani.ente10. (a) phosphorescence
l a il.ani.ente l a il.ani.ente l a il.ani.ente
16. (b) sahexagonal
s sas sas s13.
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----ALL THE BEST----
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EVALUATION
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CONTENTS
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l .ani.ente l a i
l .ani.ente
1 sas 8. Ionic Equilibrium sas sas sas 3 sas
.
w p.apdaada .
w p.apdaada .
. .
w p.apdaada
w w w w w w
ww ww ww ww ww ww
2 9. entet
il.ani.Electro Chemistry ail.ani.entet t t
il.ani.ene
t t
il.ani.ene 7 t t
il.ani.ene
a l a l l a l a l a
d adsas d adsaas a
adsas a
adsas a
adsas
p
w.w.ap a p
w.w
a
. p a
w .wp.apda w .wp.apda w .wp.apda w
ww ww ww ww ww ww
3 10. Surface Chemistry 14
t t t t t t t t t t
ww ww ww ww ww ww
4 11. Hydroxy Compounds and Ethers 19
Padasalai.Net
aa ada ada ada aa
w pdad
.wp.a5 w .wp.apda w .wp.apda Acids w .wp.apda w .apdad
.wp26 w
ww 12. Carbonyl
ww Compounds and Carboxylic
ww ww ww ww
t t t t t
l.ani.ente l a i
l .ani.ente
a sas sas sas sas
.p.a6
pdaadsas 13. Organic Nitrogen. p.apdaada Compounds .wp.apdaada . p.apdaada . p.apdaada
33
w w w w w w w w w w
ww ww ww ww ww ww
tet t t t t t t t t
7
a la il.ani.enBiomolecules
14.
a l a il.ani.ene a la il.ani.ene a l a il.ani.ene 39
a l a il.ani.ene
ww ww ww ww ww ww
8 15. tChemistry
t in EverydaytLife
t t t t t
45 t t
ww ww ww ww ww ww

ada ada ada ada ada
ww ww ww ww ww ww
t t t t t
l a i
l.ani.ente l a i
l .ani.ente l a i
l .ani.ente
sas sas sas sas sas
.
w p.apdaada .
wp.apdaada .
w papdaada
. .
w p.apdaada .
w p.apdaada
w w w w w w
ww ww ww ww ww ww
2
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
t t t t t t t t t t
a l a il.ani.ene a l a il.ani.ene 8. IONICa l il.ani.ene
EQUILIBRIUM
a a l a il.ani.ene a l a il.ani.ene
adsa s adsa s s s
ada adsa s adsa s
ww ww ww ww ww ww
Choose the correct answer:
ete t t t t t
ail.ani.n
1. Concentration
l .ani.entein a saturated solution
of the Agl+ailions l
ete
ail.ani.n of Ag2C2O4 issa2.24 l .ente -4mol L-1
ail.ani×10 l
ete
ail.ani.n
s
ada as s
aa as s
aa as aa s aas as
.wp.apdasolubility productwof pdad
.wp.aAg .
w p.apdad p.apd3aLd-3 b) 2.66 ×10-12
-8 .w .
w p.apda3dL-3
ww
w
ww C
2 2 4O is ww
w a) 2.42 ×10
ww
wmol ww
w mol ww
w
c) 4.5 ×10-11 mol3L-3 d) 5.619 × 10–12 mol3L-3

t t t t t
l a i
l .ani.ente l a i
l .ani.ente
as
2.sFollowing solutionsdwere sas prepared by mixing sasdifferent volumes dof as
sNaOH of HCl different sas
.
w p.apdaada .
w p.apaada .
w p.apdaada .wpapaada
. .
w p.apdaada
w w w w w w
ww concentrations. ww ww ww ww ww
i. 60n.emL t t M/10 HCl + 40mL M/10

t t NaOH t t t t t t
a l a il.ai ne a l ail.ani.ene a l a il.ani.ene a l a il.ani.ene a l a il.ani.ene
adsas asas adsas adsas adsas
w .wp.apda ii. 55 mL M/10w.w p.apda+d 45 mL M/10 NaOH
HCl w .wp.apda w .wp.apda w .wp.apda w
ww ww ww ww ww ww
iii. 75 mL M/5 HCl + 25mL M/5 NaOH
t
ni.entemL tet t t t t t t
a iv.
sl ail.a100 il.ani.enmL
M/10 HCla+sla100 M/10 NaOHaslail.ani.ene a sl a il.ani.ene a sl a il.ani.ene
adsa asa asa asa asa
w.wp.apdapH of which one wof.wpthem .apdad w .
w p.apdad w pdad
.wp.ab) w .
w p.apdad w
ww ww will be equal wwto 1? a) iv ww i c) wiiw d) iii ww
3. The solubility of BaSO4 in water is 2.42 ×10-3gL-1 at 298K. The value of its solubility product
Padasalai.Net
asl
Kadspa will be (NEET -2018). asl asl -1 asl asl
s ada(Given molar mass
s of
adaBaSO4 =233g mol ad)aada
s s s
ada
w.wp.apda w .wp.apda w .wp.apda w.wp.p w .wp.apda w
ww w w
-14
a) 1.08 ×10 mol L 2 -2 w w
b)1.08 ×10 mol L -12 2 -2 ww ww ww
c) i1.08 t -10 2 -2
tet d) 1.08 ×10-8imol te2Lt -2 t t
l a l a.ni.ente×10 mol L l a i
l.ani e
. n
l a l.ani e
. n
l .ani.ente
adsaas
apda4.
a
daadsas of Ca(OH) is.p9.
asolution adsaas
apdaThe
saas
apdaadof
sas
apdaada
w .
wp. pH of a saturated
w .
w p. p 2w w . Solubility product
w .
w p. Ca(OH) 2 w.wp. w
ww ww ww ww ww ww
-15 -10 -15 -10
a) 0.5 ×10 b) 0.25 ×10 c) 0.125 ×10 d) 0.5 ×10
t t tet ni.entet t t t t
a la il.ani.ene base for bronsted
5.sConjugate a l a il.ani.enacids H O 2 and aHF
la il.aare a l a il.ani.ene a l a il.ani.ene
w .wp.apda - w .wp.a+pda w.wp.apda + - w .wp.apda w .wp.apda w
ww a) OH andwHw2 FH , respectively ww b) H3O and F w, w respectively ww ww
c) OHt- and t F- , respectively t t d) H3O+ and
t t H2F+ , respectively t t t t
il.ani.en e il.ani.ene n.en
i.ai e n.ene i.ai il.ani.ene
asl a
adsaWhich will make basic s asl a saaslal saaslal a
adsa sl a
apda6. apdaadabuffer? a daad a daad
.wp.apda
w.wp. w.wp. w.wp.p w.wp.p w w
ww ww ww ww ww ww
a) 50 mL of 0.1M NaOH+25mL of 0.1M CH3COOH
b)i.a100 t of 0.1M CH3 COOH+100
etemL etet mL of 0.1M iNH t
eteOH etet etet
s asl al ni.n s aslail.ani.n s asl al.ani.n4 s aslail.ani.n s asl ail.ani.n
ada ada aa ada ada
w.wp.apda c) 100 mL of 0.1M w .wp.apdaHCl+200 mL of 0.1M w pdad4OH
.wp.aNH w .wp.apda w.wp.apda w
ww ww ww ww ww ww
d) 100 mL of 0.1M HCl+100 mL of 0.1M NaOH
.ni.entet entet entet entet .ani.ente
t
aslaila of the following
7.saWhich lail.ani. – compounds issaamost
saasfluro
i.ni.
slala likely to behavesaas
.ni.
aslaailaLewis base? sasl a i
l
adaad adaad .wp.apda
ad
.wp.apda
ad apdaada
w w.wp.p w w.wp.p b) PF w w w w w .
w p. w
w a) BF3 w 3 w C) CF4 d)
w SiF4 ww ww
3
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
t t
.ni.ene .ni.ene t t .ni.ene t t t t
ee t t
8. Which
aslaila of these is not likely
aslaila to act as lewis base?
aslaila a) BF3 ail.an3i.n C) CO
b)aslPF d) Fas–lail.ani.ene
adsa adsa adsa asa asa
w .wp.apda9. The aqueous solutions
w .wp.apda of sodium formate,
w .wp.apdaanilinium chloride
w .apdad
.wpand w .
w p.apdad w
ww ww ww ww potassium cyanide
ww are ww
Respectively a) acidic, acidic, basic b) basic, acidic, basic
s
ada adc)
a basic, neutral, basic
s s
ada d) noneadof adathese
s s
ada
w .wp.apda w .wp.apda w.wp.apda w .wp.pa w .wp.apda w
ww ww ww
10. The percentage of pyridine (C5H5N) that forms pyridinium ion (C5H5NH) in a 0.10M ww ww ww
-9
aqueous i . ni e
. n et
tpyridine solution K i. n et C5H5N = 1.7 ×10i.ni.en
bi.entfor )teist i .ani.ente
t
i .ani.ente
t
l a l a l a l a l a la l a l l a l
sas saas adsaas saas sas
.
w p.apdaada a) 0.006% .
w p.apdaadb) 0.013% .
w p.apdac) 0.77% .wpad)
. pdaad
1.6% .
w p.apdaada
w w w w w w
ww ww ww ww ww ww
11. Equal volumes of three acid solutions of pH 1,2 and 3 are mixed in a vessel. What will be
etet
+i.ni.n il.ani.nmixture? etet t t
il.ani.ene
t t
il.ani.ene
t t
il.ani.ene
the
saslHal ion concentrationsain
a slathe a l a a l a a l a
ada aa adsas adsas adsas
w .wp.apda p.apdad
-2 w.w w .wp.apda w .wp.apda w .wp.apda w
ww a) 3.7 ×10 ww b) 10-6 ww c) 0.111 ww d) none of theseww ww
-10
12. The solubility
t t
of AgCl (s) with
t t
solubility product 1.6t ×10
t in 0.1M NaCl solution
t t
would be t t
a l ail.ani.ene a l a il.ani.ene 9 a l a il.ani.ene-11 a l a il.ani.ene a l a il.ani.ene
s -5 s
adsa a) 1.26 × 10 M adaadsab) 1.6 ×10- M s
adsa1.6 ×10 M
c) sa s
d)adZero adsa s
ww ww ww ww ww ww
13. If the solubility product of lead iodide is 3.2 ×10-8 , its solubility will be
t-3 -4
ni.entetM
-5
t -5 t
etet
.ani.ente M
a) i2×10 b) 4i.a×10 i.ente M
c) 1.6i.an×10 d) 1.8 ×10 .ani.enteM ail.ani.n
Padasalai.Net
a l a l a l a l a l a l a l a i
l a l
s
ada s s
daada s s
ada s s s s s
.wp.apda14. MY and NY3 , w .wp.apinsoluble
are salts and .wp.apda the same Ksp values
have aada6.2 ×10-13 at room
.wp.apdof .wp.apda
ada
w w w w w
ww ww ww ww ww ww
temperature. Which statement would be true with regard to MY and NY3 ?
entet
.ni. entet entet .ani.ente
t entet
aslailasalts MY and NY3 sare
a)saThe ail.ani. il.ani. than in pure water
saaslaKY
i.ani.
saaslal a i
l
apdaad apdaad aasl more soluble in 0.5M
apdaad apdaad
sas
apdaada
l
w .
wp. .
w p. .
w p. .
w p. .wp.
ww ww
b) The addition ofwthe salt of KY to the w
wwsuspension of MY and
w
wwNY3 will have no effect
ww
w
ww
w
on their solubility’s
tet t t t t t t t t
a la il.ani.en a l a il.ani.ene a la il.ani.ene a l a il.ani.ene a l a il.ani.ene
s molar solubilities
adsaThe
c) ofs MY and NY3 in pwater
adsa adsasare identical adsas adsas
w .wp.apda w .wp.apda w.w.apda w.wp.apda w .wp.apda w
ww ww ww ww ww ww
d) The molar solubility of MY in water is less than that of NY3
15. What etet etet t t
il.ani.ene volumes of 0.1M
t
i.ente and 0.01M t t
il.ani.ene
alaail.ani.n is the pH of the resulting
ala ail.ani.n solution whenaequal alaail.anNaOH ala a l a
. p.apdaadsas . p.apdaadsas . p.apdaadsas . p.apdaadsas .wp.apda
adsa s
w w HCl are mixed? ww w a) 2.0 b)w3w c) 7.0 ww w d) 12.65 w w
ww w ww w ww ww
16. The dissociation constant of a weak acid is 1×10-3 . In order to prepare a buffer solution
n.entet
lail.ai lail.ai n.entet
lail.ai n.entet n.entet
il.ai10:1 n.entet
with
asaas a pH = 4, the [Acid]
asa/as[Salt] ratio should be
asaas a) 4:3 b) 3:4 asaaslac) d) 1:10 asaaslail.ai
d d d d d
w.wp.apda w .wp.apda w .wp.apda a
w.wp.p
da
w.wp.apda w
ww 10w M KOH solution will
17. The pH of w -5
wwbe ww ww ww
a) 9 etet b) 5 etet c) 19 t d) none ofetthese

et t
l ail.ani.n la li.ani.n l a i
l.ani.ente l ail.ani.n l a i
l .ani.ente
s as adsaas sas s as sas
adaada a da apdaada adaada apdaada
w p. w.wp.p w .
w p. w
w ww ww w w ww ww
4
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
t t
i.ene4-- the conjugatelabase
.ni.ene t t t t t t t t
la2il.an
18.asH PO as ila of a l a il.ani.ene a l a il.ani.ene a l a il.ani.ene
adsa adsa adsa s asa s adsa s
.wp.apda a) PO 3− .wp.apda b) P O .wp.apdac) H PO pdad
.wp.ad) .wp.apda
ww
w 4 ww
w 2 5 ww
w 3 4 ww
w HPO42- ww
w
ww
w
19. Which of the following can act as lowery – Bronsted acid well as base?
etet etet .entet etet etet
asl ail.ani.n asl ail.ani.n
2− asl ail.ani2− asl ail.ani.n asl ail.ani.n
ada a) HCl
s adb)
a SO4
s c)
adaHPO4
s d)adBr-
s
a s
ada
w .wp.apda a
w.wp.p
da
w.wp.apda w .wp.apda w .wp.apda w
ww ww
20. The pH of an aqueous solution is Zero. The solution is ww ww ww ww
a) islightlyt t t d) basici.ni.entet t
l a .ni.ente acidic
l a
b) strongly
l a i
l.ani.ente acidic c) neutral
l ail.ani.ente l a l a l a i
l .ani.ente
adsaas
apda21.
sas
aada
apdconcentration
sas
apdaadasolution consisting adsaas
apdaof adsaas
apdasalts
w .
w p. The hydrogenwion
.
w p. of a
w buffer
.wp. w.wp. a weak acid and
w .
w its
p. w
ww ww ww ww ww ww
is given by
etet
+ n netet etet
i.n[H+]=Ka [acid] .ani.n etet n etet
la]il.ani.=Ka [acid] / [salt]saaslail.ani. b) [H ] = Ka [salt] lail.anc) lail.ani.
+
a)s[H
a s s as s aslaild) [H= ]=Ka [salt] / [acid]
s as
ada ad a ad ad a ad a ad a
w.wp.p 22. Which of theww .wp.apda w .wp.apda w .wp.apda w .wp.apda w
w w w w
w following relation iswcorrect for degree ofwhydrolysis of ammonium
w w ww
acetate? t t a) h = (Kh/C) ½ t t b) h = (Ka/Kb) ½ t t c) h = (Kh/Ka Kb) ½ t t d) h = (Ka Kb / Kh) ½ t t
il.ani.ene il.ani.en e il.ani.ene il.ani.ene il.ani.ene
asl a asl a as
-5l a asl a a sl a
adsa Dissociation constant
23. adsa of NH4 OH is 1.8 axda10 adsa the hydrolysis constant adsa of NH4Cl wouldadbe adsa
w.wp.apda w .wp.apda w.wp.p w.wp.apda w .wp.pa w
ww ww w w w ww
a) 1.8 ×10-19 b) 5.55 ×10-10w c) 5.55 ×10-5 w d) 1.80 ×10-5 w
Padasalai.Net
ada ada ada ada ada
w.wp.apdaADDITIONAL QUESTIONS: w .wp.apda w .wp.apda w .wp.apda w .wp.apda w
ww ww ww ww ww ww
1. Which of the following is present in an antacid tablet?
entet
.ani. entet entet .ani.ente
t entet
aslailNaOH
sa(a) s(b) ail.ani. i.ni.
slala 3 a i
l ail.ani.(b) or (c)
apdaad apdaad aasl Mg(OH)2
apdaad apdaad
(c)saaAl(OH) sas
apdaada
l (d) seither
aasl
.
wp. .
w p.
w 2. Which of thewfollowing
w .
w p. .
w p. .wp.
ww w anww
can act as w wwLowry – Bronsted theory?
acid as well as basewby ww
w
ww
w
(a) H2Otet (b) NH3tet (c) NH4OH (d) Ca(OH)2tet

n en n en n entet en t t
il.ani.ene
as
i
lal.a i.
as
i
lal .
a i .
as
i
lal .
a i .
aslail.ani. a l a
s
a
daad In the reaction HCI
a3.
s
ad+aadH2O ⇌ H3O + Cl which
a – s
a
adaad one of the acid-base
sa
adaadpair? adsas
w.wp.p w.wp.p w.wp.p w.wp.p w .wp.apda w
w w w
w+ –w
w w w – ww ww
(a) HCl + H3O (b) HCI + CI (c) H3O + Cl (d) H2O + Cl
4. Ina[Cr(H
i .ni ente2tO)6]3+ which one iof
. tet following acts as.niLewis
.ni.enthe .entet acid? t t
il.ani.ene
t t
il.ani.ene
al l a alala alaila a l a a l a
. p.apdaadsas . p.apdaadsas 3+ . p.apdaadsas .wp.a(d)
asa s
pdadCr3- .wp.apda
adsa s
ww (a) Cr ww (b) Cr w w (c) (HO)6 w w w
ww ww ww ww ww ww
5. The value of ionic product of water at 25°C is ………………..
etet etet et
ni.ent-14 n.entet etet
s(a)
asl ail1.anix.n10-7 (b)
s asla1il.anxi.n107 (c)s 1
asl axil.a10 il.ai14
(d)as1aasxla10 s asl ail.ani.n
ada ada ada d ada
ww 6. The pH of 0.001 ww M HCI solution is w w
……… ww ww ww
(a) 3 etet (b) 2 etet (c) 1 t (d) 11 t t

l ail.ani.n i.ani.n
la l l a i
l.ani.ente l a i
l .ani.ente l a i
l .ani.ente
s as adsaas sas sas sas
adaada a da apdaada apdaada apdaada
w p. w .
w p. w .
w p. w
w ww ww ww ww ww
5
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
.ni.ene t t t t
.ani.enea buffer solution? .ni.ene t t t t t t
7. Which
aslaila of the followingasis
lailnot aslaila a l a il.ani.ene a l a il.ani.ene
adsa s asa asa s asa s
.wp.apda (a) CH COOH +wCH aada
.wp.apdCOONa . p.apdad . p.apdad . p.apdad
w w w
(b) NHw4wOH + NH4Cl (c) H2CO w w w w w
ww 3 ww 3 w3w+ NaHCO3 (d) NaOHw+wNaCI ww
8. The conjugate base of H2O and H2SO4 are …………..
etet etet n.entet etet etet
asl ail.ani.n– asl ail.ani.n 2 - aslail.ai 2- asl ail.ani.n asl ail.ani.n
ada(a) OH and HSO4 adaad(b)
s a H4O and SO4 adaad(c)
s a OH and SO4
s ada (d) H3O and HSO
s s
4 ada
w .wp.apda w .wp.p w .wp.p w .wp.apda w .wp.apda w
ww ww ww -10 ww
9. The dissociation constant of a weak acid is 1.0 x 10 . The equilibrium constant for the reaction ww ww
with t t base is
strong (a) 1.0 t -5
xt 10 tet-9
(b) 1.0i.nxi.en10 (c) 1.0 xi.n10 9
t (d) 1.0 x 10 14
t t
lalai.ni.ene lala i.ni.ene
lala lala lala i.ente i.ni.ene
a daadsaas a daadsaas a daadsaas a daadsaas a daadsaas
w.wp. 10. The pH of a solution
p w.wp. at 25°C containing
p w.wp0.10
. p M sodium acetate
w.wp. and 0.03 M acetic
p wacid
.wp. is …………..
p w
ww ww ww ww ww ww
(pKa for CH3COOH = 4.57) (a) 4.09 (b) 5.09 (c) 6.10 (d) 7.09
t t t
nte0.1 t
i.enteis ………….. t t t t
11.sA
a l il.ani.eneacid is 0.1% ionised
weak
a a l ail.ani.ein M solution. a Its
l a il.anpH a l a il.ani.ene a l a il.ani.ene
ww (a) 2 ww (b) 3 ww (c) 4 ww (d) 1 ww ww
12. The pHt of
t pure water or neutral
t t
solution at 50°C is t……………
t (pKw = 13.2613
t t
at 50°C) t t
s
adsa(a) 7.0 s
ads(b)
a 7.13 s
adsa6.0
(c) s
(d)ads6.63
a adsa s
ww ww ww ww -5 w
w-14 2 2 ww
13. What is the pH of 1 M CH3COOH solution?. Ka of acetic acid is 1.8 x 10 . K = 10 mol litre .
(a) i9.4 etet (b) 4.8 etet (c) 3.6i.ani.entet (d) 2.4 i.ani.entet etet
al.ani.n ail.ani.n ail.ani.n
Padasalai.Net
a l a l lal lal l
d s
ada s d s
ada s d adsaas d adsaas s
ada as
a a
w.wp.p14. The pH of 0.001
a a
p.pNaOH will be ………….(a)
M
w.w
a a
w.wp.p 3
a
2 .wp.p
(b)ww a (c) 11 w p.apda12
(d)
.w w
ww ww ww w ww ww
15. When solid potassium cyanide is added in water then ……………
entet
.ani. will increase .ni. entet entet .ani.ente
t
.ani.ente
t
alailpH
(a) alaila lail.anwill
(b)saaspH i. decrease
sasl ail sasl a i
l
a daadsas daadsas
.wp.ap apdaad apdaada apdaada
w.wp.p w the same w .
w p. w .
w p. w.wp. w
ww ww
(c) pH will remain ww ww
(d) electrical conductivity will not change ww ww
16. pH of atesolution
t is 5. Its hydroxyl
tet ion concentrationteist ………….. t t t t
a
en
lail.ani. a
en
lail.ani. a
en
lail-5.ani. a l a il.ani.ene a l a il.ani.ene
s
a s sa s s
a s as
(d)ads10 -9
adsas
adaad (a) 5 adaad(b) 10 ad 10
ada(c) .wp.apda .wp.apda
w w w ww ww ww
17. Which one of the following is a buffer?
t etet etet t t t t
.ani.en3te
(a)ailCH COOH + CH3COONa
ail.ani.n (b) CH3COOH
ail.an+i.nCH3COONH4 a il.ani.ene a il.ani.ene
ala ala a l a a l a l
. p.apdaadsas . p.apdaadsas .w
adsa
p.apd3aCOOH
s
.wp.apda
adsa s
.wp.apda
adsa s
ww (c) NaOH + NaCI
ww (d)
w CH + NH 4 CI w w w
ww ww ww ww ww ww
18. By adding a strong acid to the buffer solution, the pH of the buffer solution ……………..
t etet t tet etet
(a)l .ani.ente
ailremains constant l i.ente
ail.ani.n(b) increases saslail.an(c) decreases l il.ani.enbecomes
a(d) zero l ail.ani.n
s
ada as s
ada as ada s
ada as s
ada as
ww 19. The unit of w w product of waterwKwis ……………
ionic ww ww ww
-1 -1
(a) mol
etet L (b) mole-2
tetL
-2
(c) mol-2eLte-1t (d) mol2 Le-2tet t
l .ani.ente
adaada adaada adaada adaada apdaada
w p. w
w w w w ww ww
6
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
.ni.enet t .ni.ene t t .ni.ene t t

.ene2CrO4? t t t t
20. What
aslaila is the correct representation
aslaila of the solubility
aslaila product constant il.aniAg
aslaof a l a il.ani.ene
adsa asa asa asa asa s
w p.apdad
.wp.apda (a) [Ag+]2 [CrO w-2.w + p.apdad
-2w.w + p.apdad
-2 w.w + 2 p.apdad
-2 w.w w
ww ww4 ] (b) [Ag ] [CrO
w4w ] (c) [2Ag ] [CrOw4 w] (d) [2Ag ] [CrO4ww] ww
21. Which pair will show common ion effect?
ada(a) BaCI2 + Ba(NO3a)d
s 2 ad(b)
sa NaCI + HCI (c)
adaNH4OH + NH4CI a(d)
s adAgCN
s
a + KCN s
ada
w .wp.apda w .wp.pa w.wp.apda w .wp.pda w .wp.apda w
ww ww ww ww ww ww
t t 9. ELECTROCHEMISTRY t t t
l a i
l .ani.ente l a i
l .ani.ente
adsaas
apda1.
sas
apdaada that have a total adsaas
apdacharge
sas
apdaada is
sas
apdaada
w .
w p. The number ofw .
w p.
electrons w .
w p. of 9650 p.
coulombs
w.w w .
w p. w
ww ww ww ww ww ww
a) 6.22 ×1023 b) 6.022 ×1024 c) 6.022 ×1022 d) 6.022 ×10−34
entet entet entet entet t t
il.ani.ene
2. aslail.ani.
Consider the following a lail.ani.cell reactions: saaslail.anMn
half
s
i. 2+ + 2e− → Mn laE°
as
il.ani.= -1.18V a l a
daadsa daadsa daad daadsa adsas
a
w.wp.p
a
w.wp.p
a
w.wp.p 2+ w .wp3+.ap w .wp.apda w
ww ww ww Mn →wwMn + e- E = -1.51V
ww ww
2+ 3+
The E° fortethe
t reaction 3Mn →Mn+2Mn
tet , and the possibility
tet of the forward
tet reaction t t
a
en
lail.ani. a
en
lail.ani. a
en
lail.ani. a l a il.ani.en a l a il.ani.ene
a s
a s a s
a s a s
a s s
adsa non spontaneous adsa s
adaare
d respectively. p.apdada) 2.69V and spontaneousadad b) -2.69 and
.wp.apda .wp.apda
w w.wp.p ww.w w w.wp.p w w w
w w w ww ww ww
c) 0.33V and Spontaneous d) 4.18V and non spontaneous
3. The entet cell used is watches
button entet function as follows entet etet etet
lail.ani. lail.ani. lail.ani. ail.ani.n ail.ani.n
Padasalai.Net
s as a s as a s as a s asl s asl
ada ada ada ada ada
w.wp.apda Zn (s) + Ag2 O w(s)
.wp.a+pdaH2 O (l ↔) 2 Ag (s)
w pda2+
p.aZn
.w
+ (aq) + 2OH -
(aq)
ww ww ww ww ww ww
the half cell potentials are Ag 2O (s) + H O (l) + 2e- → 2Ag (s) + 2 OH- (aq) E° = 0.34V
t t t t t
l.ani.ente l a i
l .ani.ente
Thesascell potential will dbe sas a) 0.84V b)s1.34V
as c) 1.10V adsaas d) 0.42V sas
.
wp.apdaada .
w p.apaada .
w p.apdaada .
w p.apda .wp.apdaada
w w w w w w
ww ww
4. The molar conductivity of a 0.5 mol wwdm-3 solution of AgNO ww3 with electrolytic conductivity
ww ww
−3 −1
of 5.76 ×10
etet S cm at 298 K isetet a) 2.88 S cm2mol-1
etet b) 11.52 Secm t t mol
2 -1
t t
a lail.ani.
n
a lail.ani.
n
a la il.ani.n a l a il.ani.ne a l a il.ani.ene
sa s sa s adsas 2 -1 sas S cm2 mol -1 adsas
adaad adaad .wp.apda S cm mol
c) 0.086 .wp.ad)
a28.8
pdad .wp.apda
w w.wp.p w w.wp.p w w w w
w w ww ww ww ww
5.
t t t t t t t t t t
ww ww ww ww ww ww
Calculate Λ° HOAC using appropriate molar conductances of the electrolytes listed above at
t t t t t t t t t t
i.ni.ene
lala la C . i.ni.ene alala i.ni.ene lalai.ni.ene i.ni.ene
adsaas dilution in water
dinfinite
asla25°
dadsaat a) 517.2
dadsas b) 552.7 dsaas
c)da390.7 d) 217.5 dadsaaslala
aa aa aa aa apa
w.wp.p w.wp.p w.wp.p w.wp.p w.wp. w
ww w w
6. Faradays constant is defined as ww ww ww ww
a) charge carried by 1 electron

nentet nentet
b) charge carried tby one mole of electrons t t
l a i
l .ai. l ail.ai. l a i
l.ani.ente l a i
l .ani.ente l a i
l .ani.ente
as sas sas a a
. p.
adsacharge
apdac) required .w
to
p . aada
apddeposit apdaada
one mole of.wpsubstance
. d) charge
. p. daadsas by 6.22 ×1010
apcarried . p. pdaadsas
aelectrons.
w w w w w w w w w
ww ww ww ww ww ww
7
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
7. How i.ni.ene are required
aslaila many faradays ofaelectricity
ne following reaction
il.ani.ethe
aslafor
.ni.ene
aslaila to occur il.ani.ene
adsa adsa slala asa asa a
adsa sl a
w .wp.apdaMnO - → Mn2+ w.wp.apda a) 5F w .
w p.apdad w .
ww 4 ww b) 3F
ww c) 1F ww d) 7F ww ww
8. A current strength of 3.86 A was passed through molten Calcium oxide for 41minutes and
40
adaseconds. The mass
s of
adaCalcium in grams deposited
s s
ada at the cathode adisa (atomic mass of Ca
s s
ada
ww ww
is 40g / mol and 1F = 96500C). ww a) 4 ww
b) 2 c) 8 ww d) 6 ww
9. During t
t electrolysis of molten t
t sodium chloride, the t t required to produce
time t t 0.1mol of t
i.ni.ene
lala lala i.ni.ene i.ni.ene
lala i.ni.ene lala l a i
l .ani.ente
a adsaas sas
apdaada
w.wp. chlorine gas using
p wa.wpcurrent
.p of 3A is w.wp. p w.wp. p w .
w p. w
ww ww ww ww ww ww
a) 55 minutes b) 107.2 minutes c) 220 minutes d) 330 minutes
10. Thea ntet
il.ani.enumber of electrons a i.ente
t
il.andelivered at the cathode
a
t t
il.ani.eneduring electrolysis a ni.entaetcurrent of 1A inlail.ani.entet
il.aby
a l a l a l a l
a daadsas a daadsas a daadsas a daadsas a daadsaas
p. p
w.w 60 seconds is (charge p. p
w.w of electron = 1.6w×10 p. p
w.w −19C ) p
w.w . p p
w.w . p w
ww ww w ww ww ww
a) 6.22 ×1023
t t
b) 6.022t ×10 t
20
c)t 3.75
t ×10 20
t t d) 7.48 ×10
23
t t
n
il.ai e
. ne n
il.ai e
. n e n
il.ai e
. ne n
il.ai e
.n e il.ani.ene
asl a asl a asl a asl a a sl a
adsa Which of the following
11. adsa electrolytic solution adsahas the least specific adsconductance
a adsa
ww ww ww ww ww ww
a) 2N b) 0.002N c) 0.02N d) 0.2N
12. While t t t t etet etet etet
i.ani.enecharging lead storage
i.ani.enebattery ail.ani.n ail.ani.n ail.ani.n
Padasalai.Net
ada ada ada aa ada
w.wp.apda a) PbSO4 on cathode
w .wp.apda is reduced to Pb
w .wp.apda b) PbSO 4 on
w .apdad is oxidised towPbO
.wpanode .wp.apd2a w
ww ww ww ww ww ww
c) PbSO4 on anode is reduced to Pb d) PbSO4 on cathode is oxidised to Pb
t t t entet t
i .ani.ente the following cells i.ani.enI)teLeclanche cell lail.ani.ente .ni. .ani.ente
13. a
Among
sasl l sasl a l sas aslaila
II) Nickel –saCadmium cell sasl a i
l
.
wp.apdaada .
w p.apdaada .
w p.apdaada .wp.apda
ad
.wp.apdaada
w w w w w w
ww ww ww storage battery
III) Lead w
IV)
w Mercury cell ww ww
Primary cells
tet are a) I andteIVt b) I and IIItet c) III and IVtet d) II and III tet
n en n en n en n en en
s
a as
i
lal.a i.
s
a as
i
lal .
a i .
saas
i
lal .
a i .
saas
i
lal .
a i .
saaslail.ani.
ad Zinc can be coated
ada14. adaaon adaad
d iron to producepgalvanized iron but the daad
areverse is not possible. ad is
adaIt
w w.wp.p w w.wp.p w w.w.p w w.wp.p w w.wp.p w
w w w w w ww
Because a) Zinc is lighter than iron b) Zinc has lower melting point than iron
t t t
.ani.ente negative electrode etet etet t t
a l a il.ani.ene c) Zinc hasaillower
ala ala ail.ani.npotential than iron
ala ail.ani.n a l a il.ani.ene
adsa s daadsas daadsas daadsas adsa s
w.wp.apda w . p.ap . p
d)wZinc has higher negative.ap .
w w electrode potential p.ap
w wthan iron w .wp.apda w
ww ww ww ww ww ww
15. Assertion : pure iron when heated in dry air is converted with a layer of rust.
n.entet
lail.ai : Rust has the compositionFe
lail.ai n.entet
l
etet
ail.ani.n l
etet
ail.ani.n l
etet
ail.ani.n
Reason
asaas asaas 3O4 s
ada as s
ada as s
ada as
d d
a) if both assertion ww and reason is the correct ww ww
explanation of assertion. ww
b) if both assertion
t and reasonetare t true but reason nis.ennot t the correct explanation t of assertion. n.entet
i .ani.ente i .ani.ne i.ai te i .ani.ente .i
a
dsaasl a l
adsaasl a l
ads
a asl a l
a
d s
a asl a l
a
d s
a aslaila
ww .p.apac) assertion is true .but
d
ww p.apareason is false
d .p.apad) both assertion and
ww
d .p.apreason
d
a
ww
are false. .p.apa
d
ww w
ww ww ww ww ww ww
8
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
t t
ene t t t t t t t t
lail.aHni.2 -O2 fuel cell the a
16.asIn i.ni.ene occur at cathode
reaction .ni.ene
aslailais il.ani.ene il.ani.ene
adsa asa slala asa a
asa sl a a
asa sl a
w .wp.apda a) O (g) + 2H w .
w p.apdad − w .
w p.apdad + w .
w p.ap−dad w .
w p.apdad w
ww 2 ww2O (l) + 4e− → 4OH w(aq)
w b) H (aq)
ww+ OH (aq) → H2O (l)ww ww
c) 2H2 (g) + O2 (g) → 2H2O (g) d) H+ + e- → ½ H2
asl ail.ani.n asl ail.ani.n asl ail.ani.n asl ail.ani.n 2 asl ail.ani.n
17.
ada The equivalent conductance
s s
ada of M/36 solution
ada of a weak monobasic
s ada acid is 6mho cmadaada
s s
w .wp.apda w .wp.apda w.wp.apda w .wp.apda w.wp.p w
ww -1 ww ww 2 ww -1
equivalent and at infinite dilution is 400 mho cm equivalent . The dissociation constant of this ww ww
t 1.25 ×10−6
acid isi.ni.entea) tet6.25× 10 -6
b) c) et ×10
t1.25 −4
d) tet 10 -5
6.25× t
l a l a l a i
l.ani e
. n
l ail.
ani.en
l ail.ani e
. n
l a i
l .ani.ente
adsaas
apda18. adsaas
apdahas
a
daadsaas 0.01M, 1:1 electrolytic
awith
sas
apdaada solution (specific
sas
apdaada
w .
w p. A conductivity
w cell
.
w p. been calibrated
w .
w p. p w .
w p. w .
w p. w
ww ww ww ww ww ww
-3 −1
conductance ( k =1. 25 × 10 S cm ) in the cell and the measured resistance was 800 ohm at
etet
i.ani.n .ni.n etet −1 .ni.n etet etet
il.ani1.nc m−1 .ni.n etet
25°C aslaila
sasla.l The cell constant sis, a) 10−1 c sm
aslaila b) 101 c m−1
saslac) d) 5.7sa10 i-12
slala
ada ada ada ada ada
ww wwof a saturated solution
19. Conductivity ww of a sparingly soluble
ww salt AB (1:1 electrolyte)
ww at 298K is ww
1.85 ×10−5
t t
S m−1 . Solubility product
t t
of the salt AB at 298K
t t
(Λ° m ) –AB = 14 ×10t −3t S m2 mol−1 . t t
adsa s -12
a) 5.7 × 10apdaadsa s -12 s -12 s
b) 1.32 ×10 apdaadsa c) 7.5 ×10 apdaadsa d) 1.74 10 -12
adsa s
w.wp.apda w .wp. w.wp. w .wp. w .wp.apda w
ww ww ww ww ww ww
20. In the electrochemical cell: Zn | ZnSO4 (0.01M) || CuSO4 (1.0M) | Cu , the emf of this Daniel
et
cell isi.aEni1.e.ntWhen the concentration t t ni.entet and that CuSO 4 ichanged
i.ani.ene of is changed toi.a1.0M .ani.ente
t etet
ail.ani.n
Padasalai.Net
ada aa daada ada ada
w.wp.apdato 0.01M, the emf
w p.apdad to E2. From w
changes
.w .wp.apfollowings,
the which .wp.apisdathe relationship w
one
w .wp.apda
between w
ww ww ww ww ww ww
E1 and E2? a) E1 < E2 b) E1 > E2 c) E2 E1 d) E1 = E2
t t t t t
21. l ail.ani.ente the change inlaoxidation
Consider i
l.ani.ente state of a
Bromine
l i
l .ani.entecorresponding tolaidifferent
l.ani.ente emf values l a i
l .ani.ente
sas sas sas sas sas
.
wp.apdaada .
w p.apdaada .
w p.apdaada .
w p.apdaada .
w p.apdaada
w w w species undergoing w w w
ww as shown in the wwdiagram below: Then wwthe ww disproportional is ww ww
t t t t t t t t t t
ww ww − ww - ww ww ww
a) Br2 b) BrO4 c) BrO3 d) HBrO
22. For
l .entet cell reaction
ail.anithe l a i
l .
ani . tet 3+(aq) + 2l−(aq) →
en2Fe
la i
l .
a ni . et 2+ (aq) + l2 (aq) i.ni.entet
ent2Fe
l a l a l a
t t
il.ani.ene
a
adsa s a a
adsas a
asa s a
asa s a
asa s
w.wp.apdaE° cell = 0.24V at 298K.
w .wp.apdaThe standard Gibbs w pdad
.wp.aenergy (Δ, G°) of the
w .apdadreactions is : w.wp.apdad
.wpcell w
ww ww ww ww ww ww
a) -46.32 KJ mol−1 b) -23.16 KJ mol−1 c) 46.32 KJ mol−1 d) 23.16 KJ mol−1
n.entet
lail.ai n.entet
lail.ai 0.504gm of hydrogen
lail.ai in 2 hours. Howsamany n.entet
lail.ai grams of coppersaaslail.ai n.entet n.entet
23.
asaasA certain current liberated
asaas asaas a as a
d d d d d
ww wwby the same currentwflowing
can be liberated w w in a copper sulphate
for the same wtime ww solution ww
a) 31.75
etet b) 15.8etet c) 7.5 etet d) 63.5 t t
l ail.ani.n l ail.ani.n lali.ani.n l a i
l .ani.ente l a i
l .ani.ente
s as s as adsaas sas sas
adaada adaada a d
a apdaada apdaada
w w.wp.p w w.wp.p w.wp. p w .
w p. w .
w p. w
w w ww ww ww ww
9
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
t t
.ani.eneX at 1 atm is bubble t t
ene t t t t t t
24.asAl a ilgas a l a il.ani.through a solution a l a il.ani.ene
containing a mixtureasof l a ni.ene and 1MZ- at lail.ani.ene
il.a1MY- a
daadsa daadsa s daadsa s daadsa daadsas
. p.a
p . p.ap . p.ap . p.ap . p.ap
w w 25°C . If the reduction w w potential of Z >wYw>wX, then ww ww w
ww ww w ww ww ww
a) Y will oxidize X and not Z b) Y will oxidize Z and not X
ada c) Y will oxidize both
s X and Z
s
ada d)
adaY will reduce bothaXdaaand
s da Z
s s
ada
w .wp.apda w .wp.apda w.wp.apda w .wp.p w .wp.apda w
ww ww
25. Cell equation : A + 2B →A +2B; - 2+ ww ww ww ww
A2 + + i2e -
t
.ni.ente→ A
E° = +0.34 iV ntet log 10 K = 15.6 a
.ani.eand ati.n300K t
i.ente for cell reactions i ntet E° for
.ani.efind i .ani.ente
t
l a l a l a l l la l a l l a l
sas adsaas adsaas sas sas
.
w p.apdaBad+a+ e− → B (AIIMS.
w p.a–pda2018) a) 0.80 .wp.apdab) 1.26 c) -0.54
.
w papdaada d) -10.94
. .
w p.apdaada
w w w w w w
ww ww ww ww ww ww
i.ani.netet i.ani.n etet t t

il.ani.ene
t t
il.ani.ene
t t
il.ani.ene
ADDITIONAL
saslal QUESTIONS:
saslal a l a a l a a l a
ww ww reactions are generally
1. Electro chemical ww (a) Reduction w w
reactions (b) oxidation ww reactions ww
t t t t (c) Redoxt reactions t (d) condensation

t t reactionst t
n
il.ai e
. n e n
il.ai e
. n e n
il.ai e
. ne n
il.ai e
.n e il.ani.ene
asl a asl a -1 asl a -1 a2sl a -1 -1 a sl a
2.adsaThe unit of resistivity adsis
a (a) Ω m adsaΩ m
(b) (c) m Ohm adsa (d) Ω mapdaadsa
w.wp.apda w .wp.apda w.wp.apda w.wp.apda w.wp. w
ww ww ww ww ww ww
3. The unit of specific resistance is equal to
t -1t t -1 -1 t
.ani.ente metre
(a) iOhm (b) Ohm .ani.ente metre i.enteOhm metre lail.ani.ente (d) Ohm
.an(c) etet
ail.ani.n
Padasalai.Net
a l a l a l ail a l a i
l a a l
s
daada s s
ada s s
ada s s
ada s s
ada s
w.wp.ap4. Which is the SIw .wp.apdaof conductance? w.wp.apda
unit w .wp.apda w .wp.apda w
ww ww ww ww ww ww
(a) Siemen-1 (or) S-1 (b) Siemen (or) S (c) Sm-1 (d) S-1m-1
entet
.ni. il.ani. entet i.ani. entet .ani.ente
t
.ani.ente
t
aslaila one is the unitsaof
5. saWhich aslaspecific saaslal
conductance? sasl ail sasl a i
l
adaad adaad adaad apdaada apdaada
w w.wp.p (a) Ohm m ww.wp.p (b) Ohm-1 m ww.wp.p (c) Ohm m-1 .
w p.
w (d) Ohm-1 m-1. ww .
w p. w
w w w ww w ww
6. The unit
tet of equivalent conductance
tet is ………… t t t t t t
a la il.ani.en2 a l a il.ani.en a la il.ani.e-1ne -1 a l a il.ani.ene a l a il.ani.ene
s Sm g equivalentdadsas
adsa(a) (b) Sm-1 s
adsaOhm
(c) m as m
(d)adsOhm adsas
w .wp.apda w .wp.apa w.wp.apda w.wp.apda w .wp.apda w
ww ww ww ww ww ww
7. Which one of the following is used to measure conductivity of ionic solutions?
t t t t t t t t
l a .ani.ente scale
(a)ailmetre (b)awheat
l i.enteDynamo (d) Ammeter
il.ani.ene stone bridge alail.an(c) l a il.ani.ene l a il.ani.ene
a s as s a s a s
daadsa
.wp.ap8.
adsa
.wp.apda is used to calculate
adsa
.wp.apdathe conductivitywof
asa
pdad electrolytes?
.wp.astrong .wp.apda
adsa
w Which of the following
w w w w
ww ww ww ww ww ww
(a) Kohlraush’s law (b) Henderson equation
etet t
.ani.enteOnsagar equation etet t t
il.ani.ene law etet
s asl ail.ani.n (c) Debye-Huckel s aslailand s asl ail.ani.n (d) Ostwald’s s asladilution s asl ail.ani.n
ada ada ada ada ada
ww 9. Which one of wwthe following represents ww Debye-Huckel and wwOnsagar equation? ww ww
t t t t t
l a i
l.ani.ente l a i
l .ani.ente l a i
l .ani.ente
sas sas sas sas sas
.
w p.apdaada .
wp.apdaada .
w papdaada
. .
w p.apdaada .
w p.apdaada
w w w w w w
ww ww ww ww ww ww
10
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
t t t t t t t t t t
i.ni.ene
10. aKohlrausch’s law is applied .ni.ene
aslaila to calculate il.ani.ene il.ani.ene il.ani.ene
adsa slala adsa sasl a a
asa sl a a
adsa sl a
.wp.apda (a) molar conductance
.wp.apda at infinite dilution aada
.wp.apdof . p.apdad .wp.apda
w w w a weak electrolyte w w w w
ww ww ww ww ww ww
(b) degree of dissociation of weak electrolyte
ada(c) solubility of a sparingly
s s
ada soluble salt adaada
s s
ada s
ada
ww ww
(d) all the above ww ww ww ww
11. Thei.nsalt t t contains t t t

lala i.ente bridge used in Daniel
lala
t cell
i.ni.ene l ail.ani.ente l ail.ani.ente l a i
l .ani.ente
adsaas adsaas asaas sas
apdaada
sas
apdaada
a
w.wp. pda (a) Na2SO4 + NaCl a
w.wp.pda p.apdad
(b)w.w
Agar-Agar gel + Na2SO w.w
4p. w .
w p. w
ww ww ww ww ww ww
(c) Silica gel + CuSO4 (d) ZnSO4 + CuSO4
t t ntet act as an inert aelectrode? t t t t t t
12.sWhich
a l a il.ani.eneone of the following a l ail.ani.ecan a l il.ani.ene a l a il.ani.ene a l a il.ani.ene
ww (a) Graphiteww (b) Copper ww (c) Platinum ww (d) either a (or) w ew ww
13. The emf
t t
of Daniel cell Zn(s) + tZnt 2+aq(1m) || Cu2+aq(1m) |t Cu
t (S) iS equal to …………
t t t t
s
adsa(a) – 1.107 Volts adaads(b)s
a 1.107 Volts s
adsa3.4 Volt
(c) s
(d)ads7.6
a Volt adsa s
ww ww ww ww ww ww
14. The value of EMF of standard hydrogen electrode at 25°C is …………
etet
(a) imaximum (b) zero etet (c) negative etet (d) positive etet etet
al.ani.n ail.ani.n ail.ani.n ail.ani.n ail.ani.n
Padasalai.Net
daada
.wp.ap15.
ada
.wp.apdain SHE is made ofw…………. .wp.apda
ada
.wp.apda
ada
.wp.apda
ada
w The electrode used
w w w w
ww ww ww ww ww ww
(a) graphite (b) copper (c) platinum (d) iron
t t t t t
16.saThe
l ail i.ente
.anmaximum work thatl a i
l.ani.entebe obtained fromlaail.angalvanic
can i.ente cell is ……….. l ail.ani.ente l a i
l .ani.ente
as sas sas sas sas
.
wp.apdaad .
w p.apdaada .
w p.apdaada .
w p apdaada
. .wp.apdaada
w (a) + nFE www (b) – nFE www w (d) 96500 F w w
ww (c) 2F ww ww ww
17. For all tspontaneous
et
cell reactions,
tet the value of ?G should
tet be …………. t t t t
a
en
lail.ani. a
en
lail.ani. a la il.ani.en a l a il.ani.ene a l a il.ani.ene
s
a s sa s s
adsanegative as
(d)adspositive adsas
adaad (a) constant adaad(b) zero (c)
.wp.apda .wp.apda .wp.apda
w w ww ww ww ww
18. The value of one Faraday is equal to …………..
t t t t t -19 t x 1019C t t
l a .ani.ente C
(a)ail96400
l a il.ani.ene C
(b)a96500
l a
(c) 1a.602
l a(d)
i
l .
ani en1te.602
il.ani.enex 10 C
. l a il.ani.ene
a s as as a s a s
daadsa
.wp.ap19.
asa
p.apdad the cell potential
.w .wp.apdand
s
aada adsa
.wp.apdaof the species involved
adsa
.wp.apda in an
w Which equation
w relates w the concentration
w w w
ww ww ww ww ww ww
electro chemical reaction? (a) Henderson equation (b) Arrhenius equation
etet t t
il.ani.ene Huckel Onsagar .ani.ente
t tet
il.ani.enNemst etet
s asl ail.ani.n (c)
s aslaDebye s asl ailequation s asla(d) equation s asl ail.ani.n
ada ada ada ada ada
ww ww ww ww ww ww
t t t t t
l a i
l.ani.ente l a i
l .ani.ente l a i
l .ani.ente
sas sas sas sas sas
.
w p.apdaada .
wp.apdaada .
w papdaada
. .
w p.apdaada .
w p.apdaada
w w w w w w
ww ww ww ww ww ww
11
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
.ni.enet t .ni.ene t t
.ni.ene t t t t t t
20. Which
aslaila is Nernst equation.
adsa adsa adsa adsa s adsa s
ww ww ww ww ww ww

ada ada ada ada ada
ww ww ww ww ww ww
t t t t t
l a i
l .ani.ente l a i
l .ani.ente
sas sas sas sas sas
.
w p.apdaada .
w p.apdaada .
. .
w p.apdaada
w w w w w w
ww ww ww ww ww ww
t t t t t t t t t t
ww ww ww ww ww ww
21. Which one of the following represents Faraday’s first law?
t tet .entet t t t t
(a) .ani.en=teZit
lailm il.ani=.enZ/It
(b)lam (c) mlail=.aniIt/Z il.ani.ene
(d) Z =lamIt l a il.ani.ene
a s as as a s a s
daadsa
.wp.ap22. .wp.of
s
apdaada .passed
asa
p.apdad the amount of
asa
p.apdad
.w
asa
pdad
.wp.aliberated
w When 1 coulomb
w electric current is
w w w substance deposited wor is w
ww ww ww ww ww ww
known as (a) equivalent mass (b) electro chemical equivalent
etet t t
il.ani.ene etet etet etet
ail.ani.n ail.ani.n ail.ani.n ail.ani.n
Padasalai.Net
s asl s a
(c)sl amolar mass s asl (d) 1 Faraday s asl s asl
ada ada ada ada ada
ww 23. Which one of wwthe following is usedww in cell phone, dry cellwin w flashlight? ww ww
(a) Zn – Cu battery
n.entet
(b) Lin–.ention
t battery (c) Ag –n.eCu tbattery (d) Na, NaCI tbattery t
l ail.ai l a i
l.ai e l a i
l .ai nte l ail.ani.ente l a i
l .ani.ente
as sas sas sas sas
.p. daadsaThe
ap24. primary . .apdaadaare ………..
batteries
p . p.apdaada . p.apdaada . p.apdaada
ww ww ww ww ww ww
(a) rechargeable (b) non – rechargeable (c) reversible (d) renewable
.ni.ene t t t t t t t t t t
25. The
alailaanode and cathode il.ani.enein Leclanche cell
alaused alaare
e
il.ani.en………… respectively. .ni.ene
alaila a l a il.ani.ene
adsas asas asas asas asas
w .wp.apda (a) Zinc, Graphite
w pdad
.wp.arod w.wp.apdad w.wp.apdad w .
w p.apdad w
ww ww with MnO2 ww (b) Graphite rod
wwin MnO2 and Zinc container
ww ww
(c) Zn container and copper rod (d) Copper container and Zinc rod
t t t t t t t t t t
26. s
adsaWhich electrolyteaisdaaused s
dsa in Leclanche cell? adsa s adsa s adsa s
w.wp.apda w .wp.p w.wp.apda w .wp.apda w .wp.apda w
ww ww
(a) ZnSO4 + CuSO4 ww
(b) NH4CI + ZnCl2 (c) NaCI + CuSO4 ww (d) MnSO4 + MnO2 ww ww
27. Which one

.ni.ente
t of the followingn.eis
. i nte
used
t as cathode in.nMercury
i.ente
t button cell? .ni.entet etet
laila laila l aila laila l ail.ani.n
dadsaas s
ada as s
ada as s
ada as s
daada
as
a a
w.wp.p (a) Zinc .wp.apda
(b) Copper
w .wp.apda
(c) Zinc amalgamated
w .wp.apda (d) HgO mixed with
with mercury
w w.wp.apgraphite w
ww ww ww ww ww ww
28. Which one of the following is used as anode in Mercury button cell?
tet
.ani.en mixed with graphite tet t
i.enteZinc amalgamated
t
i.ente mercury .ani.ente
t
(a) iHgO i.ani.en i.an(b) i .anwith i
saslal saslal sasl a l sasl a l sasl a l
.
w p.apdaada .
wp.apdaada .
w papdaada
. .
w p.apdaada .
w p.apdaada
w w
(c) Copper amalgamated w
with Mercury ww with Copper www
(d) HgOwmixed w
ww ww ww ww
12
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
.ni.enet t t t
e e button cell is ………..
.ni.ene t t t t t t
29. The ail.ani.n
aslailavalue of cell emf ofaslMercury aslaila a l a il.ani.ene a l a il.ani.ene
w .wp.apda (a) 1.35V w .wp.apda (b) – 076V w .wp.apda(c) 0.34V w pdad
ww ww ww ww 100V ww ww
30. The electrolyte used in Mercury button cell is (a) Paste of kOH and ZnO
ada (b) CuSO4 + ZnSOa4 daada
s s (c) NaCl + MgCl s
ad2a (d) NH4aCI ad+aZnCl2
s s
ada
w .wp.apda w .wp.p w .wp.apda w .wp.pda w .wp.apda w
ww ww ww
31. Which of the following is an example of secondary batteries? ww ww ww
(a) iMercury t button cell i.ni.en(b) tet Leclanche cell .n(c) t t t

l a l.ani.ente l a l a l aila i.enteLead storage battery l ail.ani.ente (d) Daniel cell lail.ani.ente
as sas dsaas in Lead storage saas sas
. p. daadsaWhich
ap32. of the . .apdaada act as cathode .w
following
p p.apdaaanode
and . papdaadbattery?
. . p.apdaada
w w w w w w w w w w
ww ww ww ww ww ww
(a) Lead plate bearing PbO2, spongy Lead (b) Spongy lead, lead plate bearing PbO2
t t t t t t t t
(c)
l a .ani.ente Copper
ilLead l ail.ani.ene l a i.enteMercury oxide, PbO
il.an(d) l a il.ani.ene l a il.ani.ene
a
adsas a
adsas a
adsas a
adsas a
adsas
ww 33. Which one of wwthe following is usedww as an electrolyte in Hw2O w2 fuel cell? ww ww
(a) Aqueous
t t
CuSO4 (b) Aqueous CoO2
t t
(c) Aqueous
t t
KOH (d) NH4CI +t ZnCI
t 2 t t
34. s
adsaThe formula of rust s
adsa………..
is adsas adsa s adsa s
ww ww ww ww ww ww
(a) Fe2O3 (b) Fe2O3.xH2O (c) FeO (d) FeO.xH2O
t plating of Zinc novert t ni.entet etet etet
i.ente
35. Thei.anelectro i.ai.ene a metal is calledi.a………….. ail.ani.n ail.ani.n
Padasalai.Net
s asl al s asl al s asl al s asl s asl
ada ada ada ada ada
w.wp.apda (a) Electrolysisw.wp.apda (b) Redox reaction
w .wp.apda (c) w .wp.apda
Galvanisation (d) Passivation
w .wp.apda w
ww ww ww ww ww ww
36. Which amount of chlorine gas liberated at anode, if 1 ampere current is passed for 30 minutes
sfrom ail.ani. ail.ani. lail.ani.moles i.ani.
saaslal g (d) 0.33 g saaslail.ani.
adaad aasl NaCI solution? s(a)
aasl 0.66 moles
adaad adaad
(b)saas0.33 (c) 0.66
adaad adaad
w w.wp.p w w.wp.p w w.wp.p w w.wp.p w.wp.p w
w w w w ww ww
entet entet
10. SURFACE CHEMISTRY t t t t t t
a la i
l.ani.
a l a i
l .
a ni .
a la il.ani.ene a l a il.ani.ene a l a il.ani.ene
adsas adsas adsas asas asas
w .wp.apda1. For freudlich isotherm
w .wp.apda a graph of log wx/m .wp.apda w .
w p.apdad w .
w p.apdad w
ww ww ww is plotted against ww log P. The slope of w the
w line and ww
its y – axis intercept respectively corresponds to
t t t t t t t t t t
s
adsa a) 1/n, k adsb)s
a log 1/n, k adsa s s
c) 1/n, log k daadsa d) log 1/n, log k daadsa s
.wp.apda .wp.apda .wp.apda .p.ap .p.ap
ww
w
w w w
w w w
w ww w w ww w ww
w
2. Which of the following is incorrect for physisorption?
a) reversible
etet etet b) increases with
.ni.ente
tincrease in temperature
.ni.ente
t etet
s asl ail.ani.n s aslail.ani.n s asl aila s aslaila s asl ail.ani.n
ada ada ada ada ada
w.wp.apda c) low heat ofwadsorption
.wp.apda .wp.apda
d)wincreases with increase
w .apda
.wpin surface area w.wp.apda w
ww ww ww ww ww ww
3. Which one of the following characteristics are associated with adsorption? (NEET)
tet
.ani.en and ΔHare negative tet tet tet tet
a) iΔG i.ani.ebut i.enΔGand ΔS are negative
n ΔS is positive ail.anb) i.ani.en but ΔH is positivei.ani.en
saslal saslal sasl saslal saslal
adaada .wp.apda
ada
.wp.apda
ada
.wp.apda
ada
.wp.apda
ada
w.wp.p w
c) ΔG is negative but ΔH and ΔS are w w w w
w w w w w positive
w d)ΔG, ΔH
w and ΔS all are negative.
w w w ww
13
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
t t
.ni.ene ee t t t t
e t t
ni.ene d) gas in liquidlail.ani.ene t t
4. Fog ail.ani.na) solid in gas
aslailais colloidal solutionaslof b) il.ani.enin
aslagas gas ail.agas
c) liquidaslin as
adsa adsa asa asa adsa
w .wp.apda5. Assertion : Coagulation
w .apdad
.wp.apda power of Al3+wis.wpmore + w .
ww ww ww than Na . ww ww ww
Reason : greater the valency of the flocculating ion added, greater is its power to cause
precipitation
s
ada s
ada s
ada s
ada s
ada
ww a) if both assertion ww and reason are true ww and reason is the correct ww ww
b) if both t
t assertion and reason t true but reason nis.ennot
tare t t the correct explanation
t t of assertion. .ni.entet
lalai.ni.ene lala i.ni.ene lala i. i e lala i.ni.ene lala i
a daadsaas adaadsaas a daadsaas a d
a adsaas a daadsaas
w.wp. c) assertion is true
p but
p. reason is false w.wp.
w.w p p d) both assertion
w.wp. p and reason arewfalse.
.wp. p w
ww ww ww ww ww ww
6. Statement : To stop bleeding from an injury, ferric chloride can be applied. Which comment
t
ni.entestatement t t t t t t t
about l a il.athe is l ail.ani.ene
justified? a) Itl is
a il.ani.entetrue, ferric chloride
not l a il.ani.enisea poison. l a il.ani.ene
a
adsas a
adsas a
adsas a
adsas a
adsas
w .wp.apda w .wp.apda
3+ w .wp.apda w .wp.apda w .wp.apda w
ww b) It is true,ww Fe ions coagulate blood ww which is a negatively ww charged sol ww ww
c) It ist not
t true; ferric chloride
t t
is ionic and gets intot the
t blood stream. t t t t
s
adsa d) It is true, coagulation s
adsa takes place because s
adsa of formation of negatively adsa s charged sol awith s
adsaCl . -
w.wp.apda w .wp.apda w.wp.apda w.wp.apda w .wp.pda w

ww ww ww ww ww ww
7. Hair cream is a) gel b) emulsion c) solid sol d) sol.
8. Which tet of the following t
ntecorrectly t t etet etet
i.ani.enone i.ani.eis matched?
i.ani.ene ail.ani.n ail.ani.n
Padasalai.Net
lal lal lal l l
d adsaas d adsaas d adsaas s
ada as s
ada as
a
w.wp.p
a a a
a) Emulsion ww.wp.p – a
Smoke ww.wp.p a
ww w w ww ww ww
b) Gel – butter
t tet t t t
c)
l ail.ani.ente
foam – l a i
l.ani.enMist l a i
l .ani.ente
sas sas sas sas sas
.
wp.apdaada .
w p.apdaada .
w p.apdaada .
w ww sol www w w w
ww d) whippedwcream – ww ww ww
9. The most
tet effective electrolyte
tetfor the coagulation of
tetAs2 S3 Sol is t t t t
a
en
lail.ani. a l a il.ani.en a la il.ani.en a l a il.ani.ene a l a il.ani.ene
s
a s asBa (NO3) 2
adsb) dsaKs [Fe(CN)6] adsas d) Al2 (SO4) 3 adaadsas
adaad a) NaCl .wp.apda
ac)
.wp.apda 3 .wp.apda
w w.wp.p w w w w.wp.p w
w ww ww ww
+ ww ww
10. Which one of the is not a surfactant? a) CH3 (CH2)15 N (CH3)2 CH2Br
t t ) CH OSO - Na +t t t
t t - +
l a i.ente2) 15 NH2
b) CHa3il.an(CH
l a
c) CH e(teCH
ail.an3i.n l 2 16
a
2 2 ail.ani.ene
l a l a i.ente2 COO Na
il.ani.ene
d) OHC (CH2)a14il.anCH
a
adsa s a
adsas a
adsa s a
asa s a
adsa s
w.wp.apda11. The phenomenon
w .wp.apdaobserved when awbeam
.wp.apda of light is passed
w p.apdad a colloidal solution
.w
through w .wp.apda is w
ww ww ww ww ww ww
a) Cataphoresis b) Electrophoresis c) Coagulation d) Tyndall effect
l ni.entet
ail.aan l ni.entet
ail.aparticles l ni.entet
ail.asystem l i.ente
ail.ancathode.
t
l
etet
ail.ani.n
12.s
ada aIn
s electrical field, s
adathe
as of a colloidal
s
ada as move towardss
ada as The s
ada as
ww coagulation ofwthe w same sol is studied wwusing K2 SO4 (i), Na3 PO ww4 (ii),K4 [Fe(CN6) ] (iii) ww ww
and NaClete(iv)
t Their coagulatingepower
tet should be t t t
l a i
l.ani.ente l a i
l .ani.ente l a i
l .ani.ente
sas saasIII > II > I > IV dsaaIs> II > III > IV p.ad) saas of these sas
.
w p.apdaada a) II > I>IV > III .wp.apdaadb) .
w papdaac)
. .
w pdaad
none .
w p.apdaada
w w w w w w
ww ww ww ww ww ww
14
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
t t t t t t t t t t
l a il.ani.ene is a 4% solution
13.asCollodion a l a .enewhich one of thelafollowing
il.aniof a il.ani.ene compounds a l ain ene
il.ani.alcohol – ether aslail.ani.ene
adsa adsa s asa s asa s asa
w .wp.apdamixture? a) Nitroglycerine
w .wp.apda w .
w p.apdad w .
w p.apdad w .
w p.apdad w
ww ww b) Cellulose
ww acetate c)
wwGlycoldinitrate d)wNitrocellulose
w ww
14. Which one of the following is an example for homogeneous catalysis?
ada a) manufacture of
s ammonia
s
ada by Haber’saprocess
s
ada b) manufacture aof
dasulphuric acid byp.acontact
s s
ada
w .wp.apda w .wp.apda w.wp.pda w .wp.apda w .w pda w
ww process ww
c) hydrogenation of oil ww ww
d) Hydrolysis of sucrose in presence of all HCl ww ww
15. Match t tthe following .ani.ente

t
.ani.ente
t
.ani.ente
t
.ani.ente
t
i.ni.ene
lala l a i
l l ail l ail l a i
l
a daadsaas sas
apdaad-a
saas
apdaadpolyethylene
sas
apdaada
sas
apdaada
w.wp. p A) V2O5 w .
w p. i) High density
w .
w p. w.wp. w .
w p. w
ww ww ww ww ww ww
B) Ziegler – Natta - ii) PAN
C)
l a ni.entet
il.a
Peroxide - l a
tet
il.ani.eniii) NH l a
t t
il.ani.ene l a
t t
il.ani.ene l a
t t
il.ani.ene
a
adsas a
adsas
3 a
adsas a
adsas a
adsas
ww D) Finely dividedww Fe - w4
iv) H2wSO ww ww ww
t
At B C Dt t t t t t t t
n
il.ai e
. n e il.ai e
n e
. n il.ani.ene il.ani.ene il.ani.ene
adsa a) (iv) (i) apdaads(ii)
a (iii) adsa adsa adsa
w.wp.apda w .wp. w.wp.apda w.wp.apda w .wp.apda w
ww ww ww ww ww ww
b) (i) (ii) (iv) (iii)
c) i.ani.entet(ii) (iii) (iv) i.ani.en(i) tet etet etet etet
Padasalai.Net
ada ada ada ada ada
w.wp.apda d) (iii) w .wp.apda (ii)
(iv) (i) w .wp.apda w .wp.apda w .wp.apda w
ww ww ww ww ww ww
16. The coagulation values in millimoles per litre of the electrolytes used for the coagulation of
entet
.ani. given below (I)la(NaCl)=52
.ni. entet entet entet .ani.ente
t
As2aSla3 ilare a ila lail.ani. 2 )=0.69
(II)saas((BaCl i.ni.
slala 4 )=0.22
(III)saa(MgSO sasl a i
l
a daadsas .wp.ap daadsas .wp.apda
ad adaad apdaada
w w.wp.p The correct order
w wof w w w w.wp.p w.wp. w
w w their coagulating
w power is w ww ww
a) III >teIIt > I b) I > II t>etIII c) I > III >teIIt d) II > III>I tet t t
a la i
l.ani.en
a l a i
l .
a ni en
.
a la i
l .
a ni en
.
a l a il.ani.en a l a il.ani.ene
adsasAdsorption of a gas
17. sas solid metal surface
adon asspontaneous andadexothermic,
adsis adsas then p.apdaadsas
w .wp.apda w .wp.apda w.wp.apda w.wp.pa w.w w
ww ww ww ww ww ww
a) ΔH increases b) ΔS increases c) ΔG increases d) ΔS decreases
et amount of adsorb
18. Ifailx.aniis.entthe etet etet etet etet
ala ala ail.ani.nate and m is the amount
ala ail.ani.n of adsorbent, which
ail.ani.n of the followingail.ani.n
ala ala
. p.apdaadsas . p.apdaadsas . p.apdaadsas . p.apdaadsas . p.a
p daadsas
w w relations is not related
w w to adsorption process?
ww ww ww w
ww ww ww ww ww ww
a) x/m=f(P) at constant T b) x/m=f(T) at constant P
l .entet
ailP.ani= l
etet
ail.ani.n l
etet
ail.ani.n l
etet
ail.ani.n l
etet
ail.ani.n
s
ada ac)
s f(T) at constant s
ada m/x
as d) x/m= PT
s
ada as s
ada as s
ada as
ww 19. On which of wwthe following properties ww does the coagulating ww power of an ion depend ww ? ww
(NEET –e2018)
tet a) Both magnitude t and sign of thencharge t on the ion. nb).entSize t of the ion alonen.entet
i .ani.n i .ani.ente i.ai.ente i .ai e .i
a
d
l a l
saasc) the magnitude of adsaasl a l
a
d s
a asl a l
a
d s
a asl a l
a
d s
a aslaila
aad a a the charge on the.wpion
d a a alone
d d) the.psign
a a of charge on the.wpion
d a a alone.
d
w.wp.p w.wp.p w .p w w.p w .p w
ww ww ww ww ww ww
15
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
t t t t t t t t t t
20.asMatch
l a il.ani.enethe following alail.ani.ene a l a il.ani.ene a l a il.ani.ene a l a il.ani.ene
. p.a
pdaadsa . p.apdaadsas .
asa
p.apdad
s
.wp.apda
adsa s
.wp.apda
adsa s
ww A) Pure nitrogen ww - w w w w w
ww ww wwi) Chlorine ww ww ww
B) Haber process - ii) Sulphuric acid
ada C) Contact process
s s
ada - iii) Ammonia s
ada s
ada s
ada
ww ww
D) Deacons Process - ww iv) sodium azide (or) Barium azide ww ww ww
Whichi.nof t t t t t
lalai.entethe following is thei.ncorrect
i.ente
lala
option?
l ail.ani.ente l ail.ani.ente l a i
l .ani.ente
apdaada
sas
apdaada
sas
apdaada
w.wp. p A B.wp. C
w p D w .
w p. w.wp. w .
w p. w
ww ww ww ww ww ww
a) (i) (ii) (iii) (iv)
t t tet t t t t t t
ab)
l a il.ani.ene (ii) (iv) (i)
a l ail.ani.en(iii) a l a il.ani.ene a l a il.ani.ene a l a il.ani.ene
ww c) (iii)ww (iv) (ii) (i) ww ww ww ww
d) t t(iv) (iii) (ii) (i)t
t t t t t t t
n
il.ai e
. n e il.ai e
n e
. n il.ani.ene il.ani.ene il.ani.ene
adsa
ADDITIONAL QUESTIONS adsa : adsa adsa adsa
ww ww ww ww ww ww
1. When gas molecules are held to the surface by the formation of chemical bond the heat energy
released enteist nearly equal to i.ani.entet etet etet etet
lail.ani. ail.ani.n ail.ani.n ail.ani.n
Padasalai.Net
s as a s as a lal s asl s asl s asl
ada ada ada ada ada
w.wp.apda(a) 40 kJ/mole w.wp.apda (b) 800 kJ/molew.wp.apda (c) 400 w .wp.apda
kJ/mole (d) 4 kJ/mole
w .wp.apda w
ww ww ww ww ww ww
2. Consider the following statements:
t t t t t
l.ani.ente l a i
l .ani.ente
s(i)asIn chemisorption,dheat sas of adsorption is dhigh sas sas sas
.
wp.apdaada .
w p.apaada .
w p.apaada .
w w w w w w
ww (ii) Monolayer wwof the adsorbate is formed ww during chemisorption ww ww ww
(iii) Physisorption
etet increases with
etet increase in temperature.
etet t t t t
a lail.ani.
n
a lail.ani.
n
a lail.ani.
n
a l a il.ani.ene a l a il.ani.ene
s
a s sa s sa s adsas adsas
adaadWhich of the above aad
adstatement is / are not aad
adcorrect’? .wp.apda .wp.apda
w w w ww ww ww
(a) (i) & (ii) (b) (iii) only (c) (ii) only (d) (i) only
3. Which entet entet ni.entet t t
il.ani.ene
t t
il.ani.ene
lail.ani. of the following gases
a lail.ani. is not a permanent
a lail.agas? a a l a a l a
. p.apdaadsas . p.apdaadsas . p.apdaadsas .wp.a(d)
asa
pdadO
s
.wp.apda
adsa s
ww (a) NH3 ww (b) H2 w w (c) N2 w w w
ww ww ww ww 2 ww ww
4. Which is employed in the softening of hardwater to absorb Ca 2+ and Mg2+ ions?
t t t t etet etet etet
a l il.ani.ene
aAlumina a l il.ani.ene
aSilica a l ail.ani.n a lail.ani.n a l ail.ani.n
(a)
s
ada s (b)
s
ada s gel (c)s
ada Permutit
s (d) Charcoal
s
ada s s
ada s
ww 5. Which of thewfollowingw ww
is used in petroleum refining and w w
refining of vegetable oils? ww ww
(a) Charcoal
nentet
(b) Silica gel
nentet
(c) Pcrmutit
nentet
(d) Nickelnentet t
i.ai. i.ai. i.ai. i.ai. i .ani.ente
saaslal saaslal saaslal saaslal sasl a l
aad a
d aadad aadad aad a
d apdaada
w.wp.p w.wp.p w.wp.p w.wp.p w .
w p. w
ww ww ww ww ww ww
16
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
.ani.enet t ene t t ni.ene vanaspathi isla………… t t

.ni.ene t t t t
6. The
aslailcatalyst lail.ani.
used in theashydrogenation lail.a
of oilsasto obtain as ila a l a il.ani.ene
adsa adsa adsa asa adsa s
w .wp.apda (a) Iron w .wp.apda (b) Molybdenumw .wp.apda(c) Nickel w pdad
ww ww ww ww Copper ww ww
7. The catalyst and promoter used in Haber’s process are respectively ………..
ad(a)
sa Mo, Fe ad(b)
sa Fe, Mo (c)
adaPt, H2S
s (d)adPt,
a V 2O 5
s s
ada
ww 8. Which method ww is used for identification, ww detection and estimation ww of many substancesww even if ww
theyi.nare t t t t t t
l a li.entein micro quantities?
a i.ni.ene
l a l a l ail.ani.ente l ail.ani.ente l a i
l .ani.ente
saas saas adsaas sas sas
.
w p.apdaad(a) Lassaigne’s test
.
w p.apdaad(b) Canus method.
w p.apda(c) Kjeldhals method
.wpapdaada (d) Chromatography
. .
w p.apdaada
w w w w w w
ww ww ww ww ww ww
9. Which one of the following is an example for heterogeneous catalysis?
etet
il.ani.n i.ani.n eteti.ani.n etet t t
il.ani.ene
t t
il.ani.ene
adas(a)
aslaDecomposition of acetaldehyde
saslal
ada
by I2 catalyst
saslal
ada a
adsas
l a a
adsas
l a
ww ww
(b) Decomposition ww
of H2O2 in the presence of Pt catalyst ww ww ww
(c) Acidt hydrolysis
t of ester t t t t t t t t
s
ads(d)
a Hydrolysis of cane s
adssugar
a with mineralapacidadsas adsa s adsa s
w.wp.apda w .wp.apda w.wp. da w.wp.apda w .wp.apda w
ww ww ww ww ww ww
10. The catalyst poison in contact process of manufacture of SO3 is …………
(a) As eOtet (b) Hi.an2iS.entet (c) COi.ani.entet (d) As2Si.3ani.entet etet
ail.ani2.n 3 ail.ani.n
Padasalai.Net
s asl s asl al s asl al s asl al s asl
aa aa ada ada ada
w pdadIn Haber’s process
.wp.a11. w pdadmanufacture of w
.wp.aof .wp.apda
ammonia, the Fe catalyst
w pdapoisoned
.wp.ais by the .wp.apda of
pressure
w w
ww ww ww ww ww ww
(a) Mo (b) Co (c) H2S (d) As2O3
ail ntet
.ani.ereaction a i
l ni.enteOt acts as a catalytic
.a2H a i
l ntet
.ani.epoison ail.ani.ente
t
a i
l .ani.ente
t
12. sIn
aslthe 2H 2 + O →
s2asl 2 sasl for Pt catalyst.
sasl sasl
.
wp.apdaada .
w p apdaada
. .
w p.apdaada .
w w w w (d) H S w w
ww (a) Co ww (b) Mo ww (c) As2O3 ww 2 ww ww
13. The negative
tet catalyst in the decomposition
tet of H2O2 is
tet………….. t t t t
a la il.ani.en a l a il.ani.en a la il.ani.en a l a il.ani.ene a l a il.ani.ene
as Ethanol
ads(a) as Acetic acid
ads(b) s
adsaEthanoic
(c) acid p.a(d) as
adsMethanol adsas
w .wp.apda w .wp.apda w.wp.apda w.w pda w .wp.apda w
ww ww ww ww ww ww
14. The energy required for the reactants to reach the activated complex is called …………
t t t tet free energy ail.ani.entet
.ni.ente
(a)athreshold .ni.ente
energy (b)aactivation energy i.enteinternal energy la(d)
il.an(c) il.ani.enGibbs
sal ila s al ila a sla a s al
. p.apdaadsa . p.apdaadsa . p.apdaadsa . p.apdaadsa . p.a
p daadsas
w w 15. Which enzymeww
catalyses
w the conversion
w wof glucose into ethanol? ww ww w
ww w ww ww ww ww
(a) maltase (b) invertase (c) diastase (d) zymase
etet i.ente
t .entet etet etet
asl
16.asWhichail.ani.none of the followings aslail.anis used as a catalysts asl il.anithe
ain conversion of
s a lail.ani.n to cyclohexane?
Lindane
s s asl ail.ani.n
da ada ada ada ada
ww (a) Fe°/Pd° ww (b) Ni ww (c) Zn + HCl ww (d) LiAIH4 ww ww
17. An example
etet of liquid aerosoleis
tet……….. t t t
l.ani.ente l a i
l .ani.ente l a i
l .ani.ente
s as s as adsaaFog
s aas sas
a Soda water
adaad(a) a Milk
adaad(b) apda(c) daadsInks
a(d) apdaada
w p. w .
w p. p w .
w p. w
w w ww ww ww ww
17
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
18. Which
aslaila method is used to il.ani.ene metal sols?alail.ani.ene
aslaprepare a l a il.ani.ene a l a il.ani.ene
adsa adsa s asa asa s asa s
w .wp.apda (a) ultrasonic dispersion
w .wp.apda w .
w p.apdad w .
w p.apdad w .
w p.apdad w
ww ww (b) mechanical
ww dispersion (c)
wwBredigs arc methodww (d) peptisation ww
19. Which method is used to prepare mercury colloid?
ad(a)
sa peptisation (b) amechanical s
ada dispersionad(c)
adaultrasonic dispersion
s ad(d)
sa Bredig’s arc method s
ada
w .wp.apda w .wp.pda w.wp.pa w .wp.apda w .wp.apda w
ww ww ww
20. The conversion of a precipitate into colloid is called ………….. ww ww ww
t t
(a) coagulation (b) hydrolysis
.ani.ente
t (c) condensation
.ani.ente
t (d) peptisation
.ani.ente
t
.ani.ente
t
l ai.ni.ene
l a l a i
l l ail l ail l a i
l
aas
daadsThe
a21.
sas
apdaada of colloidal solution
sas
apdaada into precipitate.wpis adsaas
apdaknown
sas
apdaada
w .
w p. p process of conversion
w .
w p. w .
w p. w . as …………..
w .
w p. w
ww ww ww ww ww ww
(a) peptisation (b) dispersion (c) coagulation (d) decomposition
tet tet ni.entet t t t t
22. sWhich
a l a il.ani.enof the following aisl ail.ani.ensize
the of the colloidala l a il.aparticle? a l a il.ani.ene a l a il.ani.ene
ww (a) 100 μm diameter ww – 1000 μm diameter ww ww 1 mμ to 1 μm diameter
(b) ww ww
(c) 1 mμt to t 100 μm diameter t t t t
(d) 1 μm to 1 μm diameter
t t t t
n
il.ai e
. ne il.ani.ene il.ani.ene il.ani.ene il.ani.ene
a23.asa sa W3O5 sol is …………. s
apdaada adsa adsa
w.wp. pdadThe shape of tungstic apdaadacid
w.wp. w.wp. w.wp.apda w .wp.apda w
ww ww ww ww ww ww
(a) spherical (b) disc (c) plate like (d) rod like
24. Which tet of the following.ncolloid
t t has spherical shape? t t etet etet
i.ani.enone iai.ene i.ani.ene ail.ani.n ail.ani.n
Padasalai.Net
lal lal lal l l
adsaas adsaas adsaas s
aa as s
ada as
a d
a
w.wp.p (a) AS2S3
a d
a a d
a
w.wp.p (b) Fe(OH)3 ww.wp.p (c) W3O5 w pdaddust
ww ww w ww ww ww
25. Tyndall effect is possible in colloid due to ……………
s(a) ail.ani. lail.anadsorption
i. il.ani.scattering of lightal(d)
saasla(c)
i.ani. i.ani.
sasal reflection of lightsaaslal
apdaad aasl absorption of light saas(b)
ad ad
of light
ad ad
w.wp.26. w .wp.apda w .wp.apda w .wp.apda w.wp.apda w
w w The migrationw
w of sol particles under w w
w the influence of electric
w field is called ……………
w w ww
(a) electro
tet osmosis (b) electro dialysis (c) electrophoresis (d) dialysistet
i.ani.en i .
a ni entet
. i .
a ni entet
. il.ani.en
t t
il.ani.ene
as movement of dispersion
27.adsThe adsas medium under as influence of electric
adsthe adsaspotential is called adsas
………….
ww ww ww ww ww ww
(a) Electrophoresis (b) Cataphoresis (c) Electro osmosis (d) Electro dialysis
28. Which etet et used to identify
i.entnot .entettypes of emulsion? etet t t
il.ani.ene
ail.ani.none of the following
ala ail.anis
ala ail.anithe a l a ail.ani.n a l a a l a
. p.apdaadsas . p.apdaadsas .wp.apda
adsa s
.wp.a(d)
asa s asa
pdadTollen’s test w.wp.apdad
s
ww (a) dye test ww
(b)w viscosity test (c)
w conductivity test w w
ww w ww ww ww ww
29. Which one of the following is used in the purification of drinking water?
t t t t entet etet etet
(a)
a l il.ani.ene sol protected by
asilver a l il.ani.ene
agelatin (b) a l ail.ani.of
milk magnesia a lail.ani.n a l ail.ani.n
s
ada s s
ada s s
ada s s
ada s s
ada s
w.wp.apda w .wp.apda 3+ w .wp.apda w .wp.apda w.wp.apda w
ww (c) Alum containing ww Al ww (d) Argyrol ww ww ww
30. Whicheone
tet of the following isetused
et in tanning of leather?
etet t t
l a i
l.ani.n l a i
l .ani.ente l a i
l .ani.ente
saas chromium salt dadsaas a a a
daadsas (c) Argyrol .p.apdaadsas (d) Fe (OH)3 .p.apdaadsas
.
w p.apdaad(a) .
wp.apa (b) colloidal
.
w pap
. Au
w w
w w w w w w
ww ww ww ww ww ww
18
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
.ni.ene t t .ni.ene t t .ni.ene t t

ene honey? t t t t
31. Which
aslailais used to distinguish lail.ani.
aslailaNatural honey andasartificial a l a il.ani.ene
adsa adsa asa asa asa s
w .wp.apda (a) AmmoniacalwAgNO
.wp.apda w .
w p.apdad w .
w p.apdad w .
w p.apdad w
ww ww 3 (b) Fehling’s
ww solution (c)
wwArsenic suiphide solww (d) gelatin ww
32. Gold number gives ………………..
ad(a)
sa the amount of gold adapresent in the colloid
s s
ada s
ada s
ada
ww ww ww
(b) the amount of gold required to break the colloid ww ww ww
(c) the t t
amount of gold required t t to protect the colloid t t .ani.ente
t
.ani.ente
t
l ai.ni.ene
l a i.ni.ene
l a l a i.ni.ene
l a la l ail l a i
l
saas a
daadsas
a
daadsas sas sas
.
w p.apdaad(d) the measure of
.
w p.approtective power of.wa
p.aplyophillic colloid .wpapdaada
. .
w p.apdaada
w w w w w w
ww ww ww ww ww ww
t t t
ni.enteHYDROXY t t t t t t
a l a il.ani.ene a l ail.a
11. COMPOUNDS
a l a il.ani.ene AND ETHERSa l a il.ani.ene a l a il.ani.ene
ww ww ww ww ww ww
1. An alcohol (x) gives blue colour in victormayer’s test and 3.7g of X when treated with
t
te t
nte of hydrogen at a273 t t te will be the t t t
metallic
a l ail.ani.ensodium liberates 560
a l a il.ani.emL a l il.ani.enKeand 1 atm pressure
a l a il.ani.en
what
a l a il.ani.ene
adas s daada s s s s s s s s
.wp.apdapossible structurew.of
p.apX?
w adaada
p.p CH CH
.(OH) daada
.wp.apb) .
aa
p.apdad
ww
w
ww a) CHw ww w
3 CH 2 3 ww
w CH 3 – CH (OH)
ww –w w
CH 3 ww
w
c) CH3 – C (OH) – (CH3) 2 d) CH3- CH2 –CH (OH) – CH2 – CH3

etet etet .ani.ente
t entet etet
ail.ani.nof the following ail.ani.n ail.ani.bromide ail.ani.n
Padasalai.Net
2. s asl
Which s asl
compounds on reactions asl ailwith methyl magnesium s asl will gives asl
ada ada ada ada ada
ww tertiary alcohol. ww a) benzaldehyde b) ww
propanoic acid c) methyl ww propanoate d) acetaldehyde ww ww
t t t t t
l.ani.ente l a i
l .ani.ente
adsaas
apda3.
sas
apdaada
sas
apdaada
sas
apdaada
sas
apdaada
w .
wp. w .
w p. w .
w p. w .
w p. w.wp. w
ww ww ww ww ww ww
t t t t t t t t t t
ww ww ww ww ww ww
t t t t t t t t t t
ww ww ww ww ww ww

ada ada ada ada ada
ww ww ww ww ww ww
t t t t t
l a i
l.ani.ente l a i
l .ani.ente l a i
l .ani.ente
sas sas sas sas sas
.
w p.apdaada .
wp.apdaada .
w papdaada
. .
w p.apdaada .
w p.apdaada
w w w w w w
ww ww ww ww ww ww
19
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
t t
e .ni.ene t t .ani.ene t t t t t t
4. In il.ani.enreaction
aslathe sequence,
aslaila. A and X respectively
aslailare a l a il.ani.ene a l a il.ani.ene
adsa asa adsa asa s adsa s
w .wp.apda a) Chloroethane
w .apdad
.wpand w .wp.apda w .
ww ww NaOH ww b) ethanol
ww and H2SO4 ww ww
c) 2 – chloroethan -1-ol and NaHCO3 d) ethanol and H2O
5.
adaWhich one of the a
s following
s
ada is the strongest adacid
s
a s
ada s
ada
ww ww
a) 2 - nitrophenol ww
b) 4 – chlorophenol ww
c) 4 – nitrophenol ww
d) 3 – nitrophenol ww
6. t .entet
oni.nitreatment with Con H .entet2 4, predominately ntet t
l a i
l .ani.ente l a l a l ail.aniSO l ail.ani.egives l a i
l .ani.ente
sas sas sas sas sas
.
w p.apdaada .
w p.apdaada .
. .
w p.apdaada
w w w w w w
ww ww ww ww ww ww
t t t t t t t t t t
ww ww ww ww ww ww
t t t t t t t t t t
ww ww ww ww ww ww
7. Carbolic acid is
etet
a) iPhenol b) Picri et
etcacid d) benzoic etetacid d) phenylacetic etet acid etet
al.ani.n ail.ani.n ail.ani.n ail.ani.n ail.ani.n
Padasalai.Net
ada aa ada ada ada
w.wp.apda8. Which one of the w .wp.apdad
following will reactw .wp.apdaphenol to give salicyladehyde
with w .wp.apda after .wp.apda
hydrolysis.
w w
ww ww ww ww ww ww
a) Dichlo methane b) trichloroethane c) trichloro methane d) CO2
t t t t t
l.ani.ente l a i
l .ani.ente
as ) - C - CH(OH) CH
9.s(CH sas X (major sas
product) sas sas
.
wp.apdaada 3 3 .
w p.apdaada3 .
w p.apdaada .
w w w w w w
ww a) (CH ) CCH ww = CH wwb) (CH ) C = C (CH w) w ww ww
3 3 2 3 2 3 2
c) iCH t t t t) –t CH2 – CH2 - CH3 .ni.entet t t

l.ani.en2te= C(CH3 )CH2 – CH 2.n - CH
ilai.ene 3
d) CH2 = C (CH il.ani.e3ne ia il.ani.ene
d a
d a
sasla
d a
d a
sasl a
d a
d a
sasla
d a
d saaslal a
adsas
l a
aa
w.wp.p 10. The correct w IUPACaa
w.wp.p name of the compound,
aa
w.wp.p
aa
w.wp.p w .wp.apda w
ww w ww ww ww ww
a) 4 – chloro – 2,3 – dimethyl pentan – 1-ol
b)
l a ni.ente–t dimethyl – 4- chloropentan
il.a
2,3 l a
t t
il.ani.ene -1-ol la
t t
il.ani.ene l a
t t
il.ani.ene l a
t t
il.ani.ene
a
adsa s a
adsas a
adsa s a
adsa s a
adsa s
ww c) 2,3,4 – trimethylww – 4- chlorobutan ww -1-ol ww ww ww
d) 4 –t chloro
t – 2,3,4 – trimethyl
t t
pentan – 1-ol
ee ee etet etet etet
ada Assertion : Phenol
11. adamore acidic than ethanol
is ada Reason: Phenoxide ada ion is resonanceadstabilized
ada
w.wp.apda w .wp.apda w .wp.apda w .wp.apda w.wp.pa w
ww ww ww ww ww ww
a) if both assertion and reason are true and reason is the correct explanation of assertion.
b) if both t t tet true but reason.nisi.ennot
t t t t of assertion. i.ani.entet
lal i.ani.eneassertion and reason
la l i.ani.enare lal ia e the correct explanation
lal i.ani.ene lal
a daadsaas a d
aadsaas a d
aadsaas a daadsaas a daadsaas
p
w.wp. c) assertion is true p p
p. reason is false w.wp. d) both assertionwand
but
w.w p
.wp. reason are false. w.wp. p w
ww ww ww ww ww ww
20
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
t t
ni.enereaction t t t t t t t t
lail.athe
12.asIn a l a il.ani.ene a l a il.ani.ene a l a il.ani.ene a l a il.ani.ene
adsa adsa s adsa s adsa s adsa s
w .wp.apdaThe ‘Z’ is w .wp.apda w .wp.apda w .wp.apda w .wp.apda w
ww ww ww ww ww ww
a) ethane b) ethoxyethane c) ethylbisulphite d) ethanol
13.
ada The reaction Canabe
s adclassified
s
a as s
ada s
ada s
ada
ww ww ww ww ww ww
t
a) idehydration t b) Williams on t t
alcoholsynthesis t t
l a l.ni.ente
a l a i
l.ani.ente i.ni.ene
l a la l ail.ani.ente l a i
l .ani.ente
sas saas adsaas sas sas
.
w p.apdaada c) Williamson ether
.
w p.apdaadsynthesis .wp.apda
d)wdehydrogenation .
w apdaada
of alcohol
p. .
w p.apdaada
w w w w w
ww ww ww ww ww ww
14. Isoprophylbenzene on air oxidation in the presence of dilute acid gives
a) a ntetCOOH
.ani6.eH
ilC a
tet
il.ani.enb) C H COCH a
t t t t
il.ani.ene c) C6 H5 COCa6laHil.an5i.ene d) C H a- i.ente
il.anOH
t
a l 5 a l 6 5 3 a l 6 a l
5
ww 15. Assertion :wPhenol w is more reactive wwthan benzene towards ww electrophilic substitutionww reaction ww
Reason : tInt the case of phenol, tthe
t intermediate arenium
t t
ion is more stabilized
t t
by t t
adsa s
resonance. adsa s adsas adsa s adsa s
ww ww ww ww ww ww
tet assertion and reason
b)i.aifni.eboth etet are true but reason eteist not the correct iexplanation etet of assertion. etet
al n ail.ani.n ail.ani.n al.ani.n ail.ani.n
Padasalai.Net
ada ada ada ada ada
w.wp.apda c) assertion iswtrue .wp.apdabut reason is false w .wp.apda d) both .wp.apda and reason arewfalse.
assertion
w .wp.apda w
ww ww ww ww ww ww
16. HO CH2 CH2 – OH on heating with periodic acid gives
entet
.ani. tet
.ani.enb) et
i.entmethanol
.anc) .ani.entet .ani.ente
t
lailmethanoic
saasa) acid sasl a i
l Glyoxal sasl a i
l sasl ail
d) CO 2 sasl a i
l
.
wp.apdaad .
w p.apdaada .
w p.apdaada .
w w w w w w
ww ww following compound
17. Which of the wwcan be used as artireeze ww in automobile rediators? ww ww
a) methanol
tet b) ethanol c) Neopentyl alcohol d) ethan -1, 2-diol
i.ani.en i .
a ni entet
. i .
a ni entet
. i .
a ni entet
. t t
il.ani.ene
a la l a l a l a la l a l a l a l a
adsasThe reactions is an
18. dsas
aexample of adsas adsas adsas
ww ww ww ww ww ww
a) Wurtz reaction b) cyclic reaction
t t reaction d) Kolbe t t t t t t t t
a l il.ani.ene
c) Williamson
a a l a il.ani.enereactions a la il.ani.ene a l a il.ani.ene a l a il.ani.ene
adsa s asas s s daadsa s asa s
.wp.apda19. One mole of an .apdad compound (A)
.wporganic apdaadathe formula C H
.wp.with .wp8.apO reacts completely .apdad
.wpwith
w w w w w w w3w w w w
w w w w w ww
two moles of HI to form X and Y. When Y is boiled with aqueous alkali it forms Z. Z answers the
n.entet
lail.ai test. The compoundlail.ai (A) is n.entet l
etet
ail.ani.n l
etet
ail.ani.n l
etet
ail.ani.n
iodoform
asaas asaas s
ada as s
ada as s
ada as
d d
ww a) propan –ww
2-ol ww -1-ol
b) propan wwethane
c) ethoxy d) methoxy ww ehane ww
20. Among
etet the following ethers
etewhich
t one will produce
etet methyl alcohol on e
treatment
tet with hot t
l .ani.ente
s
ada as s as s as s as sas
adaHI? adaada adaada adaada apdaada
w p. w
w w w w ww ww
21
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
enet t .ni.ene t t e t t t t t t
lail.ani.
21.asWilliamson synthesis aof ipreparing i.ni.enis
dimethyl aether a / an / il.ani.ene il.ani.ene
adsa adsaslala slala asa a
adsa sl a a
adsa sl a
w .wp.apda a) SN1 reactions
w .wp.apda w .
ww ww wwb) SN2 reaction ww ww ww
c) electrophilic addition d) electrophilic substitution
22.
ada On reacting withaneutral
s ada ferric chloride,adphenol
s s
ada gives s
ada s
ada
w .wp.apda w .wp.pda w.wp.pa w .wp.apda w .wp.apda w
ww a) red colour ww b) violet colour ww c) dark green colour ww ww
d) no colouration. ww
ADDITIONAL t t t t t
l a i
l .ani.ente QUESTIONS:lail.ani.ente l ail.ani.ente l ail.ani.ente l a i
l .ani.ente
p. dsaas
apdaaWhich
1. one of the following
p.
sas
p .
sas
apdaada is named as .sorbital?
apdaada p.
sas
apdaada p.
sas
apdaada
w .
w w .
w w w w.w w .
w w
ww ww ww ww ww ww
t t t t t t t t t t
ww ww ww ww ww ww
t t t t t t t t t t
ww ww ww ww ww ww
n.entet n.entet n.entet etet

ail.ani.n
etet
ail.ani.n
Padasalai.Net
i.ai lail.ai lail.ai
d saaslal one of the following
2. aWhich asaas is a primary alcohol?
d asaas d s
ada asl s
ada asl
ww ww ww ww ww ww
t t t t t
l.ani.ente l a i
l .ani.ente
sas sas sas sas sas
.
wp.apdaada .
w p.apdaada .
w p.apdaada .
w w w w w w
ww ww ww ww ww ww
t t t t t t t t t t
ww ww ww ww ww ww
3. Which of the following is a dihydric alcohol?
t t t t t t t t t t
ala i.ni.ene la i.ni.ene lalai.ni.ene i.ni.ene i.ni.ene
(a)alEthenol
dadsas
alaEthanol
(b)
dadsas
] (c) aEthane
dadsas
– 1, 2 – dioldadsaaslala (d) Propanda–dsaa2sla–laol
aa aa aa aa aa
w w.wp.p w w.wp.p w w.wp.p w w.wp.p ww.wp.p w
w 4. Which one ofwthe following is an example
w w alcohol?
of secondary (2°) w ww
(a) Propan
entet – 2 – ol (b) Phenyl t methanol (c) Ethenol
t (d) 2 – methyl t – propan – 2 – oln.entet
i .ani. i.ani.ente i .ani.ente i .ani.ente .i
a
dsaasl a l
adsaasla l
ads
a asl a l
adsaasla l
adsaaslaila
adaWhich acts as an additive
5. ada to petrol? ada ada ada
ww ww ww ww ww ww
(a) Glycerol (b) Ethanol (c) Phenol (d) Methanol
t t t t t
l a i
l.ani.ente l a i
l .ani.ente l a i
l .ani.ente
sas sas sas sas sas
.
w p.apdaada .
wp.apdaada .
w papdaada
. .
w p.apdaada .
w p.apdaada
w w w w w w
ww ww ww ww ww ww
22
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
t t t t t t t t t t
6. The il.ani.ene name of
aslaIUPAC a l a il.ani.ene a l a il.ani.ene a l a il.ani.ene a l a il.ani.ene
adsa adsa s adsa s adsa s adsa s
ww ww ww ww ww ww

ada ada ada ada ada
ww ww
(a) 1 – methyl – 2 – propanol ww(b) 2 – methyl – p ropan – 2 – ol ww ww ww
t t alcohol
(c) Tertibutyl .ani.ente
t (d) 2 – propanol .ani.ente
t
.ani.ente
t
.ani.ente
t
li.ni.ene
a l a l a i
l l ail l ail l a i
l
dsaas
apdaaThe
a
daadsas= CH – CH OH is.p…………
apCH
sas
apdaada
sas
apdaada
sas
apdaada
w .
w p7.
. TUPAC namew of
.
w p. 2 2 w w . w.wp. w .
w p. w
ww ww ww ww ww ww
(a) Allyl alcohol (b) Propenc – 2 – ol (c) Prop – 2 – en – 1 – oI (d) Isopropyl alcohol
ntet
il.ani.eone
tet
ni.ennamed
il.ais .ani.ente
ilreagent?
t t t
il.ani.ene
t t
il.ani.ene
8. Whicha l a of the following a l a as Baeyer’s a l a a l a a l a
ww (a) acidified Kw2Cr w 2O7 (b) acidified w w
KMnO 4 (c) Cold dilutew w
alkaline KMnO4 w
(d)wLiAlH 4 ww
9. Which one of the following is called Lucas reagent? t t
i .ani entet
. i .
ani entet
. il.ani.ene
t t
il.ani.ene
t t
il.ani.ene
asl a l a sl a l asl a a sl a a sl a
adsa Conc. HCl + Anhydrous asa adsaConc. HCl + Anhydrous asa adsa
w.w p.apda(a) w.wp.apdad ZnCl2 p.apda(b)
w.w p.apdad A1CI3 w.w w .wp.apda w
ww ww ww ww ww ww
(c) LiAIH4 + H2O (d) Cold dilute alkaline KMnO4
10. Which tet
ecolour etet alcohol in Victor
is given by secondary tet
eMeyer’s test? etet etet
Padasalai.Net
l l l l l
dadsaasa d adsaasa s
ada as a s
ada as s
ada as
a a
w.wp.p (a) Red (b)
w
ap a
.wp.Green (c)
w .wp.apda
Blue (d) Yellow w .wp.apda w .wp.apda w
ww ww ww ww ww ww
11. Which mechanism is followed in the conversion of ethanol to bromoethane by HBr?
n.entet
ail.a1i mechanism il.ai 2 mechanism n.entet i.ai n.entet
il.ai E mechanism alail.ai n.entet n.entet
saaslSN
a(a) aslaSN
s(b)
a saaslal (c) E1 mechanism saasla(d) 2 ss
.
wp. d
apa d
.
w p. d
apaad
.
w p. d
apa a
d
.
w p. d
apa a
d
.
w p.apdaada
w ww following is the correct w ww wwthe w
ww 12. Which one ofwthe ww order of relativewreactivities of alcoholswin ww
dehydration entet
reaction? (a) 1°e<te2° t < 3° (b) 2° < 1°n.e<nte3°t (c) 3° < 2° < 1° n.en(d) tet 3° < 1° < 2° t t
a la i
l.ani.
a l a i
l .
a ni . n
a la i
l .
a i
a l a i
l .
a i
a l a il.ani.ene
adsas asas asas adsaspresence of DMSO? adsas
ww .p13.
.apdaWhich p.apdadto convert alcohol
reaction is .used
ww pdadketone / aldehyde.pin
.p.ato
ww .apdathe ww .p.apda ww w
ww ww ww ww ww ww
(a) Lucas test (b) Swern oxidation (c) Biological oxidation (d) Kolbe’s reaction
14. What et name of the reaction
i.entthe entet between ethanol entet entet t t
il.ani.ene
lail.anis
a s a aslail.ani.
a alail.ani.and ethanoic acid?lail.ani.
s a a s a a sl a
adsa adsa adsa asa asa
w.wp.apda(a) Esterificationw.wp.apda (b) Saponification
w pdadHydroxylation w.wp.apdad
.wp.apda(c) Ethenfication w.wp.a(d) w
ww ww ww ww ww ww
15. What is the product formed when ethylene glycol is heated at 773 K?
aila .ni.ente il.ani.ene
aEthene ail.ani.n ail.ani.n ail.ani.n
(a)alEthanal
dadsas
(b)
s
ada asl (c)s
ada sl
Ethane
a (d) s
ada sl
Oxirane
a s
ada asl
w.wp.apa w .wp.apda w .wp.apda w .wp.apda w.wp.apda w
ww 16. Which one ofwthe
w following is formed wwwhen ethane – 1, 2 w – wdiol is treated with Conc. ww H2 SO4? ww
(a) 1, 4en–tedioxane
t (b) Ethanal
entet (c) Ethanoic
entet acid (d) Etheneentet t
i.ani. i.ani. i.ani. i.ani. i .ani.ente
aad a
d aadad aadad aad a
d apdaada
w.wp.p w.wp.p w.wp.p w.wp.p w .
w p. w
ww ww ww ww ww ww
23
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
t t
ne of the following t t
e t t t t t t
17. Which
a l a il.ani.eone a l a ni.enformed
il.ais when ethylene
a l a il.ani.eneglycol is treatedawith l a
e
il.ani.enperiodic acid? aslail.ani.ene
adsa s adsa s adsa s asa s asa
w .wp.apda(a) Methanal w.wp.apda (b) Methanol w.wp.apda(c) Ethanol w pdad
.wp.a(d) w .
w p.apdad w
ww ww ww ww Ethanal ww ww
18. Identify the product formed when glycerol is treated with nitric acid and conc. H 2SO4?
a(a)
da Nitroglycerine p.apdaad(b)
s a Glyceryl triacetate
s s
ada (c) Prop – 2 – aenalada (d) Glyceric acidadaada
s s
w .wp.apda w .w w.wp.apda w .wp.pda w.wp.p w
ww ww
19. Oxidation of glycerol with dil.HNO3 gives ……… ww ww ww ww
(a) Meso t
t oxalic acid tet Glyceric acid and.ntartronic t t t
li.ni.ene
a l a l a i
l.ani.en(b) l aila i.ente acid
l .ani.ente
p. dsaasGlycerose
apdaa(c) p.
sas
apdaada (d) Glyceraldehyde
p.
sas
apdaada and dihydroxy paacetone
. p
a
daadsas p.
sas
apdaada
w .
w w .
w w .
w w.w w .
w w
ww ww ww ww ww ww
20. Which one of the following is the correct decreasing order of acidity in alcohol?
etet
i.n i.ani.n etet t
i.ente3° alcohol > 2° alcohol> t t t t
il.ani.ene 1° alcohol alail.ani.ene
(a) ail.analcohol
sasl1° > 2° alcohol
sasla>l 3° alcohol a l a il.an(b) a l a
ww (c) 2° alcohol>ww ww
1° alcohol > 3° alcohol ww
(d) 3° alcohol > 1° alcohol > 2°walcohol w ww
21. The other
t t
name of 1 , 2, 3 – trihydroxy
t t
benzene is called
t t
………. t t t t
s
dsa Pholoroglucinolp.apdaadsa
a(a) s s s
(b) Quinol apdaadsa (c) Pyrogallol apdaadsa (d) Hydroxy quinol adsa s
w.wp.apda w .w w .wp. w.wp. w .wp.apda w
ww ww ww ww ww ww
22. The IUPAC name of Catechol is known as ………..
(a) 1 i,.an3i.en–tetdihydroxy benzene t t
i.ani.ene et
(b) 1, i2.ani–.entdihydroxy benzenei.ani.entet etet
ail.ani.n
Padasalai.Net
lal lal lal lal l
dadsaas d adsaas d adsaas d adsaas s
ada as
a a
w.wp.p (c) 1, 4 – dihydroxy
ap a
w.wp.benzene
a a a
w.wp.p (d) 1, 3, 5 – trihydroxy
a
w.wp.p benzene w .wp.apda w
ww ww ww ww ww ww
23. The reaction of chiorobenzene with NaOH is known as ………..
(a) ail.ani.
saaslKolbe’s reaction s(b) ail.ani. i.ani.
saaslal
i.ani. (d) Cumene synthesis
saaslal
i.ani.
saaslal
a ad aasl Riemcr – Ticmann reaction
ad ad
(c) Dow’s process
adaad
.apdad
w.wp24. w .wp.apda w .wp.apda w .wp.apda w.wp.p w
w w What will be w w w
the product formed when w
w phenol is treated with
w zinc dust? w w ww
(a) Cumene
tet (b) Toluene (c) Ethyl benzene (d) Benzene
i.ani.en i .
a ni entet
. i .
a ni entet
. t t
il.ani.ene
t t
il.ani.ene
dsas acetylation and
25.aThe adsas
benzoylation of phenol adsascalled ……….
are adsas adsas
w .wp.apda w .wp.apda w .wp.apda w.wp.apda w .wp.apda w
ww ww ww ww ww ww
(a) Dow’s process (b) Schotten – Baumann reaction
(c) Reimer etet etet t t
il.ani.ene
t t
il.ani.ene
t t
il.ani.ene
a slail.ani.n – Tiemann reaction
a ail.ani.n
asl a
(d) Williamson
a sla ether synthesis
a sl a a sl a
adsa asa adsa daadsa adsa
w .apdaWhich
.wp26. one of the
w p.apdad
.w
following is formed .wp.apdaphenol reacts with
when
w w .wpa.apmixture of Conc. HNO
w .wp.ap3daand w
ww ww ww ww ww ww
Conc.H2SO4? (a) Ortho nitro phenol (b) Para nitro phenol
etet t t t t
il.ani2.en–e dinitro phenolalail.ani.ene (d) 2, 4 , 6 –atrinitro etet etet
s asl ail.ani.n (c)
s asla1, s s s slail.ani.n phenol s asl ail.ani.n
ada ada ada ada ada
ww 27. The conversion wwreaction of phenol of wwsalicylic acid is known wwas ww ww
(a) Schottan
etet – Baumann reaction
etet (b) Riemer
etet– Ticmann reactionetet t
l .ani.ente
s as
da Kolbe’s Schmittpreaction s as s as s as sas
adaa(c) adaada adaWilliamson’s synthesis
ada(d) adaada apdaada
w w.wp.p w w.w.p w w.wp.p w w.wp.p w .
w p. w
w w w w ww ww
24
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
.ni.ene t t t t
ene of phenol with chloroform
.ni.ene .ni.ene t t t t t t
28. What lail.ani.
aslailais the name of theasreaction aslaila and aqueous
aslaila alkali? a l a il.ani.ene
w .wp.apda(a) Kolbe’s reaction
w .wp.apda w .wp.apda(b) Cumene synthesis
ww ww ww ww ww ww
(c) Rlemer – Tiemann reaction (d) Schottan – Baumann reaction
29.aWhich
s
da one of the following
ada is formed when
s phenol
s
ada is treated with achloroform
s
da and sodium s
ada
ww hydroxide. ww ww
(a) Chiorobenzene ww (b) Salicylaldehydeww ww
t (c) Salicylic t t t t
l a i
l .ani.ente l a i
l.ani.ente acid l ail.ani.ente (d) Aniline lail.ani.ente l a i
l .ani.ente
p. dsaas
apdaaWhich
30. one of the following
p.
sas
apdaada is formed when p.
adsaas
apdaPhenol reacts with benzene
p.
sas
apdaada diazonium chloride?
p.
sas
apdaada
w .
w w .
w w .
w w .
w w .
w w
ww ww ww ww ww ww
(a) P – hyclroxy diazo phenol (b) P – hydroxy azo benzene
(c) O a ntet
il.a–ni.ehydroxy benzene a
t t
il.ani.ene a il.an(d)
t
i.enteO – hydroxy azolabenzene t t
il.ani.ene a
t t
il.ani.ene
a l a l a l a a l
ww 31. Bakelite is formed ww when phenol reacts ww with ……….. ww ww ww
(a) Methanol
t t
(b) Methanal t t (c)t Ethanal
t (d) Ethanol
t t t t
n
il.ai e
. ne n
il.ai e
. n e n
il.ai e
dsa
32.aWhich adsa is an example afor
one of the following adsmixed
a ether? adsa adsa
w.wp.apda w .wp.apda w.wp.pda w.wp.apda w .wp.apda w
ww ww ww ww ww ww
(a) Methoxy methane (b) Phenoxy benzene (c) Methoxy benzene (d) Ethoxy ethane
33. Identify tet product formed.niwhen
t t t t t
i.ente K? etet
i.ani.enthe ia .ene ethanol is treated
i.ani.enewith Conc.H 2SO4 ati.an413 ail.ani.n
Padasalai.Net
lal l al l al l al l
dadsaas s
ada as s
ada as s
ada as s
ada as
a a
w.wp.p (a) Ethene w .wp.apda (b) Ethane w .wp.apda(c) 2 – butanol w.wp.apda (d) Diethyl .wp.apda
ether
w w
ww ww ww ww ww ww
34. The mechanism involved in Williamson’s synthesis is …………
entet
i.ani. entet .ani.ente
t entet .ani.ente
t
saaslEa1l
(a) (b) E2 saaslail.ani. (c) SN2 sasl ail lail.a1ni.
(d)saasSN sasl a i
l
.
wp.apdaad .
w p.ap .
w p. daad
apdaad .
w p.apdaada .
w p.apdaada
w w Brw2 in acetic acid in the w ww major w
ww 35. Anisole undergoes
ww bromination with
ww wwabsence of catalyst,wthe ww
product tformed
et
is (a) O – bromoan isole tet (b) P – bromoan isole
en entet en tet
il.ani.en
t t
il.ani.ene
aslail.ani. as
i
lal .
a ni .
aslail.ani. a
as l a a l a
adaad
sa adaad
sa adaad
(c) Benzyl bromide sa (d)adsBromo benzene p.apdaadsas
w.wp.p w.wp.p w.wp.p w.wp.apda w.w w
w w w w w w ww ww ww
36. Which one of the following is used as a surgical anesthetic agent in surgery?
(a) Ethanoletet .ani.ente
(b) Ethoxyailethane t (c) Methoxyailethane.ani.ente
t (d) Methoxy t t
il.ani.ene propane
t t
il.ani.ene
a sl ail.ani.n
a asl a sl a sl a a sl a
w .apdaOxygen
.wp37. atom in .wp.apdais …………
ether
w w .wp.apda w .wp.apda w .wp.apda w
ww ww ww ww ww ww
(a) very active (b) replacable (c) comparatively inert (d) less active
ada ada ada ada ada
ww ww ww ww ww ww
t t t t t
l a i
l.ani.ente l a i
l .ani.ente l a i
l .ani.ente
sas sas sas sas sas
.
w p.apdaada .
wp.apdaada .
w papdaada
. .
w p.apdaada .
w p.apdaada
w w w w w w
ww ww ww ww ww ww
25
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
t t t t .ani.ente
t t t t t
a l a il.ani.ene a l a il.ani.ene 12. CARBONYL a l a ilCOMPOUNDS a l a il.ani.ene a l a il.ani.ene
ww ww ww ww ww ww
1. The correct structure of the product ‘A’ formed in the reaction (NEET)
ada ada ada ada ada
ww ww ww ww ww ww
t t t t t
l a i
l .ani.ente l a i
l .ani.ente
sas sas sas sas sas
.
w p.apdaada .
w p.apdaada .
. .
w p.apdaada
w w w w w w
ww ww ww ww ww ww
t t t t t t t t t t
adsas asas adsas adsas adsas
w .wp.apda2. The formation w w .apdad
of.pcyanohydrin .wp.apda is an example of
from acetone
ww ww ww ww ww ww
a) nucleophilic substitution b) electrophilic substitution
t t t t t t t
c)
l a .ani.ente
ilelectrophilic additionlail.ani.ente il.ani.ene
d) Nucleophilic
l a addition lail.ani.ente l a il.ani.ene
a
adsa s a
adsa s a
adsas a
adsa s a
adsa s
w.wp.apda3. Reaction of acetone w .wp.apdawith one of the following
w.wp.apda reagents involves w.wp.apdanucleophilic addition
w .wp.apda w
ww ww ww ww ww ww
followed by elimination of water. The reagent is
t etet etet t t etet
.ani.ente ail.ani.n ail.ani.n i.ni.ene ail.ani.n
Padasalai.Net
a l
a)
s ailGrignard reagent asl asl b) Sn / HCl alala a l
.wp.apda
s
ada
.wp.apda
s
ada
.wp.apda
s
ada dadsas
.p.apa .wp.apda
s
ada s
ww
w w
wwin presence of slightly
w
wwacidic solution w ww w ww
w
ww
w
c) hydrazine d) hydrocyanic acid
4. In the following
t t reaction, n.entet t t t
i.ani.ene i.ai i .ani.ente i .ani.ente i .ani.ente
saaslal adsaas
lal sasl a l sasl a l sasl a l
a pdaadProduct ‘X’ will not a da
give
p apdaada apdaada apdaada
w.wp. w.wp. w .
w p. w .
w p. w.wp. w
ww ww ww ww ww ww
a) Tollen’s test b) Victor meyer test c) Iodoform test d) Fehling solution test
t t t t t t t t t t
5. alail.ani.ene a l a il.ani.ene a la il.ani.ene a l a il.ani.ene a l a il.ani.ene
ada adsas adsas adsas adsas adsas
w.wp.p w .wp.apda w.wp.apda w.wp.apda w .wp.apda w
w w ww ww ww ww ww
a) Formaldelyde b)diacetoneammonia c) hexamethylenetetraamine d) oxime
t t t t t t t t t t
6. s
adsaPredict the product Zadsins
a the following series s
adsaof reactions adsa s adsa s
ww ww ww ww ww ww

ada ada ada ada ada
ww ww ww ww ww ww
t t t t t
l a i
l.ani.ente l a i
l .ani.ente l a i
l .ani.ente
sas sas sas sas sas
.
w p.apdaada .
wp.apdaada .
w papdaada
. .
w p.apdaada .
w p.apdaada
w w w w w w
ww ww ww ww ww ww
26
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
t t
.ni.ene 2,2 – dimethyl .ani.ene t t ene HVZ reaction. i.ani.enet t t t t t
7. Assertion:
aslaila aslailpropanoic ail.ani.give
acid doesaslnot aslal a l a il.ani.ene
adsa adsa asa asa adsa s
w .wp.apdaReason: 2 – 2, dimethyl
w .wp.apda propanoic acid w .
w p.apdad w .
ww ww ww does not have – - hydrogen
ww atom ww ww
ada b) if both assertion
s aand
da reason are true
s butadareason is not the correct
s ada explanation of aassertion.
s s
ada
w .wp.apda w .wp.apda w.wp.apda w .wp.apda w .wp.pda w
ww ww
c) assertion is true but reason is false ww ww ww
d) both assertion and reason are false. ww
8. Which toft the following represents

t t the correct order t acidity in the given
t of t
t compounds .ani.ente
t
i.ni.ene
lala i.ni.ene
lala i.ni.ene lala i.ni.ene lala l a i
l
a adsaas sas
apdaada
w.wp. p w.wp.p w.wp. p w.wp. p w .
w p. w
ww ww ww ww ww ww
t t t t t t t t t t
ww ww ww ww ww ww
t t t t t t t t t t
adsa
9. s adsa s adsas adsa s adsa s
ww ww ww ww ww ww
a) anilinium chloride b) O – nitro aniline
etet
c) ibenzene diazonium chloride etet etet benzoic acid i.ani.entet
d) m –i.annitro etet
al.ani.n ail.ani.n al i.n ail.ani.n
Padasalai.Net
a l a l a l lal l
d s
ada s d s
ada s d s
ada s d adsaas s
ada as
a a
w.wp.p 10 . Ethanoic acid
a a
w.wp.p 2 – bromoethanoic
a a
w.wp.pacid. This reaction
a
w.wp.p
a
w .wp.apda w
ww ww ww ww is called ww ww
a) Finkelstein
t
reaction t t
b) Haloform reaction t t
l.ani.ente l a i
l .ani.ente
sas adsaas reaction adaadsaas d) none of these sas sas
.
wp.apdaada c) Hell – Volhard .
w p.a–pdaZelinsky .
w p.p .
w w w w w w
ww 11 ww ww ww . ww ww
t t t t t t t t t t
adsas adsas adsas daadsas adsas
w .wp.apda a) acetylchloride w .wp.apda b) chloro aceticwacid .wp.apda c) α- chlorocyano w.wp.ap
ethanoic .wp.apdaof these
acid d) none
w w
ww ww ww ww ww ww
12. Which one of the following reduces tollens reagent a) formic acid b) acetic acid
t t t t t t t t t t
a l a il.ani.ene a l a il.ani.ene a la il.ani.enec) benzophenone a l a il.ani.ene d) none of these a l a il.ani.ene
ww 13. ww ww ww ww ww

ada ada ada ada ada
ww ww ww ww ww ww
t t t t t
l a i
l.ani.ente l a i
l .ani.ente l a i
l .ani.ente
sas sas sas sas sas
.
w p.apdaada .
wp.apdaada .
w papdaada
. .
w p.apdaada .
w p.apdaada
w w w w w w
ww ww ww ww ww ww
27
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
t t
ne t t t t t t t t
14.asThe
l a il.ani.eIUPAC name of aslail.ani.ene a sl a il.ani.ene a sl a il.ani.ene a sl a il.ani.ene
adsa adsa asa adsa adsa
w .wp.apdaa) but – 3- enoicacid w .wp.apda w .
ww ww b) butw–w1- ene-4-oicacid ww ww ww
c) but – 2- ene-1-oic acid d) but -3-ene-1-oicacid
15.s
ada s
ada s
ada s
ada s
ada
ww ww ww ww ww ww
t t t t t
l a i
l .ani.ente l a i
l .ani.ente
sas sas sas sas sas
.
w p.apdaada .
w p.apdaada .
. .
w p.apdaada
w w w w w w
ww ww ww ww ww ww
t t t t t t t t t t
ww ww ww ww ww ww
t t t t t t t t t t
ww ww ww ww ww ww

Padasalai.Net
ada ada ada ada ada
w.wp.apda16. w .wp.apda w .wp.apda w .wp.apda w .wp.apda w
ww ww ww ww ww ww
t t t t t
l.ani.ente l a i
l .ani.ente
sas sas sas sas sas
.
wp.apdaada .
w p.apdaada .
w p.apdaada .
w w w w w w
ww ww ww ww ww ww
t t t t t t t t t t
ww ww ww ww ww ww
t t t t t t t t t t
ww ww ww ww ww ww
17. Assertion : p – N, N – dimethyl aminobenzaldehyde undergoes benzoin condensation
n.entet
lail.ai : The aldehydic (-CHO) n.entet
lail.ai group is meta directing
lail.ai l
etet
ail.ani.n n.entet l
etet
ail.ani.n
Reason
asaas asaas asaas s
ada as s
ada as
d d d
a) if both assertion ww and reason is the correct
ww ww
b) if both
eteassertion
t and reasonetare
et true but reason isenot
tet the correct explanation
etet of assertion. t
l a i
l.ani.n l a i
l .ani.n l a i
l .ani.ente
as
adsaassertion dsaas as
adsaboth sas are false. sas
. p.apdac) p.apdaareason
is true .but is false .p.apdad) assertion and
. p. aada
apdreason . p.apdaada
ww ww ww ww ww ww
28
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
enet t .ni.ene t t .ni.ene t t

.ni.ene reaction t t t t
lail.ani. one of the following
18.asWhich aslaila reaction is an example
aslaila of disproporationation
aslaila a l a il.ani.ene
adsa adsa asa asa asa s
w .wp.apda a) Aldol condensation
w .wp.apda w .
w p.apdad w .
w p.apdad w .
w p.apdad w
ww ww b) cannizaro
ww reaction c) Benzoin
wwcondensation d) none
ww of these ww
19. Which one of the following undergoes reaction with 50% sodium hydroxide solution to
give
ada the corresponding
s adalcohol
sa and acid adaada a) Phenylmethanal
s s
ada b) ethanal s
ada
ww ww ww ww
c) ethanol
w
d)wmethanol ww
20. The t t
reagent used to distinguisht t between acetaldehyde
t t and benzaldehyde t t is .ani.ente
t
li.ni.ene
a l a i.ni.ene
l a l a i.ni.ene l a la i.ni.ene l a l a l a i
l
sas dsaasFehling’s solution dsaa2,4
s adsaas sas
.
w p.apdaada a) Tollens reagent
.
w p.apdaab) .
w p.apdaac) – dinitrophenyl
.wpapdahydrazine
. d) .
w .apdaada
semicarbazide
p
w w w w w w
ww ww ww ww ww ww
21. Phenyl methanal is reacted with concentrated NaOH to give two products X and Y. X
etet
i.ani.n i.ani.n etet i.ani.n etet t t
il.ani.ene
t t
il.ani.ene
reacts
saslal with metallic sodium
saslalto liberate hydrogen
saslaXl and Y are a l a a l a
ada ada ada adsas adsas
ww ww
a) sodiumbenzoate and phenol ww ww benzoate and phenyl
b) Sodium wwmethanol ww
c) phenyl
t t
methanol and sodium
t t
benzoate d)tnonet of these t t t t
n
il.ai e
. ne n
il.ai e
. n e n
il.ai e
asl a a sl a asl a asl a a sl a
adsa In which of the following
22. adsa adsa
reactions newapdcarbon – carbon bondapdis adsnot
a formed? adsa
w.wp.apda w .wp.apda w.wp. a w .wp. a w .wp.apda w
ww ww ww ww ww ww
a) Aldol condensation b) Friedel craft reaction c) Kolbe’s reaction d) Wolf kishner reduction
t “A” on reactionn.ewith
t t tet propanone and ntet in equimolari.ani.entet
i.ente
23. Ani.analkene i.ai ne O3 and Zn – H2 iO
.ani.engives i.ani.eethanol
Padasalai.Net
lal lal lal lal lal
a d
aadsaas a d
a adsaas a d
a adsaas a d
a adsaas a daadsaas
w.wp.p ratio. Addition of .wp.pto alkene “A” gives
wHCl p.p as the major product.
“B”
w.w w.wp.p The structure of .wp.p
product
w w
ww ww ww ww ww ww
“B” is
t t t t t
l.ani.ente l a i
l .ani.ente
sas sas sas sas sas
.
wp.apdaada .
w p.apdaada .
w p.apdaada .
w w w w w w
ww ww ww ww ww ww
t t t t t t t t t t
ww ww ww ww ww ww
t t t t t t t t t t
ww ww ww ww ww ww
24. Carboxylic acids have higher boiling points than aldehydes, ketones and even alcohols of
n.entet
lail.ai i.ai n.entet i.ai n.entet
etet
ail.ani.n
etet
ail.ani.n
d
comparable
asaas saaslal It is due to theira(NEET)
molecular amass.
d d saaslal s
ada asl s
ada asl
ww ww association of carboxylic
a) more extensive ww w
acid via van derwWaals force of attraction ww ww
b) formation
etet of carboxylate ion
etet t t t
l a i
l.ani.ente l a i
l .ani.ente l a i
l .ani.ente
as
adsaformation sas as dsaas sas
. p.apdac) .p.apdaada
of intramolecular H-bonding.p.apdaadsa d) formation.pof apdaaintermolecular
. apdaada
H –.pbonding
.
ww ww ww ww ww ww
29
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
t t
.ni.ene QUESTIONS:lail.ani.ene t t t t t t t t
ADDITIONAL
aslaila as a l a il.ani.ene a l a il.ani.ene a l a il.ani.ene
asa asa asa s asa s adsa s
w .apdad
.wp1. w .
w p.apdad w .
w p.apdad w pdad
.wp.a(b) w .wp.apda w
ww The IUPAC name
ww of Acrolein is (a) Prop – 2 – enal
ww ww Propanal ww ww
(c) Ethenal (d) 1 – butanal
2. aThe
da conversion of pacetyl
s ada chloride to acetaldehyde
s s
ada by the action aofdaaPd/BaSO
s
da 4 is called ……………….. s
ada
w .wp.apda w .w.apda w.wp.apda w .wp.p w .wp.apda w
ww ww ww ww
(a) Perkin’s reaction (b) Stephens reaction (c) Clemmenoon reduction (d) Rosenmund reduction ww ww
t t
3. In Rosenmunds reduction, ithe et
.ni.entaction of BaSO4 is ……………. t t .ani.ente
t
.ani.ente
t
i.ni.ene
l a l a l a l a i.ni.ene
l a la l ail l a i
l
p. dsaasPromoter
apdaa(a) (b) p. p
a
daadsas poison (c) Positive
aCatalyst p.
sas
apdaada catalyst (d) Negative
p.
sas
apdaada catalyst p.
sas
apdaada
w .
w w .
w w .
w w.w w .
w w
ww ww ww ww ww ww
4. The conversion reaction of Benzene to Benzaldehyde is known as ……………..
etet etet etet etet t t
il.ani.ene
(a) ail.ani.n
saslRosenmund reduction i.ani.n
saslal lail.ani.
(b)sasStephen n reduction
aslail.ani.
n
a l a
ada ada adaad a a s
a adsas
w .wp.apda w .wp.apda w.wp.p (d) Friedel – crafts w.wp.apdad w .wp.apda w
ww wwkoch reaction
(c) Gattermann w w w
w reaction ww ww
5. The product t t formed when Benzoyl t t chloride reactsnwith t t benzene is …………. t t t t
n
il.ai e
. n e n
il.ai e
. n e il.ai e
asl a asl a asl a a sl a a sl a
dsa Benzyl benzoateapdaads(b)
apdaa(a) a Benzophenone ada(c) asa
p d Benzyl chloride a(d)
asa
pdadBenzyl alcohol
adsa
w.wp. w.wp. w.wp. w.wp. w .wp.apda w
ww ww ww ww ww ww
6. Which one of the following is used as catalyst in Friedel Crafts reaction?
(a) Anhydroust t ZnCl2 (b) Anhydrousetet CuCl2 (c) Anhydrous etet AlCl3 (d) Androus etetCaCl2 etet
i.ani.ene ail.ani.n ail.ani.n ail.ani.n ail.ani.n
Padasalai.Net
ada aa ada ada ada
w .apdaWhich
.wp7. one of the
w p.apdad
following
.w is formed .wp.apdamethanal reacts w
when
w .wp.apdaammonia?
with w .wp.apda w
ww ww ww ww ww ww
(a) Tetramethylene hexamine (b) Hexamethylene tetramine
t t t t t
(c) l ail.ani.ente
Formaldehyde ammonia l a i
l.ani.ente (d) a i
l .ani.ente
Aldimine
l l ail.ani.ente l a i
l .ani.ente
sas sas sas sas sas
.
w p.apdaada .
w ww following is used as, w w w w
ww 8. Which one ofwthe ww an urinary antiseptic? ww ww ww
(a) Urotropine
tet (b) Ureateformaldehyde (c)teFormalin (d) Aldimm
i.ani.en i .
a ni en t
. i .
a ni en t
. t t
il.ani.ene
t t
il.ani.ene
dsas
9. aWhich adsas gives an explosive
one of the reactions s
adsaRDX? (a) Nitrationadsasof phenol adsas
ww ww ww ww ww ww
(b) Nitration of glycol (c) Nitration of urotropine (d) Nitration of glycerol
t t etet is subjected to .entet etet t t
alail.ani.ene formed whenaiAcetone
10. Theaproduct
ala l.ani.n ala ail.aniClemmenson reduction
ail.ani.nis ……………..
ala a l a il.ani.ene
. p.apdaadsas . p.apdaadsas . p.apdaadsas . p.apdaadsas .wp.apda
adsa s
w w (a) Acetic acid ww
(b)w Propanoic acid w(c)wPropane
w (d) Propanal
ww w w
ww w w ww ww ww
11. The reaction of benzaldehyde with 50% NaOH is called …………..
n.entet
ail.ai lail.ai n.entet n.entet
lail.ai lail.ai n.entet etet
ail.ani.n
d saaslBenzoin
a(a) condensation
asaas
d
(b)
dasaasClaisen – schmidt reaction
asaas
d s
ada asl
ww ww
(c) Perkin’s reaction ww (d) Cannizaro w w
reaction ww ww
t t t t t
l a i
l.ani.ente l a i
l .ani.ente l a i
l .ani.ente
sas sas sas sas sas
.
w p.apdaada .
wp.apdaada .
w papdaada
. .
w p.apdaada .
w p.apdaada
w w w w w w
ww ww ww ww ww ww
30
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
t t t t t t t t t t
12. The il.ani.ene of phenyl methanal
aslareaction
.ni.ene and ethanal inlathe
aslaila
.ni.ene
as ila presence of dilute il.ani.ene is known as ……
aslaNaOH
.ni.ene
aslaila
w .wp.apda(a) Cannizaro reaction
w .wp.apda w .wp.apda(b) Aldol condensation
ww ww ww ww ww ww
(c) Claisen – schmidt condensation (d) Perkin’s reaction
13.aWhich
s
da one of the following
ada is formed when
s benzaldehyde
s
ada reactsadwith
ada alcoholic KOH? adaada
s s
w .wp.apda w .wp.apda w.wp.apda w .wp.pa w.wp.p w
ww (a) Benzyl alcoholww ww
(b) Potassium henzoate ww
(c) Benzoin ww
(d) Benzoic acid ww
14. Whati.nis et name of the reaction

i.entthe t t between Benzaldehyde
i.ni.ene
t t and acetic anhydride?
i.ni.ene
t t
i.ni.ene i .ani.ente
t
lala lala lala lala l a l
a daadsaas a daadsaas a daadsaas a daadsaas dsaas
apdaareaction
w.wp. (a) Peridn’s reaction
p w.wp. (b) Knoerenagal
p wreaction
.wp. p (c) Cannizaro
w.wp.reaction
p (d) Kolbe’s
w .
w p. w
ww ww ww ww ww ww
15. Which one of the following is the formula of Schiff’ s base’?
etet
i.ani.n etet
.ni.n .ni.n etet i.ani.n etet
i.ani.n etet
ada
(a)
saslCa6l H5 – NH NH2
ada aslaCila6H5 CH = N – C6H5saslaila(b) Perkin’s reaction
s(b)
ada ada saslal (d) Aldol condensation
saslal ada
ww 16. Which one ofwthe
w following is used as
wwa catalyst in Knoevenagal
ww reaction? ww ww
(a) Pyrimidine
t t
(b) Pyridine t t (c) PCC t t (d) CdCl2 t t t t
n
il.ai e
. ne n
il.ai e
. n e il.ani.ene .ni.ene
ia il.ani.ene
a
dsa
17.aWhich sl a asl a
adsa is used to testaketones?
one of the following a
adsasl a
adsaaslal a
adsa sl a
w.wp.apda w .wp.apda w.wp.pda a
w.wp.p
da
w .wp.apda w
ww ww ww ww ww ww
(a) lodoform test (b) Tollen’s reagent test (c) Fehling’s solution test (d) Benedict’s solution test
18. Which ntet of the followingi.ais
i.ani.eone
tet as a hypnotic? .ni.entet
ni.enused etet
ail.ani.n
etet
ail.ani.n
Padasalai.Net
a l al a l al a l al ia a l a l
s
ada s s
ada s s
ada s s
aa s s
aa s
w pdadFormaldehyde w.wp.apdad
.wp.apda(a) Acetaldehydew.wp.apda (b) Formalin w.wp.apda(c) Paraldehyde w.wp.a(d) w
ww ww ww ww ww ww
19. Which one of the following is used as nail polish remover?
entet entet entet .ani.ente
t entet
(a) ail.an3i.CHO
saaslCH s(b) ail.ani. i.ni.
slal3aCOCH3 a i
l ni.
la5il.aCOCH
apdaad apdaad aasl HCHO
apdaad apdaad
(c)saaCH sas
apdaada
l (d) sCaa6sH 3
w .
wp. w .
w p. w .
w p. w .
w p. .wp.
ww 20. The reaction w
ofwacetic ww red phosphorous is
acid with Cl2 and wwnamed as ………………www ww
w
(a) Kolbe’s
tet reaction (b)teReimer – Tiemann reaction
i.ani.en i .
a ni entet
. i .
a ni en t
. t t
il.ani.ene
t t
il.ani.ene
dsasHeII – volhard –p.a
a(c) adsas reaction
zelinsky adsas (d) Knoevenagal sas
adreaction adsas
w .wp.apda w .w pda w.wp.apda w.wp.apda w .wp.apda w
ww ww ww ww ww ww
21. Which is one the correct order of strength of carboxylic acid?
t t t t t t t t t t
ww ww ww ww ww ww

ada ada ada ada ada
ww ww ww ww ww ww
t t t t t
l a i
l.ani.ente l a i
l .ani.ente l a i
l .ani.ente
sas sas sas sas sas
.
w p.apdaada .
wp.apdaada .
w papdaada
. .
w p.apdaada .
w p.apdaada
w w w w w w
ww ww ww ww ww ww
31
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
t t t t t t t t t t
22. The il.ani.ene increasing order
aslacorrect
.ni.ene .ni.ene acid is ………… lail.ani.ene
aslaila acid strength of carboxylic
aslaila as a l a il.ani.ene
adsa s asa asa adsa s
.wp.apda(a) F – CH – COOH apdaada
.wp.> .
w p.apdad .
w p.apdad .wp.apda
w w I – CH2 – COOHww w
> CI – CH2 – COOH > w w
Brw– CH2 – COOH w w
ww 2 ww ww ww
(b) Br – CH2 – COOH > F – CH2COOH > I – CH2COOH > Cl – CH2 – COOH
a(c)
da F – CH2 – COOHp>
s CIada– CH2COOH > Br – aCH
s ad2aCOOH > I – CH2COOH
s s
ada s
ada
w .wp.apda w .w.apda w.wp.pda w .wp.apda w .wp.apda w
ww ww ww
(d) Br – CH2 – COOH > CI – CH2 – COOH > I – CH2COOH > F – CH2COOH ww ww ww
23. The conversion t of Ethyl acetate t et action of propyl .entet is named as i.ni.entet
l a i
l .ani.ente l a i
l.ani.enteto propyl acetate l ail.aby
ni.entthe l ail.anialcohol lala
a daadsaas adaadsaas a daadsaas a d
a adsaas a daadsaas
w.wp. (a) Esterificationw.wp.
p p w.wp. (b) Transesterfication
p w.wp. p w.wp. p w
ww ww ww ww ww ww
(c) Acid hydrolysis of ester (d) Alkaline hydrolysis of ester
24. Which a ntet of the following
il.ani.eone ail.ais
tet
ni.enused as food preservative?
a
t t
il.ani.ene a
t t
il.ani.ene a
t t
il.ani.ene
a l a l a l a l a l
ww (a) Sodium formate ww (b) Sodium acetate ww (c) Sodium benzoate ww (d) Acetamide ww ww
25. Which one
t t
of the following is used
t t
in the preparationt of
t medicine like aspirin
t t
and phenacetin? t t
a(a)s s
dsa Acetyl chloridep.apdaads(b)
a Acetic acid s
adsaAcetamide
(c) s
(d)adsAcetic
a anhydride apdaadsa s
w.wp.apda w .w w.wp.apda w.wp.apda w.wp. w
ww ww ww ww ww ww
26. Which of the following will not give iodoform test?
(a) Isopropyl t t etet etet tet etet
i.ani.ene alcohol (b) Ethanol
ail.ani.n
(c) Ethi.ananal
al i.n
(d) Benzyl ealcohol
ail.ani.n ail.ani.n
Padasalai.Net
ada a
aadcarbonyl ada ada ada
w .apdaThe
.wp27. addition of .wp.apdto
HCN
w .wp.apda is an example ofw…………..
compounds
w .wp.apda reaction. w .wp.apda w
ww ww ww ww ww ww
(a) N ucleophilic substitution (b) Electrophil ic addition
t t t t t
(c) l ail.ani.ente
Nucleophilic addition l a i
l.ani.ente (d) a i
l .ani.ente
Electrophilic
l substitution l ail.ani.ente l a i
l .ani.ente
sas sas sas sas sas
.
wp.apdaada .
w p.apdaada .
w p.apdaada .
w w w w w w
ww 28. The molecular ww
formula of Urotropine wwis ………….. ww ww ww
(a) (CH2)t6eNt 4 (b) (CH2te)4tN6 (c) (CH2)2tNet2 (d) (CH2)6Nt6et t t
a
en
lail.ani. a
en
lail.ani. a
en
lail.ani. a
en
sa s sa s sa s sa s adsas
adaad adaad adaad adaad .wp.apda
w w w w ww ww
13. ORGANIC NITROGEN COMPOUNDS
t t t t t t t t t t
1. s
adsaWhich of the following s
adsa reagent can be used s
adsato convert nitrobenzene s
adsa to aniline adsa s
ww ww
a) Sn / HCl ww/ NaOH
b) ZnHg wwLiAlH
c)
w
d)wAll of these ww
4
2. The.nmethod
i.ente
t by which aniline cannot
.ni.ente
t be prepared is t
.ni.ente etet etet
laila laila laila lail.ani.n l ail.ani.n
d adsaas d adsaas d adsaas s
ada as s
ada as
a
w.wp.p
a a) degradationw.ofa a
wp.pbenzamide with w a a
Brw2.wp/.NaOH
p .wp.apda
b) potassium
w .wp.apda treated
salt of phthalimide
w w
ww ww w ww ww ww
with chlorobenzene followed by hydrolysis with aqueous NaOH solution.
t t t t t
c)
l a i
l .ani.ente
Hydrolysis of phenylcyanide
l ail.ani.ente with acidic solution
l a i
l.ani.ente d) reduction oflanitrobenzene
i
l .ani.ente by Sn /l i
HCl
a l .ani.ente
sas sas sas sas sas
.
w p.apdaada .
wp apdaada
. .
w papdaada
. .
w p.apdaada .
w p.apdaada
w w w w w w
ww ww ww ww ww ww
32
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
.ni.enet t .ni.ene t t t t t t t t
3. Which
aslaila will not undergo a i.ni.ene bromamide reaction
Hofmann .ni.ene
aslaila il.ani.ene
adsa adsa slala asa asa a
asa sl a
w .wp.apda a) CH CONHCH
w .wp.apda w .
w p.apdad w .
w p.apdad w .
w p.apdad w
ww 3 ww 3 b) CHw
3 CH
w 2 CON2 c)
wwCH3 CONH2 d)wCw6 H5 CONH2 ww
4. Assertion : Acetamide on reaction with KOH and bromine gives acetic acid
Reason
s
ada : Bromine catalysesada hydrolysis of acetamide.
s s
ada s
ada s
ada
ww ww ww ww
a) if both assertion and reason are true and reason is the correct explanation of assertion. ww ww
ntet assertion and reason

b)i.ifni.eboth t t are true but reason
i.ni.ene
t ist not the correct explanation
i.ni.ene
t t
i.ni.ene
of assertion. t t
i.ni.ene
lala lala lala lala lala
a adsaas a daadsaas
w.wp. p c) assertion iswtrue
.wp. but reason is false
p w.wp. p d) both assertion
w.wp. p and reason arewfalse.
.wp. p w
ww ww ww ww ww ww
5.
t t t t t t t t t t
ww a) bromomethane ww b)α - bromowsodiumw acetate wwmethanamine
c) ww d) acetamide ww
6. Which tone
t of the following nitro
t t
compounds does not
t t
react with nitrous acid
t t t t
ww ww ww ww ww ww

Padasalai.Net
ada ada aa aa aa
w.wp.apda7. Aniline + benzoylchloride
w .wp.apda w .wp.apdad w .
wp.apdad w .
w p.apdad w
ww ww C6wHw5 - NH - COC6 H5 thiswreactionw is known as ww ww
a) Friedel
t
– crafts reaction t
b) HVZ reaction
t t t
l.ani.ente l a i
l .ani.ente
sas sas as
adsanone sas sas
.
wp.apdaada c) Schotten – Baumann.
w p.apdaada reaction .
w p.apdad) of these
.
w w w w w w
ww ww ww
8. The product formed by the reaction an aldehyde with a prmary amine (NEET) ww ww ww
a) icarboxylic t acid t taromatic acid

b) t t c) schiff ’s basei.ni.entet d) ketone t t
l.ani.ente il.ani.ene il.ani.ene a il.ani.ene
a
adsas
la a
adsas
l a a
adsas
la
a
d saaslal a
adsas
l a
w .wp.apda9. Which of the following
w .wp.apda reaction is notwcorrect. .wp.apda aa
w.wp.p
d
w .wp.apda w
ww ww ww ww ww ww
t t t t t t t t t t
ww ww ww ww ww ww

ada ada ada ada ada
ww ww ww ww ww ww
10. When aniline reacts with acetic anhydride the product formed is
t
enteaminoacetophenone t t t t t
a) io
lal .ani.– i.ani.ene
la l l a l.ani.ente
b) m-aminoacetophenone
i l a i
l .ani.ente l a i
l .ani.ente
apdad)
sas
apdaada
sas
apdaada
w.wp. p w.wp. p
c) p – aminoacetophenone .
w p. acetanilide .
w p. .
w p.
ww ww wwww ww ww ww
w
ww
w
33
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
enet t .ni.ene t t .ni.ene .ni.ene t t t t t t

lail.ani.order of basic strength
11.asThe aslaila for methyl substituted
aslaila amines in aqueous
aslailasolution is a l a il.ani.ene
ww ww ww ww ww ww

ada ada ada ada ada
ww ww ww ww ww ww
t t t t t
l a i
l .ani.ente l a i
l .ani.ente
adsaas
apda12.
sas
apdaada
sas
apdaada
sas
apdaada
sas
apdaada
w .
w p. w .
w p. w .
w p. w.wp. w .
w p. w
ww ww ww ww ww ww
t t t t t t t t t t
ww ww ww ww ww ww
t t t t t t t t t t
ww ww ww ww ww ww

Padasalai.Net
ada ada ada ada ada
ww 13. ww ww ww ww ww
t t t t t
l.ani.ente l a i
l .ani.ente
sas sas sas sas sas
.
wp.apdaada .
w p.apdaada .
w p.apdaada .
w w w w w w
ww ww ww ww ww ww
14. Nitrobenzene on reaction with Con.HNO3 / H2SO4at 80-100°C forms which one of the following
products? etet etet
a) 1,4 – dinitrobenzene t t
il.ani.ene etet
b) 2,4,6 – tirnitrobenzene t t
il.ani.ene
lail.ani.n ail.ani.n
l la ail.ani.n
l l a
d adsaasa a
adsas a a
adsas a
ss
adaada
a a
ss
adaada
p
w.w
a
. pa c)
w .apda–
.wp1,2 dinitrobenzenew.wp.apda w.wp–.pdinitrobenzene ww.wp.p
d)w1,3 w
ww ww ww w w ww
15. C5H13 N reacts with HNO2 to give an optically active compound – The compound is
t t t t t t t t
l
a) a .ani.ente – 1- amine lail.ani.ente
ilpentan b) la
pentanil.ani.ene– 2- amine l a il.ani.ene l a il.ani.ene
a
adsa s a
adsas a
adsa s a
adsa s a
adsa s
ww ww
c) N,N – dimethylpropan ww
-2-amine d) N – methylbutan ww – 2-amine ww ww
16. Secondary
etet
nitro alkanes react
etet
with nitrous acid toetform
et etet etet
ada ada ada a
ayellow solution .p.apdaada
w pdad
.wp.apda a) red solutionw.wp.apda b) blue solutionw.wp.apdac) green solution w.wp.ad) ww w
ww ww ww ww ww ww
17. Which of the following amines does not undergo acetylation?
a) entet etet entet entet .ani.ente
t
lailt.ani–. butylamine b) lethylamine
ail.ani.n c) diethylamine
lail.ani. d) triethylamine
lail.ani. l a i
l
a daadsaasa a daadsaasa a d
aadsaasa a daadsaasa sas
apdaada
w.wp. p w.wp. p w.wp. p w.wp. p w .
w p. w
ww ww ww ww ww ww
34
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
t t t t t t t t t t
18.asWhich
l a il.ani.eneone of the following
a l a
e
il.ani.enis most basic? aslail.ani.ene a l a il.ani.ene a l a il.ani.ene
adsa adsa s asa asa s adsa s
w .wp.apda a) 2,4 – dichloroanilinew .wp.apda w .
w p.apdad w .
ww ww b) 2,4 – dimethyl aniline
ww ww ww ww
c) 2,4 – dinitroaniline d) 2,4 – dibromoaniline
19.
ada When
s s
ada is reducedawithada Sn / HCl the pairaof
s adcompounds
sa formedadare s
ada
w .wp.apda w .wp.apda w.wp.pda w .wp.pda w .wp.pa w
ww ww ww ww ww ww
a) iEthanol, t hydrozylamine t t
hydrochloride t ntet t
lala .ni.ente i.ni.ene
lala l ail.anb) Ethanol,
i.ente ammonium
l ail.ani.ehydroxide l a i
l .ani.ente
apdaada apH aas
daadsO sas
apdaada
w.wp. p c) Ethanol, .NH
w2.wpOH
.p w .
w p. d) C 3 H 5 NH
w.w
2p,
. 2 w .
w p. w
ww ww ww ww ww ww
20. IUPAC name for the amine
entet
.ani.–
il3
tet
il.an–i.enmethyl
t t
il.ani.ene
t t
il.ani.ene
t t
il.ani.ene
aa)
l a Bimethylamino a–l 3
a pentane a l a a l a a l a
ww w
b) 3 (N,N –wTriethyl) – 3- amino pentane ww ww ww ww
c) 3 – tN,N
t – trimethyl pentanamine
t t t t t t t t
s
adsa d) 3 – (N,N – Dimethyl s
adsa amino) – 3- methyl sas
adpentane adsa s adsa s
ww ww ww ww ww ww
21.
Padasalai.Net
ada ada ada ada ada
ww ww ww ww ww ww
t t t t t
l.ani.ente l a i
l .ani.ente
sas sas sas sas sas
.
wp.apdaada .
w p.apdaada .
w p.apdaada .
w w w w w w
ww ww ww ww ww ww
t t t t t t t t t t
adsasAmmonium salt of
22. dsas
abenzoic acid is heated dsas
astrongly with P2O5pand sas product so formed
adthe adsaiss
w .wp.apda w .wp.apda w.wp.apda w.w.apda w .wp.apda w
ww ww ww ww ww ww
reduced and then treated with NaNO2 / HCl at low temperature. The final compound
formed entet ni.entet i.ente
t alcohol ail.ani.entet t t
il.ani.ene
alaail.ani.is a) Benzene
a l a il.adiazonium chloride ail.anb)
a l
Benzyl
al a l a
. p.apdaadsas . p.apdaadsas
. p.apdaadsa s
. p.apdaadsas .wp.apda
adsa s
ww c)wPhenol
ww ww w d) Nitrosobenzene
ww w w w
ww w w w ww ww
23. Identify X in the sequence give below.
ada ada ada ada ada
ww ww ww ww ww ww
t t t t t
l a i
l.ani.ente l a i
l .ani.ente l a i
l .ani.ente
sas sas sas sas sas
.
w p.apdaada .
wp.apdaada .
w papdaada
. .
w p.apdaada .
w p.apdaada
w w w w w w
ww ww ww ww ww ww
35
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
enet t .ene t t .ni.ene t t

.ni.ene substitution, is l:ail.ani.ene t t t t
lail.ani. the following,asthe
24.asAmong lail.anireaction that proceeds
aslaila through an electrophilic
aslaila as
ww ww ww ww ww ww

ada ada ada ada ada
ww ww ww ww ww ww
t t t t t
l a i
l .ani.ente l a i
l .ani.ente
sas sas sas sas sas
.
w p.apdaada .
w p.apdaada .
. .
w p.apdaada
w w w w w w
ww ww ww ww ww ww
25. The major
t
product of the following
t
t t t t t t t t
adsas
reaction adsas adsas adsas adsas
ww ww ww ww ww ww
t t t t t t t t t t
ww ww ww ww ww ww

Padasalai.Net
ada ada ada ada ada
ww ww ww ww ww ww
t t t t t
l.ani.ente l a i
l .ani.ente
sas sas sas sas sas
.
wp.apdaada .
w p.apdaada .
w p.apdaada .
w Additional Questions w : w w w w
ww ww ww ww ww ww
1. Which one of the following is act as neurotransmitter?
t t t t t t t t t t
as Pyridoxine
ads(a) as Histamine
ads(b) s
adsaDopamine
(c) as
(d)adsCyano cobalamine adaadsas
w .wp.apda w .wp.apda w.wp.apda w.wp.apda w.wp.p w
ww ww ww
2. Which one of the following is an example of primary nitro alkane? ww ww ww
tet
(a) 2i.n–i.ennitropropane (b) Ethyl t
entenitrite
(c) Nitro t t
ethane (d) 2 – methyl t t – 2 – nitropropane t t
a a lala a a lail.ani. a la il.ani.ene a l a il.ani.ene a l a il.ani.ene
asa s s
daadsa nitrite are the daadsa s adsa s adsa s
w pdadNitro methane w
.wp.a3. .wp.apmethyl
and w .wp.apexamples of ……………
ww ww ww ww ww ww
(a) Position isomerism (b) chain isomerism (c) metarnersm (d) Tautomerism
.ni.n etet etet
il.ani.n oil of mirbane? i.ani.n etet etet etet
aslaila of the followingsaisslacalled
4. sWhich saslal s aslail.ani.n s asl ail.ani.n
ada ada ada ada ada
ww ww
(a) Nitro methane ww propane
(b) Nitro wwNitro benzene (d)wNitro
(c) w ethane ww
5. On direct tet
nitration of nitro benzene tet
gives ………………t t t t
l i
ala. ni e
. n
l i
ala. ni e
. n
l
ee
ail.ani.n l a i
l .ani.ente l a i
l .ani.ente
s as
a 0 – dinitro benzene s as s as sas sas
apdaad(a) apdaada da
(b) map–daadinitro benzene apdaada apdaada
w.wp. w.wp. w.wp. w .
w p. w .
w p. w
ww ww ww ww ww ww
(c) p – dinitro benzene (d) 2, 4, 6 – trinitrobenzene
36
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
.ni.ene t t .ni.ene t t
.ni.ene .ani.ene t t t t t t
6. Which
aslailais formed when nitro
aslailamethane reacts with
aslailchlorine and NaOH?aslail.ani.ene
adsa adsa adsa asa adsa
w .wp.apda (a) CH CI w .wp.apda (b) CH COCl w.wp.apda(c) CCI NO w pdad
ww 3 ww 3 ww 3 2 ww CHCI2NO2 ww ww
7. What is the IUPAC name of
ad(a)
sa Tertiary butyl amine s
ada (b) Trimethyl amine
s
ada s
ada s
ada
ww ww
(c) N, N – dimethyl methanamine ww (d) N – methyl ethanamine ww ww ww
8. Thei.IUPAC
l a l ni.entet name of
a l a i
l.ani.ente
t
l ail.ani.ente
t
l ail.ani.ente
t
l a i
l .ani.ente
t
saas dsaas saas sas sas
.
w p.apdaad(a) Methyl iso propyl
.
w p.apdaaamine (b) N – methyl
.
w p.apdaadpropan – 1 – amine
.wpapdaada
. .
w p.apdaada
w w w w w w
ww ww ww ww ww ww
(c) N, N – dimethyl methanamine (d) propan – 1 – amine
etet t t
il.ani.enisechanged to methylamine
t t
il.ani.ene by the action ntet/KOH?
il.ani.eBr
t t
il.ani.ene
ail.ani.n reaction acetamide
9. sInaslwhich a l a a l a a l aof 2 a l a
ada adsas adsas adsas adsas
ww ww
(a) Gapriel phthalimide synthesis ww (b) Hoffmann w w
degration reaction ww ww
(c) Mendius
t t
reaction t t (d) Mustard t t oil reaction t t t t
n
il.ai e
. ne n
il.ai e
. n e n
il.ai e
a sl a asl a asl a asl a a sl a
10.adsWhich
a adsa is used in the synthesis
one of the reaction adsa of aliphatic primary adsa amines? adsa
ww ww ww ww ww ww
(a) Hoffmann ammonolysis (b) Rosenmund’s reduction
etet
(c) Carbylamine reaction i.ani.entet (d) Gabriel etetphthalimide synthesis etet etet
ail.ani.n ail.ani.n ail.ani.n ail.ani.n
Padasalai.Net
aa aa ada daada ada
w pdadThe conversionwof.wpethanol
.wp.a11. .apdad into all types
w .apdaamines
.wpof by the .wp.apof
action
w ammonia alongw .wp.apdaAlumina
with w
ww ww ww ww ww ww
is (a) HVZ reaction (b) Sabatier – mailhe method
t t t t t
l ail.ani.ente (c) Carbylamine
l a i
l.ani.ente reaction l a i
l i.enteMendius reaction
.an(d) l ail.ani.ente l a i
l .ani.ente
sas sas sas sas sas
.
wp.apdaada .
w p.apdaada .
w p.apdaada .
w 12. The relative basicity w w w w w
ww ww of amine follows ww the order as …………. ww ww ww
(a) Alkylteamines
t > Aralkyl amines
tet > Ammonia > N – aralkylamine
tet > Arylamine
tet t t
a
en
lail.ani. a
en
lail.ani. a
en
lail.ani. a
en
sa s sa s s
a s sa s adsas
adaad(b) Aralkyl amines ad
>adaAmmonia > Arylamine adAlkyl amine > N – aralkylamine
ada> adaad .wp.apda
w w w w ww ww
(c) Arylamine Alkyl amine N – aralkylanilne
et
(d)aNil.ani–.entaralkylamine < Arylamineetet t t
il.ani.eneamine < Aralkyl amine etet t t
il.ani.ene
a sl a asl a ail.ani.n < Ammonia < aAlkyl
a sl a a slail.ani.n
a asl a
asa adsa adsa asa s
aada
w pdadIdentify the name
.wp.a13. w .apdathe
.wpof reaction in .wp.apdaaniline reacts with
which
w w p.apdad chloride to form
.w
Benzoyl w .wp.apdN – w
ww ww ww ww ww ww
Phenyl benzamide? (a) Hoffmann degradation reaction (b) Gabriel phthalimide synthesis
etet t t
s asl ail.ani.n (c)
s aslaSchotten – Baumann s asl ail.ani.n
reaction (d) lail.ani.n oil reaction saslail.ani.n
Mustard
s as
ada ada ada ada ada
ww 14. The reactionwof w aniline with nitrouswacid w at low temperature ww is known as …………ww ww
(a) Carbylamme
etet reaction t (b) mustard
etet oil reaction t t
l a i
l .ani.n l ail.ani.ente l a i
l.ani.n l a i
l .ani.ente l a i
l .ani.ente
saas Diazotisation sas adsaasSand meyer’s reaction sas sas
.
w p.apdaad(c) .
wp.apdaada .
w papda(d)
. .
w p.apdaada .
w p.apdaada
w w w w w w
ww ww ww ww ww ww
37
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
.ni.ene t t .ni.ene t t ee .ni.enet t t t t t

15. Which
aslaila one of the following ail.ani.n primary amines?
aslailareaction is used toaslidentify aslaila a l a il.ani.ene
w .wp.apda (a) Schotten – Baumann
w .wp.apda reaction w .wp.apda(b) Carbylamine reaction
ww ww ww ww ww ww
(c) Sand meyer’s reaction (d) Gattermann reaction
16.adThe
a reaction between
s admethylamine
s
a and CS a2dis
a known as ……………
s s
ada s
ada
ww ww
(a) mustard oil reaction ww ww
(b) Carbylamine reaction ww ww
(c) Sand t
t meyer’s reaction i.ni.entet (d) Gabriel t t t
l ai.ni.ene
l a l a l a l ail.ani.ente phthalirnide synthesis
l .ani.ente
as a sas sas sas
. p. daadsaThe
ap17. conversion of
. p. daadsas
apBenzene diazonium . p.apdaada into chlorobenzene
chloride . papdaadais known as …………
. . p.apdaada
ww ww ww ww ww ww
(a) Gabriel phthalimide synthesis (b) Carbylamine reaction
t t t t t t t t
(c)
l a .ani.ente meyer reactionlail.ani.ente
ilSand (d) l a il.ani.ene reaction
Coupling l a il.ani.ene l a il.ani.ene
a
adsas a
adsas a
adsas a
adsas a
adsas
ww 18. What is the name ww of the reaction in ww
which benzene diazonium ww chloride react with ww benzene to ww
give Biphenyl?
t t
(a) Sandmeyer’s
t t
reaction t t
(b) Gomberg
t t
reaction t t
adsa s s
adsa(c) Gattermann reaction adsas s
(d)adsBaltz
a adsa
– schiemann areaction s
w.wp.apda w .wp.apda w.wp.apda w.wp.apda w .wp.pda w
ww ww ww ww ww ww
19. Chloropicrin is used as (a) antiseptic (b) analgesic (c) insecticide (d) fertilizer
20. Replacementt t t
i.ente by fluorine is known
of diazoniumi.angroup t t etet etet
i.ani.ene i.ani.ene as ………….. ail.ani.n ail.ani.n
Padasalai.Net
lal lal l al l l
dadsaas d adsaas s
ada as s
ada as s
ada as
a a
w.wp.p (a) Gattennann
a
.wp.p a
wreaction w .wp.apda(b) Sandmeyer reaction
ww ww ww ww ww ww
(c) Baltz – Schiemann reaction (d) Comberg reaction
tet
.ani.enone .anis et
i.entthe tet
ni.enaqueous
.ain .ani.ente
t
.ani.ente
t
21. sWhich
asl ail of the following l a i
l strongest basel a i
l solution? l ail l a i
l
sas sas sas sas
.
wp.apdaada .
w p.apdaada .
w p.apdaada .
w p.apdaada .
w p.apdaada
w ww ww w ww w
ww (a) Trimethylwamine (c) Dimethylwamine ww amine
(d) methyl (b)wAniline ww
22. Liebermann’s
tet nitroso reactionteist used for testing ………….
tet t t t t
as 1° amine
ads(a) as 2° amine
ads(b) s amine
adsa3°
(c) as the above
(d)adsall adsas
ww ww ww ww ww ww
23. Carbylamine test is used in the detection of …………
t t 2° amine t t etet 1° amine t t t t
a l ail.ani.ene
(a)aaliphatic
a l a il.ani.ene (b) Aromatic
a ail.ani.n
l a a l a il.ani.ene a l a il.ani.ene
w.wp.apda (c) Aliphatic l amine
w .wp.apda w.wp.apda(d) both aliphaticwand
.wp.apdaaromatic 1° amine w .wp.apda w
ww ww ww ww ww ww

ada ada ada ada ada
ww ww ww ww ww ww
t t t t t
l a i
l.ani.ente l a i
l .ani.ente l a i
l .ani.ente
sas sas sas sas sas
.
w p.apdaada .
wp.apdaada .
w papdaada
. .
w p.apdaada .
w p.apdaada
w w w w w w
ww ww ww ww ww ww
38
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
t t t t t t t t t t
a l a il.ani.ene a l a il.ani.ene 14. BIOMOLECULES
a l a il.ani.ene a l a il.ani.ene a l a il.ani.ene
ww 1. Which one of wwthe following rotates ww
the plane polarized light ww towards left? ww ww
(NEET Phase
t t – II) a) D(+) tGlucose t (b) L(+) Glucose tet (c)D(-) Fructose tet d) D(+) Galactose.ni.entet
. ni e
. n e .ni e
. n e . ni e
. n .ni e
. n
aslailacorrect corresponding
adsaThe
2.
laila
adsaas order of names of
ad
laila
saasfour aldoses with adsaas
laila
configuration given belowadsaas
laila
a da a da a da a da a da
ww ww ww ww ww ww
Respectively is, (NEET Phase – I)1551
t .entet t t t t
lal .ani.ente
a) iL-Erythrose, L-Threose,
i.aniL-Erythrose,
la l
D-Threose
i.ani.ene
la l l ail.ani.ente l a i
l .ani.ente
a daadsaas a daadsaas a daadsaas sas
apdaada
sas
apdaada
w.wp. p w.wp.p
b)D-Threose,D-Erythrose, L-Threose, .wp. p
wL-Erythrose, w.wp. w .
w p. w
ww ww ww ww ww ww
c)L-Erythrose, L-Threose, D-Erythrose, D-Threose
a ni.entet
il.D-Erythrose,
a a
tet
il.ani.enL-Erythrose, a
t t
il.ani.ene a
t t
il.ani.ene a
t t
il.ani.ene
ad)
adsas
l D-Threose,
a
adsas
l L-Threose
a
adsas
l a
adsas
l a
adsas
l
ww 3. Which one given ww below is a non-reducing ww sugar? (NEET Phase ww – I) ww ww
a) Glucose
tet b) Sucrose c) maltose d) Lactose.tet
i .ani en
. i .
ani entet
. i .
a ni entet
. il.ani.en
t t
il.ani.ene
asl a l asl a l asl a l a sl a a sl a
adsaGlucose(HCN) Product
4. adsa(hydrolysis) Product sa + Heat) A, the compound
ad(HI adsa A is adsa
ww ww ww ww ww ww
a) Heptanoic acid b) 2-Iodohexane c) Heptane d) Heptanol
entet
5. Assertion:
A solutionlailof ntet
.ani.esucrose t t
il.ani.ene
in water isladextrorotatory. But on ni.entet
hydrolysis in the lail.ani.entet
lail.ani.
Padasalai.Net
as a as as asl ail.a a
. p.ap
s
daada .p.ap
s
daada . p.ap
s
daada .p.a
p
s
daada . p.apdaadsas
w w presence of little whydrochloric
w acid, it w
becomes
ww levorotatory.w(AIIMS)
ww ww w
ww ww w w ww ww
Reason: Sucrose hydrolysis gives unequal amounts of glucose and fructose. As a result of this
t t t t t
l.ani.ente l a i
l .ani.ente
change
sas in sign of rotation sasis observed. sas sas sas
.
wp.apdaada .
w p.apdaada .
w p.apdaada .
w p.apdaada .
w p.apdaada
w w w w w w
ww ww
a)If both accretion and reason are ww
true and reason is the wwcorrect explanation w ofwassertion ww
b) If eboth t t assertion and reason t t are true but reason t ist not the correct explanation t t of assertionetet
a la il.ani.ne a l a il.ani.ene a la il.ani.ene a l a il.ani.ene a lail.ani.
n
s
a s s
a s sa s s
a s sa s
adaad c) If assertion is.wptrueadaadbut reason is false. adaad d) if both assertionadaad and reason are.wpfalse. adaad
w w.wp.p w w .p w w.wp.p w w.wp.p w w .p w
w w w w w ww
6. The central dogma of molecular genetics states that the genetic information flows from
(NEET ni.entet – II)
lail.aPhase l a
t t
il.ani.ene la
t t
il.ani.ene l a
t t
il.ani.ene l a
t t
il.ani.ene
a
adsa s a
adsas a
adsa s a
adsa s a
adsa s
w.wp.apda a) Amino acidsw.wp.apda Protein DNA
w.wp.apda w .wp.apda w .wp.apda w
ww ww ww ww ww ww
b) DNA Carbohydrates Proteins
t etet t t etet etet
.ani.ente
ailDNA ail.ani.n i.ni.ene ail.ani.n ail.ani.n
a l
c)
s a
RNAsl Proteins alala a l a l
.wp.apda
s
ada
.wp.apda
s
ada dadsas
aa .wp.apda
s
ada s
.wp.apda
s
ada s
w w w.wp.p w w w
ww d) DNA ww RNA ww
Carbohydrates ww ww ww
7. In a nprotein,
entet various aminonacids
entet liked together by (NEET Phase – I)
nentet t t
l a i
l .ai. l ail.ai. l a i
l.ai. l a i
l .ani.ente l a i
l .ani.ente
sas saas adsaαas- Glycosidic bondadaadsaas d) β - Glycosidicadbond sas
.
w p.apdaada a) Peptide bond.wp.apdaadb) Dative bond .wp.apdac) .
w p. p .
w p. p aada
w w w w w w
ww ww ww ww ww ww
39
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
.ni.enet t t t
.ani.ene amino acid is l(AIIMS)
.ni.ene t t t t t t
8. Among
aslaila the following the
aslailachiral asaila a l a il.ani.ene a l a il.ani.ene
adsa adsa adsa adsa s asa s
w .wp.apda a) 2-ethylalanine
w .wp.apda b) 2-methylglycine
w .wp.apdac) 2-hydroxymethylserine
w .wp.apda w .
w p.apdad w
ww ww ww ww d) Tryptophan ww ww
9. The correct statement regarding RNA and DNA respectively is (NEET Phase – I)
ada a) the sugar component
s ada in RNA is an arabinos
s ada and the sugar component
s s
ada in DNA is ribose s
ada
ww ww ww ww
b) the sugar component in RNA is 2’-deoxyribose and the sugar component in DNA is arabinose ww ww
c) ithe t ntet is an arabinosei.and t sugar component t DNA is t

lala .ni.entesugar component iin
.ni.eRNA
lala ni.entethe lala
t in
i.ni.ene lala l a i
l .ani.ente
a adsaas sas
apdaada
w.wp. p w.wp.p w.wp. p w.wp. p 2’-deoxyribose
w .
w p. w
ww ww ww ww ww ww
d) the sugar component in RNA is ribose and the sugar component in DNA is 2’-deoxyribose
etet
ni.n etet
il.ani.n acids mostly exists
i.ani.n etet etet
i.ani.n b) NH2-CH(R)-COO
i.ani.n etet
10. lail.aaqueous
sasIn solution sofaslaamino saslal in, a) NH2-CH(R)-COOH
saslal saslal
ada ada ada ada ada
ww ww ww ww
c)H3N+-CH(R)-COOH d)wHw3N+-CH(R)-COO- ww
11. Whicht tone of the following tistnot produced by body?
t t t t t t
adsa s a) DNA adsa s s s
b) Enzymes apdaadsa c) Harmones apdaadsa d) Vitamins adsa s
w.wp.apda w .wp.apda w.wp. w.wp. w .wp.apda w
ww ww ww ww ww ww
12. The number of sp2 and sp3 hybridised carbon in fructose are respectively
t 1 and 4
etea) tet4 and 2
eb) ete5t and 1
c) t 5
d) e1teand etet
Padasalai.Net
ada aada ada ada ada
w.wp.apda13. Vitamin B2 is w .wp.apdknown
also as w .wp.apda w .wp.apda w .wp.apda w
ww ww ww ww ww ww
a) Riboflavin b) Thiamine c) Nicotinamide d) Pyridoxine
ail ntet
.ani.epyrimidine a i
l
t
.ani.ente in DNA are a) lCytosine
a i
l
t
.ani.ente and Adeninelab) i
l
entet
.ani.Cytosine a i
l .ani.ente
t
14. The
sasl bases present
sasl sas sas and Guanine
sasl
.
wp.apdaada .
w p.apdaada .
w p.apdaada .
w w c)wCytosine and Thiamine w w w
ww ww ww ww d) Cytosine wwand Uracil ww
15. Among
tet the following L-serine
tet is t t t t t t
adsasThe secondary structure
16. adsas of a protein refers s
adsato adsas adsas
ww ww ww ww ww ww
a) fixed configuration of the polypeptide backbone b) hydrophobic interaction
t t t t t etet t t
l .ani.ente
c)ailsequence of α-aminoaacids
l il.ani.ene la il.ani.ene d) α-helical
ail.ani.n backbone. a il.ani.ene
a s as a s ala a l
adsa
.wp.apda17. Which of the w .wp.apda
adsa adsa
.wp.apdasoluble? . p.apdaadsas .wp.apda
adsa s
w following vitamins is water
w ww w w
ww ww ww ww ww ww
a) Vitamin E b) Vitamin K c) Vitamin A d) Vitamin B
etet t t
18.s asl ail.ani.n
Complete hydrolysis sof
aslacellulose gives s asl ail.ani.n s aslail.ani.n s asl ail.ani.n
ada ada ada ada ada
ww a) L-Glucose ww b) D-Fructose ww c) D-Ribose ww d) D-Glucose ww ww
t t t t t
l a i
l.ani.ente l a i
l .ani.ente l a i
l .ani.ente
sas sas sas sas sas
.
w p.apdaada .
wp.apdaada .
w papdaada
. .
w p.apdaada .
w p.apdaada
w w w w w w
ww ww ww ww ww ww
40
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
t t
ene t t t t t t t t
19.asWhich il.ani.ene
aslastatement is correct?aslail.ani.ene a l a il.ani.ene a l a il.ani.ene
adsa daadsa asa adsa s adsa s
w .wp.apda a) Ovalbumin wis.wpa.apsimple w .
ww ww food reserve
ww in egg-white ww ww ww
b) Blood proteins thrombin and fibrinogen are involved in blood clotting
ada c) Denaturation makes
s ada protein more active
s s
ada s
ada s
ada
ww ww ww
d) Insulin maintains the sugar level of in the human body. ww ww ww
20. Glucose t t tet t t

l a i
l .ani.ente is an aldose. Which l a i
l.ani.enteone of the following l ail
reactions
.ani.en is not expected
l ail.ani.ente with glucose? lail.ani.ente
sas dsaas sas sas sas
.
w p.apdaada a) It does not form .
w p.apdaa
oxime b) It
.
w p.apdaadanot react with Grignard
does .
w papdaada reagent
. .
w p.apdaada
w w w w w w
ww ww ww ww ww ww
c) It does not form osazones d) It does not reduce tollens reagent
t t t t t t t t
21. If
l a .ani.entestrand of the DNA
ilone l a ni.entethe
il.ahas sequence l a il.ani.ene
‘ATGCTTGA’, then the il.ani.ene of
sequence
l a l a il.ani.ene
a
adsas a
adsas a
adsas a
adsas a
adsas
ww complementary wwstrand would be ww ww ww ww
a) TACGAACT
t t
b)
t tTCCGAACT c) tTACGTACT
t d) TACGRAGT
t t t t
n
il.ai e
. ne n
il.ai e
. n e n
il.ai e
adsa Insulin, a hormone
22. dsa
achemically is adsa adsa adsa
ww ww ww ww ww ww
a) Fat b) Steroid c) Protein d) Carbohydrates
23. α-D ntetGlucose and β-Di.(+)
i.ani.e(+) ani.en
et
tglucose are etet
ail.ani.n
etet
ail.ani.n
etet
ail.ani.n
Padasalai.Net
ada ada ada ada ada
w.wp.apda a) Epimers w.wp.apda b) Anomers w .wp.apdac) Enantiomers w.wp.ad)pdaConformational .wp.apda
isomers
w w
ww ww ww ww ww ww
24. Which of the following are epimers
entet
.ani. i.ani. entet .entetD(+)-Glucose and
.ani(b) ni.entet
.aD(+)-Mannose .ani.ente
t
lailD(+)-Glucose
saasa) saaslal
and D(+)-Galactose sasl a i
l sasl ail sasl a i
l
adaad .wp.apda
ad apdaada apdaada apdaada
w w.wp.p w w w .
w p. .
w p.
w and (b) w.wp. w
w c) Neither w
(a) nor (b) ww (d) Bothww (a) ww ww
25. Whichtetof the following amino acids are achiral? tet
n en n entet en t t
il.ani.ene
t t
il.ani.ene
as
i
lal.a i.
as
i
lal .
a i .
aslail.ani. a l a a l a
asa
p.apdad a) Alanine
a s
a
p.apdadb) Leucine
a s
a
p.apdac)d Proline dsas
d)aGlycine adsas
w.w w.w w.w w.wp.apda w .wp.apda w
ww ww ww ww ww ww
t t t t t t t t
.ni.ente
ADDITIONAL QUESTIONS :.ni.ente il.ani.ene il.ani.ene il.ani.ene
asa alaila
s alaila
asas asaasla a
asa sl a a
asa sl a
w pdad
.wp.a1. w .
w p.apdad w.wp.apdad w .
w p.apdad w .
w p.apdad w
ww How many isomers
ww are possible forwglucose
w that have 4 asymmetric
ww carbon atoms? ww ww
(a) 8 isomers (b) 16 isomers (c) 2 isomers (d) 4 isomers
asl ail.ani.n aslail.ani.n asl ail.ani.n aslail.ani.n asl ail.ani.n
2. adHow
sa many asymmetric adacarbon atoms areain
s adglucose?
sa s
ada s
ada
w.wp.apda w .wp.apda w .wp.pda w .wp.apda w.wp.apda w
ww (a) 4 ww (b) 3 ww (c) 2 ww (d) 1 ww ww
3. Which tet of the following.nwill

.ni.enone
t
i.ente reduce Tollen’s reagent
t
.ni.ente and Fehling’s solution?
.ni.ente
t
.ani.ente
t
ia ia ia ia i
aad a
d aadad aad a
d d a
d
apa Maltose apdaada
w.wp.p (a) Glucose ww.wp.p (b) Fructose ww.wp.p (c) Sucrose w.wp.(d) w .
w p. w
ww w w ww ww ww
41
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
t t e t t t t t t t t
4. Thea l a ani.en
il.specific rotation ofapure
l a il.ani.enαeand β (D) glucose
a l a ni.enerespectively.
il.a
are a l a il.ani.ene a l a il.ani.ene
adsa s adsa s adsa s asa s adsa s
w .wp.apda (a) 18.7°, 112° w.wp.apda (b) 112°, 18.7° w.wp.apda(c) 90°, 90° w pdad
ww ww ww ww 120°, 20° ww ww
5. Sugar differing in configuration at an asymmetric centre is known as ……………….
ad(a)
sa epimers ad(b)
sa isomers (c)
adaanomers
s (d)admonomers
s
a s
ada
ww w w
6. Which is thewproduct formed whenwfructose undergoes partial ww reduction with sodium ww amalgam ww
lalani.entet
andi.water?
l a l a
t t + mannitol
(a) Sorbital
i.ni.ene l ail
t
.ani.ente (b) D – mannose l ail
t
.ani.en+teD – galactose lail.ani.ente
t
a daadsaas saas
apdaad(c)
a
daadsas
asaccharic
sas
apdaada + ketone
sas
apdaada
w.wp. p w .
w p. Gluconic acid
w +
.
w p. p acid (d) Aldehyde
w.wp. w .
w p. w
ww ww ww ww ww ww
7. How many asymmetric carbon atoms are present in fructose?
etet
.ni.n etet etet etet t t
il.ani.ene
asla4ila
s(a) (b) 3 saslail.ani.n(c) 2 (d)sas6lail.ani.n aslail.ani.
n
a l a
apdaad a ad a ad a adsa adsas
w.wp.8. w .wp.apda w .wp.apda w .wp.apda w .wp.apda w
w w w
Two monosaccharides
w are linked by w
w to form a disaccharide. w w ww ww
t t t t t t t t t t
ww ww ww ww ww ww

Padasalai.Net
ada ada ada ada ada
ww ww ww ww ww ww
t t t t t
l.ani.ente l a i
l .ani.ente
sas sas sas sas sas
.
wp.apdaada .
w p.apdaada .
w p.apdaada .
w 9. The enzyme that w w of sucrose to glucose w and fructose is ……………. w w
ww ww catalyses the hydrolysis ww ww ww ww
(a) zymase
t (b) invertase (c) diastaset (d) maltase t
i.ani.ente i .
a ni entet
. i .
a ni ente
. t
il.ani.ene
t t
il.ani.ene
as
10.adsWhich adsas is an examplead
one of the following as – reducing sugar?
ofadsnon adsas adsas
w .wp.apda w .wp.apda w.wp.pa w.wp.apda w .wp.apda w
ww ww ww ww ww ww
(a) Glucose (b) Dextrose (c) Lactose (d) Sucrose
11. Which tet of the following.ngives
t t .entet t
.ni.ente with amylopectin? t t
i.ni.enone
a i i.ene blue colour with
a i.niamylose
a
and purple icolour
a i.ni.ene a
dadsaaslal d a
dsaaslal d adsaaslal d adsaaslal d adsaaslal
a a a a a a a a a a
w.wp.p (a) Tollen’s reagent
w.wp.p (b) Fehling’s solution
w.wp.p w.wp.p
(c) Iodinewsolution w.wp.p
(d) Bromicwwater w
ww ww ww w w ww
12. Which of the amino acid is optically inactive?
t t t t etet etet etet
(a)
a l il.ani.ene
aAlanine (b)
a l il.ani.ene
aValine (c) a l ail.ani.n
Glycine (d) ail.ani.n
Proline
a l a l ail.ani.n
s
ada s s
ada s s
ada s s
ada s s
ada s
ww 13. Which one of ww
the following is an example ww for globular protein? ww ww ww
(a) Kerating
t t (b) Myoglobin
t t (c) Collagen
t t (d) Etastin t t t
ee
ail.ani.n
ee
ail.ani.n
ee
ail.ani.n n.ene
i.ai i .ani.ente
s asl s asl s asl saaslal sasl a l
adaada adaada adaada aad a
d apdaada
w w.wp.p w w.wp.p w w.wp.p w.wp.p w .
w p. w
w w w ww ww ww
42
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
t t
.ani.ene .ni.ene t t
.ni.ene t t t t t t
14. The
aslailchemical name of vitamin
aslaila B9 is ……………. aslaila a l a il.ani.ene a l a il.ani.ene
w .wp.apda (a) biotin w .wp.apda (b) folic acid w.wp.apda(c) niacin w pdad
ww ww ww ww thiamin ww ww
15. The nucleic acid base having two possible binding sites is …………….
ad(a)
sa thymine ad(b)
sa cytosine (c)
adaguanine
s (d)adadenine
s
a s
ada
ww ww
16. Which one of the following is a protein hormone? ww ww ww ww
(a) Insulin t t (b) Androgen

.ani.ente
t (c) Cortisol
.ani.ente
t (d) Estrogen t t .ani.ente
t
l ai.ni.ene
l a l a i
l l ail i.ni.ene
lala l a i
l
a17. aas
daadsWhich sas
apdaada
sas
apdaada a d
a adsaas sas
apdaada
w .
w p. p one of the
w .
w following
p. is a steroid?
w .
w p. w.wp. p w .
w p. w
ww ww ww ww ww ww
(a) Insulin (b) Epinephrine (c) mutin (d) Estrogen
etet tet
il.ani.en(a)
t t
il.ani.ene etet t t
il.ani.ene
l ail.ani.n
18. sAasnucleotide consists of a l a base and sugara l a (b) base and il.ani.n
saslaphosphate a l a
ada adsas adsas ada adsas
ww ww ww and phosphate
(c) sugar ww base, sugar and phosphate
(d) ww ww
19. Which one
t t
is fouñd in ATP ribonucleotide?
t t t t t t t t
s
ads(a)
a Guanine s
ads(b)
a Uracil s
adsaAdenine
(c) s
(d)adsInulin
a adsa s
ww ww ww ww ww ww
20. In nucleic acid, the correct sequence is ……………..
(a) base ete–t phosphate sugari.ani.entet (b) phosphate t
–ntebase
i.ani.e – sugar etet etet
Padasalai.Net
a l lal l al l l
s
ada s adsaas s
aa as s
ada as s
ada as
a d
a
w.wp.p (c) sugar – base
a
.pda
w–.wpphosphate (d)
w p.apdad– sugar – phosphate
base
.w w .wp.apda w .wp.apda w
ww ww ww ww ww ww
21. In DNA, the complementary bases are
s(a) ail.ani. i.ni. and guanine alail.an(b)
slala
i.ani. guanine and cytosine
i. Adenine and thymine;
saaslal
i.ani.
saaslal
adaad aasl Uracil and adenine;saacytosine
ad ad sas ad ad
w.wp.p (c) Adenine and .wp.apda
wguanine; w .wp.apda w .wp.apda w.wp.apda w
w w w w thymine w w w
and cytosine (d) adenine w
w and guanine; thymine
w and uracil ww
22. RNA is different
tet from DNA because
tet RNA contains ……………
tet t t t t
a
en
lail.ani. a
en
lail.ani. a la il.ani.en a l a il.ani.ene a l a il.ani.ene
sa s sa s adsas (b) Ribose sugar sas uracil adsas
adaad(a) Ribose sugar and ad
adatymine .wp.apda .wp.apda
adand
.wp.apda
w w ww ww ww ww
(c) Doxyribose sugar and thymine (d) Deoxy ribose sugar and uracil
etet
23. Haemoglobin is ntet
il.ani.eenzyme
(a)aan il.an(b)
t
i.entea globular protein t t
il.ani.ene
t t
il.ani.ene
ail.ani.n
ala a l a a la a l a a l a
. p.apdaadsas adsas
.wp.apda (c) a vitamin w.wp.apda
adsa s
.wp.apda
adsa s
.wp.apda
adsa s
ww w (d) carbohydrate
w w w
ww ww ww ww ww ww
24. The number of essential amino acid in man is …………….
etet t t
il.ani.ene i.ente
t etet etet
(a)
s asl a8il.ani.n (b)
s asla10 (c) 20 s asl ail.an(d) 18 s aslail.ani.n s asl ail.ani.n
ada ada ada ada ada
ww 25. In fructose, the ww possible optical isomers ww are ………….. ww ww ww
(a) 12 etet (b) 16 etet (c) 8 (d) 4t t t

l.ani.ente l a i
l .ani.ente l a i
l .ani.ente
s as s as sas sas sas
w p. w .
w p. w .
w p. w
w w ww ww ww ww
43
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
t t tet i.ente
t t t t t
a l a il.ani.ene a l a il.ani.en15. CHEMISTRY a IN
l a il.anEVERYDAY LIFE a l a il.ani.ene a l a il.ani.ene
ww ww ww ww ww ww
1. Which of the following is an analgesic?
t etet etet etet etet
a)
l .ani.ente
ailStreptomycin l ail.ani.nb) Chloromycetin l ail.ani.n c) Asprin l ail.ani.n d) Penicillin saslail.ani.n
s
ada as s
ada as s
ada as s
ada as ada
w .wp.apda2. Dettol is the mixture w .wp.apda of w.wp.apda w .wp.apda w .wp.apda w
ww ww ww ww ww ww
a) Chloroxylenol and bithionol b) Chloroxylenol and α-terpineol
t t t t t
l a i
l .ani.ente l a i
l .ani.ente
sasc) phenol and iodine sas d) terpineol sas and bithionol dadsaas sas
.
w p.apdaada .
w papa
. .
w p.apdaada
w wwdisinfectants either w w w w
ww 3. Antiseptics w and wwkill or prevent growth wwof microorganisms. Identify
ww ww
which ofetthe
et following statement
etet is not true. t t t t t t
a l a il.ani.n a l ail.ani.n a l a il.ani.ene a l a il.ani.ene a l a il.ani.ene
adsas ss
aadaboric acid and hydrogen adsas peroxide are strong adsas adsas
w .wp.apda a) dilute solutions w .wp.apdof w .wp.apda w .wp.apda antiseptics. w.wp.apda w
ww ww ww ww ww ww
b) Disinfectants harm the living tissues.
c) ailA ntet solution of phenol
.ani.e
0.2% a
t t
il.ani.eneis an antiseptic awhile a
tet solution acts as .ani.edisinfectant.
il.ani.en1% a
t t
ila ne a
t t
il.ani.ene
a sl a sl sl a sl a sl
adsa asa adsa adsa adsa
w.wp.apda d) Chlorine and w .apdad are used as strong
.wpiodine w.wp.apdadisinfectants. w.wp.apda w .wp.apda w
ww ww ww ww ww ww
4. Saccharin, an artificial sweetener is manufactured from
t etet t etet etet
.ani.ente ail.ani.nb) toluene i.ente
ail.anc) ail.ani.n d) starch saslail.ani.n
Padasalai.Net
s a l
a)
s ailcellulose s asl s asl cyclohexene s asl
ada ada ada ada ada
ww 5. Drugs that bind ww to the receptor site wwand inhibit its natural wwfunction are called ww ww
a) antagonists
n.entet
b)tagonists c) enzymes
t t d) molecular targets t
l ail.ai l a i
l.ani.ente l a i
l .ani.ente
as
adsaAspirin sas sas sas sas
.
wp.apda6. is a/an .
w p.apdaada a) .
w .apdaadaacid
acetylsalicylic
p b) benzoyl
.
w p.apdaadasalicylic acid .wp.apdaada
w w w w w w
ww ww ww ww ww ww
c) chlorobenzoic acid d) anthranilic acid
.ni.ene t t .ni.ene t t
.ni.ene .ni.ene t t t t t t
7. Which
alaila one of the following
alaila structures represents
alaila nylon 6,6 polymer?
alaila a l a il.ani.ene
ww ww ww ww ww ww
t t t t t t t t t t
ww ww ww ww ww ww

ada ada ada ada ada
ww ww ww ww ww ww
t t t t t
l a i
l.ani.ente l a i
l .ani.ente l a i
l .ani.ente
sas sas sas sas sas
.
w p.apdaada .
wp.apdaada .
w papdaada
. .
w p.apdaada .
w p.apdaada
w w w w w w
ww ww ww ww ww ww
44
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
8. Natural
aslaila rubber has a l a il.ani.ene a l a il.ani.ene a l a il.ani.ene a l a il.ani.ene
adsa asa s asa s asa s asa s
w .wp.apda a) alternate cis-
w .apdad
.wpand w .
w p.apdad w .
w p.apdad w .
w p.apdad w
ww ww trans-configuration ww b) randomww cis- and trans-configuration ww ww
c) all cis-configuration d) all trans-configuration
etet etet ete t etet etet
9.
adaNylon is an example
s aof
s
da s
ada s
ada s
ada
ww a) polyamide ww b) polythene ww c) polyester ww d) poly saccharide ww ww
10. Terylene t t is an example of.ni.entet .ani.ente

t
.ani.ente
t
.ani.ente
t
l i.ni.ene
a l a lia l a l ail l ail l a i
l
sas saas adsaas saas sas
.
w p.apdaada a) polyamide .wp.apdaadb) polythene .
w p.apdac) polyester .wpad)
. pdaad
polysaccharide .
w p.apdaada
w w w w w w
ww ww ww ww ww ww
11. Which is the monomer of neoprene in the following?
t t t t t t t t t t
ww ww ww ww ww ww
t t t t t t t t t t
ww ww ww ww ww ww

Padasalai.Net
ada aada ada ada ada
w.wp.apda12. Which one ofwthe .wp.apdfollowing is a .wp.apda
bio-degradable
w polymer? w .wp.apda w .wp.apda w
ww ww ww ww ww ww
a) HDPE b) PVC c) Nylon 6 d) PHBV
tet
.ani.enstick
t
.ani.ente have a coating
t
.ani.enatepolymer, whoselamonomer .ani.ente
t
.ani.ente
t
13. Non
l ail cook wares a i
l
generally
l l a i
l
of i
l is l a i
l
sas sas sas sas sas
.
wp.apdaada .
w p.apdaada .
w p.apdaada .
w a) ethane www w w d) 1,1,2,2-tetrafluoroethane w w
ww ww
b) prop-2-enenitrile c) chloroethene ww ww ww
14. Assertion:
tet 2-methyl-1,3-butadiene
tet is the monomer
tetof natural rubber t t t t
adsasReason: Natural rubber adsas is formed through sas
adanionic adsas
addition polymerisation. adsas
ww ww ww ww ww ww
a) If both assertion and reason are true and reason is the correct explanation of assertion.
ntet assertion andareason
b)ail.aifni.eboth t t
il.ani.ene are true but areason a
t t
il.ani.eneis not the correct a .ani.ente
t
ilexplanation of assertion. a
t t
il.ani.ene
a sl asl sl a sl a sl
w.wp.apda c) Assertion iswtrue .wp.apdabut reason is false. w.wp.apda w .wp.apda w .wp.apda w
ww ww ww ww ww ww
d) Both assertion and reason are false.
n.entet
lail.ai lail.ai drug is n.entetl
etet
ail.ani.n l
etet
ail.ani.n l
etet
ail.ani.n
15.
asaasAn example of antifertility
asaas s
ada as s
ada as s
ada as
d d
ww ww
a) novestrol b) seldane ww c) salvarsan ww d) Chloramphenicol ww ww
16. The edrug

tet used to induce sleep
etet is t t t
l a i
l.ani.ente l a i
l .ani.ente l a i
l .ani.ente
sas saasbithional dsaachloroquine
s dsaas sas
.
w p.apdaada a) paracetamol.wp.apdaadb) .
w papdaac)
. .
w p. pdaaequanil
ad) .
w p.apdaada
w w w w w w
ww ww ww ww ww ww
45
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
enet t .ni.ene t t t t t t t t
17.asWhich aslaisilaa co-polymer? a l a il.ani.ene a l a il.ani.ene a l a il.ani.ene
adsa adsa adsa s asa s adsa s
w .wp.apda a) Orlon w .wp.apda b) PVC w .wp.apdac) Teflon w pdad
.wp.ad) w .wp.apda w
ww ww ww ww PHBV ww ww
18. The polymer used in making blankets (artificial wool) is
ada a) polystyrene adaadb)
s a PAN
s c)
adapolyester
s d)adpolythene
s
a s
ada
w .wp.apda w .wp.p w.wp.apda w .wp.apda w .wp.apda w
ww ww wwpolymers, which of the
19. Regarding cross-linked or network ww following statement wwis incorrect? ww
a) iExamples t are Bakelitei.and t

ni.entemelamine t t t
l a l .ni.ente
a l a l a l ail.ani.ente l ail.ani.ente l a i
l .ani.ente
sas saas sas sas sas
.
w p.apdaada b) They are formed
.
w p.apdaadfrom bi and .
w .apdaada monomers .wp.apdaada
tri-functional
p .
w p.apdaada
w w w w w w
ww ww ww ww ww ww
c) They contain covalent bonds between various linear polymer chains
d)
l a ni.entet contain strong lcovalent
il.a
They a
t t
il.ani.ene bonds in their l a .ani.ente
ilpolymer
t
chain l a
t t
il.ani.ene l a
t t
il.ani.ene
a
adsas a
adsas a
adsas a
adsas a
adsas
ww 20. A mixture w ofwchloroxylenol and terpinecol ww acts as (NEET) ww ww ww
a) antiseptic
t t
b) antipyretic
t t
c) antibiotic
t t
d) analgesic
t t t t
adsa s
ADDITIONAL QUESTIONS: adsa s adsas adsa s adsa s
ww ww ww ww ww ww
1. Which one of the following is an antibiotic?
etet
(a) erythromycin (b) atenolol etet (c) amlodipine etet (d) propranolol etet etet
Padasalai.Net
aa aa daada aa ada
.wp.a2. w .apdad
.wpfollowing is an .wp.aptbr
example
w antihypertensive w .apdad
.wpdrug? w .wp.apda w
ww ww ww ww ww ww
(a) atenolol (b) amoxicillin (c) cefixime (d) tetracycline
tet
.ani.enone i.ente
t
.aninhibits ni.entet
.agrowth? .ani.ente
t
.ani.ente
t
3. sWhich
asl ail of the following l a i
l the bacterial l a i
l l ail l a i
l
sas sas sas sas
.
wp.apdaada .
w p.apdaada .
w p.apdaada
w w (b)w sulphanilamide (c) w w w
ww (a) p – aminoww benzoic acid ww wwfolic cid (d) sodium wwbenzoate ww
4. Which of the following is needed by many bacteria to produce folic acid? tet
n entet n entet n entet en t t
il.ani.ene
as
i
lal.a i.
as
i
lal .
a i .
as
i
lal .
a i .
aslail.ani. a l a
asa a s
a s
a
ad TNB a s
a adsas
w.w p.apdad(a) PABA w.wp.apdad(b) DHPS p.apda(c)
w.w p.a(d)
pdadGTN
w.w w .wp.apda w
ww ww ww ww ww ww
5. Which one of the following binds to the receptor site should inhibit its natural function?
t t t t t t t t t t
a l a il.ani.ene
(a)aantacids
a l il.ani.ene
(b)aantioxidant
a l il.ani.ene
(c) antibiotics
a a l il.ani.ene
(d) antagonists
a a l a il.ani.ene
asa s asas asa s adsa s adsa s
.wp.a6. w .apdad
.wpfollowing is used as an
w pdad
.wp.aantacid? w .wp.apda w .wp.apda w
ww ww ww ww ww ww
(a) magnesium hydroxide (b) aluminium hydroxide (c) ranitidine (d) all the above
etet i.ente
t etet etet etet
asl
7. asWhichail.ani.none of the followings aslail.anis used as painkiller? s asl ail.ani.n s aslail.ani.n s asl ail.ani.n
da ada ada ada ada
ww (a) lodoformww (b) chloropicrin ww (c) morphine ww (d) coffeine ww ww
t t t t t
l a i
l.ani.ente l a i
l .ani.ente l a i
l .ani.ente
sas sas sas sas sas
.
w p.apdaada .
wp.apdaada .
w papdaada
. .
w p.apdaada .
w p.apdaada
w w w w w w
ww ww ww ww ww ww
46
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
.ni.ene t t .ni.ene t t .ni.ene t t

.ani.ene disorder and lail.ani.ene t t t t
8. Which
aslailais used to treat stress,
aslaila anxiety, depression,
aslailsleep as
w .wp.apda schizopherenia?w.wp.apda w .wp.apda w .wp.apda w .wp.apda w
ww ww ww ww ww ww
(a) Tranquilizer (b) antibiotic (c) analgesic (d) opioids
9. adWhich
s
a one of the followings
ada is an exampleafor adatranquilizer?
s s
ada s
ada
w .wp.apda w .wp.apda w.wp.pda w .wp.apda w .wp.apda w
ww (a) cimetidine ww (b) diazepam ww (c) histamineww (d) PABA ww ww
10. Identify t medine that is n

t the used t t to treat stress, anxiety.t t depression and.nschizophrenia.
t t t
i.ni.ene
l a l a i. i.ene
l a l a i.ni.enel a la i i.ene l a l a l a i
l .ani.ente
saas saas adsaas aas
daadsadenosine sas
.
w p.apdaad(a) valium .
w p.apdaad(b) cimetidinc .
w p.apda(c) chiorofom .wpa(d)
. p .
w p.apdaada
w w w w w w
ww ww ww ww ww ww
11. Which one of the following is used to reduce fever and prevent platelet coagulation?
etet
il.ani.n etet
il.ani.n etet
i.ni.n
t t
il.ani.ene etet
.ni.n
adas(a)
aslaantibiotic ada s(b)
aslaantiseptic
ada
(c)saantioxidant
adaslala a
adsas
l a aslaila
(d) santipyretic
ww w
12. Which of thewfollowing are used forww ww pain of terminal cancer?
post operative pain and ww ww
(a) morphine,
t t
codeine t t (b) ibuprofen, t t aspirin t t t t
n
il.ai e
. ne n
il.ai e
. n e n
il.ai e
ads(c)
a methyl salicylate, dsa
asalicylic acid adsahistidine, ranitidine
(d) adsa adsa
ww ww ww ww ww ww
13. Which one of the following is an local anaesthetic?
(a) lidocaineetet (b) Propofol etet etet
(c) isoi.aflurane (d) ibuprofen etet etet
ail.ani.n ail.ani.n al ni.n ail.ani.n ail.ani.n
Padasalai.Net
aa aa a
aadgeneral ada ada
.wp.a14. w .apdad
.wpfollowing is an .wp.apd
example
w of .wp.apda
anaesthetic?
w w .wp.apda w
ww ww ww ww ww ww
(a) propofol (b) isoflurane (c) ranitidine (d) omeprazole
t t t t t
ail
15. sIdentify
l .ani.entethe intraveneouslageneral
i
l.ani.ente anaesthetics? l a i
l .ani.ente
as sas sas sas sas
.
wp.apdaada .
w p.apdaada .
w p.apdaada .
w w w w w w
ww (a) milk of magnesia ww ww
(b) lidocaine ww
(c) omeprazole ww
(d) iso fharane ww
16. Which one
tet of the following is tused
et
to provide relief tfrom
et
the allergic effects?
tet t t
as cetrizine
ads(a) as ampicillin
ads(b) s
adsaerythromycin
(c) adsas (d) milk of magnesia adsas
ww ww ww ww ww ww
17. Which of the following is used to treat respiratory tract infections, genital, gastrointestinal tract
t
ni.enteinfections? t t t t t t t t
a
andail.askin
l a a l a il.ani.ene a la il.ani.ene a l a il.ani.ene a l a il.ani.ene
adsa s adsas adsa s asa s asa s
w.wp.apda (a) ampicillin w.wp.apda (b) penicillin w.wp.apda(c) terfenadine w.wp.a(d) pdadazithromycin w.wp.apdad w
ww ww ww ww ww ww
18. Which one of the following is used to reduce the risk of infection during surgery?
t t etet n.entet etet etet
(a) l il.ani.ene
apovidone – iodine lail.ani.n (b) lail.ai lail.ani.n l ail.ani.n
s
ada as s
ada as dasaasethynyles tradiol s
ada as s
ada as
ww (c) norethindrone ww ww ww acid
(d) acetyl salicylic ww ww
19. Whicheone
tet is used as preservatives
etet for fresh vegetables
etet and fruits? t t
l a i
l.ani.n l a i
l .ani.ente l a i
l .ani.ente
saas Palmitic acid saas Palm oil adsaasodium
s sas saas
.
w p.apdaad(a) .
wp.apdaad(b) .
w papda(c)
. .
w p.apdaada
meta suiphite (d) sulphur
.
w p.apdaaddioxide
w w w w w w
ww ww ww ww ww ww
47
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
20. Sodium
aslaila salt of long chain il.ani.enebenzene sulphomc
aslaallyl
.ni.ene
aslailaacids are called ……………….
.ni.ene
aslaila a l a il.ani.ene
adsa asa asa asa adsa s
w .wp.apda (a) soap w .
w p.apdad w .
w p.apdad w .
ww ww (b) detergent (c) disinfectant
ww (d)
ww antiseptic ww ww
21. Which one of the following is a natural polymer?
ad(a)
sa cellulose, silk adaad(b) a PVC, Polytheneada(c)
s adaBuna – N, Buna –aSdaada (d) Bakelite, Nylon
s s ad6,6
s
a
w .wp.apda w .wp.p w.wp.p w .wp.p w .wp.apda w
ww ww ww ww
22. Which one of the following catalyst is used in the preparation of high density polyethylene? ww ww
(a) benzoyit t peroxide .ani.ente

t (b) zeigler t
t natta catalyst .ani.ente
t
.ani.ente
t
l i.ni.ene
a l a l a i
l i.ni.ene
l a la l ail l a i
l
saas a
daadsas adsaas sas sas
.
w p.apdaad(c) ammonium per.
w p.apsulphate .
w p.apda(d) hydrogen .w apdaada
peroxide
p. .
w p.apdaada
w w w w w w
ww ww ww ww ww ww
23. Identify the zeiglar natta catalyst.
etet
il.ani.n4 + (C2H5)3AI etet n ) Pb + TiCl
il.an2i.H il.an(c)
t
i.enteAICl3 + HCI et
.ani.entZnCI
il(d)
t t
il.ani.ene
ada s(a)
aslaTiCI ada s(b)
asla(C a
adsas
l a 5 4 4 a
adsas
l a 2 + Cone. HCI
a
adsas
l a
ww ww
24. Which one of w glass reinforcing material
the following is usedwas ww in safety helmets? ww ww
(a) nylon
t t
(b) Bakelite t t (c) terylene t t (d) orlon t t t t
n
il.ai e
. ne n
il.ai e
. n e n
il.ai e
a sl a a sl a asl a asl a a sl a
25.adsWhich
a adsa
one of the following is used to prepare adsa combs and pens?adaadsa adsa
w.wp.apda w .wp.apda w .wp.apda w.wp.p w .wp.apda w
ww ww ww ww ww ww
(a) navolac (b) soft Bakelite (c) hard Bakelite (d) neoprene
26. Which tet of the following.nis
enone et for making unbreakable
entused entet crockery? i.ani.entet etet
lail.ani. lailai. lail.ani. ail.ani.n
Padasalai.Net
a a lal
a a a l
p.apdaadsas p.apdaadsas p.apdaadsas p.a
p daadsas .wp.apda
s
ada s
.
ww (a) phenol formal
.
ww dehyde .
ww (b) melamine formal
.
ww dehyde w w
ww ww ww ww ww ww
(c) urea formal dehyde (d) navolac
ail ntet
.ani.e a i
l .entet
.anirequired a i
l
t
.ani.ente – S rubber? lail.ani.ente
t
a i
l .ani.ente
t
27. sWhat
asl are the raw materials
sasl to prepare sasl Buna sas sasl
.
wp.apdaada .
w p.apdaada .
w p.apdaada .
w ww w w + methanal w w
ww (a) phenol + wmethanol ww ww
(b) melamine ww ww
(c) styrene
tet + butadiene (d)teadipic acid + methanal
i.ani.en i .
a ni entet
. i .
a ni en t
. t t
il.ani.ene
t t
il.ani.ene
as
28.adsWhich adsas element is used
one of thepfollowing sasvulcanization of rubber?
adin adsas adsas
w .wp.apda w .w.apda w.wp.apda w .wp.apda w .wp.apda w
ww ww ww ww ww ww
(a) oxygen (b) nitrogen (c) carbon (d) sulphur
t t t t t t t t t t
ww ww ww ww ww ww
etet etet n.entet etet etet

l ail.ani.n lail.ani.n ----ALL THE lail.ai lail.ani.n l ail.ani.n
s
ada as s
ada as asaasBEST----
d s
ada as s
ada as
ww ww ww ww ww ww
t t t t t
l a i
l.ani.ente l a i
l .ani.ente l a i
l .ani.ente
sas sas sas sas sas
.
w p.apdaada .
wp.apdaada .
w papdaada
. .
w p.apdaada .
w p.apdaada
w w w w w w
ww ww ww ww ww ww
48
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
t t t t t t tet 1 cm-1 t t
a l a il.ani.eneANSWER KEY a l a il.ani.ene 9. (c) 1.0 x 109lail.ani.ene
a a l a il.ani.en(c)
18.
a l a il.ani.ene
adsa s adsa s asa s s
adsa 19. (d) 1.74 x 10-12 adsa s
w .wp.apda w .wp.apda 10. w(b) pdad
.wp.a5.09 w .wp.apda w .wp.apda w
ww ww
8. IONIC EQUILIBRIUM ww ww 20. (b) E1 w >w
E2 ww
11. (c) 4
21. (d) HBrO
1. (d) 5.619 etext 10-12 mol3 L-3 i.ani.entet 12. (d) 6.63 etet tet – 46.32 KJ mol-1 .ni.entet
il.ani.en(a)
a l ail.ani.n a l al a l ail.ani.n a l a22. laila
s s
2.ada(d) (iii) 75 mL M5 HCIap+da25 s
ada s s
aa s s s
ada 23. (b) 15.8 adsaas
w .wp.apda w .wp. 13. w(a) pdad
.wp.a9.4 a
w.wp.p
da a
w.wp.p
da
w
ww mL M5 NaOHww ww ww 24. (a) Y will wwoxidize X and not Z ww
14. (c) 11
3. (c) 1.08 x 10-10 mol2 L2 25. (a) 0.80
t t ni.entet t t
4. (a) 0.5 i .ani.enxte10-15 i .ani.ente 15. (a) pH will increase
. .ani.ente .ani.ente
l a l
as OH– and F–, sas l a l aslaila sasl ail a l a i
l
daadsa(c)
ap5. apdaada 16. (d) d
a10aad
-9 s
a apdaada daadsas
aQUESTONS
w .wp.
respectively www
.wp. w.wp.p w.wp. ADDITIONAL
w .
w p. p w
ww ww
17. (a) CH3COOH + CH3COONa
ww 1. (c) Redox ww reactions ww
6. (c) 100 mL of 0.1M HCI +
2. (b) Ω m
200 .mL toft 0.1M NH4OH t t 18. (a) remains constant
etet tet t t
a l a ilani.ene a l a il.ani.ene a lail.ani.
n
a l a il.ani.en(a)
3. Ohm metre
a l a il.ani.ene
s PF3
7.adsa(b) adsas s
2a
daad L
19. (d) amol s
-2
adsas 4. (b) Siemen (S)adaadsas
w .wp.apda w .wp.apda w.wp.p + 2 w .wp.apda w.wp.p w
ww 8. (a) BF3 ww w
w (a) [Ag ] [CrO4-2]
20. ww 5. (d) Ohm m w w
-1 -1 ww
9. (b) basic, acidic, basic
21. (c) NH4OH + NH4tCIt 6. (a) Sm2g equivalent-1
10. (b) 0.013% t t t t tet wheat stone bridge.ni.entet
il.ani.ene il.ani.ene il.ani.ene il.ani.en(b)
7. ia
11. asl a
daadsa(a) 3.7 x 10-2 asaa sl a
a a
sasl a
a a
sa sl a
a saaslal
w .wp.ap12. w .wp.apdad d
a d
.ap ELECTROCHEMISTRYw.wp.ap
w.wp9.
da d 8. (c) Debye-Huckel
a
w.wp.p
da dand
w
ww (b) 1.6 x 10-9 w Mw ww ww wwequation ww
Onsagar
13. (a) 2 x 10-3M
14. (d) Theentmolar 1. (c) 6.022 x 1022 9. etet
t solubility of etet t t t
.ani. e ail.ani.n i.ente
il.annon il.ani.n(d) all the above alail.ani.ene
Padasalai.Net
a l a il a l 2. (b) – 2.69aand l a a l a10.
s
ada s
MY in water is less than s
ada s s
ada s s
ada s aas s
w .wp.apda that of NY3 w .wp.apda w .wp.apda
spontaneous w .wp.apda 11. (b) Agar-Agar w pdad+ Na2SO4
.wp.agel w
ww ww ww(c) 1.10V
3. ww ww
12. (a) either a (or) c
ww
15. (d) 12.65
16. (d) 1:10 4. (b) 11.52 S cm2 mol-1 13. (b) 1.107 Volts
t t tet tet t
l a il.ani.ente l a il.ani.ente 5. (c) 390.7 alail.ani.en l a i
14.
l.ani.en(b) zero l a il.ani.ente
as 9
17.s(a) sas ss sas sas
.wp.apdaada .wp.apdaada 6. (b).wp .apdaada carried by one .wp.apdaada 15. (c) Platinum.wp.apdaada
charge
w 18. (c) H3PO4 w w w w w
ww ww wwmole of electrons ww 16. (b) – Nfe ww ww
19. (c) HPO42-
20. (b) strongly 7. (a) 5F 17. (c) negative
ene t t acidic ene t t te t tet t t
a lail.ani. a lail.ani. 8. (b) 2
a l a n
il.ai. e n
a l a il.ani.en(b)
18. 96500 C a l a il.ani.ene
sa s sa s asas adsas 19. (a) Nernst equation adsas
adaad adaad .apdad minutes
9. (b).p107.2 .wp.apda .wp.apda
w w.wp.p21. w w.wp.p w w w w w
w 22. C w ww(c) 3.75 x 1020
10. ww ww ww
23. (b) 5.55 x 1010 11. (b) 0.002N
t t t t t 20.etet t t
l il.ani.ene QUESTONS alail.ani.ene
ADDITIONAL
a 12. (c) PbSO4 on l a .ani.ente is
ilanode l a il.ani.n(a) m = Zit
21. l a il.ani.ene
a
adsa s adsas adsaas adsaas adsaas
ww .p.apda1. (d) either (b) or (c) .p.apda
ww w .wp.apda to Pb.
reduced
w .wp.apda .wp.apda
22. (b) electrowchemical w
ww ww ww(a) I and IV
13. ww ww ww
2. (a) H2O equivalent
14. (d) Zinc has higher negative
t–
3. (b) HCIen+teCI 23. (b)t Li – ion battery
etet e tet than te
il.ani.en(b) etet
s asl ail.ani3+. s aslail.ani.n electrode potential
s asl aila. ni . n
s asl a24. non – rechargeable s asl ail.ani.n
da(b) Cr
a4. ada iron ada ada ada
w.wp.apda w .wp.apda w .wp.apda w .wp.apda 25. (a) Zinc, Graphite
w.wp.apda rod with w
ww 5. (c) 1 x 10-14 w
w ww(d) both assertion and ww
15.
MnO2 w
w ww
reason are false.
6. (a) 3 26. (b) NH4Cl + ZnCl2
t t et + 4e– tet t
l a i
l .ani.ente l ail.ani.ente 16. (a) O2(g) + 2H2O
l a il.ani e
. nt(l)
l a i
27.
l.ani.en(c) Zinc amalgamated l a i .ani.ente
with
l
as NaOH + NaCI
7.s(d) sas sas sas sas
.
w p.apdaada .
wp.apdaada .wp .apdaada
→ 4OH–(aq)
.wp.apdaada mercury . wp.apdaada
w w w w w w
ww 8. (a) OH– and HSO ww4 ww(b) 6.25 x 10 -6
17. ww ww ww
49
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
t t
e t t 20. (d) (iv) (iii) (ii).(i) t t t t t t
a il.ani.enmixed
28. (a)laHgO with
a l a il.ani.ene a l a ilani.ene a l a il.ani.ene 11. HYDROXY
a l a il.ani.ene
adsa s adsa s adsa s adsa s daadsa s
w .wp.apda graphite. w .wp.apda w .wp.apda w .wp.apda COMPOUNDS
w .wp.apAND ETHERS w
ww 29. (a) 1.35 V ww wwADDITIONAL QUESTONS ww ww ww
30. (a) Paste of kOH and ZnO 1. (c) 400 kJ/mole 1. (a) CH3 CH (OH) CH2CH3
t t t t 2. (b) (iii) onlyail.ani.ente
t tet etet
a il.ani.enestorage battery alail.ani.ene
31. (c)aLead
l a l a l il.ani.en(c)
a2. methyl propanoate a l ail.ani.n
s s
daada(a) Lead plate bearing s
ada s aas s s
ada s s
ada s
w .wp.ap32. w .wp.apda 3. (a).pNH
w w .apda3 d w .wp.apda 3. A w .wp.apda w
ww PbO2, Spongywlead w ww(c) Permutit
4. ww w
4. (c) 2 –wchloroethan – 1 – ol ww
33. (c) Aqueous KOH 5. (b) Silica gel and NaHCO3
nte t t 6. (c) Nickel i.ani.entet tet t
34. (b) Fe
l a i
l .ani2.eO 3.xH2O
l a il.ani.ente l a l l a i
5.l.ani e
. nc) 4 – nitrophenol l a il.ani.ente
as a adsaas sas sas
p daadsa(c)
ap35. Galvanisation papdaadsas 7. (b)pFe, apdaMo p apdaada 6. b p apdaada
.w .
w 36. (c) 0.66 g w .w . w .w . w .w . w .w . w
ww ww ww(d) Chromatography ww
8. 7. (a) Phenol ww ww
9. (b) Decomposition of 8. (c) trichloro methane
t t
.ani.ene CHEMISTRY lail.ani.ene t t te t tet t t
10. iSURFACE H2O2 in the presence n
il.ai. en of Pt il.ani.en(Riemer Tiemann reaction) il.ani.ene
daada saslal sas
ada catalyst a
adsas
l a a l a
adsas 9. (b) (CH3)2 C =aCdaa(CH3)2 a
dsas
l a
w .wp.ap1. (c) 1/n, log k w .wp.apda w .wp.apda w .wp.apda w .wp.p w
ww ww ww(a) As2O3
10. ww 10. (a) 4 –wchloro w – 2, 3 – ww
2. (b) increases with increase
11. (c) H2S dimethyl pentan – 1 – ol
in temperature tet
3. s(d) l il.ani.en∆H
a∆G, and ∆S all are saslail.ai
n.entet 12. (a) Co
l a
t t
il.ani.ene l a
tet if both assertion and.ni.entet
il.ani.en(a)
11. laila
ada as ada 13. (a) Ethanol adsaas adsaas adsaasreason
.wp.apda negative. .wp.apda w.wp.p
a da
w.wp.p
a da reason are true
.p.ap daand
ww
w
ww
w
ww(b) activation energy ww
14. is the w ww w explanation
correct ww
w
4. (c) liquid in gas
15. (c) diastase of assertion.
5. (a) if botht assertion and
ete etet 16. (a) Fe°/Pd° n.entet e tet ethanol t t
il.ani.ene
ail.ani.nare true and reason ail.ani.n il.ani.n(d)
12.
Padasalai.Net
reason
a l a l a l a il.ai a l a a l a
s
ada s s
ada s 17. (c) Fogdada s s s s
ada 13. (c) Williamsonaether s
ada s
w .wp.apda is the correct explanation w .wp.apda 18. w
(c)
.apa
.wpBredigs arc method w .wp.apda w .wp.pda w
ww of assertion w
w ww ww ww
synthesis ww
19. (c) ultrasonic dispersion 14. (a) C6H5 – OH (phenol)
6. (b) It is true, Fe3+ ions
t t 20. (d) peptisation entet tet if both assertion and.ni.entet
l ai l.ani.ente blood which is a lail.ani.ente
coagulate l a il.ani. l a
15.
il.ani.en(a) laila
sas sas saas
21. (c) coagulation saas saasreason
apdaadanegatively charged.wsol apdaada aad ad aad ad reason are true
.p.apad a
and
d
w .wp.
ww
p. 22. w.wp.p w.wp.p ww w explanation w
ww 7. (b) emulsion w ww(b) 1 mμ to 1 μm diameter ww is the wcorrect ww
23. (d) rod like of assertion.
8. (b) Gel – butter
t t t t 24. (a) AS2S3 t t tet methanol t t
9. (d)
a l a il.ani.ene
AI3+
a l a il.ani.ene 25. (c) scattering a l a ni.ene
il.aof light a l a
16.
il.ani.en(c) a l a il.ani.ene
s
daadsa(b) asas asas adsas 17. (d) ethan -1, 2-diol adsas
w .wp.ap10. CH3 – (CH2)15 –.w
w .apdad
pNH2 .apdad
w.wpelectrophoresis
26.w(c) w .wp.apda w .wp.apda w
ww ww
11. (d) Tyndall effect-scattering w ww 18. (c) Kolbe wwreactions ww
27. (c) Electro osmosis 19. (d) methoxy ehane
of light
t t t t 28. (d) Tollen’s test tet 20. t t
A t t
12. (b)
a l a il.ani>.enIIe> I > IV
III
a l a il.ani.ene 29. (c) Alumsa containing
a
en
lail.ani. Al3+ a l a il.ani.ene a l a il.ani.ene
s
daadsa(a) Nitrocellulose .p.apdaadsa s a s s
adsa 21. (b) SN2 reaction asa s
w .wp.ap13. ww .apdad
w.wpchromium
30.w(a) salt w .wp.apda w .wp.apdad w
ww 14. (a) Hydrolysiswofwsucrose in w ww 22. (b) violet wwcolour ww
31. (a) Ammoniacal AgNO3
presence of all HCl
t t 32. (d) the measure of
il.ani.en(i)e (ii) (iii) etet etet tet
eADDITIONAL QUESTONSentet
15. (a)a(iv)
s asl s asl ail.ani.n protective s asl ail.ani.n of a
power s aslail.ani.n s aslaila
.ni.
daada(a) III > II > I
.wp.ap16. .wp.apda
ada ada ad a ada ad a 1.
ada ad a
w w w.wp.p colloid
lyophillic w.wp.p w.wp.p w
ww 17. (a) ∆S decreases ww– ∆S is –ve ww ww ww ww
18. (d) x/m = mPT
t t t 2. t t t
19. (a) Both
l a il.ani.entemagnitude and l a il.ani.ente l a i
l.ani.ente l a i
3.
l
e
.ani.en(c) Ethane – 1, 2 – diol
l a i
l .ani.ente
sas a
daadsas sas sas dsaas
.wp.apdaadasign of the charge on .wp.
the
ap .
w papdaada
. .
w p.apdaada 4. (a) Propan –.wp2.ap–daaol
w w w w w w
ww ion. ww ww ww 5. (b) Ethanol ww ww
50
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
t te – p ropan – 2 lail.ani.ene
t t .ani.ene t t tet Catalyst poison t t
6. (b)
a l a2il.an–i.enmethyl
a
12. CARBONYL
lailCOMPOUNDS
aa a l a il.ani.en(b)
3.
a l a il.ani.ene
s
daadsa– ol daadsas daadsas s
adsa 4. (c) Gattermann adsa s
ww. p.ap ww. p.ap 1. A
ww. p.ap w .wp.apda w .wp.apdakoch w
ww 7. (c) Prop – 2 – w enw– 1 – Oi ww ww ww
reaction ww
2. (d) Nucleophilic addition
8. (c) Cold dilute alkaline 3. (c) hydrazine in presence of 5. (b) Benzophenone
etet etet e te t tet Anhydrous AlCl
il.ani.en(c) etet
s
KMnO
asl ail.ani.4n s asl ail.ani.n slightly acidic
s asl ni.n
ail.asolution s asl a6. s
3 ail.ani.n
asl
daada(a) Conc. HCl + Anhydrous
.wp.ap9. .wp.apda
ada
4. (b) .wpVictor
aa
.apdad meyer test .wp.apda
ada 7. (b) Hexamethylene
.wp.apda
ada
w w w w w w
ww ZnCl2 ww ww(c)
5. ww ww
tetramine ww
10. (c) Blue hexamethylenetetraamlne 8. (a) Urotropine
l a l .entet
11. (c) Ei.a1nimechanism
l a il.ani.ente
t
6. A l a il.ani.e nte t
l a9.
il
tet Nitration of urotropine
.ani.en(c) l a il.ani.ente
t
as sas a sas sas
. p. daadsa(a)
ap12. 1° < 2° < 3°
. p.apdaada 7. (a) . pif
. daadsasassertion and
apboth . p.apdaada 10. (c) Propane.wp.apdaada
w
w 13. (b) Swern oxidation w w w w w w w reaction w
ww ww wwreason are true and reason ww 11. (d) Cannizaro ww ww
14. (a) Esterification is the correct explanation 12. (c) Claisen – schmidt
t t t t t t tet t t
a l il.ani.ene
15. (d) Oxirane
a a l a il.ani.ene of assertion.
a l a il.ani.ene a l a il.ani.encondensation a l a il.ani.ene
s 1, 4 – dioxane
adsa(a)
16. adsas asas > CH3COOH adaadsas 13. (c) Benzoin adaadsas
w .wp.apda w .wp.apda 8. (a).w
w .apdad
pFCH2COOH w.wp.p w.wp.p w
ww 17. (a) Methanal ww ww> BrCH2COOH > ww 14. (a) Peridn’s ww reaction ww
18. (a) Nitroglycerine CICH2COOH 15. (b) C6H5 CH = N – C6H5
19. (b) Glyceric t t t t t t tet Pyridine t t
a l a il.ani.ene acid and a l a il.ani.ene 9. (c) benzeneladiazonium
a il.ani.ene a l a
16.
il.ani.en(b) a l a il.ani.ene
s
adsatartronic acid adsa s adsa s s
adsa 17. (a) lodoform test adsa s
w .wp.apda w .wp.apda w .wp.apda
chloride
ww 20. (a) 1° alcohol w >w 2° alcohol > ww(c) Hell – Volhard – Zelinsky
10. ww ww
18. (c) Paraldehyde ww
3° alcohol reaction 19. (c) CH3COCH3
21. (c) Pyrogallol t t t t etet 20.e(c) tet HeII – volhard – zelinsky etet
il.ani.ene il.ani.ene 11. (a) acetylchloride ail.ani.n ail.ani.nreaction ail.ani.n
Padasalai.Net
22. s asl a s asl a s asl s asl s asl
ada(b) 1, 2 – dihydroxy adaada ada ada ada
w .wp.apda benzene w.wp.p w .w.apda acid
12. (a)pformic
ww ww wwB
13. ww ww ww
23. (c) Dow’s process 21.
14. (a) but – 3 – enoicacid 22. (c) F – CH2 – COOH > CI –
24. (d) Benzene t t tet tet t
l a il.ani.ente l a il.ani.ente 15. D
l a il.ani e
. n
l a il.ani.enCH 2COOH > Br – CH2lCOOH a il.ani.ente
as Schotten – Baumannadsaas a sas sas
25.s(b)
apdaada ada 16. A apdaadsas apdaada apdaada
w w .wp. reaction w w.wp.p w .wp . w .wp. > I – CH2COOH
w .wp . w
w w ww(b) if both assertion andww
17. ww
23. (b) Transesterfication ww
26. (d) 2, 4 , 6 – trinitro phenol reason are true but reason 24. (c) Sodium benzoate
27. (c) Kolbe’s t t Schmitt reaction .ni.entet t t tet t t
il.ani.ene – Tiemann ia is not the correct n
il.ai. en e il.ani.en(d)
25. Acetic anhydride lail.ani.ene
28.
d ad a l
(c)
sas aRlemer
d adsaaslal explanation a l a
adsas of assertion. a l a
adsas 26. (d) Benzyl alcohol a
adsas
aa
w.wp.p reaction w.wp.p
aa
w .wp.apda w .wp.apda w .wp.apda w
ww ww ww(b) cannizaro reaction ww
18. ww
27. (c) Nucleophilic addition ww
29. (b) Salicylaldehyde 19. (a) Phenylmethanal 28. (a) (CH2)6N4
30. (b) P – hydroxy azo
i .an i entet
. t t
il.ani.ene
20. (b) Fehling’s solution
il.ani.ene
t t t t
il.ani.ene
t t
il.ani.ene
l a
benzene
as l asl a asl a asl a asl a
daadsa
.wp.ap31. .wp.apda
adsa 21. (c) phenyl
.wp.apda
adsa methanol and
.wp.apda
adsa 13. ORGANIC
s
aada
.wp.apdNITROGEN
w (b) Methanal w w w w w
ww ww wwsodium benzoate ww w
wCOMPOUNDS ww
32. (c) Methoxy benzene 22. (d) Wolf kishner reduction
33. (d) Diethyl t ether 1. e(a) t Sn / HCl
.ani2.ente etet 23. C
.ani.ente
t
.ani.nte il.ani.ene
t t
34.s(c)
asl a i
SNl s asl ail.ani.n 24. (d) formation s asl a il s asl a i
2.l (b) potassium salt s a
ofsl a
daada ada ada of ada aa
w .wp.ap35. (b) P – bromoan isole w .wp.apda w .wp.apda
intermolecular H – w
bonding .wp.apda phthalimide w .apdad with
.wptreated w
ww ww ww ww ww ww
36. (b) Ethoxy ethane chlorobenzene followed by
37. (c) comparatively t inert t ADDITIONAL QUESTONS t hydrolysis
t with aqueous tet
ete ete .ani.ente .ani.ente e
s asl ail.ani.n s asl ail.ani.n l a
1. (a) Propads–aas2 – enal
il s asl a il NaOH solution s asl ail.ani.n
adaada adaada .apda
aa
p.apdad 3. (a) CH3CONHCH3 .p.apda
ada
w w.wp.p w w.wp.p w.wpRosenmund
2. w(d) reductionww.w ww w w
w w ww ww ww ww
51
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
t t t t 10. (d) Gabriel phthalimide t t tet Cytosine and Thiamine t t

4. (d)
a l a il.ani.eneassertion and
both
a l a il.ani.ene a l a il.ani.ene a l a il.ani.en(c)
14.
a l a il.ani.ene
adsa s adsa s adsa s s
adsa 15. C adsa s
w .wp.apda reason are false w.wp.apda w .wp.apda
synthesis
ww 5. (c) methanamine ww ww(b) Sabatier – mailhe ww
11. w
16. (d) α –whelical backbone ww
6. (c) (CH3)3CNO2 – method 17. (b) Vitamin K
t t etet t t tet D – Glucose etet
a l il.ani.ene
30anitroalkane
a l ail.ani.n 12. (a) Alkyl amines
a l
e e
ail.ani.n> Aralkyl a l il.ani.en(d)
a18. a l ail.ani.n
s s
daada(c) Schotten – Baumann s
ada s s
ada s s s
ada 19. (c) Denaturation s
ada s
w .wp.ap7. w .wp.apda w .wp.apda > Ammonia > N – w.wp.apda
amines
w .wp.apda makes w
ww reaction ww wwaralkylamine > Arylamine ww protein ww more active ww
8. (c) schiff ‘s base 13. (c) Schotten – Baumann 20. (b) It does not react with
9. B i.ani.entet i .ani.ente
t reaction i .ani.e nte t
i
tet
.ani.enGrignard reagent i .ani.ente
t
asl a l sas l a l sas l a l sas l a l sas l a l
. p. daadsa(d)
ap10. acetanilide
. p.apdaada . .apdaada
14. (c) pDiazotisation
. p.apdaada 21. (a) TACGAACT . p.apdaada
w
w 11. (d) N(CH3)2H >wN(CH3)H2 w w w w w w w w w
ww w > ww(b) Carbylamine reaction
15. ww 22. (c) Protein ww ww
N(CH3)3 > NH3 16. (a) mustard oil reaction 23. (b) Anomers
t t t t t t tet Both (a) and (b) .ni.entet
il.ani.ene and H2O
12. (a) H3PO2 il.ani.ene 17. (c) Sand meyer ene
il.ani.reaction il.ani.en(d)
24. ia
13. a l a
s C6H5 – OH
adsa(a) a
adsas
l a
18. (b) Gombergad a l a
sas reaction adsas 25. (a) Alanine dadsaaslal
a l a
w .wp.apda w .wp.apda w.wp.p
aad
w.wp.p
aad
w.wp.p
aa
w
ww ww
14. (d) 1, 3 – dinitrobenzene ww(c) insecticide
19. ww ww ww
15. (d) N – methylbutan – 2 – 20. (c) Baltz – Schiemann ADDITIONAL QUESTONS
amine t t t t reaction t t 1. tet 16 isomers t t
a l a il.ani.ene a l a il.ani.ene a l a il.ani.ene a l a il.ani.en(b) a l a il.ani.ene
16. s
adsa(b) blue solution adsa s s
adsa amine
21. (c) Dimethyl s
adsa 2. (a) 4 adsa s
ww 17. (d) triethyl amine ww (3°amine) ww(b) 2° amine
22. ww 3. (a) Glucose ww ww
18. (b) 2, 4 – dimethyl aniline 23. (d) both aliphatic and 4. (b) 112°, 18.7°
19. (a) Ethanol, t t hydrozylamine .ni.entet aromatic 1° amine t t 5.n.en(a) t t epimers t t
il.ani.ene il.ani.ene il.ai e il.ani.ene
Padasalai.Net
a l a laila l a l a l a
d s s
adahydrochloride d adsaas s as
14.adBIOMOLECULES
a s as
ada 6. (a) Sorbital + mannitol s
ada as
a a
w.wp.p20. (d) 3 – (N, N – Dimethyl w.wp.p
a a
w .wp.apda w .wp.apda 7. (b) 3 w .wp.apda w
ww ww ww(c) D(-) Fructose
1. ww ww ww
amino) – 3 – methyl 2. (d) D – Erythrose, D – 8. (a) glycosidic linkage
pentane t t t L– 9. en(b) t invertase t
l a il.ani.ente l a il.ani.ente Threose, L – Erythrose,
l a il.ani.ente l a il.ani. te l a il.ani.ente
21.sB as sas sas sas 10. (d) Sucrose dadsaas
apdaada apdaada Threoseapdaada apdaada aa
.wp.
w 22. (b) Benzyl alcohol w .wp. w .wp. w .wp. 11. (c) Iodine w.wp.p w
ww ww ww(b) Sucrose
3. ww ww solution ww
23. A 4. (a) Heptanoic acid 12. (c) Glycine
24. B t t t t t t 13.e(b) tet Myoglobin t t
25. a
B l a il.ani.ene a l a il.ani.ene 5. (a) If both accretion
a l a il.ani.ene and a l a il.ani.n(b)
14. folic acid a l a il.ani.ene
adad asas adadasas reason dsastrue and reason p.apdaadsas
aare adsas
w.wp.p w.wp.p w .wp.apda w .w 15. (c) guanine w .wp.apda w
w w w w wwis the correct explanation ww ww ww
ADDITIONAL QUESTONS of assertion 16. (a) Insulin
1. (c) Dopamine t t t t 17. (d) Estrogen
il.ani.eneethane il.ani.ene
6. (c) DNA RNA Proteins
i .ani entet
. i .ani entet
. t t
il.ani.ene
2. sa(c)
aslaNitro a sl a asl a l asl a l
18. (d) base, sugar and asl a
daad adsa 7. (a) Peptide adsa bond adsa adsa
w.wp.ap3. (d) Tautomerism w .wp.apda w .wp.apda w .wp.apda phosphate w .wp.apda w
ww ww ww(c) 2 – hydroxymethylserine
8. ww ww ww
4. (c) Nitro benzene 9. (d) the sugar component in 19. (c) Adenine
5. (b) m – tdinitro benzene 20. (d) tet base – sugar –
et
.ani.e3nNO etet RNA is ribose and
.ani.ente
t sugar
the
.ani.enphosphate il.ani.ene
t t
6. s(c)
asl a i
l
CCI 2 s asl ail.ani.n component s asl a il s asl a il s asl a
daada ada ada in DNA is 2’ – ada ada
w .wp.ap7. (c) N, N – dimethyl w .wp.apda w .wp.apda
deoxyribose w .wp.apda 21. (b) Adenine w .apdathymine;
.wpand w
ww ww ww ww ww ww
methanamine 10. (d) H3N+ – CH(R) – COO– guanine and cytosine
8. (b) N – methyl propan – 1 – 11. (d) Vitamins entet 22. (b)t Ribose sugar and uracil t
e tet .ani.ente
t te ete
a
amine
asl i
l .ani . n
l a il l i
ala . ni . l il.ani.en(b)
a23. a globular protein l ail.ani.n
daadsa(b) sas 12. (d) 1 and s5as s as s as
ap9. apdaada aa
.apdad adaada 24. (b) 10 adaada
w .wp. Hoffmann w .wp.
degration 13. w.wpRiboflavin
(a) w.wp.p w.wp.p w
ww reaction ww w w w w
25. (c) 8 w
w ww
52
t t t t t t t t t t
ww ww ww ww ww ww
l l l l l
p
w.w .p p
w.w . p p
w.w . p p
w.w . p p
w.w. p w
ww ww ww ww ww ww
t t t t .entetbut tet antipyretic t t

a l a il.ani.ene a l a il.ani.ene 14. (c) assertion a l a il.anitrue
is
a l a il.ani.en(d)
11.
a l a il.ani.ene
adsa s adsa s adsa s s
adsa 12. (a) morphine,acodeine adsa s
w .wp.apda15. CHEMISTRY IN EVERYDAY w .wp.apda w .wp.apdais false
reason
w .wp.apda w .wp.pda w
ww ww ww(a) novestrol
15. ww ww
13. (a) lidocaine ww
LIFE
16. (d) equanil 14. (b) isoflurane
1. (c)Asprin t t t t t t tet iso fharane etet
il.ani.ene i.ani.ene 17. (d) PHBV ail.ani.n e e il.ani.en(d)
a15. ail.ani.n
aslaChioroxylenol
2.adsa(b) and a a –dsaaslal aas asl s asl
ada 16. (a) cetrizine adaada s asl
ada
w.wp.p terpineol w.wp.p
ada
w w .apdad
18. (b).pPAN
w .wp.apda w.wp.p w
ww ww ww(d) They contain strongww
19. ww
17. (d) azithromycin ww
3. (a) dilute solutions of boric
covalent bonds in their 18. (a) povidone – iodine
acid and hydrogen
t t t tet sodium meta suiphite t
l a il.ani.ente l a il.ani.ente polymer chain
l a il.ani.ente
l a19.
il.ani.en(c) l a il.ani.ente
as
speroxide are strong sas sas sas sas
.wp.apdaada .wp.apdaada .w .apdaada
20. (a)pantiseptic
.wp.apdaada 20. (b) detergent .wp.apdaada
w antiseptics w w w w w
ww ww ww ww ww silk
21. (a) cellulose, ww
4. (b) toluene
ADDITIONAL QUESTONS 22. (b) zeigler natta catalyst
5. (a) antagonists t t t t tet TiCI4 + (C2H5)3AI .ni.entet
il.ani.ene acid saaslaila
.ni.ente 1. (a) erythromycin t
il.ani.ene il.ani.en(a)
23. ia
lsaacetylsalicylic
6. sa(a)
a a
sas l a sas 24. (c) terylene dadsaaslal
a l a
adaad adaad aad a
2. (a) atenolold aad ad aa
w w.wp.p7. D w w.wp.p w.wp.p w.wp.p w.wp.p w
w w ww(b) sulphanilamide
3. ww 25. (a) navolac ww ww
8. (c) all cis – conflguration
4. (a) PABA 26. (b) melamine formal
9. (a) polyamide t t t t t t tet t t
5. (d) antagonists
10.s(c)
a l il.ani.ene
apolyester a l a il.ani.ene a l a il.ani.ene a l a il.ani.endehyde a l a il.ani.ene
daada s adsa s 6. (d) all s
adsaabove
the s
adsa 27. (c) styrene + butadiene adsa s
w.wp.ap11. A w .wp.apda w .wp.apda w.wp.apda w .wp.apda w
ww ww ww(c) morphine
7. ww 28. (d) sulphur ww ww
12. (d) PHBV
8. (a) Tranquilizer
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l l l l l

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t tetLiquation t entet refining t

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ene t t .ni.ene t t .ni.ene agent? t tt t t t

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t t tet tet tet t t

l a l ni.entet electronic configuration

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t t tet tet tet t t

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