Reaction Mechanism in MOF Based Heterogeneous Catalysis

1
Reaction Mechanism in MOF based Heterogeneous Catalysis
NAME OF THE STUDENT: FAISAL MEHTAB
ROLL NUMBER: 204-PHD-21
NAME OF THE TEACHER: Dr. Nazir Ahmad
SUBJECT: Nanochemistry
DEPARTMENT OF CHEMSTRY
GC UNIVERSITY, LAHORE.
2
Abstract
Metal–organic frameworks (MOFs) have gotten a lot of interest in recent years as selective
oxidation catalysts and building supports. We examine current findings on the use of MOFs in
heterogeneous liquid-phase selective oxidation catalysis using the green oxidant–aqueous
hydrogen peroxide in this brief review paper. This research will focus on MOFs with exceptional
thermal and chemical stability, such as Cr(III)-based MIL-101, Ti(IV)-based MIL-125, Zr(IV)-
based UiO-66(67), Zn(II)-based ZIF-8, and others. The impact of metal nature and MOF structure
on catalytic activity and oxidation selectivity is investigated, as well as the mechanisms of
hydrogen peroxide activation. In other circumstances, we also try to figure out if there are any
links between MOFs' liquid-phase adsorption properties and their catalytic performance. In
addition, attempts to use MOFs as supports for the production of single-site catalysts by
modifying them with heterometals will be discussed in relation to the utilisation of such catalysts
for H2O2 activation. The important challenges of catalyst stability and reusability are given
special consideration. The use of MOF catalysts in H2O2-based selective oxidation is reviewed,
as well as its limitations.
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Table of Contents
1. Introduction.........................................................................................................................3
1.1 MOF.................................................................................................................................3
1.2 Structure..........................................................................................................................3
1.3 Catalysis:.........................................................................................................................3
1.4 Design.............................................................................................................................4
1.5 Metal Ions or Metal Clusters..........................................................................................5

2.Proposed mechanism for the oxidation of ethane to ethanol in Fe0.1 Mg1.9
(DOBDC).............................................................................................................................6
3. Mechanism of jasminealdehyde synthesis catalyzed by UiO-66/UiO-66-NH2.............. .8
4. Mechanism of Co@SBU catalysed reactions...................................................................9
5. Proposed mechanism for the oxidation of cyclooctane catalyzed by

NHPI/Fe(BTC)......................................................................................................................10
6. Development of heterogeneous catalysts for the cycloaddition of CO 2 with
Epoxides..........................................................................................................................10
7. First applications of MOFs in oxidation catalysis with H2O2.................................................................14
8. Graphical Extract........................................................................................................14
9. Pioneer Scientist................................................................................................................16
9.1 Omar M. Yaghi................................................................................................................16
10. References........................................................................................................................48
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Reaction Mechanism in MOF based Heterogeneous Catalysis

1. Introduction
1.1 Metal–Organic Framework (MOF)
MOFs are a type of substance that consists of metal ions or clusters that are coupled to organic
ligands to form one-, two-, or three-dimensional structures. They are a type of coordination
polymer that has the unique property of being porous. The organic ligands used are sometimes
referred to as "struts" or "linkers," with 1,4-benzenedicarboxylic acid being one example (BDC).
A metal–organic framework, in more formal terms, is a coordination network with organic
ligands that contain possible voids. A coordination network is a coordination compound that
extends in one dimension through repeating coordination entities but has cross-links between two
or more individual chains, loops, or spiro-links, or a coordination compound that extends in two
or three dimensions through repeating coordination entities and eventually, a coordinated effort a
polymer is a coordination molecule that consists of repeated coordination entities that can stretch
in one, two, or three dimensions[1-2].
In some cases, the pores are stable during elimination of the guest molecules (often solvents) and
could be refilled with other compounds. Because of this property, MOFs are of interest for the
storage of gases such as hydrogen and carbon dioxide. Other possible applications of MOFs are
in gas purification, in gas separation, in water remediation, in catalysis, as conducting solids and
as supercapacitors. The synthesis and properties of MOFs constitute the primary focus of the
discipline called reticular chemistry (from Latin reticulum, "small net"). In contrast to
MOFs, covalent organic framework (COFs) are made entirely from light elements (H, B, C, N,
and O) with extended structures [4-7].
MOFs as heterogeneous catalysts for selective oxidations with H2O2, with a focus on the
mechanistic features of the reactions as well as stability and reusability challenges. The use of
MOFs as supports for the creation of single-site selective oxidation catalysts by heterometal
modification will also be explored in regard to H2O2-based oxidations. MOFs with excellent
chemical and thermal stability, such as Cr(III)-based MIL-101, Ti(IV)-based MIL-125, Zn(II)-
based ZIF-8, Zr(IV)-based UiO-66(67), and others, are the focus of this research. Since metal–
oxygen clusters (MOCs) or polyoxometalates (POMs) were recently surveyed in the structural
nodes or cages of MOFs [41,42].
MIL-101 MIL-125 ZIF-8

5
UiO-66 UiO-67 Zr-abtc

1.2 Structure
MOFs are made up of two main components: a metal ion or cluster of metal ions and a linker,
which is an organic molecule. The materials are often referred to as hybrid organic–inorganic
materials as a result of this; however, this language has recently been officially deprecated.
Monovalent, divalent, trivalent, and tetravalent ligands are the most common organic units. The
structure and thus the characteristics of the MOF are determined by the metal and linker used. The
size and form of pores are influenced by the metal's coordination preference, which dictates how
many ligands can bind to the metal and in which orientation [3].
A naming system has been created to characterise and arrange the structures of MOFs. Secondary
building units (SBU) are MOF subunits that have topologies that are shared by numerous
structures. Each topology, also known as a net, is given a symbol that consists of three bold
lower-case letters. A pcu net, for example, is present in MOF-5. Bridging ligands are attached to
the SBUs. Di- and tricarboxylic acids are common bridging ligands for MOFs. The backbones of
these ligands are usually stiff. Benzene-1,4-dicarboxylic acid (BDC or terephthalic acid),
biphenyl-4,4'-dicarboxylic acid (BPDC), and trimesic acid are examples of tricarboxylic acids.
1.3 Catalysis
Although applications for MOFs have yet to be developed, they show potential as heterogeneous
catalysts. They are particularly promising for use as catalysts because of their high surface area,
adjustable porosity, and diversity of metal and functional groups. In catalysis, zeolites are
extremely valuable. The two-coordinated oxide linkers and the fixed tetrahedral coordination of
the Si/Al connecting sites limit zeolites. There are only about 200 zeolites known. MOFs, on the
other hand, have a wider range of coordination geometries, polytopic linkers, and auxiliary
ligands (such as F, OH, and H2O). It's also rare to find zeolites with pore sizes larger than 1 nm,
limiting zeolites' catalytic applications to tiny organic compounds (typically no larger than
xylenes). In addition, the mild synthetic conditions used in MOF synthesis allow for the direct
insertion of sensitive functions into the framework structures. Because of the severe conditions
utilised to make zeolites and other microporous crystalline oxide-based materials, such a method
would not be practical (e.g., calcination at high temperatures to remove organic templates). MIL-
101, a metal-organic framework, is one of the most widely utilised MOFs for catalysis involving
transition metals such as Cr. However, in aqueous media and under extremely oxidising
circumstances, the stability of some MOF photocatalysts is quite low.
Zeolites are still not available in enantiopure form, which prevents their use in catalytic
asymmetric synthesis in industries such as pharmaceuticals, agrochemicals, and fragrances. To
make efficient asymmetric catalysts, enantiopure chiral ligands or their metal complexes have
been integrated into MOFs. When isolated polynuclear sites, dynamic host–guest reactions, and a
hydrophobic cavity environment are combined, some MOF materials may be able to bridge the
gap between zeolites and enzymes. MOFs could be useful in the production of semi-conductors.
MOFs are semiconductors or insulators with band gaps between 1.0 and 5.5 eV, which may be
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changed by changing the degree of conjugation in the ligands, indicating that they could be
photocatalysts, according to theoretical simulations.
1.4 Design
MOFs, like other heterogeneous catalysts, may be easier to separate post-reaction and recycle
than homogeneous catalysts. They can also help to improve catalyst stability in some
circumstances. They usually have substrate-size selectivity as well. Nonetheless, whereas
substrate size selectivity is definitely critical for reactions in biological systems, it is of limited
use in abiotic catalysis because sufficiently clean feedstocks are often accessible.
MOF-5
1.5 Metal Ions or Metal Clusters
The cyanosilylation of aldehydes by a 2D MOF (layered square grids) of formula Cd(4,4'-
bpy)2(NO3)2 was one of the first reports of MOF-based catalysis. The focus of this study was on
size and shape-selective clathration. A two-dimensional square-grid MOF with single Pd(II) ions
as nodes and 2-hydroxypyrimidinolates as struts was used in the second set of examples. The
palladium centres in this MOF catalyse alcohol oxidation, olefin hydrogenation, and Suzuki C–C
coupling despite initial coordinative saturation. If all of the Pd centres are catalytically active,
these reactions must entail redox oscillations of the metal nodes between Pd(II) and Pd(0)
intermediates, as well as drastic changes in coordination number, which would undoubtedly lead
to destabilisation and potential destruction of the original framework. The fact that the catalytic
processes are heterogeneous and occur within the MOF is supported by the observation of
substrate shape and size selectivity. However, it's difficult to rule out the possibility that catalysis
is taking place at the surface of MOF-encapsulated palladium clusters/nanoparticles (i.e. partial
decomposition sites) or defect sites, rather than at transiently labile but otherwise intact single-
atom MOF nodes, at least for hydrogenation. For the cubic compound MOF-5, "opportunistic"
MOF-based catalysis has been described. The Friedel–Crafts tert-butylation of toluene and
biphenyl appears to be catalysed by this material, which consists of coordinatively saturated Zn4O
nodes and fully complexed BDC struts (see above for abbreviation). Furthermore, para alkylation
is highly preferred over ortho alkylation, which is assumed to reflect the MOF's ability to
encapsulate reactants. [8-10].
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Zeolite Catalyst
2. Proposed mechanism for the oxidation of ethane to ethanol in Fe0.1 Mg1.9 (DOBDC)
Based on the intermediates, the following theoretical mechanistic investigation revealed
four important steps: 1) breakage of the N-O bond of N2O to generate an iron(IV)oxo
intermediate; 2) activation of the C-H bond of ethane to form the Fe(III) (S = 5/2)-OH
species by the highly active intermediate; 3) radical rebound to form ethanol; 4) ethanol
release (Figure 4).
Currently, the field of C-H functionalization is quickly developing to incorporate the
benefits of photochemical and electrochemical catalysis, resulting in the development of
selective and efficient reactions. The extremely selective benzene hydroxylation to phenol
could be performed over two Fe-based metal-organic frameworks [MIL-100(Fe) and MIL-
68(Fe)] employing hydrogen peroxide (H2O2) as an oxidant using MOFs materials in
photocatalytic systems. After 24 hours of illumination, an ideal benzene conversion of 30.6
percent was attained with an H2O2:benzene ratio of 3:4 over MIL-100(Fe). The Fe-based
MOFs MIL-100(Fe) and MIL-68(Fe), which contain trimers of FeO6 octahedra clusters and
corner-sharing FeO4(OH)2 octahedra, respectively, can convert H2O2 to •OH radical by
Fe2+ reduction under irradiation, may transform H2O2 to •OH radical. The
hydroxycyclohexadienyl radical is generated when the •OH attacks the benzene ring, and the
phenol is formed once the proton and electron are released from the hydroxycyclohexadienyl
radical.
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Proposed mechanism for the oxidation of ethane to ethanol in Fe0.1Mg1.9(dobdc).

Finally the Fe-based MOF can reproduce to complete the photocatalytic cycle (Figure ).
(a) Photocatalytic benzene hydroxylation catalyzed by Fe-based- MOFs to form phenol. (b) Possible reaction
mechanism for the photocatalytic benzene hydroxylation over MIL-100(Fe).
Despite these advantages, MOFs' stability toward temperature, moisture, and some
reactants is lower than inorganic crystalline porous counterparts such as zeolites used in
industry, due to the presence of organic linkers and the weakness of the metal-ligand
coordinative bond compared to covalent Si-O bonds. The harsh reaction conditions (> 200
°C) in gas phase catalysis constantly reduce the lives of the catalysts and generate side
reactions such as thermal cracking and coke production. MOFs are often required to exhibit
strong mechanical resilience, thermal and structural stability as catalysts in gas-phase C-H
activation processes. Fortunately, some exceptionally stable Zr-, Al-, and Hf-based MOFs
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with variable crystallinity and various topologies have been produced as catalysts or catalyst
supports for C-H activation using high-valence metal ions and polycarboxylate linkers.
3. Mechanism of jasminealdehyde synthesis catalyzed by UiO-66/UiO-66-NH2
Speybröck's mechanistic investigation into a cross-aldol reaction to create jasminaldehyde,

catalysed by Zr MOFs UiO-66 and UiO-66-NH 2, is an outstanding example of how relevant
this subject might be[11]. This is a simple reaction for which the use of a MOF isn't always
necessary. This work, on the other hand, is a great example of how mechanistic understanding
can help with catalyst design. Functionalization of the terephthalate linkers with amino groups
has been shown to increase the rate of jasminaldehyde synthesis in previous experiments. It
was believed that the insertion of a basic functionality in the region of the Lewis acidic Zr
cluster provides a bifunctional catalyst that surpasses the original [12]. The authors
demonstrated that the NH2 group plays no role in the catalytic cycle using advanced DFT
techniques and experimental validation. Instead, it encourages substrate adsorption onto/into
the MOF, which accounts for the faster starting rate. Regardless of whether or not the NH2
group is present, the reaction proceeds in the same way, and the reaction rates are similar at
later stages. The rate-determining step was identified as a proton transfer from the Zr-oxo
cluster to the carbonyl oxygen of the adsorbed aldol product; hydrogen bonding with the
amino groups had no role in the reaction process. Inside the pore, there is undoubtedly a case
of bifunctionality. The metallic cluster contains Lewis acidic sites for substrate activation as
well as basic oxo species for proton relay. However, the grafted NH2 groups on the linkers
have little beneficial effect, and actually promote the formation of undesired imine species
from the reactants. More research like this is needed to gain a better knowledge of what
happens inside the pore and how the reactants interact with the framework in order to create
better catalysts.
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4. Mechanism of Co@SBU catalysed reactions
The vanadium-node-functionalized UiO-66 was produced by functionalizing the Zr6(μ3-

O)4(μ3-OH)4 node of UiO-66 with redox-active VV ions, which was active in the gas-phase
oxidative dehydrogenation of cyclohexene, selectively producing benzene at low conversion
(100 mol percent selectivity at 2 percent conversion). The reaction took place at 250-350 °C in a
packed-bed flow reactor with O2 as the oxidant, demonstrating that stable Zr-MOFs may be
employed as catalysts for high-temperature gas-phase chemical transformations.
The Hupp and Farha group discovered and produced NU-1000 (Zr-NU-1000 or Hf-NU-
1000), a thermally and chemically stable Zr-MOF that was widely used as a catalyst or
catalytic support. The strong interaction between the carboxylates of the ligand and the
zirconium nodes accounts for its exceptional thermal and chemical stability. NU-1000 has
bigger holes than UiO-66, with hexagonal pores measuring 31 Åand trigonal pores at 10 Å.
The smaller pores connect perpendicularly to the larger pores, making it a better catalyst or
catalysis support. The pKa values for μ3-OH, Zr–OH2, and Zr–OH are 3.59±0.02,
5.75±0.04, and 8.2±0.1, respectively, in the NU-1000 Zr6(μ3-O)4(μ3-OH)4(H2O)4(OH)4.
By using solvent aided ligand integration (SALI) and atomic layer deposition in a MOF, the
Lewis acidity of the Zr6 nodes can provide isolated reactive sites for specific chemical
reactions (AIM). The well-defined Zr-based nodes, in particular, can provide reactive sites
for postsynthetic metalation by AIM and C-H activation via solvothermal deposition in a
MOF (SIM). Due to the structural uniformity of the MOFs supports, metal ions installed on
nodes of MOFs via AIM or SIM have more well-defined structures and uniform size than
metal ions installed on nodes of MOFs via conventional approaches such as impregnation,
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ion exchange, and sol-gel encapsulation [13-15].

5. Proposed mechanism for the oxidation of cyclooctane catalyzed by NHPI/Fe(BTC)
Under mild circumstances, N-hydroxyphthalimide (NHPI) can accelerate the oxidation of
cycloalkanes and alkylbenzenes with oxygen by interacting with transition metal acetates as
a beneficial co-catalyst (an electron-transfer mediator). The selectivity, on the other hand, is
low. Garcia et al. reported a catalyst based on Fe(BTC) MOF (BTC=1,3,5-
benzenetricarboxylate) that incorporated NHPI as a radical initiator (NHPI/Fe(BTC)) for the
aerobic oxidation of cyclooctane to achieve excellent selectivity towards the formation of
cyclooctanone/cyclooctanol mixtures as the only oxidation products at high ( Weak
interactions cause the NHPI to be adsorbed onto nodal FeIII ions, forming the phthalimide
N-oxyl radical (PINO), which then abstracts a hydrogen atom from the cycloalkane to form
the cyclooctyl radical. Radicals can be trapped by molecular oxygen to form hydroperoxide,
which then decomposes into cyclooctanone and cyclooctanol thanks to the MOFs' transition
metal ions. The synergistic interactions in catalysis between MOFs and encapsulated guest
species were highlighted in this study. [16].
6. Development of heterogeneous catalysts for the cycloaddition of CO 2 with

epoxides
In the field of carbon dioxide chemical fixation, the development of heterogeneous
catalysts for the cycloaddition of CO2 with epoxidest to form cyclic carbonates is a hot
topic. The employment of carbon dioxide and epoxides to generate cyclic carbonates is
said to be the most environmentally benign method of chemically fixing carbon dioxide
because all atoms are used (Scheme). Cyclic carbonates are essential molecules that have a
variety of uses, including polar aprotic solvents, lithium-ion battery electrolytes,
monomeric polymer synthesis, degreasing agents, chemical intermediates, and cosmetics.
However, the chemical inertness of CO2, which necessitates the use of a catalyst, is the
most serious flaw. For this appealing reaction, a variety of catalysts have been
developed, including both homogeneous and heterogeneous catalysts. Metal halide and
metallic oxide transition metal complexes, organic bases, ionic liquids, and quaternary
ammonium are examples of homogeneous catalysts. The recovery and isolation of such
catalysts is a major impediment to their use in industry. As a result of these
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characteristics, heterogeneous catalyst has attracted the interest of researchers. Most

heterogeneous catalysts, on the other hand, have lesser catalytic activity or are exposed
to harsh reaction conditions. As a result, research into the development of a
cycloaddition reaction catalyst capable of efficiently catalysing carbon dioxide under
mild reaction conditions is needed. [17-31].
In some of the past work, metal–organic frameworks (MOFs) have shown excellent
heterogeneous catalytic activity due to their chemical functionalities and ease of
recovery for recycling, from the reaction system making MOFs a potential candidate for
Synthesis of cyclic carbonates from epoxides and CO2
heterogeneous catalysis. Because of their affinity for CO2, MOFs constitute excellent
catalysts for the synthesis of cyclic carbonates from CO2 and epoxides. In 2009, the first
chemical fixation of carbon dioxide was investigated using MOF catalysts (MOF-5) to
generate cyclic carbonates. Several materials in this research topic have been reported
since then. MOF-5, Cr-MIL-101, ZIF-68, and ZIF-95, among MOF materials, have been
explored in the cycloaddition process of carbon dioxide for the creation of cyclic
carbonates, with promising results. The catalytic activity of a heterogeneous catalyst in
the cycloaddition to generate cyclic carbonates is related to the Lewis acid and Lewis
base involved in the catalyst's reaction, according to previous studies. Lewis acid–base
sites can harmonise and activate substrate molecules, allowing the reaction and products
to proceed more quickly. Many MOF materials, on the other hand, have limited catalytic
activity, poor stability, and harsh catalytic conditions, limiting their use in commercial
applications. As a result, exploring, producing, and screening different MOF materials
with outstanding catalytic performance is a hot topic in carbon dioxide cycloaddition
research.
The goal of our research was to create a stable and long-lasting MOF catalyst
([Zn3(BTC)2]) for cyclic carbonates production using a solvothermal technique. To play
its good synergistic effect, the [Zn3(BTC)2] unit has Lewis acid and base catalytic sites,
as well as a strong nucleophilic anionic promoter (TBAB). The [Zn3(BTC)2]/TBAB
catalytic system was found to have high activity and selectivity under solvent-free and
relatively moderate reaction conditions. The yield of cyclic carbonate was 99 percent
under ideal reaction conditions, and [Zn3(BTC)2] has a higher content of Lewis acids–
bases than its heterogeneous and homogeneous counterparts, demonstrating satisfactory
catalytic performance. After being recycled multiple times, the catalyst still exhibits a
high level of activity. The high stability of [Zn3(BTC)2] suggests that it is an effective heterogeneous
13
catalyst for carbon dioxide chemical fixation. [32-39].
Catalytic performance of fresh and recycled [Zn3(BTC)2]/TBABr in the synthesis of styrene carbonate from carbon dioxide and styrene
oxide.
The catalyst's recycling was investigated in order to confirm the catalytic activity's
persistence and outstanding stability in the cycloaddition reaction. Figure 1 shows the
catalytic activity of the reused [Zn3(BTC)2] catalyst. For each cycle, the used catalyst
was centrifuged and thoroughly washed with ethanol and distilled water to remove the
products adhered to the catalyst's surface, then dried at 80°C for 12 hours under vacuum
to remove trapped ethanol and water molecules in the pores, and finally reused catalyst
for the next run. Both styrene oxide conversion and styrene carbonate yield were
reduced minimally in each experiment. However, when the catalyst was recycled three
times, both the feedstock conversion and the product yield began to decline marginally.
Although the satisfied selectivity to styrene carbonate did not change obvi- ously, the
conversion rate dropped to 95% after recycling the catalyst five times, and the conversion
rate recorded in the sixth run was close to 90%. There is a partial loss of catalyst. Under the
optimum conditions determined above, the [Zn3(BTC)2]/TBAB catalyst system was found
to be suitable to a variety of epoxides. Table shows a summary of the findings. All of the
epoxides had a high conversion rate and a good product yield. Many researchers have
evaluated the catalytic performance of [Zn3(BTC)2] with that of other MOF heterogeneous
A comparison of the catalytic performance of the [Zn 3(BTC)2]/ TBAB system with other. In
this study, MOF catalysts were observed in the same reaction system.
All of the other MOFs documented in the literature require the help of a co-catalyst. All of
these MOF catalytic reactions were carried out under comparatively benign conditions, with
temperatures and CO2 pressures ranging from 60 to 140°C and 10 to 20 bar, respectively.
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Scheme : Proposed mechanism for the cyclic addition reaction of CO2 and styrene oxide in the presence of [Zn3(BTC)2]/TBABr.
The yield of the product and the TOF value of [Zn3(BTC)2]/TBAB in the cycloaddition
reaction were compared with the different MOFs in Table 2. This study used a very modest
amount of co-catalyst (0.31 10—4 mmol). These findings show that [Zn3(BTC)2]/ TBAB is
effective in the conversion of carbon dioxide to cyclic carbonates. The separation of the
product/catalyst from the reaction mixture requires higher yields. The [Zn3(BTC)2]/TBAB
catalytic system may catalyse epoxide cycloaddition to create cyclic carbonates, as
shown in Scheme. The presence of Lewis acidic sites and strong nucleophilic anions
can effectively activate the epoxides and so boost the ring-opening process, according
to previous reports based on experimental and density functional theory (DFT) research.
While Lewis basic sites conduct a nucleophilic assault that activates carbon dioxide. Br
— is derived from n-Bu4NBr and is utilised to attack and activate less hindered carbon
atoms in epoxides, resulting in reactive oxygen anion open-loop production. Following
that, the opening epoxide's oxygen anion reacts with CO2 to generate an intermediate.
Finally, Br— is removed from the intermediate by a ring-closing process, which
produces the appropriate cyclic carbonate while regenerating the catalyst. The following
cycle reaction begins right away. As a result, we confirmed that the catalyst comprised
both acidic and alkaline sites, which were beneficial for the carbon dioxide and epoxide
reactions. The high catalytic activity of the catalyst system under relatively moderate
conditions is due to the synergistic effect of [Zn3(BTC)2] and n-BuN4Br[40].
7. First applications of MOFs in oxidation catalysis with H2O2

15
The chromium(III) terephthalate Cr-MIL-101 ([Cr3X(H2O)2O(BDC)3]; X = F, OH; MIL

stands for Matérial Institut Lavoisier) developed by Férey and associates [48] is one of the first
applications of MOFs in oxidation catalysis with H2O2. MIL-101 has a rigid zeotype (MTN)
crystal structure with quasi-spherical cages of two modes (2.9 and 3.4 nm) accessible through
windows of approximately 1.2 and 1.6 nm (Figure ). Mesoporosity along with strong chemical,
thermal, and hydrothermal stability are characteristics of this MOF that play a crucial role in
catalysis. The ability to create coordinatively unsaturated sites (CUS) in Cr(III) metal nodes by
removing terminal water molecules using thermal treatment after evacuation is an additional
advantage for catalysis [43,44].
Activation of MIL-101 and thioether oxidation over coordinatively unsaturated sites (CUS)
8. Graphical Extract
The oxidation of propylene glycol (PG) over UiO-66 [130] is a reaction in which
homolytic activation of H2O2 has resulted in the creation of valuable chemicals. The reaction
proceeds with a high degree of regioselectivity, with the major product being hydroxyacetone
(HA). Additives of radical chain scavengers have a rate-inhibiting effect, implying that the
oxidation process is mediated by radical chains. Close reaction rates in air and inert
atmosphere imply that molecular oxygen does not participate in the oxidation process. The
composition of the solvent had a significant impact on HA yields and oxidant consumption
efficiency. Adsorption investigations demonstrated that PG adsorption on UiO-66 from pure
CH3CN is significant (the adsorption constant calculated using the Langmuir model was 290
60 M1), whereas a mixed solvent H2O/CH3CN 3/7 (v/v) showed almost little adsorption
(Figure) [130]. As a result, the authors hypothesized that deposited PG molecules block Zr
active sites, preventing oxidant adsorption and activation. The highest catalytic performance
(85% selectivity toward HA at around 10% PG conversion) was achieved in acetonitrile
containing 30% H2O, which agrees with this idea.
16
17
9. Pioneer Scientist
9.1 Omar M. Yaghi
Affiliations: 1992- Arizona State University, Tempe, AZ, United
1998 States
1999- University of Michigan, Ann Arbor, Ann Arbor,

2006 MI
2007- University of California, Los Angeles, Los

Chemistry
2011 Angeles, CA
2012- Chemistry University of California, Berkeley, Berkeley, CA
Area:
inorganic
Website:
https://chemistry.berkeley.edu/faculty/chem/yaghi
18
270 high-probability publications.

Yea Citation Score
r
2022 Lyu H, Chen OI, Hanikel N, Hossain MI, Flaig RW, Pei X, Amin A, Doherty MD, Impastato RK, 0.355
Glover TG, Moore DR, Yaghi OM. Carbon Dioxide Capture Chemistry of Amino Acid
Functionalized Metal-Organic Frameworks in Humid Flue Gas. Journal of the American Chemical
Society. PMID 35080872 DOI: 10.1021/jacs.1c13368
2020 Wang H, Shi Z, Yang J, Sun T, Rungtaweevoranit B, Lyu H, Zhang YB, Yaghi OM. Docking of 0.732
Cu(I) and Ag(I) in Metal-Organic Frameworks for Adsorption and Separation of
Xenon. Angewandte Chemie (International Ed. in English).
PMID 33247510 DOI: 10.1002/anie.202015262
2020 Nguyen HL, Gropp C, Ma Y, Zhu C, Yaghi OM. 3D Covalent Organic Frameworks Selectively 0.323
Crystallized through Conformational Design. Journal of the American Chemical Society.
PMID 33186498 DOI: 10.1021/jacs.0c11064
2020 Gropp C, Ma T, Hanikel N, Yaghi OM. Design of higher valency in covalent organic 0.312
frameworks. Science (New York, N.Y.). 370. PMID 33093081 DOI: 10.1126/science.abd6406
2020 Gropp C, Canossa S, Wuttke S, Gándara F, Li Q, Gagliardi L, Yaghi OM. Standard Practices of 0.351
Reticular Chemistry. Acs Central Science. 6: 1255-1273.
PMID 32875067 DOI: 10.1021/Acscentsci.0C00592
2020 Zhao C, Lyu H, Ji Z, Zhu C, Yaghi OM. Ester-Linked Crystalline Covalent Organic 0.372
Frameworks. Journal of the American Chemical Society.
PMID 32786782 DOI: 10.1021/Jacs.0C07015
2020 Nguyen HL, Gropp C, Yaghi OM. Reticulating 1D Ribbons into 2D Covalent Organic 0.328
Frameworks by Imine and Imide Linkages. Journal of the American Chemical Society.
PMID 31995371 DOI: 10.1021/Jacs.9B13971
2020 Xu W, Tu B, Liu Q, Shu Y, Liang C, Diercks CS, Yaghi OM, Zhang Y, Deng H, Li Q. 0.683
Anisotropic reticular chemistry Nature Reviews Materials. 1-16. DOI: 10.1038/S41578-020-0225-
X
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2019 Xu W, Pei X, Diercks CS, Lyu H, Ji Z, Yaghi OM. A Metal-Organic Framework of Organic 0.387
Vertices and Polyoxometalate Linkers as a Solid-State Electrolyte. Journal of the American
Chemical Society. PMID 31642665 DOI: 10.1021/Jacs.9B10418
2019 Matheu R, Gutierrez-Puebla E, Monge MÁ, Diercks CS, Kang J, Prévot MS, Pei X, Hanikel 0.325
N, Zhang B, Yang P, Yaghi OM. Three-Dimensional Phthalocyanine Metal-Catecholates for High
Electrochemical Carbon Dioxide Reduction. Journal of the American Chemical Society.
PMID 31613614 DOI: 10.1021/Jacs.9B09298
2019 Zhang B, Mao H, Matheu R, Reimer JA, Alshmimri SA, Alshihri S, Yaghi OM. Reticular 0.346
Synthesis of Multinary Covalent Organic Frameworks. Journal of the American Chemical Society.
PMID 31276387 DOI: 10.1021/Jacs.9B05626
2019 Cho HS, Yang J, Gong X, Zhang YB, Momma K, Weckhuysen BM, Deng H, Kang JK, Yaghi 0.771
OM, Terasaki O. Isotherms of individual pores by gas adsorption crystallography. Nature
Chemistry. PMID 31086299 DOI: 10.1038/S41557-019-0257-2
2019 Ding M, Flaig RW, Jiang HL, Yaghi OM. Carbon capture and conversion using metal-organic 0.368
frameworks and MOF-based materials. Chemical Society Reviews.
PMID 31032507 DOI: 10.1039/C8Cs00829A
2018 Diercks CS, Kalmutzki MJ, Diercks NJ, Yaghi OM. Conceptual Advances from Werner 0.35
Complexes to Metal-Organic Frameworks. Acs Central Science. 4: 1457-1464.
PMID 30555897 DOI: 10.1021/Acscentsci.8B00677
2018 Liu Y, Diercks CS, Ma Y, Lyu H, Zhu C, Alshmimri SA, Alshihri S, Yaghi OM. 3D Covalent 0.304
Organic Frameworks of Interlocking 1D Square Ribbons. Journal of the American Chemical
Society. PMID 30532960 DOI: 10.1021/Jacs.8B12177
2018 Yaghi OM, Cordova KE. Building a Global Culture of Science - The Vietnam 0.775
Experience. Angewandte Chemie (International Ed. in English).
PMID 30423215 DOI: 10.1002/Anie.201812076
2018 Kalmutzki MJ, Hanikel N, Yaghi OM. Secondary building units as the turning point in the 0.405
development of the reticular chemistry of MOFs. Science Advances. 4: eaat9180.
20
PMID 30310868 DOI: 10.1126/Sciadv.Aat9180
2018 Diercks CS, Liu Y, Cordova KE, Yaghi OM. Publisher Correction: The role of reticular chemistry 0.776
in the design of CO reduction catalysts. Nature Materials.
PMID 30087423 DOI: 10.1038/S41563-018-0159-5
2018 Liu Y, O'Keeffe M, Treacy MMJ, Yaghi OM. The geometry of periodic knots, polycatenanes and 0.466
weaving from a chemical perspective: a library for reticular chemistry. Chemical Society Reviews.
PMID 29726872 DOI: 10.1039/C7Cs00695K
2018 Schrimpf W, Jiang J, Ji Z, Hirschle P, Lamb DC, Yaghi OM, Wuttke S. Chemical diversity in a 0.307
metal-organic framework revealed by fluorescence lifetime imaging. Nature Communications. 9:
1647. PMID 29695805 DOI: 10.1038/S41467-018-04050-W
2018 Diercks CS, Liu Y, Cordova KE, Yaghi OM. The role of reticular chemistry in the design of 0.8
COreduction catalysts. Nature Materials. PMID 29483634 DOI: 10.1038/S41563-018-0033-5
2018 Lyle SJ, Flaig RW, Cordova KE, Yaghi OM. Facilitating Laboratory Research Experience Using 0.816
Reticular Chemistry Journal of Chemical Education. 95: 1512-1519.
DOI: 10.1021/Acs.Jchemed.8B00265
2018 Cordova KE, Yaghi OM. Aufbau einer globalen Wissenschaftskultur – die Vietnam‐ 0.775
Erfahrung Angewandte Chemie. 131: 1566-1575. DOI: 10.1002/Ange.201812076
2017 Diercks CS, Lin S, Kornienko N, Kapustin EA, Nichols EM, Zhu C, Zhao Y, Chang CJ, Yaghi 0.697
OM. Reticular Electronic Tuning of Porphyrin Active Sites in Covalent Organic Frameworks for
Electrocatalytic Carbon Dioxide Reduction. Journal of the American Chemical Society.
PMID 29284263 DOI: 10.1021/Jacs.7B11940
2017 Osborn Popp TM, Yaghi OM. Sequence-Dependent Materials. Accounts of Chemical Research. 0.308
50: 532-534. PMID 28945416 DOI: 10.1021/Acs.Accounts.6B00529
2017 Zhao Y, Guo L, Gándara F, Ma Y, Liu Z, Zhu C, Lyu H, Trickett CA, Kapustin EA, Terasaki 0.741
O, Yaghi OM. A Synthetic Route for Crystals of Woven Structures, Uniform Nanocrystals, and
Thin Films of Imine Covalent Organic Frameworks. Journal of the American Chemical Society.
21
PMID 28845988 DOI: 10.1021/Jacs.7B07457
2017 Addicoat M, Bennett T, Chapman K, Denysenko D, Dincă M, Doan H, Easun T, Eddaoudi 0.651
M, Farha O, Gagliardi L, Haase F, Hajiahmadi Farmahini A, Hendon C, Jorge M, Kitagawa S,
Yaghi OM, et al. New directions in gas sorption and separation with MOFs: general
discussion. Faraday Discussions. PMID 28832697 DOI: 10.1039/C7Fd90044A
2017 Carraro F, Chapman K, Chen Z, Dincă M, Easun T, Eddaoudi M, Farha O, Forgan R, Gagliardi L, 0.776
Haase F, Harris D, Kitagawa S, Knichal J, Lamberti C, Lee JM, ... ... Yaghi OM, et al. Catalysis
in MOFs: general discussion. Faraday Discussions. PMID 28832064 DOI: 10.1039/C7Fd90046E
2017 Banerjee T, Bennett T, Butler K, Easun TL, Eddaoudi M, Forgan R, Gagliardi L, Hendon C, Jorge 0.651
M, Lamberti C, Lee JM, Leus K, Li J, Lin W, Ranocchiari M, Yaghi OM, et al. Electronic,
magnetic and photophysical properties of MOFs and COFs: general discussion. Faraday
Discussions. PMID 28832059 DOI: 10.1039/C7Fd90043K
2017 Rungtaweevoranit B, Diercks CS, Kalmutzki MJ, Yaghi OM. Spiers Memorial Lecture:. Progress 0.334
and prospects of reticular chemistry. Faraday Discussions.
PMID 28820210 DOI: 10.1039/C7Fd00160F
2017 Flaig RW, Osborn Popp TM, Fracaroli AM, Kapustin EA, Kalmutzki MJ, Altamimi RM, Fathieh 0.313
F, Reimer JA, Yaghi OM. The Chemistry of CO2 Capture in an Amine-Functionalized Metal-
Organic Framework under Dry and Humid Conditions. Journal of the American Chemical Society.
PMID 28817269 DOI: 10.1021/Jacs.7B06382
2017 Kapustin EA, Lee S, Alshammari AS, Yaghi OM. Molecular Retrofitting Adapts a Metal-Organic 0.358
Framework to Extreme Pressure. Acs Central Science. 3: 662-667.
PMID 28691079 DOI: 10.1021/Acscentsci.7B00169
2017 Yang J, Trickett CA, Alahmadi SB, Alshammari A, Yaghi OM. Calcium L-Lactate Frameworks 0.347
as Naturally Degradable Carriers for Pesticides. Journal of the American Chemical Society.
PMID 28578568 DOI: 10.1021/Jacs.7B04542
2017 Yang J, Zhang YB, Liu Q, Trickett CA, Gutierrez-Puebla E, Monge MÁ, Cong H, Aldossary 0.786
A, Deng H, Yaghi OM. Principles of Designing Extra-Large Pore Openings and Cages in Zeolitic
Imidazolate Frameworks. Journal of the American Chemical Society.
22
PMID 28398726 DOI: 10.1021/Jacs.7B02272
2017 Al-Maythalony BA, Alloush AM, Faizan M, Dafallah H, Elgzoly MA, Seliman AA, Al-Ahmed 0.791
A, Yamani ZH, Habib MA, Cordova KE, Yaghi OM. Tuning the Interplay between Selectivity
and Permeability of ZIF-7 Mixed Matrix Membranes. Acs Applied Materials & Interfaces.
PMID 28140567 DOI: 10.1021/Acsami.6B15803
2017 Helal A, Yamani ZH, Cordova KE, Yaghi OM. Multivariate metal-organic frameworks National 0.775
Science Review. 4: 296-298. DOI: 10.1093/Nsr/Nwx013
2017 Cordova KE, Yaghi OM. The ‘folklore’ and reality of reticular chemistry Materials Chemistry 0.775
Frontiers. 1: 1304-1309. DOI: 10.1039/C7Qm00144D
2017 Trickett CA, Helal A, Al-Maythalony BA, Yamani ZH, Cordova KE, Yaghi OM. The chemistry 0.82
of metal–organic frameworks for CO2 capture, regeneration and conversion Nature Reviews
Materials. 2. DOI: 10.1038/Natrevmats.2017.45
2016 Choi KM, Kim D, Rungtaweevoranit B, Trickett CA, Barmanbek JT, Alshammari AS, Yang 0.356
P, Yaghi OM. Plasmon-Enhanced Photocatalytic CO2 Conversion within Metal-Organic
Frameworks under Visible Light. Journal of the American Chemical Society.
PMID 28004911 DOI: 10.1021/Jacs.6B11027
2016 Bose P, Sukul PK, Yaghi OM, Tashiro K. Synthesis of a Water-soluble Metal-Organic Complex 0.804
Array. Journal of Visualized Experiments : Jove. PMID 27768089 DOI: 10.3791/54513
2016 Schoedel A, Li M, Li D, O'Keeffe M, Yaghi OM. Structures of Metal-Organic Frameworks with 0.824
Rod Secondary Building Units. Chemical Reviews.
PMID 27627623 DOI: 10.1021/Acs.Chemrev.6B00346
2016 Zhao Y, Lee SY, Becknell N, Yaghi OM, Angell CA. Nanoporous Transparent MOF Glasses with 0.792
Accessible Internal Surface. Journal of the American Chemical Society.
PMID 27539546 DOI: 10.1021/Jacs.6B07078
2016 Catarineu NR, Schoedel A, Urban P, Morla MB, Trickett CA, Yaghi OM. Two Principles of 0.823
Reticular Chemistry Uncovered in a Metal-Organic Framework of Heterotritopic Linkers and
23
Infinite Secondary Building Units. Journal of the American Chemical Society.

PMID 27517606 DOI: 10.1021/Jacs.6B07267
2016 Jiang J, Furukawa H, Zhang YB, Yaghi OM. High Methane Storage Working Capacity in Metal- 0.747
Organic Frameworks with Acrylate Links. Journal of the American Chemical Society.
PMID 27442620 DOI: 10.1021/Jacs.6B05261
2016 Fracaroli AM, Siman P, Nagib DA, Suzuki M, Furukawa H, Toste FD, Yaghi OM. Seven Post- 0.325
Synthetic Covalent Reactions in Tandem Leading to Enzyme-Like Complexity within Metal-
Organic Framework Crystals. Journal of the American Chemical Society.
PMID 27346625 DOI: 10.1021/Jacs.6B04204
2016 Nguyen HL, Gándara F, Furukawa H, Doan TL, Cordova KE, Yaghi OM. A Titanium-Organic 0.847
Framework as an Exemplar of Combining the Chemistry of Metal- and Covalent-Organic
Frameworks. Journal of the American Chemical Society.
PMID 26998612 DOI: 10.1021/Jacs.6B01233
2016 Jiang J, Zhao Y, Yaghi OM. Covalent Chemistry Beyond Molecules. Journal of the American 0.78
2016 Liu Y, Ma Y, Zhao Y, Sun X, Gándara F, Furukawa H, Liu Z, Zhu H, Zhu C, Suenaga K, 0.73
Oleynikov P, Alshammari AS, Zhang X, Terasaki O, Yaghi OM. Weaving of organic threads into
a crystalline covalent organic framework. Science (New York, N.Y.). 351: 365-9.
PMID 26798010 DOI: 10.1126/Science.Aad4011
2016 Kim H, Cho HJ, Narayanan S, Yang S, Furukawa H, Schiffres S, Li X, Zhang YB, Jiang J, Yaghi 0.699
OM, Wang EN. Characterization of Adsorption Enthalpy of Novel Water-Stable Zeolites and
Metal-Organic Frameworks. Scientific Reports. 6: 19097.
PMID 26796523 DOI: 10.1038/Srep19097
2016 Schoedel A, Ji Z, Yaghi OM. The role of metal–organic frameworks in a carbon-neutral energy 0.796
cycle Nature Energy. 1. DOI: 10.1038/Nenergy.2016.34
2016 Rungtaweevoranit B, Zhao Y, Choi KM, Yaghi OM. Cooperative effects at the interface of 0.333
nanocrystalline metal–organic frameworks Nano Research. 9: 47-58. DOI: 10.1007/S12274-015-
24
0970-0
2015 Cordova KE, Furukawa H, Yaghi OM. The Development of Global Science. Acs Central Science. 0.773
1: 18-23. PMID 27162942 DOI: 10.1021/Acscentsci.5B00028
2015 Nguyen NT, Furukawa H, Gándara F, Trickett CA, Jeong HM, Cordova KE, Yaghi OM. Three- 0.799
Dimensional Metal-Catecholate Frameworks and their Ultrahigh Proton Conductivity. Journal of
the American Chemical Society. PMID 26595681 DOI: 10.1021/Jacs.5B10999
2015 Waller PJ, Gándara F, Yaghi OM. Chemistry of Covalent Organic Frameworks. Accounts of 0.335
Chemical Research. PMID 26580002 DOI: 10.1021/Acs.Accounts.5B00369
2015 Sukul PK, Bose P, Takei T, Yaghi OM, He Y, Lee M, Tashiro K. A water-soluble metal-organic 0.779
complex array as a multinuclear heterometallic peptide amphiphile that shows unconventional
anion dependency in its self-assembly. Chemical Communications (Cambridge, England).
PMID 26558655 DOI: 10.1039/C5Cc08973E
2015 Sung Cho H, Deng H, Miyasaka K, Dong Z, Cho M, Neimark AV, Ku Kang J, Yaghi OM, 0.57
Terasaki O. Extra adsorption and adsorbate superlattice formation in metal-organic
frameworks. Nature. PMID 26550825 DOI: 10.1038/Nature15734
2015 Kornienko N, Zhao Y, Kley CS, Zhu C, Kim D, Lin S, Chang CJ, Yaghi OM, Yang P. Metal- 0.764
Organic Frameworks for Electrocatalytic Reduction of Carbon Dioxide. Journal of the American
2015 Siman P, Trickett CA, Furukawa H, Yaghi OM. l-Aspartate links for stable sodium metal-organic 0.364
frameworks. Chemical Communications (Cambridge, England).
PMID 26473175 DOI: 10.1039/C5Cc07578E
2015 Trickett CA, Gagnon KJ, Lee S, Gándara F, Bürgi HB, Yaghi OM. Definitive Molecular Level 0.364
Characterization of Defects in UiO-66 Crystals. Angewandte Chemie (International Ed. in
English). 54: 11162-7. PMID 26352027 DOI: 10.1002/Anie.201505461
2015 Lin S, Diercks CS, Zhang YB, Kornienko N, Nichols EM, Zhao Y, Paris AR, Kim D, Yang 0.797
P, Yaghi OM, Chang CJ. Covalent organic frameworks comprising cobalt porphyrins for catalytic
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CO2 reduction in water. Science (New York, N.Y.).

PMID 26292706 DOI: 10.1126/Science.Aac8343
2015 Sue AC, Mannige RV, Deng H, Cao D, Wang C, Gándara F, Stoddart JF, Whitelam S, Yaghi OM. 0.827
Heterogeneity of functional groups in a metal-organic framework displays magic number
ratios. Proceedings of the National Academy of Sciences of the United States of America. 112:
5591-6. PMID 25901326 DOI: 10.1073/Pnas.1416417112
2015 Zhang YB, Furukawa H, Ko N, Nie W, Park HJ, Okajima S, Cordova KE, Deng H, Kim J, Yaghi 0.835
OM. Introduction of functionality, selection of topology, and enhancement of gas adsorption in
multivariate metal-organic framework-177. Journal of the American Chemical Society. 137: 2641-
50. PMID 25646798 DOI: 10.1021/Ja512311A
2015 Zhao Y, Kornienko N, Liu Z, Zhu C, Asahina S, Kuo TR, Bao W, Xie C, Hexemer A, Terasaki 0.769
O, Yang P, Yaghi OM. Mesoscopic constructs of ordered and oriented metal-organic frameworks
on plasmonic silver nanocrystals. Journal of the American Chemical Society. 137: 2199-202.
PMID 25622094 DOI: 10.1021/Ja512951E
2015 Sajna K, Fracaroli AM, Yaghi OM, Tashiro K. Modular synthesis of metal-organic complex 0.701
arrays containing precisely designed metal sequences. Inorganic Chemistry. 54: 1197-9.
PMID 25602193 DOI: 10.1021/Ic5025372
2015 Furukawa H, Müller U, Yaghi OM. "Heterogeneity within order" in metal-organic 0.396
frameworks. Angewandte Chemie (International Ed. in English). 54: 3417-30.
PMID 25586609 DOI: 10.1002/Anie.201410252
2014 Klonowski P, Goloboy JC, Uribe-Romo FJ, Sun F, Zhu L, Gándara F, Wills C, Errington 0.782
RJ, Yaghi OM, Klemperer WG. Synthesis and characterization of the platinum-substituted Keggin
anion α-H2SiPtW11O40(4-). Inorganic Chemistry. 53: 13239-46.
PMID 25409288 DOI: 10.1021/Ic502617K
2014 Jiang J, Gándara F, Zhang YB, Na K, Yaghi OM, Klemperer WG. Superacidity in sulfated metal- 0.797
organic framework-808. Journal of the American Chemical Society. 136: 12844-7.
PMID 25157587 DOI: 10.1021/Ja507119N
26
2014 Nguyen NT, Furukawa H, Gándara F, Nguyen HT, Cordova KE, Yaghi OM. Selective capture of 0.821
carbon dioxide under humid conditions by hydrophobic chabazite-type zeolitic imidazolate
PMID 25044990 DOI: 10.1002/Anie.201403980
2014 Choi KM, Jeong HM, Park JH, Zhang YB, Kang JK, Yaghi OM. Supercapacitors of 0.724
nanocrystalline metal-organic frameworks. Acs Nano. 8: 7451-7.
PMID 24999543 DOI: 10.1021/Nn5027092
2014 Wang LJ, Deng H, Furukawa H, Gándara F, Cordova KE, Peri D, Yaghi OM. Synthesis and 0.828
characterization of metal-organic framework-74 containing 2, 4, 6, 8, and 10 different
metals. Inorganic Chemistry. 53: 5881-3. PMID 24878113 DOI: 10.1021/Ic500434A
2014 Gándara F, Furukawa H, Lee S, Yaghi OM. High methane storage capacity in aluminum metal- 0.348
organic frameworks. Journal of the American Chemical Society. 136: 5271-4.
PMID 24661065 DOI: 10.1021/Ja501606H
2014 Furukawa H, Gándara F, Zhang YB, Jiang J, Queen WL, Hudson MR, Yaghi OM. Water 0.721
adsorption in porous metal-organic frameworks and related materials. Journal of the American
Chemical Society. 136: 4369-81. PMID 24588307 DOI: 10.1021/Ja500330A
2014 Li D, Furukawa H, Deng H, Liu C, Yaghi OM, Eisenberg DS. Designed amyloid fibers as 0.469
materials for selective carbon dioxide capture. Proceedings of the National Academy of Sciences of
the United States of America. 111: 191-6. PMID 24367077 DOI: 10.1073/Pnas.1321797111
2014 Li M, Li D, O'Keeffe M, Yaghi OM. Topological analysis of metal-organic frameworks with 0.411
polytopic linkers and/or multiple building units and the minimal transitivity principle. Chemical
Reviews. 114: 1343-70. PMID 24191753 DOI: 10.1021/Cr400392K
2014 Barman S, Khutia A, Koitz R, Blacque O, Furukawa H, Iannuzzi M, Yaghi OM, Janiak C, Hutter 0.394
J, Berke H. Synthesis and hydrogen adsorption properties of internally polarized 2,6-
azulenedicarboxylate based metal-organic frameworks Journal of Materials Chemistry A. 2:
18823-18830. DOI: 10.1039/C4Ta04393F
2014 Wang LJ, Deng H, Furukawa H, Gándara F, Cordova KE, Peri D, Yaghi OM. Synthesis and 0.775
characterization of metal-organic framework-74 containing 2, 4, 6, 8, and 10 different
27
metals Inorganic Chemistry. 53: 5881-5883. DOI: 10.1021/ic500434a
2014 Li M, Li D, O'Keeffe M, Yaghi OM. Topological analysis of metal-organic frameworks with 0.4
polytopic linkers and/or multiple building units and the minimal transitivity principle Chemical
Reviews. 114: 1343-1370. DOI: 10.1021/cr400392k
2014 Suga M, Asahina S, Sakuda Y, Kazumori H, Nishiyama H, Nokuo T, Alfredsson V, Kjellman T, 0.586
Stevens SM, Cho HS, Cho M, Han L, Che S, Anderson MW, Schüth F, ... ... Yaghi OM, et al.
Recent progress in scanning electron microscopy for the characterization of fine structural details
of nano materials Progress in Solid State Chemistry. 42: 1-21.
DOI: 10.1016/J.Progsolidstchem.2014.02.001
2014 Nguyen NTT, Furukawa H, Gándara F, Nguyen HT, Cordova KE, Yaghi OM. Back Cover: 0.775
Selective Capture of Carbon Dioxide under Humid Conditions by Hydrophobic Chabazite-Type
Zeolitic Imidazolate Frameworks (Angew. Chem. Int. Ed. 40/2014) Angewandte Chemie
International Edition. 53: 10828-10828. DOI: 10.1002/Anie.201406995
2014 Nguyen NTT, Furukawa H, Gándara F, Nguyen HT, Cordova KE, Yaghi OM. Selective capture 0.775
of carbon dioxide under humid conditions by hydrophobic chabazite-type zeolitic imidazolate
frameworks Angewandte Chemie - International Edition. 53: 10645-10648.
DOI: 10.1002/anie.201403980
2014 Nguyen NTT, Furukawa H, Gándara F, Nguyen HT, Cordova KE, Yaghi OM. Rücktitelbild: 0.775
Selective Capture of Carbon Dioxide under Humid Conditions by Hydrophobic Chabazite-Type
Zeolitic Imidazolate Frameworks (Angew. Chem. 40/2014) Angewandte Chemie. 126: 11004-
11004. DOI: 10.1002/Ange.201406995
2013 Peri D, Ciston J, Gándara F, Zhao Y, Yaghi OM. Crystalline fibers of metal-peptide double 0.772
ladders Inorganic Chemistry. 52: 13818-13820. PMID 24256366 DOI: 10.1021/Ic402435Z
2013 Zhang YB, Su J, Furukawa H, Yun Y, Gándara F, Duong A, Zou X, Yaghi OM. Single-crystal 0.703
structure of a covalent organic framework. Journal of the American Chemical Society. 135: 16336-
9. PMID 24143961 DOI: 10.1021/Ja409033P
2013 Hwang Y, Sohn H, Phan A, Yaghi OM, Candler RN. Dielectrophoresis-assembled zeolitic 0.557
imidazolate framework nanoparticle-coupled resonators for highly sensitive and selective gas
28
detection. Nano Letters. 13: 5271-6. PMID 24099583 DOI: 10.1021/Nl4027692
2013 Furukawa H, Cordova KE, O'Keeffe M, Yaghi OM. The chemistry and applications of metal- 0.841
organic frameworks. Science (New York, N.Y.). 341: 1230444.
PMID 23990564 DOI: 10.1126/Science.1230444
2013 Kong X, Deng H, Yan F, Kim J, Swisher JA, Smit B, Yaghi OM, Reimer JA. Mapping of 0.6
functional groups in metal-organic frameworks. Science (New York, N.Y.). 341: 882-5.
PMID 23887875 DOI: 10.1126/Science.1238339
2013 Furukawa H, Cordova KE, O'Keeffe M, Yaghi OM. The chemistry and applications of metal- 0.776
organic frameworks Science. 341. DOI: 10.1126/science.1230444
2013 Hwang Y, Phan A, Galatsis K, Yaghi OM, Candler RN. Zeolitic imidazolate framework-coupled 0.534
resonators for enhanced gas detection Journal of Micromechanics and Microengineering. 23.
DOI: 10.1088/0960-1317/23/12/125027
2013 Brown JW, Henderson BL, Kiesz MD, Whalley AC, Morris W, Grunder S, Deng H, Furukawa 0.65
H, Zink JI, Stoddart JF, Yaghi OM. Photophysical pore control in an azobenzene-containing
metal-organic framework Chemical Science. 4: 2858-2864. DOI: 10.1039/C3Sc21659D
2013 Houndonougbo Y, Signer C, He N, Morris W, Furukawa H, Ray KG, Olmsted DL, Asta M, Laird 0.304
BB, Yaghi OM. A combined experimental-computational investigation of methane adsorption and
selectivity in a series of isoreticular zeolitic imidazolate frameworks Journal of Physical
Chemistry C. 117: 10326-10335. DOI: 10.1021/Jp3096192
2012 Choi SB, Furukawa H, Nam HJ, Jung DY, Jhon YH, Walton A, Book D, O'Keeffe M, Yaghi OM, 0.578
Kim J. Reversible interpenetration in a metal-organic framework triggered by ligand removal and
addition. Angewandte Chemie (International Ed. in English). 51: 8791-5.
PMID 22807234 DOI: 10.1002/Anie.201202925
2012 Gándara F, Uribe-Romo FJ, Britt DK, Furukawa H, Lei L, Cheng R, Duan X, O'Keeffe M, Yaghi 0.829
OM. Porous, conductive metal-triazolates and their structural elucidation by the charge-flipping
method. Chemistry (Weinheim An Der Bergstrasse, Germany). 18: 10595-601.
PMID 22730149 DOI: 10.1002/Chem.201103433
29
2012 Morris W, Volosskiy B, Demir S, GÃ¡ndara F, McGrier PL, Furukawa H, Cascio D, Stoddart 0.512
JF, Yaghi OM. Synthesis, structure, and metalation of two new highly porous zirconium metal-
organic frameworks. Inorganic Chemistry. 51: 6443-5. PMID 22676251 DOI: 10.1021/Ic300825S
2012 Fracaroli AM, Tashiro K, Yaghi OM. Isomers of metal-organic complex arrays. Inorganic 0.697
Chemistry. 51: 6437-9. PMID 22667815 DOI: 10.1021/Ic300744X
2012 Deng H, Grunder S, Cordova KE, Valente C, Furukawa H, Hmadeh M, Gándara F, Whalley AC, 0.836
Liu Z, Asahina S, Kazumori H, O'Keeffe M, Terasaki O, Stoddart JF, Yaghi OM. Large-pore
apertures in a series of metal-organic frameworks. Science (New York, N.Y.). 336: 1018-23.
PMID 22628651 DOI: 10.1126/Science.1220131
2012 Zhou HC, Long JR, Yaghi OM. Introduction to metal-organic frameworks. Chemical Reviews. 0.51
112: 673-4. PMID 22280456 DOI: 10.1021/Cr300014X
2012 Coskun A, Hmadeh M, Barin G, Gándara F, Li Q, Choi E, Strutt NL, Cordes DB, Slawin 0.608
AM, Stoddart JF, Sauvage JP, Yaghi OM. Metal-organic frameworks incorporating copper-
complexed rotaxanes. Angewandte Chemie (International Ed. in English). 51: 2160-3.
PMID 22266928 DOI: 10.1002/Anie.201107873
2012 O'Keeffe M, Yaghi OM. Deconstructing the crystal structures of metal-organic frameworks and 0.4
related materials into their underlying nets. Chemical Reviews. 112: 675-702.
PMID 21916513 DOI: 10.1021/Cr200205J
2012 Morris W, He N, Ray KG, Klonowski P, Furukawa H, Daniels IN, Houndonougbo YA, Asta 0.344
M, Yaghi OM, Laird BB. A combined experimental-computational study on the effect of topology
on carbon dioxide adsorption in zeolitic imidazolate frameworks Journal of Physical Chemistry C.
116: 24084-24090. DOI: 10.1021/Jp307170A
2012 Tranchemontagne DJ, Park KS, Furukawa H, Eckert J, Knobler CB, Yaghi OM. Hydrogen 0.837
storage in new metal-organic frameworks Journal of Physical Chemistry C. 116: 13143-13151.
DOI: 10.1021/Jp302356Q
2012 O'Keeffe M, Yaghi OM. Deconstructing the crystal structures of metal-organic frameworks and 0.4
related materials into their underlying nets Chemical Reviews. 112: 675-702.
DOI: 10.1021/cr200205j
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2012 Choi SB, Furukawa H, Nam HJ, Jung DY, Jhon YH, Walton A, Book D, O'Keeffe M, Yaghi 0.4
OM, Kim J. Reversible interpenetration in a metal-organic framework triggered by ligand removal
and addition Angewandte Chemie - International Edition. 51: 8791-8795.
DOI: 10.1002/anie.201202925
2011 Barman S, Furukawa H, Blacque O, Venkatesan K, Yaghi OM, Jin GX, Berke H. Incorporation of 0.375
active metal sites in MOFs via in situ generated ligand deficient metal-linker complexes. Chemical
Communications (Cambridge, England). 47: 11882-4.
PMID 21983899 DOI: 10.1039/C1Cc14387E
2011 Song J, Luo Z, Britt DK, Furukawa H, Yaghi OM, Hardcastle KI, Hill CL. A multiunit catalyst 0.805
with synergistic stability and reactivity: a polyoxometalate-metal organic framework for aerobic
decontamination. Journal of the American Chemical Society. 133: 16839-46.
PMID 21913693 DOI: 10.1021/Ja203695H
2011 Gassensmith JJ, Furukawa H, Smaldone RA, Forgan RS, Botros YY, Yaghi OM, Stoddart JF. 0.514
Strong and reversible binding of carbon dioxide in a green metal-organic framework. Journal of
the American Chemical Society. 133: 15312-5. PMID 21877735 DOI: 10.1021/Ja206525X
2011 Furukawa H, Go YB, Ko N, Park YK, Uribe-Romo FJ, Kim J, O'Keeffe M, Yaghi OM. 0.782
Isoreticular expansion of metal-organic frameworks with triangular and square building units and
the lowest calculated density for porous crystals. Inorganic Chemistry. 50: 9147-52.
PMID 21842896 DOI: 10.1021/Ic201376T
2011 Phan A, Czaja AU, Gándara F, Knobler CB, Yaghi OM. Metal-organic frameworks of vanadium 0.568
as catalysts for conversion of methane to acetic acid Inorganic Chemistry. 50: 7388-7390.
PMID 21766786 DOI: 10.1021/Ic201396M
2011 Choi KM, Jeon HJ, Kang JK, Yaghi OM. Heterogeneity within order in crystals of a porous 0.301
metal-organic framework Journal of the American Chemical Society. 133: 11920-11923.
PMID 21749096 DOI: 10.1021/Ja204818Q
2011 Uribe-Romo FJ, Doonan CJ, Furukawa H, Oisaki K, Yaghi OM. Crystalline covalent organic 0.743
frameworks with hydrazone linkages. Journal of the American Chemical Society. 133: 11478-81.
PMID 21721558 DOI: 10.1021/Ja204728Y
31
2011 Vairaprakash P, Ueki H, Tashiro K, Yaghi OM. Synthesis of metal−organic complex 0.642
arrays. Journal of the American Chemical Society. 133: 759-61.
PMID 21174403 DOI: 10.1021/Ja1097644
2011 Queen WL, Brown CM, Britt DK, Zajdel P, Hudson MR, Yaghi OM. Site-specific CO 2 0.759
adsorption and zero thermal expansion in an anisotropic pore network Journal of Physical
Chemistry C. 115: 24915-24919. DOI: 10.1021/Jp208529P
2011 Wan S, Gándara F, Asano A, Furukawa H, Saeki A, Dey SK, Liao L, Ambrogio MW, Botros YY, 0.428
Duan X, Seki S, Stoddart JF, Yaghi OM. Covalent organic frameworks with high charge carrier
mobility Chemistry of Materials. 23: 4094-4097. DOI: 10.1021/Cm201140R
2011 Grant Glover T, Peterson GW, Schindler BJ, Britt D, Yaghi O. MOF-74 building unit has a direct 0.784
impact on toxic gas adsorption Chemical Engineering Science. 66: 163-170.
DOI: 10.1016/J.Ces.2010.10.002
2010 Doonan CJ, Tranchemontagne DJ, Glover TG, Hunt JR, Yaghi OM. Exceptional ammonia uptake 0.825
by a covalent organic framework Nature Chemistry. 2: 235-238.
PMID 21124483 DOI: 10.1038/Nchem.548
2010 Barman S, Furukawa H, Blacque O, Venkatesan K, Yaghi OM, Berke H. Azulene based metal- 0.351
organic frameworks for strong adsorption of H2. Chemical Communications (Cambridge,
England). 46: 7981-3. PMID 20871899 DOI: 10.1039/C0Cc02589E
2010 Bloch ED, Britt D, Lee C, Doonan CJ, Uribe-Romo FJ, Furukawa H, Long JR, Yaghi OM. Metal 0.809
insertion in a microporous metal-organic framework lined with 2,2'-bipyridine. Journal of the
American Chemical Society. 132: 14382-4. PMID 20849109 DOI: 10.1021/Ja106935D
2010 Li Q, Sue CH, Basu S, Shveyd AK, Zhang W, Barin G, Fang L, Sarjeant AA, Stoddart JF, Yaghi 0.718
OM. A catenated strut in a catenated metal-organic framework. Angewandte Chemie
(International Ed. in English). 49: 6751-5. PMID 20715253 DOI: 10.1002/Anie.201003221
2010 Smaldone RA, Forgan RS, Furukawa H, Gassensmith JJ, Slawin AM, Yaghi OM, Stoddart JF. 0.529
Metal-organic frameworks from edible natural products. Angewandte Chemie (International Ed. in
English). 49: 8630-4. PMID 20715239 DOI: 10.1002/Anie.201002343
32
2010 Morris W, Leung B, Furukawa H, Yaghi OK, He N, Hayashi H, Houndonougbo Y, Asta M, Laird 0.323
BB, Yaghi OM. A combined experimental-computational investigation of carbon dioxide capture
in a series of isoreticular zeolitic imidazolate frameworks. Journal of the American Chemical
Society. 132: 11006-8. PMID 20698658 DOI: 10.1021/Ja104035J
2010 Furukawa H, Ko N, Go YB, Aratani N, Choi SB, Choi E, Yazaydin AO, Snurr RQ, O'Keeffe 0.668
M, Kim J, Yaghi OM. Ultrahigh porosity in metal-organic frameworks. Science (New York, N.Y.).
329: 424-8. PMID 20595583 DOI: 10.1126/Science.1192160
2010 Britt D, Lee C, Uribe-Romo FJ, Furukawa H, Yaghi OM. Ring-opening reactions within porous 0.838
metal-organic frameworks. Inorganic Chemistry. 49: 6387-9.
PMID 20560600 DOI: 10.1021/Ic100652X
2010 Oisaki K, Li Q, Furukawa H, Czaja AU, Yaghi OM. A metal-organic framework with covalently 0.558
bound organometallic complexes. Journal of the American Chemical Society. 132: 9262-4.
PMID 20557041 DOI: 10.1021/Ja103016Y
2010 Valente C, Choi E, Belowich ME, Doonan CJ, Li Q, Gasa TB, Botros YY, Yaghi OM, Stoddart 0.663
JF. Metal-organic frameworks with designed chiral recognition sites. Chemical Communications
(Cambridge, England). 46: 4911-3. PMID 20523946 DOI: 10.1039/C0Cc00997K
2010 Deng H, Olson MA, Stoddart JF, Yaghi OM. Robust dynamics Nature Chemistry. 2: 439-443. 0.6
PMID 20489710 DOI: 10.1038/nchem.654
2010 Deng H, Doonan CJ, Furukawa H, Ferreira RB, Towne J, Knobler CB, Wang B, Yaghi OM. 0.606
Multiple functional groups of varying ratios in metal-organic frameworks Science. 327: 846-850.
PMID 20150497 DOI: 10.1126/Science.1181761
2010 Li Q, Zhang W, Miljani? OS, Knobler CB, Stoddart JF, Yaghi OM. A metal-organic framework 0.704
replete with ordered donor-acceptor catenanes. Chemical Communications (Cambridge, England).
46: 380-2. PMID 20066298 DOI: 10.1039/B919923C
2010 Phan A, Doonan CJ, Uribe-Romo FJ, Knobler CB, O'Keeffe M, Yaghi OM. Synthesis, structure, 0.832
and carbon dioxide capture properties of zeolitic imidazolate frameworks. Accounts of Chemical
Research. 43: 58-67. PMID 19877580 DOI: 10.1021/Ar900116G
33
2010 Valente C, Choi E, Belowich ME, Doonan CJ, Li Q, Gasa TB, Botros YY, Yaghi OM, Stoddart 0.485
JF. Metal-organic frameworks with designed chiral recognition sites Chemical Communications.
46: 4911-4913. DOI: 10.1039/c0cc00997k
2010 YAGHI OM, SCOTT MJ, HOLM RH. ChemInform Abstract: Rhenium-Selenium-Chlorine Solid 0.515
Phases: Cluster Excision and Core Substitution Reactions of Molecular Species. Cheminform. 24:
no-no. DOI: 10.1002/chin.199306034
2010 Smaldone RA, Forgan RS, Furukawa H, Gassensmith JJ, Slawin AMZ, Yaghi OM, Stoddart JF. 0.316
Cover Picture: Metal-Organic Frameworks from Edible Natural Products (Angew. Chem. Int. Ed.
46/2010) Angewandte Chemie International Edition. 49: 8535-8535.
DOI: 10.1002/Anie.201004618
Metalorganic frameworks from edible natural products Angewandte Chemie - International
Edition. 49: 8630-8634. DOI: 10.1002/anie.201002343
Titelbild: Metal-Organic Frameworks from Edible Natural Products (Angew. Chem.
46/2010) Angewandte Chemie. 122: 8715-8715. DOI: 10.1002/Ange.201004618
2009 Britt D, Furukawa H, Wang B, Glover TG, Yaghi OM. Highly efficient separation of carbon 0.781
dioxide by a metal-organic framework replete with open metal sites Proceedings of the National
Academy of Sciences of the United States of America. 106: 20637-20640.
PMID 19948967 DOI: 10.1073/Pnas.0909718106
2009 Zhao YL, Liu L, Zhang W, Sue CH, Li Q, Miljani? OS, Yaghi OM, Stoddart JF. Rigid-strut- 0.735
containing crown ethers and [2]catenanes for incorporation into metal-organic
frameworks. Chemistry (Weinheim An Der Bergstrasse, Germany). 15: 13356-80.
PMID 19946906 DOI: 10.1002/Chem.200902350
2009 Lu Z, Knobler CB, Furukawa H, Wang B, Liu G, Yaghi OM. Synthesis and structure of 0.303
chemically stable metal-organic polyhedra. Journal of the American Chemical Society. 131:
12532-3. PMID 19689142 DOI: 10.1021/Ja905101S
34
2009 Li Q, Zhang W, Miljani? OS, Sue CH, Zhao YL, Liu L, Knobler CB, Stoddart JF, Yaghi OM. 0.729
Docking in metal-organic frameworks. Science (New York, N.Y.). 325: 855-9.
PMID 19679809 DOI: 10.1126/Science.1175441
2009 Tranchemontagne DJ, Mendoza-Cortés JL, O'Keeffe M, Yaghi OM. Secondary building units, 0.829
nets and bonding in the chemistry of metal-organic frameworks. Chemical Society Reviews. 38:
1257-83. PMID 19384437 DOI: 10.1039/B817735J
2009 Long JR, Yaghi OM. The pervasive chemistry of metal-organic frameworks. Chemical Society 0.386
Reviews. 38: 1213-4. PMID 19384431 DOI: 10.1039/B903811F
2009 Banerjee R, Furukawa H, Britt D, Knobler C, O'Keeffe M, Yaghi OM. Control of pore size and 0.833
functionality in isoreticular zeolitic imidazolate frameworks and their carbon dioxide selective
capture properties. Journal of the American Chemical Society. 131: 3875-7.
PMID 19292488 DOI: 10.1021/Ja809459E
2009 Uribe-Romo FJ, Hunt JR, Furukawa H, Klöck C, O'Keeffe M, Yaghi OM. A crystalline imine- 0.829
linked 3-D porous covalent organic framework. Journal of the American Chemical Society. 131:
4570-1. PMID 19281246 DOI: 10.1021/Ja8096256
2009 Yaghi OM, Li Q. Reticular chemistry and metal-organic frameworks for clean energy Mrs 0.528
Bulletin. 34: 682-690. DOI: 10.1557/Mrs2009.180
2009 Tranchemontagne DJ, Mendoza-Cortés JL, O'Keeffe M, Yaghi OM. Secondary building units, 0.776
nets and bonding in the chemistry of metal-organic frameworks Chemical Society Reviews. 38:
1257-1283. DOI: 10.1039/b817735j
2009 Banerjee R, Furukawa H, Britt D, Knobler C, O'Keeffe M, Yaghi OM. Control of pore size and 0.776
functionality in isoreticular zeolitic imidazolate frameworks and their carbon dioxide selective
capture properties Journal of the American Chemical Society. 131: 3875-3877.
DOI: 10.1021/ja809459e
2009 Zhao Y, Liu L, Zhang W, Sue C, Li Q, MiljanicÌ O, Yaghi O, Stoddart J. Cover Picture: Rigid- 0.631
Strut-Containing Crown Ethers and [2]Catenanes for Incorporation into Metalâ “Organic
Frameworks (Chem. Eur. J. 48/2009) Chemistry - a European Journal. 15: 13269-13269.
35
DOI: 10.1002/Chem.200990191
2008 O'Keeffe M, Peskov MA, Ramsden SJ, Yaghi OM. The Reticular Chemistry Structure Resource 0.564
(RCSR) database of, and symbols for, crystal nets. Accounts of Chemical Research. 41: 1782-9.
PMID 18834152 DOI: 10.1021/Ar800124U
2008 Morris W, Doonan CJ, Furukawa H, Banerjee R, Yaghi OM. Crystals as molecules: postsynthesis 0.582
covalent functionalization of zeolitic imidazolate frameworks. Journal of the American Chemical
Society. 130: 12626-7. PMID 18754585 DOI: 10.1021/Ja805222X
2008 Britt D, Tranchemontagne D, Yaghi OM. Metal-organic frameworks with high capacity and 0.833
selectivity for harmful gases Proceedings of the National Academy of Sciences of the United States
of America. 105: 11623-11627. PMID 18711128 DOI: 10.1073/Pnas.0804900105
2008 Hunt JR, Doonan CJ, LeVangie JD, Côté AP, Yaghi OM. Reticular synthesis of covalent organic 0.644
borosilicate frameworks. Journal of the American Chemical Society. 130: 11872-3.
PMID 18707184 DOI: 10.1021/Ja805064F
2008 Furukawa H, Kim J, Ockwig NW, O'Keeffe M, Yaghi OM. Control of vertex geometry, structure 0.824
dimensionality, functionality, and pore metrics in the reticular synthesis of crystalline metal-
organic frameworks and polyhedra. Journal of the American Chemical Society. 130: 11650-61.
PMID 18693690 DOI: 10.1021/Ja803783C
2008 Tranchemontagne DJ, Ni Z, O'Keeffe M, Yaghi OM. Reticular chemistry of metal-organic 0.825
polyhedra. Angewandte Chemie (International Ed. in English). 47: 5136-47.
PMID 18528833 DOI: 10.1002/Anie.200705008
2008 Wang B, Côté AP, Furukawa H, O'Keeffe M, Yaghi OM. Colossal cages in zeolitic imidazolate 0.576
frameworks as selective carbon dioxide reservoirs. Nature. 453: 207-11.
PMID 18464739 DOI: 10.1038/Nature06900
2008 Gould SL, Tranchemontagne D, Yaghi OM, Garcia-Garibay MA. Amphidynamic character of 0.81

crystalline MOF-5: rotational dynamics of terephthalate phenylenes in a free-volume, sterically
unhindered environment. Journal of the American Chemical Society. 130: 3246-7.
PMID 18288839 DOI: 10.1021/Ja077122C
36
2008 Banerjee R, Phan A, Wang B, Knobler C, Furukawa H, O'Keeffe M, Yaghi OM. High-throughput 0.763
synthesis of zeolitic imidazolate frameworks and application to CO2 capture. Science (New York,
N.Y.). 319: 939-43. PMID 18276887 DOI: 10.1126/Science.1152516
2008 Walton KS, Millward AR, Dubbeldam D, Frost H, Low JJ, Yaghi OM, Snurr RQ. Understanding 0.816
inflections and steps in carbon dioxide adsorption isotherms in metal-organic frameworks. Journal
of the American Chemical Society. 130: 406-7. PMID 18154291 DOI: 10.1021/Ja076595G
2008 Walton KS, Millward AR, Dubbeldam D, Frost H, Low JJ, Yaghi OM, Snurr RQ. Understanding 0.776
inflections and steps in carbon dioxide adsorption isotherms in metal-organic frameworks Journal
of the American Chemical Society. 130: 406-407. DOI: 10.1021/ja076595g
2008 O'Keeffe M, Peskov MA, Ramsden SJ, Yaghi OM. The Reticular Chemistry Structure Resource 0.4
(RCSR) database of, and symbols for, crystal nets Accounts of Chemical Research. 41: 1782-1789.
DOI: 10.1021/ar800124u
2008 Tranchemontagne DJ, Hunt JR, Yaghi OM. Room temperature synthesis of metal-organic 0.842
frameworks: MOF-5, MOF-74, MOF-177, MOF-199, and IRMOF-0 Tetrahedron. 64: 8553-8557.
DOI: 10.1016/J.Tet.2008.06.036
2008 Tranchemontagne DJ, Hunt JR, Yaghi OM. ChemInform Abstract: Room Temperature Synthesis 0.776
of Metal-Organic Frameworks: MOF-5, MOF-74, MOF-177, MOF-199, and IRMOF-
0. Cheminform. 39. DOI: 10.1002/chin.200846226
2008 Tranchemontagne D, Ni Z, O'Keeffe M, Yaghi O. Retikuläre Chemie metall‐organischer 0.794

Polyeder Angewandte Chemie. 120: 5214-5225. DOI: 10.1002/Ange.200705008
2007 Kaye SS, Dailly A, Yaghi OM, Long JR. Impact of preparation and handling on the hydrogen 0.53
storage properties of Zn4O(1,4-benzenedicarboxylate)3 (MOF-5). Journal of the American
Chemical Society. 129: 14176-7. PMID 17967030 DOI: 10.1021/Ja076877G
2007 Côté AP, El-Kaderi HM, Furukawa H, Hunt JR, Yaghi OM. Reticular synthesis of microporous 0.639
and mesoporous 2D covalent organic frameworks. Journal of the American Chemical Society. 129:
12914-5. PMID 17918943 DOI: 10.1021/Ja0751781
37
2007 Hayashi H, Côté AP, Furukawa H, O'Keeffe M, Yaghi OM. Zeolite A imidazolate 0.589
frameworks. Nature Materials. 6: 501-6. PMID 17529969 DOI: 10.1038/nmat1927
2007 El-Kaderi HM, Hunt JR, Mendoza-Cortés JL, Côté AP, Taylor RE, O'Keeffe M, Yaghi OM. 0.669
Designed synthesis of 3D covalent organic frameworks. Science (New York, N.Y.). 316: 268-72.
PMID 17431178 DOI: 10.1126/Science.1139915
2007 Delgado-Friedrichs O, O'Keeffe M, Yaghi OM. Taxonomy of periodic nets and the design of 0.472
materials. Physical Chemistry Chemical Physics : Pccp. 9: 1035-43.
PMID 17311144 DOI: 10.1039/B615006C
2007 Furukawa H, Miller MA, Yaghi OM. Independent verification of the saturation hydrogen uptake 0.329
in MOF-177 and establishment of a benchmark for hydrogen adsorption in metal-organic
frameworks Journal of Materials Chemistry. 17: 3197-3204. DOI: 10.1039/B703608F
2007 Pawsey S, Moudrakovski I, Ripmeester J, Wang LQ, Exarhos GJ, Rowsell JLC, Yaghi OM. 0.573
Hyperpolarized 129Xe nuclear magnetic resonance studies of isoreticular metal-organic
frameworks Journal of Physical Chemistry C. 111: 6060-6067. DOI: 10.1021/Jp0668246
2007 Huang BL, Ni Z, Millward A, McGaughey AJH, Uher C, Kaviany M, Yaghi O. Thermal 0.78
conductivity of a metal-organic framework (MOF-5): Part II. Measurement International Journal
of Heat and Mass Transfer. 50: 405-411. DOI: 10.1016/J.Ijheatmasstransfer.2006.10.001
2006 Delgado-Friedrichs O, O'Keeffe M, Yaghi OM. Three-periodic nets and tilings: edge-transitive 0.456
binodal structures. Acta Crystallographica. Section a, Foundations of Crystallography. 62: 350-5.
PMID 16926483 DOI: 10.1107/S0108767306022707
2006 Park KS, Ni Z, Côté AP, Choi JY, Huang R, Uribe-Romo FJ, Chae HK, O'Keeffe M, Yaghi OM. 0.834
Exceptional chemical and thermal stability of zeolitic imidazolate frameworks. Proceedings of the
National Academy of Sciences of the United States of America. 103: 10186-91.
PMID 16798880 DOI: 10.1073/Pnas.0602439103
2006 Sudik AC, Côté AP, Wong-Foy AG, O'Keeffe M, Yaghi OM. A metal-organic framework with a 0.823
hierarchical system of pores and tetrahedral building blocks. Angewandte Chemie (International
Ed. in English). 45: 2528-33. PMID 16570337 DOI: 10.1002/Anie.200600175
38
2006 Wong-Foy AG, Matzger AJ, Yaghi OM. Exceptional H2 saturation uptake in microporous metal- 0.362
PMID 16536503 DOI: 10.1021/Ja058213H
2006 Grzesiak AL, Uribe FJ, Ockwig NW, Yaghi OM, Matzger AJ. Polymer-induced heteronucleation 0.781
for the discovery of new extended solids. Angewandte Chemie (International Ed. in English). 45:
2553-6. PMID 16534819 DOI: 10.1002/Anie.200504312
2006 Rowsell JL, Yaghi OM. Effects of functionalization, catenation, and variation of the metal oxide 0.642
and organic linking units on the low-pressure hydrogen adsorption properties of metal-organic
frameworks. Journal of the American Chemical Society. 128: 1304-15.
PMID 16433549 DOI: 10.1021/Ja056639Q
2006 Chen B, Liang C, Yang J, Contreras DS, Clancy YL, Lobkovsky EB, Yaghi OM, Dai S. A 0.507
microporous metal-organic framework for gas-chromatographic separation of
alkanes. Angewandte Chemie (International Ed. in English). 45: 1390-3.
PMID 16425335 DOI: 10.1002/Anie.200502844
2006 Spencer EC, Howard JA, McIntyre GJ, Rowsell JL, Yaghi OM. Determination of the hydrogen 0.552
absorption sites in Zn4O(1,4-benzenedicarboxylate) by single crystal neutron
diffraction. Chemical Communications (Cambridge, England). 278-80.
PMID 16391733 DOI: 10.1039/B511941C
2006 Stallmach F, Gröger S, Künzel V, Kärger J, Yaghi OM, Hesse M, Müller U. NMR- 0.309
Untersuchungen zur Diffusion von Kohlenwasserstoffen im metall-organischen Netzwerk MOF-
5 Angewandte Chemie. 118: 2177-2181. DOI: 10.1002/Ange.200502553
2005 Millward AR, Yaghi OM. Metal-organic frameworks with exceptionally high capacity for storage 0.842
of carbon dioxide at room temperature. Journal of the American Chemical Society. 127: 17998-9.
PMID 16366539 DOI: 10.1021/ja0570032
2005 Côté AP, Benin AI, Ockwig NW, O'Keeffe M, Matzger AJ, Yaghi OM. Porous, crystalline, 0.8
covalent organic frameworks. Science (New York, N.Y.). 310: 1166-70.
PMID 16293756 DOI: 10.1126/Science.1120411
39
2005 Rowsell JL, Eckert J, Yaghi OM. Characterization of H2 binding sites in prototypical metal- 0.595
organic frameworks by inelastic neutron scattering. Journal of the American Chemical Society.
127: 14904-10. PMID 16231946 DOI: 10.1021/Ja0542690
2005 Ni Z, Yassar A, Antoun T, Yaghi OM. Porous metal-organic truncated octahedron constructed 0.58
from paddle-wheel squares and terthiophene links. Journal of the American Chemical Society.
127: 12752-3. PMID 16159240 DOI: 10.1021/Ja052055C
2005 Rowsell JL, Spencer EC, Eckert J, Howard JA, Yaghi OM. Gas adsorption sites in a large-pore 0.608
metal-organic framework. Science (New York, N.Y.). 309: 1350-4.
PMID 16123294 DOI: 10.1126/Science.1113247
2005 Rowsell JL, Yaghi OM. Strategies for hydrogen storage in metal--organic 0.622
PMID 16028207 DOI: 10.1002/Anie.200462786
2005 Chen B, Ockwig NW, Millward AR, Contreras DS, Yaghi OM. High H2 adsorption in a 0.774
microporous metal-organic framework with open metal sites. Angewandte Chemie (International
Ed. in English). 44: 4745-9. PMID 15924282 DOI: 10.1002/anie.200462787
2005 Sudik AC, Millward AR, Ockwig NW, Côté AP, Kim J, Yaghi OM. Design, synthesis, structure, 0.829
and gas (N2, Ar, CO2, CH4, and H2) sorption properties of porous metal-organic tetrahedral and
heterocuboidal polyhedra. Journal of the American Chemical Society. 127: 7110-8.
PMID 15884953 DOI: 10.1021/Ja042802Q
2005 Sudik AC, Côté AP, Yaghi OM. Metal-organic frameworks based on trigonal prismatic building 0.78
blocks and the new "acs" topology. Inorganic Chemistry. 44: 2998-3000.
PMID 15847400 DOI: 10.1021/Ic050064G
2005 Ockwig NW, Delgado-Friedrichs O, O'Keeffe M, Yaghi OM. Reticular chemistry: occurrence and 0.813
taxonomy of nets and grammar for the design of frameworks. Accounts of Chemical Research. 38:
176-82. PMID 15766236 DOI: 10.1021/Ar020022L
2005 Rosi NL, Kim J, Eddaoudi M, Chen B, O'Keeffe M, Yaghi OM. Rod packings and metal-organic 0.793
frameworks constructed from rod-shaped secondary building units. Journal of the American
Chemical Society. 127: 1504-18. PMID 15686384 DOI: 10.1021/Ja045123O
40
2005 Chen B, Ockwig NW, Fronczek FR, Contreras DS, Yaghi OM. Transformation of a metal-organic 0.809
framework from the NbO to PtS net. Inorganic Chemistry. 44: 181-3.
PMID 15651861 DOI: 10.1021/Ic048612Y
2005 Yaghi OM. Hydrogen Storage in Metal-Organic Frameworks Acta Crystallographica Section A. 0.394
61: 69-69. DOI: 10.2172/1039149
2005 O'Keeffe M, Yaghi OM. Retucular chemistry-Present and futere prospects Journal of Solid State 0.4
Chemistry. 178: v-vi. DOI: 10.1016/S0022-4596(05)00368-3
2005 Delgado-Friedrichs O, Foster MD, O'Keeffe M, Proserpio DM, Treacy MMJ, Yaghi OM. What 0.425
do we know about three-periodic nets? Journal of Solid State Chemistry. 178: 2533-2554.
DOI: 10.1016/J.Jssc.2005.06.037
2005 Centrone A, Siberio-Pérez DY, Millward AR, Yaghi OM, Matzger AJ, Zerbi G. Raman spectra of 0.804
hydrogen and deuterium adsorbed on a metal-organic framework Chemical Physics Letters. 411:
516-519. DOI: 10.1016/J.Cplett.2005.06.069
2005 Rowsell JLC, Yaghi OM, Chen B, Ockwig NW, Millward AR, Contreras DS. Cover Picture: 0.773
Strategies for Hydrogen Storage in Metal-Organic Frameworks / High H2 Adsorption in a
Microporous Metal-Organic Framework with Open Metal Sites (Angew. Chem. Int. Ed.
30/2005) Angewandte Chemie International Edition. 44: 4647-4647.
DOI: 10.1002/Anie.200590101
2005 Rowsell JLC, Yaghi OM, Chen B, Ockwig NW, Millward AR, Contreras DS. Titelbild: Strategien 0.773
für die Wasserstoffspeicherung in metall-organischen Kompositgerüsten / High H2 Adsorption in
a Microporous Metal-Organic Framework with Open Metal Sites (Angew. Chem.
30/2005) Angewandte Chemie. 117: 4723-4723. DOI: 10.1002/Ange.200590100
2005 Rowsell JLC, Yaghi OM. Strategien für die Wasserstoffspeicherung in metall-organischen 0.547
Kompositgerüsten Angewandte Chemie. 117: 4748-4758. DOI: 10.1002/Ange.200462786
2004 Düren T, Sarkisov L, Yaghi OM, Snurr RQ. Design of new materials for methane 0.311
storage. Langmuir : the Acs Journal of Surfaces and Colloids. 20: 2683-9.
PMID 15835137 DOI: 10.1021/La0355500
41
2004 Bonneau C, Delgado-Friedrichs O, O'Keeffe M, Yaghi OM. Three-periodic nets and tilings: 0.398
minimal nets. Acta Crystallographica. Section a, Foundations of Crystallography. 60: 517-20.
PMID 15507732 DOI: 10.1107/S0108767304015442
2004 Rowsell JL, Millward AR, Park KS, Yaghi OM. Hydrogen sorption in functionalized metal- 0.826
PMID 15125649 DOI: 10.1021/Ja049408C
2004 Wu JS, Melcer N, Sharp WP, O'Keeffe M, Spence JC, Yaghi OM. Structural study of new 0.383
hydrocarbon nano-crystals by energy-filtered electron diffraction. Ultramicroscopy. 98: 145-50.
PMID 15046793 DOI: 10.1016/J.Ultramic.2003.08.007
2004 Chae HK, Siberio-Pérez DY, Kim J, Go Y, Eddaoudi M, Matzger AJ, O'Keeffe M, Yaghi OM. A 0.686
route to high surface area, porosity and inclusion of large molecules in crystals. Nature. 427: 523-
7. PMID 14765190 DOI: 10.1038/Nature02311
2004 Rowsell JLC, Yaghi OM. Metal-organic frameworks: A new class of porous 0.62
materials Microporous and Mesoporous Materials. 73: 3-14.
DOI: 10.1016/J.Micromeso.2004.03.034
2003 Delgado Friedrichs O, O'Keeffe M, Yaghi OM. Three-periodic nets and tilings: semiregular 0.442
nets. Acta Crystallographica. Section a, Foundations of Crystallography. 59: 515-25.
PMID 14581751 DOI: 10.1107/S0108767303017100
2003 Plévert J, Sanchez-Smith R, Gentz TM, Li H, Groy TL, Yaghi OM, O'Keeffe M. Synthesis and 0.752
characterization of zirconogermanates. Inorganic Chemistry. 42: 5954-9.
PMID 12971765 DOI: 10.1021/Ic034298G
2003 Vodak DT, Kim K, Iordanidis L, Rasmussen PG, Matzger AJ, Yaghi OM. Computation of 0.728
aromatic C3N4 networks and synthesis of the molecular precursor N(C3N3)3Cl6. Chemistry
(Weinheim An Der Bergstrasse, Germany). 9: 4197-201.
PMID 12953205 DOI: 10.1002/Chem.200304829
2003 Chae HK, Kim J, Friedrichs OD, O'Keeffe M, Yaghi OM. Design of frameworks with mixed 0.546
triangular and octahedral building blocks exemplified by the structure of [Zn4O(TCA)2] having
the pyrite topology. Angewandte Chemie (International Ed. in English). 42: 3907-9.
42
PMID 12949865 DOI: 10.1002/Anie.200351546
2003 Yaghi OM, O'Keeffe M, Ockwig NW, Chae HK, Eddaoudi M, Kim J. Reticular synthesis and the 0.833
design of new materials. Nature. 423: 705-14. PMID 12802325 DOI: 10.1038/Nature01650
2003 Rosi NL, Eckert J, Eddaoudi M, Vodak DT, Kim J, O'Keeffe M, Yaghi OM. Hydrogen storage in 0.834
microporous metal-organic frameworks. Science (New York, N.Y.). 300: 1127-9.
PMID 12750515 DOI: 10.1126/Science.1083440
2003 Li H, Kim J, O'Keeffe M, Yaghi OM. [Cd16In64S134]44-: 31-A tetrahedron with a large 0.721
cavity. Angewandte Chemie (International Ed. in English). 42: 1819-21.
PMID 12722070 DOI: 10.1002/Anie.200250748
2003 Delgado Friedrichs O, O'Keeffe M, Yaghi OM. Three-periodic nets and tilings: regular and 0.426
quasiregular nets. Acta Crystallographica. Section a, Foundations of Crystallography. 59: 22-7.
PMID 12496458 DOI: 10.1107/S0108767302018494
2003 Plévert J, Gentz TM, Groy TL, O'Keeffe M, Yaghi OM. Layered structures constructed from new 0.455
linkages of Ge7(O,OH,F)19 clusters Chemistry of Materials. 15: 714-718.
DOI: 10.1021/Cm020469O
2003 Friedrichs OD, O'Keeffe M, Yaghi OM. The CdSO4, rutile, cooperite and quartz dual nets: 0.447
Interpenetration and catenation Solid State Sciences. 5: 73-78. DOI: 10.1016/S1293-
2558(03)00002-5
2003 Li H, Kim J, O'Keeffe M, Yaghi OM. Cover Picture: [Cd16In64S134]44: 31-Å Tetrahedron with 0.4
a Large Cavity (Angew. Chem. Int. Ed. 16/2003) Angewandte Chemie International Edition. 42:
1775-1775. DOI: 10.1002/Anie.200390385
2003 Li H, Kim J, O'Keeffe M, Yaghi OM. Titelbild: [Cd16In64S134]44: 31-Å Tetrahedron with a 0.4
Large Cavity (Angew. Chem. 16/2003) Angewandte Chemie. 115: 1817-1817.
DOI: 10.1002/Ange.200390358
2002 Rosi NL, Eddaoudi M, Kim J, O'Keeffe M, Yaghi OM. Infinite secondary building units and 0.704
forbidden catenation in metal-organic frameworks. Angewandte Chemie (International Ed. in
43
English). 41: 284-7. PMID 12491410 DOI: 10.1002/1521-3773(20020118)41:2<284::Aid-

Anie284>3.0.Co;2-M
2002 Vodak DT, Braun M, Iordanidis L, Plévert J, Stevens M, Beck L, Spence JC, O'Keeffe M, Yaghi 0.794
OM. One-step synthesis and structure of an oligo(spiro-orthocarbonate). Journal of the American
Chemical Society. 124: 4942-3. PMID 11982342 DOI: 10.1021/Ja017683I
2002 Eddaoudi M, Kim J, Vodak D, Sudik A, Wachter J, O'Keeffe M, Yaghi OM. Geometric 0.84
requirements and examples of important structures in the assembly of square building
blocks. Proceedings of the National Academy of Sciences of the United States of America. 99:
4900-4. PMID 11959942 DOI: 10.1073/Pnas.082051899
2002 Eddaoudi M, Kim J, Rosi N, Vodak D, Wachter J, O'Keeffe M, Yaghi OM. Systematic design of 0.843
pore size and functionality in isoreticular MOFs and their application in methane storage. Science
(New York, N.Y.). 295: 469-72. PMID 11799235 DOI: 10.1126/Science.1067208
2002 Eddaoudi M, Kim J, O'Keeffe M, Yaghi OM. Cu(2)[o-Br-C(6)H(3)(CO(2))(2)](2)(H(2)O)(2). 0.691

(DMF)(8)(H(2)O)(2): a framework deliberately designed to have the NbO structure type. Journal
of the American Chemical Society. 124: 376-7. PMID 11792198 DOI: 10.1021/Ja017154E
2002 Rosi NL, Eddaoudi M, Kim J, O'Keeffe M, Yaghi OM. Advances in the chemistry of metal- 0.784
organic frameworks Crystengcomm. 4: 401-404. DOI: 10.1039/B203193K
2001 Plévert J, Gentz TM, Laine A, Li H, Young VG, Yaghi OM, O'Keeffe M. A flexible germanate 0.721
structure containing 24-ring channels and with very low framework density. Journal of the
American Chemical Society. 123: 12706-7. PMID 11741447 DOI: 10.1021/Ja016996A
2001 Chae HK, Eddaoudi M, Kim J, Hauck SI, Hartwig JF, O'Keeffe M, Yaghi OM. Tertiary building 0.575
units: synthesis, structure, and porosity of a metal-organic dendrimer framework (MODF-
1). Journal of the American Chemical Society. 123: 11482-3.
PMID 11707128 DOI: 10.1021/Ja011692+
2001 Kim J, Chen B, Reineke TM, Li H, Eddaoudi M, Moler DB, O'Keeffe M, Yaghi OM. Assembly 0.798
of metal-organic frameworks from large organic and inorganic secondary building units: new
examples and simplifying principles for complex structures. Journal of the American Chemical
44
Society. 123: 8239-47. PMID 11516275 DOI: 10.1021/Ja010825O
2001 Eddaoudi M, Kim J, Wachter JB, Chae HK, O'Keeffe M, Yaghi OM. Porous metal-organic 0.575
polyhedra: 25 A cuboctahedron constructed from 12 Cu2(CO2)4 paddle-wheel building
blocks. Journal of the American Chemical Society. 123: 4368-9.
PMID 11457217 DOI: 10.1021/Ja0104352
2001 Eddaoudi M, Moler DB, Li H, Chen B, Reineke TM, O'Keeffe M, Yaghi OM. Modular chemistry: 0.833
secondary building units as a basis for the design of highly porous and robust metal-organic
carboxylate frameworks. Accounts of Chemical Research. 34: 319-30.
PMID 11308306 DOI: 10.1021/Ar000034B
2001 Chen B, Eddaoudi M, Hyde ST, O'Keeffe M, Yaghi OM. Interwoven metal-organic framework on 0.727
a periodic minimal surface with extra-large pores. Science (New York, N.Y.). 291: 1021-3.
PMID 11161211 DOI: 10.1126/Science.1056598
2001 Vodak DT, Braun ME, Kim J, Eddaoudi M, Yaghi OM. Metal-organic frameworks constructed 0.842
from pentagonal antiprismatic and cuboctahedral secondary building units Chemical
Communications. 2534-2535. DOI: 10.1039/B108684G
2001 Braun ME, Steffek CD, Kim J, Rasmussen PG, Yaghi OM. 1,4-Benzenedicarboxylate derivatives 0.814
as links in the design of paddle-wheel units and metal-organic frameworks Chemical
Communications. 2532-2533. DOI: 10.1039/B108031H
2000 Eddaoudi M, Li H, Yaghi OM. Highly porous and stable metal-organic frameworks: Structure 0.612
design and sorption properties Journal of the American Chemical Society. 122: 1391-1397.
DOI: 10.1021/Ja9933386
2000 Li H, Eddaoudi M, Plévert J, O'Keeffe M, Yaghi OM. Ge2ZrO6F2· (H2DAB)H2O:1 A 4- 0.765

connected microporous material with "bow tie" building units and an exceptional proportion of 3-
rings Journal of the American Chemical Society. 122: 12409-12410. DOI: 10.1021/Ja003228V
2000 Chen B, Eddaoudi M, Reineke TM, Kampf JW, O'Keeffe M, Yaghi OM. Cu2(ATC)·6H2O: 0.721
Design of open metal sites in porous metal-organic crystals (ATC: 1,3,5,7-Adamantane
Tetracarboxylate) [27] Journal of the American Chemical Society. 122: 11559-11560.
45
DOI: 10.1021/Ja003159K
2000 Reineke TM, Eddaoudi M, Moler D, O'Keeffe M, Yaghi OM. Large free volume in maximally 0.692
interpenetrating networks: The role of secondary building units exemplified by
TB2(ADB)3[(CH3)2SO]4·16[(CH3)2SO] Journal of the American Chemical Society. 122: 4843-
4844. DOI: 10.1021/Ja000363Z
2000 Yaghi OM, O'Keeffe M, Kanatzidis M. Design of solids from molecular building blocks: Golden 0.4
opportunities for solid state chemistry Journal of Solid State Chemistry. 152: 1-2.
DOI: 10.1006/Jssc.2000.8733
2000 O'Keeffe M, Eddaoudi M, Li H, Reineke T, Yaghi OM. Frameworks for extended solids: 0.801
Geometrical design principles Journal of Solid State Chemistry. 152: 3-20.
DOI: 10.1006/Jssc.2000.8723
1999 Li H, Eddaoudi M, Yaghi OM. An Open-Framework Germanate with Polycubane-Like 0.769

Topology. Angewandte Chemie (International Ed. in English). 38: 653-655.
PMID 29711558 DOI: 10.1002/(Sici)1521-3773(19990301)38:5<653::Aid-Anie653>3.0.Co;2-C
1999 Reineke TM, Eddaoudi M, O'Keeffe M, Yaghi OM. A Microporous Lanthanide-Organic 0.728

Framework. Angewandte Chemie (International Ed. in English). 38: 2590-2594.
PMID 10508349 DOI: 10.1002/(Sici)1521-3773(19990903)38:17<2590::Aid-Anie2590>3.0.Co;2-
H
1999 Li H, Laine A, O'Keeffe M, Yaghi OM. Supertetrahedral sulfide crystals with giant cavities and 0.781
channels Science (New York, N.Y.). 283: 1145-7.
PMID 10024236 DOI: 10.1126/Science.283.5405.1145
1999 Li H, Eddaoudi M, O'Keeffe M, Yaghi OM. Design and synthesis of an exceptionally stable and 0.839
highly porous metal- organic framework Nature. 402: 276-279. DOI: 10.1038/46248
1999 Eddaoudi M, Li H, Reineke T, Fehr M, Kelley D, Groy TL, Yaghi O. Topics in Catalysis. 9: 105- 0.833
111. DOI: 10.1023/A:1019110622091
46
1999 Li H, Eddaoudi M, Laine A, O'Keeffe M, Yaghi OM. Noninterpenetrating indium sulfide 0.81
supertetrahedral cristobalite framework Journal of the American Chemical Society. 121: 6096-
6097. DOI: 10.1021/Ja990410R
1999 Reineke TM, Eddaoudi M, Fehr M, Kelley D, Yaghi OM. From condensed lanthanide 0.705
coordination solids to microporous frameworks having accessible metal sites Journal of the
American Chemical Society. 121: 1651-1657. DOI: 10.1021/Ja983577D
1999 Barton TJ, Bull LM, Klemperer WG, Loy DA, McEnaney B, Misono M, Monson PA, Pez G, 0.596
Schere GW, Vartuli JC, Yaghi OM. Tailored porous materials Chemistry of Materials. 11: 2633-
2656. DOI: 10.1021/Cm9805929
1999 O'Keeffe M, Yaghi OM. Germanate zeolites: Contrasting the behavior of germanate and silicate 0.496
structures built from cubic T8O20 units (T = Ge or Si) Chemistry - a European Journal. 5: 2796-
2801. DOI: 10.1002/(Sici)1521-3765(19991001)5:10<2796::Aid-Chem2796>3.0.Co;2-6
1999 Reineke TM, Eddaoudi M, O'Keeffe M, Yaghi OM. Ein mikroporöses Gerüst aus Lanthanoid- 0.692
Ionen und organischen Bausteinen Angewandte Chemie. 111: 2712-2716.
DOI: 10.1002/(Sici)1521-3757(19990903)111:17<2712::Aid-Ange2712>3.0.Co;2-M
1999 Li H, Eddaoudi M, Yaghi OM. Ein Germanat mit offener Gerüststruktur und Polycuban-artiger 0.732
Topologie Angewandte Chemie. 111: 682-685. DOI: 10.1002/(Sici)1521-
3757(19990301)111:5<682::Aid-Ange682>3.0.Co;2-7
1998 Li H, Yaghi OM. Transformation of Germanium Dioxide to Microporous Germanate 4-Connected 0.674
Nets Journal of the American Chemical Society. 120: 10569-10570. DOI: 10.1021/ja982384n
1998 Li H, Eddaoudi M, Groy TL, Yaghi OM. Establishing microporosity in open metal-organic 0.805
frameworks: Gas sorption isotherms for Zn(BDC) (BDC = 1,4-benzenedicarboxylate) [28] Journal
of the American Chemical Society. 120: 8571-8572. DOI: 10.1021/Ja981669X
1998 Li H, Eddaoudi M, Richardson DA, Yaghi OM. Porous germanates: Synthesis, structure, and 0.732
inclusion properties of Ge7O14.5F2 · [(CH3)2NH2]3(H2O)0.86 [26] Journal of the American
Chemical Society. 120: 8567-8568. DOI: 10.1021/Ja9813919
47
1998 Li H, Davis CE, Groy TL, Kelley DG, Yaghi OM. Coordinatively Unsaturated Metal Centers in 0.674
the Extended Porous Framework of Zn3(BDC)3·6CH3OH (BDC = 1,4-
Benzenedicarboxylate) Journal of the American Chemical Society. 120: 2186-2187.
DOI: 10.1021/Ja974172G
1998 Yaghi OM, Li H, Davis C, Richardson D, Groy TL. Synthetic Strategies, Structure Patterns, and 0.674
Emerging Properties in the Chemistry of Modular Porous Solids† Accounts of Chemical Research.
31: 474-484. DOI: 10.1021/Ar970151F
1997 Yaghi OM, Li H, Groy TL. A Molecular Railroad with Large Pores: Synthesis and Structure of 0.707
Ni(4,4'-bpy)(2.5)(H(2)O)(2)(ClO(4))(2).1.5(4,4'-bpy).2H(2)O. Inorganic Chemistry. 36: 4292-
4293. PMID 11670081 DOI: 10.1021/Ic970423A
1997 Yaghi OM, Li H, Groy TL. Crystal structure of 1,2,4,5-benzenetetracarboxylate monohydrate 0.674
cerium( III), C10H4CeO9 Zeitschrift FüR Kristallographie - New Crystal Structures. 212: 457-
458. DOI: 10.1524/Ncrs.1997.212.1.457
1997 Yaghi OM, Jernigan R, Li H, Davis CE, Groy TL. Construction of a new open-framework solid 0.696
from1,3,5-cyclohexanetricarboxylate and zinc(II) building blocks Journal of the Chemical Society-
Dalton Transactions. 2383-2384. DOI: 10.1039/A702287E
1997 Yaghi OM, Davis CE, Li G, Li H. Selective guest binding by tailored channels in a 3-D porous 0.731
zinc(II)-benzenetricarboxylate network Journal of the American Chemical Society. 119: 2861-
2868. DOI: 10.1021/Ja9639473
1997 Yaghi OM, Li G, Li H. Crystal Growth of Extended Solids by Nonaqueous Gel 0.714
Diffusion Chemistry of Materials. 9: 1074-1076. DOI: 10.1021/Cm970069E
1996 Yaghi OM, Li H, O'Keeffe M. Synthesis and Structure of a Metal-Organic Solid Having the 0.721
Cadmium(II) Sulfate Net Mrs Proceedings. 453. DOI: 10.1557/Proc-453-127
1996 Yaghi OM, Li H, Groy TL. Construction of Porous Solids from Hydrogen-Bonded Metal 0.746
Complexes of 1,3,5-Benzenetricarboxylic Acid Journal of the American Chemical Society. 118:
9096-9101. DOI: 10.1021/Ja960746Q
48
1995 Yaghi OM, Li G, Li H. Selective binding and removal of guests in a microporous metal–organic 0.75
framework Nature. 378: 703-706. DOI: 10.1038/378703A0
1995 Yaghi OM, Li H. Hydrothermal Synthesis of a Metal-Organic Framework Containing Large 0.674
Rectangular Channels Journal of the American Chemical Society. 117: 10401-10402.
DOI: 10.1021/Ja00146A033
1992 Yaghi OM, Scott MJ, Holm RH. Rhenium-selenium-chlorine solid phases: cluster excision and 0.515
core substitution reactions of molecular species Inorganic Chemistry. 31: 4778-4784.
DOI: 10.1021/ic00049a013
1992 Yaghi OM, Scott MJ, Holm RH. Rhenium-selenium-chlorine solid phases: Cluster excision and 0.376
core substitution reactions of molecular species Inorganic Chemistry. 31: 4778-4784.
DOI: 10.1021/Ic00049A013
1992 Che TM, Day VW, Francesconi LC, Klemperer WG, Main DJ, Yagasaki A, Yaghi OM. Mono- 0.513
and diprotonation of the [(.eta.5-C5H5)Ti(W5O18)]3- and [(.eta.5-C5Me5)Ti(W5O18)]3-
anions Inorganic Chemistry. 31: 2920-2928. DOI: 10.1021/Ic00039A047
1992 Klemperer WG, Marquart TA, Yaghi OM. New Directions in Polyvanadate Chemistry: From 0.499
Cages and Clusters to Baskets, Belts, Bowls, and Barrels Angewandte Chemie International
Edition in English. 31: 49-51. DOI: 10.1002/anie.199200491
1992 Klemperer WG, Marquart TA, Yaghi OM. New directions in polyvanadate chemistry: From cages 0.499
and clusters to baskets, belts, bowls, and barrels Angewandte Chemie (International Edition in
English). 31: 49-51. DOI: 10.1002/Anie.199200491
1992 Klemperer WG, Marquart TA, Yaghi OM. Neue Richtungen in der Polyvanadat-Chemie: Von 0.499
Käfigen und Clustern zu Körben, Bändern, Schalen und Fässern Angewandte Chemie. 104: 51-53.
DOI: 10.1002/Ange.19921040108
1991 Day VW, Klemperer WG, Yaghi OM. Induced molecule self-organization Nature. 352: 115-116. 0.499
DOI: 10.1038/352115C0
49
1991 Klemperer WG, Marquart TA, Yaghi OM. Shape-selective binding of nitriles to the inorganic 0.527
cavitand, V12O32 4- Materials Chemistry and Physics. 29: 97-104. DOI: 10.1016/0254-
0584(91)90007-H
1989 Day VW, Klemperer WG, Yaghi OM. Synthesis and characterization of a soluble oxide inclusion 0.499
complex, [CH3CN.cntnd.(V12O324-)] Journal of the American Chemical Society. 111: 5959-
5961. DOI: 10.1021/Ja00197A077
1989 Day VW, Klemperer WG, Yaghi OM. A new structure type in polyoxoanion chemistry: synthesis 0.499
and structure of the V5O143- anion Journal of the American Chemical Society. 111: 4518-4519.
DOI: 10.1021/ja00194a068
1989 Day VW, Klemperer WG, Yaghi OM. A new structure type in polyoxoanion chemistry: Synthesis 0.499
and structure of the V5O14 3- anion Journal of the American Chemical Society. 111: 4518-4519.
DOI: 10.1021/Ja00194A068
1989 DAY VW, KLEMPERER WG, YAGHI OM. ChemInform Abstract: A New Structure Type in 0.499
Polyoxoanion Chemistry. Synthesis and Structure of the V5O3- 14 Anion. Cheminform. 20.
DOI: 10.1002/chin.198940038
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Reaction Mechanism in MOF Based Heterogeneous Catalysis

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Reaction Mechanism in MOF based Heterogeneous Catalysis

NAME OF THE STUDENT: FAISAL MEHTAB

ROLL NUMBER: 204-PHD-21

NAME OF THE TEACHER: Dr. Nazir Ahmad

1.5 Metal Ions or Metal Clusters..........................................................................................5

4. Mechanism of Co@SBU catalysed reactions...................................................................9

5. Proposed mechanism for the oxidation of cyclooctane catalyzed by

Reaction Mechanism in MOF based Heterogeneous Catalysis

MIL-101 MIL-125 ZIF-8

UiO-66 UiO-67 Zr-abtc

Proposed mechanism for the oxidation of ethane to ethanol in Fe0.1Mg1.9(dobdc).

Speybröck's mechanistic investigation into a cross-aldol reaction to create jasminaldehyde,

4. Mechanism of Co@SBU catalysed reactions

The vanadium-node-functionalized UiO-66 was produced by functionalizing the Zr6(μ3-

ion exchange, and sol-gel encapsulation [13-15].

6. Development of heterogeneous catalysts for the cycloaddition of CO 2 with

characteristics, heterogeneous catalyst has attracted the interest of researchers. Most

Synthesis of cyclic carbonates from epoxides and CO2

catalyst for carbon dioxide chemical fixation. [32-39].

7. First applications of MOFs in oxidation catalysis with H2O2

The chromium(III) terephthalate Cr-MIL-101 ([Cr3X(H2O)2O(BDC)3]; X = F, OH; MIL

1999- University of Michigan, Ann Arbor, Ann Arbor,

2007- University of California, Los Angeles, Los

2012- Chemistry University of California, Berkeley, Berkeley, CA

270 high-probability publications.

Infinite Secondary Building Units. Journal of the American Chemical Society.

CO2 reduction in water. Science (New York, N.Y.).

metals Inorganic Chemistry. 53: 5881-5883. DOI: 10.1021/ic500434a

detection. Nano Letters. 13: 5271-6. PMID 24099583 DOI: 10.1021/Nl4027692

2008 Gould SL, Tranchemontagne D, Yaghi OM, Garcia-Garibay MA. Amphidynamic character of 0.81

2008 Tranchemontagne D, Ni Z, O'Keeffe M, Yaghi O. Retikuläre Chemie metall‐organischer 0.794

English). 41: 284-7. PMID 12491410 DOI: 10.1002/1521-3773(20020118)41:2<284::Aid-

2002 Eddaoudi M, Kim J, O'Keeffe M, Yaghi OM. Cu(2)[o-Br-C(6)H(3)(CO(2))(2)](2)(H(2)O)(2). 0.691

Society. 123: 8239-47. PMID 11516275 DOI: 10.1021/Ja010825O

2000 Li H, Eddaoudi M, Plévert J, O'Keeffe M, Yaghi OM. Ge2ZrO6F2· (H2DAB)H2O:1 A 4- 0.765

1999 Li H, Eddaoudi M, Yaghi OM. An Open-Framework Germanate with Polycubane-Like 0.769

1999 Reineke TM, Eddaoudi M, O'Keeffe M, Yaghi OM. A Microporous Lanthanide-Organic 0.728

4.Mon M, Bruno R, Ferrando-Soria J, Armentano D, Pardo E (2018). "Metal–organic framework

5. Cejka J, ed. (2011). Metal-Organic Frameworks Applications from Catalysis to Gas

6. O'Keeffe M, Yaghi OM (2005). "Reticular chemistry—Present and future

9. Llabresixamena F, Abad A, Corma A, Garcia H (2007). "MOFs as catalysts: Activity, reusability

10. Ravon U, Domine ME, Gaudillère C, Desmartin-Chomel A, Farrusseng D (2008). "MOFs as acid

22. P. P. Pescarmona and M. Taherimehr, Catal. Sci. Technol., 2012, 2, 2169.

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