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    3.30 More Epoxide Synth Answers

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    KHOA HÓA HỌC
    (1) Starting with compounds containing 3 or fewer carbons, form a Grignard reagent which is reacted with a carbonyl compound and worked up with acid to form the desired product. (2) The starting material is reacted with PBr3 and magnesium in diethyl ether to form a Grignard reagent. This is then reacted with benzophenone and worked up with acid to form the desired brominated product.

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    3.30 More Epoxide Synth Answers

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    KHOA HÓA HỌC
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    (1) Starting with compounds containing 3 or fewer carbons, form a Grignard reagent which is reacted with a carbonyl compound and worked up with acid to form the desired product. (2) The starting material is reacted with PBr3 and magnesium in diethyl ether to form a Grignard reagent. This is then reacted with benzophenone and worked up with acid to form the desired brominated product.

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    Epoxide Synth

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    (1) Starting with compounds containing 3 or fewer carbons, form a Grignard reagent which is reacted with a carbonyl compound and worked up with acid to form the desired product. (2) The starting material is reacted with PBr3 and magnesium in diethyl ether to form a Grignard reagent. This is then reacted with benzophenone and worked up with acid to form the desired brominated product.

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    5 views1 page

    3.30 More Epoxide Synth Answers

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    KHOA HÓA HỌC
    (1) Starting with compounds containing 3 or fewer carbons, form a Grignard reagent which is reacted with a carbonyl compound and worked up with acid to form the desired product. (2) The starting material is reacted with PBr3 and magnesium in diethyl ether to form a Grignard reagent. This is then reacted with benzophenone and worked up with acid to form the desired brominated product.

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    of 1

    Synthesis Practice: Making C-C Bonds

    1. Provide a complete synthesis of the following desired products. You may use any organic or inorganic
    reagents in addition to the indicated starting materials. You do not need to show any mechanisms.

    a) Starting Materials= Any compounds with 3 or fewer carbon atoms

    O 1. mix OH
    +
    MgBr 2. H+ wkup
    (+/-)

    1. NaH
    2. MeI

    OMe

    (+/-)
    Desired Product

    b)

    1. PBr3

    OH 2. Mg, Et2O MgBr


    Starting Material

    O
    1. Ph

    2. H+ wkup

    Br

    OH Br2 O

    Ph Ph
    (You may ignore stereochem.)
    Desired Product

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