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Acids, Bases and Salts MCQs
Acids, Bases and Salts MCQs
IMPORTANT POINTS
1. Acid: A compound which on dissolving in water furnishes proton [hydrogen ion (H')] as
the
only positively charged ion is called an acid.
Or
A compound which on dissolving in water furnishes hydronium ion as only positively charped
d
ion is called an acid.
2. Organic acid: An acid derived from an animal or vegetable origin is called organic acid,e.o
formic acid; acetic acid; citric acid; tartaric acid, etc.
3. Mineral acid: An acid derived from minerals is HCI, H,SO4, HNO,
called mineral acid, e.g.,
HBr, etc.
4. of be
Basicity acid: The number
an
of hydrogen ions [H* (aq)], which
molecule of an acid on complete ionisation is called basicity of the acid.
can produced by one
5.
Monobasic acid When : molecule ofone
ion [H" (aq)] then the acid is said to be
an acid on complete ionisation produces
monobasic, e.g.. HC1; HNO3, HBr, HI, HCOOH
one
hydrogen
CH,COOH.
6. Dibasic acid When one molecule of an acid on complete ionisation
produces two hydrogen ions
[H(aq)] then the acid is said to be dibasic, e.g., : HSO4, H2SO3, H2C03, (COOH)2, HS.
7. Tribasic acid : When one molecule of an acid on complete ionisation
produces three hydrogen
ions [H (aq)], then the acid is said to be tribasic, e.g.,
: H3PO4, H3PO3.
8. Strength of an acid : The degree of dissociation of an acid in aqueous solution is called strength
of an acid.
No. of acid molecules ionised
Degree of dissociation =
x100.
No. of molecules of acid in solution
9. Strong acids : The acids which undergo almost complete ionisation (more than 30%) in an
aqueous solution, thereby producing high concentration of H* (aq) ions, are called strong acids,
e.g., HNO3, HCI and H2SO4.
10. Weak acids The acids which undergo partial dissociation in an
aqueous solution (less than 30%),
thereby producing low concentration of H* (aq) ions, are called weak acids. e.g., HC03, H2S03.
H2S, HI, HCN, CH,C0OH, HCOOH.
11. Concentration of an acid It is the measure of the amount of water present in an acid.
12.Concentrated acid : An acid which contains very little or no water is
called concentrated ac
13. Dilute acid. : An acid which contains
large amount of water is called dilute acid. Generaly
speaking, if concentration of an acid isI mole/litre of water or less, it is called dilute acid.
14. Hydracid : An acid which contains hydrogen and a non-metallic element, other than
called hydracid. eg., : HCl; HBr; HI; HF; HCN; oxygen
HS.
15. Oxyacid : An acid which contains oxygen, along with hydrogen and one more allic
element is called an oxyacid. e.g., : HNO3, HNO2, non-meta
H,SO4, H2SO3, HPO4, HaPO3, H2CO3
16. Volatile acid: An acid which easily changes into its vapours below 100 °C is
called volatile ac
17. Methods of preparation of Acids:
(a) By synthesis or direct combination
H2+ Cl, Sunlight 2HCI
(b) By action of non-metallic oxides on water
H20+SO H,SOO
(C) By displacement of more a volatile acid by a less volatilc acid from a salt:
2NaCl+ H2SO4 (cone.) Heat(conc.)
Na,SO4 + 2HCI
(d) By the oxidation of non-metals:
S+ 6HNO HSO4 + 2H,0 + 6NO2
18. Physical properties of Acids
1. Acids have a sharp sour taste in
aqueous solution.
an
2. Acids turn blue litmus red, methyl orange solution pink and phenolphthalein solution
colourless.
3. Strong acids have corrosive action on the skin.
19. Chemical properties of Acids :
1. Acids react with oxides and hydroxides of metals to form salt and water only.
CuO +HsO4 CusO4 + H2O
2NaOH + H,SO4 NaSO4 + 2H,0
2. Acids react with metallic carbonates to form salt, carbon dioxide and water.
CaCO3 +2HNO3 Ca(NO3)2 + CO2 + H20
3. Acids react with metallic sulphites to form salt, sulphur dioxide and water.
NaSO3 + 2HCI 2NaCI + SO2 + H20
4. Acids react with activemetals to form salt and hydrogen.
Zn + dil. H,S04 ZnSO4 + H2
20. Base : A compound which reacts with H" (aq) ions of an acid to form salt and water as the only
products is called a base.
21. Alkali: An alkali is a compound which on dissolving in water furnishes OH ions as only negative
ions.
22. Acidity of a base : The number of H" (aq) ions of an acid, which will react completely with one
molecule of a base, to form salt and water as the only products is called acidity of a base.
23. Monoacidic base : When one H (aq) ion of an acid, reacts completely with one molecule of a
base, to form salt and water as the only products, then the base is said to be monoacidic, e.g.,
NaOH; KOH; NH4OH.
24. Diacidic base : When two H (aq) ions of an acid, react completely with one molecule of a base,
to form salt and water as the only products, then the base is said to be diacidic, e.g., Ca(OH)2,
Zn(OH)2, Fe(OH)2.
25. Triacidic base : When three H (aq) ions of an acid, react completely with one molecule of a base,
to form salt and water as the only products, then the base is said to be triacidic, e.g., Al(OH)3.
Fe(OH)3, Cr(OH)3.
26. Strong base: A base which almost completely dissociates in water, to produce high concentration
of hydroxyl ions (OH) is called a strong base, eg, : NaOH, KOH, LiOH, Ba (OH)%.
27. Weak base : A base, which undergoes partial dissociation in water, and produces low concentration
of hydroxyl ions, is called a weak base. eg., : NH,OH, Mg(OH)2, Ca(OH)2
28. General methods for the preparation of bases
1. By the action of oxygen on metals: 2Mg + O2 2MgO
the action of water or steam on active mctals
2. By
2Na 211,0 2NaOI H2
3. By the action of water on soluble metallic oxides
C'aO +H,0 (Ca(OH);
4. By dissolving ammona gas in water:
NH+ H0 NH,OH
alkali solution:
S. By treating soluble salts of metals with caustic
AlCl + 3NaOH Al(OH), + 3NaCl
6. By the action of heat on metallic carbonates
CaCO heat CaO +CO
7. By the action of heat on metallic nitrates
2Pb(NO)>C 2PbO +4NO2 + O2
39. Anhydrous salt: A salt which does not contain any water of crystallisation is called an anhydrous
salt. For example, NaCI, NaNO3, Pb(NO3)2
40. Hydrated salt: A salt which contains a definite number of molecules of water attached loosely
to its one molecule is called a hydrated salt.
Examples : (i) CuSO4.5H,0 (i) Na,CO3.10H,0
41. Water of crystallisation : The number of water molecules which are loosely attached to one
molecule of a salt is called water of crystallisation.
42. Deliquescent substances: The water soluble substances which absorb moisture from the air
and then dissolve in it, so as to fornm a liquid are called deliquescent substances, whereas the
phenomenon is called deliquescence.
Examples: (i) Anhydrous CaCl2
(ii) Anhydrous FeCl3
43. Hygroscopic substances: The substances which absorb moisture from the airbut do not change
their state are called hygroscopic substances.
-SECTIONI=
3H2S04
In the above
Al,(SO4)3 +
6H,0
chemical equation the acidity of
(A) 1
Al(OH)3 is:
(B) 6 C) 3 (D) 2
54. The mixed salt
amongst the salts given below is:
(A) NaKSO4
(B) FeSO4.7H0
C) K4[Fe(CN)6 (D) FeSO4(NH,)SO4.6H,0
55. The soluble sulphide amongst the sulphides given below is:
(A) FeS (B) PbS (C) NaS (D) CuS
56. The salt which forms a neutral solution in water is:
(A) (NH4)2SO4 (B) NaSO4 (C) Na-COOs (D) Cu(NO3)2
57. The salt which is not anhydrous
amongst the following is:
(A) Lead nitrate crystals (B) Sodium chloride
(C) Ferous sulphate crystals (D) Sugar crystals
58. A salt which contains definite number of molecules of water, attached
loosely to its one molecule
is called:
(A) wet salt (B) re-hydrated salt (C) hygroscopic salt (D) hydrated salt
59. The salt which is deliquescent amongst following is:
(A) Ferric chloride crystals (B) Copper sulphate crystals
C) Calcium oxide (D) Sodium nitrate
60. The colour of pH paper in odourless solution of pH 7 is
(A) deep blue (B) yellow (C) green (D) orange
61. CafOCI) CI is an example of:
(A) double salt (B) mixed salt (C) complex salt (D) basic salt
62. When sodium hydroxide solution is added to iron (II) chloride solution the colour of
precipitate
(A) bluish white (B) white (C) dirty green (D) brown
63. The acid which is tribasic is:
(A) H3PO4 (B) HSO (C) HNOD (D) CH COOH
64. The colour of pH paper in limewater [Ca(OH)2sol| is:
(A) green (B) red (C) blue (D) orange
65. Ammonium hydroxide is an example of
(A) strong alkali (B) weak alkali (C) strong base (D) none of these
66. Ammonium hydroxide sol reaets completely with 1ICI solution to form ammonium ehloride
solution and water. When a plH paper is held in the above reaction mixture, the colour of pli
paper is:
117. The salt which on dissolving in water forms acidic solution is:
(A) sodium carbonate (B) sodium sulphate
( C ) zinc nitrate (D) ammonium carbonate
SECTION II=
1. A solution M turns blue litmus red while another solution N turns
red litmus blue. In the
above context answer the following questions by choosing the correct answer from the op
tions given below:
G) M must contain
(A) hydronium ion (B) hydroxyl ion (C) any positive ion (D) oxide ion
(ii) N must contain
(A) hydronium ion (B) oxide 1on C) hydroxyl ion (D) any negative ion
(ii) When M and N are mixed together, one of the product will be
(A) acid (B) base (C) alkali (D) salt
(iv) When M and N are mixed together, the other product will
be
(A) acid (B) base (C) alkali
(v) Ifa piece of magnesium was put into a solution
(D) water
M, the gas evolved would be
(A) hydrogen (B) oxygen (C) earbon dioxide (D) nitrogen
2. The pH values of three solutions P,
Q and R are given in the table.
Solution
pH value
P
12
Q
R
Answer the following questions by choosing the correct answer from the options given below: