nguyenduylong89899@gmail.com DE THI GIUA Ki HOA HQC 2- CH1015 ki 20201 — MA DE 091120.1 (Cu 1: Phan img: 2HI(k) + H2(k) + (kK) €6 hang so can bang Kp= 9. G ciing nhiét 6, phan tng dién ra theo chiéu nao khi 4p suat riéng phn cia Hb, b Lan luyt 1a 0.2; 0,45 va 0,1 atm. A. Phin img 6 trang thai cin bang B. Khéng don due chiéu phan tmg C. Phan img dién ra theo chiéunghich —_—D. Phan img dién ra theo chiéu thuan Cu 2: Trong mét binh dung tich | lit nguéi ta nap vao 1,0 mol khi A, 1,4 mol khi B. va 0,5 mol khi C. O nhiét 46 xac dinh, sau khi can bang A(k) + B(k) € 2C(k) duge thict lap thi, nong 46 cua C 1a 0,75 mol/|. Gia tri hang s6 can bang cua phan img 1a: A.K=05 BK=125 CK=125 _D.K=0,15 | Cu 3: Diém ba trang thai cia m6t chat li nhiét d6 va ap suat ma 6 d6 ba pha ca chat do (khi, long, rn) co thé cing t6n tai trong can bang nhiét déng lure hoc. Bac tur do C cua hé tai vi tri can bang nay bang: A. Khong thé xéc dinh B20 c.0 D1 Cfu 4: Ti cae gia tri AH 6 cling diéu kién phan img 2SO2(k) + On(k) + 2SOx(k) AH: = -196 kJ; 2S(r) + 302(k) — 280x(k) AH> = -790 kI Tinh gid tri AH; 6 cing diéu kign ciia phan dng: S(x) + Or(k) +SOr(k) A.AH3=297kJ — B.AH3=-594kJ— C.AH3=-297kJ_—-D. AH) =594kJ (Cu 5: Tinh nhiét hinh thanh (nhiét sinh) chuan cua CH3OH long, biét C(gr) + Ox(k) + CO~k) AH; =-94 kcal/mol Ha(k) + 502(k) > H:0() AH2 = -68,5 kcal/mol CH,OH()) + 20.(k) + CO,(k) + 2H0()) AH; =-171 keallmol A.-402 keallmol —B.-60 kcal/mol C. 402 keal/mol___D. 60 kcal/mol Cu 6: Cho can bing CO2(k) + H2(k) CO(k) + HeO(k) Tinh hing sé cn bing K. biét tai thoi diém can bang c6 0.4 mol CO»; 0,4 mol Hz; 0,8 mol CO va 0,8 mol H20 trong mét binh cé thé tich 1 lit. Néu nén hé cho thé tich cua hé gidm xudng, cn bang sé chuyén dich nhu thé nao? A. Ke=8; theo chieu thuan B. Ke = 4; theo chiéu thuan C.Ke=8; theo chiéu nghich D. Ke = 4; khéng di Cfiu 7: Tinh AH? cia phan img sau 6 1500K: C(gr) + 02(k) >CO2(k), biét AH? 295 (kJ/mol): - -393,51 C*p(I/molK): 8,64 29,36 37,13 A. -394,556 kJ B. -39,4556 kJ C. -294,556 kJ D. -364,556 kJnguyenduylong89899@gmail.com Cau 8: Luong nhiét toa ra khi dét chay hoan toan 3 g kim loai Mg bang O2(k) tao ra MgO(1) la 76 kJ 6 digu kign chudn, Nhiét hinh thanh (nhiét sinh) chun ctia MgO(1) 1a (Mg = 24 g/mol): A.304KI —B.-608 KI C. 304k D. 608 kJ CAu 9: Phat biéu sau day khong ding: A. Phan img héa hoc cé AG <0 c6 kha ning xay ra vé phirong dién nhiét dong hoc. B. Bién thién entropy li tiéu chun dinh long xéc dinh chiéu va gigi han cia cic qua trinh trong hé cé lap. C. Bién thién entanpy tur do AG a tiéu chuén dinh long xac dinh chiéu va giéi han ctia céc qua trinh trong hé khong c6 lap, trong diéu kién dang nhiét, dang ap. D. Bién thién entanpy ty do AG 1a tiéu chuan dinh Iuong xac dinh chiéu va gidi han cla cdc qua trinh trong hé khéng cé lap, trong diéu kién ding nhiét, dang tich. Cu 10: Phan img: 3H:(k) + No(k) + 2NHs(k) c6 hang sd can bang K, = 5,9.10° tai 298K, hiéu img nhiét ctia phan img AH® = -92,2 kJ. Tinh hing sé can bang Kp cia phan img tai 600K. Coi AH? ciia phan tmg khéng déi trong khong nhiét 46 298 ~ 600K. A. 3,710? B. 8,2.10° c. 43.107 D.5,6.10° Cfiu 11: S6 pha cia hé edn bang sau la bao nhiéu: MgCOs(r) + MgO(r) + CO2(k) A2 Bl C4 D3 Cfiu 12: Cho cdc phan img va céc hing sé can bing Kp tuong img. Gia sir hé dang 6 trang thai cén bang, phan img nao sau day duge coi la da xiy ra hoan toan: A. 2C(r) + O2(k) 2CO(K) Ky = 10" B. 2Clo(k) + 2H;O(k) + 4HCI(k) + Oo(k) Ky = 1,88.10"S C. FeO(r) + CO(k) © Felt) + COo(k) Ky = 0,403 D. CHsCH2CH2CH,(k) + CHsCH(CH3)x(k) Ky = 2,5 Céu 13: Cho phan img: CaCOs(r) + CaO(r) + COx(k) diéu kién chun va 298K, phan ting c AH®208 = 42,5 kcal, AS°29g = 38.4 cal/K. Nhiét d6 tai dé CaCOs bat dau phan huy 1a (coi AH°, AS° khéng doi theo nhiét d6): A. 1107K B. 1000,4K C. 1106,77K D.274,11K (Cu 14: Phan émg CO(k) + 2Ha(k) <> CH,OH(k) 6 AG°r phu thude vao nhiét 46 AG°r = 95429 — 230,53.T (J). Xée dinh AH®, AS® ciia phan tng (coi chiing khong doi theo nhiét a0), A. AH? = 95429 J, AS°= -230,53 /K ——_B. AH® = -95429 J, AS° = -230,53 /K C. AH? = 95429 kJ, AS° = 230,53 KD. AH® = 95429 J, AS® = 230,53 /K CAu 15: Bac tu do va cac thong sé trang thai anh xac dinh trang thai can bing cua hé sau lan lurot Li: No(k) + 3H,(k) <> 2NHs(k) A.3:T, P va ty 1é s6 mol No:H> B. 0: trang thai cn bing ita hé hoan toan xdc dinh C.1:T hoac P D.2:TvaPnguyenduylong89899@gmail.com C4u 16: Cho cae phan ing: (1) No(k) + 202(k) + 2NOx(k); (2) 2NO2(k) «+ No(k) + 20x(k), (3) NO2(k) © Nok) + O2(6) mot nhiét d6 xic dinh, hing s6 cn bang cita phan img (1) la 100. Hang s6 cn bang cia cde phan img (2) va (3) lan lot 1a: A.0,01 vi0.001 __B. -100 va-50 C.0,01 va0,1 D.10 vas Cu 17: 6 46°C, cn bang N204(k) «+ 2NOx(k) c6 hang s6 can bang K, = 0,66. Tinh 6 phan ly (%) ctia NoOs 6 46°C biét ap suat chung tai thoi diém cén bang la 0,5 atm. A. 66,67% _ B.75% C. 80% D. 50% CAu 18: Cho cn bing héa hoc sau: 2SO,(k) + O2(k) + 2SOx(k) AH <0 Trong cac bién phap: (1) ting nhiét dé; (2) ting ap sudt chung ciia hé phan img: (3) ha nhigt do; (4) gia ndng 49 SOs, (5) giém ap sudt chung cita hé phan img. Nhing bién phap nao lam cén bang trén chuyén dich theo chiéu thuan? A.(), 2), 4) B. (2), 3), 4) C. (1), (2), (5) D. (2), (3), (5) Céu 19: Cho phan tmg: CaH(I) + O2(k) —> 6CO2(k) + 3H20(h) Dau cua bién thién sé mol khi va bién thién entropy cui phan img trén 1a: A.An>0;AS=0 B.An<0;AS>0 C.An>0;AS<0 _D.An>0;AS>0 Cfu 20: Phan tmg: 2502(k) + x(k) > 280x(K) c6 hang sé can bing Kp = 4,438.10" 6 700°C.Néa thém vio hé can bing mét long khi Nz, céc hing s6 cn bang Kp, Ke thay di nhw thé nio néu cde yéu td dp sudt oan bing va nhiét 46 duoe git nguyen? A. Kp tang, Ke giam B. K, kh6ng doi, K, giam C. Ky khong déi, K, tang D. Ky va Ka khong d6i —Hét--nguyenduylong89899@gmail.com Dap Gn tham khéo: 2 ‘ 5 olalo}>|o 9 = vale] >|