Clu 1: Cho cfin bing héa hoe sau: 1 2802 (k) + On (ke) #8 280s (k); AH <0 400+ w bify Cho cde bign phép; - Tang nhigt 4, ‘Tang 4p sudt chung cia hg phan img; Ha nhiet dg, Giém ndng 49 SO;; “* Giam 4p sudt chung cia hé phan (mg. ‘Trong cfc bién php trén, nhting bign phap ndo lam cn bing chuyén dich theo chiéu thuan? A. (1), 2), 4), (5) Boo. C. (2), 3), (4), (5) #D. (1), (2), 4) ‘Cfiu 2: Cho cén bing héa hoe: Ha (k) + 12 (k) 2HI(k); AH > 0 rl CAn bing khéng bj chuyén dich khi: A. ting mhiét 49 cia hé B. giam néng 46 HI C. ting néng 46 Ha 4(D) gidm 4p suit chung cia hé. Cfu 3: Cho cn bing héa hoe sau trong binh kin: 2NO> (k) = N04 (k) (miu nu 43) (chong mau) Biét khi hg nhiét 46 cia binh thi mau nau dé nhet dan. Phan tmg thudn cd . AH > 0, phin ting toa nbiét ew <0, phin ting t6a nhigt «C. AH > 0, phan tng thu nhigt D. AH <0, phan img thu nhigt Cfiu 4: Cho cée cn biing héa hoe sau: 2802 (k) + O2 (k) = 280s (k) No (k) + 3H & 2NHs (k) ¥CO2 (k) + Ha (k) = CO (k) + #20 (&) 2HI (k) = Ha (k) + 12 (k) Khi thay déi 4p suit, cdc cn bang héa hoc déu khong bj chuyén dich la A. (1) va 3) B. 2) va (4) c.a)va@) hlowe Cafu 5: Xét can bang: No(k) + 3Ha(k) 5 2NH3(k) , aaBiéu thite hing s6 cén bing cia phan ing la: (1) Fn (k)+ hk &®) S$ 2H (k) (2) 2NO (k) + Or (k) $ 2NO> (k) (3) CO (W) + Ch{k) $ COCh (k) (4) CaCOs (1) $5 Ca0 (¢) + CO2 (k) (5) 3Fe (1) + 4H20 (k) 5 Fess (x) + 44 (k) Céc cfin bing chuyén djch theo chiéu thufin khi ting 4p suét la: A.(1), 4). B.(1), (5). +C- (2), (3), (5). BO, @). Cau 7: Ngudi ta cho No va He vao wong ah kin dung tich khong di va thye hign phan img: bt tik s 2NHs Sau m6t thai gian, néng 49 ede chit trong bi nhur Sau: [Nz] = 2M; [Ha] = 3M; [NH] = 2M. Néng 4§ mol/l cia Nz va He ban dau lan hyot 1a: ‘ © 3 va 6. 4B.2vA3. C.4 vas, D.2va4, Cau 8: Chon phuong én ding: ‘Cfiu 6: Cho cdc can bing: ‘ Cho phan img: No (k) + O2(k)=2NO (k) c6 “Hive = +1808 10, G ditu kign tiéu chudn 6 25°C,, khi thu duge 1 mol khi NO tir phan img trén thi: a) Luong nhiét thu vao la 180,8 kJ, 1b) Lugng nhiét toa ra la 90,4 kJ. Luong nhiét thu vio 1a 90,4 KJ. @) Lung nbigt toa ra la 180,8 ki. ‘Cu 9: Chon trudng hop ding. G diéu kign tiéu chuan, 25°C phan img: Ha(k) + % Ox(k) = H20(6) Phat ra mot long nhiét 241,84 kJ. Tir day suy ra: 1) Nhiét dét chay tiéu chun & 25°C cita khi hydro 1A -241,84k/mol 2) Nhiét tao thanh tiéu chudn 6 25°C cia hoi nude 1a -241,84kI/mol 3) Higu img nhiét cita phan tmg trén 6 25°C 1a -241,84kIry L / ZvxvxeC4) Nang lugng lién két H ~ O la 120,92 ki/mol a) 1,3,4 () 17,34 nw) 13 oD 24 Cau 10: Chon truéng hop dung. Trong cdc higu img nhiét (DH) cua. me phan tmg cho dudi day, gid tri nao 1a higu (mg mhigt ait chay? hE? 1) C(gr) + '402(k) = COW) 8 =-110,55 KI 2H) +4020 = 1.00) SHS =.97,84K5 3) C(er) + 00) = Coxe). 4H ¥8 =-393,50K a) 3 b) 13 49 12 @) 23 Cu 11: Chon truéng hgp ding. Cho nhigttgothanh iu chudn 625° cia céc chlt NHs, NO, Hi0 lin ligt bing: -46,3;+90,4 va-241,8 ki/mol. Hay tinh higu img nhiét cia phan tng: 2NH(k) + 5/202(k) » 2NO(K) + 3H20(6) @ ~ 452kI b) +406.8 kT 9) 406.8 ad +452K) “au 12: Chon gid tri ding. Khi dét chy than chi bing oxy ngudi ta thu duge 33g khi cacbonic vi c6 70,9 keal thoat ra 6 diéu kién tiéu chudn, vay nhiét tao thanh tiéu chuén cia khi cacbonic cé gia tri (kcal/mol). 7oeey a) -709 b) 94,5 -@ 45 a) 686 Céu 13: Chon phuong én ding: Phan img: ° INOx{k) 2Na0«(k) of AOxe = -4,83510. Tinh hing sé can bing Kecta phin img NOx(k)=% N2Odk) & 298K. @) Kp=7,04 b) Ke=17442,11 ye) Kp=172,03 a) Ke=13,11 Cu 14: Chon gia tr ding. Tir cde gid tri AH & cing diéu kign cia céc phan img: (A) 280:(k) + O2(k) = 2S0s(k) AH = -196 kd (2) 2S) + 30x(k) = 280x(k) AFB = -790 KI tinh gia tri AH 6 cing digu kign 46 cia phan tg (3): S(r)+ O2(ke) = SO2(k) So, 99,70: 20. OS 1D aa) SO: & Oe - S037 2 p 4 Zar S400 - $0, aCe NN ay 1, aS 4 7? p 30. Foy ra ea Sea Cc. 4 AH, > SH, +4M “athe Are AyAH = -297kJ ©) AH3=594 ks Cau 15: Cho cdc en bing: (1) He (k) + Ia (k) $ 2H (k) (2) 2NO (k) + O2 (k) $ 2NO> (k) (3) CO (k) + Chak) 5 COCh (k) (4) CaCOs (£) $ CaO () + CO2 (k) (5) 3Fe () + 4H2O (K) 5 FesO4 (1) + 4H (&) $6 pha cé trong hé ln lugt la: 1,1,1,3,3 b)1,1,1,2,2 0) 1,1,1,3,2 4)1,1, 1,23 ‘Cu 15: Cho phan tmg 3Fe (r) + 4H20 (k) 5 FesOs (1) + 4H (k) Béc tudo cia hé la... ¥ nghia cia né li ti Du =o 4a) 1,chicé ép sudtanh huing dénhé can bing = * (&) ty chi c6 mhigt 4p anh huéng dén he cfn bing +0) 2, canbiét d6 va dp sudt anh hudng dén edn bing d) 0, khdng cé yéuté nao anh hudng dén can bing trén Céu 16: Hé duéi day 1a tang hay gidm 46 hin loan? vi sao? CO (&) + Clk) $ COCh (6) a) Tang vi An>0 (b). Giam vi An <0 c) Bing 0 viAn~0 d) Khéng thé xée dinh duge Cau 17: Cho phan tmg: A(k) $ Bk) G nhigt 45 TI = 300K, hing s6 can bing K = 10-2. 6 nhiét 49 T2 = 500K, hing 6 can bing K = 10-4. Phat biéu mio ding: ra. Hé thu nbiét, AH>0 b, H6 téa nhigt, AH > 0 b. Hé thu nbigt, AH <0 (@xe¢ a ahi, AH <0 Cau 18: Cho cée phan img: (1) Cer + 02(k) > COx(k) (2) Fh (k) + 1/202 (K) > H:0 () (3) H20 (®) S H20 (1) S6 cu tir, s6 pha lan lugt 1a: #9), G.2), G,2), (2.2) b) (3.3), (3,3), (2,2) } (3,2), (3,2), (12) 4) B.2), 3,2), (11) Céu 19: Chon phwong én ding: Phin img: 2A(k) + B(k) = 3C(r) + D(k) ¢6:Q. AS <0 b) AS=0 9) AS>0 4) Khéng dir dodn duye déu cia AS (Cau 20: Chon phuong én ding: Phin img 30/1) 20,09) dibukiga itu chudn 06 4B" = 284410, 29% = 139.8 IK. Biét ring bién thin entanpi va bién thién entropi cia phan img it bién déi theo nhigt 49, Vay phat biéu nao dusi day 1a phi hop voi qua trinh phan tmg: @) Phan tmg khing xay ra tr phat & moi nbiét 46. db) GO nhiét 46 cao, phan tg dién ra ty phat. ¢) Onhiét dp thip, phan img dién ra tu phét. d) Phan img xay ra ty phét 6 moi nhigt d6.