Wh by th be ke yl, 2 wh yor, - . MRT ren wtf L ud tyon, tong Any eh My tom Kou as Baste | Sty, HdisOV we ety, = 4eev- rik Aa) Ay 2 fut / tu O naty nt @ a5'c k 2 i ct Wi of wf th He Ak hey uch thay 0 gan Dag cn fy gy dg J Adi hin hash, lh Ay, 6! cde bay Cha pih kg de a 2S \ oly a y co #08 a Aki Ae: ae REF = Asm ty. FOL fh ly RR ihn A uO gid, a dee tush Ua P= AGE wnt, - tuo Js wh del de he MAD gta NW. pla ach typ, “ (28, 48.46) Gue, t& oo ae oh Apa, Caste de 45 107 9) TK dy Met tan (well) tak %, WE Aauugin chal Da fat awd MG biiy sas re ua Gy Foy Mh Ty ty ta Boom ah a dug te ta, J baa Wn 8d C4 te wth A ApS? ' o) Dy da Jyai, be Aa cud on opm; ot OM a fy tay Doak ta 3 asic gig 1 ies day? x Gath aru) (4) A) Wwe dig scan baby Kot AG uh pla ay UD 2? ate a oc iste © gay gat = O1d6y; ota = oifo V us: Wag a wy HE uh oe pled say ai an'c we 28'c hin Saat Wiig Si ple sie phe “eG Nae wpe alg» Tad, velig ldg Atgh fe’ uh pda algHe, 713 here. 1 - H Sa ‘ ek Bs Tae S00 mh chy dh bat hot payee vad He ok da tn, Th pn ul dun, diy ta AA TB t tide B) Uo tap Ay nee Bik, Se lie AS ee es eA dag tl Ma addy 1 Ge adh ig hh ; BPO yak ig Hea A ont awh al fag = Bit ag uty = V Cot Se Se thy ka dee Bo 4/2 -n8D = mit ays | & gt a8 Toe tk Last ow es Jove ap pot OV et Ag = OE ¥ wf / Cat. ele tal air qian bah Aah yuk aa aaa & 6 ) Kak Ah Addiq @ vin HO tub play uty B) Toth MAT ghar Gk At ARE a ag hak aly ta gin AP dows, Yub) un dng Cia, Toh wlan ub Ag de dod ate i ae ae wii feo wd dug dh he 0/apy Tihk pR ud dung Gh fon a ) ce he a th eo Sg, Uy, AE Aig. dang ib HE hay * Gea March feisty ly tosh oy at! Feely op lool RE Ad och woah , €8 anaes ME petite = SION ET pea = Oyoov fan do - ve ani ay Ta Aaya te ily fe aly ten fee we Wee haat Pe TE demo l= SEY ee a a bead dec of © anja = die b) Ral Med tt BL da ge” va te che 3 dae at te &% Au 4, = Ban tb edn Soak Co oe W Bi hab Lady en Be th cal peg me A doy, ret Hn Aauat Shei Chath pel 8 Gin dak mn 200 nga @Cau 44.2 Thang, wth pee hdc wl oe ee wig 48 Cha AG gia AL nde wld tay S00 gldy S3TTC) Whig He chek aay Gah a ut A ne 4000 qld. Kak duh! Ree ge ste! ap 1H. ; *) Wak qfan da! wig oh ak bon Boh gfeh di 3/4 Bad) 34%c 1 Nig icy dost oo’ ek pen dy Se. Wal die doy Uh pie tau? Bet. {9G Ute atm) CH) [Me oman a at an | Gr, (te dain) , hah tay ky ud RN, od 25% Bs. uy t: Cau As, (Ro plc wg: Mo, Co day Adin 400 BS uh ph tig Be 46 10 54. 1g bay Amt Aod Eg = 52 He ut teh gl ula 42 rap Sigig 6° fol op Mes Aot g SBM, A hat tan och NgtOel, df who a TBP dime 154 g/L, Tah a “aig vhia ts T: : a) Wh den ue Ayr, WE gt uth ding Agdh Iodine? 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(Sa tS ak pin Wy A Mad ay 2 esr ed we as Hy\ ANY Sosa Kay oun | oy bal Oe ty =0/t0 V- cre wd pin chug Mi chy 0h OL eQychun tad oT Wh oe que Osh Gal Aye ol a ten ue Plah ry tung a . VU ay Ee in Lg ety Gis. YH iy 9 Wed + REE) S60A Ais & BE ® bay do~ted Sea Ink Hy foot Ad wl Bt) Ee 41 Vik Rip kay Aa Aigo nts to ro Y tip tig MS ook tel Ey uh pla uly vGa 30. q Tadhg tuk hag deo club! tig al a dot Nee O14 a talk Cyt) = Sb torte {Gs Pay, Sh ole bavete Ce Gm AN cf aig Ft al dung, ch wt cote wn. Wh Qu @ Aalg in bay han by ont ky Wwe ORL begote . Gayy, el wl nigh ch, ale pln hag te Do tude” » ae) yan tl Hise uy My phy Alaa Wa wey dd gag vet alg doo a a Cds lah leatc tala pha aby ) Tih MEX gtan dil PO% chad Ae WY pln ig. 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Yr Ast saa’ sal Wig Maw ews Andy Mh Cat, 0108 ‘ 8) St kw 3a Auk tds Andy 1 Tol So? ; 2 plan SFC @ ye ye ob Ft 8 AMC & = Abe 43 54 a Foe oka Be 4k nay alg eh fed Tay ula) Rah) = H Tih Hat goen Ad 50% ck dete plan Maj 8? 44% S Ngfst Ae mah Lap 4 pin eau ol! 2500 2din uc ¢ = Tash platin ndaly Areny 46 Cds Fe CWO Oe A ir Re (Wl) 5 74m ~ Teh bac subg tiny dug dich My ou, Ce © Ft ip 2 02Vy C gti = OY 9 Tilt te an tg & ob pin ae by) Waa ep wm do gin Wi! ok caf Ube dn ate J Naf oh pata uy Yay ta MOE py An wee - fe. Srs5%, of dng Heh Chumt oom; wif On 410.40? us NU va Aso US dung Ath tay MD GH wd dung did au dus by bao abit? A 4! 25% | Wig sot dn Ay wb on Chomy be = 15,4605 WT quo a Ady Ay ah we - - Hi . Sig "Ws AL ud unt ple ly 6c w tee fas a bal ANG A075 2 we! See ty yg, Jo“ F A wht stds eed Ad wh Wak 4 wd WE dd plc a y DV Nay Hitey Fond on ult phar ly Neg Wt, O1con afpe? DEthi min Hoa hye HCHIOIS— 07-01-19 (That gian: 60 phy Clu 1 (15d), 1. G nhitng qude gia hin di, miki tyét voi nhiu vi dy, ngs ta thudng rie mudi an lén myét ten during d& lim tuyét a tan, Gia thich ngin gon nguyen nha eta hign wong niy 2 Filen glicol (CH,OH-CH;OH) li mit chit ching dé hing ding cho 616. Bi Ib chit tan trong nude vi khing bay hoi Tink abit 46 bit daw 36; cia dung dich chia 651,0g hop chit niy trong 2505 auréc. Bit kHsO) = 0,520; C=12, O16 vi iu HI (2,50). ‘Dj hoa tan cia Mg(OH); & nhigt 46 T la 6,9.10% (mol). Tinh & cling nhigt dT: 1, Tieh s6 tan cia Mg(OH)> va pH ea dung dich bio hda Ma(OF), 2.6 ho an cit Mg(OH); trong dung dich NaOH 0, 1M. Ciu M1 6.09) 1. Cho | pin: (-) Zn | Zn(NOs}s 1M || Cu(NOs)2 1M | Cu (+) ‘Tinh suit dign dng ctia pin & 25°C. Viét phirong trinh phan img & céc dign cue, phan img ting cng, xie dinh chigu dang electron va chigu dong dién ki pin lim viee? Cho bidt 25°C 6° zn" 2n=-0,76V va 8° Cu" Cu =0,34V, 2, Co eda bing sau trong dung dich aude & 25°C: 2Cu" > Cu + Cu (1) 2. Xe digh chiéu cua phan img (1) 6 digu kign chudn vi 25°C? b. Tinh hing sé cin bing K vt AG" ea phn tng (1) 25% Cho bidt & 25°C: 6 cu 134V vil €" Cu (Cu = 0,52V. Ciu IV G,0d). 1. Hing s8 vin tbe ei mot phin & 61°C va 71°C lin lugt bing 0,157.10" phat va 0,445.10" phi! Xie dinh bd vi inh ning lugng hoat hoa cia phan img. 2, Oxit mety! phan huy theo phan ting bic 1: (C11}:0 (&) —» CH 0) + CO) # Th Ban du chi osit metyl vii ép suit do duge ki P, ~ 300 mmllg. Véi (= 10 gidy, do duve ap sult chung P = 308,1 mullg. Tink hing s6 th d6 k-va thoi gian nia phn img t > (phat 8 thé tich 6 dinh)(Thi két thie HP 19-06-2019) béthisé. 01 Cau 1 (1,5 diém) Vinh nhiét do bar dau dong dic va nhigt dO bat diu séi cua dun; : ig dich chia 17.1 g duong saccaroze (CiaHs20),) trong $00 g nude. Biét: ky(H,O)=1,86: k.(H:0}= 0,52: C=12, O= 16 va HEL. (That gian kam bec 60 pity Cau 2 3.0 diém) - Tron 800 ml dung dich Ag! bao hoa vi 200 ml dung dich Hl 0,5M 625°C. Tinh pH va néng 5 4 cua Ag’ va cia dung dich sau khi tron, Biét @ 2: 5°C. tich sé tan cua Agi 1a 1.5.10. 2. Tinh pH eta dung dich axit HCOOH 1M 6 25°C. Biat 625°C. K,(HCOOH) = 1.7.10, Cau 3 (3.5 diém) |. Mét pin durge eau tao nhu sau 6 25°C: 3 (-) Pt| Fe!" 0.2 M; Fe™* 0.4 M | Fe" 0.4 M; Fe™ 0.2 M| PI(+) a. Tinh suat dign dong cua pin. b. Viet phurong trinh phan img xay: rad cic dign cye va phan img tong cong. <. Tinh néng d6 eae ion Fe" va @ cae dign exe khi phan img trong pin dat dén trang thai can bang. - Co ean bang sau trong dung dich nude 6 25°C: 3Au" «+ Au + 2Au (1) a. Tinh hing sé cn bing K cia phan img (1) 6 25°C. b. Tinh €° aucvaw 6 25°C. Cho biét €°Av'/Au' = 1.4 V: 8° Aut/Au = 1,7 Vs Tich 98 tan cia AuCl 6 25°C Ia 0". Cau 4 (2.0 diém) Nong d6 ctia cde chat tai 53°C trong phan img 2N;Ox (k) > 4NO; (k) + O, (k) thu durge trong bang thye nghiém sau: N3Og 0.0200. 0.0169 0.0142 0.0120 O.O10L Ning 46 (M) NO; Ae dinh thoi gian cén lai mt nua Itegng NOs (ty2) doi véi phan dmg phan hay khi N,Ox 6 nhigt 46 55°C b) Tinh ton thoi gian con tai mot nira lugng NOs khi biét hang sé tée do bling 1.7 x 107 (5), ©) Nang dO cua N20; sau thai gian St, 5. d) Xae dinh thoi gian dé ndng 46 cua NO, gid xudng con 12.5% ndng dbiban dau.del 7/1/2019 Cau 1:(1,5d) Dd CH3COOH 0,1M €6 K, = 1,75.10° & 25°C. Hdi néu thém 0,05 mol HCI vao 11 dd trén thi pH cia dd tao thanh bang bao nhiéu ? ( Bd qua sy dién li cla nudc). Cau 2: ( 2d) Cho pu’ sau: Fe3* + 3H20 = Fe(OH)3 + 3H* K = 10° 25°C. 1. Cho biét chiéu pu & di’u kin chuan va & 25°C. 2. Tinh tich s6 tan ctia Fe(OH): 6 25°C. Biét tich s6 ion cla nude 6 25°C ld 1074. Cau 3: (3,54) Cho so dO pin dién sau & 25°C: Pt | Sn** 0,11; Sn?*10° M Il Ag* 0,01M Ag Biét 6 25°C 06 €§,,4+ jgq2+ = 0,15 V VA Exgt ag = 0.8 V. 1. Xdc dinh cy (+) va cy (-) cua pin. 2. Viet pu’ xay ra & cdc dién cue va pu tong cong xay ra trong pin khi pin hoat d6ng. 3. Tinh hang sé can bang cua pu da viét & 25°C. 4. Tinh AG cia pu da viét & 25°C. Cau 4: (3d) 1. Hang s6 vn téc cla 1 pu’ & 20°C va 25°C [an lot bang 5,6 I/mol.ph. Xac dinh: - Bac cua pu. - Nang lugng hoat héa cua pu. - Hé sé nhiét d6 cua toc dé pu (y). 2. Tai sao t6c dé pu lai giam dan theo thdi gian ?chk S1Op : 1.869, C12. O=16¥