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1.solar Radiation
1.solar Radiation
Fig. 4: Emissions of carbon due to fossil fuel used in the world. A: Total, B: Petroleum, C: Coal,
D: Natural gas, E. carbon emissions due to cement production. Arranged by Prof. Dr. Asad Naeem Shah
USE OF FOSSIL FUEL Cont.
• Figure 5 shows the trends of petroleum consumption by the world's
two most populous countries—India and China—as compared to
USA, Japan, and South Korea.
As the economies of these countries are growing, the people are
copying the lifestyle which the consumerist western countries had
adopted till recently.
Million barrels per day
Years
Arranged by Prof. Dr. Asad Naeem Shah
USE OF FOSSIL FUEL Cont.
• The increasing use of vehicles, other materials, and power
surely has contributed to the degradation of the environment
at much faster rate than the ability of the environment to
assimilate. From 2004 onwards, the demand for petroleum by
India and China has begun to rise faster than it has ever
before.
• The world's oil reserves are now 'peaking', which means there
are no new reserves to be found and if we continue to use the
existing reserves at the present rate, from now onwards the
reserves will keep declining till they get totally exhausted by
about 2080 (Fig.6).
• All other fossil fuels are expected to peak by 2030 and exhaust
by 2230.
Arranged by Prof. Dr. Asad Naeem Shah
USE OF FOSSIL FUEL Cont.
Fig. 6: Peaking of fossil fuel use and the eventual exhaustion of fossil fuels.
A: All fossil fuels combined, B: Petroleum crude, C: Coal, D: Natural gas.
Arranged by Prof. Dr. Asad Naeem Shah
USE OF FOSSIL FUEL Cont.
• Thus, within a matter of less than 200 years we have burnt
away half of all the fossil fuels which the earth had taken
several million years to generate.
• The carbon that had been 'plucked' from the atmosphere (and
water bodies), and had been sequestered over millions of
years has been released back to the atmosphere (and oceans)
by us in just under 200 years. And if we continue at the
present rate we would release all of the sequestered carbon
in another 200 years.
• Can such a massive interference with the global ecosystems
be done without any side effects showing up?
𝑵𝒐, 𝒊𝒕 𝒄𝒂𝒏′ 𝒕 𝒃𝒆!
• So we have global warming and ocean acidification on our
hands now!
Arranged by Prof. Dr. Asad Naeem Shah
GLOBAL WARMING
The increasing trends of atmospheric C02 concentration in the 140
years, during which large quantities of fossil fuels were used, are
given in Table 1.
TABLE 1: Trends in atmospheric C02 and average air temperature (IPCC, 2007)
Year Atmospheric C02 (ppmv) Average temperature
(°C)
1800 280 15
1870 280 15
1950 305 15.2
1970 325 15.2
1988 350 15.5
2000 360 15.8
2006 375 16
2008 380 16 +
2050 forecast -550 Up to 17.2
2100 forecast Up to ~800 Up to ~19.2
Fig. 3
Arranged by Prof. Dr. Asad Naeem Shah
PROBLEM
Obtain Wien's displacement law by using Plank’s law of
radiation i.e.
𝑪𝟏
𝑬𝝀𝒃 = 𝑪𝟐
𝝀𝟓 . 𝒆 𝝀𝑻 − 𝟏
𝐶2 = 14387.9 𝜇𝑚. 𝐾
where
𝐴 = sin 𝜙 cos 𝛽
𝐶 = sin 𝛽 sin 𝛾
𝐷 = cos 𝜙 cos 𝛽
360° 284 + 𝑛
𝛿 = 23.5 𝑠𝑖𝑛 = −17.5℃
365
Also 𝜔 can be calculated at 10 AM, which is −30°
Thus from the Eqn. given below, 𝜃𝑖 may be calculated:
𝑯𝒄 = 𝑮𝒃∗ 𝒄𝒐𝒔 𝜽𝒊 + 𝑮𝒅 𝒅𝒕
Fig. 2: Short (including visible) and long wave (far infrared) spectral
distributions at the top of the atmosphere.
Arranged by Prof. Dr. Asad Naeem Shah
ATMOSPHERIC ABSORPTION AND
RELATED PROCESSES Cont.
It is obvious from Fig. 2 that a definite distinction can be made
between the spectral distribution (i) of the Sun’s radiation
(short wave) and (ii) that of the thermal sources (long waves).
The infrared long wave fluxes, however, at the Earth’s surface
are themselves complex and large. The atmosphere radiates
both down to this surface and up into space.
The temperature of the Earth’s system in space is that of the
outer atmosphere and not of the ground and sea surface.
The Earth’s average surface (not space) temperature is 17℃ i.e.
~40⁰C greater than the effective temperature 𝑇𝑒 of the outer
atmosphere or space.
Arranged by Prof. Dr. Asad Naeem Shah
ATMOSPHERIC ABSORPTION AND
RELATED PROCESSES Cont.
Actually, the atmosphere acts as an infrared blanket, because some of
its gases absorb long wave radiation. Thus increase in surface
temperature (relative to what it would be without the atmosphere) is
called the greenhouse effect, and the gases responsible for it are called
greenhouse gases (GHG).
The glass of a horticultural glasshouse (a greenhouse) likewise prevents
the transmission of infrared radiation from inside to out, but does
allow the short wave solar radiation to be transmitted.
Thus the Earth’s atmosphere is not only a source and sink of chemical
substances for life, it provides the physical mechanisms for controlling
the environmental temperature at which life continues and at which
water for life remains liquid.
ABSORPTION IN THE ATMOSPHERE: In order to explain the
absorption processes, the solar short wave and the atmospheric long
wave spectral distributions may be divided into following regions:
Arranged by Prof. Dr. Asad Naeem Shah
ATMOSPHERIC ABSORPTION AND
RELATED PROCESSES Cont.
Short wave ultraviolet region (𝝀 < 𝟎. 𝟑𝝁𝒎): Solar radiation is
completely removed at sea level by absorption in O2, O3, O and N2
gases and ions.
Near ultraviolet region ( 𝟎. 𝟑𝝁𝒎 < 𝝀 < 𝟎. 𝟒 μm): Only a little
radiation is transmitted, but enough to cause sunburn.
Visible region (𝟎. 𝟒𝝁𝒎 < 𝝀 < 𝟎. 𝟕μm): The pure atmosphere is
almost totally transparent to visible radiation, and becomes an
open ‘window’ for solar energy to reach the earth. About half of
the solar irradiance is in this spectral region as shown in Fig. 3.
However, aerosol particulate matter (PM) and pollutant gases can
cause significant absorption effects.
Near infrared region (𝟎. 𝟕𝝁𝒎 < 𝝀 < 𝟐. 𝟓μm): About 50% of the
extraterrestrial solar radiation is in this region. Up to about 20% of
this may be absorbed, mostly by water vapor and also by carbon
dioxide (CO2) in the atmosphere. Arranged by Prof. Dr. Asad Naeem Shah
ATMOSPHERIC ABSORPTION AND
RELATED PROCESSES Cont.
Far infrared region λ > 𝟏𝟐 μ𝒎 : The atmosphere is almost
completely opaque in this part of the spectrum.