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Atoms (PPT 2)
Atoms (PPT 2)
Atoms (PPT 2)
Equation.
Particle In One Dimension
e,g – Particle in a box
∞ ∞
Consider the motion of a particle of mass ‘m’
along x- axis and confined between the walls of
the container of length ‘a’.
The Schrodinger’s equation in one dimension is
given by:
….. (1)
Since the particle travels along x-axis only and is
moving in the region x = 0 and x = a.
𝝍 = 𝑨𝒔𝒊𝒏 𝜶𝒙 …… (6)
𝝍 = 𝑨𝒔𝒊𝒏 𝜶𝒂 …… (7)
The
Theright
rightside
sideofof
equation (5)(7)
equation cancan
be zero only
be zero
when
only either
whenA=0 𝛂a =or0. sin 𝛂a = 0.
or sinA=0
either
then𝚿𝚿will
IfIfAA==0,0,then willbebezero
zeroat at
allall
points in in
points the
box
the which is impossible,
box which therefore
is impossible, therefore
sin𝛂𝛂aa==00
sin