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02.10.22 - SR - STAR CO-SC (MODEL-A&B) - Jee - Adv - 2019 - P1 - PTA-3 - QP
02.10.22 - SR - STAR CO-SC (MODEL-A&B) - Jee - Adv - 2019 - P1 - PTA-3 - QP
02-10-22_SR.STAR CO-SUPERCHAINA(MODEL-A&B)_JEE-ADV_PTA-3_SYLLABUS
PHYSICS: COM and Collisions: Systems of particles; Centre of mass and its
motion; Impulse; Elastic and inelastic collisions.
CHEMISTRY: HYDROCARBONS:
Alkanes: Homologous series; Physical properties (melting points, boiling
points and density) and effect of branching on them; Conformations of
ethane and butane (Newman projections only); Preparation from alkyl
halides and aliphatic carboxylic acids; Reactions: combustion,
halogenation (including allylic and benzylic halogenation) and oxidation.
Alkenes and Alkynes : Physical properties (boiling points, density and
dipole moments); Preparation by elimination reactions; Acid catalysed
hydration (excluding the stereochemistry of addition and elimination);
Metal acetylides; Reactions of alkenes with KMnO4 and ozone;
Reduction of alkenes and alkynes; Electrophilic addition reactions of
alkenes with X2, HX, HOX, (X=halogen); Effect of peroxide on addition
reactions; cyclic polymerization reaction of alkynes.
MATHEMATICS: Indefinite Integration: integration as the inverse process of
differentiation, indefinite integrals of standard functions.
integration by parts, integration by the methods of substitution and
partial fractions.
ax 2 bx c dx and ax b ax 2 bx c dx
Narayana IIT Academy 02-10-22_SR.IIT_*CO-SC(MODEL-A&B )_JEE-Adv_PTA-3_Q’P
TIME: 3HRS IMPORTANT INSTRUCTIONS Max Marks: 186
PHYSICS
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I (Q.N : 1 – 4) Questions with Single Correct Options +3 -1 4 12
One of More Correct Options Type
Sec – II (Q.N : 5 – 12) +4 -1 8 32
(partial marking scheme) (+1)
Questions with Numerical Value Type
Sec – III (Q.N : 13 – 18) (e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐1 +3 0 6 18
27.30)
Total 18 62
CHEMISTRY
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I (Q.N : 19 – 22) Questions with Single Correct Options +3 -1 4 12
One of More Correct Options Type
Sec – II (Q.N : 23 – 30) +4 -1 8 32
(partial marking scheme) (+1)
Questions with Numerical Value Type
Sec – III (Q.N : 31 – 36) (e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐ +3 0 6 18
127.30)
Total 18 62
MATHEMATICS
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I (Q.N : 37 – 40) Questions with Single Correct Options +3 -1 4 12
One of More Correct Options Type
Sec – II (Q.N : 41 – 48) +4 -1 8 32
(partial marking scheme) (+1)
Questions with Numerical Value Type
Sec – III (Q.N : 49 – 54) (e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐ +3 0 6 18
127.30)
Total 18 62
m2 m2
A) sin 1 B) sin 1
m2 m2 m1
1 2
m1 m2
C) sin 1 D) sin 1
m2 m2 m1
1 2
A) m 4m0 g m0 2 gh B) m 4m0 g m0 32 gh
C) m m0 g m0 2 gh D) m m0 g m0 32 gh
5 5
A) m , towards right B) m , towards left
4 4
5 5
C) m , towards right D) m , towards left
8 8
4. A particle of mass m collides elastically with the pan of mass M 2m of a spring
balance, as shown in figure. Pan is in equilibrium before collision. Spring constant is K
and speed of the particle before collision is v0 . Maximum height attained by the particle
after collision from the point of collision is …
SECTION – II
(MULTIPLE CORRECT CHOICE TYPE)
This section contains 8 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE is/ are correct.
Marking scheme +4 for correct answer , 0 if not attempted and -1 in all other cases.
5. A block of mass M has a circular cut with a frictionless surface as shown. The block
rests on the horizontal frictionless surface of a fixed table. Initially the right edge of the
block is at x 0 , in a co-ordinate system fixed to the table. A point mass ‘m’ is released
from rest at the topmost point of the path as shown and it slides down. When the mass
loses contact with the block, its position is ‘x’ and the velocity is ‘v’. At that instant,
which of the following options is/are correct?
mR
B) The position of the point mass is : x 2
M m
2 gR
C)The velocity of the point mass m is : v
m
1
M
m
D) The velocity of the block M is: V 2 gR
M
6. A ball of mass 2 kg strikes a floor as shown in figure. For this situation mark the correct
statement(s)
A) The impulse experienced by ball during the collision is acting along the + ve y-
direction and has a magnitude of 50 NS.
B) Floor may be rough or smooth
9
C) Coefficient of restitution between floor and ball is
16
D) The direction of impulse experienced by ball during the collision is along a direction
somewhere between the + ve y-axis and + ve x-axis
7. A boy throws a ball with initial speed 2 ag at an angle to the horizontal. It strikes a
smooth vertical wall and returns to his hand, if the boy is standing at a distance ‘a’ from
the wall. which of the following options is/are correct?
2u sin
A) The time of flight is greater than
g
1
D) the coefficient of restitution between the ball and the wall is .
4sin 2 1
3J
A) If 1350 the Speed of C is
7m
10 J
B) If 1350 the Speed of B is
7m
15J
C) If 1270 the speed of A is
91m
52 J
D) If 1200 the Speed of B
15m
9. Two spheres are moving towards each-other. Both have same radius but their masses are
1
2kg and 4 kg respectively and coefficient of restitution is e then which of the
3
following options is/are correct?
4
B) Magnitude of impulse during reformation is SI units.
3
A)the maximum distance between the blocks during the subsequent motion of the
2 Fm1
system is lo
K (m1 m2 )
B)the minimum distance between the blocks during the subsequent motion of the system
2 Fm1
is lo
K (m1 m2 )
C)the maximum distance between the blocks during the subsequent motion of the system
2 Fm2
is lo
K (m1 m2 )
D)the minimum distance between the blocks during the subsequent motion of the system
is lo
11. Laila and Majnu are on a boat for a picnic. The boat is initially at rest. Laila has a big
watermelon which she throws towards Majnu. The man catches the melon and eats half
of it. He throws back the remaining half to Laila. She eats the half of the melon that she
receives and throws the reamining part to Majnu. Majnu again eats half of what he
receives returns the remaining part back to Laila. This continues till the melon lasts. The
two are sitting at the two ends of the boat which has a length L.Combined mass of the
boat and the two lovers is M 0 and the mass of the water melon is M. Assume that the
boat can move horizontally on water without any resistive force. The displacement of the
boat when
L
B) Watermelon gets finished is if M 0 5M
9
L
C) Immediately after Laila eat for the first time is if M 0 3M
6
L
D) Immediately after Laila eat for the first time is if M 0 5M
12
12. A wooden wedge of mass 10m has a smooth groove on its inclined surface. The groove
is in shape of quarter of a circle of radius R 0.55m . The inclined face makes an angle
11
cos 1 with the horizontal. A block ‘A’ of mass m is placed at the top of the
5
groove and given a gentle push so as to slide along the groove. There is no friction
between the wedge and the horizontal ground on which it has been placed. Neglect
width of the groove.
A) The magnitude of displacement of the wedge by the instant the block A reaches the
bottom of the groove is 5cm
B) The magnitude of displacement of the wedge by the instant the block A reaches the
bottom of the groove is 6cm
C) The magnitude of displacement of the wedge by the instant the block A rotate
through 600 about point O on wedge is between 4cm and 4.5cm
D) The magnitude of displacement of the wedge by the instant the block A rotate
through 600 about point O on wedge is between 4.5cm and 4.75cm
14. Two identical balls each of mass M (=1.25 kg) and radius R are kept in contact and are
connected to two identical unstretched springs each of force constant k(=100 N/m). A
third ball also of mass M but radius R/2 strikes with the two balls symmetrically with
speed v0(=1.6m/s) and comes to rest just after the impact. Find the maximum
compression in each spring in cm.
R/2
M
vo
k k
R R
M M
15. Block ‘A’ of mass m is hanging from a vertical spring of spring constant K and is at rest.
m 1
The value of SI Units. Block ‘B’ also of mass m strikes the block ‘A’ with
k 150
velocity ‘v’ and sticks to it. Then find the value of ‘v’ in m/s for which the spring just
attains natural length. Take g = 10 m/s2.
m1m3
sphere 2 for the sphere 3 to acquire maximum velocity is , find the value of K.
K
the distance of any point on rod measured from one end. Centre of mass of the rod from
KL
the given end is at a distance of on the rod. Find the value of K.
3
2l
18. A is a fixed point at a height above a perfectly inelastic smooth horizontal plane. A
3
light inextensible string of lengthl has one end attached to A and other to a heavy
ball. The ball is held at the level of A with string just taut and released from rest. The
gl
speed of ball just after striking the plane is n times m/s. Find n. (Neglect the size of
27
2l
3
A) B) C) D)
( x) ( y) ( z) ( w)
A) x > y > w > z B) y > x > w > z C) x > w > z > y D) z > x > y > w
21. Identify ‘Z’ (major product) in the following reaction series,
CH3 CH CH2
(i)B 2H6 /THF;(ii)H2 O 2 /OH
(X)
Al2O 3
(Y)
HOCl
(Z)
Cl OH OH
A) Mixture of H3C and H3C B) H3C
Cl Cl Cl
Cl Cl
C) H3C D) H3C
HO Cl
22. Three isomeric alkenes A, B and C, (C5H10) are hydrogenated to yield 2 – methyl butane.
A and B give the same 3 ROH on oxymercuration – demercuration. B and C give
different 1 ROH on hydroboration – oxidation. Some of the possible isomeric structures
for C5H10 are as follows
(I) CH 3 CH 2 CH 2 CH=CH 2 (II) CH 2 = CH - CH(CH 3 ) 2
A) B) C) D)
24. An alkene on reductive ozonolysis yields only ethanal. The other isomer(s) of this alkene
on reductive ozonolysis may give
A) Propanal B) Methanal C) Propanone D) Isobutanal
25. Correct statement(s) regarding addition of Br2 to the following compound is/are
Me
H
Et
H
H Me
A) Br2 serve as electrophile in the first step of reaction
B) Total two (major) products are formed.
C) Cyclic bromonium ion is formed as the intermediate.
D) If this addition proceeds in H2O, bromohydrin forms as product
26. Identify the correct statement(s) about the product “A and B” formed in the following
reactions :( Consider only major products for both reactions and Assume carbocations do
not rearrange)
27.
Br
Excess alcoholic O3 /H 2O
mixture of products P1 and P2
KOH/ X
Br
P2 on reaction with MnO2 and conc. H2SO4 give CO2 and H2O only
1.
2.
AlCl3
Q1 C
Zn/Hg
oncHCl
R1 1.S
OCl2
S1
LiAlH4
T1 H /
e/
U1 S V
2.AlCl3
A) X is
B) U1 is aromatic
C) T1 gives white turbidity immediately with Lucas reagent.
D) V is naphthalene.
28.
C6 H10 ( X )
excess Cl2 / CCl4
C6 H10Cl2 ( B)
O3 / H 2O2
C) Compound (A) can gives +ve iodoform test assuming at least five carbon atoms are
present in the parent chain.
D) Only one structure is possible for (X) which satisfies all the conditions.
SR.IIT_*CO-SC Page. No. 13
Narayana IIT Academy 02-10-22_SR.IIT_*CO-SC(MODEL-A&B )_JEE-Adv_PTA-3_Q’P
29. Which of the following reactions are correctly matched with their major products?
COOH
(i) NaOH
A)
(ii) Electrolysis
COOH
COOH
(i) NaOH
B)
COOH
(ii) Electrolysis
Cl
CHCl3(1eq) / Me3COK
C)
Δ
Cl
D) Alc.KOH/Δ
H3C N CH3
H2O2/Δ
A (Major product)
D)
CH3
Major product A is
32. The number of alkenes (open chain as well as cyclic) of six carbon giving same product
with HBr in presence of peroxide and absence of peroxide
33. How many compound(s) give three structural products (including one product is
formaldehyde) after ozonolysis.
If :
p = number of ( – H) in compound X;
q = number of ( – H) in compound Y
Then value of (q – p) is
H
B
Ni
2
A
HOTKMnO 4
diethyl Ketone + CO 2
Alkene
Cl 2
hν
X
Fractional
distillation
Y fractions
number of isomeric
monochloro products
36.
1
1
1 4 x 3
1 4 x 3
A) 6 tan 1 1 c B) 3ln 1
c
x3 1 4 x
3
1
1
1 4 x 3
1 4 x 3
C) 6 cot 1 1 c D) 3ln 1
c
x 3 1 4 x
3
x. f ( x) dx equals to
x2 x2 x2 x2 x2 x2 x2
A) ln x c B) ln x c C) ln x c D) ln x c
2 4 2 2 2 2 4
(where c is the integration constant)
x 2 1 nx
40. n4 x x 4 dx equals
1 x 1 1 nx x 1 1 nx
n n n x x C n tan C
2 2
A) B)
2 nx 4 4 nx x 2 x
A) f B) f C) f D) f
4 4 2 4 2 4 4 4 2 4 2 4
7
x 1 4 dx g x & g 1 0 . Then which of the following option(s) is/are
42. If 15
x 2 4
incorrect?
A) Largest set of values of " x " for which g x is defined is R {2}
B) Largest set of values of " x " for which g x is defined is R [2, 1)
C) Range of y g ( x) is 0,
4
11
3
D) g t t 2
11
cos x sin x 1 x
43. If e x sin x x dx log e f x g x c where c is integration constant and
f x is positive function such that f 1 0 3, g 0 0 then
A) f x g x is an even function
B) f x g x is an increasing function
C) f 0 g 2 1
D) If a function h x is such that h x e x f x g x then maximum value of h x is 1
sin 2 x
dx e .g x c , where
f x
If e
x tan x
x tan x
2
x sec
44. ' c ' is a constant of
2
integration then which of the following is/are incorrect?
A) f 0 is equal to 1
3
B) Number of solution(s) of the equation g x 2
1
x 3 is 3
2 2
3
C) Number of solution(s) of the equation g x
1
2 x 3 is 1
2 2
D) f x is an even function
1 x 1
2
1 x2 1 1 x2 2 x 1 1 x
2 c
1
C) tan ln c D) tan
2 2 2x 4 2 x2 2 x 1 4 2x 2x 2
(where ' c ' is a constant of integration)
3cot 3 x cot x
46. If tan x 3 tan 3x dx p f x q g x c where ' c ' is a constant of integration, then
1 3 tan x
A) p 1; q ; f x x; g x n
3 3 tan x
1 3 tan x
B) p 1; q ; f x x; g x n
3 3 tan x
2 3 tan x
C) p 1; q ; f x x; g x n
3 3 tan x
1 3 tan x
D) p 1; q ; f x x; g x n
3 3 tan x
is equal to 1 .
B) If is one irrational root of equation f x f ' x 0 , then 4 4 3 2 2 4
is equal to 0.
C) f x is Strictly decreasing in ,1
C) 2 A B 0 D) 2 A B 2
(Where c is the constant of integration and A and B are lowest form of rational numbers)
1
constants, for m=97 and n=33, equals ______ (where [.] denotes Greatest
A B
Integer Function and x represents modulus of x)
sec x(2 sec x)
50. If (1 2sec x)2
dx = f ( x ) c ; where c is the integration constant and the curve
y f ( x ) passes through the origin, then 2 f f ( ) equals
2
P x
n
x18 1
51. If 1
dx can be expressed as c where P x is polynomial in ' x '
10 x 5
x 54
3x 2 x
42
36 6
of lowest possible degree, n is the lowest form of a rational number and c is the
integration constant then the number of distinct real solution(s) of P x 0 is
52. Let
cot 2 x cot 3x tan 2 x tan 7 x tan 5 x dx a ln tan 2 x b ln sin 3x c ln sec 5 x d ln cos 7 x C
where a, b, c, d Q and C is the constant of integration. If a b c d can be expressed
m
as in the lowest from, then m n equals
n
1 3 x
m
53. Let dx k 1 3 x C , where k N , m is a rational number which is in the
3
x2
p
form of where p, q are coprimes and C is the constant of integration then k 2m is
q
equal to
3e x 5sin x 10 cos x
54. Let I dx mx n n e x 4sin x 3cos x C , where C is constant of
e x 4sin x 3cos x
integration and m, n N , then the value of m 2 n 2 is _______