Adhesives Used For Mounting Photographic Prints of The 19th and Early 20th Centuries

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Adhesives used for mounting photographic prints

of the 19th and early 20th centuries


Alice Cannon

State Library of Victoria


acannon@slv.vic.gov.au

Abstract
This paper is the result of research conducted to determine the types of adhesives used to mount print photographs
up until 1920. Sources consulted included conservation literature, historical photographic journals and the relevant
trade and patent literature. A total of 185 recipes were found. The adhesive recipes were inventoried and the
various constituents of these recipes are discussed, particularly in reference to their possible effects on solubility and
permanence. Along with the recipes, a short history of adhesives for photographs is provided, including a discussion
on mounting methods. Pre-1920 photographers were concerned with all issues of permanence, and adhesives were
recognised as a potential source of deterioration. This would appear to have led to a generally conservative choice
of adhesive. The identified recipes tended to be simple, with 41.6% consisting only of the adhesive material and its
solvent. Starch and gelatine were the most common adhesives used, with dextrin and gum arabic also used frequently.
Less common were rubber, animal glue, shellac, flour and gum tragacanth. Fish glue, mastic, balsam, casein, egg, elemi
and gutta percha were used occasionally. About a quarter of all recipes contained more than one adhesive material,
with common mixtures including gelatine, gum arabic or dextrin mixed with starch or dextrin mixed with gelatine.
When additional ingredients were added, these were most often preservatives, such as carbolic acid or essence of clove,
or humectants, such as glycerine and sugar.

Keywords: photographs, mounting, adhesive, starch, gelatine

Introduction affect how easily a problematic adhesive can be removed.


Although not the primary concern of the early For this reason, pre–1920 adhesive recipes were
photographer, mounting was nonetheless recognised as collected to find out more about the adhesives used to
an important step. Adhesives and mounting methods mount early photographs. Recipes were collected from
were a regular topic of discussion in photographic contemporary photographic journals, newspapers and
journals of the time, and it would appear many budding relevant trade publications. The ingredients in each
photographers found mounting their photographs a recipe were tabulated, in order to gain an understanding
challenge of the highest order: ‘Many amateurs manage of their relative prevalence—and thus how likely it is
their work admirably well until they come to the that a conservator working on photographic collections
mounting of their prints, and as they approach this stage may encounter them.
it is with great fear and trembling…’ (AGJ 1896). Information about the manner in which photographs
Photographers were also concerned about the effect were mounted was also collected, as it can reveal practices
of adhesives on the longevity of their prints. ‘It is an that have since affected the condition of the photograph.
incontestable fact known to all photographers…that the
fading of silver prints is more often caused by the way in Terminology
which the picture is mounted rather than being due to Pre-1920 photographic sources generally refer to
any inherent defect in the process by which the picture adhesives for mounting as mountants. Paste usually
has been produced. The fault may lie in the mount or indicates a flour or starch-based adhesive but was
card to which the picture is attached, or it may be due also used to describe various wax preparations used
to the paste or other medium by which the print is as coatings. The term glue usually denotes animal
fastened to its support’ (Anon 1892b). glue. Gum could be used to describe gum arabic, gum
Conservators are also interested in the effects of tragacanth and other plant gums, or dextrin, which was
adhesives on image permanence, as well as issues that prepared from starch treated with acid and/or heat.

1 AICCM Bulletin Volume 32, 2011


For example, the term British gum referred to a type of the 1930s and 1940s, respectively (Norris & Draghetti
dextrin prepared by roasting starch. 1962, pp. 349–352 & pp. 366–8). Though acrylic
acid was first synthesised in 1843 and trials of acrylic
Components of an adhesive esters were conducted in the 19th century, commercially
The ingredients of an adhesive formulation consist useful syntheses of acrylic esters were not discovered
of at least one adhesive material (such as gelatin or until 1928 (Eisenträger & Druschke 1977, p. 528). It
starch), a solvent (often water) and various additives. is therefore unlikely such materials will be found on
The adhesive (or binder) is the material that gives the photographic materials mounted prior to 1920.
formulation its tack. Secondary adhesive substances,
added in smaller quantities, are sometimes referred to as Mounting photographs prior to 1920
“tackifiers”, especially when they increase the initial “grab” Photographs were mounted for presentation
of the adhesive. Furthermore, the working and drying purposes—for display at home, for sale or for exhibition
properties of adhesives are often altered by the addition in competitions. Scrapbooks and photo albums
of various preservative materials, driers, plasticising became common during the Victorian era and, though
agents, pigments and perfumes. photo corners and other non-adhesive attachments
methods were also used, adhesives were often used to
Adhesive materials available prior to 1920 attach prints to the page. A popular amateur pursuit,
Plants and animals were the primary sources of adhesive photographic mounting was performed both in
materials in the 19th and early 20th centuries. Animal professional studios and by home photographers.
glue, plant gums (e.g. gum arabic, gum tragacanth) and Some photographic formats required mounting in
various preparations of starch and flour had been used order to be viewed successfully. Albumen prints are
as adhesives for centuries. Shellac, casein and blood almost always found mounted to a secondary support,
were also used; casein and blood glues became more as the paper used in their production was very thin and
important commercially in the lead-up to World War I, the addition of the albumen coating gave them a strong
as adhesives for plywood. tendency to curl. The albumen process was predominant
Rubber was a 19th century discovery—at least for the throughout the 19th century but many other processes
west. Patents relating to natural rubber cements and were also available—salted paper prints, platinotypes,
adhesives were issued from 1843 (Palinchak & Yurgen cyanotypes, carbon prints, Woodburytypes, gelatin
1962: 209). Rubber is often referred to as india-rubber and collodion printing-out papers, and developing-
or caoutchouc in literature of the time. out papers. The albumen process became especially
An exception to the largely organic nature of popular after Disderi’s patent of the carte-de-visite
adhesives from this era was waterglass, soluble sodium in 1854 (Nadeau 1994, p. 27 & p. 59). The carte-de-
or potassium silicate. Waterglass was used extensively in visite, cabinet card and Paris panel are all examples of
the box-making industry from about 1825; it is unclear standard-sized mounts that were popular for albumen
to what extent it was used in other industries (Teesdale prints, though other processes can be found adhered to
& Bezeau 1922, p. 17). these formats also (Messier 2008).
Acetylated carbohydrates were known as early as From the very beginning, photographers were
1865; collodion (nitrated starch) was one of the major concerned with issues of permanence, and thus the
materials used for photographic binders throughout choice of mounting adhesive was important: ‘There
the 19th century. However, it is rare to find reference are few things which contribute more to the general
to collodion as an adhesive material. Cellulose acetate perfection of result in a picture than the mode in which
preparations do not appear in patent literature as it is mounted; and, as most photographers know, much
lacquers until 1910–11 (Gettens & Stout 1966, p. 9), of the permanency depends upon the adhesive material
though they were being used to prepare film materials used in mounting’ (Simpson 1861, p. 551).
at an earlier date. Likewise, though experiments were Staining and fading of print photographs were
recorded as early as 1872, the first patent for a phenolic common themes within the photographic literature
resin product was not issued until 1899 and the first of the time. The 1855 Photographic Committee on
use of phenol formaldehyde resin as a wood adhesive Positive Printing, known as ‘The Fading Committee’,
occurred in 1901 (Hemming 1962, pp. 298–9). found that fading was largely due to sulphur from
Synthetic adhesives would appear to be a purely residual fixing solutions or from atmospheric pollutants.
20th-century phenomenon. Patents for polyvinyl acetate As the effects of sulphur were thought to worsen in
and polyvinyl alcohol preparations were first issued in the presence of moisture, the committee expressed
the 1920s and were in commercial production by 1929, concern at the hygroscopic nature of many adhesives
but were not commercially widespread in the US until used to mount prints, including gelatin, gum and paste,

2
but recommended gelatin for mounting as a much were more varied. For example, the term ‘alcohol’ in
smaller amount was needed to create a good bond (von Table 1 includes references to methylated spirits and
Waldthausen 2005). ‘spirit of wine’; ‘sugar’ may have been included in a recipe
Photographers noted that fading or changes to the as white sugar, rock candy or honey.
gloss of the photograph often only occurred where a Of the total number of ingredients identified, 19 were
mountant had been applied to the reverse: ‘…a friend… adhesive materials—including sugar, which was also
has made it a practice to secure the edges of his used as a humectant. Table 2 contains a summary of
pictures only…the pictures in this case have all proved the substances used as adhesive materials and as other
permanent in character, except at their edges, where they recipe components. Twenty-four per cent of recipes
are attached to the mounts’ (Anon 1892c; Anon 1893c). included more than one adhesive material. Common
Acidity and moisture were often identified as mixtures were starch and gelatine, starch and dextrin,
factors affecting the longevity of the image. For starch and gum arabic, and rubber mixed with shellac.
example, Hardwich (1859, pp. 171–3) pointed to acids Plant resins such as mastic and elemi were also added
that ‘dissolved silver oxide’, including ammonia and to rubber on occasion, presumably to act as tackifiers.
sizing agents such as alum or rosin, as well as many Adhesives based on or including rubber, shellac and
mountants: ‘All cements of an acid nature, or which are plant resins could be expected to have discoloured
liable to become sour by acetous fermentation, should severely with the passage of time and to be unresponsive
be avoided.’ Others wrote on the importance of keeping to aqueous resolubilisation treatments. Combinations
photographs dry: ‘We believe that both these mountants of plant and animal adhesives (such as starch and
[starch and glue] are safe provided that the pictures to gelatine) may also prove to be less soluble now, as starch
which they are applied are kept from damp, for damp would inhibit the natural solubility of the gelatine. The
will set up chemical changes, which will often account Maillard reaction may also occur between protein and
for the destruction of the pictures subjected to its carbohydrate molecules, causing a brown discolouration
influence’ (Anon 1892b). and increasing insolubility (Cannon 2011).
Ten identified ingredients were used as preservatives
Analysis of published recipes to 1920 (see Table 2); carbolic acid and oil of cloves were the
Given photographers’ concern for purity, it is not most common. Proportions of such preservatives
surprising that most adhesive formulations recommended were generally 1% or less (Wall 1896c). For example,
for photographic prints were quite simple. Nineteenth Bacharach (1892, p. 290) recommended adding a trace
and early 20th-century adhesive recipes for paper, such of salicylic acid to starch paste, having dissolved the acid
as those listed in trade books by Standage (1902) and first in a little alcohol (‘five grains to a quart of paste is
Dawidowsky and Brannt (1905) often contained multiple ample’) to prevent decomposition and souring. Alcohol
additives, to adjust the working properties, viscosity, was sometimes used to cover unused adhesive to prevent
drying time and other characteristics of the resultant spoilage (Wall 1896c). It is difficult to judge how the
adhesive. However, those recommended for photographs inclusion of such preservatives may have affected the
contain very few additives, if any at all. ageing characteristics of the adhesive, save that they are
Of the 185 recipes for mountants found within likely to have become more acidic.
photographic journals and trade books, 41.6% Six ingredients were used as solvents—water was the
contained only two ingredients—the adhesive material most common solvent for gelatine, starch and similar
and its solvent. An additional 18.9% contained three binders, and various organic solvents (e.g. benzol,
ingredients and 21.6% contained four. The additional naphtha) were used with rubber, gutta percha and
ingredients were generally another adhesive material, plant resins. Acids (e.g. nitric acid) were sometimes
another solvent (such as alcohol or methylated spirits) added to gelatine and animal glue to lower their gelling
or a little preservative. The most complicated recipe temperature, so that they would be soluble at room
found contained eight ingredients: two adhesives (starch temperature and not require heating for use. These acids
and dextrin), water, glucose syrup, soap, borax, clove would have broken down the protein chains and may
oil and milk (Standage 1893, pp. 120–1). The simplest contribute to yellowing on ageing. Recipes for casein
recipes entailed ironing sheets of gutta percha between included a solution of borax to aid solubilisation.
photograph and mount, or rubbing the print with the Materials like chalk (calcium carbonate) were
‘juice of an onion’ (Anon 1901). occasionally added as acid neutralisers. Glycerine and
Table 1 lists all the ingredients found within the sugar were added to give flexibility to the dried film.
adhesive recipes, alphabetically. Forty-eight separate For example, on the use of gelatine, one author wrote
ingredients were identified, though the terms used to that ‘…the buckling may to some extent be avoided by
describe these ingredients within the recipes themselves the addition of sugar, three or five per cent…’ (Anon

3
Table 1. Ingredients within recipes for photographic mountants to 1920, arranged alphabetically

Ingredient Probable purpose Percentage Number


of recipes of recipes
(of 185 total) (of 185 total)
Acetic acid To lower gelling temperature of animal glue and gelatine 2.7% 5
Alcohol/methylated spirit Solvent, preservative, to prevent cockling 27.0% 50
Alum (aluminium potassium sulphate) Waterproofing agent 3.8% 7
Aluminium sulphate Waterproofing agent/adhesion enhancer 1.6% 3
(e.g. aids adhesion to wood and other surfaces)
Ammonia/ammonium hydroxide Preservative 1.6% 3
Animal glue Adhesive 8.1% 15
Balsam Adhesive/tackifier 1.1% 2
Benzol (benzene) Solvent (for rubber) 3.2% 6
Borax (sodium tetraborate) To solubilise casein 1.6% 3
Calcium carbonate (chalk) pH adjustment (to neutralise acids) 1.1% 2
Carbolic acid (phenol) Preservative 13.0% 24
Casein Adhesive 1.1% 2
Chloral hydrate Preservative 0.5% 1
Chloroform (trichloro methane) Solvent (for rubber) 3.8% 7
Chrome alum Hardener/waterproofing agent 0.5% 1
Creosote Preservative 1.1% 2
Dextrin Adhesive 16.2% 30
Egg, egg white Adhesive 1.1% 2
Elemi Adhesive/tackifier 1.1% 2
Essential oil (e.g. oil of wintergreen, Preservative, scent, to mask odours 1.6% 3
lavender)
Fish glue Adhesive 1.6% 3
Flour Adhesive 4.9% 9
Formaldehyde/formalin Hardener/waterproofing agent 0.5% 1
Gelatine Adhesive 27.0% 50
Glycerine Humectant (for flexibility) 11.9% 22
Gum arabic Adhesive 13.5% 25
Gum hog Adhesive 0.5% 1
Gum tragacanth Adhesive 3.8% 7
Gutta percha Adhesive 1.1% 2
Linseed oil Waterproofing agent 0.5% 1
Mastic Adhesive/tackifier 1.6% 3
Miscellaneous or unspecified Adhesive 1.6% 3
carbohydrate
Naphtha Solvent (for rubber) 2.7% 5
Nitric acid To lower gelling temperature of animal glue and gelatine 0.5% 1
Oil of cloves Preservative 5.4% 10
Oxalic acid To lower gelling temperature of animal glue and gelatine 1.1% 2
Rubber Adhesive 9.2% 17
Salicylic acid Preservative 1.6% 3
Shellac Adhesive/tackifier 5.4% 10
Soap Surfactant 1.6% 3
Sodium bicarbonate pH adjustment (to neutralise acid) 1.1% 2
Solvent, unspecified Solvent (for rubber) 2.7% 5
Starch Adhesive 27.6% 51
Sugar Adhesive and/or humectant (for flexibility and to prevent cockling) 8.1% 15
Tartaric acid To separate casein from milk 1.1% 2
Thymol Preservative 1.6% 3
Water Solvent 81.6% 151
Zinc sulphate Preservative 0.5% 1

4
1879). Aluminium sulfate, aluminium potassium sulfate and gum tragacanth were often used as tackifiers, shellac
(alum), chrome alum, formaldehyde and linseed oil for rubber-based adhesives and gum tragacanth in
were used as waterproofing agents, though their use combination with other starch-based adhesives. When
does not appear to have been widespread. Adhesives used as the primary adhesive material, shellac was often
containing these ingredients would be expected to resist used in combination with mastic (e.g. Dann 1879).
resolubilisation treatments (Cannon 2011). The rest of the ingredients found were used in
It can be seen from Table 3, where the ingredients less than five recipes each. Casein is only mentioned
have been listed in order of prevalence, that the most occasionally (e.g. Standage 1893, pp. 120-121) and egg
common ingredients in photographic mountants were white or albumen almost never—perhaps surprisingly,
water, starch, gelatine, alcohol, gum arabic, dextrin, given its widespread use as the photographic binder for
glycerine, rubber and carbolic acid, all used in over 10% albumen prints.
of recipes. The next most common ingredients were Only one reference to waterglass was discovered
animal glue, shellac, flour, oil of cloves, gum tragacanth, during the course of this research, in relation to its use
sugar, benzol, naphtha and unspecified solvents for as a ‘substratum in collotype work’. The author states,
rubber, all used in more than five recipes. Animal glue furthermore, that waterglass had ‘no photographic
and flour are the less pure forms of gelatin and starch, applications’, suggesting that it was unlikely to have
and so were less popular with photographers. Shellac been used as a photographic mountant to any great

Table 2. Components of photographic mountants to 1920

Purpose Identified ingredients Notes re permanence and solubility


Adhesive/tackifier Animal glue, balsam, casein, dextrin, Isoprenes (rubber, gutta percha) and terpenes (plant resins and
egg or egg white, elemi, fish glue, shellac) may be expected to discolour more with age and will be
flour, gelatine, gum arabic, gum hog, unresponsive to aqueous treatments.
gum tragacanth, gutta percha, mastic, Animal glue and flour-based adhesives are less pure products and
rubber, shellac, starch, sugar are likely to have discoloured more than gelatine and starch-based
adhesives.
Dextrin and gum arabic tend to remain soluble on aging, even in
cold water. Casein and egg proteins are difficult to solubilise in any
solvent.
Mixtures of proteins and carbohydrates (eg gelatine mixed with
starch) may be less soluble than expected, due to reactions
between functional groups on polymer chains.
Solvent Alcohol, benzol (rubber), borax Organic solvents are likely to have evaporated on setting and
solution (casein), chloroform (rubber), may have negligible long-term effects. Borax is a strongly alkaline
chloroform (rubber), naphtha (rubber), substance, which may have caused image fading.
water
Preservative Alcohol, ammonium hydroxide, These were typically added in small quantities. Some, like
carbolic acid, chloral hydrate, creosote, alcohol, would only have had an effect on the adhesive prior to
essential oil, oil of cloves, salicylic acid, setting. Others will have altered the pH of the adhesive (perhaps
thymol, zinc sulphate only slightly), which may have affected image fading and/or
discolouration. Essential oils are complex substances; it is difficult
to predict what effect they may have on an adhesive. Zinc sulphate
may cause proteins to become insoluble.
Humectant Glycerine, sugar As these materials retain moisture, adhesives containing either
of these materials may be more water soluble. Higher moisture
content may have led to greater fading of the photograph.
To lower gelling Acetic acid, nitric acid, oxalic acid Acids will have contributed to the breakdown of long protein
temperature of chains within the adhesive. The adhesive may be more acidic and
animal glue and may have discoloured more. Oxalic acid can act as a chelating
gelatine agent and bleach.
pH adjustment Calcium carbonate, sodium Alkaline substances may have contributed to image fading.
bicarbonate
Hardener or Alum, aluminium sulphate, chrome Adhesives containing these substances are likely to be much less
waterproofing agent alum, formaldehyde, linseed oil soluble when using aqueous treatments.
Perfume Various essential oils – e.g. Essential oils are complex and varied substances; it is difficult to
wintergreen, lavender predict what effect they may have on an adhesive. They would
have been added in small quantities.
Surfactant Soap May in fact decrease the solubility of the adhesive, as soaps were
typically composed of a metallic salt of a fatty acid. Soaps were used
as a wash solution by bill-posters, to improve weather resistance.

5
Table 3. Prevalence of ingredients within recipes for photographic mountants to 1920
Ingredient Probable purpose Percentage Number
of recipes of recipes
(of 185 total) (of 185 total)
Water Solvent 81.6% 151
Starch Adhesive 27.6% 51
Alcohol/methylated spirit Solvent, preservative, to prevent cockling 27.0% 50
Gelatine Adhesive 27.0% 50
Dextrin Adhesive 16.2% 30
Gum arabic Adhesive 13.5% 25
Carbolic acid (phenol) Preservative 13.0% 24
Glycerine Humectant (for flexibility) 11.9% 22
Rubber Adhesive 9.2% 17
Animal glue Adhesive 8.1% 15
Sugar Adhesive and/or humectant (for flexibility and to prevent cockling) 8.1% 15

Oil of cloves Preservative 5.4% 10


Shellac Adhesive/tackifier 5.4% 10
Flour Adhesive 4.9% 9
Alum (aluminium potassium sulphate) Waterproofing agent 3.8% 7
Chloroform (trichloro methane) Solvent (for rubber) 3.8% 7
Gum tragacanth Adhesive 3.8% 7
Benzol (benzene) Solvent (for rubber) 3.2% 6
Acetic acid To lower gelling temperature of animal glue and gelatine 2.7% 5
Naphtha Solvent (for rubber) 2.7% 5
Solvent, unspecified Solvent (for rubber) 2.7% 5
Aluminium sulphate Waterproofing agent/adhesion enhancer 1.6% 3
(e.g. aids adhesion to wood and other surfaces)
Ammonia/ammonium hydroxide Preservative 1.6% 3
Borax (sodium tetraborate) To solubilise casein 1.6% 3
Essential oil (e.g. oil of wintergreen, lavender) Preservative, scent, masking of odour 1.6% 3
Fish glue Adhesive 1.6% 3
Mastic Adhesive/tackifier 1.6% 3
Miscellaneous or unspecified carbohydrate Adhesive 1.6% 3
Salicylic acid Preservative 1.6% 3
Soap Surfactant 1.6% 3
Thymol Preservative 1.6% 3
Balsam Adhesive/tackifier 1.1% 2
Calcium carbonate (chalk) pH adjustment (to neutralise acids) 1.1% 2
Casein Adhesive 1.1% 2
Creosote Preservative 1.1% 2
Egg, egg white Adhesive 1.1% 2
Elemi Adhesive/tackifier 1.1% 2
Gutta percha Adhesive 1.1% 2
Oxalic acid To lower gelling temperature of animal glue and gelatine 1.1% 2
Sodium bicarbonate pH adjustment (to neutralise acid) 1.1% 2
Tartaric acid To separate casein from milk 1.1% 2
Chloral hydrate Preservative 0.5% 1
Chrome alum Hardener/waterproofing agent 0.5% 1
Formaldehyde/formalin Hardener/waterproofing agent 0.5% 1
Gum hog Binder 0.5% 1
Linseed oil Waterproofing agent 0.5% 1
Nitric acid To lower gelling temperature of animal glue and gelatine 0.5% 1
Zinc sulphate Preservative 0.5% 1

6
extent (Anon 1893a). Waterglass is a highly alkaline research (1993) indicates early products may have
substance; it thus may have been found to be unsuitable consisted of a thin sheet of paper impregnated with
for photographic materials. shellac or another resin. The sheet was placed between
Preparation methods most commonly involved the the photograph and its mount and attached with a
use of heat to help bring the adhesive into solution, by heated iron. Gutta percha could also be used as a heat-
warming the adhesive solution over a flame or in a water set tissue; it could be purchased in sheet form from the
bath. Often, glue or starch was softened in cold water chemist, placed on the reverse of the photograph to be
for some time, after which boiling water was added mounted and ironed in place (Anon 1908).
and the mixture stirred until a suitable consistency was
reached. Those recipes that involved the use of organic Choice of mountant—working properties
solvents were less likely to need heat. ‘A good mounting material is a blessing to photographers…’
(Anon 1879). Simpson (1861, p. 551) listed the necessary
Commercial products qualities of a mountant as ‘easy to prepare, easy to use,
Adhesive manufacturing was an identifiable industry in efficient when used, and free from deleterious effect upon
the 1800s, growing more robust with the approach of the photograph’. He also noted ‘curling and cockling’
the 20th century. A variety of commercial mountants as factors in adhesive choice. Individual photographers
were available. Photographic journals contain would have had their preferences for particular adhesives;
advertisements and recommendations for various some preferred patent or commercially available mixtures,
tradenames, including Higgins’ Photo-Mountant (Anon others preferred to prepare their own recipes.
1895a; Anon 1895b), Messrs. Houghton’s “Excelsior” Working properties would have been one of the first
(Anon 1892a), Fallowfield’s starch-based P.O.P. considerations of the photographer. Animal glue, rubber,
Mountant (Anon 1893b), Le Page’s Liquid Glue (SB starch and gum adhesives required different preparation
1896a) and Le Page’s clarified fish glue (Wall 1896a), methods and varied in working qualities such as tack,
Seccotine (Anon 1906a) and Glucine (APT 1896). viscosity and drying time. However, it would appear
Examples of these products can be seen in Figures 1-5. that photographers had divergent opinions on which
The composition of such commercial preparations adhesive best fulfilled these qualities. For example, one
is difficult to determine. Le Page products were correspondent preferred gelatine mountants to starch,
often advertised as being based on fish glue, at least finding starch ‘messy’ (Hypop 1896a) whereas another
until synthetic materials became available later in the preferred starch ‘as it can be used with greater facility
twentieth century. A number of patents for Higgins’ and cleanliness than gum-arabic…’ (Simpson 1861, p.
adhesive preparations detail various methods of 551). Others found gelatine too viscous to apply easily,
preparing starch, flour and dextrin, usually with the and the need for heat to keep gelatine liquid was often
addition of alkaline substances such as borax and seen as a disadvantage (Anon 1879).
sodium hydroxide, to act as a preservative and to Cockling was another factor that affected the choice
increase the viscosity and adhesiveness of the product of adhesive. Glue and starch adhesives both contained
(Higgins 1891, 1895, 1896a, 1896b, 1897, 1900). a comparatively large quantity of water, which led to
Editorials in photographic journals referred to the the cockling of the photograph or mount. For this
ready availability of gelatine, dextrin and starch- reason many photographers preferred to use ‘india-
based mountants (‘almost every dealer makes such a rubber’ or caoutchouc, mixed with benzole (benzene),
mountant’—Anon 1903), but do not go into specifics. mineral naphtha or another suitable solvent. Shellac in
Even when preparing their own adhesives, methylated spirits was also recommended by some for
photographers were wont to use commercial products: this reason (Anon 1892b; Bacharach 1892; Hardwich
‘Of the various kinds of paste, that made of starch is 1859, pp. 171–3). Others tried to use paste or glues
preferable…I prefer the patent starch, in powder, and that had cooled slightly or contained less water, to make
without the blue tint for my own use’ (Simpson 1861, them as ‘dry’ as possible (e.g. Anon 1891).
p. 551). Various brands of gelatine, glue and starch were Rubber went through periods of intense popularity
mentioned: Oswego’s starch (Anon 1892b), Glenfield’s as an adhesive, despite the cautions of some early
powdered starch (SB1896b) and Nelson’s sheet gelatine writers. Simpson (1861, p. 551) writes that ‘[it] is
(Hypop 1896a). scarcely suitable for general mounting purposes but is
Commercial ‘dry mount’ tissues for heat-set invaluable for fixing prints in albums or scrapbooks.
application were also marketed and mentioned in A slight touch of the paste at each corner attaches
photographic journals—products such as Kodak’s Dry the print to its place in the scrap-book, and keeps it
Mounting Tissue (Anon 1906b). The composition perfectly flat, without the slightest contraction, or
of these products is also unclear, although Watkins’ cockling.’ Some objected to its smell, but otherwise

7
barrier layers (Blanchard
1867; Robinson 1867).
Such barrier layers will
have reacted with both
the adhesive and the
photograph on ageing,
most likely contributing
to greater insolubility
of the adhesive and
staining or fading of the
photograph.
However, as one
correspondent writes, ‘You
do not always want the
same kind of mounting
material’ (Anon 1879).
The appropriateness of
a particular adhesive for
the type of print to be
mounted was considered.
‘If it is a thin delicate
sheet to be mounted,
no one would think of
taking thick hot glue,
nor when a stiff carbon
impression is to be fixed
is he likely to employ
gum water” (Simpson
1861, p. 551). Starch
and dextrine appeared to
be common choices for
thin materials, such as
albumen photographs (e.g. Anon 1879), whereas glue
were ‘not aware of any chemical objection to its use’ was preferred for ‘papers of greater area and substance,
(Martin 1862). In 1867 GH Egerton (1867) wrote such as enlargements on bromide paper’ (Anon 1892b).
in to The British Journal of Photography to tell of ‘dirty One author recommended a mixture of gum and glue
brown that penetrated the paper’. However, during for ‘stubborn prints which want a good deal of cement
1867, extensive correspondence about a “new” method upon them’ (Anon 1879).
of utilising rubber as an adhesive appeared in the pages Mountant choice also appears to have changed
of the Journal. The method involved applying a solution with the introduction of new photographic methods.
of rubber in benzole to both surfaces, mount and print, Gelatine and collodion coated papers were found to
and allowing them to dry. The two surfaces then only be easily abraded while damp, and so photographers
required pressure to join them—effectively, an early avoided ‘wet’ adhesives like starch paste and tried ‘drier’
pressure-sensitive adhesive system. The cleanliness of adhesives, such as the tackier animal glues and various
the process and the absence of cockling were seen as ready-made mountants, such as Houghton’s “Excelsior”
definite advantages, as were its perceived preservative (Anon 1892b; Anon 1892a). One author recommended
effects against damp and pollutants, prompting the using gelatine mixed with methylated spirits for
editor of the Journal to write ‘the death-blow has been mounting bromide paper as it avoided wetting the
given to dextrine, starch, gum…as mountants’ (Anon surface (Hypop 1896b).
1867). The tendency of rubber to oxidise and cause Occasionally, reversibility was a valued characteristic.
staining was apparently as yet unrecognised; some Gelatine was preferred by at least one journal
photographers even recommended using rubber as a correspondent because ‘…if any of the mountant gets on
barrier layer between the print and other adhesives the surface it can be easily got off with a handkerchief
used. Plant resins and collodion were also employed as dipped in water. The print, too, can be easily got off

8
the mount by placing blotting-paper over the print layer may subsequently affect the deterioration of the
and soaking it with warm water, or by sponging it over photograph and/or react with the adhesive, resulting in
with water’ (Hypop 1896a). Rubber-based adhesives discolouration of the support and/or image fading.
were less easy to remove: ‘the only thing to do is to split Surprisingly, to the modern photograph conservator,
the mount with a knife till there is only a thin film of it seems rare that mounted prints were dried under
card left on the print, and then to soak it in mineral weight: ‘In some extreme cases it will be found necessary
naphtha or bisulphide of carbon. The smell of this is so to dry the prints between towels under pressure of a pile
unpleasant that it is better, after splitting off the card, of books or a letter press, to prevent the curling up of
to rub the rest down with a bit of cuttlefish or pumice- the edges’ (Anon 1892c); ‘…never mind about bumps,
stone or blunt knife’ (Wall 1896b). they disappear as it dries, and place on one side in not
too warm a place to dry’ (Erudio 1896).
Mounting equipment and methods However, curling and warping was a problem for
There is a marked consistency within early instructions some and was the topic of much correspondence
for mounting photographs. Prints were nearly to photographic journals. It was known that many
always adhered to their mounts when dampened or adhesives contracted on drying, and that adhesives
wet—if not straight from the wash bath, then they containing water were more likely to cause cockling of
were re-dampened using sponges or sheets of damp papers and boards. The methods used to counteract
linen or a handkerchief, or placed again in a bath of this phenomenon varied. Some simply used non-
water—‘they will then lie perfectly flat, and cause no aqueous adhesives, such as rubber and shellac, or tried
difficulty’ (Simpson 1861, p. 551). Excess moisture was to minimise the amount of water in their adhesive
removed from the print, using either a rubber “squeegee” formulation. Others advocated bending the mounted
(obtained from a glazier) and rubbed over the print with prints while they dried, to counteract the force of the
a sheet of waxed paper or rubber cloth in between, or drying adhesive: ‘…either bend the mount and print into
pressed with the fingers through a thin linen or calico. an arc of a circle, with the print outside, and keep in this
(Blotting paper was not recommended, as it could leave position by strings till dry, or else paste a piece of paper
fluff on the print). a little larger than the print on the back of the mount’
The item was pasted out ‘…with a wide, flat brush, in (Wall 1896e).
a thin, even coating, taking care that no lumps are left on Others pre-pasted their prints, allowing them to dry
the print before applying it to the mount, and that the fully before mounting, and re-dampened the prints by
edges and corners are well covered…’, usually on a sheet placing them between sheets of damp blotter or with a
of glass, but sometimes on zinc or ebonite. The print sponge (Towler 1864: Ch XXXII). Mr Stuart’s method
was pasted from the centre outwards, ‘on no account… of mounting was referred to in journals with reasonable
from end to end’ (FHK 1896). A knife blade was frequency. Stuart’s method involved pre-pasting the
used to lift the photograph, which was then carefully prints with starch, allowing them to dry, dampening
placed on the mount, and the whole was pressed the mounts and placing the pre-pasted photographs on
with the fingers or squeegeed into place, again with a top, and then running the prints and mounts through
layer of cloth in between. Sometimes mounted prints a lithographic press. Journals reported that he was able
were placed between the covers of a book and rubbed to mount 3,000 items in 15 hours by this method.
vigorously. Excess paste was removed with a clean cloth, Amateur correspondents noted that Mr Stuart’s method
though warnings were made not to get any on the front would have gained almost universal use if a press had
of the photograph if one could help it (see Anon 1892c; not been required (Anon 1863a).
SB 1896b; Erudio 1896; FHK 1896; Hunger 1896; Commercial enterprises were more likely to use
Anon 1896a; Wall 1896a; Wall 1896d; A.G.J. 1896; equipment to speed up the mounting process. It is
Hardwich 1859, pp. 171–3). more difficult to trace popular commercial practice, as
Some authors recommended soaking the prints in a there were fewer published records of this nature. The
solution of alum prior to mounting, to harden them and patent record can be of some assistance. Patents exist
make them less susceptible to damage (Hunger 1896), for improved machinery for mounting large numbers of
even going so far as to say that this step ‘never should mounts quickly (Studds 1893; Dorticus 1895; Hoddle
be omitted’ (A.G.J 1896). Others first varnished the 1895) or outline designs for pre-gummed photographic
backs of their prints with a solution of gutta percha, mounts (Delépine 1896; McCabe 1896; Radford 1898).
rubber, collodion or plant resin as a protective barrier Other patents outline patterns for gummed photo-
layer between the print and the adhesive, ‘whereby corners (Lake 1893) or methods of drying mounted
the decomposition of the gum or paste is not liable photographs without curvature (Renard 1895). Patent
to affect the photograph’ (Dunelm 1857). Such a records from this time also reveal a tendency to ‘pre-glue’

9
photographic mounts, so that the process of mounting nature, high moisture content, or an inclination
could become quicker. to discolour (e.g. rubber, animal glue) may have
Equipment such as the ‘Zenith Mounter’ perhaps fell contributed to image fading and/or discolouration of
in between the needs of the commercial and amateur the support. Many of the adhesives may now prove
practitioner; certainly it seems to have been aimed intractable during conservation treatment, due to their
more at the amateur market, as advertisements were inherent non-aqueous nature (rubber) or due to contact
placed in amateur journals. Essentially, the Zenith with various waterproofing agents, such as alum. These
Mounter consisted of a board to which the mount and agents may have been added to the adhesive itself, or
photograph could be clipped, and an attached roller applied to the photograph in a wash solution, as part
lowered and rolled over the print to ensure contact, one of the mounting process. Other components of the
end at a time, without risk of movement during the adhesive may have reacted with each other to bring
process (Anon 1896b). It is difficult to imagine that about decreased solubility, such as the combination of
it saved a great deal of time, as mounts still had to be starch and gelatine.
mounted one at a time in a relatively labour-intensive For those who conquered the challenges of mounting
manner. Similar machines were made by the Messrs photographs, success proved to be a rewarding
Bullock Brothers, of Leamington (Anon 1863b) and Mr experience: ‘Mounting is now a pleasure to me, and if
Solomon of Red Lion Square (Anon 1865). any of your readers who are in difficulties follow the
After mounting and drying, the photographs may have plan that I have, they will soon derive as much pleasure
been put through rolling machines or burnishers, to impart from mounting as developing…’ (SB 1896b). There is
a smooth surface to the print (Burgess 1862, p. 22) no doubt that poor quality adhesives and mount boards
Alternatively, unmounted prints were often passed have taken their toll on many early photographic prints;
beneath the rollers of a glazing or ‘planishing’ machine however, the well-mounted print does indeed remain a
in order to perform two operations in one step— pleasure to all.
mounting the print to the cardboard backing and
providing a more pleasing surface to the photograph Author biography
(Towler 1864: Ch XXXII). Alice Cannon trained in paper conservation at the
University of Canberra, Australia, 1992-1994. She
Conclusions has since completed a postgraduate certificate in
Mounting photographs was evidentially a topic of photographic conservation and a Master of Arts by
great concern for the nineteenth and early twentieth- Research, both at the University of Melbourne. The title
century photographer. If not performed successfully, of her Masters thesis was Adhesives for paper, 1870–
mounting could ruin the results of many hours of 1920: Recipes and proprietary products. She currently
labour. Thus, photographers debated the advantages and works as a paper and photograph conservator at the
disadvantages of various adhesives, with respect to issues State Library of Victoria, Melbourne, Australia.
of permanence, working qualities and drying properties.
The conservator faced with mounted photographs References
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