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Drag Reduction of Iraqi Crude Oil Flow In Pipelines by Polymeric Additives

Article · December 2018

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Farhan Lafta Auda Braihi


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International Journal of Mechanical Engineering and Technology (IJMET)
(IJM
Volume 9, Issue 13, December 2018,
201 pp. 1049–1060, Article ID: IJMET_09_13_110
110
Available online at http://www.iaeme.com/ijmet/issues.asp?JType=IJMET&VType=9&IType=13
ISSN Print: 0976-6340 and ISSN Online: 0976-6359

© IAEME Publication Scopus Indexed

DRAG REDUCTION OF IRAQI


IRAQI CRUDE OIL
FLOW IN PIPELINES
PIPELINES BY POLYMERIC
ADDITIVES
Farhan Lafta Rashid
University of Kerbala, Petroleum Eng. Dept.

Akram Jassim Jawad, Auda J.Braihi


Unviersity of Babylon, Faculty of Materials Engineering,
Polymers and
an Petrochemical Industries Dept

Ahmed Hashim
University of Babylon

ABSTRACT
In this work, a Drag Reducing Agent
Agent (DRA) has been employed to reduce the drag
of Iraqi crude oil using Poly Vinyl Pyridine (PVP) at different concentrations (0, 500,
750, 1000, 1250 and 1500 ppm). Results show that a significant decrease in flow index
values has been achieved at a concentration
concen range of (750-1500
1500 ppm) in which the
lowest value is obtained at a PVP concentration of 1000 ppm. This has been clarified
by obtaining flow indexes of less than unity indicating the sample shear thinning.
Thus, using a DRA concentration of 1500 ppm decreases the pressure drop by 35.7 %
for a pipeline capacity, pipe diameter and length of 0.02 m3/s, 0.0508 m and 10 m,
respectively. In addition, a maximum drag reduction of 35.1 % has been achieved at
the highest concentration (1500 ppm). Therefore, the
the DRA addition saves the pumping
power and increases the produced flow by 35.1 % and 27.5 %, respectively.
Keywords: Drag reduction, polymeric additive, rheological characterization,
characterization pumping
power.

Cite this Article: Farhan Lafta Rashid, Auda J.Braihi, Ahmed Hashim, Akram Jassim
Jawad, Drag Reduction of Iraqi Crude Oil Flow In Pipelines by Polymeric,
Polymeric
International
ernational Journal of Mechanical Engineering and Technology,, 9(13), 2018, pp.
1049-1060.
http://www.iaeme.com/ijmet/issues.asp?JType=IJMET&VType=9&IType=13

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IJMET/index.asp 1049 editor@iaeme.com
Drag Reduction of Iraqi Crude Oil Flow In Pipelines by Polymeric

INTRODUCTION
Flowing liquids in pipelines can be occupied by high friction losses, especially in the case of
turbulent flow. Therefore, drag reduction is essential to reduce these losses using a small
quantity of additives (DRA). This would be crucial in many applications to reduce the
required pumping energy (head of the pump). So, a drag reducing agent is added to crude oil
transmission pipelines to achieve this goal [1, 2]. This can provide several benefits in pipeline
systems such as saving pumping power, reducing consumption of energy, enhancing flow rate
and decreasing pump sizes [3].
The drag reduction phenomenon was firstly observed by Mysels [4-6]. Mysels compared
the pressure of gasoline and gasoline thickened with aluminum di-soaps flow through the
same pipe. In 1948, Toms [7] also observed the drag reduction phenomenon, while he was
investigating a polymer degradation. He discovered that the use of polyxdcc methyl
methacrylate in mono-chlorobenzene causes a decrement in the turbulent skin friction drag up
to 80 %. It is also found that the flow rate could be raised due to the addition of the tasted
polymer at a constant pressure gradient.
Wang et al. [8] carried out a direct simulation of numerical study using a model of spring-
dumbbell to examine the inhomogeneous phenomena of polymer molecules during drag
reducing in a flow channel using polymer additives. Results show that the concentration of
polymer additives and elongation in buffer layer are highest, and most molecules of polymer
are parallel to the direction of streamwise and vertical to the direction of spanwise. Because of
the elastic effect of polymer, the balance of turbulent kinetic energy varies dramatically.
Hassanean et al [9] studied the effect of a DRA on the flow lines of crude oil production
in the Egyptian western desert. The DRA used in their study is poly alpha olefin of a high
molecular weight. The obtained results showed that this DRA has a significant effect on the
pressure drop and fanning friction factor. Thus, the pressure drop is decreased by 36% at a
pipeline capacity of 18,804 bbl./day when a 60 ppm of the DRA is added. So, the fanning
friction factor and shear stress are decreased by 47%.
Niccolo et al. [10] investigated three types of poly(acrylamide-co-NaAMPS) and pure
PHPAAm as polymers induced a drag reduction and a mechanical polymer degradation in 1"
horizontal bore circular cross-section pipe. It is found that the existence of NaAMPS groups
can increase the ability of PHPAAm to reduce the frictional drag while the sensitivity to
mechanical degradation remains unchanged.
DeGroot et al. [11] conducted a Computational Fluid Dynamics (CFD) simulation using
k–ω shear-stress transport (SST) as a turbulence model to simulate the effect of a macroscale
surface modification in terms of longitudinal grooves shape on the drag reduction in laminar
and turbulent channel flows. Results show that the approximate drag reduction can be
specified by evaluating the geometry drag reduction employing the first Fourier model of a
grooved geometry.
Jacob and Mei [12] performed a numerical study to simulate the drag coefficient and
vortex shedding for a two-dimensional bluff body and a Reynolds number range of (1-4x106).
They reported that the drag coefficient is reduced by 75% at maximum actuators power input.
So, an increase in Strouhal number for each successive increase in actuator power is observed.
The objective of the present work is to investigate the effectiveness (%DR) of drag
reducing agent (PVP) on drag reduction of Iraqi crude oil. This can be accomplished by
studying the effect of different additive concentrations on Rheological characterization,
pressure drop (or head loss), pumping power saving and flow increase.

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Farhan Lafta Rashid, Auda J.Braihi, Ahmed Hashim, Akram Jassim Jawad

EXPERIMENTAL PART
LIQUID
Iraqi crude oil was used in this test as a flowing liquid which is supplied from Al-Najaf
refinery–Iraq. The physical properties of the crude oil at 25 oC are: viscosity =27.5 cp,
specific gravity =0.885, and API=32.36.

DRAG REDUCING AGENT


Poly vinyl pyridine is soluble in polar solvents such as water. It is also soluble in various
alcohols, such as ethanol and methanol as well as in more exotic solvents such as the heavy
eutectic solvent created by choline chloride and urea. So, it has prime wetting properties and
can form films [13, 14]. In the present work, poly vinyl pyridine is used at different
concentrations 500, 750, 1000, 1250 and 1500 ppm.

DESCRIPTION OF CIRCULATING FLOW LOOP SYSTEM


The test rig used in present work consists of a crude oil reservoir of dimensions (0.75 x 0.75 x
0.75 m) and a pump (flow rate =30 L/min., maximum head=30 m, maximum power =0.74
hp). This pump is used to circulate the treated crude oil from the reservoir through the pipe. A
flow meter is also used to measure the flow rate (flow rate=8 m3/h) of the treated crude oil
through the system. Tow pressure gauges are fixed at two different point on the pipe to
measure the pressure drop. A stainless-steel pipe of 10 m in length and inside diameter of
0.0508 m is used. A schematic diagram of the test rig is shown in Fig. (1). In addition, a
viscometer and density tester are used to measure the viscosity and density of the crude oil as
shown in Fig. (2) and Fig. (3), respectively. After the experimental apparatus is built, the
crude oil treated with different PVP concentrations is circulated through the flow loop system
to measure different affecting parameters.

RESULTS AND DISCUSION


In this work, equations (1-4) are used to predict the flow Reynolds number (Re), percentage
of the flow increase (%FI), percentage of the drag reduction (%DR), and Darcy friction factor,
respectively [15, 16]:

= (1)

1
% = . −1 100 (2)
%
1−

∆ −∆
% = (3)
!

2 ∆
#= (4)
$ %

Δ b and Δ a are the pressure drop before and after the DRA is added, respectively and $ is the
where v is the linear velocity, is fluid density, is dynamic viscosity, is pipe diameter,

pipe length.

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Drag Reduction of Iraqi Crude Oil Flow In Pipelines by Polymeric

RHEOLOGICAL CHARACTERIZATION
PVP polymer is added to the crude oil as a drag reducer at different concentration (0, 500,
750, 1000, 1250 and 1500) to investigate their effect on the flow characteristics of the Iraqi
crude oil. Fig. (4) shows that the density of the crude oil increases as the concentration of the
PVP increases. On the other hand, the viscosity
Relationship between shear stress and shear rate of the crude oil treated with different
concentrations of the DRA (0, 500, 750, 1000, 1250 and 1500 ppm) is illustrated in Fig.6. It is
observed that at concentration of 0 ppm (pure crude oil), almost a linear increase in the shear
stress is shown with the shear rate. This concentration exhibits the highest values of the shear
stress at all values of the shear rate compared with other concentrations. In addition, a
considerable decrease in the shear stress is obtain by adding the DRA to the crude oil. This
reduction varies as the concentration of the DRA varies and the highest decrease (lowest shear
stress) is observed at a concentration of 1500 ppm. It is also observed that the shear stress at a
concentration of 750 ppm is higher than that at 500 ppm.
Figure (7) shows the viscosity–shear rate relationship for the tested crude oil treated with
different concentrations (0, 500, 750, 1000, 1250 and 1500 ppm) of the DRA (PVP) at a
constant temperature of 25 oC. From this figure, it is shown that adding the DRA reduces
significantly the viscosity of the crude oil and the reduction depends on the DRA
concentration in the crude oil. Consequently, the lowest and highest reduction is obtained at
750 and 1500 ppm, respectively. This means that the influence of the tested DRA in reducing
the pipeline pressure drop is not attributed to its effect on viscosity but it is attributed mainly
to its effect of reducing the degree of turbulence energy inside the pipeline network, thereby
reducing gradually the shear stress which is clearly presented in figure (8).

CONSISTENCY INDEX AND FLOW INDEX


The Power law model can be used to describe any material behavior that obeys the power law.
In this model, if the power law index (flow index) is greater than unity (n>1), this means that
the sample is shear thickening, n<1 denotes that the sample is shear thinning and n=1 shows a
Newtonian, viscous behavior. This would normally be apply on the data that show
monotonically shear thinning behavior, rather than on the data areas that show plateaus, i.e.
the zero shear and infinite shear viscosities. After the log shear stress versus log shear rate is
plotted for the obtained experimental data, the power law trend line is fitted to obtain a
formula representing the data. The model is:
Shear stress = KDn
Where K = consistency index, D=shear rate, and n = power law exponent (flow index)
Figures (9, 10, 11, 12, 13 and14) present the shear stress vs shear rate with different PVP
additive concentrations (0, 500, 750, 1000, 1250 and 1500 ppm), respectively. For all these
figures, the flow indexes are less than unity which means that the sample is shear thinning and
the values of flow index are clearly decreased by adding the PVP at concentration of (750 to
1500 ppm). In addition, the minimum value of the flow index is obtained at a PVP
concentration of (1000 ppm).

CRUDE OIL FLOW CHARACTERSTICS


Figure (15) shows variation of pressure drop with different concentrations of the PVP. It is
shown that the pressure drop decreases with increasing the PVP concentration. This is
because that the addition of DRA (PVP) reduces the viscosity and therefore the Reynolds
number will increase which leads to decrease the friction factor, thereby the pressure drop
decreases. Accordingly, the head loss decreases as shown in figure (16).

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Farhan
han Lafta Rashid, Auda J.Braihi, Ahmed Hashim, Akram Jassim Jawad

Figure (17) manifests the PVP concentration effect on the process of drag reduction. This
figure shows that the %DR increases with increasing
increasing the PVP concentration. The increment in
%DR is regarded to the increase in the associated additive molecules in the drag reduction
process. A maximum drag reduction of 35.1% is achieved at the largest concentration (1500
ppm). Therefore, the DRA addition increases the saving in pumping power as shown in figure
(18).
Another benefit of the DRA addition is increasing the flow as shown in figure (19). the
maximum flow increase is found to be 27.5 % which is obtained at PVP concentration of
(1500 ppm).

Fig
Figure (1): Circulating flow loop system

Figure (2): Viscometer cone-plate

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Drag Reduction of Iraqi Crude Oil Flow In Pipelines by Polymeric

Figure (3) Density tester decreases with increasing of the concentration as shown in Fig. (5).

Figure (4): Variation of crude oil density with PVP concentration

Figure (5): Variation of crude oil dynamic viscosity with PVP concentration

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Farhan Lafta Rashid, Auda J.Braihi, Ahmed Hashim, Akram Jassim Jawad

Figure (6): Shear stress-shear rate variation for the tested crude oil treated with different
concentrations (0, 500, 750, 1000, 1250 and 1500 ppm) of the PVP

Figure (7): Viscosity-shear rate variation for the tested crude oil treated with different concentrations
(0, 500, 750, 1000, 1250 and 1500 ppm) of the PVP

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Drag Reduction of Iraqi Crude Oil Flow In Pipelines by Polymeric

Figure (8): Shear stress-viscosity variation for the tested crude oil treated with different
concentrations (0, 500, 750, 1000, 1250 and 1500 ppm) of the PVP

Figure (9): Analysis plot power law for pure crude oil (0 ppm PVP)

Figure (10): Analysis plot power law for crude oil with addition of (500 ppm PVP)

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Farhan Lafta Rashid, Auda J.Braihi, Ahmed Hashim, Akram Jassim Jawad

Figure (11): Analysis plot power law for crude oil with addition of (750 ppm PVP)

Figure (12): Analysis plot power law for crude oil with addition of (1000 ppm PVP)

Figure (13): Analysis plot power law for crude oil with addition of (1250 ppm PVP)

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Drag Reduction of Iraqi Crude Oil Flow In Pipelines by Polymeric

Figure (14): Analysis plot power law for crude oil with addition of (1500 ppm PVP)

Figure (15): Variation of pressure drop with different concentrations of PVP

Figure (16): Variation of head loss with different concentrations of PVP

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Farhan Lafta Rashid, Auda J.Braihi, Ahmed Hashim, Akram Jassim Jawad

Figure (17): Variation of the drag reduction (%) with different concentrations of PVP

Figure (18): Variation of the pumping power with different concentrations of PVP

Figure (19): Variation of the flow increase (%) with different concentrations of PVP

CONCLUSIONS
The drag reduction effect is very important in many applications such as petroleum flow in pipeline
systems. The drag reduction behavior of PVP has been studied. It is concluded that adding a small
amount of PVP concentration can provide a significant impact on the characteristics of the fluid flow
in the turbulent flow. So, it is proven that the PVP is an effective drag reducing agent in the fluid
turbulent flow, especially, at relatively high concentration of the PVP. The percentage of the drag

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Drag Reduction of Iraqi Crude Oil Flow In Pipelines by Polymeric

reduction also increases due to the reduction of the crude oil viscosity. Besides that, pressure drop (or
head loss) also decreases as the PVP concentration increases. Accordingly, the pumping power and the
flow can be optimized. Thus, the PVP additive is found to be an efficient drag reducing agent for the
Iraqi crude oil.

ACKNOWLEDGMENT
We would like to express our deep thanks and respect to all members of (Faculty of Materials
Engineering, Polymers and Petrochemical Industries Department) for their cooperation.

REFERENCES
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Heat and Mass Transfer 51(2), pp. 835-843.
[3] Lixin, C., Dieter, M., Andrea, L., 2007, “Boiling Phenomena with Surfactants and
Polymeric Additives: A State-Of-The-Art Review,” International Journal of Heat and
Mass Transfer 50(1), pp. 2744-2771.
[4] Mysels, K., 1971, "Early experiences with viscous drag reduction," Chem. Eng. Prog.
Symp. Seri., 67(111), pp.45-49.
[5] Mysels, K., 1949, “U.S. Pat.,” 2(492), pp.173-179.
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J.,1954, "Flow of gasoline thickened by napalm," Ind. Eng. Chem.,46, pp. l0l7-1019.
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[8] Wang, Y., Yu , B., Xuan, W., Peng, W., 2012, “POD and wavelet analyses on the flow
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[9] Hassanean, M., Awad, M., Marwan, Bhran, A., 2016, “Studying the rheological
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[10] Niccolo, L., Brun, I., Zadrazil, L., Norman, Alexander, B., Christos, N., 2016, “On the
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hydraulic fracturing,” Chemical Engineering Science, 146(2), pp. 135–143.
[11] DeGroot, C., Wang, C., Floryan, J., 2016, “Drag Reduction Due to Streamwise Grooves in
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[12] Jacob, T., Mei, Z., 2016, “Active Flow Control Schemes for Bluff Body Drag Reduction,”
ASME Proceedings, 11th Symposium on Active Fluid Dynamics and Flow Control
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[13] Wohlfarth, C., 2010, "Thermodynamic Properties of Polymer Solutions," Landolt-
Bornstein, New Series, Group VIII,6, Springer.
[14] Sapir, L., Stanley, C., Harries, D., 2016, "Properties of Polyvinyl pyrrolidone in a Deep
Eutectic Solvent," J. Phys. Chem. A., 120, pp.3253–3259.
[15] Darby, R., 2001, “Engineering Fluid Mechanics,” Marcel Dekker, New York, NY, USA,
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[16] Holland, F., Bragg, R., 1995 “Fluid Flow for Chemical Engineers,” Edward Arnold,
London, UK, 2nd edition.

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