Professional Documents
Culture Documents
TARGET: JEE (Main + Advanced) 2022 Course: VIKAAS (JA) NO. C1
TARGET: JEE (Main + Advanced) 2022 Course: VIKAAS (JA) NO. C1
P - C H E M I S T RY
EST INFORM AT IO
DPP
DAILY PRACTICE PROBLEMS
ANSWER KEY
1. (C) 2. (A) 3. (D) 4. (C) 5. (A) 6. (C) 7. (D)
8. (D) 9. (A) 10. (ABD) 11. (ACD)
12. State function : a, b, c, d, g, h, j ; Path function : e, f, i, k
13. Intensive : a, c, d, f, g, h, i, k ; Extensive : b, e, j, l
14. Open system : b, f, g, i, j ; Closed system : a, c, h ; Isolated system : d, e
1. In thermodynamics, a process is called reversible when :
(A) surrounding and system change into each other.
(B) there is no real boundary between system and surrounding.
(C*) the surrounding is always in equilibrium with the system.
(D) the system changes into the surrounding spontaneously.
Å"ekxfrdh esa] ,d çØe mÙØe.kh; dgykrk gS] tc %
(A) ifjos'k rFkk fudk;] ,d nwljs esa ifjofrZr gksaA
(B) ifjos'k rFkk fudk; ds e/; dksbZ okLrfod ifjlhek ugha gksA
(C*) ifjos'k lnSo] fudk; ds lkFk lkE; esa jgsA
(D) fudk;] ifjos'k esa Lor% ifjofrZr gksA
2. A thermodynamic system goes in cyclic reversible process as represented in the following P–V
diagram:
,d Å"ekxfrdh ra=k] uhps n'kkZ;s P–V vkjs[k ds vuqlkj] ,d pfØ; mRØe.kh; izØe esa Hkkx ysrk gS %
The net work done during the complete cycle is given by the area :
pØ iw.kZ djus ds nkSjku fd;k x;k ifj.kkeh dk;Z] fuEu {ks=k }kjk fn;k tkrk gS %
(A*) cycle ACBDA (B) AA1B1BDA (C) AA2B2B (D) AA1B1BCA
(A*) pØ ACBDA (B) AA1B1BDA (C) AA2B2B (D) AA1B1BCA
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.-1
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
DPPs BOOKLET-3 VIKAAS (JA) | CHEMISTRY
3. Which of the following are not state functions?
(I) E (II) q (III) W (IV) G
(A) (I)and (IV) (B) (II) (III) and (IV) (C) (I), (II)and (III) (D*) (II) and (III)
fuEu esa ls voLFkkQyu dkSulk ugha gS ?
(I) E (II) q (III) W (IV) G
(A) (I)vkSj (IV) (B) (II) (III) vkSj (IV) (C) (I), (II)vkSj (III) (D*) (II) vkSj (III)
Sol. q, w are at path functions. q, w iFk Qyu ij gSA
4. A well stoppered thermoflask contains some ice cubes. For small time duration, this is an example of a-
,d vPNh rjg cUn FkeZl ¶ykLd esa dqN cQZ ds VqdM+s gSaA de le; vUrjky ds fy;s ;g ......... mnkgj.k gS&
(A) Closed system (B) Open system (C*) Isolated system (D)Non-thermodynamic
system
(A) cUn fudk; dk (B) [kqys fudk; dk (C*) foyfxr fudk; dk (D) ukWu&Å"ekxfrdh; fudk; dk
5. When ammonium chloride is dissolved in water, the solution becomes cold. The dissolution process is -
tc veksfu;e DyksjkbM dks ty esa feyk;k tkrk gS] rks foy;u B.Mk gks tkrk gSA ?kqyus dk izØe gS –
(A*) Endothermic (B) Exothermic (C) Supercooling (D) None of the above
(A*) Å"ek'kks"kh (B) Å"ek{ksih (C) vfr'khru (D) buesa ls dksbZ ugha
9. Among the following, the respective number of closed, open and isolated systems is:
(a) Boiler (b) coolant system in a nuclear reactor
(c) Thermos flask (d) Universe
(e) Living things (f) Human body
(g) A cup of tea (h) A closely packed room in which a split air-conditioner is working.
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.-2
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
DPPs BOOKLET-3 VIKAAS (JA) | CHEMISTRY
fuEu esa ls can] [kqys] rFkk foyfxr fudk;ksa dh Øe'k% la[;k D;k&D;k gS %
(a) ckW;yj (b) 'khryu fudk; ¼ra=k½ esa ukfHkdh; izfrdkjh (nuclear reactor)
(c) rkiLFkk;h ik=k (d) czãk.M
(e) thfor çk.kh (f) ekuo 'kjhj
(g) ,d I;kyk pk; (h) ,d can dejk] ftlesa ijrh; ok;q ç'khrd (split air-conditioner) dk;Z dj jgk gSA
(A*) 1, 5, 2 (B) 1, 6, 1 (C) 2, 4, 2 (D) 2, 5, 1
14. Classify the following among closed, open and isolated system :
(a) Pressure cooker (b) Boiler
(c) Liquid cooling system of an automobile (d) Thermos flask
(e) Universe (f) Living things
(g) Human body (h) Electrochemical cells
(i) A cup of tea
(j) A closely packed room in which a split air-conditioner is working.
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.-3
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
DPPs BOOKLET-3 VIKAAS (JA) | CHEMISTRY
fuEu dks can] [kqys] rFkk foyfxr fudk;ksa esa oxhZd`r dhft;s %
(a) çs'kj dqdj (b) ckW;yj
(c) ,d Lopfyr okgu dk nzo 'khryu fudk; ¼ra=k½ (d) rkiLFkk;h ik=k
(e) czãk.M (f) thfor çk.kh
(g) ekuo 'kjhj (h) fo|qr jklk;fud lsy
(i) ,d I;kyk pk;
(j) ,d can dejk] ftlesa ijrh; ok;q ç'khrd (split air-conditioner) dk;Z dj jgk gSA
Sol. Open system : b, f, g, i, j ; Closed system : a, c, h ; Isolated system : d, e
Sol. [kqyh fudk; : b, f, g, i, j ; cUn fudk; : a, c, h ; i`Fkd fudk; : d, e
P - C H E M I S T RY
EST INFORM AT IO
DPP
DAILY PRACTICE PROBLEMS
ANSWER KEY
1. (B) 2. (D) 3. (B) 4. (A) 5. (D) 6. (C) 7. (A)
8. (D) 9. (A) 10. (A) 11. (B) 12. (D) 13.* (BC) 14.* (BD)
15. 80 J, –90 J 16. 6 kJ 17. 0 18. (Ap, s); (Bp,r,s) ; (C q); (D p, r, s)
1. The work done during the expansion of a gas from a volume of 4 dm 3 to 6 dm3 against a constant
external pressure of 3 atm, is :
(A) – 6 J (B*) – 608 J (C) + 304 J (D) – 304 J
fdlh xSl ds 4 Mseh3 vk;ru ds 6 Mseh3 vk;ru esa izlkj ds nkSjku 3 ok;qe.Myh; cká nkc ds fo:) fd;k x;k
dk;Z gksxk
(A) – 6 twy (B*) – 608 twy (C) + 304 twy (D) – 304 twy
Sol. Work done fd;k x;k dk;Z (W) = – Pext (V2 – V1)
= – 3 x (6 – 4) = – 6 L-atm
= – 6 x 101.32 J
( 1 L-atm = 101.32 J)
= – 607.92 608 J
2. Three moles of an ideal gas expanded spontaneously into vacuum. The work done will be:
(A) Infinite (B) 3 Joules (C) 9 Joules (D*) Zero
,d vkn'kZ xSl ds rhu eksy fuokZr esa Lor% izlkfjr gksrs gSaA fd;k x;k dk;Z fuEu gksxk %
(A) vuUr (B) 3 twy (C) 9 twy (D*) 'kwU;
Sol. Since the ideal gas expands spontaneously into vacuum, Pext = 0, hence work done is also zero.
gy pwafd fuokZr esa vkn'kZ xSl Lor% izlkfjr gksrh gS blfy, Pext = 0 vr% fd;k x;k dk;Z Hkh 'kwU; gksrk gSA
3. Which of the following is not a thermodynamic function ?
(A) Internal energy (B*) Work done (C) Enthalpy (D) Entropy
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.-4
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
DPPs BOOKLET-3 VIKAAS (JA) | CHEMISTRY
fuEu esa ls ,d Å"ekxfrdh; Qyu dkSulk ugha gS \
(A) vkUrfjd ÅtkZ (B*) fd;k x;k dk;Z (C) ,UFkSYih (D) ,UVªkWih
Sol. Thermodynamic functions are : Internal energy, enthalpy, entropy, pressure, volume, temperature, free
energy, number of moles.
Sol. Å"ekxfrdh; Qyu % vkUrfjd ÅtkZ] ,UFkSYih] ,UVªkWih] nkc] vk;ru] rkieku] eqDr ÅtkZ] eksyksa dh la[;k gksrs gSaA
4. For a reversible process, calculate magnitude of work done from the
following PV diagram :
(A*) 4
(B) 6
(C) 2
(D) 0
4. ,d mRØe.kh; çØe ds fy,] fuEu P-V vkjs[k ds vk/kkj ij] fd;s x;s
dk;Z ds ifjek.k dh x.kuk dhft;s %
(A*) 4
(B) 6
(C) 2
(D) 0
5. The internal energy change when a system goes from state A to B is 40 kJ/mol. If the system goes from
A to B by a reversible path and returns to state A by an irreversible path, what would be the net change
in internal energy ?
,d ra=k voLFkk A ls B esa tkrk gS rks vkUrfjd ÅtkZ ifjorZu 40 kJ/mol gSaA ;fn ra=k ,d mRØe.kh; iFk }kjk A
ls B dh vksj tkrk gS o ,d vuqRØe.kh; iFk }kjk voLFkk A dh vksj iqu% tkrk gS] rks vkUrfjd ÅtkZ esa dqy
ifjorZu D;k gS \
(A) 40 kJ (B) > 40 kJ (C) < 40 kJ (D*) Zero‘’¼'kwU;½
Sol. E = 0, in a cyclic process. (E = 0,,d pØh; izØe gSA)
6. In a system, a piston caused an expansion against an external pressure of 1.2 atm giving a change in
volume of 32 L for which E = –51 kJ. What was the value of heat involved : (Take 1 L atm = 100 J)
,d ra=k esa ,d fiLVu] 1.2 atm ds ckg~; nkc ds fo:) izlkfjr gksdj] vk;ru esa 32 L dk ifjorZu nsrk gS] ftlds
fy, E = –51 kJ gSA ifjorZu ds fy, Å"ek dk eku D;k gksxk % (yhft, 1 L atm = 100 J)
(A) –36 kJ (B) –13 kJ (C*) –47 kJ (D) 24 kJ
Sol. w = Pext V
w = – 1.2 × 32 = – 38.4 lt atm.
= – 38.4 × 100 J = – 3840 J = – 3.84 kJ
E = q + w
so, q = E – w = – 51 + 3.84 = – 47.16.
7. In a closed insulated container a liquid is stirred with a paddle to increase the temperature, which of the
following is true ?
,d Å"ekjks/kh ik=k esa rki c<+kus ds fy;s nzo dks isMy ls foMksfyr fd;k tkrk gSaA fuEu esa ls dkSu&lk lgh gSa %
(A*) E = W 0, q = 0 (B) E = W = 0, q 0
(C) E = 0, W = q 0 (D) W = 0, E = q 0
Sol. In closed insulated contianer a liquid is stirred with a paddle to increase the temprature, therefore No
heat exchange with surrounding, so for it q = 0.
Hence, from first law of thermodynamics
cUn dqpkyd ik=k esa ,d isaMy ds lkFk ,d nzo dks fgyk;k tkrk gS rkfd rkieku esa o`f) dh tk lds vr% ifjos'k
ds lkFk dksbZ Å"eh; fofues; ugha gksrk gSA q = 0.
vr% Å"ekxfrdh ds izFke fu;e ls
E = q + W
if ;fn, q = 0
E = W but not equal to zero.
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.-5
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
DPPs BOOKLET-3 VIKAAS (JA) | CHEMISTRY
E = W 'kwU; ds cjkcj ugha gSA
8. 2 mole of an ideal gas expands isothermally and reversibly from 1 L to 10 L at 300 K. What is the
internal energy change :
300 K ij ,d vkn'kZ xSl ds 2 eksy] 1 L ls 10 L rd lerkih; rFkk mRØe.kh; :i ls çlkfjr gksrs gSaA bl çØe esa
vkarfjd ÅtkZ ifjorZu D;k gS %
(A) 4.98 kJ (B) 11.47 kJ (C) –11.47 kJ (D*) 0 kJ
9. If 1 mole of an ideal gas expands isothermally at 37ºC from 15 litres to 25 litres, the maximum work
obtained is:
;fn 37ºC ij lerkih; :i ls ,d vkn'kZ xSl ds 1 eksy dks çlkfjr djus ij vk;ru 15 yhVj ls 25 yhVj gks
tkrk gS rks çkIr vf/kdre dk;Z fuEu gS %
(A*) 12.87 L atm (B) 6.43 L atm (C) 8.57 L atm (D) 2.92 L atm
V2 25
Sol. W max, iso = – 2.303 nRT log = – 2.303 × 1 × 0.0821 × 310 × log
V1 15
= – 58.61 × 0.22 = – 12.87 L atm
(–ve sign shows work of expansion i.e. work done by the system)
V
gy- W vf/kdre]lerkih; = – 2.303 nRT log 2
V1
25
= – 2.303 × 1 × 0.0821 × 310 × log
15
= – 58.61 × 0.22 = – 12.87 L atm
(–ve fpUg dk;Z çlkj dks n'kkZrk gS vFkkZr~ fudk; }kjk fd;k x;k dk;Z)
10. The q value and work done in isothermal reversible expansion of one mole of an ideal gas from initial
pressure of 1 bar to final pressure of 0.1 bar at constant temperature 273 K are:
1 eksy vkn'kZ xSl ds fy;s fu;r rki 273 K ij izkjfEHkd nkc 1 ckj ls vfUre nkc 0.1 ckj rd mRØe.kh;
lerkih; izlkj esa q dk eku rFkk fd;k x;k dk;Z fuEu gS %
(A*) 5.22 kJ, –5.22 kJ (B) –5.22 kJ, 5.22 kJ (C) 5.22 kJ, 5.22 kJ (D) –5.22 kJ, –5.22 kJ
11. Select the incorrect statement :
(A) A continuous curve can be plotted between thermodynamic parameters for a reversible process.
(B*) An irreversible process takes infinite time for completion.
(C) There is an infinitesimal difference between driving force and opposing force in a reversible
process.
(D) None of these
vlR; dFku dk p;u dhft;s :
(A) ,d mRØe.kh; izØe ds fy;s] Å"ekxfrdh; izkpyksa esa ,d lrr~ oØ cuk;k tk ldrk gSA
(B*) ,d vuqRØe.kh; izØe] iwjk gksus ds fy;s vuUr le; ysrk gSA
(C) ,d mRØe.kh; izØe esa] pykus okys cy o foijhr cy esa vuUr lw{e vUrj gksrk gSA
(D) buesa ls dksbZ ugha
12. Choose the incorrect statement :
(A) system and surrounding are always separated by a real or imaginary boundary.
(B) perfectly isolated system can never be created.
(C) in reversible process, energy change in each step can be reversed.
(D*) irreversible process is also called quasi-equilibrium state.
xyr dFku dk p;u dhft;s %
(A) fudk; rFkk ifjos'k ges'kk] okLrfod vFkok dkYifud ifjlhek }kjk i`Fkd jgrs gSaA
(B) iw.kZr% foyfxr fudk; dk fuekZ.k dHkh ugha fd;k tk ldrk gSA
(C) mÙØe.kh; çØe esa çR;sd in esa ÅtkZ ifjorZu] mÙØe.kh; gks ldrk gSA
(D*) vuqÙØe.kh; çØe dks Doklh lkE;okLFkk (quasi-equilibrium state) Hkh dgk tkrk gSA
13.* 1 mole of argon gas is expanded isothermally and reversibly from 10L to 100L. Which of the following
options is/are incorrect for the process :
(A) E = 0 (B*) W = 0 (C*) heat supplied (q) = 0(D) T = 0
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.-6
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
DPPs BOOKLET-3 VIKAAS (JA) | CHEMISTRY
1 eksy vkxZu xSl] 10 L ls 100 L rd lerkih; rFkk mRØe.kh; :i ls izlkfjr gksrh gSA izØe ds fy, fuEu esa ls
dkSulk@dkSuls fodYi xyr gS@gSa %
(A) E = 0 (B*) W = 0 (C*) nh xbZ Å"ek (q) = 0 (D) T = 0
14.* For isothermal expansion of an ideal gas sample, the correct relation(s) is/are : (Consider all quantities
with sign according to IUPAC convention and the reversible and irreversible processes are carried out
between same initial and final states.)
(A) W rev > W irrev (B*) W irrev > W rev (C) qrev < qirrev (D*) Erev = Eirrev
vkn'kZ xSl ds ,d uewus ds lerkih; izlkj ds lanHkZ esa lgh lEcU/k fuEu gS@gSa % ¼ IUPAC fu;eksa ds vuqlkj lHkh
inksa dks fpUg ds lkFk ysa rFkk mRØe.kh; o vuqRØe.kh; izØe] leku izkjfEHkd rFkk vfUre voLFkk ds e/; lEiUu
fd;s tkrs gSaA½
(A) W mRØe.kh; > W vuqRØe.kh; (B*) W vuqRØe.kh; > W mRØe.kh;
(C) qmRØe.kh; < qvuqRØe.kh; (D*) EmRØe.kh; = EvuqRØe.kh;
15. When a system is taken from state 'a' to state 'b' in fig. along path 'acb', 100 J
of heat flows into the system and the system does 40 J of work. How much
heat flows into the system along path 'aeb' if work done by the system is 20 J?
The system returns from 'b' to 'a' along path 'bda'. If the work done on the
system is 30 J, does the system absorb or liberate heat ? How much ?
Uba = – 60 J
W bda = 30 J
Uba = Qbda + W bda
or Qbda = Uba – W bda
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.-7
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
DPPs BOOKLET-3 VIKAAS (JA) | CHEMISTRY
Sol. q = E – W
1.2 75 100
= – 15 + = – 6 kJ
1000
17. A thermodynamic system undergoes cyclic process ABCDA as shown in figure. Calculate the value of
work done.
vkd`fr esa n'kkZ;s vuqlkj pØh; izØe ABCDA ij ls ,d Å"ekxfrdh; ra=k xqtjrk gSA fd;s x;s dk;Z dh x.kuk
dhft;s
P
C B
3P0
2P0 O
P0 A D
V
V0 2V0
Ans. 0
Sol. Work done by the gas = Work done on the gas = POVO / 2.
So, total work done = 0.
Sol. xSl }kjk fd;k x;k dk;Z = xSl ij fd;k x;k dk;Z = POVO / 2.
blfy,] fd;k x;k dqy dk;Z = 0.
18. Match the column :
Column I Column II
P
B
V
V
A B
(B) (q) Temperature is constant
T
P A
T
P
B
V
V
A B
(B) (q) rkieku fu;r jgrk gS
T
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.-8
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
DPPs BOOKLET-3 VIKAAS (JA) | CHEMISTRY
P A
T
P
B
T
Ans. (A p, s) ; (B p, r, s) ; (C q) ; (D p, r, s)
P / I-CHEMISTRY
EST INFORM AT IO
DPP
DAILY PRACTICE PROBLEMS
ANSWER KEY
1. (C) 2. (A) 3. (B) 4. (D) 5. (D)
6. (D) 7. (B) 8. (B) 9. (A) 10. (A)
11. (A) 12. (C) 13. (A) 14. (B) 15. (C)
16. (B) 17. (C) 18. (B)
1. Which of the following is correct option for free expansion of an ideal gas under adiabatic condition ?
:)ks"e fLFkfr esa ,d vkn'kZ xSl ds eqDr izlkj ds fy, fuEu esa ls dkSu lk fodYi lgh gS \
(A) q = 0, T 0, w = 0 (B) q 0, T = 0, w = 0
(C*) q = 0, T = 0, w = 0 (D) q = 0, T < 0, w 0
Sol. For free expansion of an Ideal gas under adiabatic condition q = 0 T = 0 W = 0.
:)ks"eh; ifjfLFkfr;ksa esa ,d vkn'kZ xSl ds eqDr izlkj ds fy, q = 0 T = 0 W = 0 gSA
2. 20 g Ar gas is allowed to expand reversibly and isothermally at 300 K from 5 L to 10 L. Calculate the
approximate value of work done. (Take R = 25/3 J/K/mole, at.wt of Ar = 40 u)
300 K ij 20 g Ar xSl dks 5 L ls 10 L rd mRØe.kh; rFkk lerkih; :i ls çlkfjr fd;k x;kA rc fd;s x;s
dk;Z ds yxHkx eku dh x.kuk dhft;sA (R dks 25/3 J/K/mole rFkk Ar dk ijek.kq nzO;eku = 40 u ysa)
(A*) – 862.5 J (B) – 375 J (C) – 1437.5 J (D) – 1250 J
V2 20 10
Sol. W = – 2.303 nRT log W = – 2.3 × × 25/3 × 300 log = – 862.5 J.
V1 40 5
3. The work done in an adiabatic process on an ideal gas by a constant external pressure would be :
,d :)ks"eh; izØe esa fu;r ckâ; nkc }kjk ,d vkn'kZ xSl ij fd;k x;k dk;Z fuEu ds cjkcj gksxk %
(A) Zero ('kwU;) (B*) E (C) H (D) q
Sol. From I law of thermodynamics E = Q + W
where Q = 0 for adiabatic process.
gy. Å"ekxfrdh ds izFke fu;e ds vuqlkj E = Q + W
tgk¡ Q = 0 gS :)ks"eh; izØe ds fy,A
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.-9
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
DPPs BOOKLET-3 VIKAAS (JA) | CHEMISTRY
4. P–V plots for two gases during an adiabatic process are given in the figure :
uhps n'kkZ;s fp=k esa] nks xSlksa ds fy,] ,d :)ks"eh; izØe ds nkSjku P–V vkjs[k fn;s x;s gSa %
nkc
Volume vk;ru
Plot A and plot B should correspond to : (Assume ideal behaviour)
vkjs[k A rFkk vkjs[k B, fuEu xSlksa ls lEcfU/kr gksus pkfg;s % (vkn'kZ O;ogkj ekusa)
(A) He and O2 (B) SO2 and Ar (C) O2 and He (D*) Both (B) and (C)
(A) He rFkk O2 (B) SO2 rFkk Ar (C) O2 rFkk He (D*) (B) o (C) nksuksa
Sol. for O2 = 1.44 for He = 1.66.
5. For an ideal gas having molar mass M, specific heat at constant pressure can be given as :
,d vkn'kZ xSl] ftldk eksyj nzO;eku M gS] ds fy, fu;r nkc ij fof'k"V Å"ek] fuEu izdkj ls nh tk ldrh gS %
RM R RM R
(A) (B) (C) (D*)
–1 M( 1) –1 M( 1)
6. Equal volumes of two monoatomic gases, A and B, at same temperature and pressure are mixed. The
ratio of specific heats (Cp/Cv) of the mixture will be :
nks eksuks,VkWfed xSlksa] A rFkk B ds cjkcj vk;ru] leku rki vkSj nkc ij feyk;s tkrs gSaA feJ.k dh vkisf{kd Å"ek
(Cp/Cv) dk vuqikr fuEu gksxk %
(A) 0.83 (B)1.50 (C) 3.3 (D*) 1.67
CP 5 R 5
Sol. = 32 = = 1.67
CV 2R 3
7. An ideal gas with Cv = 3R expands adiabatically into a vacuum thus doubling its volume. The final
temperatue is given by :
,d Cv = 3R dh vkn'kZ xSl dks fuokZr esa :)ks"eh; :i ls izlkfjr fd;k tkrk gS rks bldk vk;ru nqxquk gks tkrk
gS rks vfUre rkieku fn;k tk ldrk gSA
T1
(A) T2 = T1[2–1/3] (B*) T2 = T1 (C) T2 = 2T1 (D) T2 =
2
Sol. It is free expansion where T = 0 ;g eqDr izlkj gSA tgk¡ T = 0
8. What is the difference between change in enthalpy and change in internal energy at constant volume :
fu;r vk;ru ij ,UFkSYih ifjorZu rFkk vkarfjd ÅtkZ ifjorZu esa vUrj D;k gS %
(A) 0 (B*) VdP (C) –VdP (D) PdV
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.-10
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
DPPs BOOKLET-3 VIKAAS (JA) | CHEMISTRY
10. % yield of the following reaction is plotted against pressure at a definite temperature.
,d fuf'pr rkikeu ij fuEu vfHkfØ;k dh % yfC/k o nkc ds chp vkjs[k [khpk¡ x;k gSA
2SO2(g) +O2(g) 2SO3(g)
Which of the following reaction is correct ? fuEu esa ls dkSulh vfHkfØ;k lgh gS \
T3
%
yield T2
T1
P
(A*) T1 > T2 > T3 (B) T3 > T2 > T1 (C) T1 = T2 = T3 (D) T1 < T2 < T3
Sol. Reaction is exothermic, therefore, yield will decreases with increase in temperature.
vfHkfØ;k Å"ek{ksih gS] vr% rkieku esa o`f) ds lkFk yfC?k esa deh vk tk,sxhA
11. N2O4(g) 2NO2(g) at a constant temperature, vapour density of N2O4 is found to be 30. Calculate %
dissociation of N2O4.
N2O4(g) 2NO2(g) fu;r rkieku ij N2O4 ok"i ?kuRo 30 ik;k tkrk gSA N2O4 dh % fo;kstu dh x.kuk
dhft,A
(A*) 53.3% (B) 46.7% (C) 16.7% (D) 83.3%
12. What can be said about work done in going through the cyclic process shown in the adjacent figure :
(A) ifjek.k = 4L atm; ra=k ds }kjk dk;Z fd;k x;k gSA
(B) ifjek.k = 16L atm; ra=k ij dk;Z fd;k x;k gSA
(C*) ifjek.k = 4L atm; ra=k ij dk;Z fd;k x;k gSA
(D) dksbZ dk;Z ugha fd;k x;k gSA
13. Calculate the heat needed to raise the temperature of 20 g iron from 25ºC to 500ºC, if specific heat
capacity of iron is 0.45 JK–1g–1.
20 g vk;ju dk rki 25ºC ls 500ºC rd c<+kus ds fy, vko';d Å"ek dh x.kuk dhft;s] ;fn vk;ju dh fof'k"V
Å"ek /kkfjrk 0.45 JK–1g–1 gSA
(A*) 4275 J (B) 225 J (C) 15.66 J (D) 2250 J
14. The energy required to vapourise one mole of benzene at it's boiling point is 31.2 kJ. For how long a
100 W electric heater has to be operated in order to vaporize a 100 g sample of benzene at it's boiling
temperature?
csUthu ds ,d eksy dks blds DoFkaukd fcUnq ij ok"ihd`r djus ds fy, vko';d ÅtkZ 31.2 kJ gSA blds DoFkaukd
fcUnq ij csUthu ds 100 xzke çkn'kZ dkss ok"ihd`r djus ds fy, 100 W ds ,d fo|qr ghVj dks fdrus le; ds fy,
dk;Z djuk iM+sxk\
(A) 743 sec (B*) 400 sec (C) 3.12 × 104 sec (D) 371 sec
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.-11
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
DPPs BOOKLET-3 VIKAAS (JA) | CHEMISTRY
15. Predict which of the following reaction(s) have a positive entropy change ?
I. Ba2+ (aq) + SO42– (aq) BaSO4 (s)
II. CaCO3 (s) CaO (s) + CO2 (g)
III. 2SO3 (g) 2SO2 (g) + O2 (g)
(A) I and II (B) III (C*) II and III (D) II
crkb;s fd fuEu eas ls dkSulh vfHkfØ;k ,d /kukRed ,UVªkWih ifjorZu j[krh gS %
I. Ba2+ (aq) + SO42– (aq) BaSO4 (s)
II. CaCO3 (s) CaO (s) + CO2 (g)
III. 2SO3 (g) 2SO2 (g) + O2 (g)
(A) I rFkk II (B) III (C*) II rFkk III (D) II
Sol. ng is + ve (ng /kukRed gSA½
16. The positive value of S indicates that-
(A) The system becomes less disordered (B*) The system becomes more disordered
(C) The system is in equilibrium position (D) The system tends to reach at equilibrium position
S ds /kukRed eku ls izdV gksrk gS fd &
(A) fudk; de vO;ofLFkr gks tkrk gSA (B*) fudk; vf/kd vO;ofLFkr gks tkrk gSA
(C) fudk; lkE; dh fLFkfr esa gSA (D) fudk; lkE; dh fLFkfr ds igq¡pus dks izfs jr gksrk gSA
17. If there are two compartments in a container of equal volume. 1L each, if one compartment is
containing 4 gm of He and in other there is vaccum, then the S when the separator between the
compartments has been removed, will be
;fn ,d daVsuj es leku vk;ru 1L çR;sd ds nks daikVZesaV gSA ;fn ,d daikVZesaV esa 4 xzke He gS rFkk nwljs esa
fuokZr gS rks tc daikVZesaV ds e/; esa ls i`Fkd~dkjh dks gVk nsrs gS rks S gksxkA
(A) 0 (B) – R ln 2 (C*) R ln 2 (D) 2 R ln 4
18. One mole of an ideal diatomic gas (Cv = 5 cal) was transformed from initial 25°C and 1 L to the state
when temperature is 100°C and volume 10 L. The entropy change of the process can be expressed as
(R = 2 calories/mol/K)
,d eksy vkn'kZ f}ijek.oh; xSl (Cv = 5 cal) dks] izkjfEHkd 25°C rFkk 1 L ls ml voLFkk esa :ikUrfjr fd;k x;k
tc rki 100°C o 10 L vk;ru gSA izØe dk ,UVªkWih ifjorZu fuEu izdkj O;Dr fd;k tk ldrk gSA
298 373
(A) 3 ln + 2 ln 10 (B*) 5 ln + 2 ln 10
373 298
373 1 373 1
(C) 7 ln + 2 ln (D) 5 ln + 2 ln
298 10 298 10
Tf Vf
Sol. S = nCV ln + nR ln
Ti Vi
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.-12
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
DPPs BOOKLET-3 VIKAAS (JA) | CHEMISTRY
P / I-CHEMISTRY
EST INFORM AT IO
DPP
DAILY PRACTICE PROBLEMS
ANSWER KEY
1. (C) 2. (D) 3. (B) 4. (D) 5. (B)
6. (A) 7. (D) 8.* (BD) 9.* (ABD) 10.* (ABD)
11.* (ABC) 12.* (AC) 13. (D) 14. (B) 15. (A)
16. 8 17. 7 18. 1
19. (A) p, s, t ; (B) p, r, s, t ; (C) q, r; (D) p,r,s,t 20. (A) – r; (B)–p; (C)–(r),(D)–q.
1. Two moles of an ideal gas undergo the following process :
(a) a reversible isobaric expansion from (P atm, V L) to (P atm, 2V L).
(b) a reversible isochoric change of state from (P atm, 2V L) to (P/2 atm, 2V L).
(c) a reversible isothermal compression from (P/2 atm, 2V L) to (P atm, V L).
Sketch with labels each of the processes on the same P-V diagram.
,d vkn'kZ xSl ds nks eksy fuEu izØe ds vUrxZr vkrs gS %
(a) (P atm, V L) ls (P atm, 2V L) rd ,d mRØe.kh; lenkch; izlkj
(b) (P atm, 2V L) ls (P/2 atm, 2V L) rd ,d mRØe.kh; levk;ruh; ifjorZu
(c) (P/2 atm, 2V L) ls (P atm, V L) rd ,d mRØe.kh; lerkih; lEihM+u
leku P-V js[kkfp=k ij izR;sd izØe dk js[kkfp=k cukb;sA
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.-13
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
DPPs BOOKLET-3 VIKAAS (JA) | CHEMISTRY
3. A child bought a balloon which became very small in size the next day. Which is correct statement
about ballon?
(A) It is isolated system (B*) It is an open system.
(C) It is a closed system (D) It exchanges only energy with the surrounding.
,d ckyd ,d xqCckjk yk;k tks fd vxys fnu cgqr NksVk gks x;kA xqCckjs ds laca/k esa dkSulk dFku lgh gS\
(A) ;g ,d foyfxr ra=k gSA (B*) ;g [kqyh ra=k (open system) gSA
(C) ;g cUn ra=k gSA (D) ;g okrkoj.k ls dsoy ÅtkZ dk fofu;e djrk gSA
Sol. Due to leakage of gas i.e. mass transfer from system to surrounding.
xSl ds /kheh xfr ls folj.k ds dkj.k vFkkZr~ ra=k ls okrkoj.k esa nzO;eku LFkkukUrj.k gksrk gSA
4. Some statements are given for the following equilibrium.
NH4HS(s) NH3(g) + H2S(g) ; H = +ve
S1 : On increase in temperature, equilibrium pressure of ammonia increases.
S2 : On increase in volume of container at constant temperature, equilibrium pressure of ammonia
increases.
S3 : On increase in mass of NH4HS(s) in the container at constant temperature, equilibrium pressure of
ammonia increases.
(A) T T T (B) F F F (C) T T F (D*) T F F
fuEufyf[kr lkE; ds fy, dqN dFku fn;s x;s gaS&
NH4HS(s) NH3(g) + H2S(g) ; H = +ve
S1 : rki esa o`f} djus ij] veksfu;k ds lkE; nkc esa o`f) gksrh gSA
S2 : fu;r rki ij] ik=k ds vk;ru esa o`f) djus ij] veksfu;k ds lkE; nkc esa o`f) gksrh gSA
S3 : fu;r rki ij] ik=k esa] NH4HS(s) ds nzO;eku esa o`f) djus ij] veksfu;k ds lkE; nkc esa o`f) gksrh gSA
(A) T T T (B) F F F (C) T T F (D*) T F F
5. 7.5 KJ heat is added to a closed system and its internal energy decreases by 12 KJ. So, ____ of work
is done ____ the system. For a new process, if the work is zero, then ____ of heat is ____ for the
same changes in state of system.
(A) 4.5 KJ, on, 12 KJ, released (B*) 19.5 KJ, by, 12 KJ, released
(C) 4.5 KJ, by, 12 KJ, absorbed (D) 19.5 KJ, on, 12 KJ, released
,d can fudk; esa Å"ek dh 7.5 KJ ek=kk nh tkrh gS rFkk bldh vkUrfjd ÅtkZ esa 12 KJ ls deh vkrh gSA vr%
voLFkk ifjorZu esa fudk; ____ , ____ dk dk;Z gksrk gSA ,d vU; leku voLFkk ifjorZu ds fy,] çØe esa ____
dh ÅtkZ ____ gksrh gS] ;fn bl çØe ds fy, dk;Z 'kwU; gSA
(A) ij] 4.5 KJ, 12 KJ, mRlftZr (B*) }kjk] 19.5 KJ, 12 KJ, mRlftZr
(C) }kjk] 4.5 KJ, 12 KJ, vo'kksf"kr (D) ij] 19.5 KJ, 12 KJ, mRlftZr
Sol. Q = 7.5 KJ
U = – 12 KJ
U = Q + W
W = –12 – 7.5 = –19.5 KJ. Ans.
Now vc W = 0,
U = Q Q = U = – 12 KJ Ans
6. For a reaction to occur spontaneously-
(A*) (H – TS) must be negative (B) (H + TS) must be negative
(C) H must be negative (D) S must be negative
fdlh vfHkfØ;k ds Lor% pkfyr gksus ds fy;s vko';d gS]
(A*) (H – TS) _.kkRed gksuk pkfg, (B) (H + TS) _.kkRed gksuk pkfg,
(C) H _.kkRed gksuk pkfg, (D) S _.kkRed gksuk pkfg,
7. For the reaction, C3H8(g) + 5O2(g) 3CO2(g) + 4H2O()
at constant temperature, H – E is :
vfHkfØ;k C3H8(g) + 5O2(g) 3CO2(g) + 4H2O() ds fy, fLFkj rki ij] H – E gSa &
(A) + 3RT (B) – RT (C) + RT (D*) – 3RT
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.-14
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
DPPs BOOKLET-3 VIKAAS (JA) | CHEMISTRY
8.* A sample of ideal gas is compressed from an initial volume of 2v0 to v0 using three different processes
(from same initial state).
First : Reversible isothermal process
Second : Reversible adiabatic process
Third : Irreversible adiabatic process by a constant external pressure
Then :
(A) Work done in first process will be greater than in second process.
(B*) Final pressure of gas will be minimum in first process.
(C) Enthalpy change of sample will be highest in isothermal process.
(D*) Final temperature of gas will be highest in third process.
rhu fofHkUu izØeksa dks iz;qDr dj izkjafHkd vk;ru 2v0 ls v0 rd ,d vkn'kZ xSl ds uewus dks laihfMr fd;k tkrk
gSA (leku izkjfEHkd voLFkk ls)
izFke : mRØe.kh; lerkih; izØe
f}rh; : mRØe.kh; :)ks"eh; izØe
r`rh; : ,d fu;r ckâ; nkc }kjk vuqRØe.kh; :)ks"e izØe
rc %
(A) izFke izØe esa fd;k x;k dk;Z] f}rh; izØe ls mPp gksxkA
(B*) izFke izØe esa xSl dk vfUre nkc fuEure gksxkA
(C) lerkih; izØe esa uewus dk ,UFkSYih ifjorZu mPpre gksxkA
(D*) r`rh; izØe esa xSl dk vfUre rkieku mPpre gksxkA
Sol. (A) Work done in first process will be lesser than in second process
(since W isothermal (lesser area under PV graph) < W reversible adiabatic (greater area under PV graph)).
(B) Tf(isothermal) < Tf(reversible adiabatic) < Tf(irreversible adiabatic). So, for same final volume vo, Pf(isothermal) < Pf(reversible
adiabatic) < Pf(irreversible adiabatic).
(C) Enthalpy change of sample will be zero in isothermal process, while it will be greater than zero in
reversible adiabatic as well as irreversible adiabatic process (since temperature increases in both).
gy. (A) izFke izØe esa fd;k x;k dk;Z] f}rh; izØe ls fuEu gksxkA
(pw¡fd W lerkih; (PV vkjs[k ds vUrxZr U;wu {ks=kQy) < W mRØe.kh; :)ks"eh; (PV vkjs[k ds vUrxZr mPp {ks=kQy)).
(B) Tf(lerkih;) < Tf(mRØe.kh; :)ks"eh;) < Tf(vuqRØe.kh; :)ks"eh;). vr%, leku vfUre vk;ru vo ds fy;s, Pf(lerkih;) < Pf(mRØe.kh;
:)ks"eh;) < Pf(vuqRØe.kh; :)ks"eh;).
(C) uewus dk ,UFkSYih ifjorZu lerkih; izØe esa 'kwU; gksxk] tcfd ;g mRØe.kh; :)ks"eh; izØe rFkk lkFk gh
vuqRØe.kh; :)ks"eh; izØe esa 'kwU; ls vf/kd gksxk (pw¡fd nksuksa esa rkieku c<+ jgk gS)A
9.* Which of the following occurs with increase in entropy.
(A*) Disolution of salt (B*) Egg boiling
(C) Adsorption of gas on solid surface (D*) Diffusion of gas
fuEufyf[kr izØeks esa ls dkSulk ,UVªksih esa o`f) ds lkFk lEiUu gksrk gSA
(A*) yo.k dk foys; gksuk (B*) v.Ms dk mcyuk
(C) Bksl lrg ij xSl dk vf/k'kks"k.k (D*) xSl dk folj.k
10.* Which statement regarding entropy is/are incorrect ?
(A*) A completely ordered deck of cards has more entropy than a shuffled deck in which cards are
arranged randomly.
(B*) A perfect ordered crystal of solid nitrous oxide has more entropy than a disordered crystal in which
the molecules are oriented randomly.
(C) 1 mole N2 gas at STP has more entropy than 1 mole N2 gas at 273 K in a volume of 11.2 litre.
(D*) 1 mole N2 gas at STP has more entropy than 1 mole N2 gas at 273 K and 0.25 atm.
,UVªksih ds fo"k; esa fuEu esa ls dkSulk dFku vlR; gS \
(A*) iw.kZr% O;ofLFkr rk'k ds iÙkksa dh xM~Mh dh ,UVªksih] vfu;fer :i ls O;ofLFkr rk'k ds iÙkkas dh xM~Mh dh
rqyuk esa vfèkd gksrh gSA
(B*) iw.kZ :i ls O;ofLFkr Bksl ukbVªl vkWDlkbM fØLVy dh ,UVªksih] fØLVy esa vfu;fer :i ls O;ofLFkr v.kqvksa
ds fØLVy dh vis{kk vf/kd gksrh gSA
(C) STP ij 1 eksy N2 xSl dh ,UVªksih] 11.2 yhVj vk;ru ,oa 273 K rki ij mifLFkr 1 eksy N2 xSl dh rqyuk
esa vfèkd gksrh gSA
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.-15
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
DPPs BOOKLET-3 VIKAAS (JA) | CHEMISTRY
(D*) STP ij 1 eksy N2 xSl dh ,UVªksih] 273 K rFkk 0.25 atm ij mifLFkr 1 eksy N2 xSl dh vis{kk vf/kd gksrh gSA
Sol. For same amount of gas at constant temperature, lesser is the volume, lower will be the entropy.
fu;r rki ij xSl leku ek=kk ds fy, vk;ru de gksus ij ,sUVªkWih Hkh de gksxhA
11.* For the process H2O() (1 bar, 373 K) H2O(g) (1 bar, 373 K), the correct set of thermodynamic
parameters is:
izØe H2O() (1 bar, 373 K) H2O(g) (1 bar, 373 K), ds fy;s Å"ekxfrdh iSjkehVj dk lgh leqPp; gS %
(A*) G = 0 (B*)S > 0 (C*) H > 0 (D) G = –ve
Sol. H2O(,1bar, 373K) H2O(g, 1bar, 373 K)
S > 0
H > 0
G = 0
12.* At 300 K, the reaction which have the following values of thermodynamic parameter, occur
spontaneously.
300 K ij] ,d vfHkfØ;k] Å"ekxfrdh ekiØeksa ds fuEu eku j[krh gS] rc vfHkfØ;k Lor% gksxh ;fn vfHkfØ;k fuEu
esa ls dkSuls eku j[krh gS %
(A*)Gº = – 400 kJ mol–1 (B)Hº = 200 kJ mol–1, Sº = – 4 JK–1 mol–1
(C*)Hº = –200 kJ mol , Sº = 4 JK mol
–1 –1 –1 (D)Hº = 200 kJ mol–1, Sº = –40 JK–1 mol–1
Sol. Gº = Hº – TSº; In case of options (A) & (C), Gº is negative.
gy- Gº = Hº – TSº; fodYi (A) rFkk (C) dh ifjfLFkfr esa] Gº _.kkRed gSA
Comprehension # (13 to 15)
One mole of Helium gas undergoes a reversible cyclic process ABCDA as shown in the figure.
Assuming gas to be ideal, answer the following questions :
16. An orbital has the difference in angular and radial nodes as 2 and radial nodes equal to 1. Find the sum
of principal quantum number and azimuthal quantum number.
,d d{kd ds fy, dks.kh; rFkk f=kT;h; uksM+ ds e/; vUrj nks gS rFkk f=kT;h; uksM+ dh la[;k ,d gS rc eq[;
DokaVe la[;k rFkk f}xa'kh DokaVe la[;k ds ;ksx dk eku Kkr dhft,A
Ans. 8
17. If the change in entropy of the system when 2 moles of an ideal diatomic gas ( = 1.4) is heated from
400 K to 800 K under constant pressure conditions is xR ln 2, find the value of x.
tc ,d f}ijek.ohd vkn'kZ xSl ( = 1.4) ds 2 eksy dks fu;r nkc ifjfLFkfr esa 400 K ls 800 K rd xeZ fd;k
tkrk gSA rc ;fn ra=k dh ,UVªksih esa ifjorZu xR ln2 gS rc X dk eku Kkr dhft;s \
Ans. 7
V1 V
Sol. = 2 ( P = constant) ( P = fu;r)
T1 T2
T2 V
= 2 =2
T1 V1
T V
S = nCV ln 2 + nR ln 2 = 5R ln 2 + 2R ln 2 = 7 R ln 2 x = 7.
T1 V1
18. For a perfectly crystalline solid, (CP)m = aT3, where a is a constant. If (CP)m at 10K is 0.375 J/K-mol,
then find the value of molar entropy at 20K (in J/K-mol).
,d Li"V% fØLVyh; Bksl ds fy, (CP)m = aT3 gS tgk¡ a ] ,d fu;rkad gS ;fn 10K ij] (CP)m dk eku 0.375 J/K-
mol gS rc] 20K ij eksyj ,sUVªksih dk eku (J/K-mol esa) Kkr dhft;s \
Ans. 1
3
Sol. (Cp)m = aT3 0.375 = a (10)3 a = × 10–3
8
20 20 20
(CP )m dT aT3 8000a 8000 3
2
Sm = = aT dT = = × × 10–3 = 1J/K–mol3
0
T 0
3 3 3 8
0
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.-17
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
DPPs BOOKLET-3 VIKAAS (JA) | CHEMISTRY
19. Match the processes given in column-I performed on an ideal gas sample with changes in column-II :
Column I Column II
(A) Isothermal expansion against constant external pressure (p) Suniv > 0
(B) Free expansion against vacuum under isothermal conditions. (q) Ssys = 0
(C) Reversible adiabatic compression (r) Ssurr = 0
(D) Free expansion against vacuum under adiabatic conditions. (s) Ssys > 0
(t) Gsys < 0
LrEHk I esa fn;s x;s ,d vkn'kZ xSl ds izkn'kZ ij fd;s x;s izØeksa dks] LrEHk II esa fn;s x;s ifjorZuksa ls lqesfyr
dhft,A
LrEHk I LrEHk II
(A) fu;r ckg~; nkc ds fo:) lerkih; izlkj (p) SczEgk.M > 0
(B) lerkih; ifjfLFkfr;ksa esa fuokZr ds fo:) eqDr izlkj (q) Sfudk; = 0
(C) mRØe.kh; :)ks"eh; lEihMu (r) Sifjos'k = 0
(D) :)ks"eh; ifjfLFkfr;ksa esa] fuokZr ds fo:) eqDr izlkj (s) Sfudk; > 0
(t) Gfudk; < 0
Ans. (A) p, s, t (B) p, r, s, t (C) q,r (D) p,r,s,t
20.
Column I
Column II
(Thermodynamic properties of
(Condition for spontaneity of chemical reaction)
chemical reaction)
(A) H < O , S < O (p) Chemical reaction is spontaneous at all temperatures.
Chemical reaction is spontaneous at high temperature
(B) H < O, S > O (q)
and non spontaneous at low temperatures.
Chemical reaction is non spontaneous at high
(C) H > O, S < O (r)
temperatures and spontaneous at low temperatures.
Chemical reaction is non spontaneous at all
(D) H > O, S > O (s)
temperatures.
LrEHk I
LrEHk II
(jklk;fud vfHkfØ;k ds
(jklk;fud vfHkfØ;k dh Lor% çofrZrk dh 'krZ)
Å"ekxfrdh; y{k.k)
(A) H < O , S < O (p) jklk;fud vfHkfØ;k leLr rkiksa ij Lor% çofrZZr gSaA
jklk;fud vfHkfØ;k mPp rki ij Lor% çofrZr gS rFkk fuEu rki
(B) H < O, S > O (q)
ij vLor% çofrZr gSaA
jklk;fud vfHkfØ;k mPp rki ij vLor% çofrZr gS rFkk fuEu
(C) H > O, S < O (r)
rki ij Lor% çofrZr gSaA
(D) H > O, S > O (s) jklk;fud vfHkfØ;k leLr rkiksa ij vLor% çofrZr gSaA
Ans. (A) – r ; (B) – p ; (C) – (r) , (D) – q.
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.-18
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
DPPs BOOKLET-3 VIKAAS (JA) | CHEMISTRY
P / I-CHEMISTRY
EST INFORM AT IO
DPP
DAILY PRACTICE PROBLEMS
ANSWER KEY
1. (D) 2. (A) 3. (A) 4. (B) 5. (D)
6. (B) 7. (C) 8. (B) 9. (A) 10. (C)
11. (C) 12. (C) 13. (D) 14. (D) 15. (B)
16. (A) 17. (A) 18. (C) 19. (D) 20. (C)
1. Consider the following changes :
fuEu ifjorZuksa ij fopkj dhft, %
1
(i) H2(g) + aq. H+(aq.) (ii) 2O(g) O2(g)
2
(iii) NH4+(g) + Cl–(g) NH4Cl(s) (iv) P4 (black) + 5O2(g) P4O10(s)
Which of the above does not represent H°formation of the product :
mijksDr esa ls dkSulk] mRikn ds H°lEHkou dks iznf'kZr ugha djrk gS %
(A) II, III (B) I, IV (C) I, II, III (D*) II , III, IV
3
2. Given that S(s) + O2(g) SO3(g) + 2x KCal
2
1
SO2(g) + O2(g) SO3(g) + y KCal
2
What would be the enthalpy of formation of SO2 :
3
fn;k x;k gS fd S(s) + O2(g) SO3(g) + 2x KCal
2
1
SO2(g) + O2(g) SO3(g) + y KCal
2
SO2 ds laHkou dh ,UFkSYih D;k gksxh %
(A*) – 2x + y (B) 2x – y (C) – x + y (D) x – y
3. For the two reactions given below :
H2(g) + ½O2(g) H2O () + x1 kJ mol–1
H2(g) + ½O2(g) H2O (g) + x2 kJ mol–1
Compare the magnitude of x1 and x2 : (x1 and x2 are the heat released in above two processes)
uhps nh xbZ nks vfHkfØ;kvksa ds fy, %
H2(g) + ½O2(g) H2O () + x1 kJ mol–1
H2(g) + ½O2(g) H2O (g) + x2 kJ mol–1
x1 rFkk x2 ds ifjek.k dh rqyuk dhft, % (x1 rFkk x2, mijksDr nksuksa izØeksa esa fu"dkflr Å"ek gSA)
(A*) x1 > x2 (B) x1 < x2
(C) x1 = x2 (D) cannot be compared rqyuk ugha dh tk ldrh
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.-19
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
DPPs BOOKLET-3 VIKAAS (JA) | CHEMISTRY
Sol. Some of the heat is used to vaporise the H2O ()
(H2O () dks ok"ihd`r djus ds fy, dqN ek=kk esa Å"ek iz;qDr gksrh gSA)
4. The combustion of 0.2 mole of liquid carbon disulphide CS2 at constant pressure to give CO2(g) and
SO2(g) releases 215 kJ of heat. What is Ho for CS2(l) in kJ mol–1 :
fu;r nkc ij nzo dkcZu MkbZlYQkbM CS2 ds 0.2 eksy ds ngu ij CO2(g) rFkk SO2(g) fu"dkflr gksrh gS rFkk
215 kJ Å"ek fu"dkflr gksrh gSA CS2(l) ds fy, Ho dk eku kJ mol–1 esa fuEu gksxk %
Hfº kJ mol–1
CO2(g) –393.5
SO2(g) –296.8
(A) 772.1 (B*) 87.9 (C) 384.7 (D) – 2062.1
Sol. CS2() + 3O2(g) CO2 (g) + 2SO2(g) ; Hºrxn. = 5 × – 215 = – 1075 kJ
Hºrxn. = Hºf (CO2) + 2 × Hºf (SO2) – Hºf (CS2)
Hºf (CS2) = (– 393.5 – 2 × 296.8) – (–1075)
Hºf (CS2) = 87.9
5. Calculate the heat of combustion of carbon monoxide at 17ºC at constant volume from the given
enthalpy of reactions at 17ºC :
fu;r vk;ru ij 17ºC ij dkcZu eksuksvkWDlkbM ds ngu dh Å"ek dh x.kuk dhft,] ;fn 17ºC rki ij
fuEufyf[kr vfHkfØ;kvksa ds fy, vfHkfØ;k dh ,UFkSYih ds eku fn;s x;s gSa %
(i) C (s) + O2 (g) CO2 (g) ; H1 = 97000 Cal
(ii) CO2 (g) + C (s) 2CO (g) ; H2 = 39000 Cal
(A) –136000 Cal (B) –135420 Cal (C) –68000 Cal (D*) –67710 Cal
6. In the combustion of 2.0 g of methane 25 kcal heat is liberated, heat of combustion of methane would
be-
(A) 100 kcal (B*) 200 kcal (C) 300 kcal (D) 400 kcal
2.0 xzke esFksu dks tykus ij 25 fdyks dSyksjh rki mRiUu gksrk gS] esFksu dh ngu Å"ek gksxh&
(A) 100 fdyks dSyksjh (B*) 200 fdyks dSyksjh (C) 300 fdyks dSyksjh (D) 400 fdyks dSyksjh
7. The value of heat of formation of SO2 and SO3 are –298.2 kJ and –98.2 kJ. The heat of reaction of the
following reaction will be :
1
SO2 + O2 SO3
2
SO2 rFkk SO3 dh laHkou Å"ek dk eku –298.2 kJ rFkk –98.2 kJ gSA rc fuEu fØ;k dh vfHkfØ;k Å"ek gksxh&
1
SO2 + O2 SO3
2
(A) –200 kJ (B) –356.2 kJ (C*) +200 kJ (D) –396.2 kJ
8. For the equations :
C(diamond) + 2H2(g) CH4(g) ;H1 and C(g) + 4H(g) CH4(g) ; H2
Select the correct option :
(A) H1 = H2 (B*) H1 > H2
(C) H1 < H2 (D) Nothing can be said with certainty
fuEu lehdj.kksa ds fy, %
C(ghjk) + 2H2(g) CH4(g) ;H1 rFkk C(g) + 4H(g) CH4(g) ; H2
lgh fodYi dk p;u dhft;s %
(A) H1 = H2 (B*) H1 > H2
(C) H1 < H2 (D) fuf'pr :i ls dqN dgk ugha tk ldrk gSA
9. Consider the following reactions :
fuEu vfHkfØ;kvksa dk voyksdu dhft, :
(i) H+(aq) + OH–(aq) = H2O()– x1 kJ mol–1
1
(ii) H2(g) + O2 (g) = H2O() – x2 kJ mol–1
2
(iii) CO2(g) + H2(g) = CO(g) + H2O() – x3 kJ mol–1
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.-20
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
DPPs BOOKLET-3 VIKAAS (JA) | CHEMISTRY
5
(iv) C2H2(g) + O2 (g) = 2CO2(g) + H2O() + x4 kJ mol–1
2
Enthalpy of formation of H2O () is :
H2O () ds fy, lEHkou ,UFkSYih fuEu gS %
(A*) + x2 kJ mol–1 (B) + x3 kJ mol–1 (C) – x4 kJ mol–1 (D) + x1 kJ mol–1
Sol. Enthalpy of formation : The amount of heat evolved or absorbed during the formation of 1 mole of a
compound for its constituent elements is known as heat of formation. So, the correct answer is :
lEHkou dh Å"ek : 1 eksy ;kSfxd ds fuekZ.k ds nkSjku blds vo;oh rRoksa ls mRlftZr ;k vo'kksf"kr Å"ek dh ek=kk
lEHkou dh Å"ek ls tkuh tkrh gSA blfy, lgh mÙkj fuEu gS :
1
H2(g) + O2 (g) H2O() , H = + x2 kJ mol–1
2
10. The enthalpy of neutralization of a strong base and strong acid is 57.0 kJ eq –1. The heat evolved when
0.5 mole of HNO3 are added to 1 L of 0.2 M NaOH solution is :
izcy {kkj o izcy vEy ds mnklhuhdj.k dh ,UFkSYih 57.0 kJ eq–1 gSA HNO3 ds 0.5 eksy dks 1 L, 0.2M NaOH
foy;u esa feykus ij] mRlftZr Å"ek fuEu gS %
(A) 20 kJ (B) 28.5 kJ (C*) 11.4 kJ (D) 34.9 kJ
11. The heat evolved in neutralizing a solution containing 1 mole of HCN with a strong alkali is 3 KCal. The
enthalpy of dissociation of HCN is :
,d izcy {kkj ds lkFk HCN ds ,d eksy ;qDr foy;u ds mnklhuhdj.k esa mRlftZr Å"ek 3 KCal gSA HCN ds
fo;kstu dh ,UFkSYih dk eku fuEu gksxk %
(A) 54.1 KCal/mol (B) 60.1 KCal/mol (C*) 10.7 KCal/mol (D) 16.7 KCal/mol
Sol. enthalpy of dissociation = (13.7 – 3) KCal = 10.7 KCal
12. The rates of diffusion of two gases A and B are in the ratio 1 : 4. Then the ratio of molecular masses :
A rFkk B nks xSlksa ds folj.k dh nj dk vuqikr 1 : 4 gSA rks buds vkf.od Hkkjks dk vuqikr %
(A) 1/12 (B) 5/24 (C*) 16 (D) 1/6
r1 1 w1 2
Sol. ,
r2 4 w2 3
r1 M2 M2
= 16 : 1
r2 M1 M1
13. Calculate the molality of one litre solution of 49% H2SO4 (weight/volume). The density of the solution is
1.49 g/ml.
49% H2SO4 (Hkkj/vk;ru) ds ,d yhVj foy;u dh eksyyrk dh x.kuk dhft,A foy;u dk ?kuRo 1.49 g/ml gSA
(A) 2.5 (B)10 (C) 2 (D*) 5
Sol. 49%(w/v) H2SO4 means 49g of H2SO4 is present in 100 ml of solution.
So mass of solution is = v × d
= 100 × 1.49 = 149 gram
Now mass of solvent = 149 – 49 = 100 g
49
/
So molality = 100 98 = 5m
/1000
Sol. 49%(w/v) H2SO4 dk vFkZ gS fd 49g H2SO4, 100 ml foy;u esa mifLFkr gSA
vr% foy;u dk Hkkj gS =v×d
= 100 × 1.49 = 149 xzke
vc foyk;d dk Hkkj = 149 – 49 = 100 g
49
/ 98
vr% eksyyrk = 100
= 5m
/1000
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.-21
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
DPPs BOOKLET-3 VIKAAS (JA) | CHEMISTRY
14. Which of the following option is correct :
(A) When a liquid and its vapour are at equilibrium and the pressure is suddenly increased, cooling
occurs.
(B) N2(g) + O2(g) 2NO(g)–Heat; the equilibrium shifts in backward direction on increasing the
temperature.
(C) Vapour pressure of particular liquid at a particular temperature depends upon surface area of liquid
exposed.
(D*) None of these
fuEu esa ls lgh fodYi dkSulk gS %
(A) tc nzo o bldh ok"i lkE;koLFkk esa gS rc] vpkud nkc c<+kus ij 'khryu gks tkrk gSA
(B) N2(g) + O2(g) 2NO(g)–Å"ek; rkieku c<+kus ij vfHkfØ;k] i'p fn'kk esa LFkkukUrfjr gksrh gSA
(C) fuf'pr rkieku ij fuf'pr nzo dk ok"i nkc [kqys gq, nzo ds i`"Bh; {ks=kQy ij fuHkZj djrk gSA
(D*) buesas ls dksbZ ugha
Sol. (A) Due to condensation of vapour , heat is liberated.
(A) ok"i ds la?kuu ds dkj.k] Å"ek eqDr gksrh gSA
Sol. (B) Reaction goes in forward direction.
(B) vfHkfØ;k vxz fn'kk esa LFkkukUrfjr gksrh gSA
15. For the reaction PCl5(g) PCl3(g) + Cl2(g) ; H = +ve, taking place in a closed container, initially
starting with only PCl5, the value of observed vapour density at equilibrium ______ with decrease in
temperature.
(A) Decreases (B*) Increases
(C) Remains constant (D) First decreases, then increases
vfHkfØ;k PCl5(g) PCl3(g) + Cl2(g) ; H = +ve, dks ,d can ik=k esa djk;k tkrk gSA izkjEHk esa dsoy] PCl5
dks fy;k tkrk gSA rc rkieku esa deh ds lkFk lkE; ij izsf{kr ok"i ?kuRo ds eku esa _________ gksrh gSA
(A) deh (B*) o`f)
(C) eku fu;r jgrk gS (D) igys deh rFkk fQj o`f)
Sol. As temperature is decreased, the equilibrium will shift in backward direction according to Le-Chatelier's
(Vd)Th
principle, leading to an decrease in value of (degree of dissociation). Now, (V.D.)obs =
1
so, as decreases, (V.D.)obs increases.
Sol. rkieku esa deh ds lkFk] yh&'ksrsfy, fl)kUr ds vuqlkj] lkE; i'p fn'kk esa foLFkkfir gksrk gS] rFkk (fo;kstu dh
(Vd)lS)kfUrd
ek=kk) esa Hkh deh gksxh] vr% (VD)izsf{kr =
1
vr%, esa deh ds lkFk (VD)izsf{kr esa o`f) gksrh gSA
3
16. A monoatomic ideal gas (CV = R) is allowed to expand adiabatically and reversibly from initial
2
volume of 8 L at 300 K to a volume of V2 at 250 K. V2 is : (Given (4.8)1/2 = 2.2)
(A*) 10.56 L (B) 17.6 L
(C) 11.52 L (D) Expansion not possible since temperature has decreased
3
,d ,dy ijek.kfod xSl (CV = R) dks :)ks"e rFkk mRØe.kh; :i ls 300 K rki ij izkjfEHkd vk;ru 8 L ls]
2
250 K ij vfUre vk;ru V2 rd izlkfjr gksus fn;k tkrk gSA rc V2 fuEu gS % (fn;k x;k gS % (4.8)1/2 = 2.2)
(A*) 10.56 L (B) 17.6 L
(C) 11.52 L (D) izlkj laHko ugha gS] D;kssafd rkieku ?kV x;k gSaA
Sol. TV–1 = constant (fu;rkad)
5 2
= –1=
3 3
300 × (8)2/3 = 250 × (V2)2/3 (V2)2/3 = 4.8
V2 = (4.8) 4.8 × 2.2 = 10.5 L
3/2
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.-22
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
DPPs BOOKLET-3 VIKAAS (JA) | CHEMISTRY
17. An ideal gas is expanded from volume V0 to 4V0 by following two ways : (from same initial state)
(a) st using reversible isothermal expansion from V0 to 2V0 , then using reversible adiabatic expansion
from 2V0 to 4V0 .
(b) st using reversible adiabatic expansion from V0 to 2V0, then from 2V0 to 4V0 using reversible
isothermal expansion.
Then which of the following options is correct :
(A*) Work done in (a) process > work done in (b) process
(B) Work done in (b) process > work done in (a) process
(C) Work done in (b) process = work done in (a) process
(D) Work done in both processes cannot be compared
,d xSl dks fuEu nks iFkkas ls vk;ru V0 ls 4V0 rd izlkfjr fd;k x;k gS % (leku izkjfEHkd voLFkk ls)
(a) st esa V0 ls 2V0 rd mRØe.kh; lerkih izlkj dk mi;ksx fd;k x;k rFkk fQj 2V0 ls 4V0 rd mRØe.kh;
:)ks"e izlkj dk mi;ksx fd;k x;kA
(b) st esa V0 ls 2V0 rd mRØe.kh; :)ks"e izlkj dk mi;ksx fd;k x;k rFkk fQj 2V0 ls 4V0 ls mRØe.kh; lerkih
izlkj dk mi;ksx fd;k x;kA
rc fuEu esa ls dkSulk dFku lgh gS %
(A*) izØe (a) esa fd;k x;k dk;Z > izØe (b) esa fd;k x;k dk;Z
(B) izØe (b) esa fd;k x;k dk;Z > izØe (a) esa fd;k x;k dk;Z
(C) izØe (b) esa fd;k x;k dk;Z = izØe (a) esa fd;k x;k dk;Z
(D) nksuksa izdzeksa esa fd;s x;s dk;Z dh rqyuk ugha dh tk ldrh
18. The average energy required to break a P – P bond in P4 (s) into gaseous atoms is 53.2 kcal mol–1. The
bond dissociation energy of H2(g) is 104.2 kcal mol–1; Hf0 of PH3(g) from P4(s) is 5.5 kcal mol–1. The P-
H bond energy in kcal mol–1 is [Neglect presence of Van der Waals forces in P4(s)]
P4 (s) v.kq esa P–P ca/k dks rksM+us ds fy,] xSlh; ijek.kqvksa esa fo;kstu ds fy, vko';d] vkSlr ÅtkZ 53.2 kcal
mol–1 gSA H2(g) dh ca/k fo;kstu ÅtkZ 104.2 kcal mol–1 gSA P4(s) ls PH3(g) dh Hf0 5.5 kcal mol–1 gSA P-H ca/k
ÅtkZ kcal mol–1 esa gSA [P4(s) esa ok.Mjoky cyksa dh mifLFkfr dks ux.; eku dj]
(A) 85.2 (B) 57.6 (C*) 76.9 (D) 63.3
Sol. P4(s) 4P(g) H = 53.2 × 6
H2(g) 2H(g) H = 104.2
1 3
P4(s) + H2(g) PH3(g) H = 5.5
4 2
1 3
× 6 × 53.2 + × 104.2 – 3P–H = 5.5 P–H = 76.866 i.e. 76.9 kcal mol–1
4 2
19. Heat of atomisation of NH3 and N2H4 are x kcal mol–1 and y kcal mol–1 respectively. Calculate average
bond energy of N—N bond.
NH3 o N2H4 ds ijek.kohdj.k dh m"ek (heat of atomisation) Øe'k% x kcal mol–1 o y kcal mol–1 gSaA N—N
cU/k dh vkSlr cU/k ÅtkZ ifjdfyr dhft,A
4y 3x 2y 3x 4y 3x 3y 4x
(A) kcal mol–1 (B) kcal mol–1 (C) kcal mol–1 (D*) kcal mol–1
3 3 4 3
20. Consider the following changes :
fuEu ifjorZuksa dk voyksdu dhft;s %
Na+(g) Na+(aq) H1 .... (1)
Na(s) Na+(g) H2 .... (2)
Cl–(g) Cl–(aq) H3 .... (3)
Cl2(g) 2Cl–(g) H4 .... (4)
Na+(g) + Cl–(g) NaCl(s) H5 .... (5)
NaCl(s) Na+(aq) + Cl–(aq) H6 .... (6)
Hydration enthalpy of NaCl can be defined by sum of the following :
NaCl dh ty;kstu ,UFkSYih dks fuEu esa ls fdlds ;ksx }kjk ifjHkkf"kr fd;k tk ldrk gS %
(A) H1 + H2 +H3 +H4/2 (B) dsoy H6 only
(C*) H1 + H3 (D) H2 +H4/2 +H5 + H6
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.-23
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
DPPs BOOKLET-3 VIKAAS (JA) | CHEMISTRY
P / I-CHEMISTRY
EST INFORM AT IO
DPP
DAILY PRACTICE PROBLEMS
ANSWER KEY
1. (B) 2. (D) 3. (D) 4. (A) 5. (C)
6. (B) 7. (C) 8. (C) 9. (C) 10. (D)
11. (D) 12. (C) 13. (C) 14. (D) 15. (B)
16. (i) 2NaOH + 2NO2 NaNO2 + NaNO3 + H2O (ii) 6NaOH + 3Br2 5NaBr + NaBrO3 + 3H2O.
(iii) 6NaOH + 4S 2Na2S + Na2S2O3 + 3H2O (iv) 4NaOH + 2F2 4NaF + O2 + 2H2O.
(v) PbO + 2NaOH Na2PbO2 + H2O
17. (A – p) ; (B – q, s, t) ; (C – t) ; (D – q, r) 18. (D) 19. (B) 20. (A)
1. Which of the following gives propyne on hydrolysis ?
fuEu esa ls dkSu] ty vi?kVu }kjk izksikbu cukrk gS \
(A) Al4C3 (B*) Mg2C3 (C) B4C (D) La4C3
2. Which of the following compounds on thermal decomposition yields a basic as well as an acidic oxide ?
fuEu esa ls fdl ;kSfxd ds rkih; vi?kV~u ij ,d {kkjh; vkWDlkbM ds lkFk&lkFk ,d vEyh; vkWDlkbM Hkh izkIr
gksrk gS \
(A) KClO3 (B) NaNO3 (C) K2CO3 (D*) MgCO3
Hint : MgCO3 MgO + CO2
(Basic) (Acidic)
3. Which of the following statements is incorrrect ?
(A) The superoxide ion (i.e. O2–) is stable only in presence of larger cations such as K+, Rb+, Cs+.
(B) Alkali metals are normally kept in kerosene oil.
(C) All the alkali metal hydrides are ionic solids with high melting points.
(D*) The concentrated solution of alkali metals in liquid ammonia is paramagnetic in nature.
fuEu esa ls dkSulk dFku vlR; gS %
(A) lqijvkWDlkbM vk;u (O2–), cM+s /kuk;uksa tSls K+, Rb+, Cs+ ds lkFk gh LFkk;h gksrk gSA
(B) {kkjh; /kkrqvksa dks lkekU;r% dSjkslhu esa j[kk tkrk gSA
(C) lHkh {kkjh; /kkrqvksa ds gkbMªkbM] vk;fud Bksl gksrs gS rFkk mPp xyukad j[krs gSaA
(D*) {kkjh; /kkrqvksa dk nzo veksfu;k esa lkUnz foy;u] çd`fr esa vuqpqEcdh; gksrk gSA
Sol. (A) Bigger anion is stabilised by bigger cation through lattice energy effect.
(B) Because of their high reactivity towards air and water.
(C) True Statement
(D) In concentrated solution, unpaired electrons with opposite spins paired up – forming the solution
diamagnetic.
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.-24
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
DPPs BOOKLET-3 VIKAAS (JA) | CHEMISTRY
Sol. (A) cM+s _.kk;u tkyd ÅtkZ izHkko ls cM+s /kuk;u }kjk LFkk;hd`r jgrk gSA
(B) D;ksafd budh ok;q o ty ds izfr mPpfØ;k'khyrk gksrh gSA
(C) lR; dFku
(D) lkfUnzr foy;u esa fopfjr pØ.k ;qDr v;qfXer bysDVªkWu ;qfXer gksdj fopyu dks izfrpqEcdh; cukrs gSA
4. The pair of compounds which cannot exist together in solution is :
(A*) NaHCO3 and NaOH (B) Na2CO3 and NaHCO3
(C) Na2CO3 and NaOH (D) NaHCO3 and NaCI
;kSfxdks dk dkSulk ;qXe] foy;u esa ,d lkFk ugha jg ldrk gS %
(A*) NaHCO3 o NaOH (B) Na2CO3 o NaHCO3
(C) Na2CO3 o NaOH (D) NaHCO3 o NaCI
Sol. Since NaHCO3 is an acid salt of H2CO3. it reacts with NaOH to form Na2CO3 and H2O.
NaHCO3 + NaOH Na2CO3 + H2O.
gy- pwafd NaHCO3, H2CO3 dk ,d vEy yo.k gSA ;g NaOH ds lkFk vfHkfØ;k dj Na2CO3 o H2O cukrk gSA
NaHCO3+ NaOH Na2CO3 + H2O.
5. Which of the following statements is true for all the alkali metals ?
(A) Their nitrates decompose on heating to give the corresponding nitrites and oxygen.
(B) Their chlorides are deliquescent and crystallise as hydrates.
(C*) They react with water to form hydroxide and hydrogen.
(D) They readily react with halogens to form ionic halides, M+X–.
lHkh {kkjh; /kkrqvksa ds fy, fuEu esa ls dkSulk dFku lR; gS \
(A) buds ukbVªsV] xeZ djus ij fo?kfVr gksdj lacaf/kr ukbVªkbV rFkk vkWDlhtu nsrs gSA
(B) buds DyksjkbM] izLosn~d ¼deliquescent½ gksrs gaS rFkk ty;ksftr :i esa fØLVyhd`r gksrs gSaA
(C*) ;s ty ds lkFk fØ;k djds gkbMªksDlkbM rFkk gkbMªkstu cukrs gaSA
(D) ;s gSykstu ds lkFk rqjUr fØ;k djds vk;fud gSykbM, M+X– cukrs gaSA
Sol. (A) 4 LiNO3 2Li2O + 4NO2 + O2
2NaNO3 2NaNO2 + O2 (similar decomposition with the nitrates of K, Rb and Cs)
(B) Only LiCl is deliquescent and crystallises as a hydrate LiCl.2H2O
(C) 2M + 2H2O 2M+ + 2OH– + H2 (M = an alkali metal)
(D) Halides of Li are covalent in nature.
(A) 4 LiNO3 2Li2O + 4NO2 + O2
2NaNO3 2NaNO2 + O2 (ukbVªkbV K, Rb rFkk Cs ds lkFk lkeu fo?kVu)
(B) dosy LiCl izLos|; gS rFkk gkbVªsV LiCl.2H2O ds :i esa fØLVyhd`r jgrk gSA
(C) 2M + 2H2O 2M+ + 2OH– + H2 (M = ,d {kkj /kkrq)
(D) Li ds gSykbM lgla;ksth izd`fr ds gksrs gSA
6. Which of the following reactions of potassium superoxide supply oxygen gas in the breathing
equipments used in space and submarines ?
(1) reaction of superoxide with nitrogen in the exhaled air
(2) reaction of superoxide with moisture in the exhaled air
(3) reaction of superoxide with carbon dioxide in the exhaled air
(A) (1), (2) and (3) (B*) (2) and (3) only (C) (2) only (D) (1) and (2) only
varfj{k rFkk iaMqfCc;ksa esa fuEu esa ls iksVsf'k;e lqij vkWDlkbM dh dkSulh vfHkfØ;k] 'olu ;a=k esa vkWDlhtu xSl ds
çokg ds fy, iz;qDr dh tkrh gS \
(1) fu"dkflr ok;q esa ukbVªkstu dh lqij vkWDlkbM ds lkFk vfHkfØ;kA
(2) fu"dkflr ok;q esa ueh dh lqij vkWDlkbM ds lkFk vfHkfØ;kA
(3) fu"dkflr ok;q esa dkcZuMkbZvkWDlkbM dh lqij vkWDlkbM ds lkFk vfHkfØ;kA
(A) (1), (2) rFkk (3) (B*) dsoy (2) rFkk (3) (C) dsoy (2) (D) dsoy (1) rFkk (2)
Sol. (2) KO2 + 2H2O KOH + H2O2 + 1/2O2
(3) 4KO2 + 2CO2 2K2CO3 + 3O2
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.-25
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
DPPs BOOKLET-3 VIKAAS (JA) | CHEMISTRY
7. Statement-1 : Lithium is the most powerful reducing agent and sodium is the least powerful reducing
agent amongst the alkali metals in aqueous solutions.
Statement-2 : Lithium has the highest hydration enthalpy and the sodium the least value.
(A) Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1.
(B) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for Statement-1
(C*) Statement-1 is True, Statement-2 is False
(D) Statement-1 is False, Statement-2 is True
dFku-1 : tyh; foy;u esa] {kkjh; /kkrqvksa esa yhfFk;e lcls çcy vipk;d dkjd gS rFkk lksfM;e lcls nqcZy
vipk;d gSA
dFku-2 : yhfFk;e mPpre foyk;du ,UFkSYih j[krk gS rFkk lksfM;e] lcls deA
(A) dFku&1 lR; gS] dFku&2 lR; gS; dFku&2, dFku&1 dk lgh Li"Vhdj.k gSA
(B) dFku&1 lR; gS] dFku&2 lR; gS; dFku&2, dFku&1 dk lgh Li"Vhdj.k ugha gSA
(C*) dFku&1 lR; gS] dFku&2 vlR; gSA
(D) dFku&1 vlR; gS] dFku&2 lR; gSA
Sol. (i) E Li+/Li = –3.04 ; Na+ / Na = – 2.71 which is least among the alkali metals.
(ii) Hydration enthalpy / KJ mol–1
Li = – 506 ; Na = – 406 ; Cs has the least Hhyd = – 276
Sol. (i) E Li+/Li = –3.04 ; Na+ / Na = – 2.71 tks {kkjh; /kkrqvksa esa lcls de gSA
(ii) foyk;du ÅtkZ / KJ mol–1
Li = – 506 ; Na = – 406 ; Cs , Hfoyk;du = – 276 dk eku de j[krk gSA
8. Which of the following statements is not true about the dilute solutions of alkali metals in liquid
ammonia?
(A) They are deep blue coloured solutions.
(B) They are highly conducting in nature.
(C*) They are diamagnetic in nature.
(D) Ammoniated cation and solvated electron are formed in the solution.
nzo veksfu;k esa {kkjh; /kkrqvksa ds ruq foy;u ds fy, fuEu esa ls dkSulk dFku lR; ugha gS \
(A) ;g xgjs uhys jax dk foy;u gSA
(B) ;g izd`fr esa vR;f/kd pkyd gksrk gSA
(C*) ;g izd`fr esa izfrpqEcdh; gksrk gSA
(D) foy;u esa veksfud`r /kuk;u rFkk foy;hd`r bysDVªkWu curk gSA
Sol. M + (x + y)NH3 [M(NH3)x]+ + [e(NH3)y]–
It is paramagnetic due to the presence of the unpaired electrons
v;qfXer bysDVªkWu dh mifLFkfr ds dkj.k ;g izfrpqEcdh; gksrk gSA
9. Which of the following has the highest solubility in water ?
fuEu esa ls fdldh] ty esa foys;rk lokZfèkd gksrh gS \
(A) LiOH (B) KOH (C*) CsOH (D) RbOH
10. Which is correct order of ionic mobility in aqueous medium –
(A) Li(aq ) Na(aq ) Rb(aq )
(B) Al (3aq 2
) Mg ( aq ) Na( aq )
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.-26
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
DPPs BOOKLET-3 VIKAAS (JA) | CHEMISTRY
{kkjh; /kkrqvksa ds fy, fuEu ess ls dkSulk dFku vlR; gS \
(A) lHkh {kkjh; /kkrqvksa ds yo.k] cqUlsu Tokyk dks ,d ykf{.kd jax iznku djrs gaSA
(B) {kkjh; /kkrqvksa ds dkcksZusV ds rkih; LFkkf;Ro dk lgh c<+rk gqvk Øe Li2CO3 < Na2CO3 < K2CO3 < Rb2CO3
< Cs2CO3 gSA
(C) lHkh {kkjh; /kkrqvksa esa ls lhft+;e lokZfèkd fØ;k'khy gSA
(D*) lHkh xyr gSaA
12. HCl is added to following oxides. Which one would give H2O2?
HCl dks fuEu esa ls dkSuls vkWDlkbM esa feykus ij H2O2 izkIr gksrk gS ?
(A) MnO2 (B) PbO2 (C*) BaO2.8H2O (D) NO2
Sol. BaO2.8H2O + 2HCl BaCl2 + H2O2 + 8H2O
13. S1 : Plaster of paris is a hemihydrate of calcium sulphate obtained by heating the gypsum above 393 K.
S2 : Sodium carbonate is used in water softening.
S3 : The order of mobilities of the alkali metal ions in aqueous solutions is Li+ > Na+ > K+ > Rb+ > Cs+.
S1 : ftIle dks 393 K ds Åij xeZ djus ij dSfYl;e lYQsV dk gsehgkbMªsM izkIr gksrk gS] mls IykLVj vkWQ isfjl
dgrs gaSA
S2 : lksfM;e dkcksZusV dk mi;ksx] ty dks e`nw cukus esa fd;k tkrk gSA
S3 : tyh; foy;u esa {kkjh; /kkrq vk;u dh xfr'khyrk dk Øe Li+ > Na+ > K+ > Rb+ > Cs+ gSA
(A) T T F (B) T T T (C*) F T F (D) F F F
Sol. S1 : (2 CaSO4.2H2O) 2 (CaSO4). H2O + 3H2O ; above 393 K dead burnt plaster is obtained.
393 K
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.-27
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
DPPs BOOKLET-3 VIKAAS (JA) | CHEMISTRY
Ans. 6NaOH + 3Br2 5NaBr + NaBrO3 + 3H2O.
(iii) NaOH + S
Ans. 6NaOH + 4S 2Na2S + Na2S2O3 + 3H2O.
(iv) NaOH (hot & conc.) (xeZ rFkk lkUnz) + F2
Ans. 4NaOH + 2F2 4NaF + O2 + 2H2O.
(v) PbO + NaOH
Ans. PbO + 2NaOH Na2PbO2 + H2O
17. Match the compounds listed in column-I with the characteristic(s) listed in column-II.
Column-I Column-II
(A) BeO (s) (p) Amphoteric in nature
(B) NaHCO3 (crystalline) (q) Imparts characteristic colour to Bunsen flame.
(C) BeCl2(s) (r) Produce H2O2 and O2 on reaction with water.
(D) CsO2(s) (s) Shows hydrogen bonding
(t) Has a chain structure
LrEHk-I esa fn;s x;s ;kSfxdksa dks LrEHk-II esa fn;s x;s vfHky{k.kksa ds lkFk lqesfyr fdft,A
LrEHk-I LrEHk-II
(A) BeO (s) (p) mHk;/kehZ izo`fr
(B) NaHCO3 (fØLVyh;) (q) cqulsu Tokyk esa vfHkyk{k.khd jax n'kkZrs gSA
(C) BeCl2(s) (r) ty ds lkFk vfHkfØ;k dj H2O2 o O2 nsrs gSA
(D) CsO2(s) (s) gkbMªkstu ca/k n'kkZrs gSA
(t) J`a[kyk ljapuk j[krk gSA
Ans. (A – p) ; (B – q, s, t) ; (C – t) ; (D – q, r)
Sol. (A) BeO is amphoteric in nature becuase it reacts with acid as well as base.
(B) Hydrogen bonding; HCO3– ions are linked into an infinite chain through H-bonding.
(C)
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.-28
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
DPPs BOOKLET-3 VIKAAS (JA) | CHEMISTRY
Na2CO3 NaOH
(Castic-soda)
+ H2O Ca(OH)2
(slaked lime) 1 part slaked lime + 3 or 4 parts silica + water
SiO2
(mortar)
used as a building material
CaO
Quicklime Absorbs CO2 gas
CaCN2 + C
+ Coke N2 H2O
CaC2 (Nitrolium) NH3
Heated in electric use as a fertilizer
furnace at 20000C
H2O
C2H2
(Acetylene)
Memorize this theory as soon as you get the DPP. Revise it regularly and master this concept by practice.
Na2CO3 NaOH
(dkWfLVd&lksMk)
+ HO
2 Ca(OH)2
(cw>k pwuk) 1 Hkkx cw>k pwuk + 3 ;k 4 Hkkx flfydk + ty
SiO2
(eksVkZV)
bldk mi;ksx Hkou fuekZ.k djus okys
inkFkksZ esa fd;k tkrk gSA
CaO
(fcuk cw>k CO2 xSl dk vo’kks"k.k
gqvk pwuk)
CaCN2+ C
+ dksd N2 HO
CaC2 (ukbZVªkfs y;e) 2
NH3
2000ºC rki ij oS|qr moZjd dh rjg iz;qDRk
HkV~Vh esa xeZ djuk
HO
2
C2H2
¼,sflfVyhu½
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.-29
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
DPPs BOOKLET-3 VIKAAS (JA) | CHEMISTRY
Memorize this theory as soon as you get the DPP. Revise it regularly and master this concept by practice.
19. What will obtained when slaked lime react with Na2CO3 ?
fuEu esa ls dkSulk mRikn izkIr gksrk gS tc cw>s gq,s pwus dh vfHkfØ;k Na2CO3 ds lkFk djkrs gS ?
(A) Na2O2 (B*) NaOH (C) NaNH2 (D) NaNO3
P / I-CHEMISTRY
EST INFORM AT IO
DPP
DAILY PRACTICE PROBLEMS
ANSWER KEY
1. (B) 2. (B) 3. (B) 4. (C) 5. (D) 6. (C) 7.* (AB)
8.* (ACD) 9.* (AB) 10.* (ABC) 11. 5 12. 4 13. 4 14. 1
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.-30
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
DPPs BOOKLET-3 VIKAAS (JA) | CHEMISTRY
2. The function of fluorspar in the electrolytic reduction of alumina dissolved is fused cryolite (Na 3AlF6) is
(A) as a catalyst
(B*) to lower the temperature of the melt and to make the fused mixture very conducting
(C) to decrease the rate of oxidation of carbon at the anode
(D) none of these above
laxfyr Øk;ksykbV (Na3AlF6) esa ?kqfyr ,sY;qfeuk ds oS|qr vi?kVuh; viPk;u esa ¶yksjLikj dk dk;Z gksrk gSA
(A) mRizsjd ds :i esa gSA
(B*) xfyr dk rki de djuk rFkk laxfyr feJ.k dks vfrpkyd cukuk
(C) ,uksM+ ij dkcZu dh vkWDlhdj.k dh nj dks ?kVkuk
(D) buesa ls dksbZ ugha
3. Aqueous solution of potash alum is :
(A) alkalline (B*) acidic (C) neutral (D) soapy
iksVk'k ,sye~ dk tyh; foy;u fuEu gksrk gS %
(A) {kkjh; (B*) vEyh; (C) mnklhu (D) lkcquhd`r
Sol. It is acidic because of the hydrolysis of Al2(SO4)3 according to the following reaction.
Al2 (SO4)3 + 6H2O 2Al(OH)3 + 3H2SO4.
gy- fuEufyf[kr vfHkfØ;k ds vuqlkj Al2(SO4)3 ds ty vi?kVu ds dkj.k ;g vEyh; gSA
Al2 (SO4)3 + 6H2O 2Al(OH)3 + 3H2SO4.
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.-31
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
DPPs BOOKLET-3 VIKAAS (JA) | CHEMISTRY
8.* Which of the following can produce B2O3 ?
(A*) Heating borax with conc. H2SO4 (B) Passing CO2 through aq. NaBO2
(C*) Combustion of diborane, B2H6. (D*) Warming H3BO3 crystals till red hot.
fuEu esa ls dkSu B2O3 dks mRikfnr dj ldrk gS\
(A*) lkUnz H2SO4 ds lkFk cksjsDl dks xeZ dj (B) tyh; NaBO2 esa ls CO2 izokfgr dj
(C*) Mkbcksjsu, B2H6 dk ngu dj (D*) H3BO3 fØLVy dks yky rIr rd xeZ djds
9.* Which of the following are correct about B2H6 ?
(A*) each ‘B’ atom is sp3 hybridised
(B*) It consists of two-”3 centre 2 electron bonds”
(C) The two bridging H-atoms are in the plane of the molecules
(D) All of these
B2H6 ds ckjs esa fuEu esa ls lgh gS \
(A*) izR;sd ‘B’ ijek.kq sp3 ladfjr voLFkk esa gSA (B*) blesa nks] rhu dsUnz-nks-bysDVªkWu cU/k gksrs gSaA
(C) nks lsrq H-ijek.kq v.kq ds ry esa gh gksrs gSaA (D) mijksDr lHkh
Sol. ‘A’ and ‘B’ are correct on the basis of structure of B2H6.
B2H6 dh lajpuk ds vk/kkj ij ‘A’ o ‘B’ lgh gSaA
10.* Which of the following hydrides react with water ?
fuEu esa ls dkSuls gkbMªkbM ty ds lkFk vfHkfØ;k djrs gS \
(A*) B2H6 (B*) NH3 (C*) NaH (D) C2H6
Sol. B2H6 + H2O H3BO3 + H2
NH3 + H2O NH4OH
NaH + H2O NaOH + H2
C2H6 + H2O no reaction. vfHkfØ;k ugha gksrhA
11. In borax ion how many B–O–B bonds present :
cksjsDl vk;u esa fdrusa B–O–B caèk gS %
Ans. 5
12. In diborane maximum how many 2c – 2e bonds present :
MkbZcksjsu esa vf/kdre fdrus 2c – 2e caèk gS %
Ans. 4
13. How many oxides in the following are basic in water:
fuEu esa ls fdrus vkWDlkbM ty esa {kkjh; gksrs gS %+
B2O3, Al2O3, CO2, SO2, NO2, CaO, Na2O, K2O, Cs2O, CaO
Ans. 4
14. Basicity of H3BO3 is
H3BO3 dh {kkjdrk gS %
Ans. 1
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.-32
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
DPPs BOOKLET-3 VIKAAS (JA) | CHEMISTRY
P / I-CHEMISTRY
EST INFORM AT IO
DPP
DAILY PRACTICE PROBLEMS
O = Oxygen
= Silicon
O O
(A) SiO44– & Si3O88– (B*) SiO44– & Si3O108– (C) SiO42– & Si3O92– (D) SiO34– & Si3O108–
(A) SiO44– o Si3O88– (B*) SiO44– o Si3O108– (C) SiO42– o Si3O92– (D) SiO34– o Si3O108–
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.-33
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
DPPs BOOKLET-3 VIKAAS (JA) | CHEMISTRY
5. Which one of the following oxides is neutral ?
fuEu esa ls dkSulk mnklhu vkWDlkbM gS \
(A*) CO (B) SnO2 (C) ZnO (D) SiO2
7. Which gas is formed when CaC2 is allowed to react with dilute HCl ?
(A) Ethane (B) Ethene (C*) Ethyne (D) Methane
tc CaC2 dks ruq HCl ds lkFk vfHkd`r fd;k tkrk gS] rks dkSulh xSl curh gS \
(A) ,sFksu (B) ,Fkhu (C*) ,Fkkbu (D) esFksu
Sol. CaC2 + 2HCl CaCl2 + HCCH
Ethyne
,Fkkbu
8. Which of the following oxidation states are the most characterstics for lead and tin, respectively ?
ySM o fVu ds fy, fuEu esa ls dkSulh vkWDlhdj.k voLFkk Øe'k% lokZf/kd :i ls vfHkyk{kf.kd gSa \
(A*) + 2 , + 4 (B) + 4 , + 4 (C) + 2 , + 2 (D) + 4 , + 2
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.-34
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
DPPs BOOKLET-3 VIKAAS (JA) | CHEMISTRY
P / I-CHEMISTRY
EST INFORM AT IO
DPP
DAILY PRACTICE PROBLEMS
ANSWER KEY
1. (A) 2. (B) 3. (D) 4. (A) 5. (B)
6. (A) 7. (C) 8. (B) 9. (C) 10. (C)
11.* (BCD) 12. 49 13. 42 14. 10 15. 17
16. 56 17. 36 18. 19
1. If for reaction N2 (g) + 3H2 (g) 2NH3 (g), H1º = – 30 kJ/mole at temperature 300 K and if specific
heat capacities of different species are sP, N2 = 1 J/gºC, sP, H2 = 10 J/gºC and sP, NH3 = 2 J/g ºC, then
H2º at 400 K for the same reaction will be : (assume heat capacities to be constant in given
temperature range)
;fn vfHkfØ;k N2 (g) + 3H2 (g) 2NH3 (g) ds fy, 300 K rki ij H1º = – 30 kJ/mole gS rFkk ;fn fofHkUu
Lih'kht dh fof'k"V Å"ek /kkfjrk,¡ sP, N2 = 1 J/gºC, sP, H2 = 10 J/gºC rFkk sP, NH3 = 2 J/g ºC gSa] rks leku
vfHkfØ;k ds fy, 400 K ij H2º fuEu gksxk % (nh gqbZ rki ijkl esa Å"ek /kkfjrk,¡ fu;r ekfu,)
(A*) – 32 kJ/mole (B) – 28 kJ/mole (C) – 32.7 kJ/mole (D) – 27.3 kJ/mole
Sol. H02 = [–30 kJ/mole] + [{2 × 2 × 17 – 28 – 3 × 2 × 10} (100) J/mole]
= (–30 kJ/mole) + (–2000 J/mole) = –32 kJ/mole.
2. A sample contain Fe2(SO4)3, FeSO4 and impurities. A 600 g sample contains 48 g impurities and equal
moles of Fe2(SO4)3 and FeSO4. The % of Fe2(SO4)3 in the mixture is :
(A) 33.33% (B*) 66.7% (C) 83.33% (D) none of these
,d uewus esa Fe2(SO4)3, FeSO4 rFkk v'kqf);k¡ fo|eku gSaA 600 xzke uewus esa 48 xzke v'kqf) rFkk Fe2(SO4)3 ,oe~
FeSO4 ds cjkcj eksy ik;s tkrs gaSA vr%] bl feJ.k esa Fe2(SO4)3 dk izfr'kr fuEu gS&
(A) 33.33% (B*) 66.7% (C) 83.33% (D) buesa ls dksbZ ugha
3. What volume of air at STP containing 21% of oxygen by volume is required to completely burn sulphur
(S8) present in 200 g of sample, which contains 20% inert material which does not burn. Sulphur burns
1
according to the reaction: S8 (s) + O2 (s) SO2 (s)
8
(A) 23.52 litre (B) 320 litre (C) 112 litre (D*) 533.33 litre
ok;q] tks vk;ru dk 21% vkWDlhtu ;qDr gSa STP ij] bldk vk;ru D;k gSa tcfd ;g 200 g izkn'kZ esa mifLFkr
lYQj (S8) dks iw.kZ :i ls tykus ds fy, vko';d gksa] tks fd 20% vfØ; inkFkZ j[krk gSa tks fd ugha tyk;k
1
tkrk gSaA fuEu vfHkfØ;k ds vuqlkj lYQj tyk;k tkrk gSa % S8 (s) + O2 (s) SO2 (s)
8
(A) 23.52 yhVj (B) 320 yhVj (C) 112 yhVj (D*) 533.33 yhVj
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.-35
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
DPPs BOOKLET-3 VIKAAS (JA) | CHEMISTRY
5. If the density of a gas sample is 4 g/L at pressure 1.2 105 Pa, the value of vrms will be :
;fn 2 105 Pa nkc ij xSl ds ,d uewus dk ?kuRo 4 g/L gks] rks vrms dk eku fuEu gksxk %
(A) 600 m/s (B*) 300 m/s (C) 150 m/s (D) 450 m/s
3RT 3P 3 1.2 105
Sol. vRMS = = = = 300 m/s
M 4
6. A 4 : 1 molar ratio mixture of helium and methane is contained in a vessel at 10 bar pressure. Due to a
hole in the vessel, the gas mixture leaks out. The molar ratio composition of the mixture effusing out
initially is :
10 bar nkc ij ,d ik=k esa ghfy;e o esFksu ds 4 : 1 eksyj vuqikr okys feJ.k dks j[kk tkrk gSA ik=k esa fNnz gksus
ds dkj.k xSlh; feJ.k dk fjlko gksrk gSA izkjEHk esa fulfjr gksus okys feJ.k dk eksyj vuqikr laxBu fuEu gS %
(A*) 8 : 1 (B) 16 : 1 (C) 32 : 1 (D) 6 : 1
Sol. Pressure of helium = 8 bar
Pressure of CH4 = 2 bar
rHe P MCH4 8 16 8
= 1 = = =8:1
rCH4 P2 MHe 2 4 1
gy- ghyh;e dk nkc = 8 bar
CH4 dk nkc = 2 bar
rHe P MCH4 8 16 8
= 1 = = =8:1
rCH4 P2 MHe 2 4 1
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.-36
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
DPPs BOOKLET-3 VIKAAS (JA) | CHEMISTRY
(A) HF and HF (B*) HF and HS– (C) HS– and HF (D) HS– and CH3COOH
dqN vEyksa dks muds lEcaf/kr lkE; fLFkjkadksa ds vk/kkj ij uhps lwphc) fd;k x;k gS %
HF(aq) + H2O() H3O+ (aq) + F (aq) Ka = 7.2 × 104
HS(aq) + H2O() H3O+ (aq) + S2 (aq) Ka = 1.3 × 1011
CH3COOH(aq) + H2O() H3O+(aq) + CH3COO (aq) Ka = 1.8 ×105
çcyre vEy dkSulk gS rFkk dkSulk vEy] çcyre la;qXeh {kkj j[krk gS \
(A) HF rFkk HF (B*) HF rFkk HS– (C) HS– rFkk HF (D) HS– rFkk CH3COOH
Ans. Strongest acid HF; weakest acid HS— and weakest acid (HS—) has the stongest conjugate base.
çcyre vEy HF; nqcZy vEy HS— rFkk nqcZyre vEy (HS—) çcyre la;qXeh {kkj j[krk gSA
9. Several bases are listed below with their respective Kb values :
NH3(aq) + H2O () NH4+(aq) + OH– (aq). Kb = 1.8 × 105
C5H5N(aq) + H2O () C5H5NH+(aq) + OH(aq). Kb = 1.5 × 109
N2H4(aq) + H2O() + –
N2H5 (aq) + OH (aq). Kb = 8.5 × 107
Which is the weakest base and which base has the weakest conjugate acid ?
(A) C5H5N and C5H5N (B) NH3 and NH3 (C*) C5H5N and NH3 (D) NH3 and N2H4
dqN {kkjksa dks muds lEcfU/kr lkE; fLFkjkadksa (Kb) ds ekuksa ds vk/kkj ij] uhps lwphc) fd;k x;k gS %
NH3(aq) + H2O () NH4+(aq) + OH– (aq). Kb = 1.8 × 105
C5H5N(aq) + H2O () C5H5NH+(aq) + OH(aq). Kb = 1.5 × 109
N2H4(aq) + H2O() N2H5+(aq) + OH– (aq). Kb = 8.5 × 107
nqcZyre {kkj dkSulk gS rFkk dkSulk {kkj nqcZyre la;qXeh vEy j[krk gS \
(A) C5H5N rFkk C5H5N (B) NH3 rFkk NH3 (C*) C5H5N rFkk NH3 (D) NH3 rFkk N2H4
Ans. strongest base NH3 ; weakest base C5H5N and NH3 has the weakest conjugate acid.
çcyre {kkj NH3 ; nqcZyre {kkj C5H5N rFkk NH3 nqcZyre la;qXeh vEy j[krk gSA
10. What is the Kb of a weak base that can produce one OH ion per molecule, if its 0.04 M solution is 2.5%
ionized :
;fn ,d nqcZy {kkj dk 0.04 M foy;u 2.5% vk;fur gksrk gS] rFkk blds çfr v.kq ls ,d OHmRiUu gksrk gS] rc
nqcZy {kkj dk Kb D;k gksxk %
(A) 2.5 × 104 (B) 2.5 × 106 (C*) 2.5 × 105 (D) 2.5 × 107
11.* For which one of the following equation Hºr not equal to Hºƒ for the product ?
fuEu esa ls fdl vfHkfØ;k ds fy, Hº vfHkdkjd dk eku] mRIkkn ds fy, Hºƒ ds cjkcj ugha gSa %
(A) Xe(g) + 2F2(g) XeF4(g) (B*) 2CO(g) + O2(g) 2CO2(g)
(C*) N2(g) + O3(g) N2O3(g) (D*) CH4(g) + 2Cl2(g) CH2Cl2() + 2HCl(g)
Sol. When one mole of a substance is directly formed from its constituent elements, then the enthalpy
change is called heat of formation.
tc ,d inkFkZ dks ,d eksy blds vkilh rRoksa ls lh/ks curk gS] rks ,UFkSYih ifjorZu dks lEHkou dh Å"ek dgrs gSaA
For the reaction vfHkfØ;k ds fy,
Xe (g) + 2F2 (g) XeF4 (g)
1 mol
H°react = H°f
12. From the following bond energy and standard Hº values for the formation of elements in gaseous
state, calculate the standard enthalpy of formation (in kCal/mol) of acetone(g) :
xSlh; voLFkk esa rRoksa ds fuekZ.k ds fy, ekud Hº ,oa ca/k ÅtkZ ds eku uhps fn;s x;s gSaA buls ,lhVksu(g) ds
laHkou dh ekud ,UFkSYih dh x.kuk (kCal/mol esa) dhft,A
Standard Hº Bond energies
ekud Hº ca/k ÅtkZ
H (g) = 52 kCal/mol C H = 99 kCal/mol
O (g) = 59 kCal/mol C C = 80 kCal/mol
C (g) = 171kCal/mol C = O = 81 kCal/mol
Ans. 49
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.-37
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
DPPs BOOKLET-3 VIKAAS (JA) | CHEMISTRY
13. Given the following standard enthalpies of reaction :
(i) Enthalpy of formation of water = 68.3 kCal/mol
(ii) Enthalpy of combustion of acetylene = 310.6 kCal/mol
(iii) Enthalpy of combustion of ethylene = 337.2 kCal/mol
Calculate the heat of reaction for the hydrogenation of acetylene into ethylene (in kCal/mol) at constant
pressure.
Report your answer in terms of magnitude, rounding it off to the nearest whole number.
uhps dqN vfHkfØ;kvksa ds fy, vfHkfØ;k dh ekud ,UFkSfYi;ksa ds eku fn;s x;s gSa %
(i) ty dh laHkou ,UFkSYih = 68.3 kCal/mol
(ii) ,flfVyhu ds ngu dh ,UFkSYih = 310.6 kCal/mol
(iii) ,Fkhyhu ds ngu dh ,UFkSYih = 337.2 kCal/mol
fu;r nkc ij ,flfVyhu ds ,fFkyhu esa gkbMªkstuhdj.k dh Å"Ekk dk eku (kCal/mol esa) Kkr dhft,A
viuk mÙkj ifjek.k ds :i esa fudVre iw.kk±d esa nhft;sA
Ans. 42
14. Estimate rH (in kJ) for 2C4H10(g) C8H18(g) + H2(g). Given bond energy of CC and CH are 347
and 441 kJmol1. The enthalpy of formation of H(g) atom is 217.5 kJmol 1. Report your answer after
dividing by 10.
2C4H10(g) C8H18(g) + H2(g) vfHkfØ;k ds fy,] rH dk eku (kJ esa) Kkr dhftc,A CC rFkk CH ca/k dh
ca/k ÅtkZvksads eku Øe'k% 347 rFkk 441 kJmol1 fn;s x;s gSaA H(g) ijek.kq dh laHkou ,UFkSYih dk eku 217.5
kJmol1 gSA viuk mÙkj 10 ls Hkkx nsdj nhft,A
Ans. 10
15. Using the data (all values are in kilocalories per mole at 25ºC) given below, calculate the bond energy
of CH and CC bonds.
Hºcombustion (ethane) g = 372 ; Hºcombustion (propane) g = 530
Hº for C(graphite) C (g) = 172 ; Bond energy of HH bond = 104
Hfº of H2O(l) = 68 ; Hfº of CO2 (g) = 94
Report your answer as the difference of two values.
uhps fn;s x;s vk¡dM+kas (25ºC ij lHkh eku] fdyksdSykjh izfr eksy esa fn;s x;s gaS) dk mi;ksx djrs gq,] CH rFkk
CC caèk dh ca/k ÅtkZvksa dh x.kuk dhft,A
Hºngu¼,Fksu½ g = 372 ; Hº ngu ¼izksisu½ g = 530
Hº for C (xzsQkbV) C (g) = 172 ; HH ca/k dh ca/k ÅtkZ = 104
H2O(l) ds fy, Hfº = 68 ; CO2 (g) ds fy, Hfº = 94
viuk mÙkj nksuksa ekuksa ds vUrj ds :i esa nhft,A
Ans. 17
16. Determine the standard enthalpy change of the reaction: C 3H8(g) + H2(g) C2H6(g) + CH4(g), using
the given enthalpy of combustion values under standard conditions :
Compound H2 (g) CH4 (g) C2H6 (g) C (graphite)
Hº (kJ/mole) 286 890 1560 393.5
The standard enthalpy of formation of C3H8 (g) is 104 kJ/mol. Report your answer in terms of
magnitude, rounding it off to the nearest whole number.
C3H8(g) + H2(g) C2H6(g) + CH4(g) vfHkfØ;k ds fy,] ekud ,UFkSYih ifjorZu dh x.kuk dhft,A ekud
ifjfLFkfr ds vUrxrZ ngu ,UFkSfYi;ksa ds eku fn;s x;s gSa %
;kSfxd H2 (g) CH4 (g) C2H6 (g) C (xzsQkbV)
Hº (kJ/mole) 286 890 1560 393.5
C3H8(g) dh ekud laHkou ,UFkSYih dk eku 104 kJ/mol gSA viuk mÙkj ifjek.k ds :i esa fudVre iw.kk±d esa
nhft;sA
Ans. 56
17. The standard molar enthalpies of formation of cyclohexane () and benzene () at 25°C are –156 and
+49 KJ mol–1 respectively. The standard enthalpy of hydrogenation of cyclohexene () at 25°C is
–119 KJ mol–1. Use these data to estimate the resonance energy of benzene in KCal mol–1. Report your
answer in terms of magnitude, rounding it off to the nearest whole number.
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.-38
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
DPPs BOOKLET-3 VIKAAS (JA) | CHEMISTRY
25°C rki ij lkbDyksgSDlsu () rFkk csUthu () ds lEHkou dh ekud eksyj ,UFkSYih Øe'k% –156 rFkk +49 KJ
mol–1 eksy gSA 25°C ij lkbDyksgSDlsu () dh gkbMªkstuhdj.k dh ekud ,UFkSYih –119 KJ mol–1 gSA mDr vk¡dM+ksa
dh lgk;rk ls csUthu dh vuquknh ÅtkZ dh KCal mol–1 esa x.kuk dhft;sA viuk mÙkj ifjek.k ds :i esa fudVre
iw.kk±d esa nhft;sA
Ans. 36
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.-39
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
DPPs BOOKLET-3 VIKAAS (JA) | CHEMISTRY
P / I-CHEMISTRY
EST INFORM AT IO
DPP
DAILY PRACTICE PROBLEMS
ANSWER KEY
1. (C) 2. (B) 3. (A) 4. (C) 5. (B)
6. (C) 7. (B) 8. (B) 9.* (AC) 10.* (ACD)
11.* (BCD) 12.* (ABCD) 13. (C) 14. 8 15. 50
16. (C) 17. (D) 18. (B) 19. (C)
1. Select the correct statement :
(A) Na2HPO3 is an acid salt.
(B) Water acts as a base, when ammonia is dissolved in it.
(C*) All aqueous solutions, whether neutral, acidic or basic, contain both H + & OH ions.
(D) All of these
lR; dFku dk p;u dhft, %
(A) Na2HPO3 ,d vEyh; yo.k gSA
(B) ty ,d {kkj ds :i esa dk;Z djrk gSa tc bles veksfu;k ?kksyh tkrh gSA
(C*) lHkh tyh; foy;u] pkgs mnklhu] vEyh; vFkok {kkjh; gksa] H+ rFkk OH nksuksa vk;u ;qDr gksrs gSaA
(D) mijksDÙk lHkh
2. Aqueous solution of CuSO4 is ______ due to the hydrolysis of ______ ions.
(A) acidic, SO42– (B*) acidic, Cu2+ (C) basic, Cu2+ (D) basic, SO42–
_______ vk;u ds ty&vi?kV~u ds dkj.k CuSO4 dk tyh; foy;u ______ gksrk gSA
(A) SO42–, vEyh; (B*) Cu2+, vEyh; (C) Cu2+, {kkjh; (D) SO42–, {kkjh;
Sol. 2+
[Cu(H2O)6] + H2O +
[Cu(H2O)5(OH)] + H3O +
3. NH4Cl (aq) is :
(A*) acidic due to NH4+ (B) acidic due to Cl– (C) basic due to NH4+ (D) basic due to Cl–
NH4Cl ¼tyh;½ :
(A*) NH4+ ds dkj.k vEyh; gS (B) Cl– ds dkj.k vEyh; gS
(C) NH4+ ds dkj.k {kkjh; gS (D) Cl– ds dkj.k {kkjh; gS
4. Which of the following salts does not undergo hydrolysis :
fuEu esa ls dkSuls yo.k dk ty vi?kVu ugha gksrk gS %
(A) CH3COONH4 (B) FeCl3.6H2O (C*) KCl (D) KCN
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.-40
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
DPPs BOOKLET-3 VIKAAS (JA) | CHEMISTRY
6. In which of the following cases, the aqueous solution is not basic :
I. BeCl2 II. LiCN III. (NH4)2C2O4 IV. C5H6NBr V. NaF
(A) II & V only (B) I & IV only (C*) I, III & IV (D) I & III Only
fuEu esa ls dkSulk tyh; foy;u {kkjh; ugha gS %
I. BeCl2 II. LiCN III. (NH4)2C2O4 IV. C5H6NBr V. NaF
(A) dsoy II rFkk V (B) dsoy I rFkk IV (C*) I, III rFkk IV (D) dsoy I rFkk III
7. The self ionization constant for pure formic acid, K = [ HCOOH 2+ ] [HCOO] has been estimated as 10
6
at room temperature.The density of formic acid is 1.15 g/cm 3. The percentage of formic acid
converted to formate ion is :
dejs ds rki ij 'kq) QkWfeZd vEy ds fy, Lor% vk;uu fLFkjkad K = [ HCOOH2+ ][HCOO] dk eku 10 6
ifjdfyr fd;k x;k gSA QWkfeZd vEy dk ?kuRo 1.15 g/cm3 gSA QWkfeZd vEy dk fdruk çfr'kr QkWesZV vk;u esa
ifjofrZr gS \
(A) 0.002 % (B*) 0.004 % (C) 0.006 % (D) 0.008 %
Sol. K = [HCOOH2+] [HCOO–] = 10–6.
[HCOO–] = 10–3 mol/L.
1 liter solution of HCOOH has = 1150 g mass.
HCOOH dk ,d yhVj foy;u = 1150 xzke æO;eku j[krk gSA
1150
moles of (HCOOH) in 1 litre solution = = 25 mol.
46
,d yhVj foy;u esa (HCOOH) ds eksy = 1150 = 25 mol.
46
out of 25 mol HCOOH 10–3 mol are ionised into HCOO– ions.
25 mol HCOOH esa ls 10–3 mol HCOO– vk;u esa vk;fur gksxsa
10 –3
% dissociation (izfr'kr fo;kstu) = × 100 = 0.004%
25
8. Match the following forms of Vander waal’s equation for 1 mole of a real gas with given conditions :
(a) high pressure (i) PV = RT + Pb
(b) low pressure (ii) PV = RT – a/V
(c) force of attraction between gas molecules is negligible (iii) PV = RT + a/V
(d) volume of gas molecules is negligible (iv) PV = RT – Pb
(a) mPp nkc (i) PV = RT + Pb
(b) fuEu nkc (ii) PV = RT – a/V
(c) xSl v.kqvksa ds e/; vkd"kZ.k dk cy ux.; gS (iii) PV = RT + a/V
(d) xSl v.kqvksa dk vk;ru ux.; gS (iv) PV = RT – Pb
(A) (a) (i), (b) (ii), (c) (iv), (d) (iii) (B*) (a) (i), (b) (ii), (c) (i), (d) (ii)
(C) (a) (iii), (b) (iv), (c) (iv), (d) (iii) (D) (a) (iii), (b) (iv), (c) (i), (d) (ii)
9.* When wave length of a small moving particle is equal to four times the distance travelled in one second
then
tc ,d NksVs xfreku d.k dh rjax }S/;Z] mlds }kjk ,d lsd.M esa r; dh xbZ nwjh dh pkj xquk gks rks rjax}S/;Z
dk eku gksxkA
h h h h
(A*) (B) (C*) 2 (D)
mv m m p
h
Sol. =
mV
= 4V
V=
4
h
2 =
m
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.-41
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
DPPs BOOKLET-3 VIKAAS (JA) | CHEMISTRY
h
=2
m
Passage #
Relative strengths of conjugate acid base pairs :
HCIO 4 CIO4 – very weak bases
Strong acids
HCI CI– Negligible tendency
Stronger acid 100% dissociated Weaker base
– to be protonated in
H2SO 4 HSO4
in aqueous solution
HNO3 NO3 –
aqueous solution
H3O+ H2O
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.-42
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
DPPs BOOKLET-3 VIKAAS (JA) | CHEMISTRY
SO24
HSO 4
H2PO4
H3PO 4
NO2
HNO2
HF F
Weak acids Weak bases
CH3COOH CH3CO2
Exist in solution as Moderate tendency
H2CO3 HCO3
a mixtureof HA to be protonated
H2S HS
A ,and H3O in aqueous solution
NH4 NH3
HCN CN
HCO3 CO32
H2O
OH
H3O+ H2O
SO24
HSO 4
H2PO4
H3PO 4
NO2
HNO2
HF nqcZy vEy F
CH3COOH foy;u esa] HA CH3CO2 nqcZy {kkj tyh; foy;u
H2CO3
A rFkk H3O ds HCO3 esa izksVksuhd`r gksus dh
H2S feJ.k ds :i esa HS izo`fÙk lkekU;
NH4 mifLFkr gksrs gS NH3
HCN CN
HCO3 2
CO3
H2O OH
20 atm
A B
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.-44
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
DPPs BOOKLET-3 VIKAAS (JA) | CHEMISTRY
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.-45
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
DPPs BOOKLET-3 VIKAAS (JA) | CHEMISTRY
17. Select the correct statement :
(A) NH3 is a differentiating solvent for acids (B) H2O is a differentiating solvent for bases
(C) CH3COOH is a leveling solvents for acids (D*) CH3COOH is a differentiating solvent for acids
lgh dFku dk p;u dhft, %
(A) vEyksa ds fy, NH3 fo"kevk;uu foyk;d gSA
(B) {kkjksa ds fy, H2O fo"kevk;uu foyk;d gSA
(C) vEyksa ds fy, CH3COOH levk;uu foyk;d gSA
(D*) vEyksa ds fy, CH3COOH fo"kevk;uu foyk;d gSA
18. Acidic strength of HClO4 is more than HCl when :
(A) H2O is used as a solvent. (B*) CH3COOH is used as a solvent.
(C) NH3 is used as a solvent. (D) None of these.
HClO4 dh vEyh; lkeF;Zrk] HCl ls vf/kd gksxh %
(A) H2O foyk;d dh Hkk¡fr ç;qDr gksxkA (B*) CH3COOH foyk;d dh Hkk¡fr ç;qDr gksxkA
(C) NH3 foyk;d dh Hkk¡fr ç;qDr gksxkA (D) buesa ls dksbZ ugaha
19. Select the incorrect statement:
(A) H3O+ is the strongest acid in water.
(B) Bases stronger than water are leveling solvent for acids.
(C*) Bases weaker than water are leveling solvent for acids.
(D) Bases weaker than water are differentiating solvent for acids.
xyr dFku dk p;u dhft, %
(A) H3O+ ty esa çcyre vEy gSA
(B) vEyksa ds fy,] ty ls çcy {kkj levk;uu foyk;d gSaA
(C*) vEyksa ds fy,] ty ls nqcZy {kkj levk;uu foyk;d gSaA
(D) vEyksa ds fy,] ty ls nqcZy {kkj fo"kevk;uu foyk;d gSaA
P / I-CHEMISTRY
EST INFORM AT IO
DPP
DAILY PRACTICE PROBLEMS
ANSWER KEY
1. (B) 2. (A) 3. (B) 4. (A) 5. (B)
6. (B) 7. (B) 8. (D) 9. (D) 10. (D)
11. (C) 12. (D) 13.* (AD) 14.* (ABD) 15. 6
16. pH = 6.39 17. (A) - (p, q, s) ; (B) - (p, r) ; (C) - (p, r, s) ; (D) - (q, s)
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.-46
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
DPPs BOOKLET-3 VIKAAS (JA) | CHEMISTRY
1. Solution containing 0.1 N NH4OH and 0.1 N NH4Cl has pH = 9.25.Then find out pKb of NH4OH.
0.1 N NH4OH o 0.1 N NH4Cl ;qDr foy;u dh pH = 9.25 gSA rc NH4OH dk pKb Kkr dhft;sA
(A) 9.25 (B*) 4.75 (C) 3.75 (D) 8.25
NH4 Cl
Sol. pOH = pKb + log
NH4 OH
0.1
14 – 9.25 = pKb + log pKb= 4.75.
0.1
2. Both conc. being 1 M, the factor by which the percent hydrolysis of CH 3COO– is greater in CH3COONH4
than in CH3COONa is (Ka (CH3COOH) = Kb (NH4OH)).
nksuksa dh lkanzrk 1 M gS fdl dkjd (xq.kkad) ls CH3COO¯ dk ty vi?kVu CH3COONa dh rqyuk esa
CH3COONH4 esa vf/kd gSA (Ka (CH3COOH) = Kb (NH4OH)) .
(A*) 236 (B) 136 (C) 36 (D) 3
3. Calculate the pH of a 0.1 M K3PO4 solution. The third dissociation constant of phosphoric acid is 10 –12.
Given (0.41)1/2 = 0.64 ; log 3 = 0.48
0.1 M K3PO4 foy;u ds pH dh x.kuk dhft;s \ QkWLQksjhd vEy dk r`rh; fo;kstu fu;rkad ()10–12 gSA
fn;k gS (0.41)1/2 = 0.64 ; log 3 = 0.48
(A) 12.5 (B*) 12.44 (C) 12.25 (D) 12
Kw 10 14
Sol. Kh = = = 10–2
K a3 10 12
Ch 2
Kh =
(1 h)
Kh 10 2
as 1 – h = 1, h = = = 0.316
C 0.1
as h > 0.1 1 – h 1
101 h 2
10–2 = or 0.1 (1 – h) = h2
(1 h )
or, 0.1 – 0.1 h = h2
or, h + 0.1 h – 0.1 = 0
0.1 (0.1)2 4 0.1
or, h = = 0.27
2
as, PO43– + H2O HPO42– + OH–
c(1 – h) ch ch
[OH–] = ch
= 0.1 0.27
= 27 10–3
pOH = 3 – log 27 = 3 log33 = 3 – 3 log 3
= 3 – 3 0.48
= 1.56
pH = 14 – 1.56 = 12.44
4. Two pairs of salts are given, each in 0.1M aqueous solution. Which solution has a higher pH ? The
strength of acids is HF > HOCl > HOBr > HCN.
(A*) NaCN and NaOBr (B) NaF and NaOCl (C) NaF and NaOBr (D) NaCN and NaOCl
yo.kksa ds nks ;qXe fn;s x;s gSa ftuesa izR;sd dh lkUnzrk 0.1 M gS] fuEu esa ls fdl foy;u dk pH mPpre gS \
vEyksa dh lkEFkZ; dk Øe HF > HOCl > HOBr > HCN gSA
(A*) NaCN rFkk NaOBr (B) NaF rFkk NaOCl (C) NaF rFkk NaOBr (D) NaCN rFkk NaOCl
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.-47
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
DPPs BOOKLET-3 VIKAAS (JA) | CHEMISTRY
5. Choose the correct statement(s) :
(A) pH of acidic buffer solution decrease if more salt is added.
(B*) pH of basic buffer solution increases if more base is added.
(C) Both (A) and (B)
(D) None of these
lgh dFku pqfu;s %
(A) ;fn yo.k dh ek=kk c<+k;h tk;s] rks vEyh; cQj foy;u dh pH ?kVrh gSA
(B*) ;fn {kkj dh ek=kk c<+k;h tk;s] rks {kkjh; cQj dh pH c<+rh gSA
(C) (A) o (B) nksuksaA
(D) buesa ls dksbZ ughaA
[Salt]
Sol. (A) is incorrect because pH = pKa + log for acidic buffer.
[Acid]
If [Salt] increases, pH of acidic buffer will increase.
[Salt]
(B) is correct because pOH = pKb + log for basic buffer.
[Base]
If [Base] increases, pOH will decrease, pH will increase as pH = 14 – pOH.
[ yo.k ]
gy- (A) xyr gS D;kasfd vEyh; cQj ds fy, pH = pKa + log .
[ vEy]
;fn [yo.k] esa o`f} gksrh gS] rks vEyh; cQj dk pH esa o`f} gksxh.
[ yo.k ]
(B) lgh gS D;kasfd {kkjh; cQj ds fy, pOH = pKb + log .
[{kkj ]
;fn [{kkj] eas o`f} gksrh gS rks, pOH esa deh gksxh o pH esa o`f) gksxh D;kasfd pH = 14 – pOH.
6. To prepare a buffer solution of pH = 4.04, amount of Barium acetate to be added to 100 mL of 0.1 M
acetic acid solution [pKb(CH3COO–) = 9.26] is :
(A) 0.05 mole (B) 0.025 mole (C*) 0.001 mole (D) 0.005 mole
pH = 4.04 dk cQj cukus ds fy, 0.1 M ,flfVd vEy ds 100 mL ds lkFk csfj;e ,flVsV dh feyk;h xbZ ek=kk
fuEu gS% [pKb (CH3COO–) = 9.26]
(A) 0.05 eksy (B) 0.025 eksy (C*) 0.001 eksy (D) 0.005 eksy
Sol. For the buffer solution of CH3COOH & CH3COO –
7. The pOH of a basic buffer (e.g. NH4OH/NH4Cl is 5. If the concentration of the salt is tripled whereas that
of base remains same, what is the new value of pOH ? (Given log 3 0.48)
,d {kkjh; cQj (mnk. NH4OH/NH4Cl) dk pOH 5 gSA ;fn yo.k dh lkUnzrk frxquh dh tkrh gks] tgk¡ {kkj leku
jgrk gSA pOH dk u;k eku D;k gS \ (fn;k gS log 3 0.48)
(A) 4.52 (B*) 5.48 (C) 6.48 (D) 3.52
[salt] [ yo.k ]
Sol. pOH = pKb + log ¼ ½=5
[base] [{kkj ]
3 [salt] 3[ yo.k ] [salt] [ yo.k ]
pOH = pKb + log ¼ ½= pKb + log ¼ ½ + log3 = 5 + log3 = 5 + 0.48 = 5.48.
[base] [ {kkj ] [base] [{kkj ]
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.-48
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
DPPs BOOKLET-3 VIKAAS (JA) | CHEMISTRY
8. Which one of the following is not a buffer solution ?
fuEu esa ls cQj foy;u dkSulk ugha gS\
(A) 0.8 M H2S + 0.8M KHS (B) 2M C6H5NH2 + 2M C6H5 N H3Br–
(C) 3M H2CO3 + 3M KHCO3 (D*) 0.05 M KClO4 + 0.05M HClO4
In the above shown energy diagram, the three wavelengths 1, 2 and 3 are in the ratio of ............
respectively.
mijksDr iznf'kZr ÅtkZ vkjs[k es]a rhu rjax-nS/;Z 1, 2 rFkk 3 dk vuqikr Øe'k% ............ gksxk %
(A) 1 : 2 : 3 (B) 1 : 4 : 3 (C) 2 : 3 : 5 (D*) 1 : 3 : 4
1 1 1
Sol. 1 : 2 : 3 = : :
E1 E2 E3
1 1 1
= : : 1:3:4
40.8 13.6 10.2
11. The vapour density of N2O4 at a certain temperature is 40. What is the percentage dissociation of N 2O4
at this temperature according to the given reaction ? N 2O4(g) 2NO2(g)
,d fuf'pr rkieku ij N2O4 dk ok"i ?kuRo 40 gSA bl rkieku ij nh xbZ vfHkfØ;k ds vuqlkj N2O4 dk %
fo;kstu D;k gksxk ? N2O4(g) 2NO2(g)
(A) 7.5% (B) 95% (C*) 15% (D) 1.5%
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.-49
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
DPPs BOOKLET-3 VIKAAS (JA) | CHEMISTRY
13.* Equal volume of 0.1M NaCl and 0.1M FeCl2 are mixed with no change in volume due to mixing. Which
of the following will be true for the final solution. (No precipitation occurs). Assume complete
dissociation of salts and neglect any hydrolysis.
0.1M NaCl vkSj 0.1M FeCl2 ds leku vk;ru dks feykus ij muds vk;ru esa dksbZ ifjorZu ugha gksrk gSA buesa ls
vfUre foy;u ds fy;s dkSulk lR; gSA ¼dksbZ vo{ksi ugha curk½ ekuks yo.k dk iw.kZ fo;kstu gksrk gS vkSj fdlh
ty vi?kVu dks NksM+ nks&
(A*) [Na+] = 0.05 M (B) [Fe2+] = 0.1M (C) [Cl] = 0.3M (D*) [Cl] = 0.15M
14.* The pH values of which of the following solution in general does not depend on the concentration of
solution:
(A*) An aqueous solution of Ammonium formate (HCOONH4)
(B*) An aqueous solution of Sodium bicarbonate (NaHCO3)
(C) An aqueous solution of Potassium sulphide (K2S).
(D*) An aqueous solution of Barium chloride (BaCl2)
fuEu esa ls dkSuls foy;u dk pH eku lkekU;r% foy;u dh lkUnzrk ij fuHkZj ugh djrk gSA
(A*) veksfu;e QkesZV (HCOONH4) dk tyh; foy;u
(B*) lksfM;e ckbZdkcksZusV (NaHCO3) dk tyh; foy;u
(C) iksVsf'k;e lYQkbM (K2S) dk tyh; foy;u
(D*) csjh;e DyksjkbM (BaCl2) dk tyh; foy;u
1
Sol. (A) pH = (pKw + pKa – pKb)
2
pK a1 pK a2
(B) pH =
2
1
(C) pH = (pKw + pKa2 + log10C)
2
(D) pH = 7
15. How many of the following species on mixing with water produce acidic solutions ?
fuEu esa ls fdruh Lih'kht ty ds lkFk fefJr djus ij vEyh; foy;u nsrh gS \
FeCl3 ; CuSO4 ; CO2 ; NaCl ; KCN ;
NH4Cl ; C6H5NH3+Cl– ; BCl3, CaCO3;
Ans. 6
Sol. FeCl3, CuSO4, CO2, NH4Cl ; C6H5NH3+Cl– ; BCl3.
16. Calculate the pH in a 0.1 M solution of NH4OCN. Ka (HOCN) = 3.3 x 104, Kb (NH3) = 1.8 × 105
NH4OCN ds 0.1 M foy;u ds pH dh x.kuk dhft,A Ka (HOCN) = 3.3 x 104, Kb (NH3) = 1.8 × 105
Ans. pH = 6.39
1 1
Sol. pH = (pKw + pKa – pKb) = [14 + 3.4814 – 4.7447] = 6.368.
2 2
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.-50
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
DPPs BOOKLET-3 VIKAAS (JA) | CHEMISTRY
17. Match the column :
Column I Column I I
0.1 M NaHCO3 solution (Ka1 = 5 × 10–7 & % Dissociation of H2O is less than 1.8 × 10–
(A) (p)
Ka2 = 5 × 10–11 for H2CO3) 7 %.
P / I-CHEMISTRY
EST INFORM AT IO
DPP
DAILY PRACTICE PROBLEMS
ANSWER KEY
1. (A) 2. (D) 3. (B) 4. (A) 5. (B)
6. (B) 7. (D) 8. (A) 9. (D) 10.* (BCD)
11.* (ABC) 12.* (ABC) 13.* (BCD) 14.* (ABC) 15. 1
16. 2 17. 7 18. 10 19. 28
20. (A – r ; B – s ; C – p ; D – q, r)
1. What is the pH of the solution at half neutralization in the titration of 0.1 N CH3COOH solution by 0.5 M
KOH solution : (Ka of CH3COOH = 1.8 10–5)
(A*) 4.74 (B) 9.26 (C) 4.26 (D) None of these
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.-51
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
DPPs BOOKLET-3 VIKAAS (JA) | CHEMISTRY
0.1 N CH3COOH foy;u ds 0.05 M KOH foy;u ds lkFk vuqekiu esa v)Z mnklhuhdj.k ij foy;u dh pH D;k
gS : ( CH3COOH dk Ka = 1.8 10–5)
(A*) 4.74 (B) 9.26 (C) 4.26 (D) buesa ls dksbZ ugha
Sol. pH = pKa = 4.75
+
2. The neutralisation of a strong acid by a strong base liberates an amount of energy per mole of H that-
(A) Depends upon which acid and base are involved.
(B) Depends upon the temperature at which the reaction takes place.
(C) Depends upon which catalyst is used.
(D*) Is always the same.
izcy vEy dk izcy {kkj }kjk mnklhuhdj.k djus ij H+ ds izfr eksy mRiUu ÅtkZ dh ek=kk&
(A) fuHkZj djrk gS fd dkSulk vEy rFkk {kkj mi;ksx fd;k x;kA
(B) fuHkZj djrk gS fd fdl rki ij vfHkfØ;k dh xbZ
(C) fuHkZj djrk gS fd dkSulk mRizsjd iz;ksx fd;k x;k
(D*) ges'kk leku jgrh gSA
3. The solubility of sparingly soluble electrolyte MmAa (producing Ma+ & Am– ions in aqueous solution) in
water is given by the expression :
vYi foys;h fo|qr vi?kV~; MmAa (tyh; foy;u esa Ma+ o Am– vk;u cukrk gS) dh ty esa foys;rk fdl O;atd
ds }kjk nh tkrh gS %
ma 1/ m a ma 1/ m a
K sp K sp K sp K sp
(A) s = m a (B*) s = m a (C) s = a m (D) s = a m
m a m a m a m a
4. A particular saturated solution of silver chromate, Ag2CrO4, has [Ag+] = 5 × 10–5 M and [CrO42–] = 4.4 ×
10–4 M. What is value of Ksp for Ag2CrO4 ?
flYoj ØksesV] Ag2CrO4 ds fuf'pr lar`Ir foy;u esa [Ag+] = 5 × 10–5 M rFkk [CrO42–] = 4.4 × 10–4 M gSaA
Ag2CrO4 ds fy, Ksp dk eku D;k gS \
(A*) 1.1 × 10–12 (B) 2.2 × 10–8 (C) 9.68 × 10–12 (D) 4.4 × 10–12
5. If the solubility of Ag2SO4 in 10–2 M Na2SO4 solution be 2 × 10–8 M, then Ksp of Ag2SO4 will be :
;fn 10–2 M Na2SO4 foy;u esa Ag2SO4 dh foys;rk 2 × 10–8 M gS] rc Ag2SO4 dk Ksp fuEu gksxk %
(A) 32 × 10–24 (B*) 16 × 10–18 (C) 32 × 10–18 (D) 16 × 10–24
Sol. Ag2SO4 +
2Ag + SO4 –2
(A*) W = – 2 P0 V0 ln 2, q = 2 P0 V0 ln 2, E = 0, H = 0
(B) W = – P0 V0 ln 2, q = P0 V0 ln 2, E = 0, H = 0
–10
(C) W = – 2 P0 V0 ln 2, q = 0, E = – 2 P0 V0 ln 2, H = P0 V0 ln 2
3
1 – Po Vo – 5Po Vo
(D) W = – 2 P0 V0 ( + ln 2), q = 2 P0 V0 ln 2, E = , H =
4 2 6
Sol. At A and D the temperatures of the gas will be equal, so
A o B ij xSl dk rki cjkcj gksxkA vr %
E = 0, H = 0
Now vc w = W AB + W BC + W CD = – P0 V0 – 2P0 V0 ln 2 + P0 V0 = – 2P0 V0 ln 2
and rFkk q = – W = 2 P0 V0 ln 2
9. Calculate [H+], [HCOO–] and [OCN–] in a solution that contains 0.1M HCOOH (Ka = 2.4 x 104) and 0.1
M HOCN (Ka = 4 × 104).
0.1M HCOOH (Ka = 2.4 x 10-4) rFkk 0.1 M HOCN (Ka = 4 × 104) ;qDr foy;u eas [H+], [HCOO–] rFkk
[OCN–] dh x.kuk dhft,A
(A) [H+] = (0.1 2.4 104 ) (0.1 4 104 ) 8 × 10–3 M
(B) [HCOO–] = 3 × 10–3 M
(C) [OCN–] = 5 × 10–3 M
(D*) All of these mijksDr lHkh
Sol. [H+] = = 8 × 10–3 M
[H ][HCOO ]
for HCOOH, Ka = 2.4 × 10–4 =
[HCOOH]
[HCOO¯] = 3 × 10 M –3
[H ][OCN ]
for HOCN, Ka = 4 × 10–4 =
[HOCN]
[OCN¯] = 5 × 10 M–3
10.* The graph given below shows the P-V plot for a process on an ideal gas. Select the incorrect
statement:
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.-53
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
DPPs BOOKLET-3 VIKAAS (JA) | CHEMISTRY
uhps fn;k x;k vkjs[k] ,d vkn'kZ xSl ij ,d izØe ds fy, P-V vkjs[k dks n'kkZrk gSA lgh xyr dk pquko dhft;s%
(A) Enthalpy content of the gas is constantly increasing and the process is carried out slowly.
xSl ds ,UFkSYih in esa fu;r :i ls o`f) gksrh gS rFkk izØe /khjs&/khjs lEiUu gksrk gSA
(B*) Enthalpy content of the gas first increases, then decreases and the process is carried out
quasistaticly.
xSl ds ,UFkSYih in esa igys o`f) rFkk fQj deh gksrh gS rFkk izØe fLFkj&LFkSfrd (quasistaticly) :i ls
lEiUu gksrk gSA
(C*) Enthalpy content of the gas is constant and the process takes infinite time for completion.
xSl dk ,UFkSYih in fu;r jgrk gS rFkk izØe] iw.kZ gksus ds fy, vuUr le; yxkrk gSA
(D*) Enthalpy content first decreases, then increases and the process is reversible.
xSl ds ,UFkSYih in esa igys deh rFkk fQj o`f) gksrh gS rFkk izØe mRØe.kh; gSA
Sol. The product PV is increasing so temperature will keep or increasing in the process, hence H = E +
(PV) will increase constantly
mRikn PV c<+rk gS vr% izØe esa rkieku leku jgsxk ;k c<+sxkA vr% H = E + (PV) fu;r :i ls c<+sxkA
11.* Which of the following statements is/are incorrect at 25°C :
(A*) pKa for H3O+ is 15.74 (B*) Percentage dissociation of water is 1.8 × 10–9 %
(C*) pKa + pKb = pKw for HCl & ClOH (D) pKb for OH– is – 1.74
fuEu esa dkSulk dFku 25ºC ij lR; ugha gS %
(A) H3O+ dk pKa eku 15.74 gksrk gSA (B) ty ds vk;uu dh çfr'krrk 1.8 × 10–9 % gksrh gSA
(C) HCl ,oa ClOH ds fy;s, pKa + pKb = pKw gksxkA (D*) OH– dk pKb eku – 1.74 gksrk gSA
Sol. pKa (H3O+) = –1.74 = pKb of OH–
pKa + pKb = 14 only for conjugate acid base pair.
= 1.8 × 10–9 or 1.8 × 10–7 % for H2O.
Sol. pKa (H3O ) = –1.74 = OH– dk pKb
+
1.3 × 10–13.
viuk mÙkj p2/q ds :i esa nhft;sA
Ans. 1
Sol. H2S H+ + HS– .....(i)
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.-55
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
DPPs BOOKLET-3 VIKAAS (JA) | CHEMISTRY
0.1 – x 0.25 x
HS– H+ + S– .....(ii)
x–y 0.25 y
HCl H+ + Cl– .....(iii)
0.25
0.25 [HS – ]
(i) 10–7 = [HS–] = 4 × 10–8.
0.1– x
0.25 [S2 ]
(ii) 1.3 × 10–13 = [S2–] = 2.08 × 10–20.
4 10–8 – y
16. Saccharin (Ka = 2 1012) is a weak acid represented by formula HSac. A 4 × 104 mole amount of
saccharin is dissolved in a 200 cm 3 solution of pH = 3. Assuming no change in volume, calculate the
concentration of Sac ions in the resulting solution at equilibrium.
If [Sac–] = z × Ka, report your answer as z.
lSdsfju (Ka = 2 1012) ,d nqcZy vEy gS] ftldks HSac lw=k }kjk çnf'kZr djrs gSaA lSdsfju dh 4 × 10 4 eksy
ek=kk dks 200 cm3 foy;u esa foy; fd;k tkrk gS] ftldk pH 3 gSA ;g ekudj fd vk;ru esa dksbZ ifjorZu ugha
gksrk gS] lkE;koLFkk ij ifj.kkehs foy;u esa Sac vk;u dh lkUnzrk dh x.kuk dhft,A
;fn [Sac–] = z × Ka gS, rks viuk mRrj z ds :i esa nhft,A
Ans. 2
Sol. Calculation of [H+] and [HSac] at start
izkjEHk esa [H+] o [HSac] dk ifjdyu
4 10 4 1000
[HSac] = = 0.002 M
200
The dissociation of HSac is as below
HSac dk fo;kstu fuEu izdkj gksrk gS&
HSac H+ + Sac–
At start 0.002 0.001 0
izkjEHk esa
At equi. 0.002-x 0.001 + x x
lkE; ij
[H ][Sac ] (0.01 x)x
Ka = = = 2 ×10–12
[HSac] 0.002 x
x = 4 ×10–12 M
[Sac–]equi. = 4 ×10–12 M.
17. Find the concentration of H+ ions in an aqueous solution which is saturated with H2S (0.1 M) as well as
H2CO3 (0.2 M). If [H+] = p × 10–q M, report your answer as (p + q).
Given : Ka1 = 10–7, Ka2 = 10–14 for H2S ; Ka1 = 4 × 10–7, Ka2 = 4 × 10–11 for H2CO3.
H2S (0.1 M) ds lkFk&lkFk H2CO3 (0.2 M) ds lkFk Hkh lar`Ir tyh; foy;u esa H+ dh lkUnzrk Kkr dhft;sA
fn;k gS % [H2S ds fy, K1 = 10–7, K2 = 10–14 ; H2CO3 ds fy, K1 = 4 × 10–7, K2 = 4 × 10–11] :
Ans. 7
Sol. [H+] = K1C1 K 2C2 = 107 0.1 4 107 0.2 = 3 × 10–4 M
18. At 25ºC, the dissociation constants of CH3COOH and NH4OH in an aqueous solution are almost the
same. Calculate the pH of a solution of 0.01 N CH3COOH is 4 at 25ºC. The pH of 0.01 N NH4OH
solution at the same temperature .
25ºC ij ,d tyh; foy;u esa CH3COOH rFkk NH4OH ds fo;kstu fLFkjkad dk eku yxHkx leku gSSA 25ºC ij
0.01N CH3COOH ds foy;u dh pH 4 gSA leku rki ij 0.01 N NH4OH foy;u dh pH D;k gksxh \
Ans. 10
19. Calculate the hydrogen ion concentration (in mol/dm 3) in a solution containing 0.04 mole of acetic acid
and 0.05 mole of sodium acetate in 500 mL of solution. Dissociation constant for acetic acid is 1.75
105.
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.-56
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
DPPs BOOKLET-3 VIKAAS (JA) | CHEMISTRY
Report your answer after multiplying by 2 × 106.
0.04 eksy ,flfVd vEy rFkk 0.05 eksy lksfM;e ,lhVsV ;qDr ,d 500 mL foy;u esa gkbMªkstu vk;u lkUnzrk dh
x.kuk (mol/dm3esa) dhft,A ,flfVd vEy ds fy, fo;kstu fLFkjkad = 1.75 10 5 gSA
viuk mRrj] 2 × 106 ls xq.kk djds nhft,A
Ans. 28
20. Match the following :
Column I Column I I
(A) 2 m solution of CaBr2 having density 1.4 g/mL (p) mole fraction of solute is 0.2.
3 M, 100 mL H2SO4 solution is mixed with 1 M, 300
(B) (q) mass of the solute is 160 g.
mL H2SO4 solution.
(C) 3.205 m solution of I2 solute in C6H6 solvent. (r) molarity of solution = 2 M
In 1.5 M, 2 litre solution of NaOH, 40 g NaOH is
(D) (s) molarity of solution = 1.5 M
dissolved.
fuEu dks lqesfyr dhft, %
LrEHk I LrEHk I I
(A) CaBr2 dk 2 m foy;u ¼?kuRo 1.4 g/mL) (p) foys; dk eksy izHkkt 0.2 gSA
3 M, 100 ml H2SO4 dks 1 M, 300 mL
(B) (q) foys; dk nzO;eku 160 g gSA
H2SO4 foy;u ds lkFk feykrs gSaA
3.205 m solution of I2 solute in C6H6
(C) (r) foy;u dh eksyjrk = 2 M
solvent.
In 1.5 M, 2 litre solution of NaOH, 40 g
(D) (s) foy;u dh eksyjrk = 1.5 M
NaOH is dissolved.
Ans. (A – r ; B – s ; C – p ; D – q, r)
Sol. (A) 4.5 m, CaCO3 means
4.5 moles of CaCO3 is present in 1000 g solvent.
mass of solute = 4.5 × 100 = 450 g
mass of solvent = 1000 g.
mass of solution = 1450 g.
Hence molarity = 4.5 M
3 100 1 300 3 14.5
(B) Resultant molarity = = = 1.5 M (C) mole fraction = = 0.2
400 2 14.5 55.5
(D) moles of NaOH in 2 L = 4 × 2 = 8 mole
40
moles of NaOH added = = 1 mole.
40
9
Molarity = = 4.5 M mass of NaOH = 9 × 40 = 360 g.
2
(A) 4.5 m, CaCO3 dk vFkZ
4.5 eksy CaCO3 1000 g foyk;d esa mifLFkr gS
foy; dk æO;eku = 4.5 × 100 = 450 g
foyk;d dk æO;eku = 1000 g.
foy;u dk æO;eku = 1450 g.
vr% eksyjrk = 4.5 M
3 100 1 300 3 14.5
(B) ifj.kkeh eksyjrk = = = 1.5 M (C) eksy izHkkt = = 0.2
400 2 14.5 55.5
(D) 2 yhVj esa NaOH ds eksy = 4 × 2 = 8 mole
40
feyk;s x;s NaOH ds eksy = = 1 mole.
40
9
eksyjrk = = 4.5 M NaOH dk æO;eku = 9 × 40 = 360 g.
2
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.-57
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
DPPs BOOKLET-3 VIKAAS (JA) | CHEMISTRY
P / I-CHEMISTRY
EST INFORM AT IO
DPP
DAILY PRACTICE PROBLEMS
ANSWER KEY
1. (C) 2. (D) 3. (A) 4.* (ABC) 5.* (AD)
6.* (ABC) 7. (D) 8. (A) 9. (B) 10. 5
11. 3 12. 5 13. 3 14. 15 15. 5
16. (A) q,s,t ; (B) p,q,t ; (C) p,r ; (D) q,s; (E) - t
1. Calculate (i) [H+] and (ii) [PO43–] in a 0.15 M solution of phosphoric acid, H 3PO4. Given that for H3PO4 :
Ka1 = 7.5 × 10–3, Ka2 = 6.2 × 10–8, Ka3 = 3.6 × 10–13.
(A) [H+] = 0.03 M (B) [PO43–] = 7.44 × 10–19 M (C*) Both (A) and (B) (D) None of these
0.15 M QkWLQksfjd vEy (H3PO4) ds foy;u esa (i) [H+] rFkk (ii) [PO43–] dh x.kuk dhft;sA H3PO4 ds fy,
K1 = 7.5 × 10–3, K2 = 6.2 × 10–8, K3 = 3.6 × 10–13.
(A) [H+] = 0.03 M (B) [PO43–] = 7.44 × 10–19 M (C*) (A) o (B) nksuksa (D) buesa ls dksbZ ugha
2. Find the concentration of H+, HCO3 & CO32 in a solution, which is 0.01 M wrt H2CO3 and may
contain some other non-reactive solute also. pH of this solution is 2.74.
Given : Ka(H2CO3) = 4 10 –7 ; Ka (HCO3) = 4.8 10 –11 .
,d foy;u tks H2CO3 ds lkis{k 0.01 M gS rFkk dksbZ vU; vfØ; foys; Hkh j[k ldrk gS] esa H+ , HCO3 rFkk
CO32 dh lkUnzrk,¡ Kkr dhft,A bl foy;u dh pH 2.74 gSA
fn;k x;k gS : Ka(H2CO3) = 4 10 –7 ; Ka (HCO3) = 4.8 10 –11 .
(A) [H+] = 1.8 × 10–3 M (B) [HCO3–] = 2.22 × 10–6 M
(C) [CO32–] = 6 × 10–14 M (D*) All of these mijksDr lHkh
[HPO2–
4 ]
3. The pH of blood is 7.4. What is the ratio of in the blood ? Given : Ka1, Ka2 and Ka3 for H3PO4
[H2PO4– ]
are
10–3, 8 × 10–8 and 10–12 respectively.
[HPO2–4 ]
jDr dh pH 7.4 gSA jDr esa dk vuqikr D;k gS \ fn;k gS : H3PO4 ds fy;s Ka1, Ka2 o Ka3Øe'k%
[H2PO4– ]
10–3, 8 × 10–8 o 10–12 gSaA
(A*) 2 : 1 (B) 1 : 2 (C) 3 : 1 (D) 1 : 3
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.-58
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
DPPs BOOKLET-3 VIKAAS (JA) | CHEMISTRY
Sol. H2PO4– HPO42– + H+ .
HPO4
2– HPO2– 2
8 × 10–8 = –
× 4 × 10–8.
4
–
=
H2PO 4 H2PO 4 1
4.* Two gas samples are separated by a conducting frictionless piston as shown in the figure :
If the piston is in equilibrium in the position shown. Then which of the following statement is/are correct :
gas A gas B
(A*) TA = TB
(B*) PA = PB
(C*) nB = 3nA
(D) Total Translational K.E. of Gas A = 3 × Total Translational K.E. of gas B
fp=k esa n'kkZ;s vuqlkj nks xSl uewuksa dks pkyd ?k"kZ.kjfgr fiLVu (conducting frictionless piston) }kjk i`Fkd
djrs gSA ;fn n'kkZ;h xbZ fLFkfr es fiLVu lkE;koLFkk esa gSaA rc fuEu esa ls dkSulk dFku xyr gS %&
(A*) TA = TB (B*) PA = PB
(C*) nB = 3nA (D) xSl A dh dqy xfrt ÅtkZ = 3× xSl B dh dqy xfrt ÅtkZ
Sol. Since system is conducting frictionless
Hence TA = TB and PA = PB
Since volume is different hence nB = 3nA.
Sol. pawfd fudk; pkyd rFkk ?k"kZ.kjfgr gSA
vr% TA = TB o PA = PB
pwafd vk;ru fHkUu gS vr% nB = 3nA
5.* When 0.1 mole arsenic acid (H3AsO4) is dissolved in a 1L buffer solution of pH = 8. Which of the
following options is/are correct ? For arsenic acid : Ka1 = 2.5 × 104, Ka2 = 5 × 108, Ka3 = 2 × 1013. [‘<<’
sign denotes that the high concentration is at least more than 100 times the lower one]
tc pH = 8 okys ,d cQj foy;u ds 1 L esa 0.1 eksy vklsZfud vEy (H3AsO4) ?kksyk tkrk gS] rks fuEu esa ls
dkSulk¼ls½ fodYi lgh gS¼gSa½ \ vklsZfud vEy ds fy, Ka1 = 2.5 × 104, Ka2 = 5 × 108, Ka3 = 2 × 1013 [‘<<’
fpUg crkrk gS fd mPp lkUnzrk] fuEu lkUnzrk ls de ls de 100 xquk vf/kd gS]
(A*) [H3AsO4] << [H2AsO4] (B) [H2AsO4] << [HAsO42]
2
(C) [HAsO4 ] << [H2AsO4 ] (D*) [AsO43] << [HAsO42]
8
[H3 AsO 4 ] [H ] 10 1
Sol. (A) = = = [H3AsO4] << [H3AsO4–].
[H2 AsO 4 ] K1 2.5 10 4 25000
[H2 AsO4 ] [H ] 10 8 1
(B) 2
= = 8
=
[HAsO4 ] K2 5 10 5
[AsO43 ] K3 2 10 13 1
(C) = = = [AsO43–] << [HAsO42–].
[HAsO42 ] [H ] 10 8
50000
6.* Hydrazine, N2H4, can interact with water in two stages.
N2H4(aq) + H2O(l) N2H5+ (aq) + OH–(aq) Kb1 = 8.1 × 10–7
+
N2H5 (aq) + H2O (l) 2+
N2H6 (aq) + OH (aq) – Kb2 = 9 × 10–16
What are the concentrations of OH–, N2H5+ & N2H62+ and also pH value in a 0.01 M aqueous solution of
hydrazine?
gkbMªsthu N2H4, ty ds lkFk nks inkssa esa fØ;k djrk gSA
N2H4(aq) + H2O(l) N2H5+ (aq) + OH–(aq) Kb1 = 8.1 × 10–7
+
N2H5 (aq) + H2O (l) 2+
N2H6 (aq) + OH (aq) – Kb2 = 9 × 10–16
gkbMªsthu ds 0.01 M tyh; foy;u esa OH , N2H5 o N2H6 dh lkUnzrk,¡ rFkk lkFk gh pH dk eku D;k gS \
– + 2+
(A*) [OH–] = 9 × 10–5 M (B*) [N2H5+] = 9 × 10–5 M (C*) [N2H62+] = 9 × 10–16 M (D) pH = 4.04
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.-59
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
DPPs BOOKLET-3 VIKAAS (JA) | CHEMISTRY
[N2H5+] = C1Kb1 .
[N2H6+] = Kb2 .
Comprehension
50 mL, 0.1 M HCl solution is titrated against 0.1 M NaOH solution. Titration curve is as follows :
The suitable indicator for this titration can be selected on the following basis :
The steep section of the titration curve at the equivalence point must encompass an internal of pH
values at least as large as the pH transition range of an indicator. The pH transition range of the
indicator should most concide with the steep portion of the titration curve.
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.-60
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
DPPs BOOKLET-3 VIKAAS (JA) | CHEMISTRY
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.-61
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
DPPs BOOKLET-3 VIKAAS (JA) | CHEMISTRY
10. 0.1 M solution of a weak acid HA is titrated against 0.05 N NaOH solution. Calculate pH at 1/4th and
3/4th neutralization of acid.Given that the pH of 0.1 M HA solution is 3.
pH1 pH2
Report your answer as .
2
,d nqcZy vEy HA ds 0.1 M foy;u dks 0.05 N NaOH foy;u ds fo:) vuqekfir fd;k tkrk gSA vEy ds 1/4th
rFkk 3/4th Lrj ij mnklhuhdj.k ds fy, pH dh x.kuk dhft,A fn;k gS fd 0.1 M HA foy;u dh pH 3 gSA
pH pH2
viuk mÙkj 1 ds :i esa nsaA
2
Ans. 5
11. A solution of weak acid HA was titrated with NaOH solution. The end point is obtained by the addition of
36 mLof 0.1 N NaOH solution. Now 9 mL of 0.2 N HCl solution was added to titrated solution. The final
pH was found to be 4.5. Calculate Ka for the acid HA.
Report your answer after multiplying it by 105 and rounding it off to nearest whole number.
nqcZy vEy HA ds ,d foy;u dks NaOH ds lkFk vuqekfir djrs gSaA 0.1 N NaOH foy;u ds 36 mL dks feykus
ds i'pkr~ vfUre fcUnq izkIr gksrk gSA vc 0.2 N HCl foy;u ds 9 mL dks vuqekfir foy;u esa feyk;k tkrk gSA
rc vafre pH 4.5 izkIr gksrh gSA vEy HA ds fy, Ka dh x.kuk dhft,A
viuk mÙkj 105 ls xq.kk djds fudVre iw.kk±d ds :i esa nhft,A
Ans. 3
12. 25 mL of 0.1 M aqueous pyridine (K b = 1.6 109) solution is titrated with 0.1 M hydrochloric acid.
Calculate pH at equivalence point and after 35 cm3 hydrochloric acid solution has been added.
Report your answer as the sum of two pH values, rounding it off to the nearest whole number.
0.1 M tyh; fijhMhu ( Kb = 1.6 10 9) foy;u ds 25 mL dks 0.1 M gkbMªksDyksfjd vEy ds lkFk vuqekfir djrs
gaSA rqY;kad fcUnq rFkk 35 cm3 gkbMªksDyksfjd vEy dks feykus ds ckn Øe'k% pH dh x.kuk dhft,A
viuk mÙkj] nksukas pH ekuksa ds ;ksx ds :i esa fudVre iw.kk±d ds :i esa nhft,A
Ans. 5
13. The equivalence point in a titration of 40 mL of a solution of a weak monoprotic acid occurs when 32
mL of a 0.1 M NaOH solution has been added. The pH of the solution is 5.74 after addition of 20 mL of
above NaOH solution. What is Ka of the acid ?
Report your answer after multiplying it by 106.
,d nqcZy ,dyizksfVd vEy ds foy;u ds 40 mL ds vuqekiu esa] 0.1 M NaOH foy;u ds 32 mL dks feykus ij
rqY;kad fcUnq izkIr gksrk gSA NaOH foy;u ds 20 mL dks feykus ds i'pkr~ foy;u dk pH 5.74 gSA vEy dk Ka
D;k gS \
viuk mRrj 106 ls xq.kk djds nhft,A
Ans. 3
14. Calculate the volume (in mL) of 0.1 M Na2SO4 solution, which must be added to 10 mL of HCl solution
(pH = 1), so that pH of the resulting solution becomes 2. (Given : Ka2 for H2SO4 = 10–2 and Ka1 = )
0.1 M Na2SO4 dk og vk;ru (mLesa) ifjdfyr dhft,] ftls fd HCl (pH = 1) ds 10 mL esa feyk;s tkus ij
izkIr ifj.kkeh foy;u dh pH 2 gks tk;sA (fn;k x;k gS : [H2SO4 ds fy, Ka2 = 10–2 rFkk Ka1 = ]
Ans. 15
15. What is the [Cd2+] in mol/L in 1 L of solution prepared by dissolving 0.001 mole Cd(NO 3)2 & 2 mole
NH3?
Equilibrium constant Kd for the dissociation of Cd(NH3)42+ into Cd2+ & 4 NH3 is 2 x 107. Neglect any
other compound formation by Cd2+ ions.
Report your answer after multiplying by 4 × 1011.
0.001 eksy Cd(NO3)2 rFkk 2 eksy NH3 dks ?kksydj cuk;s x;s 1 yhVj foy;u esa [Cd2+], mol/L esa D;k gS \
Cd(NH3)42+ ds Cd2+ rFkk 4 NH3 esa fo;kstu ds fy, lkE; fLFkjkad Kd 2 x 107 gSA Cd2+ vk;u }kjk fdlh vU;
;kSfxd dks curk gqvk u ekusaA
viuk mÙkj 4 × 1011 ls xq.kk djds nhft,A
Ans. 5
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.-62
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
DPPs BOOKLET-3 VIKAAS (JA) | CHEMISTRY
16. Match the following :
Column I Column II
(A) NaHCO3 (aq.) (p) Significant cationic hydrolysis
(B) CH3COONH4 (aq.) (q) Significant anionic hydrolysis
(C) K2SO4. Al2(SO4)3.24H2O (aq.) (r) Acidic (pH < 7)
(D) NaCN (aq) (s) Basic (pH > 7)
(E) NaCl (aq.) (t) pH is independent of concentration
P / I-CHEMISTRY
EST INFORM AT IO
DPP
DAILY PRACTICE PROBLEMS
ANSWER KEY
1. (B) 2. (C) 3. (A) 4. (A) 5.* (ABCD)
6.* (ABC) 7.* (CD) 8. 9 9. 0 10. 5
11. 38 12. 30 13. 50 14. 50
15. (A – s); (B – p, q); (C – q, s) ; (D – q, r)
1. 3 moles of ammonia are heated in presence of 1 mole of neon gas. At equilibrium the mole fraction of
hydrogen is found to be 0.5. The value of 'KC.V' (V – Volume of container) for the given reaction is :
1 3
NH3(g) N2(g) + H2(g)
2 2
3 eksy veksfu;k dks 1 eksy fuvkWu xSl dh mifLFkfr esa xeZ djrs gSaA lkE; ij gkbMªkstu dk eksy izHkkt 0.5 gSA nh
xbZ vfHkfØ;k ds fy, 'KC.V' dk eku Kkr djsa % (V – ik=k dk vk;ru)
1 3
NH3(g) N2(g) + H2(g)
2 2
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.-63
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
DPPs BOOKLET-3 VIKAAS (JA) | CHEMISTRY
(A) 27 3 (B*) 3 3 (C) 27 (D) 3 /8
1 3
Sol. NH3(g) N2(g) + H2(g) and 1 mole Ne
2 2
3
3x / 2 1
3-x x/2 3x/2
4x 2
1 1 3 x=2
(3 / V)3 / 2 (1/ V)1/ 2
KC = KC.V = 3 3 .
1/ V
2. A solution is saturated with respect to SrCO3 & SrF2. The [CO32] was found to be 1.2 x 103 M. The
concentration of F in the solution would be: Ksp (SrCO3) = 10–9, Ksp(SrF2) = 3 × 10–11.
,d foy;u SrCO3 rFkk SrF2 ds lkis{k lar`Ir gSA [CO32] 1.2 x 103 M ik;h x;hA foy;u esa F dh lkUnzrk D;k
gksxh% Ksp (SrCO3) = 10–9, Ksp(SrF2) = 3 × 10–11
(A) 3 x 103 M (B) 3.6 x 105 M (C*) 6 x 103 M (D) 6 x 102 M
3. Ksp of AgCl is 1.96 × 10–10. 100 mL of saturated AgCl solution is titrated with 1 × 10 –5 M NH4 SCN
solution. Minimum volume of NH4 SCN solution required to precipitate all Ag+ from saturated AgCl
solution as AgSCN is:
(A*) 140 mL (B) 14 mL (C) 1.4 L (D) None of these
AgCl dk Ksp 1.96 × 10 gSA lar`Ir AgCl foy;u ds 100 mL dks, 1 × 10–5 M NH4 SCN foy;u ds lkFk
–10
vuqekfir fd;k tkrk gSaA lar`Ir AgCl foy;u ls iw.kZ :i ls Ag+ dks AgSCN ds :i esa vD{ksfir djus ds fy,
NH4 SCN foy;u dk vko';d U;wure vk;ru fuEu gksxk %
(A*) 140 mL (B) 14 mL (C) 1.4 L (D) buesa ls dksbZ ugha
Sol. m.moles of Ag+ in 100 ml of saturated solution of AgCl = K sp × 100 = 1.4 × 10–3
4. 0.2 millimoles of Zn2+ ion is mixed with (NH4)2 S solution of molarity 0.02 M. The amount of Zn2+ that
remains unprecipitated in 20 mL of this solution would be : (Given : KSP ZnS = 4 × 10–24)
Zn2+ vk;u ds 0.2 feyheksy dks 0.02 M eksyjrk ds (NH4)2 S foy;u ds lkFk fefJr fd;k x;k gSA bl foy;u ds
20 mL esa vu~vo{ksfir jgus okys Zn2+ dh ek=kk fuEu gksxh % (fn;k x;k gS : KSP ZnS = 4 × 10–24)
(A*) 5.2 × 10–22 g (B) 2.6 × 10–22 g (C) 1.04 × 10–21 g (D) 5.2 × 10–23 g
Sol. S 2– + Zn ZnS (s)
2+
0.2 –
so in solution,
0.2
[S2–] = = 0.01 M
20
K sp 4 10 24
[Zn2+] = 2 = = 4 × 10–22 M
[S ] 0.01
4 10 24
mass of Zn2+ remain unprecipitated in 20 ml of solution = × 20 × 65 = 5.2 × 10–22 gm.
1000
gy. S2– + Zn2+ ZnS (s)
feyh eksy 0.4 0.2
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.-64
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
DPPs BOOKLET-3 VIKAAS (JA) | CHEMISTRY
0.2 –
vr% foy;u esa]
0.2
[S2–] = = 0.01 M
20
K sp 4 10 24
[Zn2+] = 2 = = 4 × 10–22 M
[S ] 0.01
4 10 24
20 ml foy;u esa Zn2+ dk nzO;eku tks vo{ksfir ugha gksrk gS = × 20 × 65 = 5.2 × 10–22 gm.
1000
5.* If the amount given below is added in pure water, will all of the salt dissolve before equilibrium can be
established, or will some salt remain undissolved ?
(a) 4.96 mg of MgF2 in 125 mL of pure water, Ksp of MgF2 = 3.2 x 10–8
(b) 3.9 mg of CaF2 in 100 mL of pure water, Ksp of CaF2 = 4 x 10–12
Also find the percentage saturation in each case. Assume no hydrolysis of cation or anion.
(A*) MgF2 will completely dissolve (B*) MgF2 solution will have 32% saturation
(C*) CaF2 will not completely dissolve (D*) CaF2 solution will have 100% saturation
;fn uhps nh x;h ek=kk dks 'kq) ty esa feyk;k tkrk gS] rks D;k lkE;koLFkk vkus ls igys lkjk yo.k foys; gksxk ;k
dqN yo.k vfoys; jgsxk ?
(a) 125 mL 'kq) ty esa MgF2 ds 4.96 mg, MgF2 dk Ksp = 3.2 x 10–8
(b) 100 mL 'kq} ty esa CaF2 ds 3.9 mg, CaF2 dk Ksp = 4 x 10–12
izR;sd ifjfLFkfr esa lar`Irrk dh izfr'kr Kkr dhft,A /kuk;u o _.kk;u dk ty vi?kVu u ekusaA
(A*) MgF2 iw.kZr% foys; gksxk (B*) MgF2 foy;u 32% lar`Ir gksxk
(C*) CaF2 iw.kZr% foys; ugha gksxk (D*) CaF2 foy;u 100% lar`Ir gksxk
6.* The solubility product for silver iodate AgIO3 is 1 x 108. If 0.1 g of solid AgIO3 is added to
100 mL of 0.02 M KIO3 solution, what are the concentrations of K+, IO3 & Ag+ at equilibrium?
flYoj vk;ksMsV AgIO3 ds fy, foys;rk xq.kuQy 1 x 108 gSA ;fn 0.1 g Bksl AgIO3 dks 0.02 M KIO3 ds 100
mL esa feyk;k tkrk gS] rks lkE;koLFkk ij K+, IO3 rFkk Ag+ dh lkUnzrk,¡ D;k gSa \
(A*) [Ag+] = 5 × 10–7 M (B*) [IO3–] = 2 × 10–2 M (C*) [K+] = 2 × 10–2 M (D) [IO3–] = 0.023 M
7.* When 0.01 mole HCl is added in 1 L of 0.01 M CH3COOH (Ka = 2 × 10–5) solution, then which statement
is wrong?
(A) Degree of dissociation of CH3COOH approaches zero.
(B) Change in pH by adding HCl would be 1.35.
(C*) On addition of HCl, Ka of CH3COOH decreases.
(D*) On addition of HCl, Ka of CH3COOH increases.
tc 0.01 eksy HCl dks 0.01 M tyh; CH3COOH (Ka = 2 × 10–5) ds 1 yhVj esa feyk;k tkrk gS] rc dkSulk
dFku xyr gS\
(A) CH3COOH ds fo;kstu dh ek=kk yxHkx 'kwU; gks tkrh gSA
(B) HCl feykus ij pH esa ifjorZu 1.35 gksxkA
(C*) HCl dks feykus ls CH3COOH ds Ka dk eku ?kV tkrk gSA
(D*) HCl dks feykus ls CH3COOH ds Ka dk eku c<+ tkrk gSA
1 1
Sol. Initial pH = (pKa – log C) = (5 – log 2 – log 0.01) = 3.35
2 2
After adding HCl, pH of solution = 2
Change in pH = 1.35
1 1
gy. izkjfEHkd pH = (pKa – log C) = (5 – log 2 – log 0.01) = 3.35
2 2
HCl feykus ds ckn, pH dk foy;u = 2
pH esa ifjorZu = 1.35
8. The number of completely filled orbitals in 29Cu which have atleast two nodes is/are :
29Cu esa de ls de nks uksM j[kus okys iw.kZiwfjr d{kdksa dh la[;k gS@gSa %
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.-65
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
DPPs BOOKLET-3 VIKAAS (JA) | CHEMISTRY
Ans. 9
Sol. 29Cu 1s2 2s2 2p6 3s2 3p6 3d10 4s1
Nodes 0 1 1 2 2 2 3 (but incompletely filled)
uksM ¼ysfdu viw.kZ Hkjk gksrk gSA½
Orbitals (d{kd) 1 3 5
So (vr%) 9.
9. (i) What pH of solution will reduce [S2–] ion to 4 × 10–18 M in a saturated (0.1 M) solution of H2S ?
(ii) What concentration of H 3O+ ions will reduce [HS–] ion to 2 × 10–6 M in a saturated (0.1 M) solution of
H2S?
Given : Ka1(H2S) = 1 × 10–7 , Ka2(H2S) = 10–14.
Report your answer as (pH + log [H3O+]).
(i) lar`Ir (0.1 M) H2S foy;u esa H3O+ vk;u dh fdl lkUnzrk ij] [S2–] vk;u dh lkUnzrk 4 × 10–18 M rd de
dh tk ldrh gS \
(ii) lar`Ir (0.1 M) H2S foy;u esa [H3O+] vk;u dh fdl lkUnzrk ij] [HS–] vk;u dh lkUnzrk 2 × 10–6 M rd de
dh tk ldrh gS \
K1(H2S) = 1 × 10–7 , K2(H2S) = 10–14.
viuk mÙkj (pH + log [H3O+]) ds :i esa nhft;sA
Ans. 0
10. Assume that 1.184 g of solid Ca(OH)2 are placed in 1 litre of pure water at 25ºC. The pH of the solution
is found to be 12. Estimate the Ksp for Ca(OH)2. Report your answer after multiplying by 107.
,slk ekusa fd 25ºC ij 'kq) ty ds 1 yhVj esa Bksl Ca(OH)2 ds 1.184 xzke j[ks tkrs gSaA foy;u dh pH 12 izkIr
gksrh gSA Ca(OH)2 ds fy, Ksp dh x.kuk dhft,A viuk mÙkj 107 ls xq.kk djds nhft,A
Ans. 5
11. If the solubility product of silver oxalate is 5 × 10–10, what will be the weight of salt (in gram) in 0.25 m 3
of a saturated solution ?
;fn flYoj vkWDlsysV dk foys;rk xq.kuQy 5 × 10–10 gS] rks ,d lar`Ir foy;u ds 0.25 m3 esa yo.k dk nzO;eku
¼xzke esa½ D;k gksxk \
Ans. 38
12. Calculate [F–] in a solution saturated with respect of both MgF 2 and SrF2. Assume no hydrolysis of
cation or anion.
Ksp(MgF2) = 9.5 x 10–9, Ksp(SrF2) = 4 x 10–9.
Report your answer after multiplying by 104.
MgF2 rFkk SrF2 nksukas ds lkis{k lar`Ir foy;u esa [F–] dh x.kuk dhft,A /kuk;u o _.kk;u dk ty vi?kVu u
ekusaA
Ksp(MgF2) = 9.5 x 10–9, Ksp(SrF2) = 4 x 10–9
viuk mÙkj 104 ls xq.kk djds nhft,A
Ans. 30
13. Determine the number of moles of AgI which may be dissolved in 1 L of 1 M CN solution. Ksp for AgI
and Kf for [Ag (CN)2] are 4 × 1017 M2 & 6.25 × 1017 respectively .
Report your answer after multiplying by 11.
1 M CN foy;u ds 1 L esa ?kksys tk ldus okys AgI ds eksykas dh la[;k Kkr dhft,A AgI ds fy, Ksp 4 × 1017
M2 rFkk [Ag (CN)2] ds fy, Kf 6.25 × 1017 gSA
viuk mÙkj 11 ls xq.kk djds nhft,A
Sol. 5
14. What is the maximum concentration (in M) of equimolar solutions of ferrous sulphate and sodium
sulphide so that when mixed in equal volumes, there is no precipitation of ferrous sulphide ? (For
ferroussulphide, Ksp = 6.25 × 10–18). Report your answer after multiplying it by 1010.
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.-66
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
DPPs BOOKLET-3 VIKAAS (JA) | CHEMISTRY
Qsjl lYQsV rFkk lksfM;e lYQkbM ds leeksyj foy;uksa dh lkUnzrk (M esa) vf/kdre D;k gks] fd bUgsa leku
vk;ru esa fefJr djus ij Qsjl lYQkbM dk vo{ksi izkIr ugha gksrk gks \ (Qsjl lYQkbM ds fy, Ksp = 6.25 ×
10–18) viuk mÙkj 1010 ls xq.kk djds nhft,A
Ans. 50
Sol. FeSO4 + Na2S FeS + Na2SO4
a a
a a
KSP = = 6.25 × 10–18
2 2
a = 4 × 6.25 × 10–18 = 4 × 625 × 10–20
2
a = 2 × 25 × 10–10 = 5 × 10–9 M
15. Match the following column :
Column I Column II
(A) AgBr (p) Solubility in water is more than expectation.
(B) AgCN (q) Solubility in acidic solution is more than that in pure water.
(C) Fe(OH)3 (r) Solubility in strongly basic solution is more than that in pure water.
(D) Zn(OH)2 (s) Solubility decreases in presence of common anion.
fuEu dks lqesfyr dhft,&
LrEHk I LrEHk II
(A) AgBr (p) ty esa vuqekfur ls vf/kd foys;rk gSA
(B) AgCN (q) vEyh; foy;u esa 'kq) ty dh rqyuk esa vf/kd foys;rk gSA
(C) Fe(OH)3 (r) izcy {kkjh; foy;u esa 'kq) ty dh rqyuk esa vfèkd foys;rk gSA
(D) Zn(OH)2 (s) le_.kk;u dh mifLFkfr esa foys;rk ?kVrh gSA
Ans. (A – s); (B – p, q); (C – q, s) ; (D – q, r)
Sol. (A) For AgBr, Ksp = [Ag+] [Br–]
so on increase in [Br–], solubility of AgBr decreases.
(B) For AgCN, Ksp = [Ag+] [CN–]
–
CN undergoes hydrolysis so solubility in water is more than expectation.
In acidic solution, CN– gets protonated so solubility of AgCN increases.
AgCN forms complex Ag(CN)2– with excess of CN–.
(C) For Fe(OH)3, Ksp = [Fe3+] [OH–]3.
In acidic solution OH– decreases so solubility increases.
Solubility decreases in presence of OH–.
(D) For Zn(OH)2, Ksp = [Zn2+] [OH–]2
Zn(OH)2 is amphoteric in nature so its solubility increases in both acidic as will as strongly basic
solution.
gy- (A) AgBr ds fy,, Ksp = [Ag+] [Br–]
vr% [Br–] dks c<+kus ij, AgBr dh foys;rk ?kVrh gSA
(B) AgCN ds fy,, Ksp = [Ag+] [CN–]
CN– dk tyvi?kVu gksrk gS blfy, ty esa bldh foys;rk vuqekfur foys;rk ls vf/kd gksrh gSA
vEyh; foy;u esa] CN– dk izksVksuhdj.k gksrk gS vr% AgCN dh foys;rk c<+rh gSA
AgCN, CN– ds vkf/kD; esa Ag(CN)2– dk ladqy cukrk gSA
(C) Fe(OH)3 ds fy,, Ksp = [Fe3+] [OH–]3.
vEyh; foy;u esa] OH– ?kVrs gS vr% foys;rk c<+rh gSA
OH– dh mifLFkfr esa foys;rk ?kVrh gSA
(D) Zn(OH)2 ds fy,, Ksp = [Zn2+] [OH–]2
Zn(OH)2 mHk;/kehZ gS blfy, bldh foys;rk vEyh; rFkk {kkjh; ek/;e esa c<+rh gSA
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.-67
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029